The present invention relates to systems and methods for removing ammonium from leachate, industrial and other wastewater streams.
A number of biofilm wastewater treatment processes can be used to remove contaminants from wastewater. One such process is referred to as a moving bed biofilm reactor (MBBR) process. MBBR processes are considered biofilm only processes with continuous flow in a completely mixed reactor. MBBR systems include an aeration tank. Contained in the aeration tank is an array of plastic biofilm carriers that support the biofilm used to treat the wastewater passing through the aeration tank. The biofilm carriers can float or in some cases may sink when not being mixed. In the course of treating wastewater, the biofilm on the carriers contacts the wastewater and a biological process ensues. There are numerous advantages to MBBR processes. Principally these advantages include ease of operation and robustness.
Similar in some respects to an MBBR process is what is referred to as an integrated fixed film activated sludge (IFAS) process. It too is a continuous flow process and entails biofilm carriers for supporting some biomass. The IFAS process, however, also includes suspended biomass. Because of the suspended biomass and the continuous flow, it is common to employ an external clarifier downstream from the aeration tank to recover the suspended biomass and recycle it to the aeration tank.
It is also possible to operate an IFAS reactor as a sequencing batch reactor. This is known as an IFAS SBR process. This process, contrasted with the MBBR and IFAS processes, is a non-continuous process. Instead, wastewater is treated in a sequence of steps including filling, aeration and mixing, followed by settling which in turn is followed by decanting. Decanting is usually provided by one or more floating decanters that reside on the surface of the water in the IFAS SBR reactor.
Many wastewaters contain ammonium-nitrogen (NH4—N) (referred to herein as ammonium). To meet various regulatory limits, the ammonium must be removed from the wastewater before the wastewater is discharged. The conventional approach employs a two-step biological process referred to as a nitrification and denitrification process.
In recent years it has been discovered that ammonium in certain waste streams such as anaerobic sludge digester dewatering liquid (found in a side stream) can be removed by utilizing different bacteria from those normally associated with conventional nitrification-denitrification. In this case, a typical process combines aerobic nitritation and an anaerobic ammonium oxidation (anammox). In the nitritation step, aerobic ammonium oxidizing bacteria (AOB) oxidize a substantial portion of the ammonium in the waste stream to nitrite (NO2−). Then in the second step, the anaerobic ammonium oxidizing bacteria (AnAOB) converts the remaining ammonium and the nitrite to nitrogen gas (N2) and a small amount of nitrate (NO3−). The total process, i.e. nitritation and the anammox process, is referred to as deammonification.
MBBR processes may be used in a side stream deammonification process to remove ammonium from reject water produced by an anaerobic digester. There are some limitations to an MBBR process in such cases. MBBR processes are typically not highly efficient in a side stream deammonification process where the feed to the anaerobic digester is pre-treated by a thermal hydrolysis process. Moreover, the capacity and conversion rate of an MBBR process are often less than ideal.
A continuous flow IFAS process, on the other hand, addresses some of these shortcomings. IFAS processes typically have high conversion rates (generally two times) and higher effluent quality. Moreover, an IFAS process can accommodate inhibiting organic compounds found in some waste streams better than an MBBR process. When a thermal hydrolysis process is used to treat the feed to an anaerobic digester, an IFAS configuration requires less warm dilution water. This lower dilution ratio is significant to thermally hydrolyzed reject water projects because thermal hydrolysis processes can provide only a limited quantity of warm water dilution. However, the continuous flow IFAS system has some disadvantages. The main disadvantage is that a continuous flow IFAS system requires an external clarifier to separate the suspended biomass from the treated effluent such that the separated suspended biomass can be returned to the IFAS reactor. External clarifiers require additional tanks and increase the footprint of the total system, which is not always available, especially in retrofit projects. In addition, external clarifiers require more mechanical equipment, such as clarifier mechanisms and pumps for returning activated sludge.
In some instances, wastewater treatment systems and processes are upgraded from time-to-time at wastewater treatment facilities. This can occur in the case of side stream deammonification processes. For example, the side stream system can be upgraded by retrofitting a thermal hydrolysis system to pre-treat the feed to an anaerobic digester. This will introduce inhibitors (organic compounds) that adversely affect the efficiency of an existing MBBR deammonification process. Furthermore, over time the flow and load to an existing MBBR may increase and the existing MBBR system might not be adequate to handle such loads. In these cases, there is a need for a retrofitable deammonification system that can accommodate inhibiting compounds and efficiently treat additional loads directed to the deammonification system and which is amenable to an easy retrofit without significantly increasing the footprint of the deammonification system.
