System and method for distributed thermoelectric heating and cooling

Information

  • Patent Grant
  • 9310112
  • Patent Number
    9,310,112
  • Date Filed
    Friday, May 23, 2008
    16 years ago
  • Date Issued
    Tuesday, April 12, 2016
    8 years ago
Abstract
A thermoelectric system and method provides distributed localized heating, cooling, or both heating and cooling. The thermoelectric system includes a plurality of thermoelectric assemblies. Each thermoelectric assembly comprises a plurality of thermoelectric elements, and each thermoelectric assembly is in thermal communication with a first working fluid and in thermal communication with a region corresponding to the thermoelectric assembly. Each thermoelectric assembly is selectively operable either to heat the region corresponding to the thermoelectric assembly by transferring heat from the first working fluid to the region corresponding to the thermoelectric assembly or to cool the region corresponding to the thermoelectric assembly by transferring heat from the region corresponding to the thermoelectric assembly to the first working fluid. Each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies.
Description
BACKGROUND

1. Field of the Invention


The present application relates generally to the field of ventilating, heating, and cooling systems for the creation and distribution of comfort air and the thermal management of sensitive systems for which temperature control is important.


2. Description of the Related Art


Heating and cooling to achieve comfort and to manage the temperature of critical systems and equipment is primarily accomplished through centralized systems. In these systems, hot and cold working fluids are used to provide temperature control for target objects within comparatively large volumes and surrounding structures. The system's capacity must be sized to heat or cool the target objects plus the thermal loads of the surrounding structures, extraneous objects and barrier materials. Heating and cooling of objects other than the targets results in significant energy waste, and slower response time for the system.


Variations of this system configuration involve conveying the working fluids conditioned in the central system to separate areas by means of specific ducts. This approach also suffers from the energy losses described above.


In buildings, centralized heating and cooling systems are used to establish and maintain occupant comfort, and in special cases, the temperature control of sensitive electronic equipment. These systems create and distribute heated and cooled air from a central point. The system is subject to significant losses as only a fraction of the thermal power developed by the central system reaches the target objects as the majority of the thermal capacity is wasted conditioning walls, ducting, ceilings, windows and furniture. Centralized heating and cooling systems with rotating mechanical parts tend to be noisy, and are subject to seal and other mechanical failures. The systems use ozone depleting refrigerants such as R-134A. With the exception of heat pump systems which operate over a narrow temperature range, a separate unit is required for heating.


Building heating and cooling is also provided by smaller, localized units, however such units utilize compressors for cooling which are noisy, vibrate, and utilize mechanical parts subject to failure, use ozone depleting refrigerants, and an additional unit is required for heating. The use of thermoelectric devices for these applications has been limited as they suffer from poor efficiency and use too much thermoelectric material to provide the needed capacity within cost constraints.


In automobiles, air is forced across an evaporator core within a centralized air handler unit to provide cool air to the passenger cabin in hot conditions. The cold air created in the air handler unit is distributed through a series of valves and air ducts to cool passengers. Such a system may supply 3,000 to 4,500 watts of cooled air at a steady state condition, of which the passengers require (and receive) only a small fraction. The majority of the cooled air is spent lowering the temperature of other parts of the cabin including the windows, head liner, seats and flooring. In addition, the cooling devices of such systems use chemicals such as R-134A with a high Green House Gas Index and operate with moving mechanical parts subject to failure.


In heating mode, the air handler unit provides heating through the same distribution system and suffers losses similar to those experienced by A/C systems as the majority of the warmed air is spent heating various elements of the cabin other than the occupants. Also, since waste heat from the engine coolant is used to heat occupants, the response time is slow. This is especially true for small-engine efficient vehicles such as diesels and hybrids. This condition has been recognized and Positive Temperature Coefficient (PTC) heaters are used to supplement engine coolant heating. However, such devices are inefficient.


The Climate Controlled Seat System (CCS™) described by Feher (U.S. Pat. No. 4,923,248, issued May 8, 1990, “Cooling and Heating Seat Pad Construction”), provides a thermoelectric system for distributed heating and cooling by embedding heating and cooling devices within an occupant's seat back and cushion, however it only partially addresses the need for occupant comfort because the human body requires heating and cooling of surfaces not touching the seat and backrest. In addition, the thermal capacity of the device is limited by the use of air as the sole working fluid due to its low heat capacity.


SUMMARY

In certain embodiments, a thermoelectric system provides distributed localized heating, cooling, or both heating and cooling. The thermoelectric system comprises at least one fluid conduit configured to allow a first working fluid to flow therein. The thermoelectric system further comprises a plurality of thermoelectric assemblies. Each thermoelectric assembly comprises a plurality of thermoelectric elements, and each thermoelectric assembly is in thermal communication with the first working fluid and in thermal communication with a region corresponding to the thermoelectric assembly. Each thermoelectric assembly is selectively operable either to heat the region corresponding to the thermoelectric assembly by transferring heat from the first working fluid to the region corresponding to the thermoelectric assembly or to cool the region corresponding to the thermoelectric assembly by transferring heat from the region corresponding to the thermoelectric assembly to the first working fluid. Each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies.


In certain embodiments, at least a portion of the first working fluid flows through the at least one fluid conduit such that the at least a portion of the first working fluid is sequentially in thermal communication with two or more thermoelectric assemblies of the plurality of thermoelectric assemblies. The at least a portion of the first working fluid can be heated by at least one of the thermoelectric assemblies and cooled by at least one of the thermoelectric assemblies. The first working fluid of certain embodiments flows repeatedly through the at least one fluid conduit. In certain embodiments, at least a portion of the first working fluid flows through the at least one fluid conduit such that the at least a portion of the first working fluid is not in thermal communication with two or more thermoelectric assemblies of the plurality of thermoelectric assemblies.


In certain embodiments, each thermoelectric assembly comprises a first side in thermal communication with the first working fluid and a second side in thermal communication with a second working fluid, and is configured to transfer heat between the first side and the second side. In certain embodiments the second working fluid is the same as the first working fluid, while in certain other embodiments, the second working fluid is different from the first working fluid. For example, the first working fluid can be water and the second working fluid can be air. In certain embodiments, at least one of the first working fluid and the second working fluid is a liquid (e.g., water). In certain embodiments, one of the first working fluid and the second working fluid is a liquid (e.g., water), and the other of the first working fluid and the second working fluid is a gas (e.g., air).


In certain embodiments, the thermoelectric system further comprises one or more valves which are adjustable to control flow of the first working fluid in the at least one fluid conduit. In certain such embodiments, the one or more valves are adjustable to place one or more selected thermoelectric assemblies in thermal communication with the first working fluid.


In certain embodiments, the thermoelectric system further comprises a thermal storage reservoir fluidically coupled to the at least one fluid conduit. The thermal storage reservoir is configured to receive the first working fluid. In certain embodiments, the thermal storage reservoir is also configured to store thermal power during peak generation events and to return thermal power to the first working fluid according to need. In certain embodiments, the thermoelectric system further comprises an intermediate heat exchanger in thermal communication with the first working fluid. The intermediate heat exchanger can be in thermal communication with a target object to be cooled or heated.


In certain embodiments, each thermoelectric assembly comprises a first heat exchanger in thermal communication with the first working fluid and a second heat exchanger in thermal communication with a second working fluid. In certain such embodiments, each second heat exchanger cools or heats the second working fluid to cool or heat the region corresponding to the thermoelectric assembly. In certain embodiments, the second working fluid flows from the region corresponding to the thermoelectric assembly to a volume to be cooled or heated. In certain embodiments, the second working fluid comprises a gas and the thermoelectric system further comprises one or more fans which drive the second working fluid from the region corresponding to the thermoelectric assembly to the volume.


In certain embodiments, the first heat exchanger comprises a plurality of fins. In certain embodiments, the second heat exchanger comprises a plurality of fins. In certain embodiments, each thermoelectric assembly comprises a plurality of N-type thermoelectric elements and a plurality of P-type thermoelectric elements, and each thermoelectric assembly further comprises a plurality of electrically conductive and thermally conductive connectors. Each of the connectors is in electrical communication and thermal communication with at least one of the plurality of N-type thermoelectric elements and with at least one of the plurality of P-type thermoelectric elements and in thermal communication with the first heat exchanger or the second heat exchanger. In certain such embodiments, each connector has a first portion and a second portion. The first portion is in thermal communication with the first heat exchanger or the second heat exchanger. The second portion is sandwiched between at least one of the plurality of N-type thermoelectric elements and at least one of the plurality of P-type thermoelectric elements.


In certain embodiments, a network of distributed thermoelectric assemblies is provided. The network comprises a plurality of thermoelectric assemblies. Each thermoelectric assembly has a first side and a second side. Each thermoelectric assembly is selectively operable either to heat a region corresponding to the thermoelectric assembly by transferring heat from a first working fluid to the region corresponding to the thermoelectric assembly or to cool the region corresponding to the thermoelectric assembly by transferring heat from the region corresponding to the thermoelectric assembly to the first working fluid. Each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies. Each thermoelectric assembly comprises a plurality of thermoelectric elements in thermal communication with the first side and with the second side of the thermoelectric assembly. Each thermoelectric assembly further comprises a first heat exchanger in thermal communication with the first side of the thermoelectric assembly. The first heat exchanger is configured to be in thermal communication with the first working fluid. Each thermoelectric assembly further comprises a second heat exchanger in thermal communication with the second side of the thermoelectric assembly and with the region corresponding to the thermoelectric assembly. The network further comprises one or more conduits fluidically coupled to the first heat exchangers of each thermoelectric assembly of the plurality of thermoelectric assemblies. The one or more conduits provide a flowpath through which the first working fluid flows to and from each of the first heat exchangers.


In certain embodiments, the first working fluid comprises water and can flow sequentially through the plurality of thermoelectric assemblies. The first working fluid of certain embodiments flows in parallel through at least some thermoelectric assemblies of the plurality of thermoelectric assemblies.


In certain embodiments, the second heat exchanger is configured to be in thermal communication with a second working fluid, which can comprise air. In certain embodiments, the second working fluid provides localized heating or cooling (e.g., conditioned air) to a volume. In certain embodiments, the volume comprises a passenger compartment of a vehicle or a portion of a building.


In certain embodiments, the network further comprises a central processing unit. Flow of the first working fluid through the one or more conduits to each first heat exchanger is adjustable in certain embodiments by at least one valve responsive to signals from the central processing unit. In certain embodiments, the network further comprises at least one sensor in electrical communication with the central processing unit. The central processing unit is configured to receive at least one signal from the at least one sensor. The at least one signal of certain embodiments is indicative of at least one condition within a volume to be locally heated or cooled. The at least one condition can be selected from the group consisting of: ambient temperature, local surface temperature, radiant loads, humidity, occupant number, occupant weight, occupant clothing thickness, and occupant location.


In certain embodiments, the network further comprises a thermal storage reservoir fluidically coupled to the one or more conduits. In certain such embodiments, the thermal storage reservoir is configured to store thermal power during peak generation events and to return thermal power to the first working fluid according to need. In certain embodiments, the network further comprises an intermediate heat exchanger fluidically coupled to the one or more conduits. In certain such embodiments, the intermediate heat exchanger is in thermal communication with a target object to be cooled or heated.


In certain embodiments, a network of distributed thermoelectric assemblies is provided for heating, cooling, or both heating and cooling localized portions of a passenger compartment of a vehicle. The network comprises a plurality of thermoelectric assemblies. Each thermoelectric assembly has a first side and a second side. Each thermoelectric assembly is selectively operable either to heat a region corresponding to the thermoelectric assembly by transferring heat from a first working fluid to the region corresponding to the thermoelectric assembly or to cool the region corresponding to the thermoelectric assembly by transferring heat from the region corresponding to the thermoelectric assembly to the first working fluid. Each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies. Each thermoelectric assembly comprises a plurality of thermoelectric elements in thermal communication with the first side and with the second side of the thermoelectric assembly. Each thermoelectric assembly further comprises a first heat exchanger in thermal communication with the first side of the thermoelectric assembly. The first heat exchanger is configured to be in thermal communication with the first working fluid. Each thermoelectric assembly further comprises a second heat exchanger in thermal communication with the second side of the thermoelectric assembly. The second heat exchanger is configured to be in thermal communication with a second working fluid. The network further comprises one or more conduits fluidically coupled to the first heat exchangers of each thermoelectric assembly of the plurality of thermoelectric assemblies. The one or more conduits provide a flowpath through which the first working fluid flows to and from each of the first heat exchangers.


