The present disclosure relates to a system and method for control of a stripper tower. More particularly, the present disclosure relates to a system and a method for adjusting the amount of saturated steam flowing into an ammonia stripper tower based on one or more temperature measurements in the stripper tower to inhibit under stripping conditions and/or to inhibit over stripping conditions.
Stripping is a process in which a first component is separated from a second component based on a difference in the vapor pressure between the first component and the second component. An ammonia stripper tower, also referred to as an ammonia stripper column, can be used to separate ammonia from an aqueous solution comprising ammonia and water. The stripper tower can be a cylindrical column comprising a packing medium. The stripper tower includes an inlet for receiving the aqueous solution. The stripper tower further includes a vapor outlet near the top of the tower for exhausting ammonia vapor, and an underflow outlet near the bottom of the tower for exhausting aqueous solution. An inlet for receiving saturated steam (the stripping medium) is also provided in the stripping tower.
During operation of the ammonia stripper tower, the aqueous feed solution enters the tower and flows downward through the packing. Simultaneously, saturated steam is introduced in the bottom of the stripper tower and rises upward through the packing. As the aqueous solution flows through the packing, the aqueous solution is heated by the saturated steam. The heating vaporizes the ammonia in the aqueous solution. The vaporized ammonia flows upward in the stripper tower and exits through the vapor outlet. The remaining aqueous solution, which is not vaporized, continues to flow downward through the packing material and exits the stripper tower through the underflow outlet. Large differences in the vapor pressures of ammonia and water allow for a high degree of separation of ammonia and water in a stripper tower at relatively low operating pressure conditions. A properly calibrated stripper tower can separate substantially all of the ammonia from an aqueous feed stream as ammonia vapor and provide an aqueous underflow stream having a relatively low ammonia concentration.
Ammonia stripping can be used during the chilled ammonia process to enable reuse of ammonia in that process. The chilled ammonia process is used to remove carbon dioxide from flue gases generated during combustion, for example, in a coal fired boiler. The process results in an aqueous solution comprising water and ammonia. Ammonia stripping is used to separate the ammonia from the water. After separation, the ammonia is reused in the chilled ammonia process. The reuse of ammonia enabled by the stripping process reduces the cost of performing the chilled ammonia process because it reduces rate at which new ammonia must be added to perform the chilled ammonia process.
Under stripping is a condition that occurs during the stripping process when the amount of saturated steam provided to the stripper tower is not sufficient to strip substantially all of the ammonia from the aqueous solution. As a result, the concentration of ammonia in the aqueous underflow solution increases. Under stripping conditions decrease the efficiency of performing the chilled ammonia process because ammonia must be added to the system to account for the ammonia in the aqueous underflow solution that is not vaporized during the stripping process, and is therefore not available for reuse in the chilled ammonia process.
Over stripping is a condition that occurs when the amount of saturated steam provided to the stripper tower is more than sufficient to vaporize the ammonia in the aqueous feed solution. As a result the additional saturated steam, some of the water in the aqueous solution is also vaporized. During over stripping conditions, energy is expended to generate the saturated steam that vaporizes the water. This additional energy outlay increases the cost of performing the chilled ammonia process.
According to aspects illustrated herein, a method for operating a stripper tower is disclosed. The method includes the step of measuring a temperature TM of an aqueous solution at a first elevation in the stripper tower. Temperature TC, which corresponds to the temperature of saturated steam at the operating pressure of the stripper tower, is calculated. The method further includes the step of calculating a temperature TDELTA. TDELTA is the difference between a temperature of an aqueous solution in the stripper tower subject to over stripping conditions and a temperature of an aqueous solution in the stripper tower subject to normal stripping conditions. The method further includes the step of adjusting a flow rate of saturated steam into the stripper tower so that TM is substantially equivalent to the difference between TC and TDELTA.
According to other aspects illustrated herein, a system for stripping ammonia from an aqueous solution is disclosed. The system includes a stripper tower having an inlet for receiving an aqueous solution and an inlet for receiving saturated steam. A first temperature sensor is configured to measure a temperature TM of the aqueous solution at a first elevation in the stripper tower. The system includes a controller with software executing thereon. A first database contains a plurality of temperatures TC, wherein each TC corresponds to a temperature of saturated steam at an operating pressure of the stripper tower. A second database contains a plurality of temperatures TDELTA, wherein each TDELTA corresponds to a difference between a temperature of the aqueous solution in the stripper tower at the first elevation subject to over stripping conditions and a temperature of the aqueous solution in the stripper tower at the first elevation with normal stripping conditions. Software executing on the controller queries the first database by the operating pressure of the stripper tower to retrieve a TC. Software executing on the controller queries the second database by the temperature of the aqueous solution in the stripper tower at the first elevation to retrieve a TDELTA. Software executing on the controller generates a signal indicative of an adjustment of a flow rate of saturated steam into the stripper tower so that TM is equivalent to the difference between TC and TDELTA.
