System and Method for Producing LNG from Contaminated Gas Streams

Abstract

A system and method for removing nitrogen and producing liquefied natural gas (“LNG”) from methane without the need for external refrigeration. The invention also relates to a system and method for removing nitrogen from methane and for producing liquefied nitrogen in addition to LNG. The system and method of the invention are particularly suitable for use in recovering and processing comparatively small volumes of methane from coal mines or from flash gas captured at an LNG loading site.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a system and method for removing nitrogen and producing liquefied natural gas (“LNG”) from gaseous streams containing methane and other impurities without the need for an external refrigeration system. The invention also relates to a system and method for removing nitrogen from methane and for producing liquefied nitrogen in addition to LNG. The system and method of the invention are particularly suitable for use in recovering and processing comparatively small volumes of methane from coal mine vent streams or streams containing methane and nitrogen captured as flash gas at an LNG loading site.

2. Description of Related Art

Because many sources of methane produced during mining, energy transport or other industrial applications are not located near a natural gas transmission pipeline or other facility having gas-processing or liquefaction capabilities, a significant amount of methane gas, often combined with other gaseous or vaporous components, is either flared or vented to the atmosphere. This is particularly true in remote or otherwise underdeveloped areas where environmental impact is less of a concern than in the United States and other developed countries.

Naturally occurring methane is often encountered in coal mines, where it poses a significant risk to miners and to the mine subsurface equipment and inventory. This risk arises from miners being unable to breathe methane gas and also because air containing more than about 5 percent methane (preferably not more than about 2 percent) poses a significant risk of explosion. For these reasons, vertical shafts are frequently drilled into coal-containing formations ahead of the mining equipment so that any pockets of methane encountered during the drilling can be brought to the surface. Air is also forced down into subterranean mines and circulated through the mine shafts to dilute any residual methane that may be present and force it to the surface as well. Once the mining equipment reaches the vertical shafts drilled to recover methane from the formation, collapses can occur that produce another kind of methane-containing gas referred to as “gob gas,” which is also extremely hazardous.

Also, at LNG loading facilities, some LNG is typically vaporized as flash gas when the product first enters the tank, which is typically in an LNG tanker or other transport vessel. Because LNG normally comprises a minor amount of residual nitrogen, and because the nitrogen vaporizes at a lower temperature than LNG, the flash gas thus produced will contain a higher percentage of nitrogen than is contained in the LNG. For this reason, even where the flash gas is captured without exposing it to air, the methane in the flash gas cannot readily be re-liquefied without first removing the nitrogen. Although the amount of methane in the flash gas is relatively minor compared to the total amount being loaded, it may not enough to justify economically the investment and expense required to remove the nitrogen and then re-liquefy the methane using conventional technology. Unfortunately, this can cause operators to resort to the more expedient but less environmentally responsible alternatives of venting or flaring the flash gas.

Advantages of recovering coal mine methane for producing LNG, the existing technologies and the importance of accommodating smaller gas flows than conventional natural gas to LNG applications are all discussed in “Coal Mine Methane and LNG,” a paper published in November 2008 by the U.S. Environmental Protection Agency Coalbed Methane Outreach Program Technical Options Series.

Prior patents disclosing other gas processing technology invented by Rayburn C. Butts of BCCK Engineering include U.S. Pat. Nos. 5,141,544; 5,257,505; and 5,375,422.

Compander technology comprising an integrally geared design with one or more expansion stages and one or more compressor stages has previously been disclosed, for example, by Cryostar Industries. The expansion of gas allows for energy to be extracted or harnessed by the use of an expander device. The expander is coupled with a matching compressor, thereby creating a stage compression as is useful in the process. Auxiliary compression is often required to produce the total amount of compression requirements.

SUMMARY OF THE INVENTION

The system and method disclosed herein facilitate the economically efficient and environmentally friendly removal of nitrogen from methane and the production of LNG without the use of an external refrigeration system. As used throughout this specification and claims, the terms “external refrigeration” and “recirculated refrigerant” refer to cooling by means of a recirculated coolant that is external to the process streams emanating directly or indirectly from the inlet gas, and also include cascade refrigeration or mixed refrigerant processes as those conventional cascade and mixed refrigerant processes are known to and understood by those of ordinary skill in the art. According to one embodiment of the invention, nitrogen removed from the methane stream is also liquefied and produced in addition to LNG. The system and method of the invention are suitable for use in processing relatively small volumes of methane in comparison to conventional natural gas processing plants, and are particularly suitable for use in processing methane recovered from coal mines and from LNG loading facilities.

