Systems and methods for efficient heating of sorbents in an indoor air scrubber

Information

  • Patent Grant
  • 10765990
  • Patent Number
    10,765,990
  • Date Filed
    Thursday, February 8, 2018
    6 years ago
  • Date Issued
    Tuesday, September 8, 2020
    4 years ago
Abstract
Embodiments of the present disclosure are directed to systems and methods for regenerating a sorbent material of a scrubber, configured for scrubbing a contaminant from indoor air from an enclosed space. Some embodiments include a sorbent material portion (SMP) including a sorbent material, which may be configured to be cycled between an adsorption phase for adsorbing a contaminant from indoor air, and a regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof, via temperature swing adsorption, into a purging airflow.
Description
TECHNICAL FIELD

Embodiments of the present disclosure generally relate to air management systems and particularly to indoor air treatment and contaminant removal therefrom.


BACKGROUND

Sorbent materials are used in gas separation, by selectively adsorbing certain gas species. Some sorbents can be regenerated by means of heat and a purging gas stream, thereby releasing the adsorbed species and allowing repeated use, in a cycle known as temperature swing adsorption.


SUMMARY OF SOME OF THE EMBODIMENTS

Treating indoor air with regenerable solid sorbents may be used as a means to achieving improved indoor air quality and improved economics of heating, ventilation and air conditioning (HVAC). The use of regenerable sorbents in a scrubber incorporated into an air management system allows for long term operation, as a relative small amount of sorbent can be used repeatedly through a two-phase cycle of adsorption and regeneration. During the adsorption phase, contaminants are captured and removed from streaming indoor air, and during regeneration, the captured contaminants are desorbed, or released, and exhausted outdoors. The contaminants may comprise carbon dioxide, volatile organic compounds, sulfur oxides, radon, nitrous oxides or carbon monoxide, for example.


The regeneration can be facilitated by elevating the temperature of the sorbent and purging it with outdoor air, acting as a purge gas, to carry away the adsorbed contaminants. In some embodiments, the heat is delivered to the sorbent by using heated outdoor air. Such heating can be achieved by a variety of methods, for example a heating coil on the incoming path of the purge gas. The heating of the purge gas represents a potential additional energy cost for operating such a regenerable sorbent scrubber, especially if the outdoor air temperature is substantially lower than the temperature required for regenerating the sorbent.


In some embodiments, the energy usage of a scrubber using regenerable sorbents may be improved by introducing a heat exchanger assembly or by heating the sorbent in a closed loop. For example, in some embodiments, during regeneration of the sorbents, incoming purge gas may capture heat from the exhausted purge gas by means of a heat exchanger assembly, for elevating the temperature of the incoming purge gas prior to entering thereto. In some embodiments, the sorbent may be heated by circulating heated air in a closed loop with respect to the sorbent until the sorbent reaches its target regeneration temperature, significantly reducing the loss of heating energy to the exhausted purge gas.


Such embodiments can reduce the amount of energy consumed by the system, or enable a higher gas temperature reaching the sorbent, thereby accelerating the regeneration and improving the net operating time of the scrubber.


In some embodiments, a system for regenerating a sorbent material of a scrubber is provided, where the scrubber is configured for scrubbing a contaminant from indoor air from an enclosed space. The system includes a sorbent material portion (SMP) including a sorbent material, which may be configured to be cycled between at least two operational phases including an adsorption phase for adsorbing a contaminant from indoor air, and a regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof, via temperature swing adsorption, into a purging airflow (which may be configured to flow over and/or through the sorbent). The system may further include a heater configured to heat at least one of the sorbent material and the purging airflow to a regeneration temperature, and a heat exchanger configured to transfer heat from a purging airflow exiting the SMP after flowing over and/or through the sorbent material (i.e., an exhausted purging airflow) to an incoming fresh purging airflow.


In some embodiments, the enclosed space may comprise a building, a house, a vehicle, or a vessel. The contaminant may be selected from the group consisting of carbon dioxide, volatile organic compounds, sulfur oxides, radon, nitrous oxides and carbon monoxide.


