Embodiments of the present disclosure generally relate to scrubbing air and contaminant removal therefrom.
Indoor air quality (IAQ) is an important consideration for numerous human-occupied spaces including buildings, residential homes, vehicles and other closed spaces occupied by humans. In part, IAQ is affected by various gas contaminants, meaning molecular species that are found indoors at a concentration higher than in natural atmospheric air. Examples of such indoor gas contaminants include carbon dioxide (CO2), carbon monoxide, volatile organic compounds (VOCs) including aldehydes, radon, inorganic compound gases, and even ozone. It is desirable to remove some of these contaminants so as to achieve a better environment for the occupants of the space. One important method of cleaning molecular contaminants from indoor air is the use of scrubbers with regenerable sorbents. These are materials that under certain conditions or temperature, pressure and contaminant concentration capture contaminant molecules (adsorption), also referred to as the adsorbates or the adsorbate species; and in other conditions can release the adsorbates (desorption, outgassing, or regeneration which is used interchangeably herein), thus enabling extended use in a cyclical pattern or adsorption and regeneration, known as a swing adsorption cycle. The “swing” refers to the change in conditions that induced the transition from adsorption to desorption.
In a typical scrubbing application, adsorption is achieved in the scrubber by streaming incoming ambient air through one or more beds of permeable adsorbent material that are placed in the scrubber. After some time, the adsorbent begins to saturate and loses its adsorptive properties, at which point it undergoes regeneration.
In conventional temperature swing adsorption (TSA) and temperature/concentration swing adsorption (TCSA), regeneration is achieved by a combination of heating a sorbent material and flushing it with a purge gas. The heating of the sorbent induces desorption, also referred to as evaporation or outgassing of the adsorbates, further enabled by the flow of purge gas to maintain a low concentration of the contaminant species in the vicinity of the sorbent. Without the flow of gas, the desorption process is suppressed by increasing concentration of the contaminant in the ambient surrounding of the sorbent, which is why the constant flow of the purge gas is essential for effective regeneration.
In some embodiments, the heating of the sorbent may be achieved indirectly, by heating the incoming purge gas, as it may be more difficult to apply heat directly to the sorbent itself. In this scenario, the purge gas serves two functions: heating the sorbent and carrying away the contaminant molecules as they evaporate off of the sorbent.
This form of regeneration requires a substantial amount of energy to continually heat up large amounts of incoming purge gas. Additionally, long cool-down time may be necessary after regeneration before the sorbent can be put back to work as an effective adsorbing agent.
In some embodiments, a close-loop heating, temperature-swing adsorption scrubbing system including a regenerative sorbent material, a fan, a heater, a first inlet having a controllable damper and configured to receive indoor air, a first outlet having a controllable damper and configured to return indoor air that has flowed over and/or through the sorbent, a second outlet having a controllable damper and configured to expel a purging airflow to an external environment, and at least one bypass conduit having a bypass damper and configured to establish a closed loop airflow between the fan, the heater and the sorbent, where the bypass damper is configured to control an airflow in the bypass conduit. The system also includes a controller configured to control the bypass damper, the fan, the heater, and the inlet and outlet dampers so as to allow the system to operate in an adsorption mode, where:
Such embodiments (and other embodiments) can include one and/or another of the following additional features, functionalities, structure, and/or clarifications, leading to still further embodiments of the present disclosure:
In some embodiments, a closed-loop heating, temperature-swing adsorption regenerative scrubbing method is provided and includes providing a scrubbing system including a sorbent material, a plurality of dampers for controlling airflow over and/or through the sorbent according to an absorption mode, a closed-loop heating mode and a flushing mode, first controlling of the plurality of dampers so as to establish flowing an indoor airflow over and/or through the sorbent during the adsorption mode, second controlling of the plurality of dampers so as to establish a closed loop airflow during the closed-loop heating mode, and third controlling of the plurality of dampers so as to establish a purging airflow during the flushing mode.
In some embodiments, an sorbent regeneration method for regenerating a sorbent in a temperature swing adsorption cycle and includes during a closed-loop heating phase, recirculating a closed volume of air over and/or through the sorbent while concurrently heating the recirculating air such that the temperature of the sorbent is gradually increased, the closed volume of air being recirculated for a predetermined duration or until an required sorbent regeneration temperature is reached, and during a purge phase, flowing air from an external air source over and/or through the heated sorbent and exhausting the air to the external environment thereafter, wherein at least one adsorbate species that has previously been adsorbed by the sorbent is removed.
Such embodiments (and other embodiments) can include one and/or another of the following additional features, functionalities, structure, and/or clarifications, leading to still further embodiments of the present disclosure:
These and other embodiments, objects and advantages will be even more understood by reference to the accompanying drawings and detailed description.
The accompanying drawings, which are incorporated in and constitute a part of this specification, exemplify the embodiments of the present invention and, together with the description, serve to explain and illustrate principles of the invention. The drawings are intended to illustrate major features of the exemplary embodiments in a diagrammatic manner. The drawings are not intended to depict every feature of actual embodiments nor relative dimensions of the depicted elements, and are not drawn to scale.
