Patent Application
20130012751
Exemplary embodiments of the present techniques relate to inhibiting corrosion of hydrocarbon systems that contain corrosive gases and water.
Hydrocarbon production is often accompanied by various other constituents, a number of which can be corrosive. In particular, carbon dioxide (CO2) and hydrogen sulfide (H2S) are two corrosive gases that may often be found in hydrocarbon reservoirs. These compounds may cause degradation of transportation and processing infrastructure elements, such as pipeline, wells, and the like, which may lead to costly repairs.
As produced, hydrocarbons may contain about 0-8% or more by volume of CO2 and 0-5% or more, by volume, of H2S. Further, hydrocarbons may contain varying amounts of water. For example, a hydrocarbon may have 0.1%, 5% or more by volume of water. Corrosion in a hydrocarbon facility may depend on three factors or ingredients, which can be thought of as forming a corrosion triangle. These ingredients are water, a corrosive or electrolytic compound, and a vulnerable metal, such as steel.
As corrosion is an electrochemical process, providing electrons to the metal may lower the corrosion 18. For example, a zinc coating can be applied to the steel 16 to inhibit corrosion 18 by supplying electrons in place of the steel 16. More expensive techniques can replace the steel 16 with a corrosion resistant alloy, such as stainless steel. Further, a zinc, magnesium, or aluminum anodes may be electrically coupled to the steel of a pipeline. The anode provides electrons as it is degraded, protecting the steel. In larger systems, the current flow from a passive sacrificial anode may be insufficient, so a generated current may be used to flow electrons through the pipeline, slowing corrosion.
Each of these methods is useful in certain situations. However, in hydrocarbon production, water and corrosive gases will ultimately need to be separated from the production stream. Accordingly, separation of the corrosive components as early in the production process as possible would be the most useful approach. Water and gas separation methods, such as amine treating, glycol dehydration, and pressure swing adsorption, among others, may be costly and technically challenging to implement in remote applications, such as on the seabed or at a hydrocarbon field.
In addition to increasing corrosion, the presence of water in hydrocarbon streams may cause problems with shipping the hydrocarbon due to the formation of clathrate hydrates with the hydrocarbons. Clathrate hydrates (commonly called hydrates) are weak composites formed from a water matrix and a guest molecule, such as methane, ethane, propane, butane, neopentane, ethylene, propylene, isobutylene, cyclopropane, cyclobutane, cyclopentane, cyclohexane, benzene, carbon dioxide, and hydrogen sulfide, among others. Hydrates may form, for example, at the high pressures and low temperatures that may be found in pipelines and other hydrocarbon processing equipment. After forming, the hydrates can agglomerate, leading to plugging or fouling of the pipeline. Various techniques have been used to lower the probability that clathrates will form or cause plugging or fouling, such as dehydration, thermodynamic inhibition, kinetic inhibition, and anti-agglomerates. As discussed above, dehydration may be difficult to implement in remote production environments.
Thermodynamic hydrate inhibitors, such as methanol, monoethylene glycol, diethylene glycol, triethylene glycol, and potassium formate, among others, lower the formation temperature of the hydrate, which may inhibit the formation of the hydrate under the conditions found in a particular process. However, these materials may be used at high levels (e.g., greater than about 10%) to achieve effective inhibition of hydrate formation.
Kinetic hydrate inhibitors (KHIs), which may also be called low dosage hydrate inhibitors, also slow the formation of hydrates, but not by changing the thermodynamic conditions. Instead, KHIs inhibit the nucleation and growth of the hydrate crystals. Such materials may include, for example, Poly(2-alkyl-2-oxazoline) polymers (or poly(N-acylalkylene imine) polymers), poly(2-alkyl-2-oxazoline) copolymers, and others. See Urdahl, Olav, et al., “Experimental testing and evaluation of a kinetic gas hydrate inhibitor in different fluid systems,” Preprints from the Spring 1997 Meeting of the ACS Division of Fuel Chemistry, 42, 498-502 (American Chemical Society, 1997).