In one embodiment, the present invention relates to a side stream deammonification process where deammonification is performed by a non-continuous flow integrated fixed film activated sludge sequencing batch reactor (IFAS SBR) without the need of employing an external clarifier.
In another embodiment, the present invention entails a single reactor designed to be an MBBR or an IFAS SBR. Converting the reactor from an MBBR to an IFAS SBR, or vice versa, is simple and easy to implement. With the design of the single tank or reactor, the two operation modes, MBBR and IFAS SBR, are interchangeable depending on the treatment needs.
The single reactor includes a fixed media retaining screen that is designed to discharge treated wastewater when the reactor assumes an MBBR mode, as well as when the reactor assumes an IFAS SBR mode. In other words, the same media retaining screen is employed or used to discharge treated wastewater in either the MBBR mode or the IFAS SBR mode.
In one particular embodiment, the present invention entails a wastewater treatment process that includes a side stream deammonification process for removing ammonium from sludge that is removed from a main stream process. The side stream may include pre-treatment via thermal hydrolysis, although that is not essential or required. The side stream includes an anaerobic digester and a downstream IFAS SBR for treating reject water from the anaerobic digester. Through a batch process carried out in the IFAS SBR, wastewater is filled, aerated and reacted in a first phase, which is then followed by a settling phase which in turn is followed by a decanting phase. In this process, the total suspended solids (TSS) emitted by the IFAS SBR is not of great concern because the effluent from the IFAS SBR can be returned to the headworks of the wastewater treatment plant. Therefore, decanting from water surface is not necessary. Solids liquid separation steps (settling and decanting) is required only to retain enough suspended biomass. Therefore, media retention screens can be used to decant the reactor liquid from both clear zone and media zone but NOT from the bottom sludge zone.
In one particular embodiment, the present invention entails a deammonification reactor for removing ammonium from wastewater and configured to function as a moving bed biofilm reactor (MBBR) or as an integrated fixed film activated sludge sequencing batch reactor (IFAS SBR), the deammonification reactor comprising:
a single deammonification tank;
an aeration grid disposed in a bottom portion of the tank;
wherein the deammonification tank is configured to contain biofilm carriers having biomass supported thereon;
wherein the single tank deammonification reactor is configured to operate either in a continuous flow MBBR mode or in a non-continuous IFAS SBR mode;
wherein the retaining screen is configured to discharge treated water when the deammonification reactor assumes an MBBR; and
wherein the retaining screen is fixed relative to the tank and configured as a decanter for decanting treated wastewater from the deammonification reactor when the deammonification reactor assumes an IFAS SBR.
In another particular embodiment, the present invention entails a method for treating wastewater containing ammonium and removing ammonium in a side stream process through deammonification in an integrated fixed film activated sludge sequencing batch reactor (IFAS SBR), the method comprising:
directing the wastewater to a mainstream biological treatment process and subjecting the wastewater to biological treatment and producing sludge and a clarified effluent;
treating the sludge in a side stream process by:
directing the sludge to an anaerobic digester in the side stream;
digesting the sludge in the anaerobic digester to produce digested sludge;
dewatering the digested sludge in the side stream to produce the reject water;
directing the reject water to the IFAS SBR which contains biomass supported on carriers and suspended biomass and removing ammonium from the reject water in the IFAS SBR through a batch process that includes a series of steps including:
filling the IFAS SBR with the reject water;
aerating the reject water in the IFAS SBR;
settling the biomass in the IFAS SBR; and
decanting treated reject water by directing the treated reject water through a fixed carrier retaining screen.
There are numerous advantages in utilizing an IFAS SBR in a side stream deammonification process. As noted above, the IFAS SBR provides a relatively high ammonium conversion rate and does not require an external clarifier which is required in a conventional continuous flow IFAS system. By utilizing the fixed media screens in the reactor to decant supernatant in the IFAS SBR, this eliminates the need for conventional floating decanters. Further, the flexibility of the IFAS SBR means that an anoxic phase can be incorporated into the process for removing nitrate that might remain from a deammonification process. Finally, the IFAS SBR mode significantly increases the capacity of the system and is especially suitable for waste streams with inhibiting compounds such as found in the effluent from a thermal hydrolysis unit.
