1. Field of application
The present invention refers to a system for producing energy from hydrogen, in particular for residential buildings, according to the preamble of claim 1.
2. Prior art
As known, hydrogen can be used to produce, for example for residential buildings, heat energy through hydrogen catalytic burners (WO 2006/136316 A1 of the applicant) or through electrical energy through fuel cells (US 2010/0164287 A1).
Catalytic burners of the applicant have been used over the years and the fuel cells, i.e. the hydrogen cells, currently have extremely advanced technologies.
In catalytic burners, the generated heat energy is used, through a heat exchanger, for heating the water of, for example, a heating system of a residential building and for heating domestic water, or for other heating purposes, for example for heating greenhouses and so on and so forth.
The hydrogen for supplying the burner is preferably produced through electrolysis, where the required electrical energy is advantageously produced by renewable sources, such as for example a photovoltaic plant. Hydrogen could also be produced by means of a reformer, or generated by methane gas.
Different control components, for example a pressure reducer, a control unit, a battery with battery charger and so on and so forth are associated to the burner.
Fuel cells were developed in particular for the automotive industry, and they provide optimal levels both in terms of performance and duration. They can also be used for producing electrical energy in residential buildings.
It is also known that fuel cells, during operation thereof, produce heat, which is generally dispersed into the environment.
From the abovementioned US 2010/0164287 A1 there is known a system for supplying electric power between a vehicle, comprising a fuel cell and a house.
The object of the present invention is that of providing a system for producing energy from hydrogen capable of supplying, for example to a residential building, the required energy whether heat and electrical energy so as to make said residential building independent from the electrical power and gas supply system, wherein—at the same time—the operative synergy between the components of the system which improves the performance of the system is exploited.
Such object is attained, according to the invention, by means of system for producing combined energy from hydrogen having the characteristics of claim 1.
Further developments of the invention are observable from the dependent claims. Numerous and significant advantages are obtained from the system for producing energy from hydrogen according to the invention.
Firstly, integration—in the system for producing energy according to the invention—of a catalytic burner and a fuel cell both of which can be supplied with hydrogen, advantageously produced through in situ electrolysis, allows the unit to use two sources, i.e. the source of heat energy and the source of electrical energy, in a manner entirely independent from the other, and thus modulate both the electric power and the heat power so as to regulate the relative consumption depending on the contingent needs, wherein the use of hydrogen both for the burner and for the fuel cell allows having a system for producing entirely zero-emission energy, given that both the fuel cell and the burner generate water vapour alone and thus no carbon dioxide and nitrogen oxides. Given that the two sources of energy (burner and fuel cell) operate independently from each other, production of electrical energy is not subordinated to that of heat energy, and vice versa. At the same time, different circuit components already required for the burner can be advantageously used at the same time also for the fuel cell. The system for producing energy according to the invention also allows improving the overall performance of the system. For example, the air used for cooling the fuel cell, available at about 40-45° C., can be used for heating the air entering the burner, thus boosting the efficiency of the latter. As outlined hereinafter, same case applies also regarding water-cooled fuel cells.
In the plant for producing combined energy according to the invention using the fuel cell, the plant can operate without being connected to the electrical power supply system, thus the system operates autonomously upon starting. This constitutes an important advantage with respect to the prior art heat generators, in that the prior art methane-powered heat generators do not operate in absence of electrical power. Having the electrical power supply system, a power outlet for possible supply from the power system and for recharging the battery of the auxiliary components in case of discharge thereof for any reason whatsoever, is however recommendable.
Associating—in the system—a hydrogen catalytic burner and a fuel cell boosts the efficiency of the latter in that it can recover the heat generated by the same during operation, instead of dispersing such heat.
Associating—to the system for producing combined energy according to the invention—a high efficiency heat pump allows obtaining further advantages. Such association—using an assembly of highly efficient technologies—would even allow recovering the energy used for producing hydrogen by electrolysis.