In some embodiments, the purging airflow may comprise outdoor air, and wherein the system may further comprise an outdoor air inlet configured to receive the outdoor air at an outdoor air temperature, and the received outdoor air may be heated directly and/or indirectly by the heater to at least the regeneration temperature. The system may further comprise an exhaust air outlet for discharging an exhausted purging airflow, and a conduit, wherein during at least an initial or first phase of the regeneration phase, the conduit may be configured in a closed loop or shunt conduit arrangement with the SMP (e.g., the outdoor air inlet and the exhaust air outlet thereof), such that during at least the initial phase of the regeneration phase, the purging airflow exiting from the SMP is directed back to an inlet/entrance of the SMP to be flowed over and/or through the sorbent material again


In some embodiments, the heater may be selected from the group consisting of an electrical coil, a hot fluid coil, a furnace, and a solar heating device. The configuration of the heat exchanger may be selected from the group consisting of a shell and tube configuration, an air coil configuration, a plate configuration, a counter-flow configuration, and a fin configuration. The heat exchanger may further comprise an outdoor air inlet for receiving an incoming fresh purging airflow and/or an exhaust air outlet for discharging an exhausted purging airflow.


In some embodiments, the system may further comprise an incoming purging airflow conduit and an exhausted purging airflow conduit, wherein the heat exchanger is configured to transfer heat from the exhausted purging airflow to the incoming purging, via thermal communication between the exhausted purging airflow conduit and the incoming purging airflow conduit.


In some embodiments, the heat exchanger may be configured to transfer heat from the exhausted purging airflow to the incoming purging airflow in an amount approximately equal to H given by the expression H=(Te−T0)×E×F, wherein E is an efficiency coefficient of the heat exchanger, F is a flow rate of the incoming purging airflow, T0 is the temperature of the outdoor air, and Te is the temperature of the exhausted purging airflow. The system may further comprise a fan to at least aid in the flow of indoor air and/or the purging airflow.


According to some embodiments, there is provided a system for regenerating a sorbent material of a scrubber configured for scrubbing a contaminant from indoor air from an enclosed space comprising a sorbent material portion (SMP) including a sorbent material which is configured to be cycled between an adsorption phase for adsorbing a contaminant from indoor air, and a regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof, via temperature swing adsorption into a purging airflow. The system may include a heater configured to heat at least one of the sorbent material and the purging airflow for flowing over and/or through the sorbent material to a regeneration temperature, and a shunt conduit, wherein during at least an initial or first phase of the regeneration phase, the shunt conduit is configured in a closed loop arrangement with the SMP, such that an exhausted purging airflow exiting the SMP is directed back into the SMP so as to be flowed over at least one of the heater and over and/or through the sorbent material.


In some embodiments, the conduit may be configured in the closed loop arrangement at least until the temperature of the sorbent material reaches the regeneration temperature. During a second phase of the regeneration phase the shunt conduit may be sealed by one or more dampers and the purging air flow is exhausted outside.


According to some embodiments, there is provided a method for regenerating a sorbent material of a scrubber for scrubbing a contaminant from indoor air from an enclosed space, comprising receiving a flow of outdoor air configured as an incoming fresh purging airflow to regenerate a sorbent material of a scrubber, the sorbent material configured to be cycled between an adsorption phase for adsorbing a contaminant from indoor air, and a regeneration phase for releasing at least a portion of the adsorbed contaminant thereof into the incoming fresh purging airflow, and facilitating thermal communication of the incoming fresh purging airflow with an exhausted purging airflow after having flowed over and/or through the sorbent material, so as to effect transfer of heat from the exhausted purging airflow to the incoming fresh purging airflow.


In some embodiments, the method may further include directly and/or indirectly heating the incoming fresh purging airflow via a heater to at least aid in heating the incoming fresh purging airflow to at least a regeneration temperature.


In some embodiments facilitating thermal communication between the incoming fresh purging airflow and the exhausted purging airflow is accomplished via a heat exchanger.


