The present disclosure relates to range finding, and more particularly, to radio frequency-based range finding.
Accurate localization with unique identification of indoor objects and objects behind visual obstructions can be critical in a variety of applications. However, current approaches suffer from numerous fundamental problems. Optical methods typically achieve high in-plane resolution but offer limited ranging accuracy. Item recognition also has a high computing load unless identification markers are used. Furthermore, objects of interest may be covered by materials such as fabrics, plastics, and building materials, which are often opaque to light. Camera-based systems have been extensively developed, and benefit from convenient use, rich information and sophisticated imaging algorithms. However, fine gesture recognition, vital-sign acquisition, three-dimensional (3D) localization of covered features or markers, and the control of haptic robotics remain challenging. Typically, multiple cameras from different viewing angles and high computational demands are required, which greatly increases system complexity and cost. In addition, camera systems are vulnerable to low ambient light and line-of-sight (LoS) obstruction. Other optical solutions, such as time-of-flight (ToF) cameras, structured-light range scanning and light detection and ranging (LIDAR), share similar problems in terms of unique identification and LoS blocking. Ultrasound ranging and imaging is an alternative approach, but has issues in terms of impedance matching when going through different layers of materials, especially for air gaps. Another approach is to use location sensors based on microelectromechanical systems (MEMS), such as the servo motor and encoder. However, the size and mechanical structure of such systems cannot effectively fit onto the human body, delicate robotic structures, or soft materials. MEMS accelerometers and gyroscopes also suffer from slow drift and their power requirement limits deployment options.
Methods based on radio-frequency (RF) have also been widely investigated. The RF identification (RFID) system can be applied to obtain a unique item-level identification, and localization can be achieved by various methods such as received signal strength indication (RSSI) with landmarks, phased-array radar, synthetic aperture radar (SAR), and inverse SAR (iSAR). However, fundamental problems in terms of precision and reliability remain. The landmark-tag method uses known coordinates and RSSI of the reference tags to retrieve the position of the unknown target tag, but suffers from insufficient range sensitivity and ambiguity from multipath interference. The SAR and iSAR methods require relative motion between the tags and reader, which is not feasible for many scenarios. For tagless methods, the phased-array radar forms narrow beams to isolate the coverage areas, but the scanning time and spatial resolution of the beam will constrain the system localization capability. The frequency modulation continuous wave (FMCW) method requires a broad frequency bandwidth and a fast Fourier transform (FFT) time window to provide high spatial resolution, and the indoor multipath will still degenerate performance substantially. Although for some applications only the tagless methods are practical, in many other real-world applications, objects can be tagged electronically, similar to the RFID system, to avoid using geometrical features for object recognition. The tag as an object transponder can backscatter the RF beacon signal integrated with the object identification and local sensor properties, which can be well isolated from other interference by subcarriers or code division to improve ranging reliability and accuracy. However, self-jamming and antenna reflection remain serious problems for ranging owing to insufficient separation of the downlink and uplink.
The phase information of the RF signal is more sensitive to the distance between the transmitter (Tx) and receiver (Rx) than RSSI, and can give higher precision if the wavelength ambiguity can be resolved. In the ideal scenario of a fully coherent Tx and Rx separated at a certain distance, Rx can use the demodulated phase of the received signal to retrieve the Tx-to-Rx distance variation, which is in a cyclic linear relation with respect to the phase variation at the given frequency. Under this simplified LoS model, no matter how small the distance change is, the phase will change accordingly. Therefore, phase-based RF ranging resolution is fundamentally limited only by the accurate Tx-Rx carrier synchronization and the phase noise skirt, not by the tradeoff of the time-domain sampling window size or bandwidth. Therefore, both high spatial and temporal resolution in ranging can potentially be achieved at the same time.
Many previous ranging methods are, in contrast, based on Fourier transforms, such as FMCW radar, and sample the data at in reciprocal k-space, recovering the range by applying the windowed Fourier transform. These methods will be unavoidably limited by the uncertainty principle in their mathematical model. For example, when the FMCW radar is configured under a certain sampling rate, the number of k-space sampling points is related to the time domain. When a narrow temporal window is applied to achieve high temporal resolution, the sinc function will spread and degenerate the spatial resolution after the convolution. This trade-off between the spatial and temporal resolution is set by the chosen mathematical procedure, not by a physical limitation. It is possible to bypass Fourier methods to mitigate the resolution tradeoff. Hilbert-Huang transforms (HHT), including empirical mode decomposition and Hilbert spectral analysis, are widely applied to analyze the nonstationary and nonlinear data set to achieve higher resolution in Fourier pairs simultaneously with higher computational cost.
