The present invention relates to a system and a method of controlling dosing of a chlorine dioxide based disinfectant into water.
In order to minimize the risk of infectious diseases, it is customary to disinfect water meant for human use. In special applications such as installations for supplying non-stationary drinking water, or the treatment of water in swimming pools, disinfection is a basic necessity. Chlorine and its species, such as, sodium perchlorite, calcium perchlorite are the most commonly used disinfectants for disinfecting water because they are economical and have good germicidal ability. However, the aforementioned disinfectants react with organic material in the water and produce various by-products of disinfection. For example, the disinfection by-products include chloramines and trihalomethanes (THMs). These by-products are restricted in many places, and especially trihalomethanes, as the same is suspected to be a carcinogen.
Alternatively, chlorine dioxide has been proposed for disinfecting water as the same is effective in the inactivation of the pathogenic organisms and unlike chlorine and its species mentioned above does not produce trihalomethanes. However, chlorine dioxide reacts with water to produce inorganic by-products, such as, chlorite and chlorate. The parameters of the water that influence the formation of chlorite and chlorate in the water, include, concentration of the disinfectant, reaction time, temperature, pH value, and total organic content of the water. These by-products are restricted in many places, as exposure to the same at low levels may lead to hemolytic anemia, while higher levels may result in an increase in methemoglobin. Thus, standards for the concentrations of chlorite and chlorate in water have been established in many countries. For example, World Health Organization (WHO) recommends 0.2 mg/l as an upper limit of concentration of chlorite in drinking water.
One embodiment provides a system for controlling dosing of a chlorine dioxide based disinfectant into water, comprising: at least one dosing unit for dosing the disinfectant into the water, at least one first sensor adapted to detect a concentration of chlorite in the water and configured to output respective first signals indicative of the concentration of the chlorite, and a controller operably coupled to the at least one first sensor to receive the first signals and operably coupled to the at least one dosing unit to send a control signal to the at least one dosing unit in response to the at least one of the first signals such that the concentration of chlorite does not exceed a chlorite threshold value.
In a further embodiment, the system further comprises at least one second sensor adapted to detect a concentration of the disinfectant in the water and configured to output respective second signals indicative of the concentration of the disinfectant, wherein the controller is configured to receive the respective second signals and configured to generate the control signal further responsive to the at least one of the second signals such that the concentration of disinfectant in the water is equal to a modified dosing setpoint value, wherein the modified dosing setpoint value is obtained by modifying a dosing setpoint value responsive to the at least one of the first signals.
In a further embodiment, the system further comprises one or more additional sensors adapted to detect one or more additional parameters influencing the formation of chlorite in the water.
In a further embodiment, the additional parameter(s) include(s) a temperature and/or a pH value of the water.
In a further embodiment, the controller is further configured to generate a look-up table comprising the detected concentration of chlorite, the concentration of disinfectant in the water, and values of at least one of the additional parameter of a plurality of respective measurement cycles and configured to store the generated look-up table in a memory.
In a further embodiment, the controller is further configured to generate the control signal in response to the concentration of disinfectant from the look-up table for the detected concentration of chlorite in the water and value of at least one of the additional parameter such that the concentration of chlorite does not exceed the chlorite threshold value.
In a further embodiment, the controller is configured to generate the control signal in response to a highest concentration of chlorite in the water or an average amount of the concentration of chlorite in the water indicated by the respective first signals provided by two or more of the first sensors at the same time.
In a further embodiment, the controller is further configured to compute a value of quality of the water as a ratio of the detected concentration of the disinfectant in the water to the concentration of chlorite in the water and provide an output signal indicative of the value of quality of the water.
In a further embodiment, the system further comprises a display operably coupled to the controller and configured to receive the output signal and provide a visual indication of the value of quality of the water responsive to the output signal.
Another embodiment provides a method of controlling dosing of a chlorine dioxide based disinfectant into water, the method comprising: providing at least one dosing unit for dosing the disinfectant into the water, detecting a concentration of chlorite in the water, generating a control signal responsive to the concentration of chlorite detected, and controlling the at least one dosing unit for dosing the disinfectant into the water responsive to the control signal such that the concentration of chlorite does not exceed a chlorite threshold value.
In a further embodiment, the generating of the control signal includes: detecting a concentration of the disinfectant in the water, and generating the control signal responsive to the concentration of disinfectant in the water such that the concentration of disinfectant in the water is equal to a modified dosing setpoint value, wherein the modified dosing setpoint value is obtained by modifying a dosing setpoint value responsive to the concentration of chlorite in the water.
In a further embodiment, the generating of the control signal includes: detecting at least one additional parameter influencing the formation of chlorite in the water, generating a look-up table comprising the detected concentration of chlorite, the concentration of disinfectant in the water, and values of at least one of the additional parameters of a plurality of respective measurement cycles, and storing the generated look-up table in a memory.
