System and print head for continuously manufacturing composite structure

Information

  • Patent Grant
  • 11110654
  • Patent Number
    11,110,654
  • Date Filed
    Tuesday, February 19, 2019
    5 years ago
  • Date Issued
    Tuesday, September 7, 2021
    3 years ago
Abstract
A system is disclosed for use in additively manufacturing a composite structure. The system may include a head configured to discharge a continuous reinforcement. The system may further include an external applicator configured to apply a matrix to the discharged continuous reinforcement, and a cure enhancer configured to expose the matrix to a cure energy at a side of the external applicator opposite the head.
Description
TECHNICAL FIELD

The present disclosure relates generally to a manufacturing system and, more particularly, to a system and print head for continuously manufacturing composite structures.


BACKGROUND

Continuous fiber 3D printing (a.k.a., CF3D™) involves the use of continuous fibers embedded within a matrix discharging from a moveable print head. The matrix can be a traditional thermoplastic, a powdered metal, a liquid resin (e.g., a UV curable and/or two-part resin), or a combination of any of these and other known matrixes. Upon exiting the print head, a head-mounted cure enhancer (e.g., a UV light, an ultrasonic emitter, a heat source, a catalyst supply, etc.) is activated to initiate and/or complete curing of the matrix. This curing occurs almost immediately, allowing for unsupported structures to be fabricated in free space. When fibers, particularly continuous fibers, are embedded within the structure, a strength of the structure may be multiplied beyond the matrix-dependent strength. An example of this technology is disclosed in U.S. Pat. No. 9,511,543 that issued to Tyler on Dec. 6, 2016 (“the '543 patent”).


Although CF3D™ provides for increased strength, compared to manufacturing processes that do not utilize continuous fiber reinforcement, improvements can be made to the structure and/or operation of existing systems. The disclosed additive manufacturing system is uniquely configured to provide these improvements and/or to address other issues of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a system for additively manufacturing a composite structure. The system may include a head configured to discharge a continuous reinforcement. The system may further include an external applicator configured to apply a matrix to the discharged continuous reinforcement, and a cure enhancer configured to expose the matrix to a cure energy at a side of the external applicator opposite the head.


In another aspect, the present disclosure is directed to another system for additively manufacturing a composite structure. This system may include a head configured to discharge a matrix-wetted continuous reinforcement, and a primary cure enhancer configured to expose the matrix-wetted continuous reinforcement to a cure energy. The system may further include an external applicator configured to discharge additional matrix onto the matrix-wetted continuous reinforcement at a location downstream of the primary cure enhancer, and an auxiliary cure enhancer configured to expose the additional matrix to additional cure energy.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is diagrammatic illustration of an exemplary disclosed additive manufacturing system; and



FIGS. 2 and 3 are diagrammatic illustrations of exemplary disclosed print heads that may be used in conjunction with the additive manufacturing system of FIG. 1.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary system 10, which may be used to continuously manufacture composite structures 12 having any desired cross-sectional shape (e.g., circular, rectangular, or polygonal). System 10 may include at least a support 14 and a head 16. Head 16 may be coupled to and moved by support 14. In the disclosed embodiment of FIG. 1, support 14 is a robotic arm capable of moving head 16 in multiple directions during fabrication of structure 12, such that a resulting longitudinal axis (e.g., a trajectory) of structure 12 is three-dimensional. Support 14 may alternatively embody an overhead gantry or a hybrid gantry/arm also capable of moving head 16 in multiple directions during fabrication of structure 12. Although support 14 is shown as being capable of 6-axis movements, it is contemplated that any other type of support 14 capable of moving head 16 in the same or a different manner could also be utilized. In some embodiments, a drive may mechanically couple head 16 to support 14, and include components that cooperate to move portions of and/or supply power to head 16.


Head 16 may be configured to receive or otherwise contain a matrix material. The matrix material may include any type of matrix material (e.g., a liquid resin, such as a zero-volatile organic compound resin, a powdered metal, etc.) that is curable. Exemplary resins include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiol-enes, and more. In one embodiment, the matrix material inside head 16 may be pressurized, for example by an external device (e.g., by an extruder or another type of pump—not shown) that is fluidly connected to head 16 via a corresponding conduit (not shown). In another embodiment, however, the pressure may be generated completely inside of head 16 by a similar type of device. In yet other embodiments, the matrix material may be gravity-fed into and/or through head 16. For example, the matrix material may be fed into head 16, and pushed or pulled out of head 16 along with one or more continuous reinforcements. In some instances, the matrix material inside head 16 may need to be kept cool and/or dark in order to inhibit premature curing or otherwise obtain a desired rate of curing after discharge. In other instances, the matrix material may need to be kept warm for similar reasons. In either situation, head 16 may be specially configured (e.g., insulated, temperature-controlled, shielded, etc.) to provide for these needs.


