System for additive manufacturing

Information

  • Patent Grant
  • 11292192
  • Patent Number
    11,292,192
  • Date Filed
    Tuesday, October 22, 2019
    5 years ago
  • Date Issued
    Tuesday, April 5, 2022
    2 years ago
Abstract
A system is disclosed for additively manufacturing a composite structure. The system may include a support, a discharge head connected to and moveable by the support, a supply of reinforcement, and a rotary tensioner located between the supply and the discharge head. The rotary tensioner may be configured to impart tension to the reinforcement and to generate a signal indicative of the tension. The system may further include a drive associated with the supply, and a controller in communication with the rotary tensioner and the drive. The controller may be configured to selectively adjust a feed parameter of the drive based on the signal to maintain a desired level of tension.
Description
TECHNICAL FIELD

The present disclosure relates generally to a manufacturing system and, more particularly, to a system for additively manufacturing composite structures and a method of operating the system.


BACKGROUND

Continuous fiber 3D printing (a.k.a., CF3D®) involves the use of continuous fibers that are at least partially coated with a matrix inside of a moveable print head, just prior to discharge from the print head. The matrix can be a thermoplastic, a thermoset, a powdered metal, or a combination of any of these and other known matrixes. Upon exiting the print head, a head-mounted cure enhancer (e.g., a UV light, an ultrasonic emitter, a heat source, a catalyst supply, etc.) is activated to initiate and/or complete curing of the matrix. This curing occurs almost immediately, allowing for unsupported structures to be fabricated in free space, without the need for a mold or an autoclave. An example of this technology is disclosed in U.S. Pat. No. 9,511,543 that issued to Tyler on Dec. 6, 2016 (“the '543 patent”). CF3D® may be inexpensive, fast, and efficient, as the use of autoclaves, molds, and manual labor associated with traditional composite manufacturing may be reduced or even eliminated.


Although CF3D® may be inexpensive, fast, and efficient, improvements can be made to the structure and/or operation of existing systems. For example, a strength of the resulting structure may be at least partially dependent on alignment and engagement of each of the reinforcements within the structure. Straighter fibers that are all engaged equally may result in a stronger structure. However, this can be difficult to achieve. The disclosed additive manufacturing system and method are uniquely configured to provide these improvements and/or to address other issues of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a support, a discharge head connected to and moveable by the support, a supply of reinforcement, and a rotary tensioner located between the supply and the discharge head. The rotary tensioner may be configured to impart tension to the reinforcement and to generate a signal indicative of the tension. The system may further include a drive associated with the supply, and a controller in communication with the rotary tensioner and the drive. The controller may be configured to selectively adjust a feed parameter of the drive based on the signal to maintain a desired level of tension.


In another aspect, the present disclosure is directed to a tension arrangement for use with a discharge head. The tension arrangement may include a rotary tensioner configured to generate tension within a reinforcement passing into the discharge head and to generate a signal indicative of the tension. The tension arrangement may also include a drive responsive to the signal to adjust a feed parameter of the reinforcement.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a diagrammatic and cross-sectional illustration of an exemplary disclosed additive manufacturing system;



FIG. 2 is an enlarged isometric illustration of an exemplary portion of the additive manufacturing system of FIG. 1; and



FIG. 3 is a side-view illustration of an alternative exemplary portion of the additive manufacturing system of FIG. 1.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary system 10, which may be used to manufacture a composite structure 12 having any desired shape. System 10 may include a support 14 and deposition head (“head”) 16. Head 16 may be coupled to and moved by support 14. In the disclosed embodiment of FIG. 1, support 14 is a robotic arm capable of moving head 16 in multiple directions during fabrication of structure 12. Support 14 may alternatively embody a gantry (e.g., an overhead bridge or single-post gantry) or a hybrid gantry/arm also capable of moving head 16 in multiple directions during fabrication of structure 12. Although support 14 is shown as being capable of 6-axis movements, it is contemplated that support 14 may be capable of moving head 16 in a different manner (e.g., along or around a greater or lesser number of axes). In some embodiments, a drive may mechanically couple head 16 to support 14, and include components that cooperate to move portions of and/or supply power or materials to head 16.


