1. Field of the Invention
The present application relates to the production of a hydrogen fuel product, and more particularly, to a system and method for producing a hydrogen fuel product from water, which fuel product may be recycled into the system.
2. Description of the Related Art
A hydrogen economy has been proposed for the distribution of energy using hydrogen. Hydrogen (H2) releases energy when it is combined with oxygen; however in the past, production of hydrogen from water requires more energy than is released when the hydrogen is used as fuel. As such, past methods of producing hydrogen have been prohibitively expensive as compared to other fuels for the same amount of energy return.
What is needed is a system for producing hydrogen that is relatively inexpensive. What is further needed is a method for producing energy (i.e., electricity, mechanical motion, etc.,) wherein hydrogen is provided as a waste product.
A system and method for generating a hydrogen fuel product is provided. Water, in the form of steam, is super-heated and exposed to a catalyst to produce a hydrogen gas, which is stored and/or recycled as fuel back into the system.
In one particular embodiment of the invention, hydrogen produced in the system is used to produce a fuel mixture that, when ignited, heats water to make steam that can drive a turbine and/or be used with a catalyst to create further hydrogen gas fuel product.
Other features which are considered as characteristic for the invention are set forth in the appended claims.
Although the invention is illustrated and described herein as embodied in a system and method for the generation of a hydrogen fuel product, it is nevertheless not intended to be limited to the details shown, since various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims.
The construction of the invention, however, together with additional objects and advantages thereof will be best understood from the following description of the specific embodiment when read in connection with the accompanying drawings.
For a fuller understanding of the nature of the present invention, reference should be made to the following detailed description, taken in connection with the accompanying drawings in which:
Like reference numerals refer to like parts throughout the several views of the drawings.
The system of the instant invention converts water (H2O) vapor to a hydrogen fuel gas using a catalyst subjected to high temperatures. This hydrogen fuel gas can be stored and used, for example, in connection with an internal combustion engine. As will be described, in one particular embodiment of the invention, hydrogen fuel gas produced from water vapor is used as a combustion product in an internal combustion engine.
Referring now to
Internal combustion engines that generate power from the combustion of hydrogen are known. As with a traditional motor vehicle internal combustion engine, the engine 130 is cooled by a liquid which, in the present case, is water from a tank 110. Additionally, as with conventional motor vehicles, the operation of the internal combustion engine 130 powers an alternator 132 that provides at its output a DC current that can be used to power an electric motor and/or provide electrical power to other systems.
As further shown in
In the instant embodiment, the water from the tank 110 is supplied to an inlet port IN of the internal combustion engine 130, via a pump 112, wherein it is used to cool the internal combustion engine 130 by being recirculated within the engine 130. The temperature of the water in the engine 130 is rapidly increased by its passage through the cylinders and heads of the engine 130, and the water is converted to a steam (i.e., water vapor). This steam leaves the engine 130 via an outlet port OUT and a pressure control valve 117, which provides the steam, via pipe 131 or exhaust manifold 134, to an outlet manifold or catalytic converter section 130a of the engine 130.
In one particular embodiment of the present invention, a catalyst or catalyzing agent 140 is provided in the catalytic converter section 130a of the engine 130. At high temperatures, the catalyzing agent 140 reacts with steam to produce hydrogen gas (H2). In the embodiment of
In one particular embodiment of the invention, the active catalyst of the catalyzing agent 140 is iron (Fe). The method of generating hydrogen by passing steam over hot iron (Fe), also known as reforming steam, was previously performed inefficiently. However, in the present embodiment of the invention, this method becomes extremely efficient, with copious amounts of H2 being created. Steam exposed to the heated catalyzing agent 140 contained in the catalytic converter section 130a of the internal combustion engine 130 produces hydrogen (H2). When generating hydrogen, the catalyzing agent 140 can be chosen to be the element Fe, preferably in the form of iron sponge. The reaction, when heated, is described by H2O+Fe=>Fe3O4+H2. Additionally, magnesium and/or zinc can be used in place of, or in addition to, iron as the catalyzing agent 140, with the end product still being H2. This is not meant to be limiting, however, as other materials that react with steam to oxidize, thus producing H2 gas, can also be used.