In certain embodiments, the first working fluid has a first thermal capacity and the second working fluid has a second thermal capacity less than the first thermal capacity. For example, the first working fluid can comprise a liquid (e.g., a 50/50 mixture of ethylene glycol and water) and the second working fluid can comprise a gas (e.g., air). In certain embodiments, each first heat exchanger comprises extruded aluminum tubes and each second heat exchanger comprises aluminum fins brazed between aluminum face sheets.


In certain embodiments, the one or more conduits are selectively fluidically coupled by one or more valves to an engine coolant loop or an auxiliary cooling radiator of the vehicle. In certain embodiments, the one or more conduits are fluidically coupled by one or more valves to a heat exchanger in thermal communication with a vehicle battery or a vehicle fuel tank.


In certain embodiments, air from at least one of the second heat exchangers is outputted into the passenger compartment from at least one location selected from the group consisting of: the headliner, one or more pillars, one or more seat cushions, one or more seat backs, and the steering column. In certain embodiments, at least one of the second heat exchangers is configured to provide temperature control for electronic equipment of the vehicle, a vehicle battery, or an inner volume of a storage container of the vehicle.


In certain embodiments, the network further comprises at least one waste heat exchanger in thermal communication with the first working fluid and configured to direct heat from the first working fluid to a thermal mass outside the passenger compartment. The thermal mass of certain embodiments is selected from the group consisting of: a frame portion, a fuel tank, a battery, and a phase change thermal capacitor. In certain embodiments, the network is configured to be operable for a period of time during which a source of electrical power for the vehicle (e.g., an engine, a battery, a capacitor, a fuel cell, a solar cell, or a flywheel) is off. In certain embodiments, the source of electrical power is the primary source of electrical power for the vehicle.


In certain embodiments, a method for heating, cooling, or both heating and cooling localized portions of a vehicle is provided. The method comprises providing a thermoelectric system comprising at least one fluid conduit configured to allow a first working fluid to flow therein and a plurality of thermoelectric assemblies. Each thermoelectric assembly comprises a plurality of thermoelectric elements. Each thermoelectric assembly is in thermal communication with the first working fluid and in thermal communication with a region of the vehicle corresponding to the thermoelectric assembly. Each thermoelectric assembly is selectively operable either to heat the region corresponding to the thermoelectric assembly by transferring heat from the first working fluid to the region corresponding to the thermoelectric assembly or to cool the region corresponding to the thermoelectric assembly by transferring heat from the region corresponding to the thermoelectric assembly to the first working fluid. Each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies. The method further comprises preconditioning at least one region of the vehicle by operating at least one thermoelectric assembly of the thermoelectric system.


In certain embodiments, preconditioning the at least one region comprises cooling or heating at least a portion of a passenger compartment of the vehicle prior to an occupant entering the passenger compartment of the vehicle. In certain embodiments, preconditioning the at least one region comprises cooling at least a portion of a passenger compartment of the vehicle below a condensation temperature so as to remove water vapor from the passenger compartment. In certain embodiments, preconditioning the at least one region comprises placing a battery of the vehicle at an optimum temperature. In certain embodiments, preconditioning the at least one region comprises placing a catalytic converter of the vehicle at an optimum temperature.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 schematically illustrates an example thermoelectric system in accordance with certain embodiments described herein.



FIGS. 2A and 2B schematically illustrate two example thermoelectric (TE) assemblies in accordance with certain embodiments described herein.



FIGS. 3A and 3B schematically illustrate two views of an example TE assembly in accordance with certain embodiments described herein.



FIGS. 4A and 4B schematically illustrate two views of another example TE assembly in accordance with certain embodiments described herein.



FIG. 5 schematically illustrates an example thermoelectric system comprising a network of distributed, thermally isolated TE assemblies in accordance with certain embodiments described herein.



FIG. 6 schematically illustrates an example thermoelectric system further comprising a thermal storage reservoir and an intermediate heat exchanger in accordance with certain embodiments described herein.



FIGS. 7A and 7B schematically illustrate two views of an example TE assembly for automotive ventilating, heating, and cooling.



FIG. 8 schematically illustrates a radiator which receives the liquid working fluid used in one or more TE assemblies.



FIG. 9 schematically illustrates an auxiliary cooling radiator which receives the liquid working fluid used in one or more TE assemblies.



FIG. 10 schematically illustrates an example thermoelectric system in which the TE assemblies are scaled according to the required capacity of the thermoelectric system.



FIG. 11 schematically illustrates an example thermoelectric system in which the TE assemblies are located in the seat cushion and the seat back.



FIG. 12 schematically illustrates an example thermoelectric system in which one or more TE assemblies provide climate control of the passenger compartment and one or more TE assemblies provide temperature control of electronic equipment of the vehicle (e.g., such as batteries) in accordance with certain embodiments described herein.



FIG. 13 schematically illustrates an example TE assembly being used to heat and/or cool a volume in which beverages or other items are stored.



FIG. 14 schematically illustrates one or more heat exchangers connected with a portion of the liquid working fluid loop to transfer heat from the liquid working fluid to the outside of the passenger compartment.



FIG. 15 is a flow diagram of a method for heating, cooling, or both heating and cooling localized portions of a vehicle in accordance with certain embodiments described herein.





DETAILED DESCRIPTION

A distributed system described by Elliot et al. (U.S. Patent Application Publication No. US2007/0000255, published Jan. 4, 2007, “Autonomous Air-Conditioning Module Intended Particularly for the Thermal Treatment of an Area of a Vehicle Cabin”) heats and cools automobile passenger cabin air by circulating the air through localized and autonomously controlled thermoelectric devices. The modules have air intake and exhaust features to force the air through the Peltier devices. The system, however, is limited in capacity as the result of several factors.


Firstly, the thermoelectric module described by Elliot operates by recirculating cabin air through a thermoelectric device. The thermal capacity of such a device is significantly limited according to the relatively low heat capacity of the working fluids used compared certain embodiments described herein.


Secondly, the thermoelectric device described by Elliot is inefficient compared to certain embodiments described herein and its operation is limited to about 12% of the Carnot efficiency with TE materials with a ZT of 1.


Thirdly, the device described by Elliot is bulky compared to certain embodiments described herein, using much more thermoelectric material (limiting capacity) and increasing the cost of the device.


Fourthly, the advantages of connecting such devices in a network where the devices share a common primary working fluid to gain system and device efficiency and capacity advantages is not anticipated or depicted in prior art.


Certain embodiments described herein provide a thermoelectric system and method that provides a significantly higher device and system efficiency and larger thermal capacity for distributed and localized heating and cooling than those described in the prior art.


Certain embodiments described herein provide a ventilating, heating and cooling system that overcomes the drawbacks and has significantly greater efficiency than that of prior art. More specifically, certain embodiments described herein aim to provide a high capacity of distributed and localized heating and cooling in an efficient manner.



FIG. 1 schematically illustrates an example thermoelectric system 100 in accordance with certain embodiments described herein. The thermoelectric system 100 comprises at least one fluid conduit 110 configured to allow a first working fluid 112 to flow therein (schematically illustrated in FIG. 1 by the arrow). The thermoelectric system 100 further comprises a plurality of thermoelectric (TE) assemblies 120. Each TE assembly 120 comprises a plurality of TE elements 122, and each TE assembly 120 is in thermal communication with the first working fluid 112 and in thermal communication with a region 130 corresponding to the TE assembly 120. Each TE assembly 120 is selectively operable either to heat the region 130 corresponding to the TE assembly 120 by transferring heat from the first working fluid 112 to the region 130 corresponding to the TE assembly 120 or to cool the region 130 corresponding to the TE assembly 120 by transferring heat from the region 130 corresponding to the TE assembly 120 to the first working fluid 112. Each TE assembly 120 is operable independently from operation of other TE assemblies of the plurality of TE assemblies.


As used herein, the phrase “each TE assembly” has a broad meaning, including, but not limited to, referring to an individual TE assembly of the plurality of TE assemblies. The thermoelectric system 100 of certain embodiments may comprise one or more other TE assemblies, besides those of the plurality of TE assemblies 120, which do not have one or more of the attributes described herein for the TE assemblies 120 which comprise the plurality of TE assemblies 120. In particular, the phrase “each TE assembly” is not to be interpreted to mean that every TE assembly of the thermoelectric system 100 conforms to the description herein.


As used herein, the phrase “region corresponding to a TE assembly” has a broad meaning including, but not limited to, a region in proximity to a TE assembly, a region in thermal communication with a TE assembly, or a region which is cooled or heated by operation of a TE assembly. Such regions do not have a specific size, shape, orientation, or position relative to the TE assemblies to which they correspond, but one or more properties of such a region (e.g., temperature, humidity) are affected at least by operation of the TE assembly to which the region corresponds. While the regions 130 of FIG. 1 are schematically shown by the dashed lines to be non-overlapping, in certain embodiments, the regions 130 can be overlapping or non-overlapping. Furthermore, while the regions 130 of FIG. 1 are schematically shown by the dashed lines to have generally similar sizes to one another, in certain other embodiments, the regions 130 can be of different sizes, shapes, orientations, or positions relative to the TE assemblies 120 to which they correspond. In certain embodiments, the regions 130 comprise objects or personnel to be cooled or heated.


In certain embodiments, the thermoelectric system 100 can comprise a network of distributed TE assemblies which is configured to provide distributed localized climate control (e.g., control of temperature, humidity, or both by heating, cooling, or both) to a volume in which people, animals, or climate-sensitive equipment may reside. For example, in certain embodiments, the thermoelectric system 100 is configured to provide conditioned air to a passenger compartment of a vehicle (e.g., car, truck, bus, train, airplane, ship), to an occupied portion of a building, or to provide climate control (e.g., control of temperature, humidity, or both by heating, cooling, or both) to electronic equipment.


In certain embodiments, the first working fluid 112 is a liquid (e.g., water), while in certain other embodiments, the first working fluid 112 is a gas (e.g., air). In certain embodiments, as schematically illustrated by FIG. 1, the at least one fluid conduit 110 comprises a pipe, tube, vent, duct, or other type of elongate passage which substantially encloses a region through which the first working fluid 112 flows. In certain other embodiments, the at least one fluid conduit 110 comprises a region through which the first working fluid 112 flows which is not substantially enclosed. In certain embodiments, the at least one fluid conduit 110 is part of a first working fluid loop 113 through which the first working fluid 112 flows repeatedly. In certain such embodiments, the first working fluid 112 can be pumped through the loop 113 to flow from a first end of the at least one fluid conduit 110, through the at least one fluid conduit 110, to a second end of the at least one fluid conduit 110, and to return to the first end of the at least one fluid conduit 110. In certain embodiments, the at least one fluid conduit 110 comprises one or more valves to control the flow of the first working fluid 112 through the at least one fluid conduit 110.


In certain embodiments, the plurality of TE assemblies 120 comprise one or more improved, high efficiency TE assemblies utilizing thermal isolation and/or high density design and construction (see, e.g., U.S. Pat. No. 6,539,725, issued to Bell on Apr. 1, 2003, “High Efficiency Thermoelectrics Utilizing Thermal Isolation,” and U.S. Pat. No. 6,625,990, issued to Bell on Sep. 30, 2003, “Thermoelectric Power Generation Systems,” each of which is incorporated in its entirety by reference herein). Other types of TE assemblies 120 are also compatible with various embodiments described herein. The TE assemblies 120 can be arranged in a series and/or parallel network with one another in which the TE assemblies 120 are connected (e.g., by electric power, device and system level control, sensory feedback, or working fluid flow).


Each TE assembly 120 of the plurality of TE assemblies 120 comprises a plurality of TE elements 122. In certain embodiments, the plurality of TE elements 122 comprises a plurality of N-type TE elements 122a and a plurality of P-type TE elements 122b. Each TE assembly 120 of certain embodiments further comprises a plurality of electrically conductive and thermally conductive connectors 123. In certain embodiments, each connector 123 is in electrical communication and in thermal communication with at least one of the plurality of N-type TE elements 122a and with at least one of the plurality of P-type TE elements 122b.