The matrix material may be used to coat any number of continuous reinforcements (e.g., separate fibers, tows, rovings, socks, and/or sheets of continuous material) and, together with the reinforcements, make up a portion (e.g., a wall) of composite structure 12. The reinforcements may be stored within or otherwise passed through head 16. When multiple reinforcements are simultaneously used, the reinforcements may be of the same material composition and have the same sizing and cross-sectional shape (e.g., circular, square, rectangular, etc.), or a different material composition with different sizing and/or cross-sectional shapes. The reinforcements may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, optical tubes, etc. It should be noted that the term “reinforcement” is meant to encompass both structural and non-structural types of continuous materials that are at least partially encased in the matrix material discharging from head 16.


The reinforcements may be exposed to (e.g., at least partially coated with) the matrix material while the reinforcements are inside head 16, while the reinforcements are being passed to head 16, and/or while the reinforcements are discharging from head 16. The matrix material, dry reinforcements, and/or reinforcements that are already exposed to the matrix material may be transported into head 16 in any manner apparent to one skilled in the art. In some embodiments, a filler material (e.g., chopped fibers) may be mixed with the matrix material before and/or after the matrix material coats the continuous reinforcements.


One or more primary cure enhancers (e.g., a UV light, an ultrasonic emitter, a laser, a heater, a catalyst dispenser, a chiller, etc.) 18 may be mounted proximate (e.g., within, on, or adjacent) head 16 and configured to enhance a cure rate and/or quality of the matrix material as it is discharged from head 16. Cure enhancer 18 may be controlled to selectively expose portions of structure 12 to energy (e.g., UV light, electromagnetic radiation, vibrations, heat, a chemical catalyst, a chilled medium, etc.) during the formation of structure 12. The energy may increase a rate of chemical reaction occurring within the matrix material, sinter the material, harden the material, or otherwise cause the material to cure as it discharges from head 16. The amount of energy produced by cure enhancer 18 may be sufficient to cure the matrix material before structure 12 axially grows more than a predetermined length away from head 16. In one embodiment, structure 12 is completely cured before the axial growth length becomes equal to an external diameter of the matrix coated reinforcement.


The matrix material and/or reinforcement may be discharged from head 16 via at least two different modes of operation. In a first mode of operation, the matrix material and/or reinforcement are extruded (e.g., pushed under pressure and/or mechanical force) from head 16 as head 16 is moved by support 14 to create the 3-dimensional trajectory within a longitudinal axis of structure 12. In a second mode of operation, at least the reinforcement is pulled from head 16, such that a tensile stress is created in the reinforcement during discharge. In this mode of operation, the matrix material may cling to the reinforcement and thereby also be pulled from head 16 along with the reinforcement, and/or the matrix material may be discharged from head 16 under pressure along with the pulled reinforcement. In the second mode of operation, where the matrix material is being pulled from head 16 with the reinforcement, the resulting tension in the reinforcement may increase a strength of structure 12 (e.g., by aligning the reinforcements, inhibiting buckling, equally distributing loads, etc.), while also allowing for a greater length of unsupported structure 12 to have a straighter trajectory. That is, the tension in the reinforcement remaining after curing of the matrix material may act against the force of gravity (e.g., directly and/or indirectly by creating moments that oppose gravity) to provide support for structure 12.


The reinforcement may be pulled from head 16 as a result of head 16 moving away from an anchor point 20. In particular, at the start of structure formation, a length of matrix-impregnated reinforcement may be pulled and/or pushed from head 16, deposited onto anchor point 20, and cured such that the discharged material adheres (or is otherwise coupled) to anchor point 20. Thereafter, head 16 may be moved away from anchor point 20, and the relative movement may cause the reinforcement to be pulled from head 16. It should be noted that the movement of reinforcement through head 16 could be assisted (e.g., via internal head mechanisms), if desired. However, the discharge rate of reinforcement from head 16 may primarily be the result of relative movement between head 16 and anchor point 20, such that tension is created within the reinforcement. It is contemplated that anchor point 20 could be moved away from head 16 instead of or in addition to head 16 being moved away from anchor point 20.