In some embodiments, facilitating thermal communication of the incoming fresh purging airflow with the exhausted purging airflow may comprise arranging an exhaust conduit for the exhausted purging airflow in close proximity to an incoming conduit for the incoming fresh purging airflow such that heat is transferred from the exhausted purging airflow to the incoming fresh purging airflow.


According to some embodiments, there is provided a method for regenerating a sorbent material of a scrubbing system for scrubbing a contaminant from indoor air from an enclosed space, comprising during at least an initial time prior to a regeneration phase for regenerating a sorbent material, operating a closed loop airflow over and/or through a sorbent material, and heating, during operation of the closed loop airflow, at least one of the closed loop airflow and/or sorbent material at least until the temperature of the sorbent material reaches a regeneration temperature.


In some embodiments, the method may further comprise receiving a flow of outdoor air configured as an incoming fresh purging airflow to regenerate the sorbent material during at least a portion of the regeneration phase, such that at least a portion of the contaminant previously adsorbed by the sorbent material is released into the incoming fresh purging airflow as it flows over and/or through the sorbent material. The method may further comprise directly and/or indirectly heating the incoming fresh purging airflow to at least a regeneration temperature.


Details of one or more variations of the subject matter described herein are set forth in the accompanying drawings and the description below. Other features and advantages of the subject matter described herein will be apparent from the description and drawings, and from the claims.





BRIEF DESCRIPTION OF THE DRAWINGS

The principles and operations of the systems, apparatuses and methods according to some embodiments of the present disclosure may be better understood with reference to the drawings, and the following description. These drawings are given for illustrative purposes only and are not meant to be limiting.



FIGS. 1A-1C are each a schematic illustration of a system for regenerating a sorbent material of a scrubber, according to some embodiments of the present disclosure; and



FIGS. 2A and 2B are a schematic illustration of a system for regenerating a sorbent material of a scrubber at a first operational phase (FIG. 2A) and at a second operational phase (FIG. 2B) according to some embodiments of the present disclosure.





DETAILED DESCRIPTION OF SOME OF THE EMBODIMENTS


FIGS. 1A-1C each illustrate a schematic diagram of a system 10 for regenerating a sorbent material of a regenerable sorbent based scrubber 100 for indoor air. In some embodiments, the scrubber 100 may comprise a sorbent 102 including a sorbent material, which may be deployed in an enclosure 104, which may or may not be air-tight. The scrubber 100 may include a single or plurality of inlets 110 and outlets 112. In some embodiments, each inlet 110 or outlet 112 may be controlled by a mechanical damper 114, shutter or valve. The scrubber 100 may operate in several modes or phases (such terms may be used interchangeably), including an adsorption phase and a regeneration phase.


During the adsorption phase, at least a portion of indoor air 115 may flow into the scrubber 100 from an enclosed space via inlet 110, and may be forced to flow through the sorbent 102, where contaminants may be trapped and removed from the air stream. Thereafter the air may proceed to emerge from the scrubber 100, via outlet 112. The flow of air through the scrubber 100 may be aided by means of a fan.


During the regeneration phase, outdoor air, a purging airflow or any other purge gas 130, may flow into the scrubber 100 via an outdoor air inlet 134 and may be exhausted as exhausted purge gas via an exhaust air outlet 136. Damper 138 may be provided to control the flow of the incoming purge gas and damper 139 may control the flow of the exhaust purge gas. The direction of flow through sorbent 102 during regeneration may be the same as during adsorption, or reversed to the indoor airflow 115 direction, as shown in FIGS. 1A-1C, depending on the configuration of the respective inlets and outlets.


In some embodiments, the heated purge gas 130 may perform several functions, one of which may include delivering heat to the sorbent 102 so as to elevate its temperature and facilitate the release of adsorbed molecular species, including the contaminants trapped in the sorbent 102, and another may be to dilute and carry away the desorbed molecules. The latter function is best achieved when the incoming purge gas 130 itself has as low as possible a concentration of the desorbed species, and lower than the concentration of the same species in the air that was initially scrubbed by the sorbent. The ability of such a lower contaminant concentration gas flow to induce desorption is sometimes referred to as concentration-swing adsorption/desorption.