Head 16 may be configured to receive or otherwise contain a matrix (shown as M in FIG. 1). The matrix may include any type of matrix (e.g., a liquid resin, such as a zero-volatile organic compound resin, a powdered metal, etc.) that is curable. Exemplary resins include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiolenes, and more. In one embodiment, the matrix inside head 16 may be pressurized, for example by an external device (e.g., by an extruder, a pump, etc.—not shown) that is fluidly connected to head 16 via a corresponding conduit (not shown). In another embodiment, however, the pressure may be generated completely inside of head 16 by a similar type of device. In yet other embodiments, the matrix may be gravity-fed into and/or through head 16. For example, the matrix may be fed into head 16, and pushed or pulled out of head 16 along with one or more continuous reinforcements (shown as R in FIG. 1). In some instances, the matrix inside head 16 may need to be kept cool and/or dark in order to inhibit premature curing or otherwise obtain a desired rate of curing after discharge. In other instances, the matrix may need to be kept warm and/or illuminated for similar reasons. In either situation, head 16 may be specially configured (e.g., insulated, temperature-controlled, shielded, etc.) to provide for these needs.


The matrix may be used to coat any number of continuous reinforcements (e.g., separate fibers, tows, rovings, socks, and/or sheets of continuous material) and, together with the reinforcements, make up a portion (e.g., a wall) of composite structure 12. The reinforcements may be stored within or otherwise passed through head 16 (e.g., fed from one or more spools 17). When multiple reinforcements are simultaneously used, the reinforcements may be of the same material composition and have the same sizing and cross-sectional shape (e.g., circular, square, rectangular, etc.), or a different material composition with different sizing and/or cross-sectional shapes. The reinforcements may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, plastic fibers, metallic wires, optical tubes, etc. It should be noted that the term “reinforcement” is meant to encompass both structural and non-structural (e.g., functional) types of continuous materials that are at least partially encased in the matrix discharging from head 16.


The reinforcements may be exposed to (e.g., at least partially coated with) the matrix while the reinforcements are inside head 16, while the reinforcements are being passed to head 16, and/or while the reinforcements are discharging from head 16. The matrix, dry (e.g., unimpregnated) reinforcements, and/or reinforcements that are already exposed to the matrix may be transported into head 16 in any manner apparent to one skilled in the art. In some embodiments, a filler material (e.g., chopped fibers, nano particles or tubes, etc.) may be mixed with the matrix before and/or after the matrix coats the continuous reinforcements.


One or more cure enhancers (e.g., a UV light, an ultrasonic emitter, a laser, a heater, a catalyst dispenser, etc.) 18 may be mounted proximate (e.g., within, on, and/or adjacent) head 16 and configured to enhance a cure rate and/or quality of the matrix as it is discharged from head 16. Cure enhancer 18 may be controlled to selectively expose portions of structure 12 to energy (e.g., UV light, electromagnetic radiation, vibrations, heat, a chemical catalyst, etc.) during material discharge and the formation of structure 12. The energy may trigger a chemical reaction to occur within the matrix, increase a rate of the chemical reaction, sinter the matrix, harden the matrix, or otherwise cause the matrix to cure as it discharges from head 16. The amount of energy produced by cure enhancer 18 may be sufficient to cure the matrix before structure 12 axially grows more than a predetermined length away from head 16. In one embodiment, structure 12 is completely cured before the axial growth length becomes equal to an external diameter of the matrix-coated reinforcement.