For example, U.S. Pat. No. 6,359,047 discloses a gas hydrate inhibitor. The inhibitor includes, by weight, a copolymer including about 80 to about 95% of polyvinyl caprolactam (VCL) and about 5 to about 20% of N,N-dialkylaminoethyl(meth)acrylate or N-(3-dimethylaminopropyl) methacrylamide. As another example, U.S. Pat. No. 5,874,660 discloses a method for inhibiting hydrate formation. The method be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitor used for practicing the method is selected from the family of substantially water soluble copolymers formed from N-methyl-N-vinylacetamide (VIMA) and one of three comonomers, vinylpyrrolidone (VP), vinylpiperidone (VPip), or vinylcaprolactam (VCap). VIMA/VCap is the preferred copolymer. These copolymers may be used alone or in combination with each other or other hydrate inhibitors. Preferably, a solvent, such as water, brine, alcohol, or mixtures thereof, is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.
Surface active agents (surfactants) may function both as KHIs and as anti-agglomeration agents (anti-agglomerates). Anti-agglomerates may prevent the agglomeration, or self-sticking, of small hydrate crystals into larger hydrate crystals or groups of crystals. For example, U.S. Pat. Nos. 5,841,010 and 6,015,929 disclose the use of surface active agents as gas hydrate inhibitors for inhibiting the formation (nucleation, growth and agglomeration) of clathrate hydrates. The methods comprise adding into a mixture comprising hydrate forming substituents and water, an effective amount of a hydrate inhibitor selected from the group consisting of anionic, cationic, non-ionic and zwitterionic hydrate inhibitors. The hydrate inhibitor has a polar head group and a nonpolar tail group not exceeding 12 carbon atoms in the longest carbon chain. The anti-agglomeration agents may allow for the formation of a flowable slurry, i.e., hydrates that can be carried by a flowing hydrocarbon without sticking to each other.
Related information may be found in U.S. Pat. Nos. 6,957,146; 5,936,040; 5,841,010; and 5,744,665. Further information may be found in: U.S. Patent Application Publication Nos. 2004/0133531, 20060092766, 2008/0312478 and 2007/0129256; Sloan, E. D., “Gas Hydrate Tutorial,” Preprints from the Spring 1997 Meeting of the ACS Division of Fuel Chemistry, 42(2), 449-56 (American Chemical Society, 1997); and in Talley, L. D. and Edwards, M., “First Low Dosage Hydrate Inhibitor is Field Proven in Deepwater,” Pipeline and Gas Journal 44, 226 (1999).
The techniques discussed above may help to prevent the formation of hydrates or the plugging of lines by hydrates, but may not help in slowing or preventing corrosion. Further, the materials used as thermodynamic or kinetic hydrate inhibitors may not be compatible with anti-corrosion agents such as coatings or chemical agents used for corrosion protection. Finally, the injection or use of these materials may not be appropriate in numerous reservoirs or process situations, due to cost or complexity.
Hydrates have been tested to determine whether they can be used to remove CO2 from H2 in a synthesis gas stream prior to combustion in a power plant. See Tam, S. S., et al., “A High Pressure Carbon Dioxide Separation Process for IGCC Plants,” Proceedings of the First National Conference on Carbon Sequestration (United States Dept. of Energy, National Energy Technology Laboratory, 2001). It was determined that hydrates could be used to remove CO2 and H2S from a synthesis gas stream (for example, generated by a partial oxidation of coal followed by a water gas shift reaction). The primary component in synthesis gas is H2, which does not form hydrates under normal process conditions (for example, less than about 1000 psia, or greater than about 77 F), which simplifies the formation and separation of other hydrates from the H2 stream.
An exemplary embodiment of the present techniques provides a method for isolating a corrosive gas in a hydrocarbon stream. The method includes reacting a host compound with the hydrocarbon stream comprising the corrosive gas. The pressure, temperature, or both, of the reaction, are controlled to maximize formation of a clathrate of the corrosive gas and minimize formation of a clathrate of a hydrocarbon in the hydrocarbon stream. The clathrate of the corrosive gas is separated from the hydrocarbon stream and melt to remove the corrosive gas.
