This disclosure relates to the manufacture of continuous glass filament strands and, more particularly, to the improved manufacture of continuous glass filament strand and fiberglass filtration media. It is particularly applicable to the manufacture of lofted continuous glass filament fiberglass media used for filtration or composites manufacturing.
The present disclosure relates to improvements to the Modigliani process as generally described in U.S. Pat. Nos. 2,081,060; 2,546,230; and 2,913,037. Subsequent improvements and variations of the Modigliani process have been made and are known in the art. Little has been done to improve upon the efficiency of the manufacturing methods and apparatus either through new control methods or through process changes.
The Modigliani process and its progeny generally involve a melting furnace feeding molten glass which discharges fine glass filaments. The glass fibers are in turn wrapped around a rotating drum. During the deposition of the fibers on the rotating drum, resins are applied to the surface of the glass as it is accumulated on the rotating drum. The resulting fiberglass mat is then removed from the drum, optionally expanded, and cured.
Returning to the beginning of the process, strands of molten glass exit the melting furnace through a multi-orifice metallic plate (bushing plate) attached to the underside of the melting furnace. The diameter of strands is determined by a combination of the diameters of orifices disposed within the bushing plate, surface velocity of the rotating drum positioned below the melting furnace, onto which glass filaments are pulled and accumulated, and chemical composition of the glass. A number of metal alloys have been used for furnace bushing plates in the manufacture of glass filaments for products such as insulation, composites, and filtration media. The economics of the application generally impact the feasibility of using each alloy. Very high-volume applications such as glass filament insulation and glass filament roving make the use of noble metal alloys, typically with a majority platinum content, both efficient and economical. Much lower volume applications, such as the production of glass composite veil or continuous glass filament media with non-random filament orientations, require a much less expensive but heat resistant metal bushing plate. Some variation of the Modigliani process is used for these lower volume applications.
In the Modigliani process generally, the bushing plate must be rapidly cooled as each mat is completed on the rotatable drum. The rapid cooling of the bushing plate temporarily stops or slows the flow of glass through the bushing plate, allowing operators to remove the completed mat from the drum. This process may be repeated multiple times per day in a typical factory. Thus, there is a need to repeatedly cool the bushing plate before returning it to operating temperature. Because the bushing plate is cemented into the bottom of the refractory furnace liner, removing the bushing from the liner after the furnace has been in service for a substantial length of time cannot be accomplished without permanently damaging the liner. In light of these conditions of use, the most sought-after characteristics for bushing plates used in the Modigliani process are resistance to the erosion of the orifices from the flowing glass filaments, resistance to warping through the multiple heating and cooling cycles, and the ability to be heated relatively uniformly.
Attempts have been made to create hybrid plates wherein the plate is made of a relatively inexpensive metal while the orifices have noble metal sleeves or liners, although such attempts have not been commercially competitive. Attempts to uniformly heat inexpensive bushing plates through an electrical-heating process have not been successful. Attempts to use noble metal bushing plates in the Modigliani process, while technically feasible, have been commercially impractical due to the operating cost and other limitations. Thus, there remains a need for a commercially viable bushing plate that exhibits resistance to erosion, resistance to warping, and the ability to be heated relatively uniformly.
Drum length is a determinant of the length of the cured fiberglass media that emerges from the fiberglass curing apparatus. Customers of cured fiberglass generally desire lightweight fiberglass in roll lengths that are up to 1200 feet. These customers also desire heavier weight rolls in lengths as short as 66 feet.
Loft height of the cured fiberglass is an important characteristic. Customers generally desire lofts from ¼ inch to 6 inches. Thinner lofts compress more easily when rolled while thicker lofts are more difficult to compress. The reason for this is that the cross linked resin bonds in cured fiberglass resist bending. The bending resistance increases with the distance the cross linked bond must travel when the loft is compressed in the process. If the bond is subjected to too much deformation, it ultimately breaks, which lessens the ability of the cured fiberglass to return to its specified loft when the roll is unwound.