The matrix and/or reinforcement may be discharged from head 16 via at least two different modes of operation. In a first mode of operation, the matrix and/or reinforcement are extruded (e.g., pushed under pressure and/or mechanical force) from head 16 as head 16 is moved by support 14 to create features of structure 12. In a second mode of operation, at least the reinforcement is pulled from head 16 (and also from spool 17, in some embodiments), such that a tensile stress is created in the reinforcement during discharge. In this mode of operation, the matrix may cling to the reinforcement and thereby also be pulled from head 16 along with the reinforcement, and/or the matrix may be discharged from head 16 under pressure along with the pulled reinforcement. In the second mode of operation, where the matrix is being pulled from head 16 with the reinforcement, the resulting tension in the reinforcement may increase a strength of structure 12 (e.g., by aligning the reinforcements, inhibiting buckling, etc.) after curing of the matrix, while also allowing for a greater length of unsupported structure 12 to have a straighter trajectory. That is, the tension in the reinforcement remaining after curing of the matrix may act against the force of gravity (e.g., directly and/or indirectly by creating moments that oppose gravity) to provide support for structure 12.


The reinforcement may be pulled from head 16 as a result of head 16 being moved by support 14 away from an anchor point 20. In particular, at the start of structure formation, a length of matrix-impregnated reinforcement may be pulled and/or pushed from head 16, deposited onto anchor point 20, and cured, such that the discharged material adheres (or is otherwise coupled) to anchor point 20. Thereafter, head 16 may be moved away from anchor point 20, and the relative movement may cause the reinforcement to be pulled from head 16. It should be noted that the movement of reinforcement through head 16 could be assisted via internal feed mechanisms, if desired. However, the discharge rate of reinforcement from head 16 may primarily be the result of relative movement between head 16 and anchor point 20, such that tension is created within the reinforcement. As discussed above, anchor point 20 could be moved away from head 16 instead of or in addition to head 16 being moved away from anchor point 20.


As can be seen in FIG. 1, head 16 may include, among other things, an outlet 22 and a matrix reservoir 24 located upstream of outlet 22. In this example, outlet 22 is a single-channel nozzle configured to discharge composite material having a generally circular, tubular, or rectangular cross-section. The configuration of head 16, however, may allow outlet 22 to be swapped out for another outlet (not shown) that discharges composite material having a different shape (e.g., a flat or sheet-like cross-section, a multi-track cross-section, etc.). Fibers, tubes, and/or other reinforcements may pass through matrix reservoir 24 and be wetted (e.g., at least partially coated and/or fully saturated) with matrix prior to discharge.


A controller 26 may be provided and communicatively coupled with support 14 and head 16. Each controller 26 may embody a single processor or multiple processors that are configured to control an operation of system 10. Controller 26 may include one or more general or special purpose processors or microprocessors. Controller 26 may further include or be associated with a memory for storing data such as, for example, design limits, performance characteristics, operational instructions, tool paths, and corresponding parameters of each component of system 10. Various other known circuits may be associated with controller 26, including power supply circuitry, signal-conditioning circuitry, solenoid driver circuitry, communication circuitry, and other appropriate circuitry. Moreover, controller 26 may be capable of communicating with other components of system 10 via wired and/or wireless transmission.


One or more maps may be stored in the memory of controller 26 and used during fabrication of structure 12. Each of these maps may include a collection of data in the form of lookup tables, graphs, and/or equations. In the disclosed embodiment, the maps may be used by controller 26 to determine the movements of head 16 required to produce desired geometry (e.g., size, shape, material composition, performance parameters, and/or contour) of structure 12, and to regulate operation of cure enhancer(s) 18 and/or other related components in coordination with the movements.


In some embodiments, a tension arrangement (“arrangement”) 28 may be associated with head 16. Arrangement 28 may help to maintain a tension within individual reinforcements passing from spool 17 through outlet 22. This may help system 10 to produce structures 12 having predictable performance and to avoid malfunctions during printing (particularly when changing print directions and/or orientations). For example, when some reinforcements are in greater tension than other reinforcements in the same structure, the higher-tension reinforcements carry more of a load placed on structure 12. These reinforcements are then at greater risk for damage and/or failure during use. Similarly, excessively high reinforcement tension inside of head 16 could cause the reinforcements to break, resulting in delayed processing and/or rejected structures 12. In contrast, reinforcements that are in low or no tension generally do not contribute to performance of the part and add only excess weight. In addition, low levels of tension could cause bunching of the reinforcements inside of head 16. Uneven levels of tension between the reinforcements can also create distortions in structure 12 during fabrication. Arrangement 28 may be beneficial to help ensure a desired and uniform level of tension within all of the reinforcements passing through head 16.