In some embodiments, the purge gas 130 may be heated by means of a heating element 140 comprising a heater and configured to come into thermal contact with the incoming purge gas 130, before it reached the sorbent 102.


The heating element 140 can be an electrical coil, a hot fluid coil, a furnace, a solar heating device, or any other suitable heating element. The heating of the incoming air can be performed in a heating unit 142. The heating unit 142 can be attached to the scrubber 100 (FIG. 1A), or can be separately located in relative vicinity to the scrubber 100 where a conduit 144 facilitates thermal contact between the purge gas 130 and the heating element 140 (FIG. 1B).


During regeneration, outdoor air or purge gas 130 may be delivered to and from the inlet 134 and outlet 136. If the entire scrubber 100 is placed outdoors, purge gas 130 can be drawn in simply by opening the damper 138 to the outside, and similarly the purge gas 130 may be exhausted by opening the damper 139 to the outside. However, if the system is placed inside a building, for example, in a mechanical room or a basement, then appropriate ducts or conduits may be required to bring in air from outside the building and to exhaust the purge gas 130 outside the building.


In some embodiments, the purge gas 130, comprising the outdoor air and received via the outdoor air inlet 134, may be heated directly and/or indirectly by the heating element 140 to at least the regeneration temperature.


The incoming purge gas 130 during regeneration may be heated to a temperature Ti. In the case of outdoor air, the temperature Ti of the purge gas 130 entering the scrubber 100, may depend on at least three parameters (according to some embodiments):


The temperature T0 of the outdoor air 130 drawn into the heating element 140.


The heat capacity C of the air at the ambient pressure and temperature conditions.


The flow rate F of the outdoor air 130.


The heating power P delivered by the heating element 140.


The change in incoming air temperature of the outdoor air 130, caused by the heating element 140, ΔT=Ti−T0 is expressed by:







Δ





T

=

P

F
×
C






As it passes through the sorbent 102, some of the outdoor air heat is transferred to the sorbent 102, thus heating the sorbent 102 while cooling the outdoor air 130. Therefore the exhausted outdoor air 130 exits the scrubber 100 at a temperature Te which is lower than Ti, but may still be higher than T0, namely warmer than the outdoor air 130 before it reaches the heating element 140.


Because Ti may be significant for the speed and efficiency of the regeneration process, and because it is directly related to T0, it is advantageous to increase T0. Increasing T0 allows the system to achieve a higher Ti with the same amount of power P, or alternatively to achieve the same Ti with less power consumption.


In some embodiments, this objective can be accomplished using a heat exchanger assembly 150 to take advantage of the fact that Te>T0. The heat exchanger assembly 150 may be placed at any suitable location, such as intermediate inlet 134 and outlet 136, as shown in FIGS. 1A and 1B. In some embodiments, the heat exchanger assembly 150 may be mounted directly at the outlet 136. In some embodiments, the heat exchanger assembly 150 may be attached to an inlet of the heating element 140. In some embodiments the heat exchanger assembly 150 may be attached to both inlet 134 and outlet 136 by means of conduits or ducts.


Heat exchange can be performed by any number of means or configurations of heat exchange assemblies for facilitating thermal communication between the exhausted purging airflow and the incoming purging airflow. The heat exchanger assembly 150 may be configured to transfer heat from the exhausted purging airflow to the incoming purging airflow via thermal communication between the exhausted purging airflow conduit and the incoming purging airflow conduit.


The thermal communication may include any type of heat transfer, such as by contact, convention or conduction, for example. In a non-limiting example, the heat exchanger assembly 150 may comprise a shell and tube configuration, an air coil configuration, a plate configuration, a fin configuration or a counter-flow configuration.


In some embodiments, the heat exchanger assembly 150 may be facilitated by having an outdoor air conduit 154, and the exhaust air conduit 156 run in parallel and in close thermal communication over an extended length of these conduits, as seen in FIG. 1C. Thermal communication can be assisted by increasing a shared surface area of the parallel conduits. The outdoor air conduit 154 may comprise an incoming purging airflow conduit and the exhaust air conduit 156 may comprise an exhausted purging airflow conduit.