It has now been discovered that integration of some of the nitrogen removal technology previously disclosed, for example, in U.S. Pat. Nos. 5,375,422, 5,257,505 and 5,141,544 with additional technology as disclosed herein, offers significant advantages not previously achievable by those of ordinary skill in the art using existing technologies. These advantages include, for example, an ability to process and liquefy methane at relatively low temperatures through the use of strategically placed turbo expander or compander units without the need for an external refrigeration system, thereby substantially reducing horsepower and compressor requirements, with attendant reductions in capital investment and operating costs. Moreover, because the economic and operational advantages of the subject system and method can be realized in facilities processing comparatively small volumes of methane, the technology can be provided and practiced at locations where methane would otherwise be flared or vented to the atmosphere, thereby eliminating or significantly reducing any adverse environmental impact.

According to one embodiment of the invention, a system is disclosed for removing nitrogen and for producing LNG from methane gas comprising other gaseous components, the system comprising a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline; and a nitrogen removal section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant.

According to another embodiment of the invention, a system is disclosed for producing LNG from methane gas comprising other gaseous components, the system comprising a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline; a first processing section configured to remove oxygen gas from the methane gas; a second processing section configured to remove carbon dioxide from the methane gas; a third processing section configured to dehydrate the methane gas; a fourth processing section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant; an LNG subcooler section disposed downstream of the fourth processing section; wherein the LNG subcooler section is configured to further cool LNG received from the fourth processing section without use of a recirculated refrigerant; conduits through which the methane gas received from the source can flow into and out of the first, second, third and fourth processing sections and the LNG subcooler section; and a receptacle for LNG received from the LNG subcooler section.

According to another embodiment of the invention, a method is disclosed for removing nitrogen and for producing LNG from methane gas comprising other gaseous components, the method comprising: providing a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline; and removing nitrogen from the methane gas and liquefying a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant.

According to another embodiment of the invention, a method is disclosed for producing LNG from methane gas containing other gaseous components, the method comprising: providing a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline; introducing the methane gas into a first processing section configured to remove oxygen gas from the methane gas; introducing the methane gas into a second processing section configured to remove carbon dioxide from the methane gas; introducing the methane gas into a third processing section configured to dehydrate the methane gas; introducing the methane gas into a fourth processing section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant; introducing the LNG received from the fourth processing station into an LNG subcooling section to further cool LNG received from the fourth processing section without use of a recirculated refrigerant; and introducing LNG received from the LNG subcooler section into a receptacle.

According to another embodiment of the invention, a system and method are disclosed for producing liquid nitrogen and LNG from methane as separate product streams without use of a recirculated refrigerant.

According to another embodiment of the invention, a system and method are disclosed for producing LNG from methane recovered from a coal mine or from an LNG loading station or facility.

According to another embodiment of the invention, a system and method are disclosed for producing LNG and liquid nitrogen from methane recovered from a coal mine or from an LNG loading station or facility,

It will be appreciated by those of ordinary skill in the art upon reading this disclosure that additional processing sections for removing oxygen, carbon dioxide, water vapor, and possibly other components or contaminants that are present with methane in the inlet gas stream, can also be included in the system and method of the invention, depending upon factors such as, for example, the origin and intended disposition of the product streams and the amounts of such other gases or impurities or contaminants as are present in the inlet gas.

BRIEF DESCRIPTION OF THE DRAWINGS

The system and method of the invention are further described and explained in relation to the following drawings wherein:

FIG. 1 is a simplified process flow diagram illustrating principal processing stages of one embodiment of a system and method for producing LNG from an inlet gas containing methane and other contaminants;

FIG. 2 is a simplified process flow diagram illustrating principal processing stages of another embodiment of a system and method for producing LNG and liquid nitrogen (“LIN”) from an inlet gas containing methane and nitrogen;

FIG. 3 is a more detailed process flow diagram illustrating one embodiment of the nitrogen removal section of the simplified process flow diagrams of FIGS. 1 and 2;

FIG. 4 is a more detailed process flow diagram illustrating one embodiment of the LNG production section of the simplified process flow diagrams of FIGS. 1 and 2; and

FIG. 5 is a modified version of the detailed process flow diagram of FIG. 4 illustrating an alternate embodiment in which a liquid nitrogen stream is produced as another byproduct of the system and method of the invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Referring to FIG. 1, one satisfactory system 10 of the invention comprises processing equipment useful for receiving methane gas and cooling it to form LNG without the use of external refrigeration or a recirculated refrigerant. Although the source of the methane gas is not critical to the system and method of the invention, some suitable sources of methane gas for use in the invention are coal mines, LNG loading facilities, and other industrial or geologic sources. The methane used as inlet gas stream 12 will typically contain other gases as well, with nitrogen, oxygen, carbon dioxide and water vapor being the most notable examples. Where present, it is generally preferable for purposes of the present invention to remove as much of the oxygen, carbon dioxide and water vapor as is reasonably possible prior to implementing the nitrogen removal and methane liquefaction portions of the invention. For this reason, system 10 of the invention as depicted in FIG. 1 includes first, second, third processing sections 14, 16, 18 for the removal of oxygen, carbon dioxide and water vapor, respectively, upstream of the nitrogen removal section 20 and the LNG subcooler section 22 and LNG storage 24 for the LNG product 26. Conventional technologies for removing oxygen and carbon dioxide from methane, and for dehydrating the methane stream to remove water vapor are generally well known and are already commercially available from various sources. For this reason, this disclosure is primarily directed to enabling those of ordinary skill in the art to produce LNG and, optionally, liquid nitrogen from a methane inlet stream without the need for external refrigeration (including cascade refrigeration or mixed refrigerant processes).