In the following description, various aspects of the present invention will be described with reference to different embodiments. For purposes of explanation, specific configurations and details are set forth in order to provide a thorough understanding of the present invention. However, it will also be apparent to one skilled in the art that the present invention may be practiced without the specific details presented herein. Furthermore, well-known features may be omitted or simplified in order not to obscure the present invention.
In some embodiments, a controllable closed loop for gas circulation creates a multi-step regeneration sequence that separates the heating of the sorbent from the flushing of the adsorbate.
Regeneration occurs in several steps. In some embodiments, a first step is shown in
As long as the external dampers are closed and air is recirculating, the evaporating adsorbate is not removed from the air volume and thus the concentration of adsorbate species in the circulating air increases, to the point that it hinders further evaporation. In other words, the sorbent temperature increases but much of the adsorbate remains on the surface of the sorbent.
In some embodiments, as seen in
In some embodiments, during the open flushing mode the heater may be turned off. As a result, the fresh purge gas is not kept warm, the sorbent gradually cools. Initially the sorbent may continue outgassing its adsorbates; at some point, the outgassing subsides and eventually stops, whether because it is depleted or because the sorbent temperature has decreased.
In some embodiments, if the sorbent cools too quickly, the system can be programmed to switch back to closed loop heating mode and then again to flush mode, and do so multiple times until sufficient amount of adsorbate has been successfully removed from the sorbent. A temperature sensor (not shown) can be installed inside the scrubber to monitor the temperature. Its reading is provided to control circuit that controls the dampers, the fan and the heater, and the circuit is programmed to maintain the desirable duration and temperature of the various phases of the regeneration process.
In designing the closed loop regeneration there is a tradeoff between, on the one hand, maintaining the sorbent without using too much heating power—which requires less fresh purge gas and less exhaust—and on the other hand, removing the evaporated adsorbates from the vicinity of the sorbent so that they do not impede further evaporation or outgassing.
Some embodiments utilize hybrid regeneration to address this tradeoff by introducing partial closed loop circulation. As seen in
The returning purge gas is also augmented by a certain amount of fresh purge gas, whereby the two are mixed, heated (if the heater is on) and then forced to flow through the sorbent. The amount of fresh purge gas naturally equals the amount of exhaust, to balance the net air volume of the scrubber.
In this hybrid or partial closed loop mode, the total airflow through the sorbent is a combination of fresh purge gas with recirculating gas returning through the closed-loop bypass 280. The ratio of exhaust to return air (namely recirculated air), which is determined by the partial or complete opening of dampers along each of the two possible paths, can be modified by controlling the mechanical position of the dampers. In some embodiments, variably controlled dampers are configured and controlled by the electronic control circuits so achieve the desired operating conditions at different stages of the regenerating procedure.
The total airflow comprises a certain percentage Pe of exhaust and a complementary percentage Pr of recirculation, where (by definition) Pe+Pr=100%. It is noted that Pe also represents the percentage of fresh incoming purge gas. As explained above, these percentages can be changed by modifying the positioning of the exhaust damper 241, the inlet damper 221, and/or the bypass damper 281.
When Pe is small compared with Pr, the load on the heating element is small since most of the circulating air has already been heated. However, the rate of dilution of the circulating air is also lower and there could be greater buildup of adsorbate concentration in the circulating air.
In contrast, higher Pe relative to Pr keeps the purge gas more diluted, namely lower adsorbate concentration, but typically requires more heat to maintain its temperature or, alternatively, causes a gradual cool down of the sorbent. A low exhaust ratio, namely low Pe mode, may be referred to as a “bleeding” mode, implying that a small fraction of the recirculating air is “bleeding out” to the exhaust, whereas the majority is recirculated. In some embodiments, a bleeding mode comprises less than 10% exhaust, which implies more than 90% recirculated. In other embodiments, a bleeding mode comprises less than 50% exhaust. In other embodiments, a bleeding mode comprises less than 20% exhaust. In other conditions, the exhaust percentage can be much higher. In some embodiments exhaust exceeds 50%. In some embodiments, exhaust exceeds 80%. In some embodiments, the bleeding mode is enabled by configuring the dampers so as to maintain Pe substantially below Pr.
In some embodiments, regeneration in a closed-loop enabled scrubber comprises a sequence of steps or stages, each characterized by the operational mode of the various dampers, the heater and the fan. In one embodiment, an optimal regeneration sequence may comprise five steps, as follows, in a non-limiting example.
Step 1: Closed-loop heating for 20 minutes, wherein the sorbent approaches a target temperature of 60° C.
Step 2: Bleeding 10% of circulation, heater still on to maintain temperature of 60° C.
Step 3: Bleeding 20% of circulation, heater still on (more dilution required as evaporation rate declines, making evaporation more sensitive to ambient adsorbate concentration).
Step 4: Bleeding 30% of circulation, heater off, slow cool down begins while still outgassing.