In some embodiments, counter-flow of the cooler incoming air and the warmer exhaust air can provide a very high rate of heat exchange.


The heat exchange assembly 150 may be designed to transfer heat between two separate gas streams, such as the incoming outdoor air 130 through the inlet 134 and the outdoor air 130 exiting the outlet 136. The amount of heat transferred, H, generally depends on the flow rate and temperature difference between the coupled streams, and on the heat transfer efficiency coefficient, E, of the heat exchange assembly 150, which is determined by the structure and physical properties thereof, as well as the operating conditions.


Thus the heat transfer may be expressed as

H=(Te−T0E×F


The heat transfer may translate directly into a reduction in the required heat of the heating element 140.


Another way to look at the impact of the heat exchange process is the change in temperatures of the two gas streams upon passing through the heat exchange assembly:

T0→T1=T0+δT


where T1 is the temperature of the incoming outdoor air 130 after it has passed the heat exchange assembly 150 and before reaching the heating element 140, and δT is the increase in its temperature as a result of the heat exchange.

Te→Tx=Te−δT′


where Tx is the temperature of the outgoing exhaust air after it has passed the heat exchange assembly 150, and δT′ is the decrease in its temperature as a result of the heat exchange.


Since this heat is imparted on the incoming outdoor air 130, it reduces the amount of power required for heating, or alternatively higher regeneration temperature is achieved, which in turn, shortens the regeneration time. A shorter regeneration time has at least two benefits: less overall energy used by the heating element, as the heating power is applied during a shorter duration; and larger fraction of the total adsorption-regeneration cycle time is dedicated to adsorption, namely to cleaning the air.


The relative impact of the heat exchange may depend on several parameters, including the efficiency of the heat exchanger and the exhaust temperature Te, and on outside temperature.


According to some embodiments, there is provided the system 10 for regenerating the sorbent material of the scrubber 100, configured for scrubbing and removing a contaminant from indoor air 115 from the enclosed space. The system may comprise a sorbent material portion (SMP) including the sorbent material which is configured to be cycled between: (i) an adsorption phase for adsorbing the contaminant from indoor air 115, and (ii) a regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof, via temperature swing adsorption into the purge gas 130. The heating element 140, including the heater, may be configured to heat at least one of the sorbent materials and/or the airflow flowing over and/or through the sorbent material to a regeneration temperature. The heat exchanger assembly 150, including the heat exchanger, may be configured to transfer heat from an exhausted purge gas exiting the SMP after flowing over and/or through the sorbent material to an incoming fresh purge gas.


According to some embodiments, there is provided a method for regenerating the sorbent material of the scrubber 100 including a scrubber 102 for scrubbing the contaminant from indoor air 115 from the enclosed space, comprising: (i) receiving a flow of outdoor air 130 configured as an incoming fresh purging airflow to regenerate the sorbent material of the scrubber 102. The sorbent material may be configured to be cycled between an adsorption phase for adsorbing the contaminant from indoor air 115, and a regeneration phase for releasing at least a portion of the adsorbed contaminant thereof into the incoming fresh purging airflow; and (ii) facilitating thermal communication of the incoming fresh purging airflow with an exhausted purging airflow after having flowed over and/or through the sorbent material, so as to effect transfer of heat from the exhausted purging airflow to the incoming fresh purging airflow.


The examples as set forth herein are meant to exemplify some of the various aspects of carrying out the invention and are not intended to limit the invention in any way.


Example Procedure

The optimal regeneration temperature is 60° C., and circulating indoor air is kept between 20-25° C., while outdoor air is 30° C. As regeneration begins, the sorbent is approximately at indoor temperature. Purge air is heated to 50° C., and the exhaust air is initially cooled by the sorbent emerging at approximately 35° C. As the regeneration proceeds, the sorbent gets warmer as does the exhaust purge air, approaching 45° C. towards the end of the regeneration phase. An ideal heat exchanger would heat the incoming air by 5-15° C. during the phase, on average about 10° C. representing about ⅓rd of the heat required for the 30 degree differential between outdoor air temperature of 30° C. and the required 60° C. optimal regeneration temperature.


