Systems and methods for controlling air distribution in a coke oven

Information

  • Patent Grant
  • 9273249
  • Patent Number
    9,273,249
  • Date Filed
    Friday, December 28, 2012
    11 years ago
  • Date Issued
    Tuesday, March 1, 2016
    8 years ago
Abstract
The present technology is generally directed to systems and methods for controlling air distribution in a coke oven. In a particular embodiment, a coke oven air distribution system comprises an oven chamber having an oven floor configured to support a coal bed, a plurality of sidewalls extending upward from the oven floor, and an oven crown covering a top portion of the oven chamber. The air distribution system further includes an air inlet positioned above the oven floor and a distributor proximate to the inlet. The inlet is configured to introduce air into the oven chamber and the distributor is configured to at least one of preheat, redirect, or spread air within the oven chamber.
Description
TECHNICAL FIELD

The present technology is generally directed to systems and methods for controlling air distribution in a coke oven.


BACKGROUND

Coke is a solid carbon fuel and carbon source used to melt and reduce iron ore in the production of steel. In one process, known as the “Thompson Coking Process,” coke is produced by batch feeding pulverized coal to an oven that is sealed and heated to very high temperatures for 24 to 48 hours under closely-controlled atmospheric conditions. Coking ovens have been used for many years to covert coal into metallurgical coke. During the coking process, finely crushed coal is heated under controlled temperature conditions to devolatilize the coal and form a fused mass of coke having a predetermined porosity and strength. Because the production of coke is a batch process, multiple coke ovens are operated simultaneously.


Coal particles or a blend of coal particles are charged into hot ovens, and the coal is heated in the ovens in order to remove volatile matter (“VM”) from the resulting coke. Horizontal Heat Recovery (HHR) ovens operate under negative pressure and are typically constructed of refractory bricks and other materials, creating a substantially airtight environment. The negative pressure ovens draw in air from outside the oven to oxidize the coal's VM and to release the heat of combustion within the oven.


In some arrangements, air is introduced to the oven through damper ports or apertures in the oven sidewall, door, or crown to the region above the coal-bed (called the crown region). In the crown region the air combusts with the VM gases evolving from the pyrolysis of the coal. However, the buoyancy effect acting on the cold air entering the oven chamber can lead to coal burnout and loss in yield productivity. More specifically, the cold, dense air entering the oven falls towards the hot coal surface. Before the air can warm, rise, combust with volatile matter, and/or disperse and mix in the oven, it creates a burn loss on the coal surface. Accordingly, there exists a need to improve combustion efficiency in coke ovens.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1A is a schematic illustration of a horizontal heat recovery coke plant, configured in accordance with embodiments of the technology.



FIG. 1B is an isometric, partial cut-away view of a portion of the horizontal heat recovery coke plant of FIG. 1A configured in accordance with embodiments of the technology.



FIG. 1C is a sectional view of a horizontal heat recovery coke oven configured in accordance with embodiments of the technology.



FIG. 2A is an isometric, partially transparent view of a portion of a coke oven having door air distributors configured in accordance with embodiments of the technology.



FIG. 2B is an isometric view of a door air distributor configured in accordance with embodiments of the technology.



FIG. 2C is a side view of the door air distributor of FIG. 2B configured in accordance with embodiments of the technology.



FIG. 2D is a partially schematic, top view of the door air distributor of FIG. 2B forming a vortex air pattern and configured in accordance with embodiments of the technology.



FIG. 3A is an isometric, partially transparent view of a coke oven having crown air distributors configured in accordance with embodiments of the technology.



FIG. 3B is a schematic illustration of a crown air distributor configured in accordance with embodiments of the technology.



FIG. 4 is a schematic illustration of a crown air distributor configured in accordance with further embodiments of the technology.



FIG. 5 is a schematic illustration of a crown air distributor configured in accordance with further embodiments of the technology.



FIG. 6 is a schematic illustration of a crown air distributor configured in accordance with further embodiments of the technology.



FIG. 7 is a schematic illustration of a door air distributor configured in accordance with further embodiments of the technology.



FIG. 8 is a schematic illustration of a door air distributor configured in accordance with further embodiments of the technology.



FIG. 9 is a schematic illustration of a door air distributor configured in accordance with further embodiments of the technology.



FIG. 10 is a schematic illustration of a door air distributor configured in accordance with further embodiments of the technology.



FIG. 11 is a schematic illustration of a door air distributor configured in accordance with further embodiments of the technology.





DETAILED DESCRIPTION

The present technology is generally directed to systems and methods for controlling air distribution in a coke oven. In a particular embodiment, a coke oven air distribution system comprises an oven chamber having an oven floor configured to support a coal bed, a plurality of sidewalls extending upward from the oven floor, and an oven crown covering a top portion of the oven chamber. The air distribution system further includes an air inlet positioned above the oven floor and a distributor proximate to the inlet. The inlet is configured to introduce air into the oven chamber and the distributor is configured to at least one of preheat, redirect, recirculate, or spread air within the oven chamber.


Specific details of several embodiments of the technology are described below with reference to FIGS. 1A-11. Other details describing well-known structures and systems often associated with coal processing and coke ovens have not been set forth in the following disclosure to avoid unnecessarily obscuring the description of the various embodiments of the technology. Many of the details, dimensions, angles, and other features shown in the Figures are merely illustrative of particular embodiments of the technology. Accordingly, other embodiments can have other details, dimensions, angles, and features without departing from the spirit or scope of the present technology. A person of ordinary skill in the art, therefore, will accordingly understand that the technology may have other embodiments with additional elements, or the technology may have other embodiments without several of the features shown and described below with reference to FIGS. 1A-11.



FIG. 1A is a schematic illustration of a horizontal heat recovery (HHR) coke plant 100, configured in accordance with embodiments of the technology. The HHR coke plant 100 comprises ovens 105, along with heat recovery steam generators (HRSGs) 120 and an air quality control system 130 (e.g., an exhaust or flue gas desulfurization (FGD) system), both of which are positioned fluidly downstream from the ovens 105 and both of which are fluidly connected to the ovens 105 by suitable ducts. The HHR coke plant 100 also includes a common tunnel 110 fluidly connecting individual ovens 105 to the HRSGs 120. One or more crossover ducts 115 fluidly connect the common tunnel 110 to the HRSGs 120. A cooled gas duct 125 transports the cooled gas from the HRSGs to the flue gas desulfurization (FGD) system 130. Fluidly connected and further downstream are a baghouse 135 for collecting particulates, at least one draft fan 140 for controlling air pressure within the system, and a main gas stack 145 for exhausting cooled, treated exhaust to the environment. Steam lines 150 can interconnect the HRSG 120 and a cogeneration plant 155 so that the recovered heat can be utilized. Various coke plants 100 can have different proportions of ovens 105, HRSGs 120, and other structures. For example, in some coke plants, each oven 105 illustrated in FIG. 1 can represent ten actual ovens.


As will be described in further detail below, in several embodiments the individual coke ovens 105 can include one or more air inlets configured to allow outside air into the negative pressure oven chamber to combust with the coal's VM. The air inlets can be used with one or more air distributors to direct, preheat, circulate, and/or distribute air within the oven chamber. The term “air” as used herein can include ambient air, oxygen, oxidizers, nitrogen, nitrous oxide, diluents, combustion gases, air mixtures, oxidizer mixtures, flue gas, recycled vent gas, steam, gases having additives, inerts, heat-absorbers, liquid phase materials such as water droplets, multiphase materials such as liquid droplets atomized via a gaseous carrier, aspirated liquid fuels, atomized liquid heptane in a gaseous carrier stream, fuels such as natural gas or hydrogen, cooled gases, other gases, liquids, or solids, or a combination of these materials. In various embodiments, the air inlets and/or distributors can function (i.e., open, close, modify an air distribution pattern, etc.) in response to manual control or automatic advanced control systems. The air inlets and/or air distributors can operate on a dedicated advanced control system or can be controlled by a broader draft control system that adjusts the air inlets and/or distributors as well as uptake dampers, sole flue dampers, and/or other air distribution pathways within coke oven system. The advanced control systems will be described in further detail below with reference to FIGS. 1B and 1C, and specific embodiments of several air inlets and air distributors will be described in further detail below with reference to FIGS. 2A-11.