Other objects and advantages of the present invention will become apparent and obvious from a study of the following description and the accompanying drawings which are merely illustrative of such invention.
With further reference to the drawings, particularly
Reactor 10 also includes biofilm carriers or media 20. Details of the biofilm carriers 20 are not dealt with herein because their construction and use is well known and appreciated by those skilled in the art. Biofilm carriers are typically made of plastic material with a density close to the density of water (1 g/cm3). In some cases, the density of the biofilm carriers is less than the density of water which means that they float in the wastewater contained in reactor 10. In many cases, floating carriers are preferable because their use generally increases the capacity of the reactor. In other cases, the density of the carriers 20 might be above the density of water, in which case these biofilm carriers sink when not being physically mixed with the wastewater in the reactor. It is appreciated that these biofilm carriers 20 support an active biomass or biofilm which is used to biologically treat wastewater in the reactor 10.
To mix the wastewater and the biofilm carriers 20, there is provided aeration grids 14 and a mixer or mixers 22. In some processes capable of being performed in the reactor 10, the mixer 22, along with air dispersed by the aeration grid 14, mixes the biofilm carriers 20 such that they are generally uniformly distributed throughout portions of the reactor 10. Generally, reactor mixing is mainly provided by the aeration. Mixers are used for special occasions such as startup and when anoxic phases are integrated into the SBR sequences.
To discharge treated water from the reactor 10, there is provided a fixed biofilm carrier retaining screen or screens (carrier screen), indicated generally by the numeral 24, for discharging treated wastewater from the reactor 10. Carrier screen 24 serves two functions. First, it serves to discharge treated water from the reactor 10. When reactor 10 is an MBBR, treated wastewater is continuously discharged via the carrier screen 24. When reactor 10 assumes an IFAS SBR, the carrier screen 24 is configured to be a decanter. Secondly, it acts as a retaining screen and prevents the biofilm carriers 20 from being discharged with the treated water from the reactor 10. One of the advantages of the present invention is that the carrier screen 24 serves to discharge treated water when the reactor 10 operates as an MBBR or as an IFAS SBR. Therefore, if there is occasion to convert the reactor 10 from an MBBR to an IFAS SBR, substantial modifications do not have to be made to the reactor 10.
Continuing to view the carrier screen 24, it is seen from
Reactor 10 is configured to be an MBBR or an IFAS SBR. The term “configured to” as used herein and in the claims means specifically designed to perform a recited function. Reactor 10 is designed to be employed in either an MBBR process or an IFAS SBR process.
Continuing to refer to
As the wastewater flows through reactor 10, biofilm on the carriers 20 contacts the wastewater. Various biological treatments can be performed in this MBBR mode by the biofilm carriers 20. Generally the biomass supported on the carriers 20 consumes organic material. Specifically, an MBBR process can be employed for denitrification, nitrification, BOD/COD removal, and deammonification.
Reactor 10 can assume an IFAS SBR without significant alterations. As noted before, in an IFAS process, both suspended biomass (the suspended biomass is depicted at 21 in
During the settling phase, as shown in
After the suspended biomass in the reactor 10 settles, decanting follows. Now valve 26B is open and valve 26A remains closed. Treated wastewater passes through the carrier screen 24 (which now acts as a decanter) into outlet 24C. Note that during decanting the media layer 42 containing the biofilm carriers 20 slowly drifts down and approaches the sludge layer 40. The decanting phase can be terminated at various times relative to the wastewater level in the reactor 10. Of course, when the upper surface of the wastewater moves below the carrier screen 24, it follows that decanting is complete. Once decanting is terminated or is complete, then another batch of wastewater is directed into the reactor 10 and the same process follows.