There is an interaction between drum circumference and curing apparatus width which affects the geometry of filament cross linking in the finished product. The design of the curing apparatus is constrained by many factors, one of which is the width of the upper loft-setting conveyor belt (or chain) which is used to set the loft of the product. Because customer product specifications for loft have narrow tolerances, typically + or − one eighth of an inch or one quarter of an inch, there can be very little deflection of the upper loft-setting conveyor across its width. At design widths exceeding 132 inches, it becomes mechanically complex and prohibitively expensive to limit deflection sufficiently. If the width of the unexpanded fiberglass mat—which is generally equal to the circumference of the drum—is greater than 22 feet, it becomes very difficult to cure the filaments such that the cross linked filaments are cured at angles of approximately 90 degrees. Such curing produces longitudinal and transverse stiffness of the finished media that are approximately equal (which is a common customer requirement.)
Longitudinal filament adherence introduces defects in stiffness and rigidity in either the X or Y (horizontal) axes. It also diminishes compressive strength and reduces the ability of media, especially in air filtration applications, to capture and hold solid and liquid particulates.
If the circumference of the rotating drum (and thus the approximate unexpanded mat width) is less than 12 feet or greater than 22 feet, the filaments will adhere to each other longitudinally for excessive distances in either the X or Y axes as they are cured, which will create insufficient finished product stiffness in one of those two axes. Such conditions also produce insufficient compressive strength (another typical customer requirement) in the loft of the finished product. In air filtration applications, those conditions can diminish the ability of the media to capture and hold particulates. Insufficient compressive strength furthermore leads to cosmetic defects such as bunching of filaments, thereby lessening the product's appeal to customers, both in air filtration and light filtration applications.
Spinning drums ranging from 12 feet to 24 feet in length with circumferences ranging from 12 to 22 feet have varying drum weights along with a variety of typical rotational speeds. The combination of drum length and drum circumferences with varying rotational speed creates vibrations, which tend to result in premature failure of a drum shaft. Failure to properly calculate the appropriate shaft diameters required for safe operation of rotatable drums of various dimensions at various surface velocities has led to shaft failures which creates unsafe conditions.
Several resin binder formulations are known in the art and may be sprayed onto the glass fiber. Generally, the process is designed such that the swath of filaments is sprayed with binder almost immediately after deposition on the drum. The resin thoroughly coats the most recently applied glass filaments and causes the glass filaments to adhere to rest of the filament mat. Proper binder coverage of the filaments may not be achieved if the centrifugal force of the rotating drum overcomes the viscosity of the binder and forces binder closer to the drum to migrate toward the filaments further from the drum.
There remains a considerable need for systems, apparatuses and methods that can improve the efficiency and quality of the manufacture of continuous glass filament media.
In this disclosure, the terms filament, fiber and strand are used interchangeably and in all cases refer to glass filament that is continuous as opposed to glass staple fiber such as that used in manufacturing fiberglass insulation.
In the present disclosure, a glass melting furnace is situated to traverse above a rotatable hollow drum of a specific range of dimensions. The furnace comprises a temperature-controlled melting reservoir adjacently coupled to a bushing plate perforated with a specific numerical range of countersunk orifices of a specific range of dimensions. The bushing plate is adjacently coupled to a cooling loop and further coupled to side shields. The cooling loop is connected to a water and air supply system which maintains a specific range of temperatures and pressures. A control system with sensors may be used to prevent clogging. The furnace assembly is mounted on tracks and traverses above the rotatable drum such that a swath of continuous glass filaments of a specific range of diameters is deposited onto the rotatable drum. The furnace assembly is communicatively coupled to a control system and sensors for controlling the speed of the traverse and the speed of rotation of the rotatable drum. The furnace assembly is further coupled to spray arms with nozzles which spray a resin binder and optionally other aqueous solutions onto the continuous glass filaments that have been deposited onto the drum. The drum rotates on a shaft of a specific range of dimensions. The shaft is coupled to load cells which are communicatively coupled to a control system. When the load cells indicate to the control system that the total weight of the mat of continuous filament glass saturated with binder, and optionally other aqueous solutions, is at the target weight, operators stop the drum, make a longitudinal cut in the mat, and remove the mat from the drum. The mat is then rolled onto a pole and subsequently unrolled onto a let-off table which comprises a chain conveyor with heat applied from above and below and a nip roller for controlling tension on the mat as it is expanded. When the mat exits the let-off table, it proceeds to a roller and water spray assembly and then to a curing apparatus. The curing apparatus comprises a plurality of heated zones, a lower conveyor belt (or chain) and an upper loft-setting belt (or chain). Once the mat exits the curing apparatus, it proceeds to a slitter-accumulator assembly and then to a windup machine. Operators remove the slit and rolled fiberglass media from the windup machine and package the rolls for shipment.