A controller 22 may be provided and communicatively coupled with support 14, head 16, and any number of cure enhancers 18. Each controller 22 may embody a single processor or multiple processors that are configured to control an operation of system 10. Controller 22 may include one or more general or special purpose processors or microprocessors. Controller 22 may further include or be associated with a memory for storing data such as, for example, design limits, performance characteristics, operational instructions, tool paths, and corresponding parameters of each component of system 10. Various other known circuits may be associated with controller 22, including power supply circuitry, signal-conditioning circuitry, solenoid driver circuitry, communication circuitry, and other appropriate circuitry. Moreover, controller 22 may be capable of communicating with other components of system 10 via wired and/or wireless transmission.


One or more maps may be stored in the memory of controller 22 and used during fabrication of structure 12. Each of these maps may include a collection of data in the form of lookup tables, graphs, and/or equations. In the disclosed embodiment, the maps may be used by controller 22 to determine the movements of head 16 required to produce the desired size, shape, and/or contour of structure 12, and to regulate operation of cure enhancers 18 in coordination with the movements.


As shown in FIG. 2, head 16 may be an assembly of multiple components that cooperate to discharge matrix-coated reinforcements (shown as R+M in FIG. 2). These components may include, among other things, a matrix reservoir 24 and a nozzle 26 that communicates with an internal volume of matrix reservoir 24 via a central (e.g., tapered) opening 28. The internal volume of matrix reservoir 24 may hold a finite supply of matrix that is sufficient to fully wet reinforcements passing therethrough at a specified (e.g., maximum) travel rate. In the depicted example, nozzle 26 is single-path nozzle configured to discharge composite material having a generally circular or rectangular cross-section. The configuration of head 16, however, may allow nozzle 26 to be swapped out for another nozzle (not shown) that discharges composite material having a different shape (e.g., a ribbon- or sheet-like cross-section).


Cure enhancer(s) 18 may be mounted at the discharge end of matrix reservoir 24 and adjacent (e.g., at a trailing side of or around) nozzle 26. Different exemplary embodiments of cure enhancers 18 are shown in FIGS. 2 and 3. In the embodiment of FIG. 2, cure enhancer 18 includes, among other things, an energy source 30, a modifier 32, and one or more transmitters 34 that extend from energy source 30 to modifier 32. Cure energy may be generated by energy source 30 and directed via transmitter(s) 34 to modifier 32. Modifier 32 may then modify the energy in any number of different ways, prior to the energy reaching the matrix within the discharging material of structure 12.


Energy source 30 may be located remotely from modifier 32. In one embodiment, energy source 30 is a UV generator mounted to head 16 (e.g., to a side, top, and/or bottom of matrix reservoir 24). It is contemplated, however, that energy source 30 could be an ultrasonic generator, an infrared heat generator, a microwave generator, a laser generator, or another type of energy generator that is mounted to head 16. It is further contemplated that energy source 30 could alternatively be mounted to support 14 and/or to an enclosure in which support 14 and/or head 16 is located, if desired. It is contemplated that, in an alternative embodiment, energy source 30 could be a negative source (e.g., configured to chill the resin), if desired.


Modifier 32 may be configured to amplify, diffuse, focus, reflect, aim, and/or otherwise condition the energy generated by energy source 30. In the embodiment of FIG. 2, modifier 32 is a diffuser configured to evenly distribute the energy from energy source 30 around a tip end of nozzle 26. As a diffuser, modifier 32 may include a hemi-toroidally shaped body having a generally reflective inner surface 36 and a generally opaque outer surface 38. The body of modifier 32 may at least partially (e.g., completely) surround nozzle 26, and include one or more energy entrance(s) 40 through which energy is received and one or more (e.g., a single) energy outlet(s) 42 through which energy is discharged. In the disclosed embodiment, energy entrance(s) 40 may be circular openings or transparent surfaces at which transmitter(s) 34 terminate. In some applications, baffles, lenses, prisms, filters, and/or other similar devices may be situated within energy entrance(s) 40 to help condition the energy within the body of modifier 32. Energy outlet(s) 42 may be generally ring-shaped, and oriented generally orthogonal to (or tilted inward or outward relative to) an axis of nozzle 26. It is contemplated that baffles, lenses, prisms, filters, and/or other similar devices may be situated within energy outlet(s) 42, if desired. In addition, modifier 32 could, itself, be an optic. In this example transmitters 34 may channel UV light into the back of the optic, and the optic may both amplify and diffuse the light into a cone.


Transmitters 34 may be configured to transmit energy from energy source 30 into modifier 32. In the disclosed embodiment, transmitters 34 are flexible light pipes (e.g., optical tubes) that are configured to transmit UV light. It is contemplated, however that other types of transmitters 34 (acoustic pipes, electronic and/or magnetic transmission lines, etc.) may be used, if desired.