In a further embodiment, the control signal is generated in response to the concentration of the disinfectant from the look-up table for the detected concentration of chlorite and the value of at least one of the additional parameters.
In a further embodiment, the control signal is generated in response to a highest concentration of chlorite in the water or an average amount of the concentration of chlorite in the water indicated by the respective first signals provided by two or more of the first sensors at the same time.
In a further embodiment, the method further comprises computing a value of quality of the water as a ratio of the detected concentration of the disinfectant in the water to the concentration of chlorite in the water, and providing a visual indication of the value of quality of the water.
Example embodiments of the present invention are further described hereinafter with reference to the accompanying drawings, in which:
Embodiment of the present invention provide a system and a method of controlling a concentration of chlorite in water generated due to the addition of a chlorine dioxide based disinfectant into the water.
Controlling the dosing of the disinfectant into the water responsive to the concentration of chlorite in the water enables in controlling the concentration of chlorite in the water more effectively as the concentration of chlorite in the water is maintained below the chlorite threshold value. The chlorite threshold value can be the concentration of chlorite specified by the Government or a standard organization as the permissible limit. This prevents users of the water from exposure to chlorite above the permissible limits.
Additionally, the dosing of disinfectant can be controlled in a continuous manner as the control signal is generated by the controller responsive to the concentration of chlorite in the water. Moreover, as the dosing of the disinfectant can be controlled in a continuous manner, the dosing of the disinfectant into the water is not required to be stopped for controlling the concentration of chlorite in the water.
According to an embodiment, further comprising at least one second sensor adapted to detect a concentration of the disinfectant in the water and configured to output respective second signals indicative of the concentration of the disinfectant, wherein the controller is configured to receive the respective second signals and configured to generate the control signal further responsive to the at least one of the second signals such that the concentration of disinfectant in the water is equal to a modified dosing setpoint value, wherein the modified dosing setpoint value is modified responsive to at least one of the first signals. This enables in efficient control of dosing of the disinfectant into the water by reducing the deviation between the amount of the disinfectant being dosed and the modified dosing setpoint value.
According to another embodiment, the system further comprises one or more additional sensors adapted to detect one or more additional parameters influencing the formation of chlorite in the water. This enables in detecting additional parameters influencing the formation of chlorite.
According to yet another embodiment, wherein the additional parameter includes a temperature and a pH value of the water.
According to yet another embodiment, the controller is further configured to generate a look-up table comprising the detected concentration of chlorite, the concentration of disinfectant in the water, and values of at least one of the additional parameter of a plurality of respective measurement cycles and configured to store the generated look-up table in a memory. This enables in storing the concentration of chlorite in the water based on previously detected parameters influencing the formation of chlorite in the water.
According to yet another embodiment, the controller is further configured to generate the control signal in response to the concentration of disinfectant from the look-up table for the detected concentration of chlorite in the water and value of at least one of the additional parameter such that that the concentration of chlorite does not exceed a chlorite threshold value. This enables in generating the control signal based on the parameters of the water detected previously and thus enables is maintaining the concentration of chlorite in the water within permissible limits based on historical data.
According to yet another embodiment, the controller is configured to generate the control signal in response to a highest concentration of chlorite in the water or an average amount of the concentration of chlorite in the water indicated by the respective first signals provided by two or more of the first sensors at the same time. Highest concentration of chlorite enables in generating the control signal such that the concentration of chlorite will not exceed the threshold value under any circumstances. Additionally, average amount enables in more effective control of dosing of the disinfectant into the water as the dosing of the disinfectant is controlled responsive to the concentration of chlorite detected by multiple sensors.
According to yet another embodiment, the controller is further configured to compute a value of quality of the water as a ratio of the detected concentration of the disinfectant in the water to the concentration of chlorite in the water and provide an output signal indicative of the value of quality of the water.
According to yet another embodiment, the system further comprises a display operably coupled to the controller and configured to receive the output signal and provide a visual indication of the value of quality of the water responsive to the output signal. This provides a visual indication of the quality of the water.
Various embodiments are described with reference to the drawings, wherein like reference numerals are used to refer to like elements throughout. In the following description, for purpose of explanation, numerous specific details are set forth in order to provide a thorough understanding of one or more embodiments. It may be evident that such embodiments may be practiced without these specific details.
Advantageously, the controller 25 can be configured to generate the control signal 35 such that the amount of disinfectant being dosed into the water by the dosing unit 15 is within a predefined range. The predefined range of dosing of the disinfectant can be stored at a memory and for example, can be selected based on the water quality or type of water being treated. In an aspect, the controller 25 can be configured to compare the value of the first signal 30 with a chlorite threshold value and generate the control signal responsive to the comparison. The chlorite threshold value can be selected as the desired upper limit of concentration of chlorite in the water and the control signal 35 can be generated such that the concentration of chlorite in the water does not exceed the chlorite threshold value. The chlorite threshold value can be stored at a memory internal or external to the controller 25. Thus, the dosing of the disinfectant by the dosing unit 15 is controlled responsive to the concentration of chlorite in the water. This allows for maintaining the concentration of chlorite in the water within the permissible limits more efficiently.