The detailed description makes reference to the accompanying figures wherein:
The figures are only intended to facilitate the description of the principles disclosed herein. The figures do not illustrate every aspect of the principles disclosed herein and do not limit the scope of the principles disclosed herein. Other objects, features, and characteristics will become more apparent upon consideration of the following detailed description.
Raw material inputs are comprised of recycled glass cullet or in some cases non-recycled glass of various configurations, urea formaldehyde or styrene resin and optionally acrylic co-polymers, acrylate polymers, water or other additives or diluents. The mixed resin is referred to as binder. The recycled glass cullet is sorted for purity and clarity or turbidity which is screened to achieve maximum dimensions of ½ inch to 1¼ inches in size. Referring to
Referring to
Molten glass exits the melting furnace 10 through an Inconel bushing plate. Forming the bushing plate out of certain grades of Inconel yields superior results in terms of glass flow rates, bushing plate lifespan, and glass filament quality. By extension, these improved results improve the economics of the manufacturing process. In some embodiments, the bushing plate is machined from 100% Inconel, namely one or more of Inconel alloys 600, 601, 690, 693, 702, and 754. No orifice inserts are used during the manufacturing process.
With reference to
As shown in
To accommodate the various applications of continuous glass filament, it is necessary to control the finished diameter of fiberglass strands. Finer diameter fiberglass strands improve the efficiency of lofted fiberglass air filtration media to capture and hold smaller diameter solid and liquid particulates. Larger diameter fiberglass strands are superior at capturing and holding larger solid and liquid particulates and also improve the rigidity and compressive strength of the finished fiberglass media. For composite applications, finer diameters are required for wrapping around acute angles, with larger fiberglass strand diameter increasing tensile strength. In other applications, such as light filtration, fiberglass strand diameter affects the aesthetics of light diffusion. A bushing plate with orifice diameter of a minimum 0.14 inch is used to produce fiberglass strand diameters used to achieve an ASHRAE MERV 8 specification. A bushing plate with orifice diameter of a maximum 0.19-inch is used to produce continuous glass filaments which hold the largest and heaviest particulates, such as paint droplets, and maintain sufficient rigidity and compressive strength.
The top seven to fifteen layers of coil 26 are composed of 1/4-inch copper refrigeration tubing 30 which carries chilled water. The cooling water is supplied either by a chiller or from near-constant temperature water well. Pressure sensors, which are monitored and controlled by the controller 46, detect if the cooling water loop is becoming clogged. Temperature sensors provide feedback to the chiller through the thermal software and sensor control of the controller 46 to control temperatures of the cooling loop assembly 24.
The bottom coil is ⅜inch copper tubing 32 perforated with side air holes 1/32-inch in diameter directed upward toward bushing plate 22. A cooling loop 32 comprises a single copper air coil that is ⅜inch diameter and allows exiting air to rapidly cool glass filaments exiting the bushing plate and to retard the flow of glass through the bushing plate as needed.
Shields 40 preferably consist of metal plates and are placed around the area below the bushing plate to prevent ambient air flow from causing filaments to collide as they exit the bushing plate orifices. Preferably, shields are placed on three sides below the bushing plate, leaving one side open to allow access by an attendant. The shields are preferably 6 to 24 inches long. In some embodiments, shorter or longer shields may be used, and shields may be positioned to encircle the entire area below the bushing plate or positioned in other configurations suitable to prevent air flow from disrupting the filaments after they exit the bushing plate.