The method may include placing a reactor configured to form the clathrate of the corrosive gas at a first location in a hydrocarbon transport system; placing a separator configured to remove the clathrate of the corrosive gas at a second location in the hydrocarbon transport system; and placing a melter configured to melt the clathrate of the corrosive gas at a third location in the hydrocarbon transport system.
Exemplary embodiments may include reacting the host compound with the hydrocarbon stream at a wellhead to form the clathrate of the corrosive gas and pumping a slurry comprising the hydrocarbon and the clathrate of the corrosive gas to a destination. A slurry of the clathrate of the corrosive gas may be formed in a reservoir and flowed to a separation system at a surface, such as the surface of the earth or an ocean. A produced sour water, the corrosive gas, or both, may be reinjected into a producing or non-producing reservoir. An anti-agglomerate may be added to the hydrocarbon stream.
Various corrosion prevention techniques may be used in exemplary embodiments of the present techniques, including, for example, adding a corrosion inhibitor to the hydrocarbon stream, using a cathodic protection system, applying a coating to a metal surface in a hydrocarbon transport system, forming a part in the hydrocarbon transport system from a corrosion resistant alloy, or any combinations thereof.
Another exemplary embodiment of the present techniques provides a system for transporting a hydrocarbon through a transportation infrastructure. The system may include a reactor configured to form a clathrate between a host compound and a corrosive gas in a hydrocarbon stream, wherein the reactor comprises a heat exchanger configured to control a temperature of the reactor to minimize a formation of a hydrocarbon clathrate. The system may also include a separator configured to remove the clathrate from the hydrocarbon stream and a melter configured to melt the clathrate and release the corrosive gas.
The system may include a pipeline configured to transport a slurry comprising the clathrate in the hydrocarbon stream. The system may also include a vessel configured to function as the reactor, the separator, and the melter. In an embodiment, the system may include a vessel configured to function as the separator and the melter. The reactor may include a static mixer. A water injection port may be located upstream of the static mixer. An injection system may be configured to inject the corrosive gas released from melting the clathrate into a well. The host compound may include water. The corrosive gas may include carbon dioxide, hydrogen sulfide, or any combination thereof.
Another exemplary embodiment provides a method for producing a hydrocarbon. The method may include producing a hydrocarbon stream that includes a corrosive gas, reacting a host compound with the hydrocarbon stream to form a slurry of a clathrate of the corrosive gas in the hydrocarbon stream, and transporting the slurry to a destination through a pipeline. The clathrate may be separated from the hydrocarbon stream and melted to remove the corrosive gas. The method may include melting the clathrate in the pipeline and separating the corrosive gas from the hydrocarbon stream at the destination.
The advantages of the present techniques are better understood by referring to the following detailed description and the attached drawings, in which:
In the following detailed description section, specific embodiments of the present techniques are described. However, to the extent that the following description is specific to a particular embodiment or a particular use of the present techniques, this is intended to be for exemplary purposes only and simply provides a description of the exemplary embodiments. Accordingly, the techniques are not limited to the specific embodiments described below, but rather, include all alternatives, modifications, and equivalents falling within the true spirit and scope of the appended claims.
At the outset, for ease of reference, certain terms used in this application and their meanings as used in this context are set forth. To the extent a term used herein is not defined below, it should be given the broadest definition persons in the pertinent art have given that term as reflected in at least one printed publication or issued patent. Further, the present techniques are not limited by the usage of the terms shown below, as all equivalents, synonyms, new developments, and terms or techniques that serve the same or a similar purpose are considered to be within the scope of the present claims.
As used herein, the terms “acid gas” and “corrosive gas” are used to refer to a gas encountered in “sour” natural gas streams or petroleum reservoirs. The gases most commonly removed from sour gas or liquid streams are carbon dioxide (CO2) and hydrogen sulfide (H2S). Other examples of acid gases include carbonyl sulfide, carbon disulfide, mercaptans and other sulfides.