Step 5: Open loop purge, bypass damper closed, accelerating cool down while extracting remaining amount of adsorbate.
Another control parameter in regeneration is the total flow, which is controlled by the fan and can be modified by use of a variable speed fan. More flow generally uses more energy but flushes the sorbent more effectively and cools down faster. Flow can be described in terms of absolute rate e.g. CFM or liters per second, or in terms of % (i.e. ratio) of maximum fan speed.
Overall, a regeneration sequence comprises a series of steps or phases, each step may be characterized by:
a) Duration
b) Damper settings, e.g. in terms of % opening relative to fully opened position for each damper
c) Heater setting (typically on/off or a thermostat feedback based on the gas temperature).
d) In case of variable speed fan, the fan speed can be one of the settings of each phase Exemplary regeneration sequences are shown in Tables 1 and 2.
Table 1 shows an exemplary regeneration sequence:
Table 2 shows another exemplary regeneration sequence:
While various inventive embodiments have been described and illustrated herein, those of ordinary skill in the art will readily envision a variety of other means and/or structures for performing the function and/or obtaining the results and/or one or more of the advantages described herein, and each of such variations and/or modifications is deemed to be within the scope of the inventive embodiments described herein. More generally, those skilled in the art will readily appreciate that all parameters, dimensions, materials, and configurations described herein are meant to be an example and that the actual parameters, dimensions, materials, and/or configurations will depend upon the specific application or applications for which the inventive teachings is/are used. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific inventive embodiments described herein. It is, therefore, to be understood that the foregoing embodiments are presented by way of example only and that, within the scope of the appended claims and equivalents thereto; inventive embodiments may be practiced otherwise than as specifically described and claimed. Inventive embodiments of the present disclosure are directed to each individual feature, system, article, material, kit, and/or method described herein. In addition, any combination of two or more such features, systems, articles, materials, kits, and/or methods, if such features, systems, articles, materials, kits, and/or methods are not mutually inconsistent, is included within the inventive scope of the present disclosure. Some embodiments may be distinguishable from the prior art for specifically lacking one or more features/elements/functionality (i.e., claims directed to such embodiments may include negative limitations).
In addition, various inventive concepts may be embodied as one or more methods, of which an example has been provided. The acts performed as part of the method may be ordered in any suitable way. Accordingly, embodiments may be constructed in which acts are performed in an order different than illustrated, which may include performing some acts simultaneously, even though shown as sequential acts in illustrative embodiments.
Any and all references to publications or other documents, including but not limited to, patents, patent applications, articles, webpages, books, etc., presented anywhere in the present application, are herein incorporated by reference in their entirety. Moreover, all definitions, as defined and used herein, should be understood to control over dictionary definitions, definitions in documents incorporated by reference, and/or ordinary meanings of the defined terms.
The indefinite articles “a” and “an,” as used herein in the specification and in the claims, unless clearly indicated to the contrary, should be understood to mean “at least one.”
The phrase “and/or,” as used herein in the specification and in the claims, should be understood to mean “either or both” of the elements so conjoined, i.e., elements that are conjunctively present in some cases and disjunctively present in other cases. Multiple elements listed with “and/or” should be construed in the same fashion, i.e., “one or more” of the elements so conjoined. Other elements may optionally be present other than the elements specifically identified by the “and/or” clause, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, a reference to “A and/or B”, when used in conjunction with open-ended language such as “comprising” can refer, in one embodiment, to A only (optionally including elements other than B); in another embodiment, to B only (optionally including elements other than A); in yet another embodiment, to both A and B (optionally including other elements); etc.
As used herein in the specification and in the claims, “or” should be understood to have the same meaning as “and/or” as defined above. For example, when separating items in a list, “or” or “and/or” shall be interpreted as being inclusive, i.e., the inclusion of at least one, but also including more than one, of a number or list of elements, and, optionally, additional unlisted items. Only terms clearly indicated to the contrary, such as “only one of” or “exactly one of,” or, when used in the claims, “consisting of,” will refer to the inclusion of exactly one element of a number or list of elements. In general, the term “or” as used herein shall only be interpreted as indicating exclusive alternatives (i.e. “one or the other but not both”) when preceded by terms of exclusivity, such as “either,” “one of” “only one of” or “exactly one of” “Consisting essentially of,” when used in the claims, shall have its ordinary meaning as used in the field of patent law.
As used herein in the specification and in the claims, the phrase “at least one,” in reference to a list of one or more elements, should be understood to mean at least one element selected from any one or more of the elements in the list of elements, but not necessarily including at least one of each and every element specifically listed within the list of elements and not excluding any combinations of elements in the list of elements. This definition also allows that elements may optionally be present other than the elements specifically identified within the list of elements to which the phrase “at least one” refers, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, “at least one of A and B” (or, equivalently, “at least one of A or B,” or, equivalently “at least one of A and/or B”) can refer, in one embodiment, to at least one, optionally including more than one, A, with no B present (and optionally including elements other than B); in another embodiment, to at least one, optionally including more than one, B, with no A present (and optionally including elements other than A); in yet another embodiment, to at least one, optionally including more than one, A, and at least one, optionally including more than one, B (and optionally including other elements); etc.
