1. Field of the Invention
The invention relates generally to a system and method for recharging a high pressure gas storage container and to an apparatus for transporting a cryogenic fluid at low pressure.
2. Background Art
Gasses are often stored under high pressure in high pressure storage containers, with applications ranging from inert gas storage for welding to oxygen tanks in space. As the pressurized gas is depleted from the high pressure storage container, the pressure of the gas drops. After a period of depletion, the high pressure storage container must be recharged.
Conventionally, the gasses that are used to recharge the depleted storage containers are transported in ambient temperature high pressure recharge gas containers. That is, when recharging a high pressure storage container, a recharge gas container containing the recharge gas at a much higher pressure than the target pressure of the high pressure storage container is transported, connected to the system, and the pressures are allowed to equalize. For example, if pressurized oxygen stored in a storage container at 21 MPa is depleted to 7 MPa, a recharge gas container of equal volume as the high pressure storage container must contain pressurized oxygen at almost 40 MPa in order to fully recharge the storage container to 21 MPa. Thus, the recharge gas container must be designed to withstand significantly higher pressures than the high pressure storage container.
A method for recharging a high pressure gas storage container unit according to one or more embodiments of the present invention comprises the steps of disposing a first heater on a recharge gas container unit, filling a recharge gas container of the recharge gas container unit with fluid in the form of a cryogenic liquid, attaching or otherwise operatively connecting the recharge gas container to a second heater, attaching or otherwise operatively connecting the second heater to the high pressure storage container unit, activating the first heater to cause the cryogenic fluid to expand out of the recharge gas container, and activating the second heater to warm the fluid expelled from the recharge gas container before entry into the high pressure gas storage container unit.
In another embodiment of the invention, a system for recharging gas stored at a high pressure in a storage container according to one or more embodiments of the present invention comprises a recharge gas container unit, a second heater operatively connected to the recharge gas container unit by piping during recharge, and a high pressure storage container unit. The recharge gas container unit comprises a recharge gas container. Fluid in a form of cryogenic fluid is disposed within the recharge gas container. A first heater is operatively connected to the recharge gas container near a neck portion of such container. The high pressure storage container unit comprises a high pressure storage container operatively connected to the second heater by piping during the act of recharging such container.
Other aspects and advantages of the invention will be apparent from the following description and the appended claims.
Exemplary embodiments of the invention will be described with reference to the accompanying figures. Like items in the figures are shown with the same reference numbers.
In embodiments of the invention, numerous specific details are set forth in order to provide a more thorough understanding of the invention. However, it will be apparent to one of ordinary skill in the art that the invention may be practiced without these specific details. In other instances, well-known features have not been described in detail to avoid obscuring the invention.
Embodiments of the invention relate to a system and method for the recharge of gas stored within a high pressure storage container. More specifically, embodiments of the invention relate to an apparatus for transporting recharge gas as a cryogenic liquid and a system and method for recharging a high pressure gas storage container.
Referring now to
In one embodiment, the recharge gas container 100 comprises a spherical cryogenic dewar, and has an inner wall 111 and an outer wall 113, with an evacuated space 112 therein filled with insulation. Although in this embodiment the recharge gas container 100 is described as spherical, the recharge gas container may be of other container shapes known in the art, such as a cylinder, tubular, etc. The inner wall 111 may be manufactured of metal or other suitable materials known in the art that can withstand cryogenic temperatures and high pressures. The outer wall 113 may be manufactured of metal or other suitable materials known in the art. At the top of the recharge gas container 100, a container outlet or neck 114, having a single wall layer, is disposed. The recharge gas container 100 is filled with a high void fraction wettable matrix 120, such as fumed silica, to provide fluid management (such as, for example, preventing cryogenic liquid from sloshing) during transport. The wettable matrix 120 is contained within the recharge gas container 100 by a fine screen 115 disposed at the container neck 114. The mesh pattern of the fine screen 115 is fine enough to prevent the wettable matrix 120 from exiting, but coarse enough to let fluid through.
The ring heater 117 is disposed around and operatively connected to the container outlet or neck 114, and the ring heater insulation 119 surrounds the ring heater 117. The ring heater insulation 119 may also surround a portion of the outer wall 113 of the recharge gas container 100, as well as a portion of the piping 131. The ring heater insulation 119 may be a closed cell foam cap, or other insulating materials known in the art. In one embodiment, the piping 131 is in a T-shaped configuration, with one end connected to the container neck 114, and the two other ends each connected to the first and second self-sealing quick disconnect fitting halves 141, 143. In one or more embodiments of the present invention, the piping 131 may be insulated.
