The present invention relates to a system and a method for treating gas arising from the evaporation of a cryogenic liquid.
The field of the present invention is more particularly the maritime transport of cryogenic liquids and still more particularly of Liquefied Natural Gas (LNG). However, the systems and the methods which will be proposed below could also find applications in on-shore installations.
At ambient temperature, liquefied natural gas exhibits a temperature of the order of −163° C. (or less). During the maritime transport of LNG, the latter is placed in tanks on a ship. Although these tanks are thermally insulated, thermal leakages exist and the exterior medium adds heat to the liquid contained in the tanks. The liquid therefore heats up and evaporates. Given the size of the tanks on a methane carrier, as a function of the thermal insulation conditions and the exterior conditions, several tonnes of gas may evaporate per hour.
It is not possible to keep the evaporated gas in the tanks of the ship for safety reasons. The pressure in the tanks would increase dangerously. It is therefore necessary to allow the gas which evaporates to escape out of the tanks. Regulations prohibit discharging this gas (if it is natural gas) into the atmosphere as is. It must be burnt.
To avoid losing this gas which evaporates, it is also known, on the one hand, to use it as fuel for the engines on board the ship transporting it and, on the other hand, to reliquefy it in order to place it back into the tanks from which it originates.
The subject of the present invention relates to the supply of the engines on board the ship on the basis of the gas which evaporates. When the consumption of the engines is more significant than the “natural” evaporation of the gas of the tanks, it is known to bleed off some gas so as to vaporize it and thereafter supply the engines. The present invention relates, however, more particularly to the reliquefaction of gas which has evaporated in cryogenic liquid tanks or containers, and more particularly in tanks or containers of methane carriers, when the evaporation of the gas is more significant than the consumption of the ship's engines.
Document EP 2 933 183 relates to a liquefied gas treatment system intended for a ship which comprises a storage container which stores a liquefied natural gas, and an engine which uses the liquefied natural gas stored in the storage container as fuel. The liquefied gas treatment system presented in this document comprises: a storage container which stores a liquefied gas, an engine which uses the liquefied gas stored in the storage container as fuel and a fuel supply pipe which can vaporize the liquefied gas and provide the gas generated to the engine as fuel. The engine receives a supply of combustible gas which is pressurized to a low pressure.
In all the embodiments proposed in this document, the gas intended to be reliquefied is cooled before its reliquefaction by the gas stream which exits the tanks before it is compressed and conducted to the engine(s). An exchanger which bears the reference 21 is then found each time in
This heat exchanger 21 creates significant head losses in the gas stream which evaporates from the tanks. Under certain operating conditions, the evaporated gas may therefore arrive at the compressor at a lower pressure than atmospheric pressure. There is then a risk of air being sucked in and mixed with the gas.
Another drawback of the system presented in this prior art document is that it does not make it possible to balance the production and the consumption of cold. The quantity of gas consumed by the engine(s) is in large measure independent of the quantity of gas which evaporates. Thus the exchange in the exchanger 21 cannot be modulated as a function in particular of the requirements, in terms of cold, in respect of the reliquefaction.
To reliquefy the gas which has evaporated, it is known to cool this gas so as to again bring it back to temperature and pressure conditions allowing it to revert to the liquid phase. This adding of cold is usually carried out by heat exchange with a refrigerant circuit comprising for example a refrigerating fluid, such as nitrogen, loop.
Thus, document EP 1 120 615 describes an apparatus to be used on ships to recompress a pressurized vapor. The recompression is performed in closed cycle in which a work fluid is compressed in at least one compressor, is cooled in a first heat exchanger, is expanded in a turbine and is reheated in a second heat exchanger, in which the compressed vapor is at least partially condensed. The apparatus comprises a first sub-assembly comprising the second heat exchanger and a second sub-assembly including the first heat exchanger, the compressor and the expansion turbine. The two sub-assemblies are placed respectively on two platforms.