In the claims, as well as in the specification above, all transitional phrases such as “comprising,” “including,” “carrying,” “having,” “containing,” “involving,” “holding,” “composed of,” and the like are to be understood to be open-ended, i.e., to mean including but not limited to. Only the transitional phrases “consisting of” and “consisting essentially of” shall be closed or semi-closed transitional phrases, respectively, as set forth in the United States Patent Office Manual of Patent Examining Procedures, Section 2111.03.
This application is a 35 U.S.C. § 371 national stage entry of PCT/US2017/028444, filed Apr. 19, 2017, titled “Systems and Methods for Closed-Loop Heating and Regeneration of Sorbents”, which claims priority to U.S. Provisional Patent Application No. 62/324,349, entitled “Partial Closed Loop Regeneration,” filed Apr. 19, 2016, which is incorporated by reference herein in its entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2017/028444 | 4/19/2017 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2017/184780 | 10/26/2017 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
1522480 | Allen | Jan 1925 | A |
1836301 | Bechthold | Dec 1931 | A |
2633928 | Chamberlain | Apr 1953 | A |
3042497 | Johnson et al. | Jul 1962 | A |
3107641 | Haynes | Oct 1963 | A |
3344050 | Mayland et al. | Sep 1967 | A |
3511595 | Fuchs | May 1970 | A |
3594983 | Yearout | Jul 1971 | A |
3619130 | Ventriglio et al. | Nov 1971 | A |
3702049 | Morris, Jr. | Nov 1972 | A |
3751848 | Ahlstrand | Aug 1973 | A |
3751878 | Collins | Aug 1973 | A |
3795090 | Barnebey | Mar 1974 | A |
3808773 | Reyhing et al. | May 1974 | A |
3885927 | Sherman et al. | May 1975 | A |
3885928 | Wu | May 1975 | A |
4182743 | Rainer et al. | Jan 1980 | A |
4228197 | Means | Oct 1980 | A |
4249915 | Sirkar et al. | Feb 1981 | A |
4292059 | Kovach | Sep 1981 | A |
4322394 | Mezey et al. | Mar 1982 | A |
4325921 | Aiken et al. | Apr 1982 | A |
4409006 | Mattia | Oct 1983 | A |
4433981 | Slaugh et al. | Feb 1984 | A |
4451435 | Hölter et al. | May 1984 | A |
4472178 | Kumar et al. | Sep 1984 | A |
4530817 | Hölter et al. | Jul 1985 | A |
4551304 | Holter et al. | Nov 1985 | A |
4559066 | Hunter et al. | Dec 1985 | A |
4711645 | Kumar et al. | Dec 1987 | A |
4810266 | Zinnen et al. | Mar 1989 | A |
4816043 | Harrison | Mar 1989 | A |
4863494 | Hayes | Sep 1989 | A |
4892719 | Gesser | Jan 1990 | A |
4917862 | Kraw et al. | Apr 1990 | A |
4976749 | Adamski et al. | Dec 1990 | A |
4987952 | Beal et al. | Jan 1991 | A |
5046319 | Jones | Sep 1991 | A |
5087597 | Leal et al. | Feb 1992 | A |
5109916 | Thompson | May 1992 | A |
5137548 | Grenier et al. | Aug 1992 | A |
5149343 | Sowinski | Sep 1992 | A |
5186903 | Cornwell | Feb 1993 | A |
5194158 | Matson | Mar 1993 | A |
5221520 | Cornwell | Jun 1993 | A |
5231063 | Fukumoto et al. | Jul 1993 | A |
5281254 | Birbara et al. | Jan 1994 | A |
5290345 | Osendorf et al. | Mar 1994 | A |
5292280 | Janu et al. | Mar 1994 | A |
5322473 | Hofstra et al. | Jun 1994 | A |
5352274 | Blakley | Oct 1994 | A |
5376614 | Birbara et al. | Dec 1994 | A |
5389120 | Sewell et al. | Feb 1995 | A |
5407465 | Schaub et al. | Apr 1995 | A |
5443625 | Schaffhausen | Aug 1995 | A |
5464369 | Federspiel | Nov 1995 | A |
5471852 | Meckler | Dec 1995 | A |
5492683 | Birbara et al. | Feb 1996 | A |
5584916 | Yamashita et al. | Dec 1996 | A |
5614000 | Kalbassi et al. | Mar 1997 | A |
5646304 | Acharya et al. | Jul 1997 | A |
5672196 | Acharya et al. | Sep 1997 | A |
5675979 | Shah | Oct 1997 | A |
5702505 | Izumi et al. | Dec 1997 | A |