In certain embodiments, each TE assembly 120 has a first side and a second side, and the TE assembly 120 is configured to transfer heat between the first side and the second side. FIGS. 2A and 2B schematically illustrate two example TE assemblies 120 in accordance with certain embodiments described herein. In FIG. 2A, the plurality of TE elements 122 and the connectors 123 are configured such that electric current flows generally in multiple directions (e.g., a generally serpentine pattern) from a connector 123, through an N-type TE element 122a, through a connector 123, and through a P-type TE element 122b. In FIG. 2B, the plurality of TE elements 122 and the connectors 123 are configured such that electric current flows generally in one direction (e.g., linearly) from a connector 123, through an N-type TE element 122a, through a connector 123, and through a P-type TE element 122b. Other configurations of the plurality of TE elements 122 and connectors 123 are also compatible with certain embodiments described herein.


In certain embodiments, each TE assembly 120 comprises a first heat exchanger 124 in thermal communication with a first set of the connectors 123 and a second heat exchanger 125 in thermal communication with a second set of the connectors 123. In certain embodiments, upon operation of the TE assembly 120, the first heat exchanger 124 is either cooled or heated by the first set of the connectors 123 and the second heat exchanger 125 is either heated or cooled by the second set of the connectors 123.



FIGS. 3A and 3B schematically illustrate two views of an example TE assembly 120 incorporating thermal isolation and high power density design and construction in accordance with certain embodiments described herein. In the TE assembly 120 of FIGS. 3A and 3B, each connector 123 of the first set of the connectors 123 is sandwiched between the first heat exchanger 124 and a pair of TE elements 122 (e.g., an N-type TE element and a P-type TE element). In certain embodiments, each of the first heat exchangers 124 are thermally isolated from one another and each of the second heat exchangers 125 are thermally isolated from one another. FIGS. 4A and 4B schematically illustrate two view of another example TE assembly 120 in accordance with certain embodiments described herein. In the TE assembly 120 of FIGS. 4A and 4B, each connector 123 has a first portion in thermal communication with the first heat exchanger 124 or the second heat exchanger 125, and a second portion sandwiched between two TE elements 122 (e.g., between an N-type TE element and a P-type TE element).


In certain embodiments, the first heat exchanger 124 comprises a solid material and comprises a first side of the TE assembly 120 in thermal communication with the first working fluid 112. The first heat exchanger 124 of certain embodiments comprises the at least one fluid conduit 110. For example, the first heat exchanger 124 can comprise a portion (e.g., a wall) of a pipe or duct in thermal communication with the first set of the connectors 123 and through which the first working fluid 112 flows. In certain embodiments, the first heat exchanger 124 comprises a plurality of fins 127 across which the first working fluid 112 flows, for example as schematically illustrated by FIGS. 3B and 4B.


In certain embodiments, the second heat exchanger 125 comprises a solid material and comprises a second side of the TE assembly 120 in thermal communication with a second working fluid 126. In certain embodiments, the second heat exchanger 125 comprises a plurality of fins 128 across which the second working fluid 126 flows, for example as schematically illustrated by FIGS. 3B and 4B. The second heat exchanger 125 of certain embodiments cools or heats the second working fluid 126 to cool or heat the region 130 corresponding to the TE assembly 120, thereby distributing thermal power locally. For example, in certain embodiments, the second working fluid 126 can flow from the region 130 corresponding to the TE assembly 120 (e.g., a region 130 within the second heat exchanger 125) to a volume to be cooled or heated. Thus, in certain embodiments, the second working fluid 126 provides localized heating or cooling to the volume.


In certain embodiments, the second working fluid 126 is the same as the first working fluid 112, while in certain other embodiments, the second working fluid 126 is different (e.g., of a different material or phase) than the first working fluid 112. For example, in certain embodiments, at least one of the first working fluid 112 and the second working fluid 126 is a liquid. In certain embodiments, one of the first working fluid 112 and the second working fluid 126 is a liquid (e.g., water), and the other is a gas (e.g., air). In certain embodiments in which the second working fluid 126 comprises a gas, the thermoelectric system 100 further comprises one or more fans which drive the second working fluid 126 from the region 130 corresponding to the TE assembly 120 to the volume to be cooled or heated. In certain embodiments, the second working fluid 126 for the various TE assemblies 120 of the thermoelectric system 100 can be the same or different from one another. For example, for each TE assembly 120 in the thermoelectric system 100, the second working fluid 126 can be selected based upon characteristics of the target region 130 corresponding to the TE assembly 120. In cooling mode, the second working fluid 126 is cooled as it passes through the TE assembly 120 and in heating mode, the second working fluid 126 is heated as it passes through the TE assembly 120. In certain embodiments, the second working fluids 126 are used to extract or deliver thermal power to target regions 130 in the distributed system.


In certain embodiments, during operation of the thermoelectric system 100, thermal power is pumped between the first working fluid 112 flowing in the at least one fluid conduit 110 and the second working fluid 126 flowing in the second heat exchanger 125. In certain such embodiments, one purpose of the first working fluid 112 can be to provide a thermal source or sink for the distributed TE assemblies 120 that are in thermal communication with the first working fluid 112. In certain embodiments, the purpose of the second working fluid 126 (and of the second heat exchanger 125) can be to deliver the thermal power, derived in parts from the first working fluid 112 and the TE elements 122 to the distributed and localized target regions 130 corresponding to the TE assemblies 120.



FIG. 5 schematically illustrates an example thermoelectric system 100 comprising a network of distributed, thermally isolated TE assemblies 120 in accordance with certain embodiments described herein. As is depicted in FIG. 5, advantageously the first working fluid 112 (e.g., water) is circulated at high flow rate though a succession of thermoelectric assemblies 120a, 120b, 120c where the first working fluid 112 experiences slight changes in temperature. When a target region 130 is being heated by a TE assembly 120 to which the region 130 corresponds, the first working fluid 112 enters the TE assembly 120 with an entrance temperature and heat is extracted (pumped) from the first working fluid 112 so that the first working fluid 112 exits the TE assembly 120 with an exit temperature slightly cooler than the entrance temperature. When the target region 130 is being cooled by the TE assembly 120 to which the region 130 corresponds, the process is reversed and the first working fluid 112 exits the TE assembly 120 with an exit temperature slightly hotter than the entrance temperature. In both heating and cooling, the slight change in temperature of the first working fluid 112 only marginally affects thermoelectric device efficiency. The properties of the first working fluid 112 and its flow rate can be selected generally to optimize device and system level performance.


As schematically illustrated by FIG. 5, in certain embodiments, each TE assembly 120 comprises one or more flow controllers 140 (e.g., valves or pumps) which selectively fluidically couple the at least one fluid conduit 110 of the TE assembly 120 to the first working fluid 112 (e.g., in a reservoir or a conduit). In certain such embodiments, the one or more flow controllers 140 are adjustable to control flow of the first working fluid 112 in the at least one fluid conduit 110 of the TE assembly 120. As schematically illustrated by FIG. 5, the one or more flow controllers 140 are adjustable to place one or more selected TE assemblies 120 in thermal communication with the first working fluid 112. In certain embodiments, the one or more flow controllers 140 are placed on an inlet side, an outlet side, or both, of the at least one fluid conduit 110 of the TE assembly 120.


In certain embodiments, the thermoelectric system 100 further comprises a controller 150 (e.g., a central processing unit or microcontroller) and a plurality of switches 151 configured to selectively provide current flow to the TE elements 122 so as to adjust, turn on, or turn off the TE elements 122 of the TE assemblies 120. In certain embodiments, the thermoelectric system 100 further comprises at least one sensor in electrical communication with the controller 150. The controller 150 is configured to receive at least one signal 152 from the at least one sensor, the at least one signal indicative of at least one condition for the thermoelectric system 100 (e.g., sensor data indicative of the ambient temperature, local surface temperature, radiant loads, temperature or fluid flow of the first working fluid 112, temperature or fluid flow of the second working fluid 126, temperature, humidity, or other operating conditions of the regions 130, number of occupants of the regions 130, occupant weight, occupant clothing thickness, occupant location, and user commands). The controller 150 is configured to respond to the signals 152 by transmitting command signals 154 to the flow controllers 140 and to switches 151 so as to control the operation of the TE assemblies 120. In certain embodiments, flow of the first working fluid 112 through the one or more conduits fluidically coupled to the first heat exchangers 124 is adjustable by at least one valve responsive to signals from the controller 150. In certain embodiments in which the thermoelectric system 100 further comprises one or more fans to control the flow of the second working fluid 126 from the TE assemblies 120, the controller 150 is further configured to transmit command signals 154 to the fans as well.


In certain embodiments, the controller 150 advantageously provides local control of the comfort air delivered by the TE assemblies, thereby advantageously providing individual passenger comfort. A distributed thermoelectric system 100 comprising one or more TE assemblies 120 may be controlled by using sensors and algorithms designed to manage fluid flow rates and temperatures of the first working fluid 112 and/or the second working fluid 126.


Input signals to the controller 150 can comprise feedback and control information from the target regions and/or objects to be cooled or heated. Such information may include, but is not limited to, parameters such as temperatures of the regions (e.g., portions of the passenger cabin), occupants (e.g., measured using infrared sensors), objects (e.g., electronic equipment), engine, engine coolant, or working fluids, input power, vehicle electrical network power, occupant number, occupant weight, occupant size, occupant clothing thickness, occupant surface temperatures, occupant location (e.g., sensing proximity to cooling/heating vents), radiant loads, humidity levels, and any other useful parameter. Control feedback signals generated by the controller 150 can include, but are not limited to, target zone temperatures, target occupant skin temperatures, and target outside/inside average temperatures. Control signals generated by the controller 150 can include, but are not limited to, signals which are used to control the localized cooling or heating in various regions by controlling the pumps, fans, valves, or TE assemblies (e.g., heating mode, cooling mode).


In certain embodiments, temperature control modes (heating and cooling) may be changed by reversing input power polarity and may be selected locally by the user or centrally (e.g., by the controller 150) utilizing sensory input signals and control algorithms. In certain embodiments, a means for localized and autonomous control (e.g., a separate controller such as a microcontroller) may be provided for each TE assembly 120 in conjunction with sensors for indicating first and second working fluid temperatures for the purpose of temperature control and device safety. The control of a distributed system comprising several or many such TE assemblies 120 alternatively may be centralized by means of sensors and algorithms designed to manage first and second fluid flow rates and temperatures with feedback from the target regions 130.


In certain embodiments, at least a portion of the first working fluid 112 is sequentially in thermal communication with two or more TE assemblies 120. For example, the portion of the first working fluid 112 flows through the at least one fluid conduits 110 of two or more TE assemblies 120. In certain such embodiments, the portion of the first working fluid 112 is heated by at least one of the TE assemblies 120 and is cooled by at least one of the TE assemblies 120. In certain embodiments, the first working fluid 112 flows in parallel through at least some TE assemblies 120. In certain embodiments, at least a portion of the first working fluid 112 is not in thermal communication with two or more TE assemblies 120. For example, the portion of the first working fluid 112 flows through a single TE assembly 120, or flows through none of the TE assemblies 120.



FIG. 6 schematically illustrates an example thermoelectric system 100 further comprising a thermal storage reservoir 160 and an intermediate heat exchanger 170 in accordance with certain embodiments described herein. In certain embodiments, one or more thermal storage reservoirs 160 and/or intermediate heat exchangers 170 can be placed at intermediate locations within the thermoelectric network 100 in fluidic communication with the first working fluid loop 113. In certain such embodiments, the controller 150 of the thermoelectric system 100 receives sensor feedback signals from the thermal storage reservoir 160 and/or the intermediate heat exchanger 170 and provides system control signals to each TE assembly 120 in response to the sensor feedback signals.


In certain embodiments, the thermal storage reservoir 160 is fluidically coupled to the at least one fluid conduit 110 and is configured to receive the first working fluid 112. Thermal storage provided by the thermal storage reservoir 160 may be used advantageously in combination with the other portions of the thermoelectric system 100 to improve over-all system efficiency and capacity by storing thermal power during peak generation events and returning the first working fluid 112 to the thermoelectric system 100 according to need.


In certain embodiments, the intermediate heat exchanger 170 is in thermal communication with the first working fluid 112, and is in thermal communication with a target object to be cooled or heated. In certain such embodiments, the intermediate heat exchanger 170 advantageously provides opportunities to reject or absorb heat from the first working fluid 112 to heat sinks or heat sources isolated from the regions 130 corresponding to the TE assemblies 120.


