1. Field of the Invention
The present invention relates generally to the cleaning of a flue gas and, in one embodiment, to a device, system and method that mitigates and/or prevents slurry deposition at the flue inlet to a wet flue gas desulfurization (WFGD) unit in order to keep the inlet dry and minimize deposition (e.g., deposition scale) at the flue inlet to the WFGD tower. In one embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box located proximate the inlet transition zone. In another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising at least one chill plate located proximate the inlet transition zone. In still another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box and at least one chill plate, where both devices are located proximate the inlet transition zone.
2. Description of the Related Art
While not wishing to be bound to any one theory, it is believed that the formation of the scale starts in the two lower corners of the WFGD inlet with the lowest gas flow, and thus, the highest possibility of stagnation and highest potential of liquid to gas in the inlet. One non-limiting theory is that in the specific case of tile-lined WFGD towers allow for more adhesion of the scale due to the porous nature of the grout and/or tile utilized therein. This allows for large pieces of scale to form and shed at one time.
Given this, one potential solution to the above problem is disclosed in U.S. Pat. No. 5,403,523 where a deflection system is utilized to maintain a cleaner WFGD inlet. Given this, an exemplary prior art solution is illustrated in
Turning to Figures,
As illustrated in
In the absence of an inlet awning 28, a thin liquid film of liquid slurry 30 flowing downwardly along the walls of the wet scrubber module 12 contacts the hot flue gas 16. However, the amount of water present in the thin liquid film of slurry 30 falling across the inlet opening to the wet scrubber module 12 is not sufficient to completely quench and humidify the hot flue gas 16. The inlet awning 28 collects all the liquid slurry 30 that falls on top of it and channels the liquid slurry 30 to the gap 38 to form the thick liquid slurry curtain 40. This larger amount of water diverted by the inlet awning 28 and forming the liquid slurry curtain 40 exceeds what is needed for complete and instantaneous quenching and humidification of the hot flue gas 16. This complete and sudden quench and humidification reduces the wet/dry interface and the possibility of solid deposition.
In the absence of an inlet awning 28, if the liquid slurry 30 and hot flue gas 16 combination contacts any surface of the inlet flue 18 or housing 14, solid deposits will form as the liquid slurry 30 evaporates. Solids form at the wet/dry interface because the water present is not sufficient to continuously and fully humidify the incoming gas. These solid deposits build up over time, which requires the wet scrubber module 12 to be shut down so that maintenance personnel can enter the wet scrubber module 12 and remove the deposits. Shut down of a wet scrubber module 12 requires that either spare wet scrubber modules 12 be available to clean the flue gas 16, that the boiler load is reduced so that the amount of flue gas produced does not exceed the capacity of the remaining on-line wet scrubber modules 12, or that there is a discharge of partially or untreated flue gas 16 directly into the atmosphere. All of these alternatives are undesirable and not accepted by the industry. It is thus preferable to maintain the wet/dry interface of the liquid slurry 30 with the hot flue gas 16 away from these surfaces, and the inlet awning 28 accomplishes this result by creating the liquid slurry curtain 40. The liquid slurry curtain 40 is maintained away from these surfaces because the inlet awning 28 extends downwardly and into the cylindrical housing 14 of wet scrubber module 12. The liquid slurry curtain 40 also provides more water than required for humidification.
As shown in
Hydraulic testing of the known inlet flue 18 and inlet awning 28 devices described above revealed a significant flue gas side total pressure drop. High flue gas side pressure drops require increased fan pressure capability, resulting in increased fan and motor capacity and increased operating costs for the life of the unit. This is very undesirable because even a 1.0 inch H2O gas side pressure drop can be assessed at values which can reach one million dollars. Therefore, reducing the flue gas side pressure drop in the wet scrubber equipment is an effective way to reduce costs. However, such reductions must still be achieved in a manner which prevents unwanted deposition of dried slurry material at the transition interface and/or zone.
Given the above, a need exists in the art for a device, system and/or method by which to reduce the amount of slurry material that deposits in the transition interface and/or zone where the flue gas inlet meets the WFGD tower.
The present invention relates generally to the cleaning of a flue gas and, in one embodiment, to a device, system and method that mitigates and/or prevents slurry deposition at the flue inlet to a wet flue gas desulfurization (WFGD) unit in order to keep the inlet dry and minimize deposition (e.g., deposition scale) at the flue inlet to the WFGD tower. In one embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box located proximate the inlet transition zone. In another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising at least one chill plate located proximate the inlet transition zone. In still another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box and at least one chill plate, where both devices are located proximate the inlet transition zone.