5707005 | Kettler et al. | Jan 1998 | A |
5827355 | Wilson | Oct 1998 | A |
5869323 | Horn | Feb 1999 | A |
5876488 | Birbara et al. | Mar 1999 | A |
5904896 | High | May 1999 | A |
5948355 | Fujishima et al. | Sep 1999 | A |
5964927 | Graham et al. | Oct 1999 | A |
5984198 | Bennett et al. | Nov 1999 | A |
6024781 | Bülow et al. | Feb 2000 | A |
6027550 | Vickery | Feb 2000 | A |
6102793 | Hansen | Aug 2000 | A |
6113674 | Graham et al. | Sep 2000 | A |
6120581 | Markovs et al. | Sep 2000 | A |
6123617 | Johnson | Sep 2000 | A |
6187596 | Dallas et al. | Feb 2001 | B1 |
6254763 | Izumi et al. | Jul 2001 | B1 |
6280691 | Homeyer et al. | Aug 2001 | B1 |
6364938 | Birbara et al. | Apr 2002 | B1 |
6375722 | Henderson et al. | Apr 2002 | B1 |
6402809 | Monereau et al. | Jun 2002 | B1 |
6428608 | Shah et al. | Aug 2002 | B1 |
6432367 | Munk | Aug 2002 | B1 |
6432376 | Choudhary et al. | Aug 2002 | B1 |
6533847 | Seguin et al. | Mar 2003 | B2 |
6547854 | Gray et al. | Apr 2003 | B1 |
6605132 | Fielding | Aug 2003 | B2 |
6623550 | Dipak et al. | Sep 2003 | B2 |
6711470 | Hartenstein et al. | Mar 2004 | B1 |
6726558 | Meirav | Apr 2004 | B1 |
6773477 | Lindsay | Aug 2004 | B2 |
6796896 | Laiti | Sep 2004 | B2 |
6797246 | Hopkins | Sep 2004 | B2 |
6866701 | Meirav | Mar 2005 | B2 |
6908497 | Sirwardane | Jun 2005 | B1 |
6916239 | Siddaramanna et al. | Jul 2005 | B2 |
6916360 | Seguin et al. | Jul 2005 | B2 |
6930193 | Yaghi et al. | Aug 2005 | B2 |
6964692 | Gittleman et al. | Nov 2005 | B2 |
6974496 | Wegeng et al. | Dec 2005 | B2 |
7288136 | Gray et al. | Oct 2007 | B1 |
7407533 | Steins | Aug 2008 | B2 |
7407633 | Potember et al. | Aug 2008 | B2 |
7449053 | Hallam | Nov 2008 | B2 |
7472554 | Vosburgh | Jan 2009 | B2 |
7645323 | Massenbauer-Strafe et al. | Jan 2010 | B2 |
7662746 | Yaghi et al. | Feb 2010 | B2 |
7666077 | Thelen | Feb 2010 | B1 |
7802443 | Wetzel | Sep 2010 | B2 |
7846237 | Wright et al. | Dec 2010 | B2 |
7891573 | Finkam et al. | Feb 2011 | B2 |
8157892 | Meirav | Apr 2012 | B2 |
8210914 | McMahan et al. | Jul 2012 | B2 |
8317890 | Raether et al. | Nov 2012 | B2 |
8398753 | Sergi et al. | Mar 2013 | B2 |
8491710 | Meirav | Jul 2013 | B2 |
8690999 | Meirav et al. | Apr 2014 | B2 |
8734571 | Golden et al. | May 2014 | B2 |
9316410 | Meirav et al. | Apr 2016 | B2 |
9328936 | Meirav et al. | May 2016 | B2 |
9399187 | Meirav et al. | Jul 2016 | B2 |
9566545 | Meirav et al. | Feb 2017 | B2 |
9802148 | Meirav et al. | Oct 2017 | B2 |
9919257 | Meirav et al. | Mar 2018 | B2 |
9939163 | Meirav et al. | Apr 2018 | B2 |
9950290 | Meirav et al. | Apr 2018 | B2 |
9976760 | Meirav et al. | May 2018 | B2 |
9987584 | Meirav et al. | Jun 2018 | B2 |
10046266 | Meirav et al. | Aug 2018 | B2 |
10086324 | Meirav | Oct 2018 | B2 |
10281168 | Meirav et al. | May 2019 | B2 |
10525401 | Meirav et al. | Jan 2020 | B2 |
10675582 | Meirav et al. | Jun 2020 | B2 |
10730003 | Meirav | Aug 2020 | B2 |
10765990 | Meirav et al. | Sep 2020 | B2 |
10792608 | Meirav et al. | Oct 2020 | B2 |
10850224 | Meirav et al. | Dec 2020 | B2 |
10913026 | Meirav et al. | Feb 2021 | B2 |
20010021363 | Poles et al. | Sep 2001 | A1 |
20010054415 | Hanai et al. | Dec 2001 | A1 |
20020056373 | Fielding | May 2002 | A1 |
20020078828 | Kishkovich et al. | Jun 2002 | A1 |
20020083833 | Nalette et al. | Jul 2002 | A1 |
20020147109 | Branover et al. | Oct 2002 | A1 |
20020183201 | Barnwell et al. | Dec 2002 | A1 |
20020193064 | Michalakos et al. | Dec 2002 | A1 |
20030037672 | Sircar | Feb 2003 | A1 |
20030041733 | Sequin et al. | Mar 2003 | A1 |
20030097086 | Gura | May 2003 | A1 |