FIGS. 1B and 1C illustrate further details related to the structure and mechanics of coke ovens and advanced control systems in coke ovens. FIG. 1B is an isometric, partial cut-away view of a portion of the HHR coke plant configured in accordance with embodiments of the technology. FIG. 1C is a sectional view of an HHR coke oven 105 configured in accordance with embodiments of the technology. Referring to FIGS. 1B and 1C together, each oven 105 can include an open cavity defined by a floor 160, a front door 165 forming substantially the entirety of one side of the oven, a rear door 170 opposite the front door 165 forming substantially the entirety of the side of the oven opposite the front door, two sidewalls 175 extending upwardly from the floor 160 intermediate the front 165 and rear 170 doors, and a crown 180 which forms the top surface of the open cavity of an oven chamber 185. In various embodiments, the front or rear doors 165, 170 can be full or half-doors. Controlling air flow and pressure inside the oven chamber 185 can be critical to the efficient operation of the coking cycle and therefore the front door 165 includes one or more primary air inlets 195 that allow primary combustion air into the oven chamber 185. In some embodiments, multiple air inlets 195 are interconnected (e.g., via a ceramic tube or other distribution system internal or external to the oven 105) such that air is supplied to each inlet 195 from the common tube. Each primary air inlet 195 includes a primary air damper 190 which can be positioned at any of a number of positions between fully open and fully closed to vary the amount of primary air flow into the oven chamber 185. In some embodiments, the damper 190 can utilize a slide or a twist top control. Alternatively, the one or more primary air inlets 195 are additionally or alternately formed through the crown 180, floor 160, sidewalls 175, and/or other location (above, at, or below the coal bed) within the oven. As will be described in detail below, one or more air distributors can be employed in connection with a primary air inlet 195 to direct, preheat, and/or distribute air within the oven chamber 185.


In operation, volatile gases emitted from the coal positioned inside the oven chamber 185 collect in the crown and are drawn downstream in the overall system into downcomer channels 200 formed in one or both sidewalls 175. The downcomer channels fluidly connect the oven chamber 185 with a sole flue 205 positioned beneath the over floor 160. The sole flue 205 forms a circuitous path beneath the oven floor 160. Volatile gases emitted from the coal can be combusted in the sole flue 205 thereby generating heat to support the reduction of coal into coke. The downcomer channels 200 are fluidly connected to chimneys or uptake channels 210 formed in one or both sidewalls 175. A secondary air inlet 215 can be provided between the sole flue 205 and atmosphere, and the secondary air inlet 215 can include a secondary air damper 220 that can be positioned at any of a number of positions between fully open and fully closed to vary the amount of secondary air flow into the sole flue 205. The uptake channels 210 are fluidly connected to the common tunnel 110 by one or more uptake ducts 225. A tertiary air inlet 227 can be provided between the uptake duct 225 and atmosphere. The tertiary air inlet 227 can include a tertiary air damper 229 which can be positioned at any of a number of positions between fully open and fully closed to vary the amount of tertiary air flow into the uptake duct 225.


In order to provide the ability to control gas flow through the uptake ducts 225 and within the ovens 105, each uptake duct 225 also includes an uptake damper 230. The uptake damper 230 can be positioned at any number of positions between fully open and fully closed to vary the amount of oven draft in the oven 105. The uptake damper 230 can comprise any automatic or manually-controlled flow control or orifice blocking device (e.g., any plate, seal, block, etc.). As used herein, “draft” indicates a negative pressure relative to atmosphere. For example a draft of 0.1 inches of water indicates a pressure of 0.1 inches of water below atmospheric pressure. Inches of water is a non-SI unit for pressure and is conventionally used to describe the draft at various locations in a coke plant. In some embodiments, the draft ranges from about 0.12 to about 0.16 inches of water. If a draft is increased or otherwise made larger, the pressure moves further below atmospheric pressure. If a draft is decreased, drops, or is otherwise made smaller or lower, the pressure moves towards atmospheric pressure. By controlling the oven draft with the uptake damper 230, the air flow into the oven 105 from the air inlets 195, 215, 227 as well as air leaks into the oven 105 can be controlled. Typically, as shown in FIG. 1C, an individual oven 105 includes two uptake ducts 225 and two uptake dampers 230, but the use of two uptake ducts and two uptake dampers is not a necessity; a system can be designed to use just one or more than two uptake ducts and two uptake dampers.


A sample HHR coke plant 100 includes a number of ovens 105 that are grouped into oven blocks 235 (shown in FIG. 1A). The illustrated HHR coke plant 100 includes five oven blocks 235 of twenty ovens each, for a total of one hundred ovens. All of the ovens 105 are fluidly connected by at least one uptake duct 225 to the common tunnel 110 which is in turn fluidly connected to each HRSG 120 by a crossover duct 115. Each oven block 235 is associated with a particular crossover duct 115. The exhaust gases from each oven 105 in an oven block 235 flow through the common tunnel 110 to the crossover duct 115 associated with each respective oven block 235. Half of the ovens in an oven block 235 are located on one side of an intersection 245 of the common tunnel 110 and a crossover duct 115 and the other half of the ovens in the oven block 235 are located on the other side of the intersection 245.


A HRSG valve or damper 250 associated with each HRSG 120 (shown in FIG. 1A) is adjustable to control the flow of exhaust gases through the HRSG 120. The HRSG valve 250 can be positioned on the upstream or hot side of the HRSG 120, or can be positioned on the downstream or cold side of the HRSG 120. The HRSG valves 250 are variable to a number of positions between fully opened and fully closed and the flow of exhaust gases through the HRSGs 120 is controlled by adjusting the relative position of the HRSG valves 250.


In operation, coke is produced in the ovens 105 by first loading coal into the oven chamber 185, heating the coal in an oxygen depleted environment, driving off the volatile fraction of coal and then oxidizing the VM within the oven 105 to capture and utilize the heat given off. The coal volatiles are oxidized within the ovens over an extended coking cycle, and release heat to regeneratively drive the carbonization of the coal to coke. The coking cycle begins when the front door 165 is opened and coal is charged onto the oven floor 160. The coal on the oven floor 160 is known as the coal bed. Heat from the oven (due to the previous coking cycle) starts the carbonization cycle. In some embodiments, no additional fuel other than that produced by the coking process is used. Roughly half of the total heat transfer to the coal bed is radiated down onto the top surface of the coal bed from the luminous flame of the coal bed and the radiant oven crown 180. The remaining half of the heat is transferred to the coal bed by conduction from the oven floor 160 which is convectively heated from the volatilization of gases in the sole flue 205. In this way, a carbonization process “wave” of plastic flow of the coal particles and formation of high strength cohesive coke proceeds from both the top and bottom boundaries of the coal bed.


Typically, each oven 105 is operated at negative pressure so air is drawn into the oven during the reduction process due to the pressure differential between the oven 105 and atmosphere. Primary air for combustion is added to the oven chamber 185 to partially oxidize the coal volatiles, but the amount of this primary air is controlled so that only a portion of the volatiles released from the coal are combusted in the oven chamber 185, thereby releasing only a fraction of their enthalpy of combustion within the oven chamber 185. The primary air can be introduced into the oven chamber 185 above the coal bed through the primary air inlets 195, with the amount of primary air controlled by the primary air dampers 190. The primary air dampers 190 can also be used to maintain the desired operating temperature inside the oven chamber 185.