The present disclosure provides devices and methods able to achieve a ranging resolution smaller than, for example, 50 micrometers using a harmonic ultrahigh frequency (UHF; for example, 300 MHz-3 GHz) RF transponder system with a sampling rate of 1 kHz or higher. For comparison, high spatial resolution can be achieved using extremely high frequency, such as in the collision avoidance radar system of 79 GHz with 4 GHz bandwidth. However, lack of dielectric penetration is a severe limitation for extremely high frequency ranging in many applications. In contrast, the presently-disclosed UHF system can potentially achieve the maximum distance of conventional RFID systems, for example, around 15 meters in free space with a Tx power which may be below 30 dBm, and can see through dielectrics such as water and common building materials. The present system may use a transponder which is battery free and can be readily integrated into a small integrated circuit package with a printed antenna, which can be conveniently and inexpensively deployed for various applications.
A radio-frequency method for range finding, includes: modulating a reference signal having an intermediate frequency, fIF, to a downlink signal having a carrier frequency, fc, using a clock signal; transmitting the downlink signal to a tag using a transmitter, the tag being located at a distance from the transceiver; receiving an uplink signal backscattered from the tag, the uplink signal having a frequency that is a harmonic of the carrier frequency; demodulating the uplink signal using the clock signal; and calculating a distance between the tag and the transceiver based on a phase of the demodulated uplink signal. The distance is calculated by comparing the coherent reference signal to the demodulated uplink signal. The uplink signal may be at a second harmonic of the carrier frequency, for example, to lower phase noise interference from leakage of the downlink signal. The step of calculating the distance may be repeated at a sampling rate to update the distance. The intermediate frequency, fIF, may be greater than a frequency where Flicker noise power density is equal to the thermal noise density. The method may include calculating a moving average comprising a predetermined number of most recent calculated distances. The uplink signal may have a unique digital identification code to provide isolation from ambient noise. The unique digital identification code may be encoded using a code-division multiple access (CDMA) protocol to provide isolation from other tags.
The method may include modulating the reference signal to one or more additional downlink signals each having an additional carrier frequency and each of the additional carrier frequencies generated using a corresponding clock signal, and wherein each of the additional carrier frequencies is not equal to fc; transmitting, using a corresponding one or more additional transceivers, the one or more additional downlink signals to the tag; receiving one or more additional uplink signals backscattered from the tag, each of the one or more additional uplink signals being at a second harmonic of a corresponding one of the one or more additional carrier frequencies; demodulating each of the one or more additional uplink signals using the clock signal of the corresponding one or more carrier frequencies; calculating a distance between the tag and each additional transceiver based on a difference between a phase of the reference signal and a phase of a corresponding one of the one or more demodulated uplink signals.
Obtaining the distance may further include dividing a result by the square root of a relative permittivity of a medium between the transceiver and the tag, wherein the relative permittivity of the medium is known and relative to a vacuum. The method may include determining a relative permittivity of a medium in which the tag disposed, using the obtained distance and a known range of the tag, wherein the relative permittivity of the medium is relative to a vacuum.
A radio-frequency system for range finding includes a transceiver and a processor. The transceiver is configured to modulate a reference signal having an intermediate frequency, fIF, to a downlink signal having a carrier frequency, fc, using a clock signal; transmit the downlink signal; receive a backscattered uplink signal from a tag, wherein the uplink signal is at a harmonic frequency of the carrier frequency; and demodulate the uplink signal using the clock signal such that transceiver is a coherent transceiver. The processor is configured to receive the demodulated uplink signal and calculate a distance between the tag and the transceiver using a phase of the demodulated uplink signal. The processor may be further configured to repeatedly calculate the distance at a sampling rate. The processor may be further configured to calculate a moving average comprising a predetermined number of most recent calculated distances.