In the embodiments of FIGS. 1, 2, and 3, arrangement 28 is illustrated as a rotary-type of arrangement, including a tensioner 30 located between spool 17 and outlet 22, and a variable drive 32 associated with spool 17. As shown in FIGS. 2 and 3, tensioner 30 may be an assembly of components including, among other things, one or more arms (e.g., spaced apart elongated plates) 34 that are pivotally connected to a bracket 36 by way of one or more axels 38. In one embodiment, outlet 22 and/or spool 17 are mounted to the same bracket 36. One or more springs (e.g., coil springs) 40 may be disposed between arms 34 and bracket 36 to bias arms 34 away from a neutral rotational angle (shown in FIG. 2). Any number of pulleys or rollers (e.g., an upstream pulley 42 and a downstream pulley 44) may be mounted to arms 34 (e.g., at opposing ends thereof), and the reinforcements from spool 17 may pass around pulleys 42, 44. When arms 34 are at the neutral rotational angle, the reinforcements may follow a straightest trajectory around pulleys 42, 44, from spool 17 through outlet 22. As spring(s) 40 pivots arms 34 away from the neutral rotational angle (e.g., in the direction of an arrow 46), the reinforcements may be moved into more of an S-shaped trajectory. As tension within the reinforcements increases, arms 34 may be pivoted against the bias of spring(s) 40 back towards the neutral position.


In some embodiments, the pivoting of arms 34 may be detected by a sensor 48. In one embodiment, sensor 48 is a rotary encoder that generates a signal indicative of the pivoting of arms 34 relative to the neutral rotational angle. In other embodiments, however, sensor 48 may be another type of sensor (e.g., a linear sensor associated with spring(s) 40, a potentiometer, etc.), if desired.


The signals generated by sensor 48 may be used (e.g., by controller 26) to selectively energize drive 32 (referring to FIG. 1). For example, in response to a signal indicating a greater amount of tension (e.g., greater rotation toward the neutral rotational angle), controller 26 may energize drive 32 a greater amount to cause more reinforcement to be dispensed and/or dispensed at a faster rate, thereby lowering the tension within the reinforcements. In contrast, in response to a signal indicating a lesser amount of tension (e.g., greater rotation away from the neutral rotational angle), controller 26 may energize drive 32 a lesser amount to cause less reinforcement to be dispensed and/or dispensed at a slower rate, thereby increasing the tension with the reinforcements. In this manner, reinforcement may be dispensed on an as-needed basis in order to maintain a desired and relatively consistent level of tension within all of the reinforcements. In one embodiment, arrangement 28 may maintain a tension within the reinforcements of less than about 5 lbs., with a resolution of about 0.1-2 lbs.


Drive 32 may embody any type of automated spool driver known in the art. In one example, drive 32 includes a motor 50 operatively connected to a shaft 52 on which spool 17 may be mounted. In the disclosed embodiment, motor 50 is connected to shaft 52 via a gear mechanism (e.g., a pair of meshed bevel gears) 54. Based on a command from controller 26, motor 50 may selectively dispense an amount of reinforcement and/or reinforcement at a commanded rate.