Actually, in practice, currently a heat pump has a coefficient of performance (COP) normally comprised between 3 and 4 values, wherein—for the sake of simplicity—a 3.5 COP is considered. A fuel cell has a yield of about 40%, hence the association of the two systems provides an overall value of 1.4 and, thus, greater than one unit. Considering that production of hydrogen through electrolysis (performance of about 75%), then the total performance would reach the value of about 1.05. This means that this system, coupled with a heat pump and with generation of hydrogen through electrolysis, allows recovering more energy with respect to that used initially, hence making it extremely advantageous. Then if the input energy is collected and stored at the right time (for example, in case of connection to the power supply system, at night when it might cost less) or if it comes from a renewable and free source (for example photovoltaic solar), the system according to the invention becomes even more convenient and advantageous.
The figures indicated above refer to products currently normally available in the market, and more precisely considering a qualitatively “average” range of products. Therefore, it can be expected that the abovementioned products may in future be replaced by other more efficient ones, hence the total yield is bound to increase and overcome the value indicated previously.
Production of hydrogen through electrolysis and using an electric heat pump however allows the obtained system to maintain a strongly “ecological and environmental” value in that it preserves the zero-emission characteristic thereof
According to a particular aspect of the invention, the system for producing electrical and heat energy according to the invention can constitute an autonomous unit adapted for the production of emergency electrical and/or heat energy for example in case of natural disasters, earthquakes and the like.
A further advantage of the invention lies in the fact that the circuit for the two sources of heat and electrical energy supplied with hydrogen and the single components are partly shared and thus the resulting circuits are much simpler and require fewer components with respect to two independent source systems.
Particular use of a system or unit for producing combined energy supplied with hydrogen for residential buildings not served by the electrical and gas supply system is also advantageous.
Further characteristics, advantages and details of the system for producing combined energy according to the invention shall be clearer from the following description with reference to some embodiments provided solely by way of example in the attached schematic drawings, wherein:
Unless otherwise specified, identical parts have identical reference numbers in the various figures in order to avoid repetition.
With reference to
B is used to indicate an inlet of the electrical power supply system while 10 and 11 are used to respectively indicate a battery charger and a buffer battery, while 12 is used to indicate an inverter connected to the fuel cell 5 and to the battery charger 10. The inverter 12 converts the produced direct current into an alternating current with a voltage upon exit C of, for example, 220V and 50 Hz, as usually provided for residential buildings in Europe.
D and E are respectively used to indicate the inlet and outlet, for example, of a heat exchanger, not illustrated, associated to the burner 4 and connected with a heating system, not illustrated.
A cooling fan 13 controllable by the CPU is associated to the fuel cell 5. The hot air 15 coming from the cooling of the fuel cell 5 is directly conveyed to the suctioning element 16 of the burner 4. This allows recovering the heat contained in the cooling air 15 without requiring further heat exchange means or devices. This cooling air 15, having a temperature of about 40-45° C., allows increasing the temperature on the catalyst, not illustrated, of the catalytic burner 4, but without exceeding the limiyt thereof
The efficiency of the burner 4 shall be maximum for heating water in particular for the low temperature radiant heating systems, operating with water at a maximum of about 40-45° C. The burner 4 in any case is also capable of bringing the water temperature to about 60° C., the ideal temperature for producing hot domestic water.
In the illustrated examples, the electrical power inlet B from the power supply system is provided for supplying the auxiliary components of the system and for charging the battery 11. The battery 11 can also be charged by the fuel cell 5 when it is operative and thus it allows an off-grid operation, i.e. independent, of the entire system 1, thus also in case of power failure.
The dashed lines from the CPU 14 to the valves 6, 7 and to the fans 13 and 16 indicate the signals subjected to the control of the CPU, which can simply be of the on/off or modulated type, depending on the degree of optimization intended to be attained, as well known to a man skilled in the art.
For the sake of representation clarity, the exiting “moist” air (containing water generated by the reaction between hydrogen and oxygen) produced by the fuel cell 5 and by the catalytic burner 4 is not illustrated in the casing 2, just like an air inlet is not illustrated.
Both the operation of catalytic burners and fuel cells is known from the prior art, hence a detailed description of the same shall not be provided herein.
Provided hereinafter is an example for dimensioning a system for producing electrical energy and heat energy according to the invention.
It is intended for providing a system or unit comprising a 1 kW fuel cell 5 and a catalytic burner 4 formed by a 5 kW module of the Applicant, i.e. of the type indicated in WO2006/136316 A1.
