Patent Application
20140345649
The present invention relates to a system and method for remediating contaminated soil, and more particularly, to a system and method for remediating highly contaminated fine soil using multiple micro hydrocyclones which finely separates the contaminated soil with contaminants like heavy metals by using the multiple micro hydrocyclones in accordance with the contamination degrees of the soil by particle size.
With the development of the industry, soil becomes contaminated with hazardous substances like oil and heavy metals, and so as to remediate the contaminated soil, thus, compositions or devices for washing the contaminated soil have been suggested.
One example of such soil washing devices is disclosed in Korean Patent Laid-Open Application No. 2003-0005713 (dated on Jan. 23, 2003) wherein the soil washing device includes a pre-washing tank and a main washing tank by which the contaminated soil can be repeatedly washed.
Further, the conventional soil washing device is configured wherein the contaminated soil is collected and poured into a mixing tank for remediation.
In this case, referring to
However, disadvantageously, the conventional soil washing devices just perform the remediation of all of the contaminated soil, irrespective of soil properties and the soil contamination degrees caused by the soil properties, that is, irrespective of the differences of the particle sizes of soil on a paddy field, farm, seaside and mountain range and the contamination degrees of the soil by particle size, thereby showing low efficiencies in remediation work.
Accordingly, the present invention has been made in view of the above-mentioned problems occurring in the prior art, and it is an object of the present invention to provide a system and method for remediating highly contaminated fine soil using multiple micro hydrocyclones which largely separates contaminated soil into fine soil containing a large amount of silt and medium soil containing a large amount of sand and finely separates the highly contaminated soil by particle size from the separated soil, such that only the highly contaminated soil can be intensively remediated.
To accomplish the above object, according to a first aspect of the present invention, there is provided a system for remediating highly contaminated fine soil using multiple micro hydrocyclones, the system including: a mill adapted to mix contaminated soil with water and to individualize the soil; a screen adapted to separate the soil introduced from the mill into soil having given particle sizes a separator adapted to finely separate the soil having particle sizes of less than a given value by particle size from the soil having the given particle sizes separated through the screen a remediating unit adapted to wash the finely separated soil introduced from the separator by particle size by means of process water for washing; and a filtering unit adapted to separately discharge the soil washed and introduced through the remediating unit and the process water for washing contained in the soil.
According to the present invention, preferably, the soil remediation system further includes a coagulating and settling unit adapted to coagulate and settle the process water for washing discharged from the filtering unit and a portion of the soil finely separated through the separator
According to the present invention, preferably, the soil remediation system further includes a process water for washing-recycling unit adapted to absorb the contaminants of the process water for washing introduced from the coagulating and settling unit and to recycle the process water for washing.
According to the present invention, preferably, the process water for washing-recycling unit is configured to absorb the contaminants inclusive of arsenic in the process water for washing onto Fe3+-modified activated carbon.
According to the present invention, preferably, the mill includes a log washer which is an instrument adapted to mix soil and water and to individualize the soil, and the contaminated soil mixed and individualized through the log washer is farm soil.
According to the present invention, preferably, the screen includes a wet vibration screen, and through the screen, the soil is separated into soil like gravel and sand having particle sizes of more than 0.075 mm and fine soil like silt having particle sizes of less than 0.075 mm.
According to the present invention, preferably, the separator includes the multiple micro hydrocyclones corresponding to the number of particle size units of the soil to be separated in such a manner as to be connected serially to each other, and the ranges of the particle sizes for the separation of the soil can be varied in accordance with the introduction speeds and the particle size variations of the lower side discharge parts of the micro hydrocyclones.
According to the present invention, preferably, the separator, which finely separates the soil in accordance with the particle sizes of the soil, includes: a first micro hydrocyclone adapted to introduce the soil having the particle sizes of more than 0.075 mm to the screen again and to convey the soil having the particle sizes of less than 0.075 mm separately; a second micro hydrocyclone adapted to convey the soil having the particle sizes between 0.040 mm and 0.075 mm to the remediating unit and to convey the soil having the particle sizes of less than 0.040 mm separately; and a third micro hydrocyclone adapted to convey the soil having the particle sizes between 0.020 mm and 0.040 mm to the remediating unit and to convey the soil having the particle sizes of less than 0.020 mm to the coagulating and settling unit.