In a typical design, the sludge volume is determined by the process's capacity for nitritation. The clear water volume, which is proportional to the sludge volume, provides a safety factor to prevent the loss of sludge during the decanting phase. Thus, the location of the carrier screen 24 should, in one example, be located at the top of the clear water zone 44 (after settling). In other words, the carrier screen 24 is located at the interface of the media layer 42 and the clear water zone 44, as shown in
One of the purposes of settling, decanting and wasting sludge is to maintain an adequate solids retention time (SRT) to retain enough AOB and at the same time to repress nitrite oxidizing bacteria (NOB) in the suspended growth. Therefore, sludge wasting can be accomplished by either sludge wasting pumps, gravity blowdown or releasing biological solids with the treated effluent.
It is pointed out that the same carrier screen 24 employed to decant in the IFAS SBR mode is the same carrier screen used to continuously discharge treated wastewater from the reactor 10 when it operates as an MBBR. This means that conventional floating decanters are not required in the reactor 10.
With further reference to
Turning to the side stream as depicted in
In any event, if a thermal hydrolysis unit 60 is employed, then the effluent therefrom is directed to an anaerobic digester 62. In cases where the thermal hydrolysis unit is not employed, sludge from the sludge holding tank 58 is directed into the anaerobic digester 62. As people ordinarily skilled in the art appreciate, the anaerobic digester 62 anaerobically digests the sludge.
Effluent from the anaerobic digester 62 is directed to a dewatering unit 64. Dewatering unit treats the sludge by producing a sludge cake and reject water which is typically relatively high in ammonium. Reject water produced by an anaerobic digester typically has a high temperature, a relatively high ammonium concentration, and generally the ratio of ammonium to carbon is relatively high. When a thermal hydrolysis unit 60 is employed in the side stream, the thermal hydrolysis unit can produce warm dilution water that is mixed with the reject water.
Reject water is directed into reactor 10 which is operated in the IFAS SBR mode and performs a deammonification process that removes ammonium from the reject water. It may be beneficial to briefly review the fundamentals of a deammonification process in the context of an IFAS SBR. Deammonification involves two separate bacteria, aerobic ammonium oxidizing bacteria (AOB) and anaerobic ammonium oxidizing bacteria (AnAOB). These are discussed in the background of the invention. An IFAS SBR process seems particularly suited for performing a deammonification process because an IFAS SBR process employs biofilm biomass and suspended biomass. In an IFAS SBR deammonification process, the suspended biomass or bacteria includes the AOB and the AOB performs a nitritation process. This leaves the biofilm biomass (AnAOB) to perform an anaerobic ammonium oxidation process that converts the remaining ammonium and the nitrite to nitrogen gas (N2) and a small amount of nitrate (NO3−).
The side stream IFAS SBR unit as shown in the side stream of the process of
Treated effluent from the IFAS SBR, which is depleted in ammonium, is recycled to the main stream for further treatment. Noteworthy is the fact that there is no clarifier or solids-liquid separation unit downstream of the IFAS SBR. In this particular process, there is little concern for total suspended solids (TSS) in the effluent leaving the IFAS SBR. This is because the effluent from the IFAS SBR is recycled to the main stream for further treatment.
Thus in the
There are numerous advantages to the reactor 10 and the side stream IFAS SBR deammonification process discussed herein. First, reactor 10 operates as a single tank deammonification reactor that can employ a continuous flow MBBR process or an IFAS SBR process without requiring substantial modifications to the reactor. Secondly, an IFAS SBR is compact. The suspended sludge retention time required for AOB growth can be very short (about 2.5 days for example) because the side stream temperature is usually relatively high, typically about 30° C. Because of the short suspended sludge retention time, the volume required for holding suspended biomass is relatively small. This is another factor that contributes to the compactness of an IFAS SBR. Thirdly, the reactor 10 includes a fixed carrier retaining screen that discharges treated water from either an MBBR or an IFAS SBR. Thus, in the case of an IFAS SBR, this design eliminates the need for conventional floating decanters. Fourthly, the present invention entails a highly efficient side stream deammonification process for removing ammonium from anaerobic digester reject water through a deammonification process carried out by an IFAS SBR.
The present invention may, of course, be carried out in other ways than those specifically set forth herein without departing from essential characteristics of the invention. The present embodiments are to be considered in all respects as illustrative and not restrictive, and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2020/039069 | 6/23/2020 | WO |
Number | Date | Country | |
---|---|---|---|
62867272 | Jun 2019 | US |