In one embodiment, a position and/or orientation of modifier 32 may be selectively adjusted. For example, an axial location and/or tilt angle of energy outlet(s) 42 may be varied with respect to a tip end and/or an axis of nozzle 26. In one example, an actuator (e.g., a lead screw 44 and motor 46) may be connected to the body of modifier 32 and selectively activated by controller 22 (referring to FIG. 1) to cause the body to be raised, lowered, and/or tilted. Any type of actuator (e.g., an electric rotary actuator, a pneumatic linear actuator, a hydraulic link, etc.) may be disposed between modifier 32 and any other component of head 16 to cause desired movements of modifier 32.


A simpler embodiment of cure enhancer 18 is illustrated in FIG. 3. In this embodiment, cure enhancer 18 includes one or more energy discharging devices (e.g., UV lights) that are mounted to head 16 (e.g., directly to a lower end of matrix reservoir 24) at a trailing side of nozzle 26. In the example of FIG. 3, a compactor 48 is located between cure enhancer 18 and nozzle 26. It is contemplated that compactor 48 could be used in conjunction with the embodiment of FIG. 2 as well, if desired.


In some embodiments, head 16 may additionally include an external matrix applicator 50 and an auxiliary cure enhancer 52 that trails behind external matrix applicator 50. With this arrangement, matrix (e.g., all of the matrix or only supplemental matrix) may be applied by applicator 50 after the reinforcement (e.g. dry reinforcement, fully wetted reinforcement, and/or partially wetted reinforcement) has been discharged from nozzle 26. And auxiliary cure enhancer 52 may be used to at least partially cure the additional matrix discharged by applicator 50.


In the disclosed embodiment, matrix applicator 50 is a spray-type applicator (e.g., a jet) that is configured to spray matrix onto an outer surface of the already-deposited reinforcement. It is contemplated, however, that another type of applicator (e.g., a drip-type applicator, a brush-type applicator, a roller-type applicator, etc.—not shown) could alternatively be used, if desired. In one example, matrix applicator 50 is connected to receive matrix from reservoir 24 (e.g., via an internal passage 54). In another example (not shown), the matrix could additionally or alternatively be received from another location (e.g., from an offboard pump or reservoir) via an external passage (not shown). The matrix may be pressurized prior to receipt by applicator 50, pressurized by applicator 50 itself (e.g., via internal pistons, turbines, or other mechanical devices), and/or pressurized by another source (e.g., by air also directed into applicator 50).


Auxiliary cure enhancer 52 may be located downstream of matrix applicator 50, relative to a travel direction of head 16. In some embodiments, auxiliary cure enhancer 52 may be configured to move (e.g., to pivot around nozzle 26) in order to maintain this relationship during cornering by head 16. For example, auxiliary cure enhancer 52 may be mounted to an arm 56, and an actuator 58 (e.g., a rotary actuator such as a channel-mounted motor or gear train) may connect arm 56 to head 16. Controller 22 (referring to FIG. 1) may selectively enable (e.g., energize or unlock) actuator 58 to cause corresponding rotation of auxiliary cure enhancer 52. Auxiliary cure enhancer 52 may include one or more energy sources (e.g., UV lights, acoustic generators, heaters, microwave generators, lasers, etc.) 60 that are at least partially enclosed within a hood 62. Hood 62 may flare outward and extend downstream to reflect energy from energy source(s) 60 inward toward structure 12, such that premature curing of the matrix being sprayed by applicator 50 is avoided. It is contemplated that hood 62 could be omitted, if desired. Like primary cure enhancer 30, it is contemplated that in an alternative embodiment, auxiliary cure enhancer 52 could be a source of negative energy, if desired.


Matrix applicator 50 may be configured to discharge matrix against the outer surface of structure 12 (e.g., the uncured, cured, or partially cured surface), such that the matrix fills voids within and/or sticks to the surfaces of structure 12. In one embodiment, a squeegee 64 may be associated with applicator 50 and/or auxiliary cure enhancer 52 and configured to wipe over and thereby smooth out the applied matrix prior to energy exposure by energy source(s) 60. Squeegee 64 may screed the liquid matrix into a smooth layer having a consistent thickness (e.g., within engineering tolerances). It is contemplated that squeegee 64 may have a width about the same as a width of material being discharged from nozzle 26, or a greater width such that multiple adjacent tracks of material (e.g., the discharging track and one or more previously discharged tracks) are wiped over by squeegee 64.


