The present invention generally relates to a thermal power plant. The present invention more particularly relates to methods and systems to integrate process control schemes for the capture of carbon dioxide with power plant steam to minimize waste heat.
Fossil fuel and natural gas power stations conventially use steam turbines and other machines to convert heat into electricity. The combustion of these fuels produce a flue gas stream that includes acid gases including carbon dioxide CO2, nitrogen oxides NOx and sulfur oxides SOx. Efforts have been made to reduce the emission of acid gases from these power stations, and in particular, to reduce the emission of greenhouse gases including CO2. As such, CO2 capture systems have been integrated into these power stations. Numerous advances have been made in this respect, leading to the CO2 generated during the combustion of fossil fuels being partly to completely separated from the combustion gases. Recently, there has been interest in aqueous absorption and stripping processes using aqueous amines to remove acid gas contaminants from combustion gas streams.
Gas absorption is a process in which soluble components of a gas mixture are dissolved in a liquid. Gas/liquid contact can be counter-current or co-current, with counter-current contact being most commonly practiced. Stripping is essentially the inverse of absorption, as it involves the transfer of volatile components from a liquid mixture to a gas. In a typical carbon dioxide removal process, absorption is used to remove carbon dioxide from a combustion gas, and stripping is subsequently used to regenerate the solvent and capture the carbon dioxide contained in the solvent. Once carbon dioxide is removed from combustion gases and other gases, it can be captured and compressed for use in a number of applications, including sequestraton, production of methanol, and tertiary oil recovery.
To effect the regeneration of the absorbent solution, the rich solvent drawn off from the bottom of the absorption column is introduced into the upper half of a stripping column, and the rich solvent is maintained at an elevated temperature at or near its boiling point under pressure. The heat necessary for maintaining the elevated temperature is furnished by reboiling the absorbent solution contained in the stripping column, which requires energy and thus increases overall operational costs.
Hence, there exists a need to provide a cost effective and operationally efficient energy source to the reboilers to regenerate the loaded aqueous amine stream.
An objective of the present invention is to provide a system and method for efficiently providing heat to an acid gas absorption/stripping process integrated with a steam power generation system.
Another objective of the present invention is to optimize overall power generation plant performance by the use of special arrangements of steam tapings (extraction points) from different turbine stages and water and/or steam cycle locations to provide energy for acid gas capture systems.
Another objective of the present invention is to provide special arrangements of steam tapings (extraction points) from different turbine stages and water and/or steam cycle locations to provide energy for acid gas capture systems that can be designed into new or retrofitted into existing power generation system designs.
Another objective of the present disclosure is to provide process control schemes to integrate steam power generation load and energy production for acid gas capture.
Accordingly, and depending on the operational and design parameters of a known technology for capture of acidic gases, an objective of the present invention may reside in the reduction of energy.
Furthermore, an objective of the present invention may reside in the environmental, health and/or economical improvements of reduced emission of chemicals used in such a technology for acid gas absorption.
In one aspect, a plant is disclosed that includes a boiler unit that produces steam, a power generation unit including at least one power generation turbine that receives the steam from the boiler unit, a gas recovery unit including two or more regenerator columns, and a secondary source of steam providing steam to each of the two or more regenerators columns at different rates.
In another aspect, a method for providing steam to a gas recovery unit is disclosed that includes providing steam to a secondary source of steam from either a boiler unit or a power generation unit, and discharging steam from the secondary source of steam, providing steam discharged from the secondary source of steam to two or regenerator columns of a gas recovery unit at different rates.
Referring now to the figures, which are exemplary embodiments, and wherein the like elements are numbered alike.
Specific embodiments of systems and processes for utilizing power generation steam to provide energy to acid gas recovery according to the invention are described below with reference to the drawings.
As can be seen in
The power generation unit 119 includes a primary consumer of steam 120 and a power generation unit 125. In this exemplary embodiment, the primary consumer of steam 120 is one or more steam turbines. The one or more steam turbines 120 are coupled to the power generation unit 125 to provide mechanical energy to the power generator 125 to generate electricity 125A. The electricity may be provided to an electrical power grid (not shown). In this exemplary embodiment, the one or more steam turbines 120 includes a high pressure (HP) turbine 121, an intermediate pressure (IP) turbine 122, and a low pressure (LP) turbine 123. In another embodiment, the one or more steam turbines 120 may include a combination of any number of turbines of similar or varying operation pressure(s).
As can be further seen in
The gas recovery unit 130 may be an acid gas capture and recovery unit. The gas recover unit 130 includes a CO2 absorption unit 130a and a CO2 regeneration unit 130b. In one embodiment, the gas recovery unit 130 may be an amine based scrubbing unit. In one embodiment, the gas recovery unit 130 may be an advanced amine process for CO2 capture. In one embodiment, the advanced amine process may be a double matrix scheme including a matrix stripping configuration.