Referring to FIG. 2, system 30 is disclosed as another suitable alternative embodiment of the invention. In this embodiment, the inlet gas 12, oxygen removal section 14, carbon dioxide removal section 16 and dehydration section 18 of the invention are provided as discussed above in relation to FIG. 1. In nitrogen removal section 20, however, a stream of nitrogen gas recovered from the methane is diverted to a nitrogen expander 175 to liquefy at least a portion of the stream, and then to a liquid nitrogen separator 196 to produce a liquid nitrogen product 204 in addition to LNG product 26 produced substantially as disclosed in relation to system 10 of FIG. 1.

Nitrogen removal section 20 of the invention as seen in FIGS. 1 and 2 is further described and explained in relation to FIG. 3. Referring to FIG. 3, a nitrogen-containing methane feed stream 56 is combined in manifold 60 with recycled methane stream 62 from an expander-compressor section that is part of LNG subcooler section 22 and is further described below in relation to FIG. 4. Combined inlet stream 57 is directed to plate fin cooler 64 or another similarly suitable heat exchange device and emerges as stream 66. Stream 66 is controlled by valve 68 to produce stream 70 having substantially the same temperature but approximately half the pressure of stream 66 before entering nitrogen fractionation tower 71. Tower 71 operates at approximately −230° F. and 300 psia, and causes the nitrogen gas to separate from the methane and flow upwardly through the tower as a vapor.

Acceptable inlet compositions in which this invention may operate satisfactorily are listed in the following Table 1:

TABLE 1
INLET STREAM COMPOSITIONS
                Acceptable Inlet Composition Ranges
Inlet Component (Inlet Percent)
Methane         20 to 100
Oxygen          0 to 15
Carbon Dioxide  0 to 5
Nitrogen        0 to 80

The flow rates, temperatures and pressures of various flow streams referred to in connection with the discussion of the system and method of the invention in relation to FIGS. 3 and 4 for a nominal inlet flow rate in this example of 19 MMSCFD appear in Table 2 below:

TABLE 2
FLOW STREAM PROPERTIES
	Stream
	Reference	Flow Rate	Temperature	Pressure
	Numeral	(lbmol/h)	(deg. F.)	(psia)
	26	575	−263	17
	56	1617	121	640
	57	1706	119	640
	62	89	120	1033
	66	1706	−230	639
	70	1706	−231	315
	72	1811	−252	280
	75	769	−252	280
	76	1043	−252	280
	76′	1043	−230	278
	77	1769	−224	280
	78	1078	−173	280
	79	1769	−206	280
	82	415	−168	280
	84	663	−168	280
	88	313	−168	280
	89	1043	−308	30
	90	350	−168	280
	94	350	−250	278
	98	350	−250	30
	100	350	−257	16
	102	350	−235	14
	104	350	110	14
	106	1421	−258	17
	108	1421	105	16
	112	1771	106	14
	115	1771	363	55
	117	1771	120	50
	119	1771	313	140
	121	1771	120	135
	123	1774	325	400
	126	1771	120	395
	128	1771	120	1034
	134	1683	120	1033
	136	1683	−12.5	1028
	138	1043	−225	28
	140	1043	110	27
	146	1771	120	635
	152	1771	120	864
	156	1771	158	1039
	160	313	−270	278
	166	1683	−200	125
	169	8	−200	124
	170	1675	−200	124
	174	1675	−253	20
	178	1526	−255	19
	180	1526	−258	17
	184	105	−258	17
	186	156	−255	19
	188	575	−263	17
	192	0	−263	17

Overhead nitrogen gas stream 72, shown as being external to tower 71 for purposes of illustration, is directed to condenser 74, but in practice condenser 74 is preferably a knockback condenser section that is internal to the tower, and is previously known. Condensate 75 is returned to the fractionation section of tower 71, and stream 76 of nitrogen gas is preferably directed to an N₂ expander that is further discussed below in relation to FIGS. 4 and 5. Q-1 represents the energy transferred to heat exchanger 99 from knockback condenser 74. Representative energy values for Q-1 and other energy streams that are identified in FIGS. 3 and 4 appear in Table 3 below:

TABLE 3
ENERGY STREAM REPORT
Energy Stream	Energy Rate
Reference Numeral	(Btu/h)	From	To
Q-1	1.08E+06	Virtual	KB
		KB	Condenser
Q-2	1.05E+06	Plate Fin	Virtual
			Reboiler
Q-4	4.26E+06		Sales
			1st Stage
Q-5	4.07E+06	1st Sales
		Cooler
Q-6	3.13E+06		Sales
			2nd Stage
Q-7	3.20E+06	2nd Sales
		Cooler
Q-8	3.31E+06		Sales
			3rd Stage
Q-9	3.52E+06	3rd Sales
		Cooler
Q-10	1.55E+06	Warm	Warm
		Expander	Comp
Q-11	965593	Low Temp	Low Temp
		Exp	Comp
Q-12	552059	N2	Nitrogen
		Exp	Comp
Q-13	1.74E+06	Warm
		Comp
		Cooler
Q-14	1.14E+06	LT Comp
		Cooler
Q-15	679952	N2 Comp
		Cooler

Stream 78 from the bottom of tower 71 is desirably directed to virtual reboiler 80 that receives heat (designated by energy stream Q-2) from plate fin cooler 64. Vapor stream 82 is returned to tower 71 and liquid methane stream 84 is directed through splitter manifold 86 to form two streams 88, 90 having comparable flow rates, temperatures and pressures. LNG stream 88 is directed to the LNG subcooling section 22 described below in relation to FIG. 4, and stream 90 is circulated through subcooler 92, valve 96 and heat exchanger 99, then back through subcooler 92 to plate fin cooler 64 as stream 102, through which it passes countercurrent to combined inlet stream 57. In this loop, the pressure of stream 90 is dropped more than about 260 psi and the stream is cooled more than 65 degrees before returning to plate fin cooler 64. In this manner, a portion of the LNG stream 84 produced in tower 71 can be recirculated for use an “internal” refrigerant for inlet stream 56. Sections of stream 90 are also designated by reference numerals 94, 98 and 100 at intermediate points between its passes through subcooler 92 to facilitate illustrating the temperature and pressure changes at various points in the loop.

Referring again to nitrogen fractionation tower 71, a sidestream 77 drawn, for example, from tray 13 of tower 71 is also directed back to and through plate fin cooler 64, again countercurrent to combined inlet stream 57, before returning as stream 79 to a lower position in tower 71, in this case tray 14. By reference to Table 2, it is seen that the temperature of the sidestream is increased by about 18° F. with virtually no change in pressure before reentering tower 71, thereby again serving as an “internal” refrigerant for inlet gas stream 56.

Stream 104 exits plate fin cooler 64 and is directed to mixing manifold 110 where it is desirably combined with stream 108 that emerges from plate fin cooler 64 after being returned as stream 106 from final LNG separator 182 of LNG subcooler section 22 as discussed below in relation to FIG. 4. Combined stream 112 is thereafter directed through an alternating series of compression stages 114, 116, 118 and sales coolers 120, 122, 124 in which the stream undergoes a net temperature increase of about 15 degrees and a net pressure increase of about 380 psi before flowing as stream 126 to a series of compression stages that are connected to and are driven by expanders, which extract mechanical energy from the expansion of gas streams that are further discussed below in relation to FIG. 4. Reference numerals 115, 117, 119, 121 and 123 are used to better illustrate the changes in temperature and pressure that the recycled material in stream 112 undergoes at intermediate points as it passes through the sales coolers before emerging as stream 126 in FIG. 3.

In summary, it is apparent from the foregoing discussion of nitrogen removal section 20 in relation to FIG. 3 and to the illustrative stream properties presented in Table 2 that substantial cooling of the inlet stream of mixed methane and nitrogen is achieved before reaching nitrogen fractionation tower 71 by strategically controlling the flows, temperatures and pressures of internal process streams and not through the use of external refrigeration.

Referring back to FIG. 1, the portion of system 10 that is inside dashed outline 200 is further described and explained in relation to FIG. 4. Referring to FIG. 4, stream 88 of LNG received from nitrogen removal section 20 of FIG. 3 is directed to subcooler 142, which is preferably a plate fin cooler or other similarly effective exchanger apparatus. The temperature of stream 88 is reduced approximately 100° F. with minimal pressure drop as it passes through subcooler 142, from which it emerges as stream 160 and is directed through manifold 162 into LNG storage section 24, from which LNG product 26 is produced. Referring to Table 2, LNG product can be produced according to the system and method of the invention at temperatures below 250° F. and pressures only slightly above atmospheric. LNG storage section 24 is desirably configured and adapted to recover any vapor that is flashed as stream 192. The substantial cooling provided by subcooler 142 to further lower the temperature of LNG received from nitrogen removal section 20 is again achieved through the use and control of internal process streams and not through use of external refrigeration.

One source of cooling within subcooler 142 is provided by expanding the gaseous nitrogen received from nitrogen removal section 20 in stream 76. Stream 76 is desirably directed to N₂ expander 175, from which it exits as stream 89, which is then directed to subcooler 142 countercurrent to the incoming flow of LNG in stream 88. Inside N₂ expander 175, the stream pressure is reduced by about 250 psi, with an attendant temperature reduction of about 55° F., to below −300° F. After emerging from subcooler 142, nitrogen stream 138 is returned to plate fin cooler 64 countercurrent to combined inlet stream 57 as described above, after which it exits as vent stream 140.

