Patent Application
20220161214
The present disclosure relates generally to the processing of spent catalyst materials, and, more particularly, to a catalyst converter and a movable storage silo for processing and transporting spent catalysts.
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen sulfide. The multi-step Claus process utilizes catalysts and recovers sulfur from the gaseous hydrogen sulfide found in raw natural gas and from the by-product gases containing hydrogen sulfide derived from refining crude oil and other industrial processes.
The processing of such catalysts and the subsequent utilization of spent catalyst has not been efficient or environmentally friendly, in that processing plants and refineries in the art simply dispose of spent catalyst in landfills. Despite increased economic and environmental pressures on sweetening plants to reduce expenditures and waste generation, plants still dispose of spent catalyst in landfills.
One alternative to disposal of spent catalysts in landfills is to utilize Claus-based spent catalysts as a raw material in local cement manufacturing plants to manufacture PO cement. The addition of the spent catalyst to the raw mixture of cement substitutes bauxite and can create mortar cubes with a strength of design cement of, for example, 5,210 psi after 28 days. The chemical composition of cement produced from Claus-based spent catalysts and other raw materials are identical to the composition of cement from conventional raw materials.
According to an embodiment consistent with the present disclosure, a converter and a movable storage silo are used for processing and transporting spent catalysts, which can then be utilized as an additive. Alternatively, the spent catalyst can be used as a raw material. For example, spent catalyst can be used in the manufacture of cement instead of being disposed in landfills.
In one embodiment, a catalyst converter comprises a first layer of balls, a second layer of balls, and a conveyor belt. The first layer of balls is configured to retain from below spent catalyst resulting from operation of an industrial process. The second layer of balls is configured to retain from above the spent catalyst. The conveyor belt is configured to separate the spent catalyst from dust. The first layer of balls can include ceramic balls. The second layer of balls can include aluminum balls. The conveyor belt can include a wire mesh having a plurality of apertures configured to pass particles of the spent catalyst smaller than the apertures. The wire mesh can be composed of stainless steel.
In another embodiment, a system comprises a catalyst converter, a dust removal subsystem, and a movable silo. The catalyst converter includes a first layer of balls configured to retain from below spent catalyst resulting from operation of an industrial process. The catalyst converter also includes a second layer of balls configured to retain from above the spent catalyst. The catalyst converter further includes a conveyor belt configured to separate the spent catalyst from dust. The dust removal subsystem is configured to remove the dust from the spent catalyst. The movable silo is configured to receive and store the separated spent catalyst and further configured to be transportable by a vehicle. The first layer of balls can include ceramic balls. The second layer of balls can include aluminum balls. The conveyor belt can include a wire mesh having a plurality of apertures configured to pass particles of the spent catalyst smaller than the apertures. The wire mesh can be composed of stainless steel. The dust removal subsystem can include a pipe configured to transport the dust away from the movable silo. Alternatively, the dust removal subsystem can include a hydraulic subsystem configured to hydraulically transport the dust away from the movable silo.
In a further embodiment, a method comprises supplying, to a catalyst converter, spent catalyst resulting from operation of an industrial process, and then retaining the spent catalyst with at least one layer of balls. The method then transfers the spent catalyst to a conveyor belt, separates the spent catalyst using the conveyor belt, transfers the separated catalyst to a movable silo, removes dust during the transferring of the separated catalyst to the movable silo, and transports the movable silo. The retaining step can comprise first providing a first layer of the balls within the catalyst converter prior to supplying the spent catalyst to the catalyst converter so as to be disposed beneath the spent catalyst, and second providing a second layer of the balls to cover the spent catalyst within the catalyst converter. The layer of balls can include aluminum balls covering the spent catalyst. The layer of balls can include ceramic balls beneath the spent catalyst. The conveyor belt can include a wire mesh having a plurality of apertures configured to pass particles of the spent catalyst smaller than the apertures. The wire mesh can be composed of stainless steel.
Any combinations of the various embodiments and implementations disclosed herein can be used in a further embodiment, consistent with the disclosure. These and other aspects and features can be appreciated from the following description of certain embodiments presented herein in accordance with the disclosure and the accompanying drawings and claims.
It is noted that the drawings are illustrative and are not necessarily to scale.
Example embodiments consistent with the teachings included in the present disclosure are directed to a system and method using a catalytic converter and a movable storage silo for processing and transporting spent catalysts, which can then be utilized, for example, in the manufacture of cement instead of being disposed in landfills.
As shown in
In an example embodiment, the ceramic balls in the second layer 22 can have the characteristics described in Tables 1-2.