The partially combusted gases pass from the oven chamber 185 through the downcomer channels 200 into the sole flue 205 where secondary air is added to the partially combusted gases. The secondary air is introduced through the secondary air inlet 215. The amount of secondary air that is introduced is controlled by the secondary air damper 220. As the secondary air is introduced, the partially combusted gases are more fully combusted in the sole flue 205, thereby extracting the remaining enthalpy of combustion which is conveyed through the oven floor 160 to add heat to the oven chamber 185. The fully or nearly-fully combusted exhaust gases exit the sole flue 205 through the uptake channels 210 and then flow into the uptake duct 225. Tertiary air is added to the exhaust gases via the tertiary air inlet 227, where the amount of tertiary air introduced is controlled by the tertiary air damper 229 so that any remaining fraction of uncombusted gases in the exhaust gases are oxidized downstream of the tertiary air inlet 227. At the end of the coking cycle, the coal has coked out and has carbonized to produce coke. The coke is preferably removed from the oven 105 through the rear door 170 utilizing a mechanical extraction system. Finally, the coke is quenched (e.g., wet or dry quenched) and sized before delivery to a user.


As discussed above, control of the draft in the ovens 105 can be implemented by automated or advanced control systems. An advanced draft control system, for example, can automatically control an uptake damper that can be positioned at any one of a number of positions between fully open and fully closed to vary the amount of oven draft in the oven 105. The automatic uptake damper can be controlled in response to operating conditions (e.g., pressure or draft, temperature, oxygen concentration, gas flow rate, downstream levels of hydrocarbons, water, hydrogen, carbon dioxide, or water to carbon dioxide ratio, etc.) detected by at least one sensor. The automatic control system can include one or more sensors relevant to the operating conditions of the coke plant 100. In some embodiments, an oven draft sensor or oven pressure sensor detects a pressure that is indicative of the oven draft. Referring to FIGS. 1A-1C together, the oven draft sensor can be located in the oven crown 180 or elsewhere in the oven chamber 185. Alternatively, an oven draft sensor can be located at either of the automatic uptake dampers 305, in the sole flue 205, at either oven door 165 or 170, or in the common tunnel 110 near or above the coke oven 105. In one embodiment, the oven draft sensor is located in the top of the oven crown 180. The oven draft sensor can be located flush with the refractory brick lining of the oven crown 180 or could extend into the oven chamber 185 from the oven crown 180. A bypass exhaust stack draft sensor can detect a pressure that is indicative of the draft at the bypass exhaust stack 240 (e.g., at the base of the bypass exhaust stack 240). In some embodiments, a bypass exhaust stack draft sensor is located at the intersection 245. Additional draft sensors can be positioned at other locations in the coke plant 100. For example, a draft sensor in the common tunnel could be used to detect a common tunnel draft indicative of the oven draft in multiple ovens proximate the draft sensor. An intersection draft sensor can detect a pressure that is indicative of the draft at one of the intersections 245.


An oven temperature sensor can detect the oven temperature and can be located in the oven crown 180 or elsewhere in the oven chamber 185. A sole flue temperature sensor can detect the sole flue temperature and is located in the sole flue 205. A common tunnel temperature sensor detects the common tunnel temperature and is located in the common tunnel 110. A HRSG inlet temperature sensor can detect the HRSG inlet temperature and can be located at or near the inlet of the HRSG 120. Additional temperature or pressure sensors can be positioned at other locations in the coke plant 100.


An uptake duct oxygen sensor is positioned to detect the oxygen concentration of the exhaust gases in the uptake duct 225. An HRSG inlet oxygen sensor can be positioned to detect the oxygen concentration of the exhaust gases at the inlet of the HRSG 120. A main stack oxygen sensor can be positioned to detect the oxygen concentration of the exhaust gases in the main stack 145 and additional oxygen sensors can be positioned at other locations in the coke plant 100 to provide information on the relative oxygen concentration at various locations in the system.


A flow sensor can detect the gas flow rate of the exhaust gases. For example, a flow sensor can be located downstream of each of the HRSGs 120 to detect the flow rate of the exhaust gases exiting each HRSG 120. This information can be used to balance the flow of exhaust gases through each HRSG 120 by adjusting the HRSG dampers 250. Additional flow sensors can be positioned at other locations in the coke plant 100 to provide information on the gas flow rate at various locations in the system. Additionally, one or more draft or pressure sensors, temperature sensors, oxygen sensors, flow sensors, hydrocarbon sensors, and/or other sensors may be used at the air quality control system 130 or other locations downstream of the HRSGs 120. In some embodiments, several sensors or automatic systems are linked to optimize overall coke production and quality and maximize yield. For example, in some systems, one or more of an air inlet 195, an inlet damper 190, a sole flue damper, and/or an oven uptake damper can all be linked (e.g., in communication with a common controller) and set in their respective positions collectively. In this way, the air inlets 195 can be used to adjust the draft as needed to control the amount of air in the oven chamber 185. In further embodiments, other system components can be operated in a complementary manner, or components can be controlled independently.


An actuator can be configured to open and close the various dampers (e.g., uptake dampers 230 or air dampers 190). For example, an actuator can be a linear actuator or a rotational actuator. The actuator can allow the dampers to be infinitely controlled between the fully open and the fully closed positions. In some embodiments, different dampers can be open or closed to different degrees. The actuator can move the dampers amongst these positions in response to the operating condition or operating conditions detected by the sensor or sensors included in an automatic draft control system. The actuator can position the uptake damper 230 based on position instructions received from a controller. The position instructions can be generated in response to the draft, temperature, oxygen concentration, downstream hydrocarbon level, or gas flow rate detected by one or more of the sensors discussed above; control algorithms that include one or more sensor inputs; a pre-set schedule, or other control algorithms. The controller can be a discrete controller associated with a single automatic damper or multiple automatic dampers, a centralized controller (e.g., a distributed control system or a programmable logic control system), or a combination of the two. Accordingly, individual primary air inlets 195 or dampers 190 can be operated individually or in conjunction with other inlets 195 or dampers 190.


The automatic draft control system can, for example, control an automatic uptake damper 230 or air inlet damper 190, 220, or 229 in response to the oven draft detected by an oven draft sensor. The oven draft sensor can detect the oven draft and output a signal indicative of the oven draft to a controller. The controller can generate a position instruction in response to this sensor input and the actuator can move the uptake damper 230 or air inlet damper 190, 220, or 229 to the position required by the position instruction. In this way, an automatic control system can be used to maintain a targeted oven draft. Similarly, an automatic draft control system can control automatic uptake dampers, inlet dampers, the HRSG dampers 250, and/or the draft fan 140, as needed, to maintain targeted drafts at other locations within the coke plant 100 (e.g., a targeted intersection draft or a targeted common tunnel draft). The automatic draft control system can be placed into a manual mode to allow for manual adjustment of the automatic uptake dampers, the HRSG dampers, and/or the draft fan 140, as needed. In still further embodiments, an automatic actuator can be used in combination with a manual control to fully open or fully close a flow path. As mentioned above, the air inlets 195 can be positioned in various locations on the oven 105 and can likewise utilize an advanced control system in this same manner. In some embodiments having both crown 180 and door 165 air entry, the inlets can be controlled collectively to drive flow circulation within the chamber 185. In various embodiments, individual ovens 105 are controlled separately, while in further embodiments a series of ovens are controlled together.