In certain embodiments in which both heating and cooling are desired, the configuration of the first working fluid loop 113 and the flow of the second working fluid 126 through the TE assemblies 120 may be altered or combined to improve system efficiency. For example, as the first working fluid 112 is cooled as it passes through a succession of TE assemblies 120 operating in heating mode (e.g., providing warmed comfort air to a region 130), the first working fluid 112 may be directed to cool a target object (e.g., high electric power dissipation electronics) where the drop in temperature over several TE assemblies 120 operating in heating mode may accrete to the cooling performance of a separate target object in a different location. Alternatively, where a first working fluid 112 receives energy while the thermoelectric system 100 is operated to cool one or more target regions 130, the resulting heated first working fluid 112 may be used to provide heat which is transferred by a subsequent TE assembly 120 to heat a corresponding region 130. Networks of first working fluid loops 113 and second working fluid loops may be employed where the localized second working fluid loops provide first working fluid functionality to separate TE assemblies 120 operating in the same or different temperature modes.


The advantages of certain embodiments described herein over prior art systems include, but are not limited to:


1. Networking of thermally isolated and/or high power density TE assemblies 120 within a distributed heating/cooling thermoelectric system 100 can improve the efficiency, capacity and/or cost basis;


2. Using a first working fluid 112 that communicates with each TE assembly 120 advantageously that can provide a higher device and system efficiency and capacity; and


3. Networking and distribution of the first working fluid 112, electric power, device and system control, and sensor feedback can advantageously combine to provide higher system efficiencies and/or capacities at lower cost.


Automotive Example


FIGS. 7A and 7B schematically illustrate two views of an example TE assembly 220 used in a thermoelectric system 100 for automotive ventilating, heating, and cooling. In certain embodiments, the one or more TE assemblies 220 of the thermoelectric system 100 have a liquid heat exchanger 224 and an air heat exchanger 225 in thermal communication with a plurality of TE elements 222 via a plurality of connectors 223. In certain embodiments, at least one of the liquid heat exchanger 224 and the air heat exchanger 225 employs thermal isolation and/or high density design and construction (e.g., as described in U.S. Pat. Nos. 6,539,725 and 6,625,990 which are incorporated in their entireties by reference herein). Advantageously, in certain embodiments, the air heat exchanger 225 can be constructed using aluminum fins brazed between two aluminum face sheets and the liquid heat exchanger 224 can be manufactured from extruded aluminum tubes. Air 226 flows through the air heat exchanger 225 and the liquid working fluid 212 flowing through the liquid heat exchanger 224 in this example is a 50/50 mixture of ethylene glycol and water, while other liquids or gases may be used in other embodiments.


The TE assembly 220 operates in heating mode by pumping heat from the ethylene glycol/water working fluid 212 through the TE assembly 220 to the air 226. In cooling mode, thermal energy is pumped by the TE assembly 220 from the air 226 to the ethylene glycol/water working fluid 212. The thermal capacity of the liquid side of the TE assembly 220 is much greater than that of the air side, so that advantageously the liquid temperature changes very little and the resulting thermal power rejected can be transported away from the TE assembly 220 with minimal temperature rise. The efficiency of the TE assembly 220 can be approximately two times that of conventional devices due to the use of thermal isolation, and the amount of thermoelectric material used can be reduced typically by a factor of 6 to 25 by means of the high density design and construction of the TE assembly 220. The capacity of the TE assembly 220 to deliver heating or cooling power is approximately 2 to 6 times that of an air-to-air device because the liquid working fluid 212 offers a larger thermal source and/or sink than would be the case with air as the first working fluid.


In an example thermoelectric system 100 utilizing a plurality of TE assemblies 220 schematically depicted by FIGS. 7A and 7B, the ethylene glycol/water working fluid 212 flows in series through a number of fluidically coupled TE assemblies 220. Because the change in temperature of the liquid working fluid 212 can be small (on the order of one to two degrees Centigrade) across each TE assembly 220, the heating or cooling efficiency of each TE assembly 220 of the thermoelectric system 100 can be about the same.


In heating mode, the thermoelectric system 100 may utilize engine coolant as the liquid working fluid 212 to assist in rapidly boosting the temperature of the passenger compartment of the vehicle. For example, as schematically illustrated by FIG. 8, the liquid working fluid 212 flows through a radiator 230 configured to cool the engine 232 and flows through the network of TE assemblies 220. In certain embodiments, the liquid working fluid 212 is used to cool the powertrain of the vehicle. In cooling mode, the liquid working fluid 212 may be circulated through an auxiliary cooling radiator 240 to improve performance as schematically depicted in FIG. 9. Advantageously, for the example implementations of FIGS. 8 and 9, flow controllers 235 (e.g., valves) can be used to switch the liquid working fluid 212 between the engine coolant loop and the other fluid loops. In certain other embodiments, the liquid working fluid 212 may be routed to a heat exchanger attached to a vehicle battery (e.g., in an electric or hybrid vehicle) to warm the liquid working fluid 212 when passenger heating is desired. Tn certain other embodiments, the liquid working fluid 212 may be cooled by routing it through a heat exchanger attached or encased within the vehicle fuel tank.


In certain embodiments, the TE assemblies 220 may be scaled and positioned in several ways to provide localized heating, cooling, or both heating and cooling of a passenger compartment 244 according to the required capacity of the thermoelectric system 100, as schematically illustrated by FIG. 10. For example, a large liquid-to-air TE assembly 220 may be arranged to deliver heating and cooling to occupants of the compartment 244 from the headliner of the vehicle (schematically illustrated in FIG. 10 by “A”), while smaller liquid-to-air TE assemblies 220 may be installed to deliver point heating or cooling to occupants in the compartment 244 at selected locations (e.g., one or more pillars denoted in FIG. 10 by “B” and “C,” and steering wheel denoted by “D”). In such a network, the liquid working fluid 212 may communicate with each TE assembly 220 to deliver high thermal power.


In addition, liquid-to-air TE assemblies 220 may be located in one or more seat cushions 250 and/or one or more seat backs 260 as schematically illustrated by FIG. 11. In certain such embodiments, the TE assemblies 220 are connected in series and/or in parallel with other TE assemblies 220 to deliver heating and/or cooling to occupants sitting in the seat or behind the seat. For example, the driver could be cooled and/or heated by a liquid-based CCS system in the front seat and the same liquid delivery system could connect to a separate TE assembly 220 with independent controls for cooling and/or heating the rear passenger behind the driver.



FIG. 12 schematically illustrates an example thermoelectric system 100 in which one or more TE assemblies 220 provide climate control of the passenger compartment 244 and one or more TE assemblies 220 provide temperature control of electronic equipment 270 of the vehicle (e.g., thermally conditioning the battery by either cooling or heating the battery) in accordance with certain embodiments described herein. In certain embodiments, the TE assemblies 220 controlling the temperature of the electronic equipment 270 may use liquid as both the first working fluid 212 and the second working fluid 226. FIG. 13 schematically illustrates an example TE assembly 220 being used to heat and/or cool an inner volume 270 of a storage container in which food, beverages, or other items are stored.


In certain embodiments, advantageously, the liquid-to-air TE assemblies 220 and the liquid-to-liquid TE assemblies 220 incorporate thermal isolation and/or high density design and construction (e.g., as described in U.S. Pat. Nos. 6,539,725 and 6,625,990 which are incorporated in their entireties by reference herein). In certain such embodiments, the TE assemblies 220 can provide significantly higher thermal capacity than air-to-air devices. In addition, in certain embodiments, the TE assemblies may use less thermoelectric material, and may operate at higher efficiency and therefore may provide cost savings. In addition, the greater thermal capacity of a first working fluid loop using liquids can be greater than that of one using air resulting in certain embodiments described herein providing a larger thermal capacity for cooling and/or heating of target regions and/or objects.


In certain embodiments, the liquid working fluid loop connecting the TE assemblies 220 may have one or more waste heat exchangers which transfer waste thermal energy at various positions from the liquid working fluid loop to a thermal mass or regions outside the passenger compartment 244. For example, as schematically illustrated by FIG. 14, in certain embodiments, one or more heat exchangers may be connected with a portion of the ethylene glycol/water liquid working fluid loop (e.g., a liquid working fluid reservoir) to transfer heat from the liquid working fluid 212 to the outside of the passenger compartment 244. In this way, cooling capacity and over-all system efficiency may be greater. Thus, waste thermal power is transferred outside of the passenger compartment 244 in a manner that is difficult for the air-to-air system as described by Elliot et al. For example, the waste thermal power from the liquid working fluid 212 may be transferred to a large thermal mass (e.g., a portion of the vehicle frame, fuel tank, battery, phase change thermal capacitor, and/or any other advantageous components or systems). In certain embodiments, the large thermal mass can be a portion of the vehicle frame in the pillars, doors, body, chassis, or under the floor of the passenger compartment 244.


In certain embodiments, the thermoelectric system 100 can be operable in a vehicle or other application for a period of time with the primary source of electric power off (e.g., engine off operation) by using a source of auxiliary power (e.g., battery, capacitor, fuel cell, solar cell, flywheel, and/or any other source of power).


Because centralized heating and cooling systems require a significant amount of input energy and engine operation to provide comfort air and to condition sensitive systems, their use has been limited to periods when the vehicle engine is operating. It is desirable, however, to precondition certain areas and sensitive systems prior to vehicle operation such as at the start or the finish of the day. Preconditioning can significantly increase passenger comfort, increase the life expectancy of sensitive systems, and can be programmed or operated autonomously to reach desired operating conditions corresponding to anticipated needs using presently available devices such as cell phones or key fobs.



FIG. 15 is a flow diagram of a method 300 for heating, cooling, or both heating and cooling localized portions of a vehicle in accordance with certain embodiments described herein. The method 300 comprises providing a thermoelectric system 100 in an operational block 310. Various examples of thermoelectric systems 100 are described herein which are compatible with certain embodiments. For example, in certain embodiments, the thermoelectric system 100 comprises at least one fluid conduit 110 configured to allow a first working fluid 112 to flow therein and a plurality of TE assemblies 120 in thermal communication with the first working fluid 112 and with a region 130 of the vehicle corresponding to the TE assembly 120.


The method 300 further comprises preconditioning at least one region 130 of the vehicle by operating at least one TE assembly 120 of the thermoelectric system 100 in an operational block 320. In certain embodiments, the thermoelectric system 100 is used to precondition selected regions or areas and/or sensitive systems or equipment prior to the engine being turned on. For example, prior to a person entering the vehicle, the thermoelectric system 100 is activated (e.g., using a cell phone or key fob) and is used to establish the desired temperature conditions (e.g., temperatures within the seat surfaces and throughout the steering wheel). The power source for the thermoelectric system 100 in certain such embodiments is the vehicle battery. In certain other embodiments, the power is provided from an external source via a power connection to the vehicle (e.g., a power cord plugged into an outlet in a building garage). In certain such embodiments, the passenger compartment of a vehicle can be precooled down on a hot day, or preheated on a cold day, prior to occupant entry. In certain embodiments, the thermoelectric system 100 can be used to precondition at least a portion of a passenger compartment of the vehicle by cooling the portion below a condensation temperature so as to remove water vapor from the passenger compartment.


In addition, preconditioning can be performed for sensitive systems of the vehicle. Such sensitive systems may include, but are not limited to, a battery or a catalytic converter. In certain embodiments, preconditioning is used to place the sensitive system at an optimum temperature that maintains and extends the life of the sensitive system (e.g., optimizing the battery's temperature to maintain and extend the battery life). This is especially advantageous for highly electrified vehicles with large and expensive battery systems. Preconditioning can also be performed to establish desired temperatures of storage containers that hold food products or sensitive materials such as biologic specimens.


In certain embodiments, preconditioning is performed using preprogrammed or autonomous control (e.g., using a cell phone or key fob) to establish desired temperature conditions prior to periods of anticipated usage, such as at the start or end of the day. For example, much like the preset thermostatic control in buildings, a schedule for activating preconditioning may be set in advance and controlled by a central processing unit or microcomputer. Alternatively, the preconditioning may be activated by a remote control means when desired. In addition, the thermal storage systems of such a network may be preconditioned as well to deliver improved efficiency during vehicle operation.


Certain embodiments described herein provide an advantageous method for heating and/or cooling occupants and/or equipment, buildings, and any other use by focusing thermal power so as to not waste energy on non-target objects. Certain embodiments described herein advantageously conserve energy by using thermoelectric devices to generate and distribute thermally conditioned fluids at or in close proximity of target objects. In doing so, the inefficiencies associated with centralized systems due to losses occurring as a result of extraneous object cooling can be avoided at least in part.