The CO2 absorption unit 130a includes a CO2 absorber (absorber) 231. The CO2 regeneration unit 130b includes two or more regenerator columns 153. Each regenerator column of the two or more regenerator columns 153 includes two or more reboilers 140. In one embodiment, one or more of the regenerator columns may have two or more reboilers. The arrangement of two or more regenerator columns 153 may be referred to as a matrix stripping configuration. In this exemplary embodiment, the two or more regenerator columns 153 includes a high pressure (HP) regenerator column 154 and associated first reboiler 141 and a low pressure (LP) regenerator column 155 and associated second reboiler 142.
The absorber 231 is provided a gas stream containing CO2 from the steam boiler unit 110 via a feed line 231a. The gas steam may be a flue gas steam. In one embodiment, the flue gas may be treated by a flue gas desulfurization unit (not shown) and/or a cooling unit (not shown) before being provided to the absorber 231. In the absorber 231, flue gas is contacted with a solvent solution that removes CO2 from the flue gas by absorption. The solvent solution may be an amine-based solvent solution. The flue gas stream, having CO2 removed, is discharged from the absorber 231 via a discharge line 231b. The absorber 231 may further include a fluid wash cycle 232 that may include a fluid wash pump 233 and a fluid wash cooler 234 to eliminate any solvent carryover.
To effect the regeneration of the solvent solution, the rich CO2 solvent solution drawn off from the bottom of the absorber 231 is introduced into the upper half of each of the two or more regenerator columns 153, and the rich solvent is maintained at a temperature at which CO2 boils off under pressure in each column. The heat necessary for maintaining the boiling point is furnished by one or more reboilers associated with each regenerator column. The reboiling process is effectuated by indirect heat exchange between part of the solution to be regenerated and a hot fluid at appropriate temperature. In the course of regeneration, the carbon dioxide contained in the rich solvent to be regenerated maintained at its boiler point is released and stripped by the vapors of the absorbent solution. Vapor containing the stripped CO2 emerges at the top of the regenerator column and is passed through a condenser system which returns to the regenerator column the liquid phase resulting from the condensation of the vapors of the absorbent solution that pass out of the regenerator column with the gaseous CO2. At the bottom of the regenerator column, the hot regenerated absorbent solution, also called the lean solvent solution, is drawn off and recycled.
In this exemplary embodiment, the HP regenerator column 154 and the LP regenerator column 155 are interconnected with the CO2 absorber 231 by a fluid interconnection system 235 that circulates solvent solution for CO2 absorption/desorption. The fluid interconnection system includes a lean cooler 236, a semi-lean cooler 237, a LP rich solution pump 238, a HP rich solution pump 239, a semi-lean/rich heat exchanger 240, a semi-lean solution pump 241, a lean/rich heat exchanger 242, a lean solution pump 243 and various lines and feeds as shown.
The solvent solution, such as an amine solution, from the CO2 absorber 231, which is discharged from the CO2 absorber rich in CO2, or in other words, CO2 rich solvent, is provided to the HP regenerator column 154 and the LP regenerator column 155 where CO2 is stripped from the solvent. CO2 is discharged from the HP regenerator column 154 and the LP regenerator column 155 via discharge lines 244 and 245, respectively, which combine for form a discharge line 246. Discharge line 246 feeds a CO2 cooler, where residual moisture is removed from the CO2 stream. A CO2 product stream is discharged from the gas recovery unit 130 via CO2 product discharge line 248.
As can be further seen in
Reduced pressure steam is discharged from the auxiliary turbine 124 and provided to the gas recovery unit 130 via an auxiliary steam line 124a. The reduced pressure steam may be provided at a pressure of between about 5 bar and about 20 bar and at a temperature of less than about 300° C.
The reduced pressure steam provided to the gas recovery unit 130 is provided to the first reboiler 141 and the second reboiler 142 via first and second auxiliary steam lines 124a2, 124a1, respectively. The reduced pressure steam is provided to each of the two or more regenerator columns 153 simultaneously and at different rates. Providing steam at different rates may include providing steam at different pressure, temperature and/or flow volume. Providing steam to each of the two or more regenerator columns 153 at different rates may be used to provided a different amount of energy to the each of the two or more regenerator columns 153 to improve the controllability of each regenerator column. The steam is provided to the two or more regenerator columns 153 at different rates by controlling the quality of the steam by using one or more steam control devices, such as but not limited to valves, expansion devices, throttling devices and any combination thereof. The regenerators 153 function in synch, however, the CO2 stripping rates and column pressures are different, to optimize the gas capture and recovery system 130 with respect to CO2 capture and energy. The first auxiliary steam line 124a2 and a second auxiliary steam line 124a1 provide steam to the first and second reboilers 141, 142 at different rates that provided a different amount of energy to the first and second reboilers 141, 142 to improve the controllability of each reboiler, which subsequently improves the controllability of the HP regenerator column 154 and the LP regenerator column 155, respectively. By improving the control of the HP regenerator column 154 and the LP regenerator column 155 by controlling the rate of steam to the first and second reboilers 141, 142, respectively, the power production of the power generation unit 119 is minimally reduced, or in other words, incurs the minimum penalty of the power production of the plant 100. Therefore the heat duty delivery is provided independent and flexible to maintain optimality of the system. In another embodiment, the reduced pressure steam is provided to the two or more reboilers 140 via two or more auxiliary steam lines.