The system may include a tag configured to receive the downlink signal at fc and to backscatter the uplink signal at the harmonic frequency of the carrier frequency. The harmonic frequency of the carrier frequency may be the second harmonic. The tag may be configured to encode a digital identification code onto the uplink signal. The tag may be configured to encode the uplink signal using a code-division multiple access (CDMA) protocol. The system may include one or more additional tags, each configured with a unique digital identification or CDMA code. The tag may be configured to transform the downlink signal to the uplink signal without offsetting a phase of the downlink signal. The tag may include a non-linear transmission line.
The system may include an analog-to-digital converter to convert the demodulated uplink signal to a digital signal, wherein the analog-to-digital converter is configured to preserve a carrier phase of the uplink signal. The system may include a clock for generating the clock signal, wherein the clock is in communication with the transceiver.
The system may further one or more additional transceivers, each configured to modulate and transmit the reference signal at a corresponding one or more additional carrier frequencies, and to receive and demodulate corresponding uplink signals, each uplink signal at a harmonic of a corresponding one of the one or more additional carrier frequencies. The processor may be further configured to determine a relative permittivity of a medium along a path between the tag and each transceiver of the one or more additional transceivers, using an obtained distance from the corresponding transceiver and a known range of the tag from the corresponding transceiver, wherein the relative permittivity of the medium is relative to a vacuum.
For a fuller understanding of the nature and objects of the disclosure, reference should be made to the following detailed description taken in conjunction with the accompanying figures.
With reference to
The downlink signal is transmitted 109 using a transceiver. The downlink signal may be transmitted 109 to a tag located at a distance from the transceiver. By “transmitted to a tag,” the downlink signal is not necessarily directed only to the tag, but may be, for example, wirelessly broadcast so as to be received at the tag. The transceiver may be an RFID reader system or a part of such a system.
The method 100 includes receiving 112 an uplink signal that is backscattered from the tag, the uplink signal being at a harmonic of the carrier frequency. For example, the uplink signal may be at a second harmonic, 2fc of the carrier frequency. The harmonic RFID system makes use of harmonic backscattering to isolate the downlink (reader to tag) and uplink (tag to reader), which results in a much lower noise floor to achieve accurate ranging. Because of the backscattering scheme, the tag and reader carrier synchronization problem is also readily avoided. A detailed comparison of conventional and harmonic RFID systems is discussed below, which includes analyses of the operational range and link budget.
The uplink signal is demodulated 115 using the clock signal. In this way, the modulating and demodulating steps use the same clock signal and are coherent. It is noted that the clock signal need not be at the carrier frequency (or a harmonic of the carrier frequency). For example, a mixer in the transmitter may use a local oscillator (at the carrier frequency) which is derived from the clock signal. Similarly, a mixer in the receiver may use a local oscillator (at a harmonic of the carrier frequency) which is derived from the clock signal.
A distance between the tag and the transceiver is calculated 118 based on a phase of the demodulated uplink signal. For example, the distance may be calculated 118 based on a difference between a phase of the reference signal and a phase of the demodulated uplink signal.
In some embodiments, the step of calculating 118 the distance is repeated at a sampling rate. For example, the steps of transmitting the downlink signal, receiving the uplink signal, demodulating the uplink signal, and calculating the distance may each be repeated at a sampling rate. In another example, the reference signal may be continuously modulated and transmitted (for some period of time), and the backscattered uplink signal may be continuously received and demodulated. The demodulated uplink signal be used to repeatedly calculate the distance between the tag and the transceiver. In this way, a moving object can be tracked over its movement. The sampling rate may be 10 Hz-10 kHz, inclusive, including every integer Hz value therebetween (e.g., 20 Hz, 100 Hz, 200 Hz, 500 Hz, 1 kHz, 1.5 kHz, 5 kHz, 8 kHz, 9 kHz). The sampling rate may be higher or lower.
The demodulated uplink signal may be sampled 121 at a sampling rate so as to digitize the demodulated uplink signal. The resulting samples may be averaged 124 over a moving average window.
In some embodiments, the method 100 may further comprise modulating 150 the reference signal to one or more additional carrier frequencies, fc2 . . . fcm. Each of the one or more additional carrier frequencies may be generated using a corresponding clock signal. The additional carrier frequencies may be coherent (using a same clock signal) or incoherent (using separate clock signals). Each of the additional carrier frequencies is not equal to fc. In this way, multiple frequencies may be used to resolve wavelength ambiguity (providing range finding over a broader range). One or more additional transceivers may be used to transmit 153 the one or more additional downlink signals to the tag, and a corresponding number of additional backscattered uplink signals are received 156 by the transceiver. Each of the received 156 additional uplink signals is modulated at a harmonic of its corresponding one of the one or more additional carrier frequencies. Each of the received 156 additional uplink signals is demodulated 159 using the clock signal of the corresponding one of the one or more carrier frequencies. A distance between the tag and each additional transceiver is calculated 162 based on a difference between a phase of the reference signal and a phase of a corresponding one of the one or more demodulated uplink signals.