Another source of cooling within subcooler 142 is provided by sequentially expanding high pressure stream 136, which passes sequentially through warm expander 164, low temperature expander scrubber 168, low temperature expander 172, and LNG separator 176. In LNG separator 176, the material from stream 136 separates into streams 178, 186, respectively, with the flow rate of stream 178 being substantially greater (by a factor of about 10) than the flow rate of stream 186. During the progression from stream 136 to stream 178, the temperature drops about 240° as the pressure drops more than 1000 psi. Reference numerals 166, 170 and 174 are used to designate stream 136 at intermediate points between warm expander 164 and LNG separator 176 to assist in identifying the temperatures and pressures of the steam at those points.

As stream 178 passes through subcooler 142, it cools slightly more and exits as stream 180 into final LNG separator 182. In LNG separator 182, the material from stream 180 separates into streams 106 and 184, respectively, with the flow rate of stream 106 again being substantially greater than the flow rate of stream 184. Stream 106 is directed back to nitrogen removal section 20 of FIG. 3, where it enters and passes through plate fin cooler 64, from which it exits as stream 108 that is combined with stream 104 in manifold 110 to produce stream 112 as discussed above in relation to FIG. 3. Referring again to FIG. 4, stream 186 from LNG separator 176 and stream 184 from final LNG separator 182 are then combined in manifold 162 to form combined stream 188 that flows into LNG storage tank 24, from which LNG product 26 is produced.

Stream 136 as described above is received by warm expander 164 from plate fin cooler 64 in nitrogen removal section 20 of FIG. 3, which enters plate fin cooler 64 as stream 134. Stream 134 is formed when stream 128 as shown in FIG. 3 is split into streams 62 and 134 in manifold 132, after which stream 62 is combined with inlet stream 56 in manifold 60. Stream 128, in turn, originates from stream 126 of FIG. 3, after passing through a loop that is further described and explained in relation to LNG subcooler section 22 in FIG. 4.

Referring again to FIG. 4, stream 126 is received from nitrogen removal section 20 and passes successively through warm compressor 142, warm compressor cooler 144, low temperature compressor 148, low temperature compressor cooler 150, nitrogen compressor 154 and N₂ compressor cooler 158, before returning to nitrogen removal section 20 as stream 182, discussed above. Intermediate stream designations 146, 150, 152 and 156 are provided for use in tracking relative temperatures and pressures through this portion of system 10 of the invention. As compared to stream 126, the temperature of stream 128 is increased by less than 50° F. but the pressure is increased by more than 600 psi. Illustrative energy streams corresponding to the movement of the material of stream 126 through the various devices as identified above between stream 126 and stream 128 are reported in Table 2. All devices identified in relation to FIGS. 3 and 4 are believed to be commercially available from sources known to those of ordinary skill in the art, and particular equipment specifications will depend upon factors that can vary, for example, according to the intended application, use site, inlet gas composition, throughputs and operating conditions.

In accordance with another alternative embodiment of the invention in which liquid nitrogen is also produced according to the system and method of the invention, which corresponds to that portion of FIG. 2 that is identified by dashed box 300 and which is further described and explained in relation to FIG. 5, stream 89 can be directed to liquid nitrogen separator 196, from which overhead stream 197 is returned to subcooler 142. Stream 197 enters subcooler 142 countercurrent to LNG stream 88 in substantially the same manner that stream 89 did in the embodiment described in relation to FIG. 4, and exits as stream 138. Stream 138 is then returned to plate fin cooler 64 in nitrogen removal section 20, as previously shown and described in relation to FIG. 3. Liquid nitrogen stream 198, which exits from the bottom of liquid nitrogen separator 196, is desirably directed to storage vessel 201, from which liquid nitrogen product stream 204 is produced, with any flashed nitrogen vapor exiting vessel 201 as vent stream 202.

It should be appreciated by those of ordinary skill in the art upon reading this disclosure that the flow rate, temperature and pressure of stream 138 as shown in FIG. 5 will differ somewhat from the values as reported in Table 2 for the embodiment described in relation to FIGS. 3 and 4, which can in turn have a slight effect on the temperatures, pressures and/or energy values for other streams reported in Tables 2 and 3 to the extent that those streams are also referred to in the alternative embodiment of FIG. 5. Otherwise, the streams and flow configurations previously described in relation to FIGS. 3 and 4 are likewise applicable to like-numbered streams in FIG. 5.

Other alterations and modifications of the invention will likewise become apparent to those of ordinary skill in the art upon reading this specification in view of the accompanying drawings, and it is intended that the scope of the invention disclosed herein be limited only by the broadest interpretation of the appended claims to which the inventor is legally entitled.