A wide range of thermal management systems are enabled by certain embodiments described herein. For example, occupants of buildings may have comfort air provided in close proximity of their work surroundings without the need to thermally condition surrounding infrastructure. In addition, the occupants may autonomously control their local temperature environment by means of simple and direct controls.


Portions of the temperature-sensitive areas, such as high density computer boards, racks, or equipment, may be conditioned locally by employing certain embodiments described herein. Certain embodiments advantageously allow such areas to be managed in proportion to the need, as opposed to functioning of centralized systems that condition an entire room or building volume without regard to local need. Thus, over cooling non-operative or low dissipation equipment and under cooling or marginally cooling highly dissipative equipment can be avoided.


Passenger vehicles have begun to adopt localized thermal management to improve passenger comfort, however such systems rely on centralized A/C systems that are not as energy efficient as needed due to the excess capacity power to condition non-essential structural elements including floors, windows, head liners, etc. Thermoelectric systems have begun to be deployed to address these issues; however their design and construction causes their efficiency and cost to fall short of commercial acceptance.


Certain embodiments described herein address these shortcomings by combining thermoelectric materials advantageously using thermal isolation and/or high density designs and construction. In addition, by careful selection of the working fluids, these systems can provide significant efficiency, cost, and/or thermal capacity increases over the prior art.


Various embodiments have been described above. Although the invention has been described with reference to these specific embodiments, the descriptions are intended to be illustrative of the invention and are not intended to be limiting. Various modifications and applications may occur to those skilled in the art without departing from the true spirit and scope of the invention as defined in the appended claims.

Claims
  • 1. A thermoelectric system for distributed localized heating, cooling, or both heating and cooling, the thermoelectric system comprising: at least one fluid conduit configured to allow a first working fluid to flow therein; anda plurality of thermoelectric assemblies, each thermoelectric assembly comprising a plurality of thermoelectric elements, each thermoelectric assembly comprising a first side and a second side and configured to transfer thermal energy between the first side and the second side, each thermoelectric assembly selectively in thermal communication with the first working fluid via the first side by a fluid flow controller corresponding to the thermoelectric assembly configured to either direct or stop flow of the first working fluid through the thermoelectric assembly relative to the first side, and each thermoelectric assembly in thermal communication with a region corresponding to the thermoelectric assembly via the second side,wherein each thermoelectric assembly is selectively operable either to heat the region corresponding to the thermoelectric assembly by the thermoelectric assembly transferring heat from the first working fluid via the first side to the region corresponding to the thermoelectric assembly via the second side or to cool the region corresponding to the thermoelectric assembly by the thermoelectric assembly transferring heat from the region corresponding to the thermoelectric assembly via the second side to the first working fluid via the first side,wherein each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies,wherein the at least one fluid conduit comprises a plurality of fluid conduits, each thermoelectric assembly in fluid communication with a fluid conduit corresponding to the thermoelectric assembly, each fluid conduit in fluid communication with a fluid loop, the fluid loop configured to allow the first working fluid to flow therein, each fluid conduit comprising an inlet side and an outlet side, the inlet side configured to direct at least a portion of the first working fluid from the fluid loop toward the thermoelectric assembly to flow through the thermoelectric assembly, the outlet side configured to direct the at least a portion of the first working fluid away from the thermoelectric assembly into the fluid loop,wherein the at least a portion of the first working fluid flows out of the fluid loop into an inlet side of a first fluid conduit corresponding to a first thermoelectric assembly of the plurality of thermoelectric assemblies, through the first thermoelectric assembly while an other portion of the first working fluid flows through the fluid loop in parallel with the at least a portion of the first working fluid flowing through the first thermoelectric assembly, and through an outlet side of the first fluid conduit back into the fluid loop when the thermoelectric system is operating,wherein, after flowing through the outlet side of the first fluid conduit back into the fluid loop, at least a part of the portion of the first working fluid sequentially flows out of the fluid loop into an inlet side of a second fluid conduit corresponding to a second thermoelectric assembly of the plurality of thermoelectric assemblies, through the second thermoelectric assembly while at least a part of the other portion of the first working fluid flows through the fluid loop in parallel with the at least a part of the portion of the first working fluid flowing through the second thermoelectric assembly, and through an outlet side of the second fluid conduit back into the fluid loop when the thermoelectric system is operating, andwherein the inlet of the second fluid conduit connects to the fluid loop directly downstream of the outlet of the first fluid conduit connecting to the fluid loop such that the first fluid conduit is in series fluid communication with the second fluid conduit while the fluid loop is in parallel fluid communication with the first and second fluid conduits.
  • 2. The thermoelectric system of claim 1, wherein at least a part of the first working fluid flows through the at least one fluid conduit such that the at least a part of the first working fluid is sequentially in thermal communication with two or more thermoelectric assemblies of the plurality of thermoelectric assemblies via the fluid flow controller corresponding to the thermoelectric assembly directing flow of the at least a part of the first working fluid through the thermoelectric assembly relative to the first side when the thermoelectric system is operating.
  • 3. The thermoelectric system of claim 2, wherein the at least a part of the first working fluid is heated by at least one of the thermoelectric assemblies and is cooled by at least one other of the thermoelectric assemblies when the thermoelectric system is operating.
  • 4. The thermoelectric system of claim 2, wherein the first working fluid flows repeatedly through the at least one fluid conduit when the thermoelectric system is operating.
  • 5. The thermoelectric system of claim 1, wherein at least a part of the first working fluid flows through the at least one fluid conduit such that the at least a part of the first working fluid is not in thermal communication with two or more thermoelectric assemblies of the plurality of thermoelectric assemblies via the fluid flow controller corresponding to the thermoelectric assembly stopping flow of the at least a part of the first working fluid through the thermoelectric assembly relative to the first side when the thermoelectric system is operating.
  • 6. The thermoelectric system of claim 1, wherein the second side is in thermal communication with a second working fluid.
  • 7. The thermoelectric system of claim 6, wherein the second working fluid is the same as the first working fluid.
  • 8. The thermoelectric system of claim 6, wherein the second working fluid is different from the first working fluid.
  • 9. The thermoelectric system of claim 6, wherein at least one of the first working fluid and the second working fluid is a liquid.
  • 10. The thermoelectric system of claim 6, wherein the first working fluid is water and the second working fluid is air.
  • 11. The thermoelectric system of claim 6, wherein the first side is in thermal communication with a first heat exchanger selectively in thermal communication with the first working fluid via the fluid flow controller corresponding to the thermoelectric assembly being configured to either direct or stop flow of the first working fluid through the first heat exchanger relative to the first side, and wherein the second side is in thermal communication with a second heat exchanger in thermal communication with the second working fluid.
  • 12. The thermoelectric system of claim 6, wherein the second working fluid flows from the region corresponding to the thermoelectric assembly to a volume to be cooled or heated when the thermoelectric system is operating.
  • 13. The thermoelectric system of claim 12, wherein the second working fluid comprises a gas and the thermoelectric system further comprises one or more fans configured to drive the second working fluid from the region corresponding to the thermoelectric assembly to the volume.
  • 14. The thermoelectric system of claim 11, wherein each thermoelectric assembly comprises a plurality of N-type thermoelectric elements and a plurality of P-type thermoelectric elements, each thermoelectric assembly further comprising a plurality of electrically conductive and thermally conductive connectors, each connector in electrical communication and thermal communication with at least one of the plurality of N-type thermoelectric elements and with at least one of the plurality of P-type thermoelectric elements and in thermal communication with the first heat exchanger or the second heat exchanger.
  • 15. The thermoelectric system of claim 14, wherein each connector has a first portion and a second portion, the first portion in thermal communication with the first heat exchanger or the second heat exchanger, the second portion sandwiched between at least one of the plurality of N-type thermoelectric elements and at least one of the plurality of P-type thermoelectric elements.
  • 16. The thermoelectric system of claim 15, wherein at least one of the first heat exchanger and the second heat exchanger comprises a plurality of fins.
  • 17. The thermoelectric system of claim 1, wherein the fluid flow controller corresponding to the thermoelectric assembly comprises a valve which is adjustable to control flow of the first working fluid in the at least one fluid conduit.
  • 18. The thermoelectric system of claim 1, further comprising a thermal storage reservoir fluidically coupled to the at least one fluid conduit, the thermal storage reservoir configured to receive the first working fluid.
  • 19. The thermoelectric system of claim 1, further comprising an intermediate heat exchanger in thermal communication with the first working fluid.
  • 20. The system of claim 1, wherein the fluid flow controller is positioned on the inlet side of each fluid conduit.
  • 21. The system of claim 1, wherein the outlet side of a first fluid conduit corresponding to the first thermoelectric assembly of the plurality of thermoelectric assemblies is connected to the inlet side of a second fluid conduit corresponding to the second thermoelectric assembly of the plurality of thermoelectric assemblies via a continuous wall of the fluid loop.
  • 22. The system of claim 21, wherein the fluid flow controller is positioned on the inlet side of each fluid conduit.
  • 23. The system of claim 1, wherein two or more regions each corresponding to at least one thermoelectric assembly are not thermally isolated from each other.
  • 24. The system of claim 23, wherein the two or more regions are positioned within a passenger compartment of a vehicle.
  • 25. The system of claim 1, wherein two or more regions each corresponding to at least one thermoelectric assembly are positioned within a same inner volume without walls forming partitions within the same inner volume to thermally isolate the two or more regions from each other within the same inner volume.
  • 26. The system of claim 25, wherein the two or more regions are positioned within a passenger compartment of a vehicle.
