Building foundations, highway tunnels, pipelines, and many other areas of the nation's infrastructure rely on adequate corrosion performance of buried metal. A representative example is provided by mechanically stabilized earth walls (MSEW), which are critical structural components in nearly all highways. The walls are often reinforced with galvanized steel buried in the soil. Voids sometimes occur in the soil and are typically filled with cement-based, hardened, controlled low-strength material (CLSM). In such cases, soil/CLSM electrochemical macrocells may develop and aggravate reinforcement corrosion.
Half-cell potential surveys of the soil, CLSM, and similar surfaces can be used for non-destructive corrosion monitoring by identifying macroscopic anodic and cathodic regions. Potential measurements can also serve to diagnose and adjust cathodic protection systems if they are needed for corrosion control. Such potential measurements commonly use conventional copper-copper(II) sulfate electrodes (CSEs), which require physical contact with the surface (and its disturbance) as well as waiting times to have a stable reading, which are both disadvantages in extensive surveys. It would, therefore, be desirable to have alternative systems and methods for monitoring buried reinforcement structures that do not have these drawbacks.
The present disclosure may be better understood with reference to the following figures. Matching reference numerals designate corresponding parts throughout the figures, which are not necessarily drawn to scale.
As described above, it would be desirable to have alternative systems and methods for monitoring reinforcement structures buried in soil. Disclosed herein are embodiments of such systems and methods. In some embodiments, the disclosed systems utilize Kelvin probes to measure soil surface electrical potentials so that a contactless measurement procedure can be performed that does not depend upon a shared electrolyte and that is inherently non-disruptive to the region sampled by the probe.
In the following disclosure, various specific embodiments are described. It is to be understood that those embodiments are example implementations of the disclosed inventions and that alternative embodiments are possible. All such embodiments are intended to fall within the scope of this disclosure.
A fast, contactless corrosion assessment system based on the Kelvin probe principle is disclosed herein. The concept, applied here for the first time for soil and CLSM measurements, is also explored for possible monitoring of cathodic protection in soils. As described below, the probe does not require contact with the soil surface and provides nearly instantaneous readings. With such a system, applications for fast monitoring of large installations or over long distances from moving vehicles for monitoring of pipelines or other extended systems can be a reality.
A Kelvin probe is essentially a parallel-plate capacitor having one vibrating side that is used to determine the natural potential difference between a sensing electrode shaped like a disk or comparable configuration (hereafter referred to for brevity as a disk) and a sample surface. By recording the potential required to null the current generated by the Kelvin probe's sensing disk, a map of surface potentials can be obtained.
Kelvin probes determine the potential difference E between two surfaces designated as the working surface and the reference surface, respectively. In the case of reinforced soil, the working surface is a small (top) portion of the outer soil surface and the reference surface is the surface on one side of a macroscopically small (e.g., approximately 10-centimeter (cm) diameter) electrode (e.g., disk) made of a suitable metallic material, for example, gold or stainless steel with a stable passive film, or even galvanized steel if its surface condition is stable enough. The disk and the soil surface are spaced a small (relative to the disk dimensions) distance, h, apart so as to approximate a parallel-plate capacitor configuration. The disk is electrically connected through electrical conductors (e.g., wires) to the metallic reinforcement structure, such as galvanized steel bars (referred to in the following for brevity as steel), buried in the soil or soil filler material. The steel bar surface is electrically connected to the external surface of the soil by an electrolytic path provided mainly by the water in the soil. Consequently, the soil and the reference (disk) surfaces are joined through an electronic and electrolytic conductive path with associated interfaces that determine the value of E. The relationship linking electrical charge Q and potential difference E across a capacitor with capacitance C is
Q=E·C Equation 1
For plates spaced by a small gap, the capacitance can be approximated by
C=ε·ε0·A/h Equation 2
where ε is the dielectric constant of the medium in the gap between the plates (normally air, ε˜1), ε0 is the permittivity of vacuum, and A is the one-sided surface area of the smaller of the plates, in this case the reference surface. Because E is fixed by the characteristics of the intervening conducting and interfacial chain, if h is changed from one static position to another, the value of Q changes as well to satisfy Equations 1 and 2. In the Kelvin probe, h is cyclically varied with time by attaching the reference disk to the end of an electrically-insulating, longitudinally-vibrating stem. Consequently, Q changes cyclically as well, resulting in an alternating current IA circulating through the conductive path. If a potential source with a known potential E′ selected at will is inserted in that path (e.g., into a break made in the connecting wire to the rebar), the potential between the reference and soil surface becomes E+E′. When E′=−E, the potential across the capacitor is zero and the alternating current vanishes. This then permits determining the value of E by varying E′ until IA=0, a condition that can be reached with great sensitivity by adequate electronic amplification. The zeroing process can be made manually or performed automatically and promptly with ordinary control circuitry, yielding an immediate record of the value of E.