Such power allows meeting basic energy needs of a small residential buidling.
The burner 4 for providing the indicated nominal power requires the following hydrogen flow rate:
5 kW/3 kWh/Nm3=1.67 Nm3/h
in which the nominal power is divided by the lowest calorific value of hydrogen.
Regarding the fuel cell 5 there is assumed an overall performance of 40% (as provided for with PEM fuel cells currently available in the market), hence hydrogen consumption shall be equivalent to:
(1 kW/3 kWh/Nm3)/0.4=0.833 Nm3/h
value provided for by the data on the plate of the fuel cells currently available in the market.
However, from the fuel cell 5—during operation—there also develops heat, which can be quantified as follows:
(0.833 Nm3/h*3 kWh/Nm3)—1 kW=1.499 thermal kW.
This heat is usually dispersed by the fan 13 arranged in proximity to the stack, in case of air cooling.
In order to increase the efficiency of the system according to the invention this heat, previously dispersed, and whose temperature is in the order of about 40° C., is recovered.
A first solution, as illustrated in
There is assumed a 75% recovery of such heat by the burner 4. Given that the latter behaves like a normal condensation boiler, it is capable of recovering part of the latent heat of the exhaust “fumes”. Experimental tests indicated a performance equivalent to
The overall thermal potential of the system is thus equivalent to
5 kW*1.07+1.499 kW*0.75=6.474 kW.
The theoretical potential instead amounts to:
(1.67+0.833)Nm3/h*3 kWh/Nm3=7.509 kW.
The overall performance of the system according to the invention shall thus be:
(6.474 kW+1 kW)/7.509 kW*100=99.53%.
The integration of a fuel cell 5 to the burner 4 allowed obtaining an increase of the thermal potential of the system by about 16%, without reducing the yield of the burner 4 per se extremely high (exceeding 100% with reference to the lowest calorific power). In the fuel cell 5 instead, following heat recovery, the yield increases considerably and reaches the value of about 85%, i.e. more than twice the nominal value.
Without the heat recovery of the fuel cell 5 the grouping of the burner 4 and of the fuel cell 5 as indicated would have lead to the following total performance:
(0.4*1.07)*100=42.8%.
Embodiments according to
The system or unit 1, respectively 2, for producing combined energy from hydrogen according to the invention illustrated in
For example,
For such purpose, the most efficient technical solution would be that of providing—in the system 1—the tank 18 for storing hydrogen in form of metal hydrides, inserted as observable in
As illustrated in
The internal storage 18 allows transferring the system 1 according to the invention from one point or station of loading hydrogen into the metallic hydride 18 and then transferring the system to a place where the electrical and/or heat energy is required, like a normal generator. In any case, the internal storage 18 of hydrogen could also serve for an emergency operation, for any reason, in case of a sudden failure of the source of hydrogen, i.e. the electrolysis device, not illustrated.
The further variant illustrated in
The system 1 according to the invention illustrated in the variant of
Two distinct water circuits are preferably provided for a better management of the flows. Furthermore, this variant allows eliminating the risk of “contaminating” the fuel cell 5 with water coming from the heating system, which could contain various types of impurities.
Temperature flows can be controlled by switching the pump 30—for circulating water in the circuit of the cooling water of the fuel cell 5—on and off A more accurate control can be carried out by modulating the speed of the pump 30, i.e. the flow rate thereof
Thus, this embodiment allows obtaining the functional behaviour described previously with the relative further improved performance.
The structural and functional description of the various systems for producing combined energy from hydrogen according to the invention, show that the same allow efficiently attaining both the main object of the present invention and the previously mentioned advantages.
Providing systems for producing combined energy from hydrogen jointly applying the single characteristics of the illustrated embodiments at will falls within the scope of protection of the invention.
The invention may be subjected—by those skilled in the art—to various modifications and variants, such as for example providing for hydrogen supply from cylinders with reducer, for example for emergency systems and units, or providing for internal hydrogen tanks of the pressurized type, proposing uses alternative to the use in residential buildings, such as for example for heating greenhouses, industrial sheds and so on and so forth, without departing from the scope of protection of the present invention, as claimed in the claims that follow.
Number | Date | Country | Kind |
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CO2010A 000037 | Jul 2010 | IT | national |