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It should be understood that although the disclosed system and method are described in relation to a specific embodiment of a stripper tower 100, the disclosed system and method are not limited in this regard. For example, the disclosed system and method can be adapted by a person of ordinary skill in the art to account for variations in the design of the stripper tower 100, the operating conditions of the stripper tower, and the properties of the aqueous solution being processed in the stripper tower, among other variables. To the extent specific dimensions, values, or specific operating conditions are included in this description, they are provided to broadly illustrate the system and method and are not intended to limit the scope of this disclosure.
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The stripper tower 100 includes a vapor outlet 120 near the top 102 of the stripper tower. The vapor outlet 120 is in fluid communication with a conduit 122 for receiving vapor generated during the stripping process. During operation, vaporized ammonia exits the stripper tower 100 via the vapor outlet 120. The stripper tower 100 includes an underflow outlet 130 near the bottom 106 of the stripper tower. The underflow outlet 130 is in fluid communication with a conduit 132 for receiving the aqueous solution the flows downward through the packing 104. During operation, aqueous solution that is not vaporized, including any unvaporized ammonia, exits the stripper tower 100 via the underflow outlet 130.
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The saturated steam conduit 142 includes a valve 160 that can be adjusted between an open position and a closed position to vary the flow rate of saturated steam entering the stripper tower 100. The controller 150 is in communication with the valve 160. The system 10 includes software 152 executing on the controller 150 for generating a signal indicative of a setting for the valve 160 to achieve a desired flow rate of saturated steam into the stripper tower 100. The signal is transmitted from the controller 150 to the valve 160 and the valve is adjusted accordingly such that the flow rate of saturated steam into the stripper tower 100 corresponds to the generated signal. In this way, the system 10 can control the flow rate of saturated steam into the stripper tower 100.
The disclosed system 10 and method is capable of affecting the stripping conditions in the stripper tower 100 by controlling the flow rate of saturated steam into the stripper tower 100. For example, if under stripping conditions occur, the valve 160 can be controlled to increase the flow rate of saturated steam into the stripper tower 100, thereby inhibiting the under stripping conditions. If, for example, over stripping conditions occur in the stripper tower 100, the valve 160 can be controlled to decrease the flow rate of the saturated steam into the stripper tower 100, thereby inhibiting over stripping conditions. If, for example, normal stripping conditions occur, the valve 160 can be controlled to maintain the flow rate of saturated steam into the stripper tower 100, thereby maintaining normal stripping conditions.
The stripper tower 100 can be operated at a constant pressure. The specific constant pressure for operation depends on the type of stripper tower 100, the size of the stripper tower, the desired operation of the stripper tower, and the control of the stripper tower, among other variables. The operating pressure is typically in the range of 29 psig to 319 psig, although the operation of the stripper tower 100 is not limited in this regard and operating pressures for a stripper tower 100 may fall outside of this range.
The system 10 includes an interface 170 for inputting information indicative of the operating conditions of the stripper tower 100 into the controller 150. For example, the operating pressure of a stripper tower 100 can be input into the controller 150 via the interface 170. The interface 170 is in communication with the controller 150. Although the controller 150 and interface 170 are disclosed as separate elements in
The aqueous feed solution provided to the stripper tower 100 via the first inlet 110 has a specific ammonia content. In this description the ammonia content is generally provided as a molarity. The ammonia content of the aqueous feed solution depends on the upstream process, among other variables. The interface 170 enables a user to enter the ammonia content of the aqueous feed solution. During operation of the system 10 the aqueous underflow solution exiting the stripper tower 100 through the underflow outlet 130 typically has a target ammonia content. The actual ammonia content can vary based on the operating conditions of the stripper tower 100. The interface 170 enables a user to enter the target ammonia content of the aqueous solution exiting the stripper tower 100 through the underflow outlet 140. Although the system 10 is disclosed as having an interface 170 for receiving an input indicative of the ammonia content in the aqueous feed solution being provided to the stripper tower 100, or a target ammonia content in the aqueous underflow solution exiting the stripper tower 100 the present disclosure is not limited in this regard. For example, an alternative system in accordance with this disclosure may rely upon a sensor to detect the ammonia content of the aqueous feed solution flowing into the stripper tower 100 and transmit a signal indicative of that content to the controller 150.
