1. Object of the Invention
The invention refers, as stated in the title of this descriptive report, to a combustion system using pulverized solid fuel (for example coal or biomass) in a boiler and a method, associated with this system, to optimise the process with a view to reducing contaminating gas emissions, such as nitrogen oxides, as well as optimising the boiler's performance and operation.
2. Field of Application
The field of application for this invention is industrial boilers.
3. Background of the Invention
The vast majority of developments over the last few years to optimise industrial boilers (for example in electrical generation units) have focussed on reducing contaminating gas emissions. These gases include nitrogen oxides (NOx), generated during fossil fuel combustion such as coal, fuel oil or natural gas in industrial boilers. NOx gases mainly comprise NO and NO2 and are among the gas pollutants most harmful to our health and the environment.
Nitrogen oxides are precursors of photochemical smog and acid rain, phenomena with direct effects on the health of animals, vegetation and human beings.
The technologies applied to reduce NO emissions in this type of installation can be mainly classified into two groups: modifications and adjustments to the combustion process or primary measures and post-combustion abatement or secondary measures.
Within the primary measures group, one of the strategies applied is based on stratification of air and fuel supplies to the boiler. In this respect, the lines of actions in existing units include adjusting the operation parameters of the thermal power unit and implementing modifications in the boilers such as installing low NO burners, OFA registers (Over Fire Air), UFA (Under Fire Air), etc.
Stratification targets combustion in two or more stages, where the first or initial stage is rich in fuel and the second or subsequent stages are low in fuel. This refers to reducing the oxygen available in the areas critical for NO formation and reducing the quantity of fuel that is burnt at the maximum flame temperature. Using this procedure it acts on the thermal NO (weakened by rich mixtures) and on the NO in the fuel (turning it into N2 in the part originating from the combustion of volatiles).
One method of carrying out the concept of stratified combustion in stages is given in detail in patent U.S. Pat. No. 6,790,031. This patent is to be applied to tangential boilers where the fuel is injected into the boiler through several sets of burners (normally associated with the same mill) arranged at successive heights. Regarding the usual uniform distribution of fuel by level, the aforementioned patent establishes the stratification of the fuel contribution as an invention, so that it is higher at the lower burner level and reduces gradually through the upper levels reaching a minimum at the highest level. Using this configuration produces a reducing zone (with oxygen deficit) in the lower area of the combustion chamber and an oxidising zone in the top area, which translates into a significant reduction of NOx emissions.
The field of action for the purpose defined in the aforementioned document is restricted exclusively to the boiler for a thermo-electric power unit. In this way, it does not allude to the physical resources or the method to achieve stratification of fuel that is advocated as key when reducing NOx emissions.
Document JP 59145406 defines a pulverized coal boiler with low NOx generation equipped with a large number of burners grouped together into several levels or stages. The burners are divided into two groups, depending on the air/fuel ratio that they are fed: main burners and denitrification burners. The boiler has several levels of main burners and several levels of denitrification burners, the latter having an air/fuel ratio within the range 0.2-0.8. According to the inventors, the hydrocarbon radicals generated by the substoichiometric conditions in the denitrification burners cause an overall reduction in NOx emissions.
The coal pneumatic transport system is designed so as to guarantee supplying those levels of denitrification burners considered as key for the of overall NOx reduction process, even in the event of a mill stopping.
It is thereby established that these key burners are connected to two different mills, so that if one of these mills fails the burners will be fed by the other mill. This presents limitations regarding the degree of maintenance for the fuel supply patterns established as optimum as, although each burner has a parallel system of fuel ducts associated to two mills, only one of them transports coal when the system is in operation. In fact, providing service to a determined level of denitrification burners occurs at the cost of interrupting or drastically reducing the supply of coal to a level of main burners or another level of denitrification burners not considered as key.
In some cases the purpose of the technological development is focussed on resolving a problem associated with operating the plant rather than optimising the combustion process itself. Such is the case of the invention appearing in patent GB 582,593. This document looks at a solution to the problem of instability derived from the imbalance caused by lack of availability for a mill and the consequent lack of service for the burners fed by it. The invention focuses on a very specific configuration of the fuel transport system which defines several groups of burners, each of these groups fed by a system of ducts, and a larger number of mills. The connection between the mills and the duct systems is made so that each group of burners can be fed by more than one mill, so that, as long as the number of active mills is equal to the number of duct systems, supply to all burners is assured.