Example Procedure

The same conditions as in the previous example except that outdoor air is 0° C. An ideal heat exchanger would heat the incoming air by 35-45° C. during the phase, on average about 40° C. representing about ⅔rd of the heat required for the 60 degree differential between outdoor air temperature of 0° C. and the required 60° C. optimal regeneration temperature.


In some embodiments, as seen in FIG. 1A, a fan 160 may be provided to urge the flow of the incoming purge gas 130 and aid the flow of indoor air and/or purge gas 130.



FIGS. 2A and 2B illustrate system 162 for regenerating a sorbent material of the scrubber 100 according to some embodiments. The system 162 is designed to reduce the energy and heat required to regenerate the sorbent in scrubber 100. Similar to the embodiments of FIGS. 1A-1C, during regeneration, purge gas 130 may enter the scrubber 100 via inlet 134 and exits via outlet 136, the fan 160 may be provided to urge the flow of the incoming purge gas 130 and aid the flow of indoor air and/or purge gas 130. Heating element 140 may be provided to heat the incoming purge gas 130.


As seen in FIGS. 2A and 2B, a shunt conduit 166 or any suitable connection may be installed to shunt exiting regeneration purge gas back into the sorbent 102 via the regeneration inlet 134, through the fan 160 and the heating element 140. Dampers 170 and 172 may temporarily block the entry of fresh purge gas 130, via inlet 134, and exit of the exhausted purge gas, via outlet 136, to the outside. In other words, the shunt conduit 166 and the dampers 170 and 172 may force air inside the scrubber 100 to flow in a closed loop, rather than continually bring in fresh regeneration gas and exhaust the purge gas after it has passed through the sorbent 102.


In some embodiments, it is beneficial that the heat that is delivered to the purge gas 130 is not lost to the exhaust purge gas exiting into the outside, but is kept in circulation in a closed loop, and not needing to heat an inflow of fresh outside air, thus again allowing the purge gas 130 and the sorbent 102 to reach a target temperature faster or with less heating power.


In some embodiments, the closed loop circulation means that contaminant molecules may be kept inside and thus the sorbent 102 may not be frilly cleansed. This can be addressed by conducting two separate phases in the regeneration phase, as follows.


Phase 1: Closed Loop Heating (FIG. 2A). During this phase, the shunt conduit 166 is open, the outside regeneration dampers 170 and 172 are sealed, the heating element 140 and/or fan 160 may be in operation. The exhaust purge gas 130 exits the sorbent 102 and flows into the shunt conduit 166 and circulates until the purge gas 130 reaches the target regeneration temperature.


Phase 2: Open Purge (FIG. 2B). During this phase, the shunt conduit 166 is sealed with shunt dampers 178 and 180 and the outside dampers 170 and 172 are open, allowing fresh outdoor air to flush the sorbent 102 and exhaust, carrying away the adsorbed contaminants. During this step, the heating element 140 may be on or off, depending on a number of considerations including the outdoor air temperature, the rate of cooling of the sorbent 102 and the time required to complete the flushing.


In some embodiments, the switchover from Phase 1 to Phase 2 can be performed automatically by a controller 190, such as an electronic control system, based on any parameter including actual temperature achieved or a timed duration.


The parameters may be measured by sensors 192. The sensors 192 may be configured in any suitable manner for detecting parameters of the airflow, for example, the sensors 192 may include electronic sensors and may be placed at any suitable location.


In some embodiments, the shunt conduit 166 can be a built-in or integral part of the scrubber 100. In other embodiments, the shunt conduit 166 can be installed externally, such as by means of conventional air ducts or tubes.


In some embodiments, to model the energy use in the case of the shunt conduit 166, a time dependent analysis may be required, where Ts(t) is the temperature of the sorbent 102 and approximately also the temperature of the air returning from the shunt conduit 166 to the fan 160, and the power P(t) adjusts so as to deliver the same air temperature into the scrubber 100, but does not exceed its maximum value Pmax and does not allow the air temperature to exceed Tmax.


The ingoing air temperature Tp (t) is then given by:

Tp(t)=min[Tmax,Ts(t)+ΔT]


where ΔT is the increase in temperature due to the heating element 140.