FIG. 2A is an isometric, partially transparent view of a portion of a coke oven 205 having door baffles or air distributors 251 configured in accordance with embodiments of the technology. As described above with reference to FIGS. 1A-1C, the oven 205 includes a plurality of primary air inlets 195 configured to introduce air into the oven chamber 185. The inlets 195 can be circular, slotted, or other-shaped apertures. The distributors 251 are positioned proximate to the air inlets 195 within the oven chamber 185 and are configured to distribute, preheat, channel, damper, and/or redirect air entering the oven chamber 185. The inlets 195 can have a continuous diameter or width W through the depth D of the oven door 165 or can taper to control pressure. Further, the inlets 195 can be angled with reference to a horizontal axis generally parallel with the oven floor.



FIG. 2B is an isometric view of the door air distributor 251 and FIG. 2C is a side view of the door air distributor 251 configured in accordance with embodiments of the technology. Referring to FIGS. 2B and 2C together, the distributor 251 comprises an annulus flow deflecting baffle having an inner diameter Bi and an outer diameter Bo and a depth BD. As shown, in some embodiments Bo is greater than Bi causing the air distributor 251 to have an angled or fanned side profile to expand the distribution profile and disperse incoming air. In some embodiments, the air distributor 251 has an elevation difference from about 1-2 inches over its depth BD. In further embodiments, Bo can be less than Bi in order to narrow the distribution profile or increase pressure on the incoming air to modify the air's distribution profile (e.g., so the air can enter at a higher pressure and extend further into the chamber 185). In further embodiments, the air distributor 251 has a constant diameter. The air distributor's depth BD can cause the air distributor 251 to extend into the oven chamber 185 to deliver air further towards the center of the chamber 185. In other embodiments, the air distributor 251 can be flush or nearly flush with the oven door 165 or can be. external to the oven chamber 185. While three inlets 195 and distributors 251 are shown, there can be more or fewer in further embodiments of the technology.



FIG. 2D is a partially schematic, top view of the door air distributor 251 forming a vortex air pattern V and configured in accordance with embodiments of the technology. Referring to FIGS. 2A-2D together, in operation, the distributors 251 spread the air jet entering the oven chamber 185 and prevent the air jet from dipping as close to the coal/coke surface as would an air jet not subjected to an air distributor 251. The distributors 251 accordingly promote combustion before the air hits the coal/coke surface. In some embodiments, the distributor 251 is spaced apart from the oven door 165 and is positioned generally in front of or proximate to the inlet 195. Air entering the oven chamber 185 passes both through and around the distributor 251. The combination of these air flow patterns can create the vortex air pattern V in front of the distributor 251. The distributor 251 can thus be thought of as a vortex generator. The vortex pattern V can cause the air to stall, spin, and in some cases heat before continuing further into the oven chamber. The vortex V can enhance mixing between incoming air and combustion gases and create a flame having some characteristics of a premixed flame. In some cases, the vortex V can anchor a flame to mitigate cold air dipping.


The air entering the oven chamber 185 can also be preheated within the oven door, 165, the air distributors 251, and/or the inlets 195. More specifically, these features can function as heat exchangers, warming incoming air with heat from the oven or other source. In further embodiments, the incoming air is preheated external of the oven 205, such as in a conduit or chamber. In still further embodiments, the air can be preheated within an oven structure (e.g., within a sidewall, crown, door, or floor). In still further embodiments, the air is partially preheated external of the oven chamber 185 and then further heated proximate to the distributor 251 within the chamber 185. In various embodiments, the air entering the chamber 185 can be pressurized, controlled by a broader draft control system as described above, or flow freely or unpressurized. Further, the air can be cold, warm, or hot.


The distributors 251 can reduce yield loss by preventing direct contact between the incoming jet of air and the coal bed. More specifically, the oxygen in the air can be directed toward the crown region to burn the VM released by the coal in the coking process. The distributors can affect the air flow by injecting the air at a location further from the coal/coke surface, redirecting the air stream momentum away from the coal/coke surface, dispersing the air before it reaches the coal/coke surface, preheating the air to lower its density such that it has more time to burn or disperse before reaching the coal/coke surface, or a combination of these techniques. Any of these techniques can provide improved contact between the air and the hot oven gases, providing for faster dispersion/mixing of the oxygen with the oven gases.



FIG. 3A is an isometric, partially transparent view of a coke oven 305 having crown air inlets 361 configured in accordance with embodiments of the technology. The crown air inlets 361 can have several features generally similar to the door air inlets 195 described above with reference to FIGS. 1A-2D. For example, the crown air inlets 361 introduce combustion air through the crown 180 and into the oven chamber 185. Each air inlet 361 can include an air damper which can be positioned at any of a number of positions between fully open and fully closed to vary the amount of air flow into the oven chamber 185. The coke oven 305 further includes one or more distributors 363 configured to channel/distribute air flow into the oven chamber 185.


As shown schematically in FIG. 3B, each distributor 363 comprises a deflection plate or impingement baffle configured to disperse or redirect air entering the oven chamber 185. The distributor 363 can be coupled to the crown 180, inlet 361, or other oven feature. For example, the distributor 363 can be suspended and spaced apart from the crown 180. As air (represented by arrowed flow lines) enters the inlet 361, the air interfaces with and is diverted by the distributor 363. The distributor 363 can accordingly alter the manner in which the air enters and behaves in the oven chamber 185. More specifically, the distributors 363 spread the incoming air laterally and can cause more uniform thermal distribution within the crown and provide better air-VM mixing and combustion in the crown region.


In various embodiments, the distributor 363 can be steel, ceramic, ceramic mesh, or other material suitable for withstanding the high oven temperatures. The distributor 363 can be a solid material or can have one or more apertures therein. While the inlet 361 is shown as having two side apertures to accept air, in further embodiments the inlet 361 can have more or fewer apertures and the apertures can be on the sides or the top of the inlet 361 or can have other suitable arrangements. Similarly, the distributor 363 can allow air flow into the oven chamber 185 via more or fewer than two lateral passageways. Further, the inlet 361 and distributor 363 can have a rectangular, circular, or other shaped cross-section, and the apertures therein can comprise slots, tubes, ports, or any other flow-allowing orifice.


In some embodiments, the inlet 361 and/or distributor 363 can provide preheating of incoming air to lower its density in the manner described above. For example, the inlet 361 can comprise a ceramic or other tube that runs along the top of the oven 305 and receives heat from the oven 305 or other source. In other embodiments, such a heat exchange tube can be inside the oven. In still further embodiments, the inlet 361 can comprise a burner or other heater on the exterior of the oven 305 that heats the incoming air with natural gas or other material. The preheating material can be burned before it reaches the oven or can be introduced to the oven with the air. In further embodiments, an inert gas, combustion gas, dilution gas, or cooling gas can be added to the chamber 185 via the inlet 361 and/or distributor 363. Any of these gases can be introduced manually or as part of an advanced control system in response to a sensed operating condition. In a particular embodiment, for example, fuel can be added during or at the end of a coking cycle in response to a command by the advanced control system. In other embodiments, different materials can be added at different times during the coking cycle. For example, in some embodiments, an inert can be added during the first half of the coking cycle to prevent the influx of oxidizers and create a more purely pyrolytic environment. The inlet 361 and/or distributor 363 can function as a distribution system to supply mixtures of a heating fuel (e.g., natural gas, inert gas, dilution gas) and air to the oven chamber 185. In various embodiments, there can be more or fewer air inlets 361 than shown, and in a particular embodiment there are six inlets 361.