The rotating drum 12 is wrapped in plastic sheeting to enable the fiberglass mat's removal from the drum. Once the plastic sheeting wraps the drum, a thin application of mold release oil is applied to the surface of the sheeting. As the filament strands fall from the bushing plate, an operator assists the process in attaching the falling filament strands of molten glass to the plastic sheeting wrapped drum. Additionally, the operator may reattach filaments that have detached from the rotating drum. The rotating drum 12 has a circumferentially enlarged surface and longitudinally extended length with an extended shaft 50 (shown in
It is desirable to spin the fiberglass media on drums of specific lengths in order to manufacture desired roll lengths. Using a specific drum length avoids breaking cross-linked resin bonds. Drums that are at least 12 feet in length are used to produce continuous glass filament media for heavier weight and higher loft fiberglass products in shorter roll length. Drums as long as 24 feet are used to produce lighter weight, lower loft fiberglass media in longer roll length.
Drum circumferences of less than 12 feet create fiberglass mat that, when expanded, exhibit cross linking of resin bonded filaments approaching parallel. Such an acute angle minimizes transverse stiffness of the media, thereby promoting higher failure modes. Angles of cross linked filaments approaching 90 degrees provide stiffness in both the X and Y axes, provide higher compressive strength, improve filtration efficiency, and improve aesthetic appeal in both air and light filtration applications. Optimally, none of the acute angles formed by an intersection of cured filaments should be less than 60 degrees, and most should approach 90 degrees.
Drum circumferences greater than 22 feet do not allow for sufficient expansion of the fiberglass media or mat. This leads to filaments adhering to each other longitudinally for excessive distances. Filament adherence longitudinally introduces defects in transverse stiffness and rigidity, diminishes compressive strength, and reduces the ability of media, especially in air filtration applications, to capture and hold solid and liquid particulates. It furthermore leads to cosmetic defects, such as bunching of filaments, thereby lessening the product's appeal to customers, both in air filtration and light filtration applications.
Spinning drums ranging from 12 feet to 24 feet in length with circumferences ranging from 12 to 22 feet have varying drum weights and are operated at a variety of rotational speeds. Certain combinations of drum length, drum circumference and rotational speed create vibrations, which tend to result in premature failure of a drum shaft. To avoid shaft vibrations, shaft diameters are calculated with respect to drum weight and rotational surface velocities with resultant optimal steel shaft diameters at a minimum of 2.5 inches and no more than 4.5 inches.
The melting furnace repeatedly traverses the drum's length 18 (shown in
Urea formaldehyde resin as used in filter applications is mixed with specific additives and diluents, optimally under shear mixer conditions. In some embodiments, a binder is used that consists essentially of urea formaldehyde and polybutene, and in some embodiments, a binder is used that consists entirely of urea formaldehyde and polybutene. The diluent percent is controlled in the range of 5% to 10% of the binder weight. The binder is maintained at room temperatures by cooling and heating coils in the dispensing tanks, and is agitated in the dispensing tanks. The pH is monitored and controlled to be within the range of 7.0 to 7.8. Binder percent solids is sampled, tested, and controlled to a range of 60% to 68% solids. Additionally, the binder temperature is controlled with a reservoir as a depository for temperature-controlled binder to be sprayed via resin spray arm 42 (shown in
In some instances, styrene resin for composite applications is mixed with other diluents, optimally by a shear mixer for better mixing, and temperature controlled with heating and cooling coils in the storage and/or dispensing tanks. The diluent percent is controlled in the range of 1% to 5% of the binder weight. The pH is monitored and controlled to be within the range of 7.0 to 7.8, and the tank is continually agitated to ensure complete mixing of the styrene binder with uniform temperature in the storage and/or dispensing tanks. Binder percent solids is sampled, tested, and controlled to a range of 60% to 68% solids.
Water is conditioned soft and in some cases the water is mixed with the resin creating an aqueous solution. The water may be sprayed onto resin as it is applied to the filaments via water spray arm 44, shown in
Referring to
Due to centrifugal force of the rotating drum, insufficient binder viscosity allows the binder to migrate from the filaments closer to the drum surface to filaments farther from the drum surface. When the fiberglass mat is cured, this migration causes insufficient cross linking of the fibers on the side of the mat closest to the drum, and excessive amounts of binder on the side farthest from the drum. This results in one side of the finished fiberglass media lacking skin, rigidity, and stiffness while the other side can be excessively skinned with excessive rigidity and stiffness. Additionally, the side with excessive amounts of binder will tend to shed particles of cured resin. Any of these conditions can make the finished fiberglass media less desirable or even unusable by customers.