The intermediate frequency, fIF, and/or the carrier frequency, fc, may be selected to minimize Flicker noise and sampling jitter. For example, to minimize the Flicker phase noise, fIF may be chosen to be at a frequency greater than a frequency where the Flicker noise power density is equal to the thermal noise density. With regard to sampling jitter, fIF may be selected to be at a frequency below that at which performance is degraded by sampling jitter. Further examples are provided below.
In another aspect, the present disclosure may be embodied as a radio-frequency system 10 for range finding (see. e.g.,
The system 10 includes a signal processor 30. The signal processor 30 is in communication with the transceiver 20. The signal processor 30 is configured to receive the demodulated uplink signal from the transceiver 20, and to calculate a distance between the tag and the transceiver using a phase of the demodulated uplink signal. The signal processor 30 may be a field-programmable gate array (FPGA). The processor may include one or more modules and/or components. For example, the processor may include one or more hardware-based modules/components (e.g., an FPGA, a digital signal processor (DSP), an application specific integrated circuit, a general purpose processor, etc.), one or more software-based modules (e.g., a module of computer code stored in a memory and/or in a database), or a combination of hardware- and software-based modules.
In some embodiments, the tag 50 may form a component of the system 10. However, it should be noted that a tag may be a separate component from the system in some embodiments. The tag (harmonic tag) 50 is configured to receive the downlink signal from the transceiver 20 and to backscatter the uplink signal at a harmonic frequency of the carrier frequency. For example, the tag may be configured to backscatter an uplink signal at the second harmonic, 2fc, of the carrier frequency, fc. In a particular example, the tag may be a passive harmonic tag configured with a non-linear transmission line (NLTL) configured to backscatter the downlink signal at a harmonic frequency. The tag may be configured to encode a digital identification onto the uplink signal. For example, the digital identification may be an identification code unique to the tag. The digital identification may be encoded using a code-division multiple access protocol. In this way, the system may be able to distinguish between multiple tags which may be present. For example, the system may be configured for range finding of multiple objects using multiple tags.
In some embodiments, the system 10 comprises one or more additional transceivers 25. Each additional transceiver 25 is configured to modulate and transmit the reference signal at a corresponding one or more additional carrier frequencies, and to receive and demodulate corresponding uplink signals. And each uplink signal is at a harmonic of a corresponding one of the one or more additional carrier frequencies.
Further Discussion and Experimental Embodiments
An exemplary system 60 (shown in
A schematic of the passive harmonic transponder is shown in
A schematic of the whole experimental setup is shown in
As the phase noise can be a fundamental limit for the ranging system, a technique to achieve high resolution is to employ an adequate intermediate frequency fIF to avoid the low-frequency Flicker noise. Before the movement of the tag was considered, the ranging performance for the static position was characterized in
Because the ranging variation is related to the resolution, one of the most efficient ways to counter random noise is to apply the moving average. The ranging variation with different window sizes of 1, 10, 100, 1 k, and 10 k are shown in
Ranging Experimental Results and Analyses
An experiment was conducted using quasi-static movement to investigate the harmonic RFID ranging resolution in different materials. A wavelength of the backscattered signal will be reduced as the medium between the tag and the reader antenna has a higher permittivity. Consequently, the phase-based range calculation can be divided by the square root of the relative permittivity (εr0.5=nr). Although the shorter wavelength results in a shorter detection range within one wavelength, this drawback can be easily compensated by the multi-frequency method discussed below. In addition, resolution is usually improved in the higher-permittivity material, which is further illustrated in