  • 27. A method for heating, cooling, or both heating and cooling localized portions of a vehicle, the method comprising: providing a thermoelectric system comprising at least one fluid conduit configured to allow a first working fluid to flow therein and a plurality of thermoelectric assemblies, each thermoelectric assembly comprising a plurality of thermoelectric elements, each thermoelectric assembly comprises a first side and a second side and configured to transfer thermal energy between the first side and the second side, each thermoelectric assembly selectively in thermal communication with the first working fluid via the first side by a fluid flow controller corresponding to the thermoelectric assembly configured to either direct or stop flow of the first working fluid through the thermoelectric assembly relative to the first side, and each thermoelectric assembly in thermal communication with a region of the vehicle corresponding to the thermoelectric assembly;preconditioning at least one region of the vehicle by operating at least one thermoelectric assembly of the thermoelectric system,wherein each thermoelectric assembly is selectively operable either to heat the region corresponding to the thermoelectric assembly by the thermoelectric assembly transferring heat from the first working fluid via the first side to the region corresponding to the thermoelectric assembly via the second side or to cool the region corresponding to the thermoelectric assembly by the thermoelectric assembly transferring heat from the region corresponding to the thermoelectric assembly via the second side to the first working fluid via the first side,wherein each thermoelectric assembly is operable independently from operation of other thermoelectric assemblies of the plurality of thermoelectric assemblies,wherein the at least one fluid conduit comprises a plurality of fluid conduits, each thermoelectric assembly in fluid communication with a fluid conduit corresponding to the thermoelectric assembly, each fluid conduit in fluid communication with a fluid loop, the fluid loop configured to allow the first working fluid to flow therein each fluid conduit comprising an inlet side and an outlet side, the inlet side configured to direct at least a portion of the first working fluid from the fluid loop toward the thermoelectric assembly to flow through the thermoelectric assembly, the outlet side configured to direct the at least a portion of the first working fluid away from the thermoelectric assembly into the fluid loop;directing the at least a portion of the first working fluid from the fluid loop into an inlet side of a first fluid conduit corresponding to a first thermoelectric assembly of the plurality of thermoelectric assemblies, through the first thermoelectric assembly while an other portion of the first working fluid flows through the fluid loop in parallel with the at least a portion of the first working fluid flowing through the first thermoelectric assembly, and through an outlet side of the first fluid conduit into the fluid loop; andsequentially directing at least a part of the portion of the first working fluid from the fluid loop into an inlet side of a second fluid conduit corresponding to a second thermoelectric assembly of the plurality of thermoelectric assemblies, through the second thermoelectric assembly while at least a part of the other portion of the first working fluid flows through the fluid loop in parallel with the at least a part of the portion of the first working fluid flowing through the second thermoelectric assembly, and through an outlet side of the second fluid conduit into the fluid loop,wherein the inlet of the second fluid conduit connects to the fluid loop directly downstream of the outlet of the first fluid conduit connecting to the fluid loop such that the first fluid conduit is in series fluid communication with the second fluid conduit while the fluid loop is in parallel fluid communication with the first and second fluid conduits.
  • 28. The method of claim 27, wherein preconditioning the at least one region comprises cooling or heating at least a portion of a passenger compartment of the vehicle prior to a person entering the passenger compartment of the vehicle.
  • 29. The method of claim 27, wherein preconditioning the at least one region comprises cooling at least a portion of a passenger compartment of the vehicle below a condensation temperature so as to remove water vapor from the passenger compartment.
  • 30. The method of claim 27, wherein preconditioning the at least one region comprises preconditioning a battery of the vehicle.
  • 31. The method of claim 27, wherein preconditioning the at least one region comprises preconditioning a catalytic converter of the vehicle.
  • 32. The method of claim 27, wherein the fluid flow controller is positioned on the inlet side of each fluid conduit.
  • 33. The method of claim 27, wherein two or more regions each corresponding to one or more thermoelectric assemblies of the plurality of thermoelectric assemblies are not thermally isolated from each other.
  • 34. The method of claim 33, wherein the two or more regions are positioned within a passenger compartment of the vehicle.
  • 35. The method of claim 27, wherein two or more regions each corresponding to one or more thermoelectric assemblies of the plurality of thermoelectric assemblies are positioned within a same inner volume without walls forming partitions within the same inner volume to thermally isolate the two or more regions from each other within the same inner volume.
  • 36. The method of claim 35, wherein the two or more regions are positioned within a passenger compartment of the vehicle.
  • 37. A thermoelectric system for heating, cooling, or both heating and cooling regions, the thermoelectric system comprising: a fluid circuit configured to circulate a working fluid in the fluid circuit;a first thermoelectric device comprising a first side and a second side, the first thermoelectric device configured to transfer thermal energy between the first and second sides of the first thermoelectric device, the second side of the first thermoelectric device in thermal communication with a first region;a first flow controller in fluid communication with the fluid circuit, the first flow controller configured to selectively place the first side of the first thermoelectric device in thermal communication with the working fluid by the first flow controller either directing or stopping flow of the working fluid to the thermoelectric device relative to the first side of the first thermoelectric device;a second thermoelectric device comprising a first side and a second side, the second thermoelectric device operable independently of the first thermoelectric device, the second thermoelectric device configured to transfer thermal energy between the first and second sides of the second thermoelectric device, the second side of the second thermoelectric device in thermal communication with a second region;a second flow controller in fluid communication with the fluid circuit, the second flow controller configured to selectively place the first side of the second thermoelectric device in thermal communication with the working fluid by the second flow controller either directing or stopping flow of the working fluid to the thermoelectric device relative to the first side of the second thermoelectric device;a first fluid conduit configured to convey the working fluid in the first fluid conduit, the first fluid conduit in fluid communication with the fluid circuit and in thermal communication with the first side of first thermoelectric device to provide the thermal communication between the working fluid and the first side of the first thermoelectric device, the first fluid conduit comprising an inlet side and an outlet side, the inlet side of the first fluid conduit configured to direct the working fluid from the fluid circuit to the first thermoelectric device, the outlet side of the first fluid conduit configured to direct the working fluid away from the first thermoelectric device into the fluid circuit; anda second fluid conduit configured to convey the working fluid in the second fluid conduit, the second fluid conduit in fluid communication with the fluid circuit and in thermal communication with the first side of the second thermoelectric device to provide the thermal communication between the working fluid and the first side of the second thermoelectric device, the second fluid conduit comprising an inlet side and an outlet side, the inlet side of the second fluid conduit configured to direct the working fluid from the fluid circuit to the second thermoelectric device, the outlet side of the second fluid conduit configured to direct the working fluid away from the second thermoelectric device into the fluid circuit,wherein the first thermoelectric device is configured to heat the first region by the first thermoelectric device transferring thermal energy from the working fluid via the first side of the first thermoelectric device to the first region via the second side of the first thermoelectric device,wherein the first thermoelectric device is configured to cool the first region by first the thermoelectric device transferring thermal energy from the first region via the second side of the first thermoelectric device to the working fluid via the first side of the first thermoelectric device,wherein the second thermoelectric device is configured to heat the second region by the second thermoelectric device transferring thermal energy from the working fluid via the first side of the second thermoelectric device to the second region via the second side of the second thermoelectric device, andwherein the second thermoelectric device is configured to cool the second region by second the thermoelectric device transferring thermal energy from the second region via the second side of the second thermoelectric device to the working fluid via the first side of the second thermoelectric device,wherein at least a portion of the working fluid flows out of the fluid circuit into the inlet side of the first fluid conduit, to the first thermoelectric device while an other portion of the working fluid flows through the fluid circuit in parallel with the at least a portion of the working fluid flowing through the first fluid conduit, and through the outlet side of the first fluid conduit into the fluid circuit when the thermoelectric system is operating,wherein, after flowing through the outlet side of the first fluid conduit back into the fluid circuit, at least a part of the portion of the working fluid flows out of the fluid circuit into the inlet side of the second fluid conduit, to the second thermoelectric device while at least a part of the other portion of the working fluid flows through the fluid circuit in parallel with the at least a part of the portion of the working fluid flowing through the second fluid conduit, and through the outlet side of the second fluid conduit into the fluid circuit when the thermoelectric system is operating, andwherein the inlet of the second fluid conduit connects to the fluid circuit directly downstream of the outlet of the first fluid conduit connecting to the fluid circuit such that the first fluid conduit is in series fluid communication with the second fluid conduit while the fluid circuit is in parallel fluid communication with the first and second fluid conduits.
  • 38. The system of claim 37, wherein the first fluid conduit includes the first flow controller.
  • 39. The system of claim 38, wherein the first flow controller is positioned on the inlet side of the first fluid conduit.
  • 40. The system of claim 37, wherein the second fluid conduit includes the second flow controller.
  • 41. The system of claim 40, wherein the second flow controller is positioned on the inlet side of the second fluid conduit.
  • 42. The system of claim 37, wherein the outlet side of the first fluid conduit is connected to the inlet side of the second fluid conduit via a continuous wall of the fluid circuit.
  • 43. The system of claim 37, wherein the first and second regions each are positioned within a same inner volume without walls forming partitions within the same inner volume to thermally isolate the first and second regions from each other within the same inner volume.
  • 44. The system of claim 42, wherein the continuous wall of the fluid circuit does not have other inlet or outlet sides of fluid conduits between the outlet side of the first fluid conduit and the inlet side of the second fluid conduit.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No. 60/940,372, filed May 25, 2007, which is incorporated in its entirety by reference herein, and U.S. Provisional Application No. 60/953,157, filed Jul. 31, 2007, which is incorporated in its entirety by reference herein.