Claims

1. A system for removing nitrogen and for producing liquefied natural gas (LNG) from methane gas comprising other gaseous components, the system comprising: a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline;a nitrogen removal section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant.

2. The system of claim 1, further comprising an LNG subcooler section disposed downstream of the nitrogen removal section; wherein the LNG subcooler section is configured to further cool LNG received from the nitrogen removal section without use of a recirculated refrigerant.

3. The system of claim 2, further comprising a first processing section for removing oxygen from the methane gas upstream of the nitrogen removal section.

4. The system of claim 3, further comprising a second processing section for removing carbon dioxide from the methane gas upstream of the nitrogen removal section.

5. The system of claim 4, further comprising a third processing section for dehydrating the methane gas upstream of the nitrogen removal section.

6. The system of claim 2 comprising conduits through which the methane gas received from the source can flow into and out of the nitrogen removal section and the LNG subcooler section; and a receptacle for LNG received from the LNG subcooler section.

7. The system of claim 1 wherein the source of methane gas is a coal mine.

8. The system of claim 7 wherein the source of methane gas is coal bed methane.

9. The system of claim 7 wherein the source of methane gas is gob gas.

10. The system of claim 1 wherein the source of methane gas is gas captured from an LNG loading facility.

11. The system of claim 1 wherein the receptacle is an LNG storage tank.

12. The system of claim 1 wherein the nitrogen removal section comprises a plate fin cooler.

13. The system of claim 1 wherein the nitrogen removal section comprises a nitrogen fractionation tower.

14. The system of claim 13 wherein the nitrogen fractionation tower discharges gaseous nitrogen and LNG.

15. The system of claim 14 wherein the gaseous nitrogen is expanded and cooled.

16. The system of claim 15 wherein the expanded and cooled nitrogen is used to subcool the LNG.

17. The system of claim of claim 16 wherein the nitrogen used to subcool the LNG is recirculated to a plate fin cooler in the nitrogen removal section, wherein the recirculated nitrogen cools the methane gas.

18. The system of claim 17 wherein the recirculated nitrogen is vented after cooling the methane gas.

19. The system of claim 18 wherein the LNG subcooler section comprises at least one separator wherein cold but unliquefied methane gas is separated from the LNG and is recirculated to a plate fin cooler in the nitrogen removal section, wherein the recirculated methane gas cools the methane gas entering the nitrogen removal section.

20. The system of claim 19 including at least one compressor that compresses the recirculated methane gas exiting the plate fin cooler, which compressed recirculated methane gas is then recycled, and apparatus that splits the recycled compressed recirculated methane gas into first part and a second part.

21. The system of claim 20 including apparatus for combining the first part with the methane gas entering the nitrogen removal section upstream of the plate fin cooler and upstream of the nitrogen fractionation tower.

22. The system of claim 21 including a conduit through which the second part flows through the plate fin cooler and then into the LNG subcooler section, where it is received into at least one expander and cooled sufficiently to liquefy at least a portion thereof.

23. The system of claim 22 comprising apparatus for combining the liquefied portion with the LNG received into the receptacle.

24. The system of claim 13 comprising a recycle conduit receiving a sidestream from the nitrogen fractionation tower that is circulated through a plate fin cooler in the nitrogen removal section and then returned to the nitrogen fractionation tower below the point at which it was received into the recycle conduit.

25. The system of claim 1 wherein a nitrogen expander is disposed downstream from the nitrogen removal section and nitrogen received from the nitrogen removal section is expanded to form a mixture of nitrogen gas and liquid nitrogen.

26. The system of claim 25, further comprising a liquid nitrogen separator to separate liquid nitrogen from the mixture of nitrogen gas and liquid nitrogen.

27. The system of claim 25 comprising apparatus wherein nitrogen gas recovered from the liquid nitrogen separator is directed through the LNG subcooler section to cool LNG recovered from the nitrogen removal section.

28. A method for removing nitrogen and for producing liquefied natural gas (LNG) from methane gas comprising other gaseous components, the method comprising: providing a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline; andremoving nitrogen from the methane gas and liquefying a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant.

29. The method of claim 1 comprising subcooling the LNG without use of a recirculated refrigerant.

30. The method of claim 28 comprising removing oxygen from the methane gas prior to removing nitrogen.

31. The method of claim 28 comprising removing carbon dioxide from the methane gas prior to removing nitrogen.

32. The method of claim 28 comprising dehydrating the methane gas prior to removing nitrogen.

33. The method of claim 29 wherein the subcooled LNG is introduced into a receptacle.

34. The method of claim 33 wherein the receptacle is an LNG storage tank.

35. The method of claim 29 wherein the nitrogen is removed in a nitrogen removal section comprising a plate fin cooler.

36. The method of claim 29 wherein the nitrogen is removed in a nitrogen removal section comprising a nitrogen fractionation tower.