FIG. 3 illustrates an alternative embodiment of tensioner 30. Tensioner 30 of FIGS. 2 and 3 differ primarily in the way that axel 38 connects arms 34 to bracket 36. In particular, axel 38 of FIG. 2 may actually be divided into two stub-axels, one associated with an opposing ear tab of bracket 36 and each of arms 34. In addition, the pivot point of arms 34 may be generally centered between their opposing ends in FIG. 2. Axel 38 of FIG. 3, however, may embody a monolithic component that passes completely through a common end of arms 34 and both ear tabs of bracket 36. The design of FIG. 3 may help to reduce tolerance stack-up associated with tensioner 30 and also provide a consistent guide point for reinforcement entering head 16 (i.e., downstream pulley 44 remains stationary in FIG. 3, allowing for less movement of the reinforcement within head 16 due to changes in tension).


INDUSTRIAL APPLICABILITY

The disclosed system may be used to manufacture composite structures having any desired cross-sectional shape and length. The composite structures may include any number of different continuous fibers of the same or different types and of the same or different diameters, and any number of different matrixes of the same or different makeup. Operation of system 10 will now be described in detail.


At a start of a manufacturing event, information regarding a desired structure 12 may be loaded into system 10 (e.g., into controller 26 that is responsible for regulating operations of support 14 and/or head 16). This information may include, among other things, a size (e.g., diameter, wall thickness, length, etc.), a contour (e.g., a trajectory), surface features (e.g., ridge size, location, thickness, length; flange size, location, thickness, length; etc.), connection geometry (e.g., locations and sizes of couplings, tees, splices, etc.), functional requirements, matrix specifications (e.g., cure parameters), reinforcement specifications (e.g., desired tension levels), etc. It should be noted that this information may alternatively or additionally be loaded into system 10 at different times and/or continuously during the manufacturing event, if desired. Based on the component information, one or more different reinforcements and/or matrixes may be selectively installed and/or continuously supplied into system 10.


To install unimpregnated reinforcements into head 16, individual fibers, tows, and/or ribbons may be passed from spool 17 through tensioner 30 (e.g., between pulleys 42, 44), through matrix reservoir 24, through outlet 22, and past cure enhancer(s) 18. In some embodiments, the reinforcements may also need to be connected to a pulling machine (not shown) and/or to a mounting fixture (e.g., to anchor point 20). Installation of the matrix may include filling head 16 (e.g., reservoir 24) and/or coupling of an extruder or other source of pressurized matrix (not shown) to head 16.