Selecting the mill to supply each duct system is done via specially designed and protected on/off valves that connect the group of burners involved with one mill or another.
The invention itself does not advocate any type of adjustment to the fuel supply to each group of burners. In its design, it is established as being merely operative that, independently of the mill that might be out of service, the design conditions are maintained regarding carbon injection.
This invention refers firstly to an optimised system for the combustion of pulverized solid fuel with a view to reducing contaminating gas emissions, such as nitrogen oxides and/or improving the performance and operation of the industrial boilers, as the existing boilers in electrical generation units.
This system comprises a boiler equipped with plurality of burners distributed into several groups arranged at different levels or in zones, with each group made up of several burners, a group of solid fuel mills (at least one more than the number of mills required to generate the maximum load of the boiler) and means of transporting the solid fuel that communicate the mills with the burners.
The main specific feature introduced by the invention consists of being able to establish patterns for differential solid fuel supplies between each group of burners, associated with meeting a determined operating target (reducing NOx, improving performance, reducing unburnt carbon, etc.) so that these patterns are not modified by unavailability of one of the mills.
To do this, the equipment conveying the fuel to the boiler is organised to include the following elements:
As a complementary feature, this considers the possibility of incorporating connections between the input sections of the distributors and the flow splitters. These connections will be enabled when there is a stoppage in the support mill. In this way, the substitution mill will perform the functions of the support mill, should the latter fail.
The organisation above gives great flexibility to the unit's operation as, in addition to guaranteeing the supply of solid fuel to certain groups of burners in the event of a mill stopping, it also makes it possible to establish extreme strategies to stratify the fuel fed to the boiler, by allowing certain burners to be supplied with solid fuel from two different mills.
It should be highlighted that the means available to establish fuel stratification strategies in conventional boilers are normally reduced to adjusting mill production. In this respect, their normally narrow operating margins regarding their nominal capacity impose an insurmountable limit on the potential benefits that greater stratification can offer. In addition, and no less important, this way of operating, far from the optimum point of design for the mills, has a negative influence on its operation that can lead to mechanical problems (wear, vibration, rejection of solid fuel, etc.) and worsening the granulometry of the solid fuel produced.
This invention, therefore, allows to assure and adjust the fuel supply to certain groups of main burners, permitting supply patterns to be established that can lead to great stratification between different groups of burners, without the need to operate the mills outside their normal design point and independently of the mill that might be taken out of service for maintenance or another purpose.
This invention also focuses on an operation method that, by using the elements described, can stratify the fuel through the following process:
To complement the description, and in order to make it easier to understand the characteristics of the invention, a series of diagrams is attached for illustrative purposes whilst not limiting further aspects:
The description below gives a possible version of the aforementioned invention. Its application is extensive both in the case of producing a new boiler and the case of adapting an existing plant.
In this case, let's consider the tangential boiler (1) represented in
Among the mills (3A, 3B, 3C, 3D, 3E, 3F), we can firstly distinguish main mills (3F, 3E, 3D and 3C), that respectively supply the main burner groups (2F, 2E, 2D, 2C). From each of the main mills (3F, 3E, 3D and 3C) 4 ducts transport fuel to the main burners on their corresponding level.
From the aforementioned mills we should also distinguish a substitution mill (3B), from which 4 transport ducts also run, one for each corner. These ducts rise to the level of the first group of auxiliary burners (2B) where they split by means of the first three-way connections (4) (one per corner) into 2 groups of alternate lines; some towards the first group of auxiliary burners (2B) and others towards the distributors (5) (there are 4 distributors, one per corner) dropping down with outputs on the 4 lower levels. The first three-way connections (4) have 2 guillotine valves (6, 7) connected to their outputs to guarantee that one of the lines is completely closed when the opposite one is activated. They also have a first deflector (8) to minimise pressure drop caused by the change in direction. The distributors (5) divert the flow of solid fuel from the substitution mill (3B) towards one of the main burner groups (2F, 2E, 2D, 2B, 2C), if their corresponding main mill is out of service. The group of main burners (2F, 2E, 2D, 2B, 2C) supplied by the substitution mill (3B) is selected by means of guillotine valves (9, 10, 11, 12) and flow deflectors (13, 14, 15) associated with each output of the distributors (5).