37. The method of claim 36 wherein the nitrogen fractionation tower discharges gaseous nitrogen and LNG.

38. The method of claim 37 wherein the gaseous nitrogen is expanded and cooled.

39. The method of claim 38 wherein the expanded and cooled nitrogen is used to subcool the LNG.

40. The method of claim of claim 39 wherein the nitrogen used to subcool the LNG is recirculated to a plate fin cooler in the nitrogen removal section, wherein the recirculated nitrogen cools the methane gas.

41. The method of claim 40 wherein the recirculated nitrogen is vented after cooling the methane gas.

42. The method of claim 36 wherein the LNG subcooler section comprises at least one separator wherein cold but unliquefied methane gas is separated from the LNG and is recirculated to a plate fin cooler in the nitrogen removal section, wherein the recirculated methane gas cools the methane gas entering the nitrogen removal section.

43. The method of claim 42 including compressing the recirculated methane gas exiting the plate fin cooler, recycling the compressed recirculated methane gas, and splitting the recycled compressed recirculated methane gas into first part and a second part.

44. The method of claim 43 including combining the first part with the methane gas introduced into the nitrogen removal section upstream of the plate fin cooler and upstream of the nitrogen fractionation tower.

45. The method of claim 44 including directing a flow of the second part through the plate fin cooler and then into the LNG subcooler section, and thereafter expanding and cooling the flow sufficiently to liquefy at least a portion thereof.

46. The method of claim 45 comprising combining the liquefied portion with the subcooled LNG and introducing the subcooled LNG into a receptacle.

47. The method of claim 36 further comprising withdrawing and circulating a sidestream from the nitrogen fractionation tower through a plate fin cooler in the nitrogen removal section and then returning the sidestream to the nitrogen fractionation tower below a point at which it was withdrawn from the nitrogen fractionation tower.

48. The method of claim 29 wherein nitrogen removed from the methane gas is expanded and cooled to form a mixture of nitrogen gas and liquid nitrogen.

49. The method of claim 48 wherein the liquid nitrogen is separated from the mixture of nitrogen gas and liquid nitrogen.

50. The method of claim 49 wherein nitrogen gas recovered during separation from the liquid nitrogen is directed through the LNG subcooler section to cool LNG recovered from the nitrogen removal section.

51. A system for producing liquefied natural gas (LNG) from methane gas comprising other gaseous components, the system comprising: a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline;a first processing section configured to remove oxygen gas from the methane gas;a second processing section configured to remove carbon dioxide from the methane gas;a third processing section configured to dehydrate the methane gas;a fourth processing section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant;an LNG subcooler section disposed downstream of the fourth processing section;wherein the LNG subcooler section is configured to further cool LNG received from the fourth processing section without use of a recirculated refrigerant;conduits through which the methane gas received from the source can flow into and out of the first, second, third and fourth processing sections and the LNG subcooler section; anda receptacle for LNG received from the LNG subcooler section.

52. The system of claim 51 wherein the source of methane gas is a coal mine.

53. The system of claim 52 wherein the source of methane gas is coal bed methane.

54. The system of claim 52 wherein the source of methane gas is gob gas.

55. The system of claim 51 wherein the source of methane gas is gas captured from an LNG loading facility.

56. The system of claim 51 wherein the second processing section is disposed downstream of the first processing section.

57. The system of claim 51 wherein the third processing section is disposed downstream of the second processing section.

58. The system of claim 51 wherein the fourth processing section is disposed downstream of the third processing section.

59. The system of claim 51 wherein the receptacle is an LNG storage tank.

60. The system of claim 51 wherein the fourth processing section comprises a plate fin cooler.

61. The system of claim 51 wherein the fourth processing section comprises a nitrogen fractionation tower.

62. The system of claim 61 wherein the nitrogen fractionation tower discharges gaseous nitrogen and LNG.

63. The system of claim 62 wherein the gaseous nitrogen is expanded and cooled.

64. The system of claim 63 wherein the expanded and cooled nitrogen is used to subcool the LNG.

65. The system of claim of claim 64 wherein the nitrogen used to subcool the LNG is recirculated to a plate fin cooler in the fourth processing section, wherein the recirculated nitrogen cools the methane gas.

66. The system of claim 65 wherein the recirculated nitrogen is vented after cooling the methane gas.

67. The system of claim 61 wherein the LNG subcooler section comprises at least one separator wherein cold but unliquefied methane gas is separated from the LNG and is recirculated to a plate fin cooler in the fourth processing section, wherein the recirculated methane gas cools the methane gas entering the fourth processing section.

68. The system of claim 67 including at least one compressor that compresses the recirculated methane gas exiting the plate fin cooler, which compressed recirculated methane gas is then recycled, and apparatus that splits the recycled compressed recirculated methane gas into first part and a second part.

69. The system of claim 68 including apparatus for combining the first part with the methane gas entering subsection four upstream of the plate fin cooler and upstream of the nitrogen fractionation tower.