Referring back to
When the catalyzing agent 140 is heated by the waste heat from the hydrogen fuel combustion, the steam in the catalytic converter section 130a exposed to the catalyzing agent 140 will react with the active catalyst of the catalyzing agent 140 to produce hydrogen (H2). The hydrogen thus produced can be routed to the tank 160, located at the output of the catalytic converter 140, for storage and/or use.
If desired, at least a portion of the hydrogen gas that is produced could be diverted from the storage tank 160 for use outside of the system 100. The remainder of the hydrogen produced from the steam exposed to the superheated catalyzing agent 140 is used as fuel in the system 100. Additionally, the instant invention generates electricity, while creating hydrogen gas as a waste product of the energy creation.
In operation, the hydrogen gas produced by the reaction with the catalyzing agent 140 is provided, along with an oxygen (O2) gas, to a fuel mixer 170 in preparation for being introduced into the combustion chamber of the internal combustion engine 130. The oxygen can be provided by a source of compressed oxygen, or otherwise, by an air separator 180, as shown. In the instant embodiment, the air separator 180 has an inlet for receiving air, preferably from an air compressor (not shown in
Using PSA, a bed of crystal zeolite is utilized to trap the nitrogen portion of the air, yet allow the oxygen to pass through. Thus, the air separator 180 produces a stream of oxygen (O2) and a stream of nitrogen (N2). The oxygen stream is provided to a fuel mixing device or mixer 170. The nitrogen is routed out from the air separator 180, to a valve 182, from which it can be provided by an outlet to a tank (not shown) for storage and/or use.
The resultant oxygen produced through PSA can have from a 90% to 95% purity. Note that, although the embodiment of
The fuel mixer 170 mixes the received oxygen with a fuel component H2 and provides the fuel mixture to the combustion chamber of the engine 130, where it is ignited. In one particular preferred embodiment of the invention, control valves 172, 174 are used to maintain a stoichiometric air fuel ratio of approximately 2:1 in the combustion chamber of the engine 130. More particularly, 2H2+O2=H2O+energy. The combustion of the fuel mixture occurring in the internal combustion engine 130 produces water vapor and heat as a waste byproduct at the output 130a of the engine 130. This heat waste byproduct, which is wasted and purposely dissipated in a conventional internal combustion engine, is used in this process, thus rendering the operation of the engine of the invention substantially more efficient as compared to the 30% efficiency of a conventionally operated internal combustion engine. Stated differently, by way of explanation, the heat being rejected is, for all practical purposes, impossible to recover. However, it should be understood that by practicing the method of the present invention, significant amounts of latent heat as super-heated vapor can be recovered and converted to useful fuel product, thereby increasing the efficiency of the internal combustion engine, as well as, the furnace boiler system.
As shown in
If desired, a portion of the steam produced at the outlet of 130 can also be diverted to a steam turbine (not shown) which, in turn, generates electricity that can be used and/or stored, as desired. The steam from the turbine can additionally be brought back to the catalyzing agent 140 and converted to hydrogen.
Note that the H2 component must, at least initially, be provided from a storage tank or other source of hydrogen fuel gas, in order to start the engine 130. However, once started, the system 100 will use water from the tank 110 and from the exhaust of the engine 130 to produce hydrogen to be fed back to the fuel mixer 170, via the tank 160, for use as the fuel component to the mixer 170. Additional hydrogen fuel gas produced from the operation of the system 100 of the invention can be routed outside of the system by a valve (not shown), for later use.
In the system 100, although water vapor/steam is produced as a byproduct of the combustion of the fuel gas product, this water vapor/steam may not be enough to fuel the vehicle for sustained operation. As such, water used to cool the engine 130 is also consumed during operation of the vehicle, which water is replaced by water from the tank 110. Thus, during operation, the amount of water held in the tank 110 will be depleted. As with a conventional vehicle, a gauge 190 can be provided in the vehicle to inform the operator of the water level in the tank 110, and alert the operator to when the water in the tank should be replenished.
In this way, a fuel component H2 produced by the system 100 from water vapor in the system 100 is made into a component of a fuel mixture that is combusted in the internal combustion engine 130 as part of the engine combustion process to operate the engine 130. The operation of the engine 130 can be used to drive an electrical generator 132 that, in the preferred embodiment, produces a conventional three-phase AC output. The electrical output from the generator 132 can be stored, for example, in a battery and/or battery pack 137, and/or can be used to provide electrical power to electrical processes in the system 100. In one particular example, the generator 132 can be used to provide power to an alternative catalyst heater apparatus. Additionally, when the internal combustion engine 130 is incorporated into a motor vehicle, it should also be understood that the combustion process is, naturally, used to drive the motor vehicle, in the same manner as traditional internal combustion engines in known motor vehicles, including hybrid and pure electric vehicles.
