SYSTEM FOR FORMING LEAF LAMINATES

Information

  • Patent Application
  • 20070295448
  • Publication Number
    20070295448
  • Date Filed
    June 22, 2007
    17 years ago
  • Date Published
    December 27, 2007
    17 years ago
Abstract
A method of forming a laminate including a very thin leaf layer. In a first step an image corresponding to a desired pattern is printed in a conventional manner on said substrate using an ink having adhesive properties. The substrate and image are then covered with a very thin, frangible leaf material such a very thin metal foil. The leaf material is then laminated onto said image by applying pressure to said leaf, image and substrate. Mechanical agitation is then used to remove excess leaf outside the boundaries of the image by flaking off the excess leaf from the substrate.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a flowchart illustrating the basic steps in accordance with the system of present invention.



FIG. 2 is a cross section of a laminate produced in accordance with the present invention.





DETAILED DESCRIPTION
Basic System

My invention provides a way of manufacturing laminated articles having printed patterns fabricated using frangible materials such as very thin friable metal leafs on almost any kind of substrate. Referring now to FIG. 1, the system 10 of my invention involves five basic steps:


As shown in step 20, an image is transferred onto a substrate, by any of a large number of well-known printing methods (contact or non contact). As shown in step 22, the image is then preferably allowed to dry, depending on the application, substrate, and ink until it is partially cured but still retains a substantial amount of tackiness, although the image may be allowed to fully dry if sufficient heat and pressure are later used to the reactivate adhesive components in the ink (e.g. soften resins and restore tackiness). As further shown in step 24, the image is covered with a thin metal film or leaf comprising a frangible material. As shown in step 26, the image and leaf are then laminated by the application of pressure and heat. As finally shown in step 28, the resulting laminated image and substrate are gently scrubbed by some mechanical method to remove the excess frangible material such as rotating or moving brushes, sponges or fluid flow provided by compressed air or water jets or vacuum pressure.


Referring now to FIG. 2, a laminate 40 produced in accordance with the present invention includes three layers: the substrate 42, the (printed) ink film 44 and the metal leaf 46.


The system 10 eliminates the need to use cutting tools to form or remove excess material, increases printing speeds compared to current methods such as electro-deposition of leaf or leaf like materials, and expands the types of substrates that leafs can be combined with.


Inks containing pigments and waxes, once dry, generally cannot be laminated with frangible leafs unless they are modified to contain adhesive components. This is because they contain a discontinuous resin film. However, inks based on dyes and without waxes can be softened, even if totally dry, by heating, and can bond continuously to frangible or flake-able materials. Laminating the printed image and leaf together at elevated temperatures and under pressure has the added advantage that frangible material not in contact with the image expands (along with the moisture present in paper and in air). Because the material cannot move sideways, this expansion causes it to move upwards, making the material flake off more easily. Further, after cooling, the laminated substrate and frangible material shrink together and reduce the size of any pinholes.


System and Process Parameters

The substrate can be: any solid material (absorbent or non-absorbent) that can be exposed to direct or indirect pressure, heat or pressure and heat. The pressure applied will be in the general range 1 to 7 bar and is preferably applied for in general under a second. The heat the substrate will be exposed to should not exceed 450 Kelvin in general and will again be applied for under a second in most circumstances. Examples of possible substrates range from paper sheets as thin as airmail paper to as heavy as foam board, plastic sheets, metal sheets, food items (such as fruit), wood, stone (even marble or granite), etc.


The printing method can be: any mechanical way of printing (including non-contact) such as letterpress, planographic, flexographic, graveure, silk-screen, ink-jet, laser, or other equivalent printing methods.


The ink can be: an appropriate ink depending on the printing method and substrate used, however, inks containing substantial amounts of resinous materials or specially added adhesive components are preferred that provide sufficient tackiness for the leaf to quickly bond with the ink and substrate. Alternatively, special lamination inks containing components providing adhesive properties may be employed. Many resin based inks having conventional formulations have adequate adhesive properties.


The leaf can be: any of a number of frangible materials that are generally very thin such as metal leaf (preferably in the range of >0.21 μm but <8 μm). Leaf materials other than metals or metal alloys may be employed although very thin metal leaf made out of gold, silver, copper, palladium, or aluminum are preferred. For example, a 0.4 μm silver leaf is highly suitable. Other suitable leafs may include compositions including non-metallic materials that do not flake well at room temperature, but will flake away from substrates at lower temperatures.


The pressure can be: the pressure of the lamination will broadly vary depending on the specific application, ink, leaf, and substrate, but will generally use pressures in the range of those currently employed by commercially available lamination equipment, typically 1 to 7 bar.