In document WO 2014/095877, the natural gas evaporating from liquefied natural gas storage tanks, typically situated on board a seagoing ship, is compressed in a compressor having several stages comprising compression stages. At least one part of the compressed natural gas stream is sent to a liquefier, typically operating according to a Brayton cycle, so as to be reliquefied. The temperature of the compressed natural gas originating from the final stage is reduced to a value of less than 0° C. by passing through a heat exchanger. The first compression stage operates as a compressor operating at low temperature, and the resulting cold compressed natural gas is employed in the heat exchanger to perform the necessary cooling of the stream originating from the compression stage. Downstream of its passage through the heat exchanger, the cold compressed natural gas flows through the remaining stages of the compressor. If so desired, part of the compressed natural gas can serve as fuel and supply the engines of the seagoing ship.
The presence of a refrigerating loop with nitrogen, or else any other refrigerant gas distinct from the fluid to be refrigerated, involves providing specific equipment for the refrigerating fluid. Thus for example when a nitrogen refrigerant circuit is provided on board a ship (or elsewhere), a nitrogen treatment (purification) unit is required in order to allow its use in the cryogenic sector. It is also necessary to provide a specific tank, valves and other devices for regulating the flow of the nitrogen.
The aim of the present invention is then to provide an optimized system making it possible on board a ship transporting liquefied natural gas to supply gas to an engine on the basis of natural gas evaporating from the storage tanks of the ship and to reliquefy the gas which has evaporated and which has not been consumed in the engine. This system will not exhibit any refrigerating liquid of a nature other than that of the gas used for the supply of the engine and will limit the head losses upstream of the compressor used to supply the engine. Advantageously, the production of cold will be able to be adapted to the quantity of gas to be reliquefied.
For this purpose, the present invention proposes a system for supply based on a gas arising from the evaporation of a cryogenic liquid and for reliquefaction of this gas, said system comprising a supply line for at least one engine on which line is situated a first compression unit for said gas and a bypass to a return line on which are successively situated cooling means and first expansion means.
According to the present invention, the cooling means successively comprise a second compression unit and a heat exchanger as well as downstream of the second compression unit a bypass to a loop comprising second expansion means, and the loop rejoining the return line upstream of the second compression unit after having passed through the heat exchanger in the opposite direction with respect to the gas fraction not bypassed via the loop.
Thus, there is proposed a mechanical cooling loop which makes it possible to avoid making use of the gas which evaporates from the tanks as a source of cold to cool a part of the gas before its liquefaction. In this way, the evaporated gas from the tanks can be sent directly into the first compression unit without undergoing head losses (or by limiting to the maximum these head losses). The operation of this cooling loop is moreover independent of the other systems nearby and can thus operate almost as a closed loop of another refrigerating fluid. The expansion means make it possible to switch the fluid rapidly from a high pressure to a lesser pressure and each time this may entail an expansion turbine, or an expansion valve, or an orifice or any other equivalent system.
In this supply and reliquefaction system, a recycling line is advantageously provided, making it possible to send a non-reliquefied fraction of the gas exiting the first expansion means to the supply line for the engine upstream of the first compression unit. Advantageously, the recycling line passes through the heat exchanger.
In the cooling unit, the bypass is preferably performed within the heat exchanger in such a way that the bypass gas stream is already cooled partially so as to subsequently enter the second expansion means.
In one embodiment of such a supply and reliquefaction system, the first expansion means comprise for example an expansion valve emerging in a balloon intended to separate the liquid formed and the unliquefied gas fraction. The balloon makes it possible to carry out the separation of the gas and of the liquid and makes it possible to treat the gas and the liquid downstream differently. In such an embodiment, it is proposed that the upper part of the balloon be linked to the heat exchanger in such a way that the gas originating from the balloon enters the exchanger on the same side as the bypass, and that the lower part of the balloon be linked to a cryogenic liquid tank.