The wavelength integer from cyclic ambiguity needs to be resolved to extend the maximum operation range for the phase-based methods. Here, the dual-frequency continuous-wave (DFCW) method was used to demonstrate implementation of the range extension. Other techniques can be used. For example, sophisticated multi-frequency methods can provide more robust estimation with fewer constraints on the maximum range. Because the sensing uplink signal of the experimental embodiment was around the 2 GHz band, in air the single-frequency method can cover a distance of about 15 cm, but only 1.69 cm in water. As an illustration for extended range, the computer-control step motor drove the tag carriage forward for 5 cm in water, and backwards to the 0 point, for a travel of about three wavelengths. Based on the encoder on the step motor shaft, the travel distance monitored by the motor rotation angle was chosen as the ground truth to benchmark the ranging accuracy of the experimental embodiment, as shown in
The temporal response of the ranging system was tested further. The step motor was configured with different speeds during a tag motion of 2.5 mm. In
Similar to other ranging systems based on carrier phase information, phase errors and uncertainties caused by multipath interference play an important part in ranging accuracy and resolution. For example, a worst-case multi-path signal at an orthogonal phase to the LoS path signal with 55 dB lower magnitude can already pose a phase error of 0.1°, which is at the phase noise tolerance limit. The constant part of the phase offset can be reduced by the calibration step in a reasonably controlled indoor environment, which did not greatly contribute to the ranging errors in the experiments shown in this work. The use of a high-directivity reader antenna also helped reduce the multi-path effect by providing low antenna gain for undesirable directions (though such an antenna is not required). However, as discussed previously, when the ambient cannot be adequately controlled or the application scenarios contain large changes in the channel condition, more severe multipath interference can happen, and the ranging system may need to be adapted with broader bandwidth antennas with high directivity and/or a stable phase center, and/or more sophisticated algorithms, possibly with a compromised ranging accuracy and resolution. Moreover, in addition to the frequency reference factors discussed herein, which can limit the ranging performance, some other hardware aspects may need to be considered as well in the system setup. For example, large signal-power dynamic range due to large coverage of the operation distance may need to be adaptively compensated by improved tag and reader designs to reduce the variations in harmonic conversion by the nonlinear element.
Methods
As shown in
Additional Discussion
The phase information of the RF backscatter signal can offer accurate ranging of the transponder tag, which modulates its identification (ID) code on the RF signal to differentiate against other non-specific ambient reflection and inter-tag interference. The phase noise and transmitter/receiver (Tx/Rx) synchronization hence determine the ranging accuracy. The conventional EPC Gen2 (electronic production code generation 2) RFID system however suffers high phase noises. As shown in
Accurate phase retrieval is advantageous for phase-based ranging, which is affected by the LO performance in addition to external phase noise.
where Np is the noise power density and BWb, is the base bandwidth. When LO is at 1 GHz, the second harmonic is at the 2 GHz with the free-space wavelength of 150 mm.
When BWbb is much smaller than foffset, the phase noise spectrum can be regarded as evenly distributed. To mitigate the ranging variation caused by the phase jitter under this condition, a moving average can be helpful towards a white-noise spectrum.
For RF ranging, the carrier frequency fc can be utilized to calculate the wave number or wavelength. Inaccurate fc in the hardware system will directly introduce a ranging offset, which also accumulates along the ranging distance. In the LO specifications, ppm (parts per million) or ppb (parts per billion) describes the frequency inaccuracy. The ppm deviation can be converted to the maximum frequency difference by Eq. (2):
where df is the maximum frequency difference. The ranging errors under 0.2 meters (the blue solid line), 0.5 m (the red dashed line), 1.5 meters (the yellow dotted line), and 5 m (the purple dash-dotted line) with respect to LO inaccuracy in ppm are shown in
To make the system versatile with undemanding filter design, IF sampling is introduced, where the I/Q signals sampled by the ADC are not at the DC band. In realistic scenarios, the ADC clock aperture jitter should also be considered, which causes additional ranging variation. The ADC aperture jitter is usually described in the time domain. The digitized signal phase variation and the resulting ranging error depend on the input signal frequency. The ranging variation dR caused by the ADC jitter and the SNR of the ADC, SNRADC, can be described as:
where tjitter is the ADC clock jitter (in second), fIF is the IF frequency sampled by the ADC, and λh is the wavelength of the uplink carrier.