In some embodiments, care may be taken to ensure that the matrix discharged by applicator 50 is not cured (e.g., by enhancer(s) 18) prematurely (e.g., before being wiped over by squeegee 64). In these embodiments, a shadowing mechanism (e.g., a curtain) 66 may be placed at a transition location between cure enhancer(s) 18 and applicator 50.


INDUSTRIAL APPLICABILITY

The disclosed systems may be used to continuously manufacture composite structures having any desired cross-sectional shape and length. The composite structures may include any number of different fibers of the same or different types and of the same or different diameters, and any number of different matrixes of the same or different makeup. Operation of system 10 will now be described in detail.


At a start of a manufacturing event, information regarding a desired structure 12 may be loaded into system 10 (e.g., into controller 22 that is responsible for regulating operations of support 14 and/or head 16). This information may include, among other things, a size (e.g., diameter, wall thickness, length, etc.), a contour (e.g., a trajectory), surface features (e.g., ridge size, location, thickness, length; flange size, location, thickness, length; etc.), connection geometry (e.g., locations and sizes of couplings, tees, splices, etc.), desired surface textures, texture locations, etc. It should be noted that this information may alternatively or additionally be loaded into system 10 at different times and/or continuously during the manufacturing event, if desired. Based on the component information, one or more different reinforcements and/or matrix materials may be selectively installed and/or continuously supplied into system 10. In some embodiments, the reinforcements may also need to be connected to a pulling machine (not shown) and/or to a mounting fixture (e.g., to an anchor point). Installation of the matrix material may include filling head 16 and/or coupling of an extruder (not shown) to head 16.


The component information may then be used to control operation of system 10. For example, the reinforcements may be pulled and/or pushed along with the matrix material from head 16. Support 14 may also selectively move head 16 and/or anchor point 20 in a desired manner, such that an axis of the resulting structure 12 follows a desired three-dimensional trajectory. Once structure 12 has grown to a desired length, structure 12 may be severed from system 10.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed systems. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed system. For example, it is contemplated that the matrix discharged by applicator 50 may be the same matrix as or different from the matrix passing through nozzle 26. It is also contemplated that squeegee 64 could be replaced with another device (e.g., gas jets) that function in similar manner to smooth out the surface matrix. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A system for additively manufacturing a composite structure, comprising: a nozzle configured to discharge a continuous reinforcement;an external applicator operatively attached to the nozzle and configured to move with the nozzle and apply a matrix to the continuous reinforcement during discharging of the continuous reinforcement from the nozzle; anda cure enhancer operatively attached to the nozzle and configured to expose the matrix to a cure energy at a side of the external applicator opposite the nozzle to harden the matrix,wherein the cure enhancer includes: an energy source;a modifier located remotely from the energy source; and at least one transmitter extending from the energy source to the modifier; andwherein the modifier at least partially encircles the nozzle.
  • 2. The system of claim 1, wherein the modifier is a hemi-toroidally shaped body.
  • 3. The system of claim 1, further including an actuator configured to adjust at least one of a position and an orientation of the modifier.
RELATED APPLICATIONS

This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/656,866 that was filed on Apr. 12, 2018, the contents of which are expressly incorporated herein by reference.

US Referenced Citations (182)
Number Name Date Kind
3286305 Seckel Nov 1966 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5746967 Hoy et al. May 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6799081 Hale et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7555404 Brennan et al. Jun 2009 B2
7795349 Bredt et al. Sep 2010 B2
8221669 Batchelder et al. Jul 2012 B2
8962717 Roth et al. Feb 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9527248 Hollander Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080176092 Owens Jul 2008 A1
20080317894 Turley Dec 2008 A1
20090095410 Oldani Apr 2009 A1
20110032301 Fienup et al. Feb 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140034214 Boyer et al. Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20150165691 Mark Jun 2015 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans et al. Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170106594 Gardiner Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waatti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
20180201021 Beaver Jul 2018 A1
20190202000 Di Domenico Jul 2019 A1
Foreign Referenced Citations (30)
Number Date Country
106863772 Jun 2017 CN
4102257 Jul 1992 DE
2589481 Jan 2016 EP
3219474 Sep 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2013017284 Feb 2013 WO
2015139095 Sep 2015 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (13)
Entry
International Search Report dated May 29, 2019 for PCT/US2019/018973 to CC3D LLC Filed Feb. 21, 2019.
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-805 (May 15, 2012).
Related Publications (1)
Number Date Country
20190315054 A1 Oct 2019 US
Provisional Applications (1)
Number Date Country
62656866 Apr 2018 US