The present invention relates to wood pulping processes and more particularly to wood pulping processes including processes for concentrating pulping liquor.
This invention relates to a system and process for pulping wood which produces a wastewater stream (herein referred to as pulping effluent or liquor). The wastewater from the pulping process is directed to a pre-concentration unit. In one embodiment, the pre-concentration unit comprises one or more mechanical vapor recompression (MVR) evaporators. These evaporators concentrate the liquor to where, in one example, the solids content is approximately 15-20%. The concentrated liquor is directed to a multi-effect train that comprises a series of forced circulation solids concentrators. The concentrated liquor is heated and further concentrated in the multi-effect train, in one embodiment, to where the solids content is approximately 60-70%. The evaporators and multi-effect train is linked by a gas stripper. Contaminated condensate produced by the evaporators is directed downwardly through the gas stripper. Steam is injected into the gas stripper and strips gases such as methanol and other volatile organics from the contaminated condensate. This produces a vapor stream that is contaminated by these gases and which exits the gas stripper. This contaminated vapor stream is directed to one of the effects and the thermal energy associated therewith is utilized to heat the concentrated liquor flowing through the thermal effects and particularly a series of forced circulation solids concentrators that form the multiple effect train.
Thus, it is appreciated that in the case of a multi-effect train having three forced circulation solids concentrators, for example, the use of the contaminated vapor stream produced by the gas stripper enhances steam economy by effectively increasing the thermal effects from three to four.
Other objects and advantages of the present invention will become apparent and obvious from a study of the following description and the accompanying drawings which are merely illustrative of such invention.
The present invention relates to a wood pulping process comprising a wood pulping unit and process, a system and process for concentrating a pulping effluent or liquor produced by the pulping process, and an incinerator or boiler for burning the concentrated liquor produced by the pulping process.
As seen in
The basic system and process of the present invention entails a pre-concentrating process followed by a succeeding or second concentrating process. In the pre-concentrating process, the dry solids content of the liquor is increased from approximately 1.5% DS to 15-20% DS. This forms what is referred to herein as concentrated liquor. The concentrated liquor is then directed to the second concentrating process which converts the concentrated liquor having approximately 15-20% DS to a highly concentrated liquor having 60-70% DS. The term “highly concentrated liquor” is a relative term, a term whose meaning is relative to the term “concentrated liquor” produced in the pre-concentrating processes. That is, “highly concentrated liquor” means that the dry solids content of the highly concentrated liquor is greater than the dry solids content of the “concentrated liquor”.
In the pre-concentrating process, to be described in greater detail below, not only is concentrated liquor produced but the process also produces a contaminated or foul condensate, as well as a non-contaminated condensate. The term “non-contaminated condensate” is also a relative term that means that this particular condensate is less contaminated than the contaminated condensate.
The pre-concentrating process and the second concentrating process are linked by a gas stripper whose function is to treat contaminated condensates. The contaminated condensates, for example, are directed downwardly through the gas stripper and steam is injected into a lower portion of the stripper and rises up through the stripper, stripping contaminants, particularly gases such as methanol and volatile organics, from the contaminated condensates. Thus, a contaminated vapor stream is produced in the gas stripper. This contaminated gas stream includes substantial thermal energy and is directed to the second concentrating process where the thermal energy associated with the contaminated vapor stream is utilized to power the second liquor concentrating process. As will be discussed later, in one embodiment the second concentrating process is carried out by a multi-effect train of forced circulation solids concentrators. The thermal energy of the contaminated vapor stream produced by the gas stripper is utilized to power the forced circulation solids concentrators that form the multi-effect train.
Turning now to
In addition to the concentrated liquor, the pre-concentration system 16 produces a clean or non-contaminated condensate that is directed from the pre-concentration system via line 18 through the pre-heater 16. Since the clean condensate is relatively hot, it effectively heats the liquor passing from the wood pulping unit 10 to the pre-concentration system 16. After passing through the pre-heater 14, the clean condensate is directed through line 20 to the pulp mill for further use. Pre-concentration system 16 also produces a contaminated or foul condensate that is directed from the pre-concentration system 16 to a gas stripping unit 50 that will be subsequently discussed in detail.
Concentrated liquor produced by the pre-concentration system 16 is directed to a final or second concentration system indicated generally by the numeral 30. The function of the second concentration system 30 is to substantially concentrate the concentrated liquor produced by the pre-concentration system 16. As will be discussed subsequently herein, in one embodiment the concentrated liquor produced by the pre-concentration system 16 has a dry solids content (by weight) of approximately 15% to approximately 20%. The second concentration system 30, in one embodiment, is designed to further concentrate the concentrated liquor to a dry solids content of approximately 60% to 70%. At this concentration, the liquor can be burned in an incinerator or boiler.
