Patent Application
20080038173
For the purpose of illustrating the invention, the drawings show a form of the invention that is presently preferred. However it should be understood that the present invention is not limited to the precise arrangements and instrumentalities shown in the drawings, wherein:
The present invention includes a process and system for cleaning a flue gas stream produced by a combuster, e.g., a boiler. The process also includes neutralizing and circulating wash water discharged from a particle collection device, which is operatively connected to a WFGD system.
Referring now to
Flue gas stream 10 also travels through a particle collection device 18 that removes particles from the flue gas stream by using electric forces. Particle collection device 18 is typically a wet electrostatic precipitator (wet ESP), which is a self-washing, self-cleaning device that utilizes a liquid, referred to as “wash water,” to clean the collector surfaces 19 and other internal structures of the wet ESP. In most systems, the wash water is added as fresh wash water 20, which is added to particle collection device 18 via a conduit, such as pipework, that connects a water holding tank 22 to the particle collection device.
Particle collection device 18 is in fluid communication with a stack 24, which emits flue gas stream 10 into the atmosphere. Particle collection device 18 is also in fluid communication with a water recirculation tank 26.
Typically, water recirculation tank 26 is downstream of particle collection device 18 and is in communication with the particle collection device either by means of ducts or pipes made of metal or any other material that permits an acidified wash water 28 to flow from the particle collection device to the water recirculation tank. Acidified wash water 28 is the resulting liquid that was used to clean collecting surfaces 19 and internal structures of particle collection device 18. Acidified wash water 28 typically contains water, gypsum particles, fly ash particles, chloride ions and other constituents typically found in treated or fresh water supply sources.
Prior to, or upon entering water recirculation tank 26, the pH of acidified wash water 28 may be measured. Since acidified wash water 28 is neutralized by a neutralizing material 30 in water recirculation tank 26, measurement of the pH will allow for a more effective neutralization of the acidified wash water.
As shown in
Neutralizing material 30 is made in mix tank 32 and typically contains an alkaline material 35 and a water 40. Alkaline material 35 may be any alkaline material such as lime, limestone, magnesium, sodium, or a mixture thereof. Alkaline material 35 may be in any form suitable for use in a flue gas stream cleaning system. For example, alkaline material 35 may be in the form of a powder. Typically, alkaline material 35 is discharged from a neutralizing material tank 36 and combined with water 40 in mix tank 32, thereby forming neutralizing material 30. Neutralizing material 30 neutralizes, i.e., increases the pH, of the acidified wash water 28. Alternatively, as indicated by the dashed line in
The basic ions in alkaline material 35 or neutralizing material 30, will combine with acidic species present in acidified wash water 28, such as: sulphuric acid, sulphurous acid, hydrochloric acid, and hydrofluoric acid to form stable, water-soluble compounds.
Still referring to
Neutralizing material 30 is typically added to water recirculation tank 26 on a continuous basis in an amount effective to achieve a neutral or slightly acidic (i.e., between about 5-7 pH) wash water 38 in the water recirculation tank.
A control valve 48 or other control device such as a valve, gauge, lever, and the like, may be arranged between mix tank 32 and water recirculation tank 26. The control valve may be connected to a pH instrument located within water recirculation tank 26. Optionally, a monitoring device 50 may also be placed between mix tank 32 and water recirculation tank 26 to allow a user to monitor the amount of a neutralization material 30 sent to the recirculation tank.
Monitoring device 50 allows a user to monitor the amount of neutralizing material 30 transported to water recirculation tank 26. Monitoring device 50 may be a meter, a computer or any other instrument that allows a user to monitor the amount of neutralizing material 30.
Still referring to
Referring now to
One way system and process 120 differs from system and process 2 of
Still referring to
Now referring to
Next, at step 82, the pH of acidified wash water 28 may be measured. Measurement of the pH can occur anytime after the acidified wash water has passed through particle collection device 18. Here, it is shown that the measurement occurs after wash water 28 has been discharged from particle collection device 18.
After the pH has been measured, neutralizing material 30 or alkaline material 35 is added to acidified wash water 28 in step 84. Addition of neutralizing material 30 or alkaline material 35 neutralizes at least a portion of acidified wash water 28. Typically, the amount of neutralizing material 30 or alkaline material 35 added to acidified wash water 28 is effective to neutralize most of the acid present in the acidified wash water.
Then, in step 86, neutralized wash water 38 is produced after the neutralizing material 30 or alkaline material 35 is added to acidified wash water 28. Next, as shown in step 88, neutralized wash water 38 may then be circulated to various locations throughout flue gas cleaning systems 2 and 120.
Systems 2 and 120 allow water purged from the flue gas cleaning system to come from one source, namely a discharge stream from particle collection device 18. Accordingly, the interface between the plant's waste water treatment plant and the wet ESP/WFGD systems is simplified since only one feed line would be required between the systems.
The neutralization of the acidic wash water is important to reduce cost of the internal equipment used in a particle collection device such as a wet ESP. Generally, the overall structure and internal equipment of the wet ESP must be constructed of material resistant to the highly acidic conditions within the wet ESP. Typically these materials are higher grade alloys like C22 and C276, which are orders of magnitude more expensive than traditional carbon steel or even stainless steel. The present invention allows the wet ESP components, equipment, and surfaces exposed to the flue gas and wash water streams to be constructed of lower grade materials, with stainless steel being the most preferable choice. It has been found that the capital cost of the wet ESP can be reduced by a factor of three when the lower grade materials are used. However, the invention also contemplates retrofitting existing wet ESP systems with the mixing tank and recirculation tank to extend the life of the structures, equipment, and surfaces of the wet ESP systems.
The present invention offers advantages over prior art systems. For instance, the present invention is inexpensive, not time-consuming, and is easily retrofitted in already existing systems. Additionally, the present invention advantageously allows the control of dissolved and suspended solids sent to a waste water treatment plant. Instead of sending these solids to the waste water treatment plant where it is costly to remove them, the solids are removed via the wet FGD equipment (i.e., gypsum dewatering filters) at no additional expense.
As shown in
One or more embodiments of the present invention have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention. Accordingly, other embodiments are within the scope of the following claims.