The rate of heat transfer to the sorbent 102, Q(t) depends on the temperature difference between the sorbent 102 and the incoming purge air or purge gas 130, with some system dependent coefficient we denote as γ:

Q(t)=γ×(Tp(t)−Ts(t))


And the rate of change of the sorbent temperature is simply given by its heat input Q(t) divided by its heat capacity, Cs, we arrive at a simple differential equation:










T
s




t


=


γ

C
s




(


T
p

-

T
s


)






This equation approximately solves for an exponential time dependence:

Ts(tT0+(Tmax−T0)e−(γ/Cs)t


that asymptotically approaches Tp and therefore Tmax, and the rate of approach, namely the heating time, depending on the choice of system parameters such as, for example, sorbent mass, heating element power, and air flow rate.


According to some embodiments, there is provided the system 162 for regenerating the sorbent material of the sorbent 102 of the scrubber 100. The system 162 may comprise a sorbent material portion (SMP) which may include the sorbent material which is configured to be cycled between (i) the adsorption phase for adsorbing a contaminant from indoor air, and (ii) a regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof, via temperature swing adsorption into a purging airflow. The system 162 may comprise the heating element 140, which may be configured to heat at least one of the sorbent material and the purging airflow for flowing over and/or through the sorbent material to a regeneration temperature. The system 162 may comprise the shunt conduit 166, wherein during at least an initial phase of the regeneration phase, the shunt conduit 166 may be configured in a closed loop arrangement with the SMP such that an exhausted purging airflow exiting the SMP is directed back through the heating element 140 and over and/or through the sorbent material.


According to some embodiments, there is provided a method for regenerating the sorbent material of the scrubber 100 for scrubbing the contaminant from indoor air 115 from an enclosed space, comprising: (i) during at least an initial time prior of a regeneration phase for regenerating the sorbent material, operating a closed loop airflow over and/or through the sorbent material; and (ii) heating, during operation of the closed loop airflow, at least one of the closed loop airflow and/or sorbent material at least until the temperature of the sorbent material reaches a regeneration temperature.


Dampers 178 and 180 may be formed as a three-way damper. It is noted that in addition or in place of the dampers and fans described herein, other components such as valves, blowers, or shutters, may be used to control the volume of indoor air 115 and/or outdoor air 130 entering and/or exiting the scrubber 100.


In some embodiments, system 162 may additionally include the heat exchanger assembly 150 of system 10 and may be used for transferring heat from the exhausted purging airflow exiting the SMP after flowing over and/or through the sorbent material to the incoming fresh purging airflow.


The enclosed pace may include any closed area such as buildings, homes, vessels or vehicles.


The scrubber 100 may be placed in any suitable location. In some embodiments, the scrubber 100 may operate in conjunction with an air handling unit of a centralized HVAC. In some embodiments, the scrubber 100 may operate in conjunction with an air handling unit of a distributed air circulation system, such as a fan-coil system. In some embodiments, the scrubber 100 may be a stand-alone-unit and may be placed in an enclosed space.


Various implementations of some of embodiments disclosed, in particular at least some of the processes discussed (or portions thereof), may be realized in digital electronic circuitry, integrated circuitry, specially configured ASICs (application specific integrated circuits), computer hardware, firmware, software, and/or combinations thereof. These various implementations, such as associated with the controller 190 or control unit, for example, may include implementation in one or more computer programs that are executable and/or interpretable on a programmable system including at least one programmable processor, which may be special or general purpose, coupled to receive data and instructions from, and to transmit data and instructions to, a storage system, at least one input device, and at least one output device.


Such computer programs (also known as programs, software, software applications or code) include machine instructions/code for a programmable processor, for example, and may be implemented in a high-level procedural and/or object-oriented programming language, and/or in assembly/machine language. As used herein, the term “machine-readable medium” refers to any computer program product, apparatus and/or device (e.g., non-transitory mediums including, for example, magnetic discs, optical disks, flash memory, Programmable Logic Devices (PLDs)) used to provide machine instructions and/or data to a programmable processor, including a machine-readable medium that receives machine instructions as a machine-readable signal. The term “machine-readable signal” refers to any signal used to provide machine instructions and/or data to a programmable processor.