The high permittivity of the media can enhance the ranging resolution. As shown in Eq. (4), the measured ranging distance change is ΔDm, which is related to the phase change ΔϕD caused by tag movement distance AD and media permittivity εr, phase change Δϕn caused by hardware noise, and the wavelength in the media λε
Equation (4) clearly shows the linear relationship of the ranging distance and the phase when the wavelength ambiguity is not considered. We can reformulate this equation according to the wavelength in air λ0:
The term before the plus sign is the true ranging distance change, and the later term is the distance change caused by the noise. The phase noise caused by the hardware often has statistical characteristics which are independent to εr. Hence, the ranging variation would be reduced by εr−0.5 in comparison with the measurement in air.
where Pt is the transmitting power, Gt the Tx antenna gain, Gr the Rx antenna gain, λ the wavelength, d the distance between Tx and Rx, and Pr the received power. The link budget was estimated under the condition of Pt=30 dBm (reader Tx power), Gt=8 dB (reader Tx antenna gain), Gr=3 dB (tag antenna gain), and λ=0.3 m for downlink and 0.15 m for uplink harmonics. When d=3 m, the received power of the tag will be 0 dBm. After the NLTL converts the signal to harmonic with conversion loss of 15 dB, the Tx power from the tag is −15 dBm. Based on the same equation, the received power at the reader Rx will be −52 dBm. Under the noise floor of −122 dBm (the base bandwidth is set at 100 kHz), we have the Rx SNR at 70 dB. When the distance is up to 15 meters, the received power of the tag will be −12 dBm and the Rx SNR will drop to 42 dB, which will reduce the raw data accuracy but can still be mitigated by the moving average method due to the still high SNR. The simplified link budget analysis above is based on ideal devices and setup without consideration of variations and strong interferences. At the maximum operating range, the received power at the tag and the SNR at the reader Rx can be further reduced in realistic scenarios. However, the present estimate of SNR at 42 dB still has room to give, as many ranging receivers can be reasonably operated with SNR >20 dB.
In at least some aspects, the present concepts include a radio-frequency method for range finding, the method comprising the acts of modulating an analog signal having an intermediate frequency, fIF, to a carrier frequency, fc, using a clock signal, transmitting the modulated signal to a tag using a transceiver, the tag being located at a distance from the transceiver, receiving an uplink signal backscattered from the tag, the uplink signal being modulated at a harmonic of the carrier frequency, demodulating the uplink signal using the clock signal and calculating a distance between the tag and the transceiver based on a phase of the demodulated uplink signal. In some aspects, this method further includes modulating the analog signal to one or more additional carrier frequencies, fc2 . . . fcm, each of the one or more additional carrier frequencies derived from a common accurate reference clock signal, and wherein each of the additional carrier frequencies is not equal to fc, transmitting, using a corresponding one or more additional transceivers, the one or more additional modulated signals to the tag, receiving one or more additional uplink signals backscattered from the tag, each of the one or more additional uplink signals being modulated at a second harmonic of a corresponding one of the one or more additional carrier frequencies, demodulating each of the one or more additional uplink signals using the clock signal of the corresponding one or more carrier frequencies, calculating a distance between the tag and each additional transceiver based on a difference between a phase of the analog signal and a phase of a corresponding one of the one or more demodulated uplink signals, and choosing optimal fIF and fc's to minimize the phase noise and uncertainties arising from the Flicker noise and the sampling jitter.
In at least some aspects, the present concepts includes a radio-frequency system for range finding, including a transceiver configured to modulate an analog signal having an intermediate frequency, fIF, to a carrier frequency, fc, using a clock signal, transmit the modulated signal, receive a backscattered uplink signal from a tag, wherein the uplink signal is transformed to modulated at a harmonic frequency of the carrier frequency and modulated with a digital code, and demodulate the uplink signal using a coherent reference clock signal, wherein the radio-frequency system further includes a processor configured to receive the demodulated uplink signal and calculate a distance between the tag and the transceiver using a phase of the demodulated uplink signal in which the coherent reference clock signal relates to the local oscillator of the receiver being derived from the same reference clock in the transmitter. In at least some aspects, the radio-frequency system processor is further configured to repeatedly calculate the distance between the tag and the transceiver at a sampling rate between 20 Hz-10 kHz.
Although the present disclosure has been described with respect to one or more particular embodiments, it will be understood that other embodiments of the present disclosure may be made without departing from the spirit and scope of the present disclosure.