Further, excessive binder viscosity causes the binder spray to be uneven and causes atomized binder particles to adhere to each other and not flow over the glass filaments with uniform coverage. This results in binder cross linking of filaments that is neither uniform nor sufficiently rigid with significant surface skin or compressive strength. At a minimum, at the extremes of ambient relative humidity, controlling binder viscosity at a very low relative humidity requires air pressure at the resin spray nozzle as low as 6 pounds per square inch. Additionally, for high relative humidity, air pressure is required at the resin spray nozzle as high as 32 pounds per square inch.
To achieve a proper coverage of the binder, the binder spray pattern width is monitored and controlled by an operator. In some embodiments, the binder spray pattern width is monitored and controlled by the controller 46 through the use of sensors. Because the glass melting furnace 10 continually traverses back and forth above the rotating drum 12, and because a traversing speed may vary from product to product, the width of the cone-shaped spray pattern must be controlled by an operator or controller 46 to assure proper coating and adhesion of a swath of fibers. Preferred spray widths range from 2 inches to 6 inches.
The fiberglass mat article is complete when a total weight measurement of glass fiber, resin mixture, and water has reached the weight prescribed in the formulation for each specific product. Attainment of the product specific weight can be controlled in some cases by load cells or by calculating the time necessary for that product specific weight to be attained. The formula of the load cell weight control is achieved by taking the weight of the mat on the drum and subtracting the weight of the drum. When the mat reaches its product specific weight, the spinning of the drum is complete and the operator actuates the braking mechanism on the drum drive. The drum has a V-shaped slot that runs longitudinally parallel to the axis of rotation of the drum from one end to other across the width of the drum and thereby across the width of the continuous strand filament mat lying thereupon. The operator uses this slot to cut the mat from the drum. At this point, the mat is promptly removed from the drum, laid on a flat surface, and covered with plastic sheeting. From there the mat is rolled onto a steel bar in a direction parallel to the longitudinal axis of the drum. The weight of the mat is confirmed and recorded by weighing the rolled mat and calculating the net rolled mat weight.
With reference to
Referring to
Quality of finished product is maintained through an extensive process of inline and post curing quality control process steps. Such steps include measuring loft and roll width through the use of a fixture that cuts out single square foot samples. Another fixture is used to measure the compressive strength of a square foot sample. Each square foot sample is weighed. Additionally, the bottom skin and, if the product includes one, the top skin of a sample are removed, and a scale is used to determine the percentage by weight of the skin(s).
The detailed description is not intended to be limiting or represent an exhaustive enumeration of the principles disclosed herein. It will be apparent to those of skill in the art that numerous changes may be made in such details without departing from the spirit of the principles disclosed herein.
This application is a continuation-in-part of U.S. patent application Ser. No. 15/224,175, filed Jul. 29, 2016, which is a continuation-in-part of U.S. patent application Ser. No. 14/181,426, filed Feb. 14, 2014, now U.S. Pat. No. 9,446,978, which claims the benefit of U.S. Provisional Application No. 62/282,444, filed Jul. 31, 2015. This application is also a continuation-in-part of U.S. patent application Ser. No. 15/640,503, filed Jul. 1, 2017, which is a continuation of U.S. patent application Ser. No. 15/151,478, filed May 10, 2016, now U.S. Pat. No. 9,695,084, which claims the benefit of U.S. Provisional Application No. 62/179,572, filed May 11, 2015. All of the foregoing applications are incorporated by reference herein in their entirety.
Number | Date | Country | |
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62179572 | May 2015 | US |
Number | Date | Country | |
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Parent | 15151478 | May 2016 | US |
Child | 15640503 | US |
Number | Date | Country | |
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Parent | 15224175 | Jul 2016 | US |
Child | 16167309 | US | |
Parent | 14181426 | Feb 2014 | US |
Child | 15224175 | US | |
Parent | 15640503 | Jul 2017 | US |
Child | 14181426 | US |