With interfaces having well-defined boundaries and locally-uniform electric charge profiles, the potential E measured by the Kelvin probe is the difference between the Volta (outer) potential ΨR of the reference surface and the Volta potential of ΨW of the working surface being examined
E=ΨR−ΨW Equation 3
The metallic reference disk generally approximates those conditions and may be considered to have a well-defined, spatially averaged ΨR value. The soil or soil void filler surface is quite heterogeneous, as is the distribution of the electrolyte responsible for much of the electric charge configuration in the material. Hence, ΨW can be considered only as an effective value, i.e., that of an ideal conductor that would yield the same experimental results as those obtained with the soil. Thus, ΨW may be viewed as representing an approximate average of the potential of the surface of the soil beneath the footprint of the reference surface disk. Lateral heterogeneity up to the centimeter scale (pore space-soil or soil void filler particles domain) is expected to be reasonably averaged beneath the disk, but some sensitivity to the distribution of the soil components which can be greater than several centimeters, can be anticipated.
The value of E measured by the Kelvin probe can be determined by the system schematically illustrated in
E=X′WS+XSR−XARXAWΔΦW Equation 4
Supported by the outer housing 18 is a Kelvin probe 24 that comprises a vibration generator 26, a stem 28 that extends from the vibration generator, and a dry reference electrode 30 that is mounted to a distal tip of the stem. In some embodiments, the vibrating generator 26 comprises an electromagnetic voice coil that linearly displaces the stem 28, and therefore the reference electrode (see double-headed arrow), in response to a magnetic field generated from current passing through the coil. As is also shown in
The reference electrode 30 can comprise a metal disk or alternatively shaped element having a diameter or equivalent dimension ranging from several millimeters to several centimeters. Irrespective of its shape or size, the electrode 30 has a planar outer surface that faces the soil surface 20. Example metals include pure, corrosion-resistant metals, such as gold, and metal alloys, such as stainless steel, that may require a passive film for corrosion resistance, or other electrically conducting materials if stable enough surface conditions exist. The stem 28 can comprise a shaft of an insulating material that is not prone to static charge buildup, such as a polymeric material or wood. Provided within the housing 18 along with the vibration generator 26 is a preamplifier 34 that is electrically coupled to the reference electrode 30, for example with a conductive wire 36.
The reinforced soil assessment system 10 further comprises a control unit 38 that controls operation of the system. While the control unit 38 can be separate from the measurement unit 16 as shown in
As shown in
As the reference electrode 30 oscillates, electrical signals from the electrode are amplified by the preamplifier 34 and captured by the control unit 38, which stores them within memory 42. Optionally, the signals are first processed by the processing device 40 to identify the electrical potential E represented by the signals. The electrical potential can also be displayed to the user with the display 46.
As mentioned above, the non-contact reinforced soil assessment system can comprise wheels instead of feet to enable the system to be moved along the soil surface.
Unlike the system 10, however, the system 60 is adapted to be moved (e.g., pulled) across the soil surface 20 (e.g., by a motorized vehicle) in the direction indicated by the arrow 62. Accordingly, wheels 64 are mounted to the measurement unit 16 to enable it to roll across the soil surface 20. In some embodiments, force distribution members, such as planks of cardboard, wood, or another rigid material can be positioned beneath the wheels to distribute the force applied to the soil surface 20 by the wheels. Alternatively, continuous track assemblies (not shown) can be used to distribute the force. Other controlled-height, hovering, and suspension arrangements, such as very low altitude flight drones, can be used as well.
As is further illustrated in
Because measurements are taken at multiple points along the length of the soil surface 20, it is important to determine where each measurement was taken. To this end, the control unit 38 can be electrically coupled with another electrical conductor 72 to a distance measurement device (not shown) mounted to the axle 68 of one of the wheels 64. With such a device, the angular position of the wheel 64 at the point at which each measurement is taken can be recorded and, with knowledge of the diameter of the wheel 64, can be converted into a linear distance.