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Advantageously, the controller is configured to modify the dosing setpoint value within the predefined range of dosing of the disinfectant into the water. Thus, the modified dosing setpoint value within the predefined range will be the optimized dosing setpoint value. In the present aspect, the controller 25 can be configured to modify the dosing setpoint value based on the comparison of the value of the first signal 30 with the chlorite threshold value. Thus, modifying of the dosing set point value depending on the concentration of chlorite in the water allows maintaining the concentration of chlorite in the water within permissible limits. Additionally, the modification of the dosing setpoint value based on the concentration of chlorite in the water, enables controlling the chlorite concentration in water in the standard process of dosing of disinfectant in the water.
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In the present aspect, advantageously, the controller 25 can be configured to modify the dosing setpoint value first signal 30 and the second signal 45. The control signal can be generated by obtaining the values of the first signal 30 and the second signal 45. The value of the second signal 45 provides the concentration of the disinfectant in the water. In an aspect, the controller 25 responsive to the first signal 30 and the second signal 45 can compare the value of the first signal 30 with the chlorite threshold value and the value of the second signal with a predefined range, wherein the predefined range specifies the permissible concentration of disinfectant in the water. The permissible concentration of a disinfectant can be specified by each country for its jurisdiction or can be the one specified by a standard organization. Based on the comparisons, the controller 25 can be configured to generate the control signal 35 such that the concentration of chlorite in the water does not exceed the chlorite threshold value and the concentration of the disinfectant in the water is within the predefined range. For example, if the concentration of chlorite is relatively very less than the chlorite threshold value and the concentration of disinfectant in the water is on the lower side of the predefined range, the control signal 35 can be generated such that the dosing of the disinfectant in the water can be increased to achieve adequate concentration of the disinfectant in the water. Adequate concentration of the disinfectant in the water enables disinfecting the water adequately. The adequate concentration of the disinfectant is achieved by maintaining the concentration of chlorite in the water within the permissible limits. This enables in preventing the users of the water to exposure of concentrations of chlorite above the permissible limits.
A “controller” as used herein is a device for executing machine-readable instructions stored on a computer readable medium, for performing tasks and may comprise any one or combination of, hardware and firmware. For example, the controller may be implemented using a processor, microcontroller, microprocessor, electronic devices, or other electronic units to perform the functions described herein or a combination thereof. The machine-readable instructions may be stored within the controller or external to the controller.
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In embodiments where the dosing setpoint value is determined based on the flow rate of the water, the dosing set point value can be modified based on the concentration of chlorite in the water and one or more of the additional parameters detected and the control signal 35 can be generated based on the modified dosing set point value. Moreover in embodiments, where the system 10 operates in a closed feedback loop for correcting deviations in dosing of the disinfectant in the water, the control signal 35 can be generated based on the difference between the modified dosing setpoint value and the measured concentration of disinfectant in the water.
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The embodiments described herein can be used for maintaining the concentration of chlorite in water within the permissible limits generated due to addition of chlorine dioxide based disinfectants to water. Water can be disinfected for human consumption, such as, swimming, bathing, drinking, and the like and also for industrial use, e.g. in water coolant circuits. Chlorite is one of the by-products generated when water is disinfected with specifies of chlorine. Chlorite has negative effect on the health of a user when the user is exposed to concentrations of chlorite above the permissible limits. Thus, controlling the dosing of the disinfectant into the water responsive to the concentration of chlorite in the water enables in maintaining the concentration of chlorite in the water within the permissible limits more effectively. The embodiments described can be implemented with a standard process of dosing of disinfectant into water which are well established and recognized. Additionally, the dosing of the disinfectant into the water can be controlled in a continuous manner without requiring stopping of the dosing of the disinfectant into the water. Moreover, drinking water is supplied in pipes and the embodiments described herein enables in efficient control and correction of dosing of disinfectant into the water such that concentration of chlorite is maintained within the permissible limits.
While this invention has been described in detail with reference to certain example embodiments, it should be appreciated that the present invention is not limited to those precise embodiments. Rather, in view of the present disclosure which describes the current best mode for practicing the invention, many modifications and variations would present themselves, to those of skill in the art without departing from the scope and spirit of this invention. The scope of the invention is, therefore, indicated by the following claims rather than by the foregoing description. All changes, modifications, and variations coming within the meaning and range of equivalency of the claims are to be considered within their scope.
Number | Date | Country | Kind |
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11168627.5 | Jun 2011 | EP | regional |
This application is a U.S. National Stage Application of International Application No. PCT/EP2012/058510 filed May 9, 2012, which designates the United States of America, and claims priority to EP Patent Application No. 11168627.5 filed Jun. 3, 2011. The contents of which are hereby incorporated by reference in their entirety.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2012/058510 | 5/9/2012 | WO | 00 | 7/23/2014 |