The temperature can be: the temperature of the lamination will vary depending on specific application, but will be close to Ring and Ball softening point of the resin used in the ink or glue or for most such cases approximately 450 Kelvin.


The drying time can be: depending upon the substrate, ink, leaf, degree of the bond required and the thicknesses of the materials, the laminating time will range from a fraction of a second to more than 10 seconds.












Sample Ink Formulations










Potential Ink


Amounts


System
Example
Ingredients
(g)













Ink-jet ink
A
Bleached & Dewaxed Shellac
11.0




(food grade)




Ethanol
22.0




Butyrolactone
158.0




Morfast 108 Black
12.0


Ink-jet ink
B
Bleached & Dewaxed Shellac
6.67




(food grade)




Ethanol
13.33




Normal Butanol
50.0




Tertiary Butanol
50.0




Isopropanol
33.0




Butyrolactone
10.0




Baso 124 yellow dye (BASF)
7.0


Flexo Ink
C
Nitrosol 250 LR (Aqualon)
20.0




Water
200.0




Triethanolamine
5.0




Propylene Glycol Mono Propylene
5.0




Ether




Diacetone alcohol
5.0




Pontamine Yellow RB Liquid
5.0


Dry Offset
D
Pace 382
65.0




Propylene Glycol
5.0




Thixotropic Varnish
30.0








Claims
  • 1. A method of forming a laminate including a leaf characterized by a pattern on a substrate, comprising the steps of: a) printing an image corresponding to said pattern on said substrate using an ink having adhesive properties;b) covering said substrate including said image with a thin frangible leaf;c) laminating said leaf onto said image by applying pressure to said leaf, image and substrate; andd) mechanically agitating said leaf in order to remove excess leaf outside the boundaries of the image by flaking the excess leaf off the substrate.
  • 2. The method of claim 1, further including the steps of: drying said image until said ink is substantially cured, and wherein:said step of laminating also includes applying heat to said leaf and printed image.
  • 3. The method of claim 1, further including the step of: allowing said image to dry until said ink is partially cured but still retains substantial tackiness.
  • 4. The method of claim 1, wherein: said planar substrate comprises paper.
  • 5. The method of claim 1, wherein: said frangible leaf comprises a silver leaf of about 0.4 cm thickness.
  • 6. The method of claim 5, wherein: said ink includes resinous components providing adhesive properties.
  • 7. The method of claim 1, wherein: said frangible leaf comprises a aluminum leaf.
  • 8. The method of claim 1, wherein: said step of agitating includes using brushes to provide mechanical abrasion to said leaf.
  • 9. The method of claim 7, wherein: said step of agitating includes using compressed air to provide mechanical abrasion to said leaf.
  • 10. The method of claim 1, wherein: said step of printing is performed using an ink-jet printer.
  • 11. The method of claim 1, wherein: said step of printing is performed using a letterpress printer.
  • 12. The method of claim 1, wherein: said step of printing is performed using a planographic printer.
  • 13. The method of claim 1, wherein: said step of printing is performed using flexographic printer.
  • 14. The method of claim 1, wherein: said step of printing is performed using a silk-screen printing process.
  • 15. A method of forming a laminate having a thin metal leaf layer in order to fabricate an electrical circuit or decorative element on the surface of the laminate, comprising the steps of: a) printing a pattern for said circuit on a planar substrate using an ink having adhesive properties;b) covering said substrate including said pattern with a thin frangible metal leaf;c) laminating said metal leaf onto said pattern by applying pressure to said leaf, pattern and substrate; andd) flaking the metal leaf off of said substrate outside of the boundaries of said pattern.
  • 16. The method of claim 15, further including: drying said pattern until said ink is substantially cured, and wherein:said step of laminating also includes applying heat to said leaf and printed pattern.
  • 17. The method of claim 15, wherein: said planar substrate comprises paper.
  • 18. The method of claim 15, wherein: said planar substrate comprises a food item.
  • 19. The method of claim 15, wherein: said frangible leaf comprises a silver leaf.
  • 20. The method of claim 15, wherein: said frangible leaf comprises a copper leaf.
  • 21. The method of claim 15, wherein: said frangible leaf comprises aluminum leaf.
  • 22. The method of claim 15, wherein: said step of flaking includes using mechanical abrasion to remove said leaf outside the boundaries of said image.
  • 23. The method of claim 22, wherein: said step of flaking includes using a brush to provide said mechanical abrasion.
  • 24. The method of claim 15, wherein: said step of printing is performed using an ink-jet printer.
  • 25. The method of claim 15, wherein: said ink includes resinous materials providing adhesive properties.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of and priority from U.S. Provisional Patent Application 60/815,936 filed Jun. 23, 2006, which is incorporated herein by reference.

Provisional Applications (1)
Number Date Country
60815936 Jun 2006 US