Referring to the second concentration system 30 in more detail, in one embodiment, the system comprises a multi-effect train comprised of three forced circulation solids concentrators referred to generally by the numerals 32, 34 and 36. Forced circulation solids concentrator 32 forms a first effect, forced circulation solids concentrator 34 forms a second effect and forced circulation solids concentrator 36 forms a third effect. These forced circulation solids concentrators include vapor bodies denoted VB 1, VB 2 and VB 3. Further, they include heat exchangers HE 1, HE 2 and HE 3. Finally, the forced circulation solids concentrators include recirculation pumps identified by the numerals 42, 44 and 46.
Pre-concentration system 16 and the second concentration system 30 are linked by the gas stripper 50. Gas stripper 50 functions to remove contaminants from the contaminated condensate produced by the pre-concentrating system 16 and the resulting vapor stream is utilized to supply thermal energy for driving the second concentration system 30.
As shown in
Steam generated by the re-boiler 66 moves up through the gas stripper 50 and out an upper vent therein. This results in a contaminated vapor stream that includes substantial thermal energy. In one embodiment, there is sufficient thermal energy in the contaminated vapor stream to substantially drive the forced circulation solids concentrators 32, 34 and 36, discussed above. To utilize this thermal energy, the contaminated vapor stream is directed from the gas stripper 50 via line 70 to heat exchanger HE 1 associated with the first forced circulation solids concentrator 32. The contaminated vapor stream enters HE 1 and heats concentrated liquor passing therethrough. There is substantial thermal energy associated with the contaminated vapor stream directed through HE 1 and this vaporizes water in the concentrated liquor, producing additional vapor and further concentrating the liquor passing through HE 1. The contaminated vapor stream entering HE 1 condenses and forms another condensate that may also be contaminated with COD and this contaminated condensate is directed from HE 1 via line 72 into an upper portion of the gas stripper 50 where the contaminated condensate from HE 1 combines with the contaminated condensate produced by the pre-concentration system 16. Thus, the two contaminated condensates combine in the gas stripper 50 and descend through the uprising steam where the steam removes gases from both.
Energy associated with the contaminated vapor stream produces additional vapor that is collected in VB 1 of the first forced circulation solids concentrator 32. Vapor collected in VB 1 is sometimes referred to as a secondary vapor stream. It is used to power the second effect or the second forced circulation solids concentrator 34. As seen in
Thus, it is seen that the thermal energy associated with the contaminated vapor stream exiting the gas stripper 50 is utilized to drive the multi-effect train of forced circulation solids concentrators and to further concentrate the pre-concentrated liquor produced by the pre-concentration system 16.
To further concentrate the liquor in line 84, the liquor is directed into a pair of flash tanks 86. There is significant thermal energy associated with the concentrated liquor in line 84 and, hence, upon reaching the flash tanks 86, some of the liquor flashes into steam. Steam in the first flash tank is directed into HE 2 and supplements the heat energy supplied by the secondary vapor stream in line 74. Steam in the second flash tank is directed to HE 3 and supplements the heat energy supplied by the secondary vapor stream in line 76.
From the flash tanks 86, the concentrated liquor is directed to the third or final effect, the forced circulation solids concentrator 36. The concentrated liquor is continuously circulated by the pump 46 through the heat exchanger HE 3 and vapor body VB 3. Because water in the concentrated liquor is continuously vaporized, it follows that the concentrated liquor is further concentrated in this third effect. Portions of the concentrated liquor is bled from the third effect and directed to the second effect or the second forced circulation solids concentrator 34. There the pump 46 continuously circulates the concentrated liquor through HE 2 to VB 2 and back to the pump. Like in the third effect, the second effect continues to concentrate the concentrated liquor being circulated through the second effect. A portion of the concentrated liquor is bled from that being circulated in the second effect 34 and is directed to the first effect 32. There the concentrated liquor is pumped by pump 42 through heat exchanger HE 1 and through VB 1 and back to the pump. This circulation of the concentrated liquor and its exposure to the thermal energy in the heat exchanger HE 1 further concentrates the concentrated liquor being circulated through the first forced circulation solids concentrator 32. Heat exchanger HE 1 includes a vapor vent for venting vapor therefrom. This vapor vent is connected to line 91. This vapor is typically concentrated with methanol and other volatile compounds and can be directed to a trim condenser. The vapor from the trim condenser is considered as stripped of gas (SOG) and is sent outside the battery limits of the pulp plant. Heat exchanger HE 1 also includes a liquor outlet that is connected to line 90. Liquor exiting HE 1 is highly concentrated. As noted before, in one embodiment, this liquor has a dry solids content on the order of 60-70%. This highly concentrated liquor is sufficiently concentrated that it can be economically and practically disposed of through incineration. In the case of the embodiment illustrated herein, the highly concentrated liquor in line 90 is directed to an incinerator or boiler 22.