In addition, the characteristics of other materials are shown in Table 3.
The second layer 22 is positioned upon a mesh 24. The mesh 24 can be a wire mesh. The mesh 24 operates as a conveyor belt configured to transport the spent catalyst in the bed 20 to an external silo, as described below, as well as to separate the spent catalyst from dust and to separate different types of spent catalyst. In one embodiment, the mesh 24 is composed of stainless steel, which is not exposed to high temperatures or light. By using stainless steel, the mesh 24 has a high chromium content that forms an invisible layer on the stainless steel to prevent corrosion of the mesh 24.
The mesh 24 in the form of a conveyor belt separates different types of spent catalysts such as activated aluminum catalyst, super-Claus catalyst, and titanium catalyst from the ceramic balls of the second layer 22 and from dust. The conveyor belt is motorized in most embodiments and can operate as a function of whether there is catalyst to transport at any given time. Multiple meshes 24 can be used with each mesh having apertures of a specific size to hold materials of a larger size, such as the larger aluminum support balls and the ceramic support balls of the layers 18, 22, respectively. The apertures of each mesh 24 also enable materials of smaller sizes to pass through, such as particles of activated aluminum catalyst, super-Claus catalyst, and titanium catalyst, as well as dust.
The mesh 24 is positioned above a support layer 26. The support layer 26 can be a grating. The support layer 26 is mounted on a support structure 28 to position the support layer 26 and the other layers 18-24 above the bottom of the tank 12. The support layer 26 prevents any spent catalyst from migrating to the condenser through the conduit 16.
The catalyst converter 10 of
Referring to
The silo 50 receives the spent and separated catalyst from the converter 10 through the pipe 56. The pipe 56 can be fifteen inches in diameter, by way of example and not limitation. The pipe 56 is connected to a hydraulic sub-system 58 configured to remove dust from the spent catalyst from the converter 10 by pressurized air. The silo 50 can store, for example, on the order of 320 tons of spent catalyst.
In accordance with an important aspect of the present disclosure, the silo 50 is movable, and so the spent catalyst stored in the silo 50 can be transported to another location. For example, the spent catalyst can be delivered to a cement manufacturing plant. Referring to
Referring to
The method 500 transfers the separated catalyst to a movable silo 50 in step 550 using the conveyor belt 52, transfer mechanism 54, pipe 56, and a hydraulic sub-system 58 shown in
Portions of the methods described herein can be performed by software or firmware in machine readable form on a tangible (e.g., non-transitory) storage medium. For example, the software or firmware can be in the form of a computer program including computer program code adapted to cause the catalyst converter to perform various actions described herein when the program is run on a computer or suitable hardware device, and where the computer program can be embodied on a computer readable medium. Examples of tangible storage media include computer storage devices having computer-readable media such as disks, thumb drives, flash memory, and the like, and do not include propagated signals. Propagated signals can be present in a tangible storage media. The software can be suitable for execution on a parallel processor or a serial processor such that various actions described herein can be carried out in any suitable order, or simultaneously.
It is to be further understood that like or similar numerals in the drawings represent like or similar elements through the several figures, and that not all components or steps described and illustrated with reference to the figures are required for all embodiments or arrangements.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “contains”, “containing”, “includes”, “including,” “comprises”, and/or “comprising,” and variations thereof, when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
Terms of orientation are used herein merely for purposes of convention and referencing and are not to be construed as limiting. However, it is recognized these terms could be used with reference to an operator or user. Accordingly, no limitations are implied or to be inferred. In addition, the use of ordinal numbers (e.g., first, second, third) is for distinction and not counting. For example, the use of “third” does not imply there is a corresponding “first” or “second.” Also, the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of “including,” “comprising,” “having,” “containing,” “involving,” and variations thereof herein, is meant to encompass the items listed thereafter and equivalents thereof as well as additional items.
While the disclosure has described several exemplary embodiments, it will be understood by those skilled in the art that various changes can be made, and equivalents can be substituted for elements thereof, without departing from the spirit and scope of the invention. In addition, many modifications will be appreciated by those skilled in the art to adapt a particular instrument, situation, or material to embodiments of the disclosure without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiments disclosed, or to the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
The subject matter described above is provided by way of illustration only and should not be construed as limiting. Various modifications and changes can be made to the subject matter described herein without following the example embodiments and applications illustrated and described, and without departing from the true spirit and scope of the invention encompassed by the present disclosure, which is defined by the set of recitations in the following claims and by structures and functions or steps which are equivalent to these recitations.