According to the present invention, preferably, the remediating unit is adapted to perform different remediating processes if additional remediating processes are needed in accordance with the contamination degrees of the separated soil by the particle size range, for example, if the fine soil having the particle sizes of less than 0.075 mm is remarkably varied in the contamination degrees in the particle size ranges of 0.040 mm and 0.020 mm, thereby achieving effective remediation.
According to the present invention, preferably, the remediating unit includes: a first mixing tank adapted to conduct the elution of the contaminants through the process water for washing for a period of time if the soil having the particle sizes between 0.040 mm and 0.075 mm is introduced thereto; a second mixing tank adapted to conduct the elution of the contaminants through the process water for washing for a longer period of time than the first mixing tank if the soil having the particle sizes between 0.020 m and 0.040 mm is introduced thereto; and a thickener adapted to convey the highly contaminated soil to the filtering unit in a state of being substantially suppressed in elution of contaminants thereof if the highly contaminated soil coagulated and settled through the coagulating and settling unit is introduced thereto.
According to the present invention, preferably, the filtering unit includes a vacuum belt filter adapted to discharge the process water for washing from the soil conveyed through a belt filter by means of vacuum.
To accomplish the above object, according to a second aspect of the present invention, there is provided a method for remediating highly contaminated fine soil using multiple micro hydrocyclones, the method including the steps of: performing a milling step wherein contaminated soil is mixed with water and is individualized; performing a separating step wherein the individualized soil through the milling step is separated by particle size; performing a finely separating step wherein the soil having the particle sizes of less than a given value in the soil separated in the separating step is finely separated by particle size; performing a first remediating step wherein the soil having given particle size ranges in the finely separated soil through the finely separating step is washed through process water for washing; and performing a filtering step wherein the process water for washing is separated and discharged from the soil having a given particle size range not passed through the first remediating step in the finely separated soil through the finely separating step and from the soil having the given particle size ranges washed in the first remediating step.
According to the present invention, preferably, in the finely separating step the soil having the particle sizes of more than 0.075 mm is conveyed to the separating step, the soil having the particle sizes between 0.040 mm and 0.075 mm and between 0.020 mm and 0.040 mm is discharged to the first remediating step, and the soil having the particle sizes of less than 0.020 mm is discharged to the filtering step.
According to the present invention, preferably, in the first remediating step the soil retained separately by particle size is washed through the process water for washing.
According to the present invention, preferably, the method further includes the steps of: performing a coagulating and settling step wherein the soil having the particle sizes of less than 0.020 mm finely separated in the finely separating step is coagulated and settled and the coagulated and settled soil is discharged to the filtering step; and performing a second remediating step wherein the highly contaminated soil discharged from the coagulating and settling step is discharged to the filtering step in a state of being substantially suppressed in elution of the contaminants thereof.
To accomplish the above object, according to a third aspect of the present invention, there is provided a method for remediating highly contaminated fine soil using multiple micro hydrocyclones, the method including the steps of: performing a milling step wherein contaminated soil is mixed with water and is individualized; performing a separating step wherein the individualized soil is separated into coarse soil like gravel and sand having particle sizes of more than 0.075 mm and fine soil having particle sizes of less than 0.075 mm performing a finely separating step wherein the soil having the particle sizes of more than 0.075 mm introduced from the separating step is conveyed to the separating step, and the soil having the particle sizes between 0.040 mm and 0.075 mm, between 0.020 mm and 0.040 mm, of less than 0.020 mm is finely separated and discharged performing a first remediating step wherein the soil having given particle size ranges between 0.040 mm and 0.075 mm and between 0.020 mm and 0.040 mm in the finely separated soil is stored separately and washed through process water for washing; performing a filtering step wherein the soil introduced from the first remediating step and the process water for washing introduced together with the soil are separately discharged performing a coagulating and settling step wherein the process water for washing separated in the filtering step and the soil having the particle sizes of less than 0.020 mm finely separated in the finely separating step are agitated and coagulatedlysettled; performing a second remediating step wherein the highly contaminated soil discharged from the coagulating and settling step is discharged to the filtering step in a state of being substantially suppressed in elution of the contaminants thereof and performing a purifying and returning step wherein the process water for washing supplied to the coagulating and settling step is collected and purified and the purified water is conveyed to the milling step.