FIG. 4 is a schematic illustration of a crown air distributor 463 configured in accordance with further embodiments of the technology. The distributor 463 can comprise a tiered set of baffles channeling air through a plurality of apertures 467. In operation, air enters an air inlet 461 and the distributor 463 spreads the air to a range of depths in the oven chamber 185 and laterally into the crown region. While the illustrated distributor 463 comprises three apertures 467 on only one side, in further embodiments there can be apertures on multiple sides and there can be more of fewer apertures 467 at the same or additional tiers.



FIG. 5 is a schematic illustration of a crown air distributor 563 configured in accordance with further embodiments of the technology. The distributor 563 has several features generally similar to the distributor 363 described above with reference to FIG. 3B. For example, the distributor 563 can be suspended from the crown 180 and can receive air from an air inlet 561. The distributor 563 can be vertically elongated to extend to a further depth in the oven chamber 185. The distributor 563 can accordingly spread air to a region closer to the coal bed and further spaced apart from the crown 180. The elongated distributor 563 can also provide additional air preheating time via heat exchange as described above. In various embodiments, the distributor 563 can have a fixed depth or can have one or more variable baffles, adjustable springs or hinges, or other components to provide for a dynamic depth of distribution of air into the oven chamber 185.



FIG. 6 is a schematic illustration of a crown air distributor 663 configured in accordance with further embodiments of the technology. The distributor 663 has several features generally similar to the distributors described above. The distributor 663 can be suspended from the crown 180 and can receive air from an air inlet 661. The distributor 663 can be laterally elongated and have a plurality of apertures 667 on a downward-facing side. In further embodiments, the distributor 663 can be laterally elongated in only one direction and/or can have apertures additionally or alternately on other sides or upward-facing surfaces. The distributor 663 can accordingly spread air laterally and downward and can cause more uniform thermal distribution within the crown 180. By using a laterally elongated distributor having multiple distribution apertures 667, in some embodiments only a few or a single inlet 661 may be needed to provide air to the chamber 185.



FIG. 7 is a schematic illustration of a door air distributor 751 configured in accordance with further embodiments of the technology. The distributor 751 is generally cylindrically shaped and extends from and/or through the oven door 165. In some embodiments the distributor 751 extends into the oven chamber 185, while in other embodiments the distributor 751 is flush with the door 165 or a sidewall. The distributor 751 can be angled (e.g., angle θ) with respect to the oven door 165. In further embodiments, the distributor 751 can be more or less angled with respect to the door 165, and can cause air to flow upward, downward, or sideways into the oven chamber 185. In some embodiments, the angle θ is selected to direct cool air sufficiently away from the coal bed to prevent surface burn, but not so steep as to cause burning or other damage to the crown. The distributor 751 can accordingly direct air from the air inlet 195 to a desired location to maximize thermal distribution and VM combustion. In further embodiments, the position of the distributor with respect to the door 165 can be dynamic. For example, the angle θ can change manually or automatically in response to a sensed oven temperature, pressure, oxygen level, or draft condition.



FIG. 8 is a schematic illustration of a door air distributor 851 configured in accordance with further embodiments of the technology. The distributor 851 is generally similar to the distributor 751 described above with reference to FIG. 7. For example, the distributor 851 can be generally cylindrically-shaped and can extend from the air inlet 195 into the oven chamber 185 and be angled with respect to the oven door 165. Further, the distributor 851 can have a redirection plate 881 at a lateral end configured to redirect the air flow in a given direction. For example, in the illustrated embodiment, the redirection plate 881 forces air flow in an upward direction.


While the redirection plate 881 is illustrated as being coupled to a lower portion of the distributor 851, in further embodiments the redirection plate 881 can be coupled to other portions of the distributor 851, the door 165, or can otherwise be suspended in the oven chamber 185. Further, the connection between the redirection plate 881 and the rest of the distributor can be sharply angled, as shown, or can comprise a smooth contour, and can be static or dynamic.



FIG. 9 is a schematic illustration of a door air distributor 951 configured in accordance with still further embodiments of the technology. The distributor 951 is generally similar to the distributor 851 described above with reference to FIG. 8. For example, the distributor 951 can be generally cylindrically shaped and can extend from the air inlet 195 into the oven chamber 185 and be angled with respect to the oven door 165. Further, a redirection plate 957 can be spaced apart from the distributor 951 and configured to channel or redirect air flow into the oven chamber 185. The redirection plate 957 can be coupled to the distributor 951 or can be otherwise coupled to or suspended in the oven chamber 185. The angle of the redirection plate 957 with respect to the door 165 and distributor 951 can control the airflow distribution pattern in the chamber 185. In the illustrated embodiment, for example, the redirection plate 957 is positioned generally orthogonal to the pattern of air flow through the distributor 951. The air flow therefore interfaces with the redirection plate 957 and is channeled upward toward the crown and downward toward the coal bed. In some embodiments, the redirection plate 957 and/or the distributor 951 can be dynamically angled or otherwise movable with reference to each other.



FIG. 10 is a schematic illustration of a door air distributor 1051 configured in accordance with further embodiments of the technology. The distributor 1051 is generally similar to the distributor 751 described above with reference to FIG. 7. Instead of a generally cylindrical shape, however, the distributor 1051 comprises a curved shape providing a serpentine air flow pathway. While the illustrated embodiments comprises an “S” shape extending inward from the oven door 165 to the chamber 185, in further embodiments the distributor 1051 can have more or fewer curves of various angles. In some embodiments, the curved shape can cause the air entering the oven chamber 185 to spend an extended time in the distributor 1051 as compared to shorter, straighter pathways. The longer residence time in the distributor 1051 can cause the inletting air to be preheated so it does not jet to the coal/coke surface and cause surface burn.



FIG. 11 is a schematic illustration of a door air distributor 1151 configured in accordance with further embodiments of the technology. The distributor 1151 has several features generally similar to the distributors described above. For example, the distributor 1151 can be generally cylindrically shaped and can extend from the air inlet 195 into the oven chamber 185. The distributor 1151 can further include a plurality of apertures 1159 configured to release air at various points above and below the distributor at various distances from the oven door 165. In further embodiments, there can be more or fewer apertures 1159 and the apertures 1159 can be positioned on more or fewer sides of the distributor 1151. Additionally, while the illustrated distributor 1151 is shown to be generally orthogonal to the oven door 165, in further embodiments the distributor 1151 can be angled relative to the door 165.


EXAMPLES

1. A coke oven air distribution system, comprising:

    • an oven chamber having an oven floor configured to support a coal bed, a plurality of sidewalls extending upward from the oven floor, and an oven crown covering a top portion of the oven chamber;
    • an air inlet positioned above the oven floor and configured to introduce air into the oven chamber; and
    • a distributor proximate to the inlet and configured to at least one of preheat, redirect, or disperse air within the oven chamber.


2. The system of example 1 wherein the air inlet comprises an inlet in the oven crown.


3. The system of example 1 wherein the air inlet comprises an inlet in an individual sidewall.


4. The system of example 3 wherein the individual sidewall comprises an oven door.


5. The system of example 1 wherein the distributor comprises a generally cylindrical tube extending into the oven chamber.


6. The system of example 5 wherein the distributor comprises an impingement plate generally orthogonal to the cylindrical tube.


7. The system of example 1 wherein the distributor comprises an annulus flow deflecting baffle.


8. The system of example 1 wherein the distributor comprises an elongated channel having a plurality of apertures therein.


9. The system of example 8 wherein the elongated channel is elongated in a direction generally parallel to the sidewalls.


10. The system of example 8 wherein the elongated channel is elongated in a direction generally parallel to the oven floor.


11. The system of example 1 wherein the distributor comprises a serpentine pathway.


12. The system of example 1 wherein the distributor comprises a pathway angled in a direction away from the oven floor.


13. The system of example 1, further comprising an inlet damper coupled to the inlet and configured to be positioned at any one of a plurality of positions including fully opened and fully closed.


