Most, if not all, polymer zipper systems are made from Olefin-based polymers like polypropylene or polyethylene. Polymer zipper profiles are manufactured using an extrusion process. Olefin-based systems are prevalent in many polymer zipper systems due to the inherent low cost of the polymer resin and its low coefficient of friction properties. A low coefficient of friction is important so that the ball and socket of the zipper can be pushed together with minimal effort. However, Olefin-based zipper systems have their limitations. Most Olefin zipper systems made from polypropylene and polyethylene are not durable when used in exterior environments where temperature extremes affect the performance of the material. Polypropylene and polyethylene zipper profiles lack tensile and tear strength and good elongation properties. They also have excessive compression set when exposed to stress loads at higher temperatures. Therefore, they are not used for extreme applications such as “drybags” and “wet-suits” that are often used in hot environments. Rather, they are used for sandwich bags and other low performance applications.
In one embodiment, a zipper includes a ball portion. The zipper portion further includes a socket portion. The ball portion includes a leading edge, the leading edge composed of a first material having a low coefficient of friction. The ball portion includes a trailing edge and a neck portion, the trailing edge and neck portion composed of a second material. The socket includes a socket opening, the socket opening composed of the first material. The socket includes a socket interior, the socket interior composed of the second material. Optionally, the first and second materials are co-extruded. In one alternative, the zipper further includes a first zipper slide support and a second zipper slide support, the first and second zipper slide supports interconnected with the ball portion and socket portion, respectively, a first body and a second body of the first and second zipper slide supports, respectively, composed of the second material, with a first slide section of the first zipper slide support composed of the first material and a second slide section of the second zipper slide support composed of the first material. Optionally, the zipper includes a first flange portion and a second flange portion, the first and second flange portions interconnected with the first and second zipper slide supports, respectively, the first and second flange portions composed of a third material. In another alternative, the durometer of the second material is higher than the durometer of the first and third materials. Optionally, the durometer of the first material is higher than the durometer of the third material. In another alternative, the first, second, and third materials are Thermoplastic Urethane. Optionally, the first material has a durometer of 74 shore D. Alternatively, the second material has a durometer of 95 shore A. Optionally, the third material has a durometer of 75 shore A. Alternatively, the first, second, and third materials are extruded together as part of a tri-extrusion process; and the first, second, and third materials bond together during the extrusion process as a result of being composed of the sample base thermoplastic. Optionally, the zipper further includes a slide, the slide oriented on the first and second zipper slide supports, the slide operable to close the zipper.
In one embodiment, a method of forming a zipper includes extruding, as part of a tri-extrusion process, a first material, the first material forming a leading edge of a ball portion of the zipper and the first material forming an opening for a socket. The method further includes extruding, as part of the tri-extrusion process, a second material, the second material forming a trailing edge and a neck portion of the ball portion and the second material forming a socket interior of the socket. Optionally, the first material further forms a first slide section of a first zipper slide support and a second slide section of a second zipper slide support and the second material further forms a first body and a second body of the first and second zipper slide supports, respectively, and the first and second zipper slide supports are interconnected with the ball portion and socket portion. Alternatively, the method includes extruding a third material, the third material forming a first flange portion and a second flange portion, the first and second flange portions interconnected with the first and second zipper slide supports, respectively. Optionally, the durometer of the second material is higher than the durometer of the first and third materials. Alternatively, the durometer of the first material is higher than the durometer of the third material. Optionally, the first, second, and third materials are Thermoplastic Urethane. Alternatively, the first material has a durometer of 74 shore D. Optionally, the second material has a durometer of 95 shore A. Alternatively, the third material has a durometer of 75 shore A. Optionally, the first, second, and third materials are extruded together as part of a tri-extrusion process; and the first, second, and third materials bond together during the extrusion process since they are composed of the sample base thermoplastic. Optionally, the method further includes providing a slide, the slide oriented on the first and second zipper slide supports, the slide operable to close the zipper.
a shows another view of the MMEZ of
b shows the MMEZ of
a shows the MMEZ of
b shows the MMEZ of
a and 6b show an exemplary slider to be used with the MMEZ of
Described herein are embodiments of a multi-material extruded zipper (MMEZ) and methods of using it and making it. Essentially, it is advantageous for various parts of the MMEZ to be composed of multiple pieces of thermoplastic that are extruded together, where the multiple pieces of thermoplastic have different characteristics, such as different tensile strength, different elongation properties, and different durometers.