20030188745 | Deas et al. | Oct 2003 | A1 |
20040005252 | Siess | Jan 2004 | A1 |
20040020361 | Pellegrin | Feb 2004 | A1 |
20040069144 | Wegeng et al. | Apr 2004 | A1 |
20040118287 | Jaffe et al. | Jun 2004 | A1 |
20050133196 | Gagnon et al. | Jun 2005 | A1 |
20050147530 | Kang et al. | Jul 2005 | A1 |
20050191219 | Uslenghi et al. | Sep 2005 | A1 |
20050262869 | Tongu et al. | Dec 2005 | A1 |
20050284291 | Alizadeh-Khiavi et al. | Dec 2005 | A1 |
20050288512 | Butters et al. | Dec 2005 | A1 |
20060032241 | Gontcharov et al. | Feb 2006 | A1 |
20060054023 | Raetz et al. | Mar 2006 | A1 |
20060079172 | Fleming et al. | Apr 2006 | A1 |
20060112708 | Reaves | Jun 2006 | A1 |
20060148642 | Ryu et al. | Jul 2006 | A1 |
20060225569 | Schmidt et al. | Oct 2006 | A1 |
20060236867 | Neary | Oct 2006 | A1 |
20060249019 | Roychoudhury et al. | Nov 2006 | A1 |
20080119356 | Ryu et al. | Mar 2008 | A1 |
20080078289 | Sergi et al. | Apr 2008 | A1 |
20080127821 | Noack et al. | Jun 2008 | A1 |
20080135060 | Kuo et al. | Jun 2008 | A1 |
20080173035 | Thayer et al. | Jul 2008 | A1 |
20080182506 | Jackson et al. | Jul 2008 | A1 |
20080210768 | You | Sep 2008 | A1 |
20080216653 | Paton-Ash et al. | Sep 2008 | A1 |
20080293976 | Olah et al. | Nov 2008 | A1 |
20090000621 | Haggblom et al. | Jan 2009 | A1 |
20090044704 | Shen et al. | Feb 2009 | A1 |
20090071062 | Hedman | Mar 2009 | A1 |
20090120288 | Lackner et al. | May 2009 | A1 |
20090188985 | Scharing et al. | Jul 2009 | A1 |
20090214902 | Pelman | Aug 2009 | A1 |
20090220388 | Monzyk et al. | Sep 2009 | A1 |
20090260372 | Skinner et al. | Oct 2009 | A1 |
20100076605 | Harrod et al. | Mar 2010 | A1 |
20100154636 | Liu et al. | Jun 2010 | A1 |
20100224565 | Dunne et al. | Sep 2010 | A1 |
20100254868 | Obee et al. | Oct 2010 | A1 |
20100262298 | Johnson et al. | Oct 2010 | A1 |
20100275775 | Griffiths et al. | Nov 2010 | A1 |
20100278711 | Find | Nov 2010 | A1 |
20110064607 | Hedman | Mar 2011 | A1 |
20110079143 | Marotta et al. | Apr 2011 | A1 |
20110085933 | Mazyek et al. | Apr 2011 | A1 |
20110146494 | Desai et al. | Jun 2011 | A1 |
20110179948 | Choi et al. | Jul 2011 | A1 |
20110189075 | Wright et al. | Aug 2011 | A1 |
20110192172 | Delacruz | Aug 2011 | A1 |
20110206572 | McKenna et al. | Aug 2011 | A1 |
20110250121 | Schmidt | Oct 2011 | A1 |
20110262327 | Dillon et al. | Oct 2011 | A1 |
20110269919 | Min et al. | Nov 2011 | A1 |
20110277490 | Meirav | Nov 2011 | A1 |
20110296872 | Eisenberger | Dec 2011 | A1 |
20120004092 | Raatschen et al. | Jan 2012 | A1 |
20120012005 | Burke | Jan 2012 | A1 |
20120052786 | Clawsey | Mar 2012 | A1 |
20120076711 | Gebald et al. | Mar 2012 | A1 |
20120129267 | Daly | May 2012 | A1 |
20120137876 | Miller | Jun 2012 | A1 |
20120148858 | Wu | Jun 2012 | A1 |
20120152116 | Barclay et al. | Jun 2012 | A1 |
20120168113 | Karamanos | Jul 2012 | A1 |
20120216676 | Addiego et al. | Aug 2012 | A1 |
20120222500 | Riess et al. | Sep 2012 | A1 |
20120271460 | Rognili | Oct 2012 | A1 |
20120272966 | Ando et al. | Nov 2012 | A1 |
20120311926 | Mittelmark | Dec 2012 | A1 |
20120321511 | Lorcheim | Dec 2012 | A1 |
20130052113 | Molins et al. | Feb 2013 | A1 |
20130291732 | Meirav | Nov 2013 | A1 |
20130331021 | Rodell | Dec 2013 | A1 |
20140013956 | Ericson et al. | Jan 2014 | A1 |
20140242708 | Lundgren | Aug 2014 | A1 |
20140298996 | Meirav et al. | Oct 2014 | A1 |
20150078964 | Meirav et al. | Mar 2015 | A1 |
20150258488 | Meirav | Sep 2015 | A1 |
20150297771 | Law et al. | Oct 2015 | A1 |
20160228811 | Meirav et al. | Aug 2016 | A1 |
20160271556 | Okano | Sep 2016 | A1 |