As can be seen from the foregoing, the system 100 of
Referring now to
More particularly, as shown in
It should be understood that the state of the flow diverter 210 is tied to the state of the flow diverter 220, to ensure that when ambient air is used to provide the oxygen component to the fuel mixture, the nitrogen containing waste product is exhausted out to the ambient air via the exhaust pipe 230. Similarly, when the flow diverter 210 provides separated O2 to the fuel mixer, the states of the flow diverters 210, 220 are coordinated to provide the H2 gas created in the catalytic converter section 130a to the storage tank 160. Thus, in the bypass mode of operation, the system 200 can operate the internal combustion engine 130 (and generate electricity via the alternator 132) on a fuel mixture generated from previously stored hydrogen from tank 160 and ambient air provided from an inlet port AIR IN.
In one particular embodiment of the system 200 of
Thus, it can be seen from the foregoing that the system 200 of
In one particular alternate embodiment of the invention, the air separator 180 and diverter 210 are omitted entirely, and a flow diverter 220 is permanently set to vent the exhaust gases from the exhaust pipes 134 to air, while simultaneously diverting steam from the control valve 117 to the catalytic converter section 130a. Such an alternate system uses only ambient air as the oxygen source in the fuel mixture, while still producing H2 for storage in the tank 160 and subsequent use in the fuel mixture. Other modifications can be made to the presently described invention while still keeping within the spirit of the present invention. For example, if desired, the flow diverter 220 can be moved after the catalytic converter section 130a.
It is envisioned that other embodiments of a catalytic converter section having a bypass mode wherein nitrogen containing engine exhaust can be vented to atmosphere can be provided without deviating from the spirit of the instant invention. For example, in one particular embodiment of the invention, a catalytic converter section 400 of
As with the embodiment described in connection with
However, when oxygen gas (O2) from the air separator 180 of
Thus, it can be seen that the catalytic converter section 400 can be used in place of the catalytic converter section 130a of
Referring, more particularly, to
The separated oxygen (O2) stream, having from a 90% to a 95% purity, can be stored in a vessel, which is maintained under pressure. The separated oxygen is then provided to a fuel combustion chamber 315, along with hydrogen fuel gas (H2) provided from a storage tank 320, via the control valves 312 and 322. The oxygen mixes with the hydrogen in the combustion chamber 315 to form a fuel gas mixture that is ignited using the ignition element 319.
A nozzle 320 directs resultant exhaust gases produced in the combustion chamber 315 into and through an exhaust duct 325. As shown more particularly in
Referring back to
Additionally, the waste water or steam from the turbine can be returned to the exhaust duct 325 in the boiler section 330 and carried into the catalytic converter section 340, where it is further heated by the waste heat of the combustion reaction of the fuel mixture. The steam produced from water/steam exiting the turbine 360 is combined with the steam waste product of the reaction and is passed over the catalyst 340a of the catalytic converter section 340 of the exhaust duct 325. The catalyst 340a, which is also superheated by the waste heat of the combustion reaction, reacts with the steam to produce hydrogen gas. Hydrogen gas produced in the catalytic converter section 340 can be stored in the tank 320, wherein some percentage of the hydrogen thus produced is fed back into the system via the line 370, to fuel the combustor, while the majority can be tapped off for use as fuel.
Thus, the system of
The present disclosure is provided to allow practice of the invention, after the expiration of any patent granted hereon, by those skilled in the art without undue experimentation, and includes the best mode presently contemplated and the presently preferred embodiment. Nothing in this disclosure is to be taken to limit the scope of the invention, which is susceptible to numerous alterations, equivalents and substitutions without departing from the scope and spirit of the invention.
The present application claims priority to co-pending Provisional Patent Application No. 61/324,603, filed on Apr. 15, 2010, entitled SYSTEM AND METHOD FOR THE GENERATION OF HYDROGEN FUEL PRODUCT, that application being incorporated herein, by reference, in their entirety.
Number | Date | Country | |
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61324603 | Apr 2010 | US |