Accordingly, one aspect of the present invention is drawn to a scale prevention system for a wet flue gas desulfurization unit (WFGD), the system comprising: a flue structure, wherein the flue structure is connected to the inlet of an wet flue gas desulfurization unit; at least two air nozzles, each air nozzle having a respective air supply line, wherein the at least two air nozzles are positioned on the interior of the flue so as to provide air coverage across the horizontal width of the flue inlet to the wet flue gas desulfurization unit; and at least one inlet awning designed to deflect a slurry from the wet flue gas desulfurization unit, the at least one inlet awning being position above the flue inlet to the wet flue gas desulfurization unit.
In yet another aspect of the present invention, there is provided a scale prevention system for a wet flue gas desulfurization unit (WFGD), the system comprising: a flue structure, wherein the flue structure is connected to the inlet of an wet flue gas desulfurization unit; at least two air nozzles, each air nozzle having a respective air supply line, wherein at least one air nozzle is positioned on each opposite vertical interior wall of the flue so as to provide air coverage across the horizontal width of the flue inlet to the wet flue gas desulfurization unit; and at least two lateral air nozzles, each lateral air nozzle having a respective air supply line, wherein each lateral air nozzle is positioned internally of each of the at least two air nozzles and are positioned at the top edge of the flue inlet to the wet flue gas desulfurization unit so as to provide air coverage across the horizontal width of the flue inlet to the wet flue gas desulfurization unit.
In yet another aspect of the present invention, there is provided a scale prevention system for a wet flue gas desulfurization unit (WFGD), the system comprising: a flue structure, wherein the flue structure is connected to the inlet of an wet flue gas desulfurization unit; and at least two chill plates, each chill plate having a respective supply line, wherein the at least two chill plates are positioned on the interior of the flue so as to provide temperature control across the horizontal width of the flue inlet to the wet flue gas desulfurization unit.
The various features of novelty which characterize the invention are pointed out with particularity in the claims annexed to and forming a part of this disclosure. For a better understanding of the invention, its operating advantages and specific benefits attained by its uses, reference is made to the accompanying drawings and descriptive matter in which exemplary embodiments of the invention are illustrated.
The present invention relates generally to the cleaning of a flue gas and, in one embodiment, to a device, system and method that mitigates and/or prevents slurry deposition at the flue inlet to a wet flue gas desulfurization (WFGD) unit in order to keep the inlet dry and minimize deposition (e.g., deposition scale) at the flue inlet to the WFGD tower. In one embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box located proximate the inlet transition zone. In another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising at least one chill plate located proximate the inlet transition zone. In still another embodiment, a wet flue gas desulfurization (WFGD) unit, system and/or method according to the present invention comprises, among other features, a scale prevention system comprising a plenum air device and/or forced-air box and at least one chill plate, where both devices are located proximate the inlet transition zone.
As used herein, “inlet transition zone” is defined to mean the area in the WFGD inlet and/or tower where the temperature gradient is changing from “hot” to “cold” and/or the flue gas is experiencing a change in the amount of water saturation in the flue gas due to contact of the flue gas with the slurry from the WFGD. As would be apparent to those of skill in the art, the “inlet transition zone” is not located in one specific area. Rather, the “inlet transition zone” varies from one WFGD unit to another, or can even vary within the same WFGD depending upon operating conditions.
Regarding the air utilized in the various scale mitigation and/or prevention systems of the present invention, the air supplied to the various air lines and/or piping of any one or more embodiments of the present invention can be supplied from temperature controlled air from any suitable source (e.g., from any suitable air pump, compressor, etc.), or can be supplied from any surplus oxidation air that might be available from the oxidation air being supplied to the WFGD. In another embodiment, the air supplied to the various air lines and/or piping of any one or more embodiments of the present invention can be supplied from any combination of temperature controlled air from any suitable source (e.g., from any suitable air pump, compressor, etc.) and any surplus oxidation air that might be available from the oxidation air being supplied to the WFGD.
Furthermore, the temperature of the air supplied to the various air lines and/or piping of any one or more embodiments of the present invention should be within a range of about −25° F. to about +25° F. of the WFGD slurry temperature. In another embodiment, the temperature of the air supplied to the various air lines and/or piping of any one or more embodiments of the present invention should be within a range of about −20° F. to about +20° F., or about −15° F. to about +15° F., or about −10° F. to about +10° F., or about −5° F. to about +5° F., or even about −2.5° F. to about +2.5° F. of the WFGD slurry temperature. Here, as well as elsewhere in the specification and claims, individual range values and/or limits can be combined to form additional non-disclosed ranges.
Turning to the Figures,
Turning to
In one embodiment, lateral clean-out nozzles 238 and baffle plate 240 are located along the bottom edge of flue 202 as it enters into tower 204. In another embodiment, lateral clean-out nozzles 238 and baffle plate 240 are located along the top edge of flue 202 as it enters into tower 204. For the purposes of the present invention, the bottom edge of flue 202 is located closest to the bottom of tower 204. Baffle plate 240 is placed between lateral clean-out nozzles 238 in order to create multiple air zones due to the presence of at least two lateral clean-out nozzles. In one embodiment, the existence of baffle plate 240 permits each of the left and right lateral clean-out nozzles 238 to be operated independently of one another thereby permitting customized control of the air provided to the left and right portions of flue 202 as it enters tower 204. In another embodiment, left and right clean-out nozzles 238 can be operated in tandem rather than independently.