As is further shown in
Testing was conducted to confirm the viability of the above-described designs on soil. As shown in
The Kelvin probe's ability to measure surface potentials of soil and CLSM systems was examined by comparing results to measurements with a conventional CSE. The tests also evaluated the ability of the probe to monitor time-dependent potentials, as may be used for adjustment of a cathodic protection system for soil reinforcement.
The soil and CLSM regions were moderately leveled before testing to prevent accidental contact with the Kelvin probe sensing disk and the soil or the CLSM. The dual-sensor array had electric shields to minimize interfering signals. Conventional potential data for comparison were gathered with a CSE electrode connected to a high-impedance voltmeter and the embedded reinforcement, as is customary.
For the basic probe tests, a temporary, round, stainless steel surface anode was used to simulate a cathodic protection system to evaluate the ability of the probe to detect time-dependent polarization and depolarization effects. For the dual-sensor array tests, the anode was formed as a narrow rectangle near the center of a long edge of the box surface.
Through the testing, the Kelvin probe was observed to operate stably and with adequate reproducibility on the both the CLSM and the soil. The potential values that obtained were suitable to create a surface potential map, as shown in
As the native corrosion macrocell was weak, a stronger impressed current test was conducted, which served to assess the ability of the probe to detect the presence of combined interfacial and ohmic potentials. When a controlled current of approximately 1.2 mA was applied to the surface anode, the Kelvin probe successfully measured a discernable response (˜100 mV potential shift, plus dynamic response as a function of time) directly above the cathodically protected galvanized reinforcement. This response was verified with a CSE electrode in place of the Kelvin probe, where a response of approximately equal magnitude (offset as indicated earlier) was observed during polarization and depolarization cycles, as shown in
The dual-sensor array enabled scanning of the surface potential in consecutive parallel tracks for rapid acquisition of a potential map.
From this testing, it was observed that a contactless macroscopic scanning Kelvin probe can be successfully used to measure potential on the surfaces of CLSM- and soil-embedded galvanized steel reinforcements. The response was also suitable for calibration against a conventional CSE. The Kelvin probe potential measurements were rapid, stable, and reproducible enough for constructing surface maps that can be used in corrosion assessments, without any disturbance of the CLSM or soil surface. The Kelvin probe successfully operated under dynamic conditions representative of a cathodic protection installation, showing capability for electrochemical diagnostic operations. The dual-sensor array was successfully capable of mapping out simulated cathodic protection conditions.
These results are significant as Kelvin probes have never before been used to evaluate reinforcement members buried soil. Although Kelvin probe testing has been used in other applications, soil presents a unique challenge as it does not have a well-defined surface like man-made materials, such as a piece of metal. Unlike such man-made materials, the surface of soil comprises organic particulate matter that makes for a rough, inconsistent surface. In such a case, it is difficult to say where the “surface” actually lies. For instance, is the “surface” the location of the highest pieces of particulate matter, which may include loose particles, or is it somewhere deeper in the soil at a point at which a particular constant density is achieved? Moreover, as the Kelvin probe comprises a linearly vibrating disk that moves toward and away from the test surface, it was not clear whether or not this would disturb the soil surface and somehow skew the results. As the above-described test results establish, however, unexpectedly reliable results can be achieved using a Kelvin probe on soil in spite of these complicating factors.
This application is a continuation application of co-pending U.S. Non-Provisional Application entitled “Systems and Methods for Contactless Assessment of Structures Buried in Soil,” having Ser. No. 15/460,156 and filed Mar. 15, 2017, and claims priority to U.S. Provisional Application Ser. No. 62/308,548, filed Mar. 15, 2016, which is hereby incorporated by reference herein in its entirety.
This invention was made with Government support under NCHRP-IDEA Project 176 awarded by the National Cooperative Highway Research Program. The Government has certain rights in the invention.