This application is a continuation of U.S. application Ser. No. 17/289,702, filed on Apr. 28, 2021, which is a U.S. national stage entry of PCT International Patent Application No. PCT/US2019/059274, filed Oct. 31, 2019, which claims priority to U.S. Provisional Application No. 62/753,845, filed on Oct. 31, 2018, the disclosure of each of which is incorporated herein by reference.
This invention was made with government support under contract nos. DE-AR0000528 and DE-AR0000946 awarded by the Department of Energy. The government has certain rights in the invention.
Number | Name | Date | Kind |
---|---|---|---|
3758849 | Susman | Sep 1973 | A |
4307397 | Holscher | Dec 1981 | A |
5298904 | Olich | Mar 1994 | A |
5640683 | Evans | Jun 1997 | A |
5777561 | Chieu | Jul 1998 | A |
5873025 | Evans | Feb 1999 | A |
5952922 | Shober | Sep 1999 | A |
6650230 | Evans | Nov 2003 | B1 |
7096133 | Martin | Aug 2006 | B1 |
7336078 | Merewether | Feb 2008 | B1 |
7603894 | Breed | Oct 2009 | B2 |
7693626 | Breed | Apr 2010 | B2 |
7733077 | Merewether | Jun 2010 | B1 |
8024084 | Breed | Sep 2011 | B2 |
9395727 | Smith | Jul 2016 | B1 |
9443358 | Breed | Sep 2016 | B2 |
9489813 | Beigel | Nov 2016 | B1 |
9582933 | Mosterman | Feb 2017 | B1 |
9645234 | Khan | May 2017 | B2 |
9703002 | Olsson | Jul 2017 | B1 |
9733353 | Carlson | Aug 2017 | B1 |
9870056 | Yao | Jan 2018 | B1 |
9997845 | Schantz | Jun 2018 | B2 |
10738836 | Burgess | Aug 2020 | B2 |
10863313 | Markhovsky | Dec 2020 | B2 |
11238670 | Six | Feb 2022 | B2 |
20050190098 | Bridgelall | Sep 2005 | A1 |
20050206555 | Bridgelall | Sep 2005 | A1 |
20060012476 | Markhovsky | Jan 2006 | A1 |
20060022866 | Walton | Feb 2006 | A1 |
20060284727 | Steinke | Dec 2006 | A1 |
20070279194 | Carrender | Dec 2007 | A1 |
20080139156 | Behzad | Jun 2008 | A1 |
20080299933 | Chang | Dec 2008 | A1 |
20090167699 | Rosenblatt | Jul 2009 | A1 |
20100039228 | Sadr | Feb 2010 | A1 |
20110148710 | Smid | Jun 2011 | A1 |
20110187600 | Landt | Aug 2011 | A1 |
20110260839 | Cook | Oct 2011 | A1 |
20120235856 | Nogami | Sep 2012 | A1 |
20120243374 | Dahl | Sep 2012 | A1 |
20120256730 | Scott | Oct 2012 | A1 |
20130154919 | Tan | Jun 2013 | A1 |
20140320331 | Fernandes | Oct 2014 | A1 |
20150048970 | Schoor | Feb 2015 | A1 |
20150198708 | Khan | Jul 2015 | A1 |
20150204972 | Kuehnle | Jul 2015 | A1 |
20160131742 | Schoor | May 2016 | A1 |
20160363659 | Mindell | Dec 2016 | A1 |
20170108452 | Carlson | Apr 2017 | A1 |
20170131395 | Reynolds | May 2017 | A1 |
20170160380 | Searcy | Jun 2017 | A1 |
20190261137 | Markhovsky | Aug 2019 | A1 |
20210215815 | Mayer | Jul 2021 | A1 |
Number | Date | Country |
---|---|---|
102011084610 | Apr 2013 | DE |
102015222884 | May 2017 | DE |
853392 | Jul 1998 | EP |
670558 | May 2000 | EP |
3120463 | Jan 2018 | EP |
2016065368 | Apr 2016 | WO |
WO-2016065368 | Apr 2016 | WO |
Entry |
---|
Extended European Search Report for Application No. 19878965.3-1206, dated Sep. 26, 2022, 15 pages. |
Number | Date | Country | |
---|---|---|---|
20220413082 A1 | Dec 2022 | US |
Number | Date | Country | |
---|---|---|---|
62753845 | Oct 2018 | US |
Number | Date | Country | |
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Parent | 17289702 | US | |
Child | 17900480 | US |