As discussed with the embodiment shown in
As viewed in
Continuing to refer to
Continuing to refer to
In one embodiment, the forced circulation solids concentrators 32, 34 and 36 are designed to enhance heat transfer to the liquor passing through the tubes of the heat exchangers HE 1, HE 2 and HE3. This is achieved by inserting what is termed enhancers in the heat exchanger tubes. In one embodiment, a spiral-shaped element is inserted into each heat exchanger tube for the purpose of inducing a spiral flow path within the tube. Thus, the liquor entering the respective heat exchanger tubes moves through the tubes in a generally spiral path. It is generally accepted that streams having laminar flow characteristics can have lower heating rates than streams having turbulent flow characteristics because of a difference in temperature gradient. Thus, it is postulated that a more efficient heat transfer can be achieved by inducing the liquor to flow in a spiral path as the liquor moves through the respective tubes of the heat exchangers HE 1, HE 2 and HE 3.
It should be noted that the steam stripping process and resulting vapor stream effectively form a fourth thermal stage with the other three thermal stages being formed by the forced circulation solids concentrators 32, 34 and 36. Here the stripping system can be viewed as the first thermal stage with the forced circulation solids concentrators 32, 34 and 36 being viewed as the second, third and fourth thermal stages.
The overall system and process of the present invention is performed in a manner that is designed to avoid or at least reduce high temperatures that increase the scaling potential due in substantial part to the inverse solubility of salts. Another consideration in the design of a wood pulping process such as disclosed herein relates to the suspended solids in the liquor feed. For example, compared to a conventional Kraft liquor, the concentration factor for mechanical pulp effluent, for example, is much higher. In a Kraft liquor, for example, the concentration factor may be on the order of approximately 4.5 where in processes similar to that disclosed herein the concentration factor could be 40 or higher. This means that for a similar suspended solids content in the feed liquor, as the liquor becomes more concentrated, the concentration of suspended solids will increase much more in a process such as described here than in a conventional Kraft process. Therefore, in one embodiment of the present invention, the aim is to use an evaporator technology to concentrate the liquor up to approximately 15% to approximately 20% DS and then a shift the process to a forced circulation technology embodied in a multi-effect train.
The present invention may, of course, be carried out in other ways than those specifically set forth herein without departing from essential characteristics of the invention. The present embodiments are to be considered in all respects as illustrative and not restrictive, and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.
Filing Document | Filing Date | Country | Kind |
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PCT/US2014/033733 | 4/11/2014 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2015/156814 | 10/15/2015 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3807479 | Brannland et al. | Apr 1974 | A |
5989394 | Johansson et al. | Nov 1999 | A |
6258206 | Olausson et al. | Jul 2001 | B1 |
8992729 | Berg et al. | Mar 2015 | B2 |
20040107597 | Hirvonen | Jun 2004 | A1 |
20050098037 | Dietrich et al. | May 2005 | A1 |
Number | Date | Country |
---|---|---|
3120586 | May 1982 | DE |
0474659 | Aug 1993 | EP |
S4861701 | Aug 1973 | JP |
S52144401 | Dec 1977 | JP |
9623566 | Aug 1996 | WO |
9716592 | May 1997 | WO |
2012012734 | Jan 2012 | WO |
2012052619 | Apr 2012 | WO |
2013144438 | Oct 2013 | WO |
Entry |
---|
Gullichsen editor, Chemical Pulping 6B, 1999, Fapet Oy, chapter 12. |
Patel Jean-Claude, Black Liquor Evaporation:Design and Operation; Jan. 2008, TAPPI Kraft Recovery Course. |
Lin Ben, The Basics of Foul Condensate Stripping, Jan. 2008, TAPPI Kraft Recovery Course. |
Number | Date | Country | |
---|---|---|---|
20170030018 A1 | Feb 2017 | US |