The component information may then be used to control operation of system 10. For example, the in-situ wetted reinforcements may be pulled and/or pushed from head(s) 16 as support 14 selectively moves (e.g., based on known kinematics of support 14 and/or known geometry of structure 12) such that the resulting structure 12 is fabricated as desired. Operating parameters of cure enhancer(s) 18, arrangement 28 (e.g., tensioner 30 and/or drive 32) and/or other components of system 10 may be adjusted in real time during material discharge to provide for desired bonding, strength, and other characteristics of structure 12. Once structure 12 has grown to a desired length, structure 12 may be severed from system 10.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed system and methods. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed system and method. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A system for additively manufacturing a composite structure, comprising: a support;a discharge head connected to and moveable by the support;a supply of reinforcement;a tensioner located between the supply and the discharge head, the tensioner including: an arm pivotably connected to the discharge head, anda spring connected to the arm, the spring being configured to bias the arm to impart tension to the reinforcement;a sensor configured to generate a signal indicative of an orientation of the arm;a drive associated with the supply; anda controller in communication with the tensioner, the sensor, and the drive, the controller being configured to selectively adjust a feed parameter of the drive based on the signal.
  • 2. The system of claim 1, further including a bracket connecting the discharge head and at least one of the tensioner or the drive to the support.
  • 3. The system of claim 2, wherein the supply is connected to the bracket via the drive.
  • 4. The system of claim 1, wherein the signal is indicative of a pivot angle of the arm.
  • 5. The system of claim 1, further including: a first device located at a first end of the arm, the first device redirecting the reinforcement anda second device located at a second end of the arm, the second device redirecting the reinforcement.
  • 6. The system of claim 5, wherein a pivot point of the arm is concentric with the second device.
  • 7. The system of claim 1, wherein: the supply is a spool; andthe drive includes a motor operatively connected to the spool.
  • 8. The system of claim 1, wherein the discharge head includes a matrix reservoir configured to receive reinforcement from the tensioner and to wet the reinforcement with a matrix.
  • 9. The system of claim 8, wherein the reinforcement is pulled through the tensioner and the matrix reservoir by movement of the discharge head away from an anchor point.
  • 10. The system of claim 8, wherein the discharge head includes a cure enhancer configured to expose the wetted reinforcement to cure energy at a discharge location of the discharge head.
  • 11. A system for additively manufacturing a composite structure, comprising: a support;a discharge head connected to and moveable by the support;a supply of material;a rotary tensioner located between the supply and the discharge head, the rotary tensioner configured to rotate to impart tension to the material, the rotary tensioner including: an arm,a redirecting device connected to an end of the arm and engaging the supply of material, anda spring configured to bias the arm away in a direction away from a position at which the material travels along a substantially linear path between the supply and the discharge head;a drive associated with the supply; anda controller in communication with the rotary tensioner and the drive, the controller being configured to selectively adjust a feed parameter of the drive to maintain a desired position of the rotary tensioner.
  • 12. The system of claim 11, further including a sensor, wherein: the sensor is configured to generate a signal associated with an angle of the arm; andthe controller is configured to adjust the feed parameter of the drive based on the signal.
  • 13. The system of claim 11, wherein the material is pulled through the rotary tensioner by movement of the discharge head away from an anchor point.
  • 14. The system of claim 11, wherein the supply and the drive are also connected to and moveable by the support.
  • 15. The system of claim 14, wherein the rotary tensioner is also connected to and moveable by the support.
  • 16. The system of claim 11, wherein the rotary tensioner is also connected to and moveable by the support.
  • 17. The system of claim 11, wherein selectively adjusting the feed parameter comprises: increasing a rate at which the drive discharges the supply of material when a tension of the material is greater than a threshold; ordecreasing the rate at which the drive discharges the supply of material when the tension of the material is less than the threshold.
  • 18. The system of claim 11, wherein selectively adjusting the feed parameter comprises: decreasing a rate at which the drive discharges the supply of material when an angle of the arm is greater than a threshold, the angle extending from a longitudinal axis of the arm and a surface of the housing; orincreasing the rate at which the drive discharges the supply of material when the angle of the arm is less than the threshold.
  • 19. The system of claim 11, wherein: the end of the arm is a first end of the arm; anda second end of the arm is rotationally connected to the support, the second end being opposite the first end.
  • 20. The system of claim 19, wherein the redirecting device is a first redirecting device, the system further including a second redirecting device connected to the arm at the second end, wherein: the second redirecting device is upstream of the first redirecting device; and
RELATED APPLICATIONS

This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/769,498 that was filed on Nov. 19, 2018, the contents of which are expressly incorporated herein by reference.

US Referenced Citations (179)
Number Name Date Kind
3286305 Seckel Nov 1966 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5746967 Hoy et al. May 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6799081 Haie et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7555404 Brennan et al. Jun 2009 B2
7795349 Bredt et al. Sep 2010 B2
8221669 Batchelder et al. Jul 2012 B2
8962717 Roth et al. Feb 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9527248 Hollander Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080176092 Owens Jul 2008 A1
20090095410 Oldani Apr 2009 A1
20110032301 Fienup et al. Feb 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140034214 Boyer et al. Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger et al. Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170101286 Brockman Apr 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waatti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
20180126652 Mansson May 2018 A1
Foreign Referenced Citations (29)
Number Date Country
4102257 Jul 1992 DE
2589481 Jan 2016 EP
3219474 Sep 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2013017284 Feb 2013 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
WO-2017085649 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (12)
Entry
A. Di. Pietro & Paul Compston, Resin Hardness and interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/inylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012).
Related Publications (1)
Number Date Country
20200156318 A1 May 2020 US
Provisional Applications (1)
Number Date Country
62769498 Nov 2018 US