As used herein, “clathrate” is a weak composite made of a host compound that forms a basic framework and a guest compound that is held in the host framework by inter-molecular interaction, such as hydrogen bonding, Van der Waals forces, and the like. Clathrates may also be called host-guest complexes, inclusion compounds, and adducts. As used herein, “clathrate hydrate” and “hydrate” are interchangeable terms used to indicate a clathrate having a basic framework made from water as the host compound. A hydrate is a crystalline solid which looks like ice, and forms when water molecules form a cage-like structure around a “hydrate-forming constituent.”
As used herein, a “hydrate-forming constituent” refers to a compound or molecule in petroleum fluids, including natural gas, that forms hydrate at elevated pressures and/or reduced temperatures. Illustrative hydrate-forming constituents include, but are not limited to, hydrocarbons such as methane, ethane, propane, butane, neopentane, ethylene, propylene, isobutylene, cyclopropane, cyclobutane, cyclopentane, cyclohexane, and benzene, among others. Hydrate-forming constituents can also include non-hydrocarbons, such as oxygen, nitrogen, hydrogen sulfide, carbon dioxide, sulfur dioxide, and chlorine, among others.
As used herein, a “compressor” is a machine that increases the pressure of a gas by the application of work (compression). Accordingly, a low pressure gas (for example, 5 psig) may be compressed into a high-pressure gas (for example, 1000 psig) for transmission through a pipeline, injection into a well, or other processes.
As used herein, a “column” means a distillation or fractionation column or zone, i.e., a contacting column or zone, wherein liquid and vapor phases can be counter-currently contacted to effect separation of compounds in a mixture of phases. For example, a separation in a liquid-vapor system may be performed by contacting of the vapor and liquid phases on a series of vertically spaced trays or plates mounted within the column and/or on packing elements such as structured or random packing. Further, a separation of compounds in a mixture of solid, liquid, and vapor phases may be effected by counter-current flow of the solid and/or liquid phases in an opposite direction to a vapor phase. A double column comprises a higher pressure column having its upper end in heat exchange relation with the lower end of a lower pressure column.
As used herein, a “facility” as used herein is a representation of a tangible piece of physical equipment through which hydrocarbon fluids are either produced from a reservoir or injected into a reservoir. In its broadest sense, the term facility is applied to any equipment that may be present along the flow path between a reservoir and the destination for a hydrocarbon product. Facilities may comprise production wells, injection wells, well tubulars, wellhead equipment, gathering lines, manifolds, pumps, compressors, separators, surface flow lines and delivery outlets. In some instances, the term “surface facility” is used to distinguish those facilities other than wells. A “facility network” is the complete collection of facilities that are present in the model, which would include all wells and the surface facilities between the wellheads and the delivery outlets.
As used herein, a “formation” is any finite subsurface region. The formation may contain one or more hydrocarbon-containing layers, one or more non-hydrocarbon containing layers, an overburden, and/or an underburden of any subsurface geologic formation. An “overburden” and/or an “underburden” is geological material above or below the formation of interest.
As used herein, the term “gas” is used interchangeably with “vapor,” and means a substance or mixture of substances in the gaseous state as distinguished from the liquid or solid state. Likewise, the term “liquid” means a substance or mixture of substances in the liquid state as distinguished from the gas or solid state. As used herein, “fluid” is a generic term that may include either a gas or vapor.
As used herein, “kinetic hydrate inhibitor” refers to a molecule and/or compound or mixture of molecules and/or compounds capable of decreasing the rate of hydrate formation in a petroleum fluid that is either liquid or gas phase. A kinetic hydrate inhibitor can be a solid or liquid at room temperature and/or operating conditions. The hydrate formation rate can be reduced sufficiently by a kinetic hydrate inhibitor such that no hydrates form during the time fluids are resident in a pipeline at temperatures below the hydrate formation temperature.
For the inhibition of hydrate formation by thermodynamic or kinetic hydrate inhibitors, As used herein, the term “minimum effective operating temperature” refers to the temperature above which hydrates do not form in fluids containing hydrate forming constituents during the time the fluids are resident in a pipeline. For thermodynamic inhibition only, the minimum effective operating temperature is equal to the thermodynamically inhibited hydrate formation temperature. For kinetic hydrate inhibitors, the minimum effective operating temperature is lower than the thermodynamically inhibited hydrate formation temperature. For the combination of thermodynamic and kinetic inhibition, the minimum effective operating temperature may be even less than the thermodynamically inhibited hydrate formation temperature by itself.