US Referenced Citations (425)
Number Name Date Kind
413136 Dewey Oct 1889 A
1120781 Altenkirch et al. Dec 1914 A
2362259 Findley Nov 1944 A
2363168 Findley Nov 1944 A
2499901 Brown, Jr. Mar 1950 A
2944404 Fritts Jul 1960 A
2949014 Belton, Jr. et al. Aug 1960 A
2984077 Gaskill May 1961 A
2992538 Siegfried Jul 1961 A
2997514 Roeder, Jr. Aug 1961 A
3004393 Alsing Oct 1961 A
3006979 Rich Oct 1961 A
3019609 Pietsch Feb 1962 A
3071495 Hanlein Jan 1963 A
3085405 Frantti Apr 1963 A
3125860 Reich Mar 1964 A
3136577 Richard Jun 1964 A
3137142 Venema Jun 1964 A
3138934 Roane Jun 1964 A
3178895 Mole et al. Apr 1965 A
3196620 Elfving et al. Jul 1965 A
3197342 Neild, Jr. Jul 1965 A
3212275 Tillman, Jr. Oct 1965 A
3213630 Mole Oct 1965 A
3236056 Phillips et al. Feb 1966 A
3252504 Newton May 1966 A
3391727 Topouszian Jul 1968 A
3505728 Hare et al. Apr 1970 A
3522106 Debiesse et al. Jul 1970 A
3527621 Newton Sep 1970 A
3554815 Osborn Jan 1971 A
3599437 Panas Aug 1971 A
3607444 Debucs Sep 1971 A
3626704 Coe, Jr. Dec 1971 A
3635037 Hubert Jan 1972 A
3663307 Mole May 1972 A
3681929 Schering Aug 1972 A
3726100 Widakowich Apr 1973 A
3779307 Weiss et al. Dec 1973 A
3817043 Zoleta Jun 1974 A
3885126 Sugiyama et al. May 1975 A
3958324 Alais et al. May 1976 A
3986386 Beltzer et al. Oct 1976 A
4038831 Gaudel et al. Aug 1977 A
4047093 Levoy Sep 1977 A
4051691 Dawkins Oct 1977 A
4055053 Elfving Oct 1977 A
4056406 Markman et al. Nov 1977 A
4065936 Fenton et al. Jan 1978 A
4125122 Stachurski Nov 1978 A
4193271 Honigsbaum Mar 1980 A
4280330 Harris et al. Jul 1981 A
4281516 Berthet et al. Aug 1981 A
4297841 Cheng Nov 1981 A
4297849 Buffet Nov 1981 A
4402188 Skala Sep 1983 A
4420940 Buffet Dec 1983 A
4444851 Maru Apr 1984 A
4448028 Chao et al. May 1984 A
4448157 Eckstein et al. May 1984 A
4494380 Cross Jan 1985 A
4499329 Benicourt et al. Feb 1985 A
4531379 Diefenthaler, Jr. Jul 1985 A
4595297 Liu et al. Jun 1986 A
4634803 Mathiprakasam Jan 1987 A
4658599 Kajiwara Apr 1987 A
4665707 Hamilton May 1987 A
4665971 Sakurai May 1987 A
4707995 Assaf Nov 1987 A
4730459 Schicklin et al. Mar 1988 A
4753682 Cantoni Jun 1988 A
4802929 Schock Feb 1989 A
4823554 Trachtenberg et al. Apr 1989 A
4848090 Peters Jul 1989 A
4858069 Hughes Aug 1989 A
4905475 Tuomi Mar 1990 A
4907060 Nelson et al. Mar 1990 A
4922721 Robertson et al. May 1990 A
4922998 Carr May 1990 A
4947735 Guillemin Aug 1990 A
4988847 Argos et al. Jan 1991 A
4989626 Takagi et al. Feb 1991 A
5006178 Bijvoets Apr 1991 A
5029446 Suzuki Jul 1991 A
5038569 Shirota et al. Aug 1991 A
5042566 Hildebrand Aug 1991 A
5092129 Bayes et al. Mar 1992 A
5097829 Quisenberry Mar 1992 A
5111664 Yang May 1992 A
5119640 Conrad Jun 1992 A
5167129 Akasaka Dec 1992 A
5171372 Recine, Sr. Dec 1992 A
5180293 Hartl Jan 1993 A
5193347 Apisdorf Mar 1993 A
5198930 Muratomi Mar 1993 A
5228923 Hed Jul 1993 A
5232516 Hed Aug 1993 A
5254178 Yamada et al. Oct 1993 A
5269146 Kerner Dec 1993 A
5291960 Brandenburg et al. Mar 1994 A
5300197 Mitani et al. Apr 1994 A
5303771 Des Champs Apr 1994 A
5316078 Cesaroni May 1994 A
5385020 Gwilliam et al. Jan 1995 A
5386823 Chen Feb 1995 A
5407130 Uyeki et al. Apr 1995 A
5419780 Suski May 1995 A
5419980 Okamoto et al. May 1995 A
5429680 Fuschetti Jul 1995 A
5430322 Koyanagi et al. Jul 1995 A
5431021 Gwilliam et al. Jul 1995 A
5448891 Nakagiri et al. Sep 1995 A
5450894 Inoue et al. Sep 1995 A
5456081 Chrysler et al. Oct 1995 A
5483807 Abersfelder et al. Jan 1996 A
5497625 Manz et al. Mar 1996 A
5499504 Mill et al. Mar 1996 A
5544487 Attey et al. Aug 1996 A
5549153 Baruschke et al. Aug 1996 A
5561981 Quisenberry et al. Oct 1996 A
5566774 Yoshida Oct 1996 A
5576512 Doke Nov 1996 A
5584183 Wright et al. Dec 1996 A
5592363 Atarashi et al. Jan 1997 A
5594609 Lin Jan 1997 A
5605047 Park et al. Feb 1997 A
5653111 Attey et al. Aug 1997 A
5673964 Roan et al. Oct 1997 A
5682748 DeVilbiss et al. Nov 1997 A
5694770 Bruck et al. Dec 1997 A
5705770 Ogassawara et al. Jan 1998 A
5713426 Okamura Feb 1998 A
5722249 Miller, Jr. Mar 1998 A
5724818 Iwata et al. Mar 1998 A
5725048 Burk et al. Mar 1998 A
5802856 Schaper et al. Sep 1998 A
5816236 Moroi et al. Oct 1998 A
5822993 Attey Oct 1998 A
5860472 Batchelder Jan 1999 A
5867990 Ghoshal Feb 1999 A
5890371 Rajasubramanian et al. Apr 1999 A
5899086 Noda et al. May 1999 A
5901572 Peiffer et al. May 1999 A
RE36242 Apisdorf Jun 1999 E
5917144 Miyake et al. Jun 1999 A
5918930 Kawai et al. Jul 1999 A
5921088 Imaizumi et al. Jul 1999 A
5955772 Shakouri et al. Sep 1999 A
5959341 Tsuno et al. Sep 1999 A
5964092 Tozuka et al. Oct 1999 A
5966941 Choshal Oct 1999 A
5975856 Welle Nov 1999 A
5977785 Burward-Hoy Nov 1999 A
5987890 Chiu et al. Nov 1999 A
6000225 Ghoshal Dec 1999 A
6028263 Kobayashi et al. Feb 2000 A
6050326 Evans Apr 2000 A
6059198 Moroi et al. May 2000 A
6082445 Dugan Jul 2000 A
6084172 Kishi et al. Jul 2000 A
6096966 Nishimoto et al. Aug 2000 A
6105659 Pocol et al. Aug 2000 A
6119463 Bell Sep 2000 A
6122588 Shehan et al. Sep 2000 A
6127766 Roidt Oct 2000 A
6138749 Kawai et al. Oct 2000 A
6158225 Muto et al. Dec 2000 A
6203939 Wilson Mar 2001 B1
6205802 Drucker et al. Mar 2001 B1
6205805 Takahashi et al. Mar 2001 B1
6213198 Shikata et al. Apr 2001 B1
6223539 Bell May 2001 B1
6226994 Yamada et al. May 2001 B1
6230496 Hofmann et al. May 2001 B1
6270015 Hirota Aug 2001 B1
6282907 Ghoshal Sep 2001 B1
6293107 Kitagawa Sep 2001 B1
6302196 Haussmann Oct 2001 B1
6320280 Kanesaka Nov 2001 B1
6324860 Maeda et al. Dec 2001 B1
6334311 Kim et al. Jan 2002 B1
6346668 McGrew Feb 2002 B1
6347521 Kadotani et al. Feb 2002 B1
6357518 Sugimoto et al. Mar 2002 B1
6366832 Lomonaco et al. Apr 2002 B2
6385976 Yamamura et al. May 2002 B1
6393842 Kim May 2002 B2
6401462 Bielinski Jun 2002 B1
6407435 Ma et al. Jun 2002 B1
6412287 Hughes et al. Jul 2002 B1
6431257 Sano et al. Aug 2002 B1
6438964 Giblin Aug 2002 B1
6446442 Batchelor et al. Sep 2002 B1
6453993 Bujak, Jr. Sep 2002 B1
6457324 Zeigler et al. Oct 2002 B2
6464027 Dage et al. Oct 2002 B1
6474073 Uetsuji et al. Nov 2002 B1
6474081 Feuerecker Nov 2002 B1
6477844 Ohkubo et al. Nov 2002 B2
6481213 Carr et al. Nov 2002 B2
6499306 Gillen Dec 2002 B2
6510696 Guttman et al. Jan 2003 B2
6530231 Nagy et al. Mar 2003 B1
6530842 Wells et al. Mar 2003 B1
6530920 Whitcroft et al. Mar 2003 B1
6539725 Bell Apr 2003 B2
6539729 Tupis et al. Apr 2003 B2
6541139 Cibuzar Apr 2003 B1
6548750 Picone Apr 2003 B1
6554088 Severinsky et al. Apr 2003 B2
6560968 Ko May 2003 B2
6563039 Caillat et al. May 2003 B2
6569550 Khelifa May 2003 B2
RE38128 Gallup et al. Jun 2003 E
6580025 Guy Jun 2003 B2
6598403 Ghoshal Jul 2003 B1
6598405 Bell Jul 2003 B2
6605773 Kok Aug 2003 B2
6606866 Bell Aug 2003 B2
6606877 Tomita et al. Aug 2003 B2
6607142 Boggs et al. Aug 2003 B1
6611115 Wakashiro et al. Aug 2003 B2
6625990 Bell Sep 2003 B2
6637210 Bell Oct 2003 B2
6640889 Harte et al. Nov 2003 B1
6653002 Parise Nov 2003 B1
6672076 Bell Jan 2004 B2
6682844 Gene Jan 2004 B2
6700052 Bell Mar 2004 B2
6705089 Chu et al. Mar 2004 B2
6722139 Moon et al. Apr 2004 B2
6732534 Spry May 2004 B2
6779348 Taban Aug 2004 B2
6792259 Parise Sep 2004 B1
6796399 Satou et al. Sep 2004 B2
6803766 Kobayashi et al. Oct 2004 B2
6807811 Lee Oct 2004 B2
6810977 Suzuki Nov 2004 B2
6812395 Bell Nov 2004 B2
6862892 Meyer et al. Mar 2005 B1
6880346 Tseng et al. Apr 2005 B1
6883602 Drucker Apr 2005 B2
6886356 Kubo et al. May 2005 B2
6894369 Irino et al. May 2005 B2
6896047 Currle et al. May 2005 B2
6907739 Bell Jun 2005 B2
6910345 Horstmann et al. Jun 2005 B2
6915641 Harvie Jul 2005 B2
6942728 Caillat et al. Sep 2005 B2
6948321 Bell Sep 2005 B2
6959555 Bell Nov 2005 B2
6962195 Smith et al. Nov 2005 B2
6973799 Kuehl et al. Dec 2005 B2
6975060 Styblo et al. Dec 2005 B2
6986247 Parise Jan 2006 B1
7007491 Grimm et al. Mar 2006 B2
7074122 Haupt et al. Jul 2006 B2
7089756 Hu Aug 2006 B2
7100369 Yamaguchi et al. Sep 2006 B2
7111465 Bell Sep 2006 B2
7134288 Crippen et al. Nov 2006 B2
7171955 Perkins Feb 2007 B2
7231772 Bell Jun 2007 B2
7235735 Venkatasubramanian et al. Jun 2007 B2
7246496 Goenka et al. Jul 2007 B2
7310953 Pham et al. Dec 2007 B2
7363766 Eisenhour Apr 2008 B2
7380586 Gawthrop Jun 2008 B2
7416138 Ellison et al. Aug 2008 B2
7421845 Bell Sep 2008 B2
7426835 Bell Sep 2008 B2
7475551 Ghoshal Jan 2009 B2
7587902 Bell Sep 2009 B2
7650757 Bhatti Jan 2010 B2
7743614 Goenka et al. Jun 2010 B2
7779639 Goenka Aug 2010 B2
7784289 Scherer et al. Aug 2010 B2
7788933 Goenka Sep 2010 B2
7870745 Goenka Jan 2011 B2
7870892 Gawthrop Jan 2011 B2
7905278 Sato et al. Mar 2011 B2
7926293 Bell Apr 2011 B2
7932460 Bell Apr 2011 B2
7942010 Bell May 2011 B2
7946120 Bell May 2011 B2
8069674 Bell Dec 2011 B2
8079223 Bell Dec 2011 B2
8104294 Reeve Jan 2012 B2
8261868 Goenka et al. Sep 2012 B2
8359871 Woods et al. Jan 2013 B2
8408012 Goenka et al. Apr 2013 B2
8490412 Bell et al. Jul 2013 B2
8495884 Bell et al. Jul 2013 B2
8613200 LaGrandeur et al. Dec 2013 B2
8631659 Goenka Jan 2014 B2
8640466 Bell et al. Feb 2014 B2
8701422 Bell et al. Apr 2014 B2
8915091 Goenka Dec 2014 B2
20010005990 Kim et al. Jul 2001 A1
20010029974 Cohen et al. Oct 2001 A1
20020095943 Hatakeyama et al. Jul 2002 A1
20030029175 Lee Feb 2003 A1
20030084935 Bell May 2003 A1
20030094265 Chu et al. May 2003 A1
20030106677 Memory et al. Jun 2003 A1
20030140636 Van Winkle Jul 2003 A1
20030145605 Moon et al. Aug 2003 A1
20030217738 Ryon Nov 2003 A1
20040025516 Van Winkle Feb 2004 A1
20040045594 Hightower Mar 2004 A1
20040050076 Palfy et al. Mar 2004 A1
20040055312 Bell Mar 2004 A1
20040076214 Bell et al. Apr 2004 A1
20040089336 Hunt May 2004 A1
20040093889 Bureau et al. May 2004 A1
20040098991 Heyes May 2004 A1
20040177876 Hightower Sep 2004 A1
20040221577 Yamaguchi et al. Nov 2004 A1
20040237541 Murphy Dec 2004 A1
20040261829 Bell Dec 2004 A1
20040267408 Kramer Dec 2004 A1
20050000473 Ap et al. Jan 2005 A1
20050011199 Grisham et al. Jan 2005 A1
20050061497 Amaral Mar 2005 A1
20050067862 Iqbal et al. Mar 2005 A1
20050074646 Rajashekara et al. Apr 2005 A1
20050081834 Perkins Apr 2005 A1
20050121065 Otey Jun 2005 A1
20050139692 Yamamoto Jun 2005 A1
20050178128 Harwood et al. Aug 2005 A1
20050247336 Inaoka Nov 2005 A1
20050257531 Kadle et al. Nov 2005 A1
20050257545 Ziehr et al. Nov 2005 A1
20050263176 Yamaguchi et al. Dec 2005 A1