14. The system of example 13, wherein the inlet damper is automatically movable between positions in response to at least one of a draft, oxygen concentration, or temperature condition in the oven.


15. The system of example 1, further comprising at least one of a conduit or a chamber external to the oven chamber and in fluid communication with the air inlet, wherein the conduit or chamber is configured to contain and/or heat air prior to introduction to the oven.


16. The system of example 15 wherein the conduit or chamber is positioned within one or more of the sidewalls, oven floor, or oven crown.


17. A method of controlling air distribution within a coke oven, the method comprising:

    • inletting air into an oven chamber, the oven chamber comprising a floor, a crown, and a plurality of sidewalls connecting the floor and the crown, wherein at least one of the sidewalls comprises a door;
    • using a distributor to alter a pathway of the air in the chamber; and
    • heating the air along the altered pathway.


18. The method of example 17 wherein inletting air into an oven chamber comprises inletting air through at least one of the crown, one of the sidewalls, or the door.


19. The method of example 17 wherein heating the air along the altered pathway comprises utilizing the distributor as a heat exchanger.


20. A coke oven, comprising:

    • an oven chamber;
    • an air inlet in fluid communication with the oven chamber, the air inlet being configured to supply gas to the oven chamber;
    • a distributor coupled to the air inlet and configured to at least one of preheat, redirect, or distribute the gas;
    • an inlet damper in fluid communication with at least one of the distributor or the air inlet, the inlet damper being positioned at any one of a plurality of positions including fully opened and fully closed, the inlet damper configured to control an oven draft;
    • an actuator configured to alter the position of the inlet damper between the plurality of positions in response to a position instruction; and
    • a controller in communication with the actuator and configured to provide the position instruction to the actuator.


21. The coke oven of example 20, wherein the air inlet comprises a plurality of air inlets, each air inlet having an inlet damper and an actuator, and wherein the controller communicates with the plurality of actuators collectively.


22. The coke oven of example 20, wherein the air inlet comprises a plurality of air inlets, each air inlet having an inlet damper and an actuator, and wherein the controller comprises a plurality of controllers, each controller configured to communicate with an individual actuator.


23. The coke oven of claim 20, further comprising an uptake damper in communication with the controller, wherein the controller is configured to control positions of the inlet damper and the uptake damper collectively.


The systems and methods disclosed herein offer several advantages over traditional coke oven systems. The distributors can improve overall coke productivity and enhance VM gas-air combustion characteristics by better distributing air within the oven chamber and/or preheating air before introducing it to the chamber. The improved air distribution reduces coke surface burn loss and increases overall coke yield. This improved coke productivity enables better and “cleaner” combustion and more uniform temperatures in the oven crown. A more uniform temperature within the crown region helps prevent any potential hot-spots on the oven refractory walls, thus minimizing damage and costly repairs to the oven. Further, better distribution in the oven can require fewer inlets, which can enable easier advanced control over oven operation.


From the foregoing it will be appreciated that, although specific embodiments of the technology have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the technology. For example, while certain embodiments have been described as being sidewall, door, or crown air inlets/distributors, these inlets/distributors can be placed at any suitable location in the coke oven. Further, certain aspects of the new technology described in the context of particular embodiments may be combined or eliminated in other embodiments. Moreover, while advantages associated with certain embodiments of the technology have been described in the context of those embodiments, other embodiments may also exhibit such advantages, and not all embodiments need necessarily exhibit such advantages to fall within the scope of the technology. Accordingly, the disclosure and associated technology can encompass other embodiments not expressly shown or described herein. Thus, the disclosure is not limited except as by the appended claims.