20160363333 | Meirav et al. | Dec 2016 | A1 |
20170227241 | Claesson et al. | Aug 2017 | A1 |
20180147526 | Meirav et al. | May 2018 | A1 |
20180187907 | Meirav et al. | Jul 2018 | A1 |
20180236396 | Meirav et al. | Aug 2018 | A1 |
20180264396 | Meirav et al. | Sep 2018 | A1 |
20180339261 | Meirav et al. | Nov 2018 | A1 |
20180339262 | Perl-Olshvang et al. | Nov 2018 | A1 |
20190186762 | Meirav et al. | Jun 2019 | A1 |
20190247782 | Meirav et al. | Aug 2019 | A1 |
20190262761 | Meirav | Aug 2019 | A1 |
20190299154 | Meirav et al. | Oct 2019 | A1 |
20190344211 | Meirav et al. | Nov 2019 | A1 |
20190346161 | Meirav et al. | Nov 2019 | A1 |
20200139294 | Meirav et al. | May 2020 | A1 |
20200166235 | Marra et al. | May 2020 | A1 |
Number | Date | Country |
---|---|---|
2 640 152 | Apr 2010 | CA |
2141873 | Sep 1993 | CN |
2612444 | Apr 2004 | CN |
2729562 | Sep 2005 | CN |
1872388 | Dec 2006 | CN |
101001767 | Jul 2007 | CN |
101072620 | Nov 2007 | CN |
200993448 | Dec 2007 | CN |
101199913 | Jun 2008 | CN |
101444693 | Jun 2009 | CN |
101500704 | Aug 2009 | CN |
101564634 | Oct 2009 | CN |
201363833 | Dec 2009 | CN |
201618493 | Nov 2010 | CN |
102233217 | Nov 2011 | CN |
202032686 | Nov 2011 | CN |
202270445 | Jun 2012 | CN |
103119376 | May 2013 | CN |
102006048716 | Feb 2008 | DE |
0 475 493 | Mar 1992 | EP |
2 465 596 | Jun 2012 | EP |
2 387 791 | Oct 2012 | ES |
56-158126 | Dec 1981 | JP |
59-225232 | Dec 1984 | JP |
60-194243 | Oct 1985 | JP |
02-092373 | Apr 1990 | JP |
03-207936 | Sep 1991 | JP |
05-161843 | Jun 1993 | JP |
06-031132 | Feb 1994 | JP |
08-114335 | May 1996 | JP |
09-085043 | Mar 1997 | JP |
2000-202232 | Jul 2000 | JP |
2000-291978 | Oct 2000 | JP |
2001-170435 | Jun 2001 | JP |
2001-232127 | Aug 2001 | JP |
3207936 | Sep 2001 | JP |
2004-150778 | May 2004 | JP |
2005-090941 | Apr 2005 | JP |
2006-275487 | Oct 2006 | JP |
2009-150623 | Jul 2009 | JP |
2009-202137 | Sep 2009 | JP |
2010-149086 | Jul 2010 | JP |
2015-148227 | Aug 2015 | JP |
WO 8805693 | Aug 1988 | WO |
WO 0208160 | Jan 2002 | WO |
WO 0212796 | Feb 2002 | WO |
WO 2006016345 | Feb 2006 | WO |
WO 2007128584 | Nov 2007 | WO |
WO 2008155543 | Dec 2008 | WO |
WO 2009126607 | Oct 2009 | WO |
WO 2010091831 | Aug 2010 | WO |
WO 2010124388 | Nov 2010 | WO |
WO 2011114168 | Sep 2011 | WO |
WO 2011146478 | Nov 2011 | WO |
WO 2012071475 | May 2012 | WO |
WO 2012100149 | Jul 2012 | WO |
WO 2012120173 | Sep 2012 | WO |
WO 2012134415 | Oct 2012 | WO |
WO 2012145303 | Oct 2012 | WO |
WO 2012152930 | Nov 2012 | WO |
WO 2012158911 | Nov 2012 | WO |
WO 2013012622 | Jan 2013 | WO |
WO 2013074973 | May 2013 | WO |
WO 2013106573 | Jul 2013 | WO |
WO 2014015138 | Jan 2014 | WO |
WO 2014047632 | Mar 2014 | WO |
WO 2014078708 | May 2014 | WO |
WO 2014153333 | Sep 2014 | WO |
WO 2014176319 | Oct 2014 | WO |
WO 2015042150 | Mar 2015 | WO |
WO 2015123454 | Aug 2015 | WO |
WO 2017019628 | Feb 2017 | WO |
Entry |
---|
Ashrae. ANSI/Ashrae Standard 62.1-2013 Ventilation for Acceptable Indoor Air Quality. American Society of Heating, Refrigerating and Air-Conditioning Engineers, Inc., Atlanta, GA; 2013, 58 pages. |
Bennett, D. et al. (Oct. 2011) Indoor Environmental Quality and Heating, Ventilating, and Air Conditioning Survey of Small and Medium Size Commercial Buildings: Field Study. California Energy Commission. CEC-500-2011-043, 233 pages. |
Gesser, H.D., “The Reduction of Indoor Formaldehyde Gas and that Emanating from Urea Formaldehyde Foam Insulation,” Environmental International, 10:305-308 (1984). |
Goeppert, A. et al., “Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent,” J. Am. Chem. Soc., 133:20164-20167 (2011). |