As used herein, the term “natural gas” refers to a multi-component gas obtained from a crude oil well (associated gas) or from a subterranean gas-bearing formation (non-associated gas). The composition and pressure of natural gas can vary significantly. A typical natural gas stream contains methane (C1) as a significant component. Raw natural gas will also typically contain ethane (C2), higher molecular weight hydrocarbons, one or more acid gases (such as carbon dioxide, hydrogen sulfide, carbonyl sulfide, carbon disulfide, and mercaptans), and minor amounts of contaminants such as water, nitrogen, iron sulfide, wax, and crude oil.
As used herein, a “McCabe-Thiele plot” is a graph of an equilibrium concentration between two chemical components showing the concentration ratio of the components in each of two phases. In the graph, operating lines are used to define the mass balance relationships between the components. A McCabe-Thiele plot may be used to design a separation system based on the different concentrations of each of the components in each of the different phases. While McCabe-Thiele plots are generally used to design columns based on vapor-liquid equilibriums, they may be used in any phase equilibrium, such as the clathrate-liquid equilibrium discussed herein.
As used herein, “pressure” is the force exerted per unit area by the gas on the walls of the volume. Pressure can be shown as pounds per square inch (psi). “Atmospheric pressure” refers to the local pressure of the air. “Absolute pressure” (psia) refers to the sum of the atmospheric pressure (14.7 psia at standard conditions) plus the gage pressure (psig). “Gauge pressure” (psig) refers to the pressure measured by a gauge, which indicates only the pressure exceeding the local atmospheric pressure (i.e., a gauge pressure of 0 psig corresponds to an absolute pressure of 14.7 psia). The term “vapor pressure” has the usual thermodynamic meaning. For a pure component in an enclosed system at a given pressure, the component vapor pressure is essentially equal to the total pressure in the system.
As used herein, the terms “produced fluids” and “production fluids” refer to liquids or gases removed from a subsurface formation. Such produced fluids may include liquids, such as oil or water, and gases, such as natural gas, CO2, and H2S, among others.
As used herein, “reflux” is defined as a stream introduced into a distillation column at any location above the location at which the feed is introduced into the column, wherein the reflux comprises one or more components previously withdrawn from the column. Reflux typically is liquid but may be a vapor-liquid mixture or a vapor.
As used herein, “sour gas” generally refers to natural gas containing corrosive gases such as hydrogen sulfide (H2S) and carbon dioxide (CO2). When the H2S and CO2 have been removed (e.g., to less than 5 ppm) from the natural gas feedstream, the gas is classified as “sweet.” As used herein, the term “sour gas” is applied to natural gases that include H2S because of the odor that is emitted even at low concentrations from an unsweetened gas. Furthermore, H2S is corrosive to most metals normally associated with gas pipelines so that processing and handling of sour gas may lead to premature failure of such systems.
As used herein, “substantial” when used in reference to a quantity or amount of a material, or a specific characteristic thereof, refers to an amount that is sufficient to provide an effect that the material or characteristic was intended to provide. The exact degree of deviation allowable may in some cases depend on the specific context.
As used herein, “thermodynamic hydrate inhibitor” refers to a molecule and/or compound, or mixture of molecules and/or compounds capable of reducing the hydrate formation temperature in a petroleum fluid that is either liquid or gas phase. For example, the minimum effective operating temperature of a petroleum fluid can be reduced by at least 1.5° C., 3° C., 6° C., 12° C., or 25° C., due to the addition of one or more thermodynamic hydrate inhibitors. Generally the THI is added to a system in au amount sufficient to prevent the formation of any hydrate.