Given the above, the combination of side clean-out nozzles 236 and lateral clean-out nozzles 238 direct clean-out air supplied via each clean-out nozzle's respective air line and/or piping 234 in the same general direction as the flue gas flow direction (denoted by arrow 212). In another embodiment, although not illustrated, scale prevention system 200 can further include an inlet awning and/or sidewalls that cover/surround the top and/or side portions of flue 202 so as to prevent WFGD slurry “raining” down from above and then entering flue 202. Accordingly, the combination of left and right air lines and/or piping 234, left and right side clean-out nozzles 236, left and right lateral clean-out nozzles 238, and baffle plate 240 act together to prevent WFGD slurry from entering into flue 202 and causing scale to build-up on the WFGD-end of flue 202.
Turning to
In still another embodiment, although not illustrated, scale prevention system 300 can further include an inlet awning and/or sidewalls that cover/surround the top and/or side portions of flue 302 so as to prevent WFGD slurry “raining” down from above and then entering flue 302.
Turning to
It should be noted that the size, height and/or width of any of the nozzles, chill plates and/or baffle plates of the present invention can be varied as needed and/or desired. Accordingly, the present invention is not limited to just one geometric shape, layout, and or design orientation. Furthermore, the various nozzles, chill plates, and/or baffle plates can be operated in combination, various sub-combinations, or even each item independently.
While not wishing to be bound to any one advantage, or set of advantages, a scale prevention system according to the present invention prevents scale from forming and then falling into the WFGD tank. Alternatively, if scale forms the scale that forms is smaller in size and is able to broken-up into smaller pieces by the agitators and pump (absorber recycle pumps and/or bleed pumps). Given this, in the bleed pump stream, the scale pieces are able to be pumped into the primary hydroclones. The one or more systems of the present invention prevent larger scale pieces from forming and thereby prevents such scale pieces from entering into the one or more hydroclones were such pieces are not able to be removed in the underflow stream. This reduces plugging of the one or more hydroclones and thus reduces the frequency of maintenance intervals.
The present invention is also advantageous over those systems that utilize some type of water-based system to prevent scale formation at the tower end of a flue entering a WFGD. Such water-based systems are subject to a number of drawbacks including, but not limited to, undesirable variations in the WFGD tower water/aqueous balance, corrosion at the tower end of the flue entering the WFGD; and/or water supply problems that might actually end up causing an increase in scale formation.
Another potential advantage attributable to the present invention is the reduction in scale size and frequency reduces the amount and size of scale pieces that are forced through the Absorber Recycle (AR) pumps. This has the potential of reducing the amount of abrasive particles in the pump stream. Furthermore, scale pieces are typically pushed into the AR headers and into the slurry nozzles in the upper portion of the towers. These nozzles have small openings and if enough scale pieces become wedged together, there is a high likelihood of plugging AR nozzles and/or headers. Such plugging leads to a drop in SO2 removal as well as the risk of lower limestone utilization by the system. Accordingly, the one or more embodiments of the present invention can reduce the severity and/or occurrence of this phenomena thereby resulting in better SO2 removal rates as well as less damage to the one or more AR nozzles.
Given the above, the embodiments of the present invention utilize two different principles to reduce the amount of scale that forms at the flue inlet of a WFGD. The embodiments of
In still another embodiment, the air source for the various embodiments of the present invention is provided from the WFGD's oxidation air flow into the tower, then an added benefit is realized in that WFGD sites are designed and are operating with (due to tower loading turn-down) excess oxidation air. This excess oxidation air leads to adverse chemistry effects in some plants including but not limited to: (a) strong oxidizer formation with downstream impacts; (b) tower corrosion from manganese deposition forming a galvanic bridge to drive fluoride induced under-deposit corrosion; (c) adverse selenium speciation; and (d) mercury reemission. Accordingly, the use of such excess oxidation air can help to reduce, mitigate and/or eliminate one or more of the above noted negative effects.
The embodiments of
While specific embodiments of the present invention have been shown and described in detail to illustrate the application and principles of the invention, it will be understood that it is not intended that the present invention be limited thereto and that the invention may be embodied otherwise without departing from such principles. In some embodiments of the invention, certain features of the invention may sometimes be used to advantage without a corresponding use of the other features. Accordingly, all such changes and embodiments properly fall within the scope of the following claims.
This patent application claims priority to U.S. Provisional Patent Application No. 61/717,133 filed Oct. 23, 2012 and titled “System and Method for Controlling Scale Build-Up in a WFGD.” The complete text of this application is hereby incorporated by reference as though fully set forth herein in its entirety.
Number | Date | Country | |
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61717133 | Oct 2012 | US |