Gray, M.L. et al., “Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide,” International Journal of Greenhouse Gas Control, 2:3-8 (2008). |
Hodgson, A.T. and Levin, H. (Apr. 21, 2003) Volatile Organic Compounds in Indoor Air: A Review of Concentrations Measured in North America Since 1990. Report LBNL-51715, Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 31 pages. |
Hotchi, T. et al. (Jan. 2006) “Indoor Air Quahty Impacts of a Peak Load Shedding Strategy for a Large Retail Building” Report LBNL-59293. Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 17 pages. |
Jones, C.W., “CO2 Capture from Dilute Gases as a Component of Modern Global Carbon Management,” Annu. Rev. Chem. Biomol. Eng., 2:31-52 (2011). |
Kang, D-H. et al. (Jun. 14, 2007) “Measurements of VOCs emission rate from building materials during bakeout with passive sampling methods” Clima 2007 WellBeing Indoors, REHVA World Congress, Jun. 10-14, 2007, Helsinki, Finland. O. Seppänen and J. Säteri (Eds.) FINVAC [online]. Retrieved from: http://www.inive.org/members_area/medias/pdf/Inive%5Cclima2007%5CA12%5CA12C1334.pdf, 6 pages. |
Ma, C. et al., “Removal of low-concentration formaldehyde in air by adsorption on activated carbon modified by hexamethylene diamine,” Carbon, 49:2873-2875 (2011). |
Nuckols, M. L. et al., Technical Manual: Design Guidelines for Carbon Dioxide Scrubbers. Naval Coastal Systems Center, NCSC Tech Man 4110, Revision A, Jul. 1985, 10 pages. |
Offerman, F.J. et al. (1991) “A Pilot Study to Measure Indoor Concentrations and Emmission Rates of Polycyclic Aromatic Hydrocarbons” Indoor Air, 4:497-512. |
Serna-Guerrero, R. et al., “Triamine-grafted pore-expanded mesoporous silica for CO2 capture: Effect of moisture and adsorbent regeneration strategies,” Adsorption, 16:567-575 (2010). |
Sidheswaran, M.A. et al., “Energy efficient indoor VOC air cleaning with activated carbon filter (ACF) filters,” Building and Environment, 47:357-367 (2012). |
United States Environmental Protection Agency, “Carbon Adsorption for Control of VOC Emissions: Theory and Full Scale System Performance”, EPA-450/3-88-012, Jun. 1988, 84 pages. |
United States Environmental Protection Agency, “EPA Ventilation and Air Quality in Offices, Fact Sheet” Air and Radiation (6609J), 402-F-94-003, Revised Jul. 1990, 4 pages. |
Wu, X. et al. (2011) “Volatile Organic Compounds in Small- and Medium-Sized Commercial Buildings in California. Suporting Information” Environ Sci Technol, 45(20):S1-S29 [online]. Retrieved from: https://pubs.acs.org/doi/suppl/10.1021/es202132u/suppl_file/es202132u_si_001.pdf. |
Zorflex® ACC, 100% Activated Woven Carbon Cloth. Calgon Carbon Corporation, 2008, www.calgoncarbon.com, 2 pages. |
Zorflex® ACC, 100% Activated Woven Carbon Cloth, Calgon Carbon Corporation, 2011, www.calgoncarbon.com, 2 pages. |
International Preliminary Examination Report on Patentability dated Oct. 23, 2018, for International Patent Application No. PCT/US2017/028444, by Enverid Systems, Inc., 9 pages. |
International Search Report and Written Opinion, dated Jul. 18, 2017, for PCT/US2017/28444, by Enverid Systems, Inc., 10 pages. |
Pickenpaugh, Joseph G., Capt (Mar. 2013) Assessment of Potential Carbon Dioxide-Based Demand Control Ventilation System Performance in Single Zone Systems. Thesis, Air Force Institute of Technology. https://apps.dtic.mil/dtic/tr/fulltext/u2/a576145.pdf; 105 pages. |
Number | Date | Country | |
---|---|---|---|
20190143258 A1 | May 2019 | US |
Number | Date | Country | |
---|---|---|---|
62324349 | Apr 2016 | US |