20050268621 Kadle et al. Dec 2005 A1
20050278863 Bahash et al. Dec 2005 A1
20050279105 Pastorino Dec 2005 A1
20060005548 Ruckstuhl Jan 2006 A1
20060011152 Hayes Jan 2006 A1
20060059933 Axakov et al. Mar 2006 A1
20060075758 Rice et al. Apr 2006 A1
20060080979 Kitanovski et al. Apr 2006 A1
20060086118 Venkatasubramanian et al. Apr 2006 A1
20060124165 Bierschenk et al. Jun 2006 A1
20060130490 Petrovski Jun 2006 A1
20060137358 Feher Jun 2006 A1
20060150657 Spurgeon et al. Jul 2006 A1
20060168969 Mei et al. Aug 2006 A1
20060174633 Beckley Aug 2006 A1
20060188418 Park et al. Aug 2006 A1
20060219281 Kuroyanagi et al. Oct 2006 A1
20060225441 Goenka et al. Oct 2006 A1
20060254284 Ito et al. Nov 2006 A1
20060254285 Lin Nov 2006 A1
20070000255 Elliot et al. Jan 2007 A1
20070017666 Goenka et al. Jan 2007 A1
20070033951 Goenka et al. Feb 2007 A1
20070056295 De Vilbiss Mar 2007 A1
20070125413 Olsen et al. Jun 2007 A1
20070214799 Goenka Sep 2007 A1
20070220902 Matsuoka et al. Sep 2007 A1
20070261729 Hu Nov 2007 A1
20070272290 Sims et al. Nov 2007 A1
20080017362 Kwon et al. Jan 2008 A1
20080028768 Goenka Feb 2008 A1
20080028769 Goenka Feb 2008 A1
20080090137 Buck et al. Apr 2008 A1
20080115818 Cheng et al. May 2008 A1
20080230618 Gawthrop Sep 2008 A1
20080250794 Bell Oct 2008 A1
20080289677 Bell Nov 2008 A1
20080307796 Bell et al. Dec 2008 A1
20090000310 Bell et al. Jan 2009 A1
20090007572 Bell et al. Jan 2009 A1
20090007952 Kondoh et al. Jan 2009 A1
20090118869 Cauchy et al. May 2009 A1
20090133734 Takahashi et al. May 2009 A1
20090293499 Bell et al. Dec 2009 A1
20090301103 Bell et al. Dec 2009 A1
20100031987 Bell Feb 2010 A1
20100031988 Bell Feb 2010 A1
20100052374 Bell et al. Mar 2010 A1
20100101238 LaGrandeur et al. Apr 2010 A1
20100101239 LaGrandeur et al. Apr 2010 A1
20100112419 Jang et al. May 2010 A1
20100155018 Goenka et al. Jun 2010 A1
20100287952 Goenka Nov 2010 A1
20100291414 Bell et al. Nov 2010 A1
20100313576 Goenka Dec 2010 A1
20100326092 Goenka Dec 2010 A1
20100331657 Mensinger et al. Dec 2010 A1
20110067742 Bell et al. Mar 2011 A1
20110079023 Goenka et al. Apr 2011 A1
20110107772 Goenka May 2011 A1
20110107773 Gawthrop May 2011 A1
20110162389 Bell Jul 2011 A1
20110209740 Bell et al. Sep 2011 A1
20110236731 Bell et al. Sep 2011 A1
20110244300 Closek et al. Oct 2011 A1
20110247668 Bell et al. Oct 2011 A1
20110258995 Limbeck et al. Oct 2011 A1
20110271994 Gilley Nov 2011 A1
20120102934 Magnetto May 2012 A1
20120111386 Bell et al. May 2012 A1
20120174567 Limbeck et al. Jul 2012 A1
20120177864 Limbeck et al. Jul 2012 A1
20120266608 Kadle et al. Oct 2012 A1
20130037073 LaGrandeur Feb 2013 A1
20130059190 Kossakovski et al. Mar 2013 A1
20130068273 Kanno et al. Mar 2013 A1
20130104953 Poliquin et al. May 2013 A1
20130160809 Mueller Jun 2013 A1
20130167894 Brueck et al. Jul 2013 A1
20130174579 Goenka et al. Jul 2013 A1
20130186448 Ranalli et al. Jul 2013 A1
20130192271 Ranalli et al. Aug 2013 A1
20130192272 Ranalli et al. Aug 2013 A1
20130255739 Kossakovski et al. Oct 2013 A1
20130317728 Hall et al. Nov 2013 A1
20130327063 Gawthrop Dec 2013 A1
20140034102 Ranalli et al. Feb 2014 A1
20140060086 Ranalli et al. Mar 2014 A1
20140096807 Ranalli Apr 2014 A1
20140325997 Bell et al. Nov 2014 A1
20150176872 Goenka Jun 2015 A1
Foreign Referenced Citations (181)
Number Date Country
1195090 Oct 1998 CN
1236429 Nov 1999 CN
1249067 Mar 2000 CN
13 01 454 Aug 1969 DE
2319155 Oct 1974 DE
43 29 816 Mar 1994 DE
43 38 364 May 1994 DE
197 30 678 Jan 1999 DE
198 29 440 Jan 2000 DE
199 51 224 May 2001 DE
20 105 487 Oct 2001 DE
10 2009 003 737 Oct 2010 DE
10 2010 012 629 Sep 2011 DE
0 389 407 Sep 1990 EP
0418995 Mar 1991 EP
0 545 021 Jun 1993 EP
0 791 497 Aug 1997 EP
0 834 421 Apr 1998 EP
1 174 996 Jan 2002 EP
1 324 400 Jul 2003 EP
1 475 532 Nov 2004 EP
1 515 376 Mar 2005 EP
1641067 Mar 2006 EP
1 780 807 May 2007 EP
1 932 695 Jun 2008 EP
1 906 463 Mar 2011 EP
2 541 634 Jan 2013 EP
1 280 711 Jan 1962 FR
2 316 557 Jan 1977 FR
2 419 479 Oct 1979 FR
2 481 786 Nov 1981 FR
2543275 Sep 1984 FR
2 550 324 Feb 1985 FR
2806666 Sep 2001 FR
2 879 728 Jun 2006 FR
231 192 May 1926 GB
817 077 Jul 1959 GB
952 678 Mar 1964 GB
1 040 485 Aug 1966 GB
1151947 May 1969 GB
2 027 534 Feb 1980 GB
2 267 338 Dec 1993 GB
2 333 352 Jul 1999 GB
39-27735 Dec 1964 JP
56-18231 Feb 1981 JP
59097457 Jun 1984 JP
60-80044 Jul 1985 JP
63-262076 Oct 1988 JP
01 131830 May 1989 JP
01 200122 Aug 1989 JP
01 281344 Nov 1989 JP
03-263382 Nov 1991 JP
04 103925 Apr 1992 JP
04-165234 Jun 1992 JP
4-165234 Jun 1992 JP
05-37521 May 1993 JP
05-037521 May 1993 JP
05-037621 May 1993 JP
6-024235 Feb 1994 JP
06-089955 Mar 1994 JP
06-135218 May 1994 JP
6-342940 Dec 1994 JP
7-198284 Jan 1995 JP
A-7-7187 Jan 1995 JP
07-074397 Mar 1995 JP
07-089334 Apr 1995 JP
09-321355 May 1995 JP
07-54189 Jun 1995 JP
7 156645 Jun 1995 JP
A-7-202275 Aug 1995 JP
07-253224 Oct 1995 JP
07-253264 Feb 1996 JP
08-222771 Aug 1996 JP
08-316388 Nov 1996 JP
A-8-293627 Nov 1996 JP
09042801 Feb 1997 JP
9-089284 Apr 1997 JP
09-092761 Apr 1997 JP
09-254630 Sep 1997 JP
9-276076 Oct 1997 JP
9276076 Oct 1997 JP
10 012935 Jan 1998 JP
10035268 Feb 1998 JP
H10-325561 Aug 1998 JP
10238406 Sep 1998 JP
10-275943 Oct 1998 JP
10290590 Oct 1998 JP
11-317481 Nov 1998 JP
11-032492 Feb 1999 JP
11-042933 Feb 1999 JP
11 046021 Feb 1999 JP
11-182907 Jul 1999 JP
11-201475 Jul 1999 JP
11-274575 Oct 1999 JP
11-301254 Nov 1999 JP
11-342731 Dec 1999 JP
2000 018095 Jan 2000 JP
H2000-58930 Feb 2000 JP
2000 130883 May 2000 JP
2000-161721 Jun 2000 JP
00 208823 Jul 2000 JP
2000-185542 Jul 2000 JP
2000-208823 Jul 2000 JP
H2000-214934 Aug 2000 JP
2000-274788 Oct 2000 JP
2000-274871 Oct 2000 JP
2000-274874 Oct 2000 JP
2000-318434 Nov 2000 JP
2000-335230 Dec 2000 JP
01 007263 Jan 2001 JP
2001-24240 Jan 2001 JP
2001 210879 Aug 2001 JP
2001-267642 Sep 2001 JP
2001304778 Oct 2001 JP
2001-336853 Jan 2002 JP
2002-13758 Jan 2002 JP
2002059736 Feb 2002 JP
2002 232028 Aug 2002 JP
2003175720 Jun 2003 JP
2003-237357 Aug 2003 JP
2003 259671 Sep 2003 JP
2003 332642 Nov 2003 JP
2004 050874 Feb 2004 JP
2004 079883 Mar 2004 JP
2004 360522 Dec 2004 JP
2005-212564 Aug 2005 JP
2005-302851 Oct 2005 JP
2005-212564 Nov 2005 JP
2005 317648 Nov 2005 JP
2006-001530 Jan 2006 JP
2006 015965 Jan 2006 JP
2007-161110 Jun 2007 JP
2008-094366 Apr 2008 JP
2008 274790 Nov 2008 JP
2008 300465 Dec 2008 JP
2009-010138 Jan 2009 JP
2009 033806 Feb 2009 JP
2001 111646 Dec 2001 KR
10-2002-0057600 Jul 2002 KR
10-2011-0013876 Feb 2011 KR
66619 Feb 1973 LU
2 142 178 Nov 1999 RU
2 154 875 Aug 2000 RU
337 227 May 1971 SE
184886 Jul 1966 SU
1142711 Feb 1985 SU
1196627 Dec 1985 SU
WO 9420801 Sep 1994 WO
WO 9501500 Jan 1995 WO
WO 9514899 Jun 1995 WO
WO 9605475 Feb 1996 WO
WO 9722486 Jun 1997 WO
WO 9747930 Dec 1997 WO
WO 9856047 Dec 1998 WO
WO 9909360 Feb 1999 WO
WO 9910191 Mar 1999 WO
WO 9958907 Nov 1999 WO
WO 0200458 Feb 2002 WO
WO 03014634 Feb 2003 WO
WO 03074951 Sep 2003 WO
WO 03090286 Oct 2003 WO
WO 2006001827 Dec 2004 WO
WO 2005023571 Mar 2005 WO
WO 2005020340 May 2005 WO
WO 2005063567 Jul 2005 WO
WO 2005098225 Oct 2005 WO
WO 2006037178 Apr 2006 WO
WO 2006043514 Apr 2006 WO
WO 2006064432 Jun 2006 WO
WO 2007001289 Jan 2007 WO
WO 2007002891 Jan 2007 WO
WO 2007021273 Feb 2007 WO
WO 2007109368 Sep 2007 WO
WO 2008013946 Jan 2008 WO
WO 2008042077 Apr 2008 WO
WO 2008147305 Apr 2008 WO
WO 2008091293 Jul 2008 WO
WO 2008123663 Oct 2008 WO
WO 2008147305 Dec 2008 WO
WO 2012031980 Mar 2012 WO
WO 2012045542 Apr 2012 WO
Non-Patent Literature Citations (16)
Entry
Heckenberger, Thomas, “Li-on Battery Cooling,” BEHR Power Point Presentation, Technical Press Day, Stuttgart, May 20, 2009, 13 pages.
Stockholm, John G.: “Large-Scale Cooling: Integrated Thermoelectric Element Technology,” CRC Handbook of Thermoelectrics, Chapter 53, pp. 657-666. 0-8493-0146, Jul. 1995.
U.S. Appl. No. 14/158,342, filed Jan. 17, 2014, Bell, Lon Edward et al.
Diller, R. W., et al.: “Experimental results confirming improved performance of systems using thermal isolation” Thermoelectrics, 2002. Proceedings ICT '02. Twenty-First International Conference on Aug. 25-29, 2002, Piscataway, NJ USA, IEEE, Aug. 25, 2002, pp. 548-550, XP010637541 ISBN: 0-7803-7683-8.
Diller, R.W., et al., “Experimental Results Confirming Improved Efficiency of Thermoelectric Power Generation Systems with Alternate Thermodynamic Cycles,” 22nd International Conference on Thermoelectrics, 2003, pp. 571-573.
Hendricks, Terry et al., “Advanced Thermoelectric Power System Investigations for Light-Duty and Heavy Duty Applications,” National Renewable Energy Laboratory, Center for Transportation Technology & Systems, Colorado, 2002.
Lofy, John et al., “Thermoelectrics for Environmental Control Automobiles,” 21st International Conference on Thermoelectrics, 2002, p. 471-476.
Menchen, William R., et al., “Thermoelectric Conversion to Recover Heavy Duty Diesel Exhaust Energy,” Teledyne Energy Systems, Timonium, MD 1990.
Miner, A., et al. “Thermo-Electro-Mechanical Refrigeration Based on Transient Thermoelectric Effects”, Applied Physics letters, vol. 75, pp. 1176-1178 (1999).
Snyder, G. Jeffrey, et al., “Thermoelectric Efficiency and Compatibility,” The American Physical Society, Oct. 2, 2003, vol. 91, No. 14.
Tada, S., et al., “A New Concept of Porous Thermoelectric Module Using a Reciprocating Flow for Cooling/Heating Systems (Numerical Analysis for Heating Systems)” 16th International Conference on Thermoelectrics (1977).
International Search Report and Written Opinion for PCT Application No. PCT/US2008/064763, mailed Dec. 5, 2008.
Derwent-ACC-NO. 1998-283540, Kwon, H et al., Hyundai Motor Co., corresponding to KR 97026106 A, published Jun. 24, 1997 (2 pages).
Funahashi et al., “Preparation and properties of thermoelectric pipe-type modules”, ICT 25th International Conference on Aug. 6-10, 2006, Thermoelectrics, 2006, pp. 58-61.
Min et al., “Ring-structured thermoelectric module”, Semiconductor Science and Technology, Aug. 2007, vol. 22, No. 8, pp. 880-888.
Thermoelectrics Handbook: Macro to Nano, 2006, Chpt. 11, Section 11.7, pp. 11-11 to 11-15, CRC Press, Boca Raton, FL.
Related Publications (1)
Number Date Country
20090000310 A1 Jan 2009 US
Provisional Applications (2)
Number Date Country
60940372 May 2007 US
60953157 Jul 2007 US