A particularly advantageous variant embodiment of the treatment system provides that the second compression unit comprises several compression stages each with a compression wheel, that the second expansion means comprise an expansion turbine, and that each compression wheel and the expansion turbine are associated with one and the same mechanical transmission. This embodiment makes it possible to have a compact structure. Furthermore, the work recovered at the level of the expansion turbine can immediately be transmitted to the compression wheels thus promoting good energy efficiency for the system.
To facilitate the starting of the cooling unit, this system can comprise furthermore means for injecting gas into the bypass loop of the cooling unit. In this way, the cooling unit actually becomes autonomous and can be regulated as if it were a closed loop. The means for injecting gas into the bypass loop comprise for example a pump for cryogenic liquid, a vaporizer and a control valve.
The present invention also relates to:
Finally, the invention proposes a method for managing a gas stream arising from the evaporation of a cryogenic liquid, in which:
said gas stream being compressed within a first compression unit before being sent either to an engine, or to reliquefaction means,
the gas fraction sent to the reliquefaction means passes through cooling means and then expansion means and finally through a separator from which the liquid part is sent to a cryogenic liquid tank.
According to the present invention, the cooling means are means of mechanical refrigeration within which:
a gas stream is compressed in a second compression unit, and then cooled within a heat exchanger before being expanded in such a way that a gas fraction reliquefies,
after its compression, the gas stream is separated into a first gas stream part and a second gas stream part,
the first part of the gas stream is cooled and then sent to the reliquefaction means so as to be at least partially liquefied, and
the second part of the stream of the gas is fed into a loop in which said second gas stream part is expanded, and then is used to cool the first part of the gas stream before rejoining the gas stream so as to be compressed again in the second compression unit.
In such a method for managing a gas stream arising from the evaporation of a cryogenic liquid, provision is advantageously made for the gas arising from the evaporation to be compressed without prior heat exchange with another gas pipe. This makes it possible to limit the head losses before the gas enters the first compression unit.
The unliquefied gas exiting the first expansion means can be conducted by a recycling line upstream of the first compression unit. In this case, for better energy efficiency, the unliquefied gas exiting the first expansion means preferably passes through the heat exchanger before being compressed again in the first compression unit.
Details and advantages of the present invention will became more clearly apparent from the description which follows, given with reference to the appended schematic drawing in which:
In each of the appended figures, a tank 1 is illustrated. Throughout the subsequent description, it will be assumed that this is a Liquefied Natural Gas (or LNG) tank from among several other similar tanks on board a seagoing ship of methane carrier type.
The numerical values in the description which follows are given by way of purely illustrative and wholly non-limiting numerical examples. They are adapted to the treatment of LNG on board a ship but can vary, in particular if the nature of the gas changes.
The tank 1 stores the LNG at a temperature of the order of −163° C. which corresponds to the customary storage temperature of LNG at a pressure close to atmospheric pressure. This temperature depends of course on the composition of the natural gas and the storage conditions. The atmosphere around the tank 1 being at a much higher temperature than that of the LNG, although the tank 1 is very well insulated thermally, heat is added to the liquid which warms up and vaporizes. The volume of the evaporating gas being much more significant than that of the corresponding liquid, the pressure in the tank 1 therefore tends to increase as time passes and as heat is added to the liquid.
To avoid reaching overly significant pressures, the gas which evaporates is withdrawn as and when from the tank 1 (and from the other tanks of the ship) and is collected from several tanks toward a main pipe 2.
In the systems illustrated in the drawing, provision is made to use the gas which has evaporated to supply at least one engine (not represented) on board the ship and to reliquefy the surplus gas. The aim here is to avoid losing the evaporated gas and therefore either to use it for the propulsion of the ship, or to recover it and return it, in the liquid phase, to the tank 1.
To be used in an engine of the ship, the gas must firstly be compressed. This compression is then carried out within a first compression unit 3 which can be, as illustrated in the drawing, multi-staged. This unit, by way of illustrative and wholly non-limiting numerical example, takes the pressure of the gas collected in the main pipe 2 from a pressure substantially equal to atmospheric pressure to a pressure of the order of 15 to 20 bar (1 bar=105 Pa).