According to the present invention, preferably, in the purifying and returning step the contaminants inclusive of arsenic in the process water for washing is absorbed onto Fe3+-modified activated carbon.
According to the present invention, the highly contaminated soil is collectively separated by particle size in accordance with soil properties, and thus, the remediation is intensively performed for the soil by particle size.
In addition, through the intensive remediation of the soil by particle size, the present invention can prevent the inefficient work wherein even the soil having particle sizes having relatively low contamination degrees is remediated together with the soil having particle sizes having relatively high contamination degrees, and also, the present invention can reduce the working time and costs.
Hereinafter, an explanation on a system for remediating highly contaminated fine soil using multiple micro hydrocyclones according to the present invention will be in detail given with reference to the attached drawings.
According to the present invention, first, a system 100 for remediating highly contaminated fine soil using multiple micro hydrocyclones is provided to remediate highly contaminated soil, especially, the soil in specific areas around plants like steel mills, smelters and so on which is seriously contaminated with contaminants discharged from the plants. In this case, the soil near the smelter area is best in the contamination degree, and at this time, the range of the soil needed to be remediated is within a radius of 2 km around the smelter area. The contaminants contained in the contaminated soil include arsenic (As) as a main contaminant, zinc (Zn), copper (Cu), lead (Pb), cadmium (Cd), nickel (Ni), and the like.
So as to collect the information on the design of the system 100 according to the present invention, on the other hand, the soil around a plant area was separated by particle size into sand of 85.9%, gravel of 2.3% and silt of 11.8%, as shown in
Like this, it could be appreciated that the silt soil from the farm soil around the smelter area was highly contaminated with arsenic. Referring to the contamination standards of arsenic as suggested under Asterisk No. 3 of Paragraph 1 of Article 13 of the Soil Environment Conservation Act, on the other hand, a first area has arsenic of 25 mg/kg and a second area has arsenic of 50 mg/kg. Based on the contamination standards of arsenic, as shown in
The soil remediation system 100 according to the present invention made with the above-mentioned data largely includes a mill 110, a screen 120, a separator 130, a remediating unit 140, a filtering unit 150, a coagulating and settling unit 160 and a process water for washing-recycling unit 170. In this case, soil is separated by particle size through the screen 120 and the separator 130, and the soil separated by particle size contains the soil having different particle sizes therefrom. This is because the separation may be performed with the allowance range of the mechanical errors. Therefore, it should be understood that the boundary values by particle size suggested in the preferred embodiment of the present invention contain the allowance range occurring by the mechanical errors.
If farm soil is introduced from a hopper 101 to the mill 110, the mill 110 is adapted to mix the soil with water to individualize the mixed soil, which includes a log washer used as an existing mill. The log washer is configured to rotate a log in a semi-cylindrical tank disposed slantly so as to individualize soil with water, and to convey and discharge the individualized and broken soil, and to allow silt to overflow in a state of being mixed with water.
The screen 120 is adapted to separate the soil introduced from the mill 110 into gravel having a particle size of more than 2.0 mm, sand having particle sizes between 0.075 mm and 2.0 mm, and silt having particle sizes of less than 0.075 mm. In this case, the screen 120 includes a wet vibration screen used as an existing screen. The weights, water contents and arsenic concentrations of the gravel, sand and silt discharged through the screen 120 from the totally introduced farm soil are listed by the following Table 2. At this time, 3 tons are introduced from the total allowance introduction amount of 6 tons, and the whole arsenic concentration is 32.2 mg/kg.
(This data is based on the estimation for the field experiments conducted by Korea Environment Corporation on Dec. 22, 2010).
If the soil mainly containing the silt having particle sizes of less than 0.075 mm is introduced to the separator 130, the separator 130 performs the separation of the soil. In this case, the separator 130 has multiple micro hydrocyclones, as shown in
The first micro hydrocyclone 131 is adapted to introduce the soil having the particle sizes of more than 0.075 mm to the screen 120 again and to convey the soil having the particle sizes of less than 0.075 mm to the second micro hydrocyclone 132.
The second micro hydrocyclone 132 is adapted to convey the soil having the particle sizes between 0.040 mm and 0.075 mm to the remediating unit 140 and to convey the soil having the particle sizes of less than 0.040 mm to the third micro hydrocyclone 133.