The system 10 further includes a plurality of temperature sensors 180, 182 for measuring a temperature of the aqueous solution at specified points in and around the stripper tower 100. A first temperature sensor 180 is positioned near the underflow outlet 130 of the stripper tower 100. The first temperature sensor 180 is configured to measure a temperature of aqueous underflow solution exiting the stripper tower 100 via the underflow outlet 130. Although
The system 10 includes a second temperature sensor 182 positioned at a first elevation in the stripper tower 100. The second temperature sensor 182 is configured to measure a temperature of the aqueous solution in the packing medium 104 at the first elevation. Although not shown in
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The information included in the second database 192 can be determined theoretically and/or experimentally. For example, the information can be determined theoretically using calculations based on the operating parameters of the stripper tower 100. The data can also be determined experimentally, for example, during calibration of the stripper tower 100. Additionally a combination of theoretic derivation and experimental measurement can be used to determine different TDELTA for different elevations in a stripper tower, among other variables. It should be understood that the second database 192 includes a plurality of temperatures TDELTA corresponding to different operating variables of the stripper tower 100, such as, for example, ammonia content of the aqueous feed solution. It should also be understood that chart 200 in
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As with the second database 192, the data included in the third database 194 can be determined theoretically and/or experimentally. It should be understood that the third database 194 includes a plurality of temperatures T1 corresponding to different operating variables of the stripper tower 100, such as, for example, different ammonia contents of the aqueous underflow solution exiting the stripper tower 100 at the underflow outlet 130 at different operating pressures of the stripper tower. It should also be understood that the chart 400 is for illustrative purposes and is not intended to limit the scope or volume of data included in third database 194.
During operation, the system 10 is capable of inhibiting under stripping conditions by adjusting the valve 160 to control the flow rate of saturated steam into the stripper tower 100 through the inlet 140. Under stripping conditions are inhibited by adjusting the valve 160 to control a flow rate of saturated steam into the stripper tower 100 so that TB is substantially equivalent to the difference between TC and T1. The first temperature sensor 180 measures the temperature TB of the aqueous underflow solution near the underflow outlet 130. The operating pressure of the stripper tower 100 is input into the controller 150 via the interface 170. Software 152 executing on the controller 150 queries the first database 190 by the input operating pressure to return a temperature TC of saturated steam at the operating pressure of the stripper tower 100. The ammonia content of the aqueous underflow solution exiting the stripper tower 100 at the underflow outlet 130 is input into the controller 150 via the interface 170. Software 152 executing on the controller queries the third database 194 by the input ammonia content and by the input operating pressure to retrieve a temperature T1. Software 152 executing on the controller 160 generates a signal indicative of an adjustment of a flow rate of saturated steam into the stripper tower 100 at the inlet 140 so that TB is substantially equivalent to the difference between TC and T1. The signal indicative of the adjustment of the flow rate is transmitted to the valve 160 and the valve is adjusted to control the flow rate of saturated steam accordingly. This process can be repeated so that TB is substantially equivalent to the difference between TC and T1 during operation of the stripper tower 100 thereby inhibiting under stripping conditions.
During operation, the system 10 is capable of inhibiting over stripping conditions by adjusting the valve 160 to control the flow rate of saturated steam into the stripper tower 100 through the inlet 140. Over stripping conditions are inhibited by adjusting the valve 160 to control a flow rate of saturated steam into the stripper tower 100 so that TM is substantially equivalent to the difference between TC and TDELTA. The second temperature sensor 182 measures the temperature TM of the aqueous solution at a first elevation in the packing. The operating pressure is input into the controller 150 via the interface 170. Software 152 executing on the controller 160 queries the first database 190 by the inputted operating pressure to return a temperature TC, wherein TC corresponds to the temperature of saturated steam at the operating pressure of the stripper tower 100. The content of ammonia of the aqueous feed solution entering the stripper tower 100 at the inlet 110 is input into the controller 150 via the interface 170. Software 152 executing on the controller queries the second database 192 by the inputted content of the ammonia and by the inputted operating pressure to retrieve a temperature TDELTA. Software 152 executing on the controller 160 generates a signal indicative of an adjustment of a flow rate of saturated steam into the stripper tower 100 at the inlet 140 so that TM is substantially equivalent to the difference between TC and TDELTA. The signal indicative of the adjustment of the flow rate is transmitted to the valve 160 and the flow rate of saturated steam is adjusted accordingly. This process can be repeated so that TM is substantially equivalent to the difference between TC and TDELTA during operation of the stripper tower 100 thereby inhibiting over stripping conditions.
It should be understood that the described method and system for inhibiting over stripping and for inhibiting under stripping is provided for illustrative purposes only and is not intended to limit the disclosure. For example, the method and system for inhibiting over stripping can use a plurality of temperature sensors, wherein each temperature sensor is positioned at a different elevation in the packing tower. The controller can subsequently determine an appropriate TDELTA for each elevation based on the operating conditions of the stripper tower. In other embodiments, the control process for inhibiting under stripping and the control process for inhibiting over stripping are performed in a serial manner. For example, the control process for inhibiting under stripping is performed during the start up of a stripper tower. After it is determined that TB is substantially equivalent to the difference between TC and T1, the control process for inhibiting over stripping is implemented.
Although the present disclosure has been described with reference to certain embodiments thereof, it should be noted that other variations and modifications may be made, and it is intended that the following claims cover the variations and modifications within the true scope of the disclosure.