Once the act of filling of the recharge gas container 100 is completed, it is ready for transport. The low pressure relief valve 175 serves to maintain constant pressure within the recharge gas container 100 when heat leak through the walls of the recharge gas container 100 would otherwise increase the pressure therein. For example, in one embodiment the low pressure relief valve 175 may be set at 0.203 MPa (2 atm). The recharge gas container unit 1 and the low pressure relief valve unit 170 are then transported to the location of the high pressure storage container unit 2, indicated in
In one embodiment, the temperature-controlled heating block unit 160 comprises a temperature-controlled heating block 161, a check valve 185, third and fourth self-sealing quick disconnect fitting halves 145, 147, piping 133 connecting the third self-sealing quick disconnect fitting half 145 to the check valve 185, piping 134 connecting the check valve 185 to the temperature-controlled heating block 161, and piping 135 connecting the temperature-controlled heating block 161 to the fourth self-sealing quick disconnect fitting half 147. The temperature controlled heating block 161 maintains a constant preset temperature when activated. In one or more embodiments of the invention, the preset temperature is ambient. The check valve 185 prevents back flow from the high pressure storage container unit 2. The check valve 185 may have, for example, a ball member and a spring member, such that the ball member blocks fluid flow through the check valve unless the pressure on the inlet side is greater than the pressure on the outlet side of the check valve 185. In one or more embodiments of the present invention, the piping 133, 134, 135 may be insulated. Alternatively, because the fluid exiting the temperature-controlled heating block 161 may be at or near ambient temperature, only the piping 133, 134 on the inlet side of the temperature-controlled heating block 161 may be insulated. Alternatively, only the piping 135 on the outlet side of the temperature-controlled heating block 161 may be insulated. The temperature-controlled heating block 161 is surrounded by insulation 163. The insulation 163 may also cover a portion of the piping 133, 135. The temperature-controlled heating block unit 160 is operatively connected to the recharge gas container unit 1 by attaching the second self-sealing quick disconnect fitting half 143 of the recharge gas container unit 1 to the third self-sealing quick disconnect fitting half 145 of the temperature-controlled heating block unit 160 (shown as a portion of method step ST406).
The high pressure storage container unit 2 includes a high pressure storage container 200, a fifth self-sealing quick disconnect fitting half 149, and piping 137 connecting the fifth self-sealing quick disconnect fitting half 149 to the high pressure storage container 200. The high pressure storage container includes a container wall 211 and a container inlet or neck 214 which is attached to the piping 137. In one or more embodiments of the present invention, the piping 137 is insulated. The high pressure storage container 200 is capable of containing pressurized gas 11 at a high pressure level. The temperature-controlled heating block unit 160 is attached to the high pressure storage container unit 2 by attaching the fifth self-sealing quick disconnect fitting half 149 of the high pressure storage container unit 2 to the fourth self-sealing quick disconnect fitting half 147 of the temperature-controlled heating block unit 160 (shown as a portion of method step ST406 of
Once the recharge gas container unit 1, the temperature-controlled heating block unit 160, and the high pressure storage container unit 2 are operatively connected or attached as shown in
As shown in
To ensure that all fluid entering the high pressure storage container 200 is at ambient temperature, a proper heating ratio is necessary between the heater power of the temperature-controlled block heater 161 and the ring heater 117. The method for calculating this ratio will be explained in more detail below with reference to
Now at ambient temperature, the fluid 13 flows into the high pressure storage container 200 by way of piping 135, 137. Delivery of the fluid to the high pressure storage container 200 is regulated partially by controlling the ring heater 117 and can be reduced to a minimum flow by turning the ring heater off. The act of transfer is done after the heaters have brought all or substantially all of the contents (fluid 10) of the recharge gas container 100 to ambient temperature and the contents of the high pressure storage container 200 have reached thermal equilibrium with its surroundings (shown as step ST409 in
At this point, the pressurized fluid 13 originating from the recharge gas container 100 and the gas 11 of the high pressure storage container 200 are at equilibrium. That is, the pressurized fluid inside the recharge gas container 100 and the high pressure storage container 200 are at ambient temperature and at the desired gas pressure of the high pressure storage container 200. Having the benefit of this description, one of ordinary skill in the art will now recognize that this equilibrium pressure can be controlled by the amount of cryogenic fluid 10 that was transferred to the recharge gas container 100 (at step ST402).