According to the provided system and method, steam flow to the auxiliary turbine 124 is proportional to the power generated by the plant 100. In other words, more power generated by the plant 100 results in more steam available to be provided to the auxiliary turbine 124 and more steam available to the acid gas recovery unit 130. This provides a coarse anticipatory control action as the plant load changes.
In another embodiment, the ratio of steam to the auxiliary turbine 124 and steam provided to the HP turbine 121 may be calculated and maintained to a fixed value. The calculated ratio may provide a setpoint to the speed control of the HP turbine to minimize the pressure losses due to throttling the flow to the auxiliary turbine. In another embodiment, a top stage column temperature of the low pressure (LP) regenerator column 155 may be used to set the reboiler duty in the second reboiler 142.
The steam flow from the auxiliary turbine 124 to the two or more reboilers 140 may be used to control the regeneration of CO2 in the HP and LP regenerator columns 154, 155 since the flow of steam from the auxiliary turbine 124 to first and second reboilers 141, 142 may be used to control the temperature of the HP and LP regenerator columns 154, 155.
As shown in
In one embodiment, the steam in the LP steam line 310 is between about 3 bar and about 7 bar. In another embodiment, the steam in the LP steam line 310 is between about 4 bar and about 6 bar. In another embodiment, the steam in the LP line 310 is about 5 bar. In another embodiment, the steam in the LP feed line 310 is between about 300° C. and 400° C. In another embodiment, the steam in the LP steam line is between about 340° C. and 400° C. In yet another embodiment, the pressure in the LP steam line is about 400° C.
The boiler unit 110 includes a primary boiler loop 110a and a secondary boiler loop 110b. The primary boiler loop 110a receives water via a primary feed line 111a and discharges steam via a high pressure steam line 126. The secondary boiler loop 110b receives water via a secondary feed line 111b and discharges steam via a secondary steam line 516. In one embodiment, the steam discharged via the secondary steam line 516 is high pressure steam.
The steam saturator 524 receives steam from the secondary steam line 516. In one embodiment, steam from the secondary steam line 516 is provided to the steam saturator 524 at a pressure of between about 250 bar to about 320 bar and at a temperature of between about 580° C. and about 700° C. In another embodiment, the secondary steam line 516 provides steam to the steam saturator 524 at a pressure of between about 280 bar to about 300 bar and at a temperature of between about 600° C. and about 670° C.
As can be seen in
In one embodiment, the steam from the secondary steam line 516 is between about 500° C. and about 600° C. In another embodiment, the steam from the secondary steam line 516 is between about 510° C. and about 565° C. In another embodiment, the steam from the secondary steam line 516 is between about 150 bar and about 175 bar. In another embodiment, the steam from the secondary steam line 516 is between about 160 bar and about 165 bar.
Steam is provided and combined to the steam saturator 524 in a manner that produces a desired steam flow to the acid gas recovery unit 130 via auxiliary steam line 124a. In one embodiment, the reduced pressure steam may be provided at a pressure of between about 5 bar and about 20 bar and at a temperature of less than about 300° C. The reduced pressure steam is provided to first reboiler 141 and second reboiler 142. In another embodiment, the reduced pressure steam is provided to one or more reboilers. Depending on the power generation unit 119 demands, one or more of the auxiliary steam lines, as well as the secondary steam line 516 may be utilized or shut off.
While the invention has been described with reference to various exemplary embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
The present application claims the benefit under 35 U.S.C. §119(e) of Provisional Patent Application Ser. No. 61/469,919 entitled A SYSTEM AND METHOD FOR CONTROLLING WASTE HEAT FOR CO2 CAPTURE filed Mar. 31, 2011, the disclosure of which is incorporated herein by reference in its entirety. This Application is related to U.S. Patent Application No. 61/469,915, Attorney Docket No. W09/078-0(27849-0011), filed contemporaneously with this Application on Mar. 31, 2011, entitled “A SYSTEM AND METHOD FOR CONTROLLING WASTE HEAT FOR CO2 CAPTURE” assigned to the assignee of the present invention and which is incorporated herein by reference in its entirety.
Number | Date | Country | |
---|---|---|---|
61469919 | Mar 2011 | US | |
61469915 | Mar 2011 | US |