70. The system of claim 69 including a conduit through which the second part flows through the plate fin cooler and then into the LNG subcooler section, where it is received into at least one expander and cooled sufficiently to liquefy at least a portion thereof.

71. The system of claim 70 comprising apparatus for combining the liquefied portion with the LNG received into the receptacle.

72. The system of claim 61 comprising a recycle conduit receiving a sidestream from the nitrogen fractionation tower that is circulated through a plate fin cooler in the fourth processing section and then returned to the nitrogen fractionation tower below the point at which it was received into the recycle conduit.

73. The system of claim 51 wherein a nitrogen expander is disposed downstream from the fourth processing section and nitrogen received from the fourth processing section is expanded to form a mixture of nitrogen gas and liquid nitrogen.

74. The system of claim 73, further comprising a liquid nitrogen separator to separate liquid nitrogen from the mixture of nitrogen gas and liquid nitrogen.

75. The system of claim 74 comprising apparatus wherein nitrogen gas recovered from the liquid nitrogen separator is directed through the LNG subcooler section to cool LNG recovered from the fourth processing section.

76. A method for producing liquefied natural gas (LNG) from methane gas containing other gaseous components, the method comprising: providing a source of methane gas disposed proximally to a processing site, the source being accessible to the site without transport through an external pipeline;introducing the methane gas into a first processing section configured to remove oxygen gas from the methane gas;introducing the methane gas into a second processing section configured to remove carbon dioxide from the methane gas;introducing the methane gas into a third processing section configured to dehydrate the methane gas;introducing the methane gas into a fourth processing section configured to remove nitrogen gas from the methane gas and to liquefy a substantial portion of the methane gas to produce LNG without use of a recirculated refrigerant;introducing the LNG received from the fourth processing station into an LNG subcooling section to further cool LNG received from the fourth processing section without use of a recirculated refrigerant; andintroducing LNG received from the LNG subcooler section into a receptacle.

77. The method of claim 76 wherein the source of methane gas is a coal mine.

78. The method of claim 77 wherein the source of methane gas is coal bed methane.

79. The method of claim 77 wherein the source of methane gas is gob gas.

80. The method of claim 76 wherein the source of methane gas is gas captured from an LNG loading facility.

81. The method of claim 76 wherein the second processing section is disposed downstream of the first processing section.

82. The method of claim 76 wherein the third processing section is disposed downstream of the second processing section.

83. The method of claim 76 wherein the fourth processing section is disposed downstream of the third processing section.

84. The method of claim 76 wherein the receptacle is an LNG storage tank.

85. The method of claim 76 wherein the fourth processing section comprises a plate fin cooler.

86. The method of claim 76 wherein the fourth processing section comprises a nitrogen fractionation tower.

87. The method of claim 86 wherein the nitrogen fractionation tower discharges gaseous nitrogen and LNG.

88. The method of claim 87 wherein the gaseous nitrogen is expanded and cooled.

89. The method of claim 88 wherein the expanded and cooled nitrogen is used to subcool the LNG.

90. The method of claim of claim 89 wherein the nitrogen used to subcool the LNG is recirculated to a plate fin cooler in the fourth processing section, wherein the recirculated nitrogen cools the methane gas.

91. The method of claim 90 wherein the recirculated nitrogen is vented after cooling the methane gas.

92. The method of claim 86 wherein the LNG subcooler section comprises at least one separator wherein cold but unliquefied methane gas is separated from the LNG and is recirculated to a plate fin cooler in the fourth processing section, wherein the recirculated methane gas cools the methane gas entering the fourth processing section.

93. The method of claim 92 including compressing the recirculated methane gas exiting the plate fin cooler, recycling the compressed recirculated methane gas, and splitting the recycled compressed recirculated methane gas into first part and a second part.

94. The method of claim 93 including combining the first part with the methane gas introduced into subsection four upstream of the plate fin cooler and upstream of the nitrogen fractionation tower.

95. The method of claim 94 including directing a flow of the second part through the plate fin cooler and then into the LNG subcooler section, and thereafter expanding and cooling the flow sufficiently to liquefy at least a portion thereof.

96. The method of claim 95 comprising combining the liquefied portion with the LNG introduced into the receptacle.

97. The method of claim 96 further comprising withdrawing and circulating a sidestream from the nitrogen fractionation tower through a plate fin cooler in the fourth processing section and then returning the sidestream to the nitrogen fractionation tower below a point at which it was withdrawn from the nitrogen fractionation tower.

98. The method of claim 76 wherein nitrogen received from the fourth processing section is expanded and cooled to form a mixture of nitrogen gas and liquid nitrogen.

99. The method of claim 98 wherein the liquid nitrogen is separated from the mixture of nitrogen gas and liquid nitrogen.

100. The method of claim 99 wherein nitrogen gas recovered during separation from the liquid nitrogen is directed through the LNG subcooler section to cool LNG recovered from the fourth processing section.