Once the pressures in the recharge gas container 100 and the high pressure storage container 200 have equalized, the fluid transfer is finished and recharge has been accomplished. The recharge gas container unit 100 is then operatively disconnected at the self-sealing quick disconnect fitting half 143 and is available for reuse. Similarly, the temperature-controlled heating block unit 160 is operatively disconnected at the self-sealing quick disconnect fitting half 147 and stored for future use, as shown by method ST410 of
The method for sizing the heating system with a heating ratio that will work will now be explained with reference to
As explained above, to ensure that all fluid entering the high pressure storage container 200 is at ambient temperature, a proper ratio is necessary between the heater powers of the temperature-controlled block heater 161 and the ring heater 117. That is, the temperature-controlled block heater 161 must have sufficient heating power to heat the fluid 10 exiting from the recharge gas container 100 up to ambient temperature under a “highest demand” scenario. The “highest demand” scenario in this case would occur when the fluid being expelled from the recharge gas container 100 is at maximum volume per input energy and at maximum density, thereby requiring the maximum energy for the temperature-controlled block heater 161 to heat a mass of supercritical fluid (i.e. change its specific enthalpy) from the minimum temperature of the cryogenic liquid (“Tmin”) to the maximum temperature that the fluid will reach (“Tmax”).
Accordingly, the method first comprises the step ST501 of determining Tmin, Tmax, maximum pressure (“Pmax”), and minimum pressure (“Pmin”) of the system. In the present example involving oxygen, Tmin is −176° C., Tmax is an ambient temperature of 21° C., and the Pmin and Pmax are 7 MPa and 21 MPa, respectively.
Given that the specific volume is plotted against specific enthalpy for a range of constant pressures from Pmin to Pmax over the temperature range from Tmin to Tmax, the maximum slope is determined from the plot. In other words, the maximum volume of fluid expelled from the recharge gas container per unit heat input (“ΔVmax/ΔE”) by the ring heater is determined at step ST502a.
Temperature is plotted against specific volume for a range of constant pressure from Pmin in to Pmax, and the minimum specific volume (“υmin”) at Tmin is determined from the plot. The inverse of υmin, which is equal to the maximum density (“ρmax”) of the fluid, is then calculated at step ST502b.
Temperature is plotted against specific enthalpy for a range of constant pressure from Pmin to Pmax, and the maximum change in specific enthalpy (“Δhmax”) when the temperature is raised from Tmin to Tmax is determined from the plot at step ST502c. That is, the maximum amount of input heat energy necessary to heat a unit mass from Tmin to Tmax is determined.
Once ΔVmax/ΔE and ρmax are calculated, their product will yield the maximum mass of fluid expelled from the recharge gas container 100 per unit input heat energy (“ΔMmax/ΔE”) supplied by the ring heater 117 as shown by step ST503. In the present example, the product of ΔVmax/ΔE and ρmax yields 4.97*10−2 kg/kJ. Thus, in the example, a maximum of 4.97*10−2 kg of supercritical oxygen is expelled from the recharge gas container 100 per 1 kJ of heat energy inputted by the ring heater 117.
One or more embodiments of the present invention have one or more of the following advantages. The high pressure storage container 200 can be recharged without transporting gasses at high pressure in the recharge gas container 100. The transport of the recharge gas container is safer because the fluid can be transported near atmospheric pressure. The high pressure storage container 200 does not have to be designed to withstand cryogenic temperatures. The recharge gas container 100 does not have to be designed to withstand pressures higher than a target pressure of the high pressure storage container 200. A conventional high pressure storage container 200 can be recharged by the process.
Although only a few exemplary embodiments of this invention have been described in detail above, those skilled in the art, having benefit of this description, will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention as defined in the following claims. In the claims, means-plus-function and step-plus-function clauses are intended to cover the structures or acts described herein as performing the recited function and not only structural equivalents, but also equivalent structures. Thus, although a nail and a screw may not be structural equivalents in that a nail employs a cylindrical surface to secure wooden parts together, whereas a screw employs a helical surface, in the environment of fastening wooden parts, a nail and a screw may be equivalent structures.
The invention described herein was made by employee(s) of the United States Government and may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon of therefore. The invention described herein was also made in the performance of work under a NASA contract and is subject to the provisions of Section 305 of the National Aeronautics and Space Act of 1958, Public Law 85-568 (72 Stat. 435, 42 U.S.C. 2457).