After this first compression step, the gas passes into an intermediate cooler 4 in which it is cooled without appreciably modifying its pressure. The gas which has been reheated during its compression is at a temperature of the order of 40 to 45° C. on exiting the intermediate cooler (these values are given purely by way of illustration).
The gas thus compressed and cooled can then be sent through an injection pipe 5 to an engine on board the ship. This may be an engine for the propulsion of the ship or for other uses (auxiliary generator, etc.). The main pipe 2 and the injection pipe 5 form a line for supplying the engine with gas evaporated from the tanks 1.
The gas requirements at the level of the engine(s) of the ship are often lower than the “production” of gas by evaporation in all the tanks which are on board the ship. The gas not used in the engine(s) is then sent to a reliquefaction unit comprising in particular a mechanical cooling unit 10.
The cooling unit 10 comprises at its inlet a valve 6 intended in particular to control the pressure of the gas in the injection pipe 5, and then a main circuit and a loop, both of which will be described hereinafter.
The main circuit makes it possible on the basis of the gas (which is at a pressure of the order of a few bar to about 50 bar-non-limiting values-) to obtain gas at a temperature such that it passes into the liquid phase before returning to the tank 1.
The main circuit of the cooling unit 10 comprises firstly a multi-staged compressor, here comprising three successive stages with the references 11, 12 and 13. Each stage is formed by a compression wheel and the three compression wheels are driven by one and the same transmission 15 with shafts and gears. The line between the compression stages in the figures symbolizes the mechanical link between them.
After this second compression (the gas bypassing the supply line having already been compressed in the first compression unit 3), the gas passes into an intermediate cooler 16. Its pressure is then a few tens of bars, for example about 50 bar, and its temperature is again of the order of 40 to 45° C.
The gas thus compressed is then cooled within a multi-stream exchanger 17. The gas flows in this exchanger 17 in a first direction. The fluids flowing in the opposite direction (with respect to this first direction) and used to cool it will be described later.
On exiting the exchanger 17, the compressed gas cooled to a temperature of the order of −110 to −120° C. becomes liquid and is sent, still at a pressure of the order of a few tens of bars (for example about 50 bar) through an insulated pipe 22 to expansion means. In the illustrated embodiment corresponding to a preferred embodiment, an expansion valve 30 is used to further cool the reliquefied gas and to lower its pressure.
After expansion through the expansion valve 30, a methane-rich liquid and a nitrogen-rich gas (since natural gas is not composed solely of methane) are obtained at the same time. The separation of this liquid phase and of this gaseous phase is carried out within a balloon 40 in which the pressure is of the order of a few bar, for example between 3 and 5 bar.
The gas of the balloon 40 is preferably returned to the main pipe 2. In this way, it is mixed with the primary stream and will thus be partially used as fuel in the engine(s), or will pass back into the cooling unit 10. The gas originating from the balloon 40 being cold, it can be used to cool the compressed gas in the exchanger 17. Provision is therefore made to make it flow in the opposite direction in this exchanger 17 before making it return to the main pipe 2 through a linking pipe 35.
If, for diverse reasons, in particular during transient phases, the gas of the balloon 40 cannot be recycled to the main pipe 2, provision is made to send it to a flare stack or a combustion unit. A set of valves 31, 32 controls the sending of the gas from the balloon 40 to the main pipe 2 through the linking pipe 35 or to a combustion unit.
The liquid recovered at the bottom of the balloon 40 is for its part intended to return to the tank 1. Depending on the operating conditions, the liquid may be sent directly to the tank 1 (passage controlled by a valve 33), or with the aid of a pump 41 (passage controlled by a valve 34).
The return of the liquid originating from the balloon 40, directly or via the pump 41, to the tank 1 is done by way of an insulated pipe 36.