As used herein, the terms “well” or “wellbore” refer to a hole in the subsurface made by drilling or insertion of a conduit into the subsurface. The terms are interchangeable when referring to an opening in the formation. A well may have a substantially circular cross section, or other cross-sectional shapes (for example, circles, ovals, squares, rectangles, triangles, slits, or other regular or irregular shapes). Wells may be cased, cased and cemented, or open-hole well, and may be any type, including, but not limited to a producing well, an experimental well, an exploratory well, or the like. A well may be vertical, horizontal, or any angle between vertical and horizontal (a deviated well), for example a vertical well may comprise a non-vertical component.
Exemplary embodiments of the present technique provide systems and methods for forming clathrates, such as hydrates, to reduce corrosion in facilities without having to separate out corrosive gases. The formation of the hydrate has the effect of consuming the water, which may reduce corrosion in its presence. Furthermore, a hydrate formed with hydrogen sulfide (H2S), carbon dioxide (CO2), or a mixture of these gases as the guest molecules, consumes these ingredients as well, which may also reduce corrosion.
Thus, as indicated by the graph 200, CO2 and H2S form more stable hydrates than other natural gases, such as methane. As a result, these corrosive components can be preferentially selected to form hydrates at a selected temperature and pressure, which may be useful for purifying a natural gas. Further, the removal of the water and corrosive gas may reduce the tendency of the mixture to corrode a pipeline or other facility.
In an exemplary embodiment of the present techniques, the hydrocarbon (for example, a sour gas) is converted to a hydrate slurry and pumped through a pipeline to a final destination, as discussed with respect to
The reactor 604 may be an in-line or static mixer or may be a continuous stirred tank reactor (CSTR). A heat exchanger 608 can be incorporated into the reactor 604 if the temperature is too high for hydrate formation, as determined from the equilibrium curves, discussed with respect to
After the hydrate is formed, a slurry 612 of the hydrate in the hydrocarbon can be shipped to a destination. In an exemplary embodiment, the reactor 604 is placed on the ocean floor, and the destination is the surface of the ocean. In other embodiments, the reactor 604 may be placed in a well, for example, near a natural gas reservoir, and used to form a hydrate slurry 602 in the hydrocarbon returning to the surface of the earth. As discussed herein, the hydrate slurry 610 may be less corrosive than the raw hydrocarbon stream 602.
At the destination, the hydrate slurry 612 can be used as a feed to a hydrate separator 614. The hydrate separator 614 divides the hydrate slurry 612 into a sweet stream 616 (containing substantially less corrosive gases than the raw hydrocarbon stream 602) and a hydrate stream 618. The hydrate separator 614 may be a conveyor belt or other physical separation device, or may be a version of the separation column discussed with respect to
In the separation tower 702, a hydrate equilibrium gradient can be imposed by heating the bottom of the tower to slightly above the equilibrium temperature (for example, 2° F., 5° F., or more) for dissolution of the hydrate of the corrosive gas impurity (e.g., CO2, H2S, or a mixture) using a heat exchanger 704. A reflux cooler 706 may be used to inject a cooled reflux stream 708 near the top of the tower. The reflux stream 708 can be cooled to slightly below the equilibrium temperature (for example, 2° F., 5° F., or more) for the hydrates of the corrosive gas mixture. The hydrocarbon feed 710, containing corrosive gases, can be cooled using a precooler 712 to a temperature close to the equilibrium temperature. The cooled feed 714 may then be injected into a feed zone 716 in the tower 702 at which the temperature is around the incipient (or formation) temperature for hydrates.
The cooled feed 714 can be passed through spray nozzles 718 that disperse the cooled feed 714 into a fine spray 720 in order to maximize the surface area of the water droplets, which may increase hydrate formation. A stream of water 722 can be injected into a conversion zone 724 in the tower 702 to react with corrosive gases rising from the feed zone 716.
In a melt zone 726 at the bottom of the tower 702, a flow from the heat exchanger 704 can be passed through a heating coil 728, which may dissociate the hydrate into a purified corrosive gas mixture 730. The purified corrosive gas mixture 730 may be removed from the tower 702 in a gas exit stream 732 at the location of the heating coil 728. Water 734, formed from the dissociation of the hydrate may be removed in a bottoms stream 736.