Claims
  • 1. A coke oven air distribution system, comprising: an oven chamber having an oven floor configured to support a coal bed, a plurality of sidewalls extending upward from the oven floor, and an oven crown covering a top portion of the oven chamber;an air inlet positioned above the oven floor and configured to introduce air into the oven chamber; anda distributor having an inlet end portion, in fluid communication with the air inlet, an outlet end portion opposite the inlet end portion, a fluid pathway extending between the inlet end portion and the outlet end portion, an impingement plate generally orthogonal to an axis extending between the inlet end portion and the outlet end portion, and at least one outlet aperture adjacent the impingement plate in fluid communication with the fluid pathway between the inlet end portion and the outlet end portion; the at least one outlet aperture positioned to face away from the oven floor.
  • 2. The system of claim 1 wherein the air inlet comprises an inlet in the oven crown.
  • 3. The system of claim 1 wherein the air inlet comprises an inlet in an individual sidewall.
  • 4. The system of claim 3 wherein the individual sidewall comprises an oven door.
  • 5. The system of claim 1 wherein the distributor comprises a generally cylindrical tube extending into the oven chamber.
  • 6. The system of claim 5 wherein the impingement plate is generally orthogonal to the cylindrical tube.
  • 7. The system of claim 1 wherein the distributor comprises an annulus-shaped flow deflecting baffle.
  • 8. The system of claim 1 wherein the distributor comprises an elongated channel having a plurality of apertures therein.
  • 9. The system of claim 8 wherein the elongated channel is elongated in a direction generally parallel to the sidewalls.
  • 10. The system of claim 8 wherein the elongated channel is elongated in a direction generally parallel to the oven floor.
  • 11. The system of claim 1 wherein the distributor comprises a serpentine pathway.
  • 12. The system of claim 1, further comprising an inlet damper coupled to the inlet and configured to be positioned at any one of a plurality of positions including fully opened and fully closed.
  • 13. The system of claim 12, wherein the inlet damper is automatically movable between positions in response to at least one of a draft, oxygen concentration, or temperature condition in the oven.
  • 14. The system of claim 1, further comprising at least one of a conduit or a chamber external to the oven chamber and in fluid communication with the air inlet, wherein the conduit or chamber is configured to contain and/or heat air prior to introduction to the oven.
  • 15. The system of claim 14 wherein the conduit or chamber is positioned within one or more of the sidewalls, oven floor, or oven crown.
  • 16. A method of controlling air distribution within a coke oven, the method comprising: inletting air from an air inlet into an oven chamber, the oven chamber comprising a floor, a crown, and a plurality of sidewalls connecting the floor and the crown, wherein at least one of the sidewalls comprises a door;using a distributor that extends at least partially into the chamber to alter a pathway of the air in the oven chamber; the distributor having an inlet end portion in fluid communication with the air inlet, an outlet end portion opposite the inlet end portion, a fluid pathway extending between the inlet end portion and the outlet end portion, an impingement plate generally orthogonal to an axis extending between the inlet end portion and the outlet end portion, and at least one outlet aperture adjacent the impingement plate in fluid communication with the fluid pathway between the inlet end portion and the outlet end portion; the at least one outlet aperture positioned to face away from the oven floor; andheating the air along the fluid pathway extending between the inlet end portion and the outlet end portion of the distributor.
  • 17. The method of claim 16 wherein inletting air into an oven chamber comprises inletting air through at least one of the crown, one of the sidewalls, or the door.
  • 18. A coke oven system, comprising: an oven chamber;an air inlet in fluid communication with the oven chamber, the air inlet being configured to supply gas to the oven chamber;a distributor having an inlet end portion, in fluid communication with the air inlet, an outlet end portion opposite the inlet end portion, a fluid pathway extending between the inlet end portion and the outlet end portion, an impingement plate generally orthogonal to an axis extending between the inlet end portion and the outlet end portion, and at least one outlet aperture adjacent the impingement plate in fluid communication with the fluid pathway between the inlet end portion and the outlet end portion; the at least one outlet aperture positioned to face away from an oven floor within the oven chamber;an inlet damper in fluid communication with at least one of the distributor or the air inlet, the inlet damper being positioned at any one of a plurality of positions including fully opened and fully closed, the inlet damper configured to control an oven draft;an actuator configured to alter the position of the inlet damper between the plurality of positions in response to a position instruction; anda controller in communication with the actuator and configured to provide the position instruction to the actuator.
  • 19. The coke oven system of claim 18, wherein the air inlet comprises a plurality of air inlets, each air inlet having an inlet damper and an actuator, and wherein the controller communicates with the plurality of actuators collectively.
  • 20. The coke oven system of claim 18, wherein the air inlet comprises a plurality of air inlets, each air inlet having an inlet damper and an actuator, and wherein the controller comprises a plurality of controllers, each controller configured to communicate with an individual actuator.
  • 21. The coke oven system of claim 18, further comprising an uptake damper, in fluid communication with the oven chamber and positioned such that gases flow from the coke oven toward the uptake damper, in communication with the controller, wherein the controller is configured to control positions of the inlet damper and the uptake damper collectively.
US Referenced Citations (194)
Number Name Date Kind
469868 Thomas et al. Mar 1892 A
1140798 Carpenter May 1915 A
1424777 Schondeling Aug 1922 A
1430027 Piantinga Sep 1922 A
1486401 Van Ackeren Mar 1924 A
1572391 Klaiber Feb 1926 A
1721813 Geipert et al. Jul 1929 A
1818370 Wine Aug 1931 A
1848818 Becker Mar 1932 A
1955962 Jones Apr 1934 A
2394173 Harris et al. Feb 1946 A
2424012 Bangham et al. Jul 1947 A
2902991 Whitman Sep 1959 A
3033764 Hannes May 1962 A
3462345 Keman Aug 1969 A
3545470 Paton Dec 1970 A
3616408 Hickam Oct 1971 A
3630852 Nashan et al. Dec 1971 A
3652403 Knappstein et al. Mar 1972 A
3676305 Cremer Jul 1972 A
3709794 Kinzler et al. Jan 1973 A
3746626 Morrison, Jr. Jul 1973 A
3748235 Pries Jul 1973 A
3784034 Thompson Jan 1974 A
3806032 Pries Apr 1974 A
3836161 Buhl Sep 1974 A
3839156 Jakobi et al. Oct 1974 A
3844900 Schulte Oct 1974 A
3857758 Mole Dec 1974 A
3875016 Schmidt-Balve et al. Apr 1975 A
3876506 Dix et al. Apr 1975 A
3878053 Hyde Apr 1975 A
3897312 Armour et al. Jul 1975 A
3906992 Leach Sep 1975 A
3912091 Thompson Oct 1975 A
3917458 Polak Nov 1975 A
3930961 Sustarsic et al. Jan 1976 A
3957591 Riecker May 1976 A
3959084 Price May 1976 A
3963582 Helm et al. Jun 1976 A
3969191 Bollenbach et al. Jul 1976 A
3984289 Sustarsic et al. Oct 1976 A
4004702 Szendroi Jan 1977 A
4004983 Pries Jan 1977 A
4040910 Knappstein et al. Aug 1977 A
4059885 Oldengott Nov 1977 A
4067462 Thompson Jan 1978 A
4083753 Rogers et al. Apr 1978 A
4086231 Ikio Apr 1978 A
4100033 Holter Jul 1978 A
4111757 Ciarimboli Sep 1978 A
4124450 MacDonald Nov 1978 A
4141796 Clark et al. Feb 1979 A
4145195 Knappstein et al. Mar 1979 A
4147230 Ormond et al. Apr 1979 A
4189272 Gregor et al. Feb 1980 A