In the cooling unit 10, as mentioned above, is also situated a loop. This loop begins with a bypass pipe 18 which separates the gas stream downstream of the multi-staged compressor 11, 12, 13 into a first stream, or main stream, which corresponds to the main circuit described previously, and into a second stream, or bypass stream.
The bypass pipe 18 is preferably linked to the main circuit at the level of the exchanger 17. The gas which therefore enters the bypass pipe 18 is at “high pressure” (about 50 bar in the numerical example given) and at an intermediate temperature of between 40° C. and −110° C.
The gas bled off by the bypass pipe 18 is expanded within expansion means formed in the preferred embodiment retained in the drawing by an expansion turbine 14. The latter is, in the preferred embodiment illustrated in the drawing, mechanically linked to the three compression wheels corresponding to the stages 11, 12 and 13 of the multi-staged compressor of the cooling unit 10. The transmission 15 by shafts and gears links the expansion turbine 14 and the compression wheels of the multi-staged compressor. This transmission 15 is symbolized by a line linking in the figures the expansion turbine 14 to the stages 11, 12 and 13.
The gas is expanded for example to a pressure level which corresponds to its pressure level on entering the cooling unit 10, i.e. about 15 to 20 bar. Its temperature drops below −120° C. This gas stream is then sent into the exchanger 17 in the opposite direction so as to cool the gas of the main circuit, firstly the portion 19 situated downstream of the bypass pipe 18 and then the portion upstream of this bypass pipe 18. On exiting the exchanger 17, the gas regains temperatures of the order of 40° C. and can be reinjected into the main circuit of the cooling unit, upstream of the multi-staged compressor through a return pipe 21.
An open cooling loop is thus made, which uses as gas for the cooling the same gas as that which must be liquefied.
In the variant embodiment of
This variant embodiment of
In
By virtue of this configuration, it is possible to obtain a greater ratio of pressures at the level of the expansion turbine 14 than that of the multi-staged compressor of the cooling unit 10.
Finally,
Provision may also be made, were it necessary, to bleed off the Liquefied Natural Gas (presence of an arrow) on the infeed pipe 61.
The system proposed here thus provides an open loop of refrigerant gas corresponding to the refrigerated gas with production of cold at two different temperatures, a temperature of about −120° C. on exiting the expansion turbine and a temperature of about −160° C. on exiting the expansion valve. The system is independent of the engines situated on board the ship which are supplied by the evaporated gas. It allows liquefaction to be carried out solely on the basis of the evaporated gas, independently of any other exterior source of cold.
In the loop, the production of cold is permanently adapted to the load at the level of the reliquefaction means and can be regulated over a wide span by acting on the second compression unit. It is thus possible to adapt the production of cold required for the reliquefaction and to carry out the energy balancing of the system.
Under steady state conditions, no gas discharge, or gas combustion, is to be envisaged.
During its starting, the chilling within the cooling loop can be managed as with a closed loop. The cooling unit does not have any influence on the first compression unit which is also used to supply the engines (or other generators). When the loop is cold, it can remain “idle” and be used in open loop as soon as an excess of evaporated gas has to be liquefied.
The proposed system makes it possible to limit the head losses of the gas evaporating from the tank(s). This gas is collected and sent directly to the inlet of the first compression unit. The head loss is that which is unavoidable, created by the infeed of the gas through the main pipe. It is limited and makes it possible to avoid having in all the operating conditions of the system an inlet of the first compression unit which is depressurized.
It is clear furthermore that the proposed system does not require any nitrogen treatment unit or similar. Its structure is simplified through the use of a refrigerating gas of the same nature as the gas to be refrigerated and liquefied.
Of course, the present invention is not limited to the embodiments of the systems and methods described hereinabove by way of non-limiting examples but it also relates to all the variant embodiments within the capabilities of the person skilled in the art within the framework of the claims hereinafter.
Number | Date | Country | Kind |
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1558168 | Sep 2015 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FR16/52178 | 9/2/2016 | WO | 00 |