The third micro hydrocyclone 133 is adapted to convey the soil having the particle sizes between 0.020 mm and 0.040 mm to the remediating unit 140 and to convey the soil having the particle sizes of less than 0.020 mm to the coagulating and settling unit 160.
The remediating unit 140 is adapted to wash the soil introduced in a state of being separated by particle size from the separator 130 having the multiple micro hydrocyclones. In this case, the remediating unit 140 serves to remediate the contaminated soil with process water for washing.
The remediating unit 140 includes a first mixing tank 141, a second mixing tank 142 and a thickener 143, such that the soil is conveyed in a state of being substantially suppressed in elution of contaminants thereof through the first mixing tank 141, the second mixing tank 142 and the thickener 143 to the filtering unit 150.
If the soil having the particle sizes between 0.040 mm and 0.075 mm is introduced from the second micro hydrocyclone 132, the first mixing tank 141 conducts the washing of the soil with the process water for washing.
If the soil having the particle sizes between 0.020 mm and 0.040 mm is introduced from the third micro hydrocyclone 133, the second mixing tank 142 conducts the washing of the soil with the process water for washing.
At this time, since the particle sizes of the soil introduced into the first mixing tank 141 and the second mixing tank 142 are different from each other and the particle size contamination concentrations are different from each other, the amounts and concentrations of the process water for washing introduced into the first mixing tank 141 and the second mixing tank 142 are also differently set. Thus, concentration measuring instruments may be additionally installed.
Further, if the soil having the particle sizes of less than 0.020 mm is introduced from the coagulating and settling unit 160, as will be discussed later, in which the soil is coagulated, the thickener 143 conveys the soil to the filtering unit 150 in a state of being substantially suppressed in elution of contaminants thereof.
The filtering unit 150 is adapted to convey the washed soil in the remediating unit 140 located on a belt filter thereof and to separate and discharge the process water for washing from the soil. At this time, the soil separated from the filtering unit 150 is stacked to refill the area from which the contaminated soil is collected or is thrown on a separate place. Also, the process water for washing separated from the soil is collected and supplied to the coagulating and settling unit 160.
The coagulating and settling unit 160 has a settling tank in which the soil having the particle sizes of less than 0.020 mm separated in the third micro hydrocyclone 133 and the process water for washing separated from the filtering unit 150 are agitated and settled. At this time, the process water for washing may contain very fine soil passed through the belt filter of the filtering unit 150. Therefore, the settling tank has a separate coagulating agent added thereto to allow the soil having the particle sizes of less than 0.020 mm separated in the third micro hydrocyclone 133 and the fine soil contained in the process water for washing to be coagulated to obtain relatively large particle sizes. The coagulated and settled soil is supplied to the thickener 143, and the process water for washing remaining after the supply of the soil is supplied to the process water for washing-recycling unit 170.
The process water for washing-recycling unit 170 serves to collect and purify the process water for washing from the coagulating and settling unit 160 and to move the purified water to a storage tank in which the process water for washing is stored. At this time, the storage tank has Fe3+-modified activated carbon supplied thereinto so as to absorb the contaminants inclusive of arsenic contained in the process water for washing thereonto. Also, the process water for washing-recycling unit 170 is disposed to supply the purified process water for washing to the mill 110 again. Of course, the purified process water for washing is stored in the storage tank and is then introduced again to the mill 110.
On the other hand, the dotted arrows in
As shown in
Next, the broken soil is separated into the soil having predetermined particle sizes through the screen 120 (at step S20). At this time, the screen 120 includes the wet vibration screen, and the soil is separated into gravel having particle sizes of more than 2.0 mm, sand having particle sizes between 0.075 mm and 2.0 mm, and silt having particle sizes of less than 0.075 mm. In this case, the gravel and sand can be separated together with each other, and at this time, the particle sizes of more than and less than 0.075 mm are set.