The MMEZ is made from a Thermoplastic Urethane (TPU) material. Unlike Olefin-based plastics, TPUs are crosslinked polymer elastomers that exhibit rubber-like properties at high and low durometers. TPU polymers exhibit extremely high tensile and tear strengths and high elongation properties at high and low temperature extremes. TPU polymers also exhibit superior compression set resistance. TPU polymers are designed for use in extreme outdoor applications.
Unlike polypropylene and polyethylene, TPU does not have a low coefficient of friction (LCOF). Therefore, polymer zipper systems made from TPU need a frequent application of a “wiped-on” lubricant to allow the ball and socket of the zipper to easily seat together (shown as 1a and 1b in
Essentially, the MMEZ is extruded such that areas that require low friction surfaces are extruded to be composed of LCOF material, and materials that require flexibility and high strength are composed of TPU materials.
Note that generally the slide support and the non-LCOF-coated areas of the ball and socket are formed together as a single part. Generally, the zipper 100 may be thought of as including a ball and socket portion including a slide support formed of a first material, an LCOF coating of a second material on low friction areas of the zipper 100, and a flange on either side of the zipper 100 of a third material. All three materials are extruded together using a tri-extrusion manufacturing process. Because each of the materials are TPU-based, they bond together in the extrusion process. Each of the materials exhibit different properties based on their chemical makeup. The first material that forms the ball and socket (and slide support) are made from a 95 shore A durometer TPU. The LCOF coating of the second material is made from a much harder 74 shore D durometer TPU with an LCOF additive. The RF Welding Flanges 140, 145 are made of a softer 75 shore A durometer TPU. Three different materials to accomplish three separate characteristics required in the end product assembly allow the zipper to function correctly. In alternatives, only two materials may be used, a first harder material having an LCOF additive, and a softer material for the ball and socket and flanges. Alternatively, more than three materials may be used and portions of the slide supports may be made harder than the neck and trailing edge of the ball, while still using the other three materials described above. Multiple alternatives will be apparent to those skilled in the art in light of this disclosure.
The LCOF TPU that we use for the areas 220, 225, 230, 235 in
Second, as seen in
Certain areas purposefully do not have the LCOF coating to the areas pointed. Sealing areas 260, 270, 280, 290 need to be more flexible in order to create a proper seal. This is the reason two different materials are used for the main body of the zipper 100 that contains the ball 105 and socket 110. In order for the zipper to properly seal and allow for flexibility in final use, the durometer cannot be above 95 to 100 shore A. At durometers above 100 shore A, it would be too difficult to combine the zipper assembly in normal operation. Therefore, our solution allows us to strategically place a harder LCOF material coating where needed without affecting the function of the zipper assembly.
a shows flanges 130, 135, which may be referred to as “RF Welding Flanges.” MMEZ 100 is designed for use in drybag assemblies, waders, jacket pockets, and other waterproof and water-resistant applications. In order to assemble our MMEZ 100 to the end product, it must be sealed in the assembly. Radio Frequency (RF) welding is used to melt the TPU zipper to the end product. As a note, Olefin-based polymers do not respond to RF welding. Therefore, a TPU-based zipper is required for this application. However, we have determined that a TPU harder than 75 shore A may be too stiff for use in the flanges 130, 135 for this application. MMEZ 100 may work at harder durometers; however, the operation will be difficult and less desirable. When assembled to a thin jacket fabric, the flange makes a pronounced impression 410 in the jacket 420 as shown in
a and 6b show an exemplary slider to be used with the MMEZ. The slider includes upper slider body 610 and track holders 620 and pull receiver 630. Track holders 620 fit into area 22 shown in
The previous detailed description is of a small number of embodiments for implementing the systems and methods for creating a multi-material extruded zipper (MMEZ) and the systems of MMEZs and is not intended to be limiting in scope. The following claims set forth a number of the embodiments of the systems and methods for creating MMEZs and the systems of MMEZs disclosed with greater particularity.
This application is a National Stage of PCT Application No. PCT/US2014/012574 filed on Jan. 22, 2014, which PCT application claims the benefit of U.S. Provisional Application No. 61/756,539 filed Jan. 25, 2013. The above PCT and provisional patent applications are hereby incorporated by reference to the same extent as though fully contained herein.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US14/12574 | 1/22/2014 | WO | 00 |
Number | Date | Country | |
---|---|---|---|
61756539 | Jan 2013 | US |