Number | Name | Date | Kind |
---|---|---|---|
3626341 | Dao | Dec 1971 | A |
4649336 | Binder et al. | Mar 1987 | A |
4806850 | Saumade | Feb 1989 | A |
4861453 | Matsuoka et al. | Aug 1989 | A |
4942354 | Miller | Jul 1990 | A |
5136247 | Hansen | Aug 1992 | A |
5498974 | Verkuil | Mar 1996 | A |
5841282 | Christy | Nov 1998 | A |
5945594 | Kendig et al. | Aug 1999 | A |
6856159 | Tolk | Feb 2005 | B1 |
20020175892 | Braun | Nov 2002 | A1 |
20030169058 | Pierre | Sep 2003 | A1 |
20030175945 | Thompson | Sep 2003 | A1 |
20060122478 | Sliepen | Jun 2006 | A1 |
20100039127 | Orazem | Feb 2010 | A1 |
20130300419 | Hibbs | Nov 2013 | A1 |
20150185133 | Murray | Jul 2015 | A1 |
20170202202 | Crisp | Jul 2017 | A1 |
Number | Date | Country |
---|---|---|
5279081 | Sep 2013 | JP |
Entry |
---|
Akid et al., “Scanning vibrating reference electrode technique: a calibration study to evaluate the optimum operating parameters for maximum signal detection of point source activity”, Electrochimica Acta, 49, 2004, 2871-2879. |
Hu et al., “Recent progress in corrosion protection of magnesium alloys by organic coatings”, Progress in Organic Coatings 73 (2012), 129-141. |
Jamil et al., “Electrochemical behaviour of amino alcohol-based inhibitors used to control corrosion of reinforcing steel”, Electrochimica Acta 49, 2004, 2753-2760. |
Liu et al., “A MEMS-based piezoelectric power generator array for vibration energy harvesting”, Microelectronic Journal 39(2008), 802-806. |
Yee et al., “Application of a Kelvin Microprobe to the Corrosion of Metals in Humid Atmospheres”, J. Electrochem. Soc. 138(1) 1991, 55-61. |
Zhang et al., Localized corrosion behaviour of reinforcement steel in simulated concrete pore solution, Corrosion Science 51 (2009), 2130-2138. |
Non-final Office Action dated Jun. 22, 2016 in U.S. Appl. No. 13/905,761. |
Final Office Action dated Jan. 12, 2017 in U.S. Appl. No. 13/905,761. |
Non-final Office Action dated May 15, 2017 in U.S. Appl. No. 13/905,761. |
Final Office Action dated Oct. 23, 2017 in U.S. Appl. No. 13/905,761. |
Non-final Office Action dated Aug. 2, 2018 in U.S. Appl. No. 13/905,761. |
Huang, et al., “Monitoring Soil Contaminations Using a Contactless Conductivity Probe”, Geophysical Prospecting, 1995, 43, 759-778. |
Noras, “Non-Contact Surface Charge/Voltage Measurements” Capacitive probe-principle of operation. No. 3001, 2002, Trek, Inc. |
Electric-Field Contact-Less Sensing System, Reference manual, MC33794. |
Student Poster Session poster “Application of a Macroscopic Kelvin Probe for Potential Survey of Reinforcement in Soil and Cementitious Filler” presented by W. Ruth during the NACE International Annual Meeting, Corrosion 2015, Dallas, Texas, Mar. 15-18, 2015. |
Student poster “Application of a Macroscopic Kelvin Probe for Potential Survey of Reinforcement in Soil and Cementitious Filler” presented by W. Ruth at the American Institute of Chemical Engineers Southern Student Regional Conference, Clearwater Beach, FL, Apr. 10-12, 2015. |
Ournal paper “Kelvin Probe electrode for contactless potential measurement on concrete—Properties and corrosion profiling application”, A. Sagüés and M. Walsh, Corrosion Science, vol. 56, pp. 26-35 (2012). |
Conference paper “Novel Kelvin Probe electrode for non-intrusive corrosion rate evaluation of steel in aged concrete structures”, M.T. Walsh and A.A. Sagüés, pp. 569-575 in Proceedings of the 1st International Conference on Ageing of Materials & Structures, K. van Breugel and E.A.B. Koenders, Eds., Delft University of Technology, Delft, The Netherlands, 2014. |
Conference paper “Contactless Kelvin Probe Electrode for Potential and Polarization Resistance Measurements of Reinforcing Steel in Concrete”, Alberto A. Sagüés and Michael T. Walsh, Paper No. 4362, 9 pp., Corrosion 2014, NACE International, Houston, 2014. |
Conference Poster Contactless Electrode for Fast Survey of Concrete Reinforcement Corrosion by A. Sagüés and L. Emmenegger, Transportation Research Board 94th annual meeting, Jan. 11-15, 2015, Washington, DC.—Session: 296. |
Number | Date | Country | |
---|---|---|---|
62308548 | Mar 2016 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 15460156 | Mar 2017 | US |
Child | 16392991 | US |