After that, the soil mainly containing the silt having particle sizes of less than 0.075 mm separated by the screen 120 is finely separated through the separator 130 (at step S30). At this time, the separator 130 includes one or more micro hydrocyclones in accordance with the particle size units of the fine separation of the soil. According to the present invention, the fine separation of the soil is conducted through the first to third micro hydrocyclones 131 to 133 connected serially to each other. Through the first micro hydrocyclone 131, the soil having the particle sizes of 0.075 mm is separated, and thus, the soil having the particle sizes of more than 0.075 mm is conveyed to the screen 120, while the soil having the particle sizes of less than 0.075 mm is being conveyed to the second micro hydrocyclone 132. Through the second micro hydrocyclone 132, the soil having the particle sizes of 0.040 mm is separated, and thus, the soil having the particle sizes between 0.040 mm and 0.075 mm is conveyed to the remediating unit 140, while the soil having the particle sizes of less than 0.040 mm is being conveyed to the third micro hydrocyclone 133. Through the third micro hydrocyclone 133, the soil having the particle sizes of 0.020 mm is separated, and thus, the soil having the particle sizes between 0.020 mm and 0.040 mm is conveyed to the remediating unit 140, while the soil having the particle sizes of less than 0.020 mm is being conveyed to the coagulating and settling unit 160.
Next, if the soil finely separated through the separator 130 is introduced by particle size to the remediating unit 140, the soil is washed with the process water for washing and is thus primarily remediated (at step S40). At this time, since the contamination degrees of the soil by particle size are different from each other, the introducing amounts and concentrations of the process water for washing are varied. In this case, the soil having the particle sizes between 0.040 mm and 0.075 mm is introduced to the first mixing tank 141 and is washed thereinto, and the soil having the particle sizes between 0.020 mm and 0.040 mm is introduced to the second mixing tank 142 and is washed thereinto. Further, the soil having the particle sizes of less than 0.020 mm is circulated to a filtering step (at step S50) via a coagulating and settling step (at step S60) and a second remediating step (at step S70) as will be discussed later.
After that, if the soil washed in the mixing tanks of the remediating step (at the step S40) is introduced to the filtering unit 150 together with the process water for washing, the soil and the process water for washing are separately discharged through the filtering unit 150 (at the step S50). In this case, the soil is conveyed together with the process water for washing and is dewatered by vacuum absorption. At this time, the process water for washing is collected and conveyed to the coagulating and settling unit 160, and the soil is separately stacked and refilled on the area from which the soil is collected or thrown on a given area.
Next, the process water for washing introduced from the filtering unit 150 at the filtering step (at the step S50) and the soil having the particle sizes of less than 0.020 mm separated in the third micro hydrocyclone 133 are agitated and coagulatingly settled (at the step S60). The process water for washing and the soil having the particle sizes of less than 0.02 mm are mixed in the coagulating and settling tank, and at this time, a separate coagulating agent is added to the process water for washing and the soil having the particle sizes of less than 0.02 mm. Through the coagulating agent, the soil having the particle sizes of less than 0.02 mm is coagulated to have a large particle size. Of course, if the agitation is performed by means of an agitator (not shown), the working time can be reduced. In this case, the process water for washing may contain very fine soil passed through the belt filter of the filtering unit 150, and the soil is coagulated with the soil having the particle sizes of less than 0.020 mm by means of the addition of the coagulating agent.
After that, the coagulated and settled soil through the coagulating and settling step (at the step S60) is supplied to the thickener 143 and is then washed by means of the process water for washing so as to perform the second remediating step (at the step S70). At this time, the soil having the particle sizes of less than 0.020 mm is coagulated. This is to allow the soil having the particle sizes of less than 0.020 mm to be increased in particle size through the coagulating and settling step (at the step S60) so as to optimize the separation efficiency of the soil and the process water for washing in the filtering step (at the step S50). Also, the soil discharged from the thickener 143 is conveyed to the filtering step (at the step S50) in a state of being substantially suppressed in elution of contaminants thereof.
Next, the process water for washing except the soil is collected from the coagulating and settling unit 160 and is purified and conveyed through the process water for washing-recycling unit 170 (at step S80). In this case, the purification is conducted by absorbing the contaminants inclusive of arsenic contained in the process water for washing by means of Fe3+. At this time, Fe3+-modified activated carbon is supplied for the purification. Also, the purified process water for washing is conveyed to the milling step (at the step S10) and is thus supplied to individualize the soil through the mill 110.
While the present invention has been described with reference to the particular illustrative embodiments, it is not to be restricted by the embodiments but only by the appended claims. It is to be appreciated that those skilled in the art can change or modify the embodiments without departing from the scope and spirit of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2011-0116870 | Nov 2011 | KR | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/KR2012/002245 | 3/28/2012 | WO | 00 | 6/17/2014 |