4194951 Pries Mar 1980 A
4196053 Grohmann Apr 1980 A
4211608 Kwasnoski et al. Jul 1980 A
4211611 Bocsanczy et al. Jul 1980 A
4213489 Cain Jul 1980 A
4213828 Calderon Jul 1980 A
4222748 Argo et al. Sep 1980 A
4222824 Flockenhaus et al. Sep 1980 A
4224109 Flockenhaus Sep 1980 A
4225393 Gregor et al. Sep 1980 A
4235830 Bennett et al. Nov 1980 A
4248671 Belding Feb 1981 A
4249997 Schmitz Feb 1981 A
4263099 Porter Apr 1981 A
4285772 Kress Aug 1981 A
4287024 Thompson Sep 1981 A
4289584 Chuss et al. Sep 1981 A
4289585 Wagener et al. Sep 1981 A
4303615 Jarmell et al. Dec 1981 A
4307673 Caughey Dec 1981 A
4314787 Kwasnik et al. Feb 1982 A
4330372 Cairns et al. May 1982 A
4334963 Stog Jun 1982 A
4336843 Petty Jun 1982 A
4340445 Kucher et al. Jul 1982 A
4342195 Lo Aug 1982 A
4344820 Thompson Aug 1982 A
4366029 Bixby et al. Dec 1982 A
4373244 Mertens et al. Feb 1983 A
4375388 Hara et al. Mar 1983 A
4391674 Velmin et al. Jul 1983 A
4392824 Struck et al. Jul 1983 A
4395269 Schuler Jul 1983 A
4396394 Li et al. Aug 1983 A
4396461 Neubaum et al. Aug 1983 A
4431484 Weber et al. Feb 1984 A
4439277 Dix Mar 1984 A
4445977 Husher May 1984 A
4446018 Cerwick May 1984 A
4448541 Wirtschafter May 1984 A
4452749 Kolvek et al. Jun 1984 A
4459103 Gieskieng Jul 1984 A
4469446 Goodboy Sep 1984 A
4498786 Ruscheweyh Feb 1985 A
4508539 Nakai Apr 1985 A
4527488 Lindgren Jul 1985 A
4568426 Orlando et al. Feb 1986 A
4570670 Johnson Feb 1986 A
4614567 Stahlherm et al. Sep 1986 A
4645513 Kubota et al. Feb 1987 A
4655193 Blacket Apr 1987 A
4655804 Kercheval et al. Apr 1987 A
4680167 Orlando et al. Jul 1987 A
4704195 Janicka et al. Nov 1987 A
4720262 Durr et al. Jan 1988 A
4726465 Kwasnik et al. Feb 1988 A
4929179 Breidenbach et al. May 1990 A
4941824 Holter et al. Jul 1990 A
5052922 Stokman et al. Oct 1991 A
5062925 Durselen et al. Nov 1991 A
5078822 Hodges et al. Jan 1992 A
5114542 Childress et al. May 1992 A
5228955 Westbrook, III Jul 1993 A
5318671 Pruitt Jun 1994 A
5447606 Prutt et al. Sep 1995 A
5480594 Wilkerson et al. Jan 1996 A
5670025 Baird Sep 1997 A
5928476 Daniels Jul 1999 A
5968320 Sprague Oct 1999 A
6017214 Sturgulewski Jan 2000 A
6059932 Sturgulewski May 2000 A
6139692 Tamura et al. Oct 2000 A
6152668 Knoch Nov 2000 A
6187148 Sturgulewski Feb 2001 B1
6189819 Racine Feb 2001 B1
6290494 Barkdoll Sep 2001 B1
6596128 Westbrook Jul 2003 B2
6626984 Taylor Sep 2003 B1
6699035 Brooker Mar 2004 B2
6758875 Reid et al. Jul 2004 B2
6907895 Johnson et al. Jun 2005 B2
6946011 Snyder Sep 2005 B2
7056390 Fratello et al. Jun 2006 B2
7077892 Lee Jul 2006 B2
7314060 Chen et al. Jan 2008 B2
7331298 Taylor et al. Feb 2008 B2
7497930 Barkdoll et al. Mar 2009 B2
7611609 Valia et al. Nov 2009 B1
7644711 Creel Jan 2010 B2
7727307 Winkler Jun 2010 B2
7803627 Hodges Sep 2010 B2
7827689 Crane et al. Nov 2010 B2
7998316 Barkdoll et al. Aug 2011 B2
8071060 Ukai et al. Dec 2011 B2
8079751 Kapila et al. Dec 2011 B2
8152970 Barkdoll et al. Apr 2012 B2
8236142 Westbrook et al. Aug 2012 B2
8266853 Bloom et al. Sep 2012 B2
8398935 Howell, Jr. et al. Mar 2013 B2
20060102420 Huber et al. May 2006 A1
20080169578 Crane et al. Jul 2008 A1
20080179165 Chen et al. Jul 2008 A1
20080271985 Yamasaki Nov 2008 A1
20090152092 Kim et al. Jun 2009 A1
20090217576 Kim et al. Sep 2009 A1
20090283395 Hippe Nov 2009 A1
20100095521 Bertini et al. Apr 2010 A1
20100115912 Worley et al. May 2010 A1
20100287871 Bloom et al. Nov 2010 A1
20100300867 Kim et al. Dec 2010 A1
20110048917 Kim et al. Mar 2011 A1
20110120852 Kim May 2011 A1
20110192395 Kim Aug 2011 A1
20110223088 Chang et al. Sep 2011 A1
20110253521 Kim Oct 2011 A1
20110315538 Kim et al. Dec 2011 A1
20120024688 Barkdoll Feb 2012 A1
20120030998 Barkdoll et al. Feb 2012 A1
20120152720 Reichelt et al. Jun 2012 A1
20120228115 Westbrook Sep 2012 A1
20120305380 Wang et al. Dec 2012 A1
20130216717 Rego et al. Aug 2013 A1
20130306462 Kim et al. Nov 2013 A1
20140033917 Rodgers et al. Feb 2014 A1
20140048402 Quanci et al. Feb 2014 A1
20140048404 Quanci et al. Feb 2014 A1
20140048405 Quanci et al. Feb 2014 A1
20140061018 Sarpen et al. Mar 2014 A1
20140083836 Quanci et al. Mar 2014 A1
20140182195 Quanci et al. Jul 2014 A1
20140182683 Quanci et al. Jul 2014 A1
20140183024 Chun et al. Jul 2014 A1
20140183026 Quanci et al. Jul 2014 A1
20140262139 Choi et al. Sep 2014 A1
20140262726 West et al. Sep 2014 A1
20150122629 Freimuth et al. May 2015 A1
20150247092 Quanci et al. Sep 2015 A1
20150287026 Yang et al. Oct 2015 A1
Foreign Referenced Citations (71)
Number Date Country
2775992 May 2011 CA
2822857 Jul 2012 CA
2064363 Oct 1990 CN
1092457 Sep 1994 CN
1255528 Jun 2000 CN
1358822 Jul 2002 CN
2509188 Sep 2002 CN
2528771 Jan 2003 CN
1468364 Jan 2004 CN
2668641 Jan 2005 CN
202226816 May 2012 CN
212176 Jul 1909 DE
3315738 Nov 1983 DE
3231697 Jan 1984 DE
3329367 Nov 1984 DE
19545736 Jun 1997 DE
19803455 Aug 1999 DE
10154785 May 2003 DE
102009031436 Jan 2011 DE
102011052785 Dec 2012 DE
2339664 Aug 1977 FR
441784 Jan 1936 GB
606340 Aug 1948 GB
611524 Nov 1948 GB
725865 Mar 1955 GB
871094 Jun 1961 GB
50148405 Nov 1975 JP
54054101 Apr 1979 JP
57051786 Mar 1982 JP
57051787 Mar 1982 JP
57083585 May 1982 JP
57090092 Jun 1982 JP
58091788 May 1983 JP
59051978 Mar 1984 JP
59053589 Mar 1984 JP
59071388 Apr 1984 JP
59108083 Jun 1984 JP
59145281 Aug 1984 JP
60004588 Jan 1985 JP
61106690 May 1986 JP
62011794 Jan 1987 JP
62285980 Dec 1987 JP
S-62285980 Dec 1987 JP
01103694 Apr 1989 JP
01249886 Oct 1989 JP
H0319127 Jan 1991 JP
07188668 Jul 1995 JP
07216357 Aug 1995 JP
08127778 May 1996 JP
2001200258 Jul 2001 JP
03197588 Aug 2001 JP
2002106941 Apr 2002 JP
200341258 Feb 2003 JP
2003071313 Mar 2003 JP
04159392 Oct 2008 JP
2009144121 Jul 2009 JP
2012102302 May 2012 JP
960008754 Oct 1996 KR
20000012393 Mar 2000 KR
10-0797852 Jan 2008 KR
10-2011-0010452 Feb 2011 KR
10-0296700 Oct 2011 KR
101318388 Oct 2013 KR
WO-9012074 Oct 1990 WO
WO-9945083 Sep 1999 WO
WO-2007103649 Sep 2007 WO
WO-2008034424 Mar 2008 WO
WO-2010107513 Sep 2010 WO
2011000447 Jan 2011 WO
WO-2012029979 Mar 2012 WO
2013023872 Feb 2013 WO
Non-Patent Literature Citations (17)
Entry
International Search Report and Written Opinion of International Application No. PCT/US2012/072173; Date of Mailing: Sep. 26, 2013; 10 pages.
Crelling, et al., “Effects of Weathered Coal on Coking Properties and Coke Quality”, Fuel, 1979, vol. 58, Issue 7, pp. 542-546.
Database WPI, Week 199115, Thomson Scientific, Lond, GB; AN 1991-107552.
Diez, et al., “Coal for Metallurgical Coke Production: Predictions of Coke Quality and Future Requirements for Cokemaking”, International Journal of Coal Geology, 2002, vol. 50, Issue 1-4, pp. 389-412.
JP 03-197588, Inoqu Keizo et al., Method and Equipment for Boring Degassing Hole in Coal Charge in Coke Oven, Japanese Patent (Abstract Only) Aug. 28, 1991.
JP 04-159392, Inoue Keizo et al., Method and Equipment for Opening Hole for Degassing of Coal Charge in Coke Oven, Japanese Patent (Abstract Only) Jun. 2, 1992.
ASTM D5341-99(2010)e1, Standard Test Method for Measuring Coke Reactivity Index (CRI) and Coke Strength After Reaction (CSR), ASTM International, West Conshohocken, PA, 2010.
Clean coke process: process development studies by USS Engineers and Consultants, Inc., Wisconsin Tech Search, request date Oct. 5, 2011, 17 pages.
Rose, Harold J., “The Selection of Coals for the Manufacture of Coke,” American Institute of Mining and Metallurgical Engineers, Feb. 1926, 8 pages.
U.S. Appl. No. 14/655,003, filed Jun. 23, 2015, Ball, Mark A., et al.
U.S. Appl. No. 14/655,013, filed Jun. 23, 2015, West, Gary D., et al.
U.S. Appl. No. 14/655,204, filed Jun. 24, 2015, Quanci, John F., et al.
U.S. Appl. No. 14/839,384, filed Aug. 28, 2015, Quanci, John F., et al.
U.S. Appl. No. 14/839,493, filed Aug. 28, 2015, Quanci, John F., et al.
U.S. Appl. No. 14/839,551, filed Aug. 28, 2015, Quanci, John F., et al.
U.S. Appl. No. 14/839,588, filed Aug. 28, 2015, Quanci, John F., et al.
U.S. Appl. No. 14/865,581, filed Sep. 25, 2015, Sarpen, Jacob P., et al.
Related Publications (1)
Number Date Country
20140183023 A1 Jul 2014 US