On the other hand, the outputs for the distributors (5) join up with the ducts from the main mills (3F, 3E, 3D and 3C) by means of junctions (16, 17, 18, 19) located downstream of the guillotine valves (9, 10, 11, 12).
This also considers incorporating a support mill (3A), from which 4 transport ducts lead, one for each corner, that rise to the level where there is a second group of auxiliary burners (2A) where they split by means of the second three-way connections (20) (one per corner) into 2 groups of alternate lines; some towards the second group of auxiliary burners (2A) and others towards flow splitters (21) (there are 4 splitters, one per corner) dropping down with output to the 4 lower levels of burners. The second three-way connections (20) have these 2 guillotine valves (22, 23) on their outputs to guarantee that one of the lines is completely closed when the opposite one is activated. They also have a second deflector (24) to minimise pressure drop caused by the change in direction. The splitter (21) for each corner divides the flow of solid fuel from the support mill (3A) into 4 streams of two-phase air/solid fuel mixture sent towards the burners of this corner belonging to the main burner groups (2F, 2E, 2D, 2C). Each of these support streams joins each duct that connects the distributor (5) outputs for this corner with the burners belonging to the main burner groups (2F, 2E, 2D, 2C) through junctions (25, 26, 27, 28) located between the guillotine valves (9, 10, 11, 12) and the junctions (16, 17, 18, 19) with the ducts from the main mills (3F, 3E, 3D, 3C).
The distribution of the support two-phase mixture between the main burner groups (2F, 2E, 2D, 2C) is regulated by means of flow deflectors (29, 30, 31, 32) equipped with mechanisms for their intermediate positioning depending on the required distribution in terms of flows and granulometry of the solid fuel.
At each corner, the distributor (5) and the splitter (21) are connected through a joining duct (33) fitted with a guillotine valve (34) and a third set of flow deflectors (35, 36). This connection allows the substitution mill (3B) to take on the support mill work (3A) when this is out of service.
The configuration described for the system to transport fuel to the boiler (1) allows operation methodologies to be applied that are not feasible or maintainable in conventional combustion units, where each level of burners is supplied exclusively by a single mill.
As an example of these methodologies, we can highlight the strategy of fuel stratification to reduce NOxemissions. For a conventional tangential boiler, normally capable of generating the full load with 5 mills in operation, a significant reduction in NOx has been observed when one of the top 2 levels is stopped and the lower mills are forced to produce a supply pattern distinguished by higher contribution from the lower burner which decreases towards the higher burners, as shown in
This operating method is limited by the mills' maximum production capacity and, in any case, conditioned by their availability. In this respect, a stoppage in the lower level mill would oblige the top mill to start up to generate the maximum load of the boiler, which would be associated with greater generation of NOx.
The system described in this document allows us to establish more emphatic patterns of stratification from the point of view of reducing NOx, as represented in
Regarding the basic situation above, in the event that one of the main mills stops, for example the main mill (3E) that supplies the second level of groups of burners (2E), the substitution mill (3B) would be put into action, the guillotine valves (11) would be opened for the burners of group (2E) corresponding to the second level and the flow deflectors (15) of the distributors (5) would be activated so that the substitution mill (3B) supply is diverted to this burner group (2E). In parallel, distribution to the other main burner groups would be maintained (including for the second level) concerning the production of the support mill (3A).
In the same way, regarding the basic situation, in the case of the support mill (3A) stopping, the substitution mill (3B) would be put into action, the guillotine valves (34) would be opened on the joining ducts (33) that communicate the distributors (5) and the splitters (21) and the second deflectors (35, 36) would be activated to divert the streams from the substitution mill (3B) to the splitters (21) as this mill takes on the function of the support mill (3A).
The previous pattern of providing solid fuel is very practical in cases where co-combustion is considered using coal with another solid fuel (for example, biomass) In this case, the alternative fuel (for example biomass) can be pulverized in the support mill (3A) and from here, by virtue of the system of transport defined, it can be supplied to the main burner groups (2F, 2E, 2D, 2C) along with the respective streams of pulverized coal from the other mills.
Furthermore, the configuration proposed for the transport system provides great flexibility regarding other possible strategies for fuel distribution by level. One example of this is operating the boiler at full load, with 6 mills in operation, thereby making use of all the milling mass in the unit, with the consequent improvement in the overall granulometry of the pulverized fuel.
Using the same symbols as
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/ES2010/070039 | 1/22/2010 | WO | 00 | 10/26/2012 |