The sweetened hydrocarbon 738 can be removed as an exit stream 740. A portion of the exit stream 740 can be passed through the reflux cooler 706, and reinjected into the tower 702 as the cooled reflux stream 708. Another portion of the exit stream 740 can be removed as the sweetened hydrocarbon product 742.
In this exemplary embodiment, the separation tower 702 is oriented so that the sweetened hydrocarbon is removed from the top, and the water and corrosive gases are removed at the bottom. This configuration may be suitable for lighter hydrocarbons, such as natural gas. In other embodiments, for example, for liquid hydrocarbons, the separation tower 702 may be configured to have the sweetened hydrocarbon exit at the bottom of the separation tower 702 and the corrosive gases exit at the top of the separation tower 702. In an exemplary embodiment, the separation tower 702 is used to purify a hydrocarbon stream at a reservoir, allowing the sour water and corrosive gases to be reinjected into the reservoir to maintain reservoir pressure, as discussed with respect to
The injection stream 806 may be pressurized by a pump 808 to form a pressurized injection stream 810. The pressurized injection stream 810 can then be injected into a formation through a second well 812. The injection may be placed into the active reservoir from which the hydrocarbon is being produced, or into a different formation, such as an empty (produced) hydrocarbon reservoir. If the injection takes place into the active reservoir, it may help to maintain the formation pressure and, thus, production rates.
The system is not limited to that shown in the schematic 800. For example, if a reactor is placed downhole to prevent corrosion in the well casing and production lines, the raw hydrocarbon feed 710 may already be a slurry when it is injected into the separation tower 702. In this case, the separation tower 702 may be used as a separator and melter. The reconfiguration may be performed, for example, by decreasing or eliminating the water feed 722 to the tower 702.
In other embodiments, the configuration discussed with respect to
At block 904, the clathrate is separated from the hydrocarbon, for example, using a physical device such as a conveyor belt or spinning drum separator. In other embodiments, the clathrate may be separated by falling through a tower such as discussed with respect to
At block 906, the clathrate is melted or otherwise dissociated to remove the corrosive gas mixture from the host molecule. In the case of a hydrate, this procedure forms a corrosive gas mixture and sour water, i.e., water that is contaminated by some residual amount of the corrosive gases. The corrosive gas mixture and sour water may be injected into a well to sequester the corrosive gases.
Example calculations were performed to determine the theoretical efficiency of using hydrates to separate mixtures of 85 mol % CH4 with either 15 mol % CO2 or H2S. The separation of a mixture of 85 mol % CH4 and 15 mol % CO2 is discussed with respect to
The separation of the methane from the CO2, may be performed in a column or tower, as discussed with respect to
The McCabe-Thiele plot 1100 shows the number of theoretical stages (numbered one to 13 in this example), which can be used to determine column height. The theoretical stages are bound within the equilibrium curve 1108 and the points of concentration parity 1110 (i.e., points at which the concentration of a component leaving one stage is equal to the concentration of the same component entering the next stage). Operating lines 1112 are drawn along the points of concentration parity 1110.
It should be understood that the values shown along each of the axes in the McCabe-Thiele plot 1300 may be subtracted from one to determine the concentration of H2S in the respective phase. The mole fractions of the feed to the column 1306 are the same as discussed above, 15 mol % H2S and 85 mol % CH4, and the pressure is 200 psig. The temperatures for the input precooler, reflux cooler, and heater can be selected as discussed with respect to
While the present techniques may be susceptible to various modifications and alternative forms, the exemplary embodiments discussed above have been shown only by way of example. However, it should again be understood that the techniques is not intended to be limited to the particular embodiments disclosed herein. Indeed, the present techniques include all alternatives, modifications, and equivalents falling within the true spirit and scope of the appended claims.
This application claims the priority benefit of U.S. Provisional Patent Application 61/313,958 filed 15 Mar. 2010 entitled SYSTEM AND METHOD FOR INHIBITING CORROSION, the entirety of which is incorporated by reference herein.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/US2011/020385 | 1/6/2011 | WO | 00 | 8/20/2012 |
| Number | Date | Country | |
|---|---|---|---|
| 61313958 | Mar 2010 | US |