To provide for interaction with a user, the subject matter described herein may be implemented on a computer having a display device (e.g., a LCD (liquid crystal display) monitor and the like) for displaying information to the user and a keyboard and/or a pointing device (e.g., a mouse or a trackball, touchscreen) by which the user may provide input to the computer. For example, this program can be stored, executed and operated by the dispensing unit, remote control, PC, laptop, smart-phone, media player or personal data assistant (“PDA”). Other kinds of devices may be used to provide for interaction with a user as well. For example, feedback provided to the user may be any form of sensory feedback (e.g., visual feedback, auditory feedback, or tactile feedback), and input from the user may be received in any form, including acoustic, speech, or tactile input. Certain embodiments of the subject matter described herein may be implemented in a computing system and/or devices that includes a back-end component (e.g., as a data server), or that includes a middleware component (e.g., an application server), or that includes a front-end component (e.g., a client computer having a graphical user interface or a Web browser through which a user may interact with an implementation of the subject matter described herein), or any combination of such back-end, middleware, or front-end components.


The components of the system may be interconnected by any form or medium of digital data communication (e.g., a communication network). Examples of communication networks include a local area network (“LAN”), a wide area network (“WAN”), and the Internet. The computing system according to some such embodiments described above may include clients and servers. A client and server are generally remote from each other and typically interact through a communication network. The relationship of client and server arises by virtue of computer programs running on the respective computers and having a client-server relationship to each other.


Any and all references to publications or other documents, including but not limited to, patents, patent applications, articles, webpages, books, etc., presented anywhere in the present application, are herein incorporated by reference in their entirety.


Example embodiments of the devices, systems and methods have been described herein. As may be noted elsewhere, these embodiments have been described for illustrative purposes only and are not limiting. Other embodiments are possible and are covered by the disclosure, which will be apparent from the teachings contained herein. Thus, the breadth and scope of the disclosure should not be limited by any of the above-described embodiments but should be defined only in accordance with claims supported by the present disclosure and their equivalents. Moreover, embodiments of the subject disclosure may include methods, systems and devices which may further include any and all elements/features from any other disclosed methods, systems, and devices, including any and all features corresponding to systems, methods and devices for regenerating a sorbent material. In other words, features from one and/or another disclosed embodiment may be interchangeable with features from other disclosed embodiments, which, in turn, correspond to yet other embodiments. Furthermore, one or more features/elements of disclosed embodiments may be removed and still result in patentable subject matter (and thus, resulting in yet more embodiments of the subject disclosure). Also, the lack of one or more features, structure, and/or steps for one and/or another embodiment as compared to the prior art which includes such a feature(s), structure, and/or step(s) provides yet additional patentable embodiments for the present disclosure (i.e., claims for one and/or another embodiments may include negative limitations for being distinguished from the prior art).

Claims
  • 1. A system for regenerating a sorbent material of a scrubber configured for scrubbing a contaminant from indoor air from an enclosed space comprising: a sorbent material portion (SMP) including a sorbent material, the SMP configured to be cycled between at least two operational phases including: an adsorption phase for adsorbing a contaminant from indoor air, anda regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof via temperature swing adsorption into a purging airflow,wherein the system is configured to operate in one operational phase at a time; anda shunt conduit configurable in a closed loop arrangement with the SMP, such that during at least a first phase of the regeneration phase, the purging airflow exiting from the SMP is directed back to an inlet of the SMP to be flowed over and/or through the sorbent material again.
  • 2. The system of claim 1, wherein the conduit is configured in the closed loop arrangement at least until the temperature of the sorbent material reaches the regeneration temperature.
  • 3. The system of claim 1, wherein during a second phase of the regeneration phase the shunt conduit is closed off by one or more dampers and the purging air flow is exhausted to the outdoor environment.
  • 4. The system of claim 1, further comprising a heater configured to heat at least one of the sorbent material and the purging airflow to a regeneration temperature.
  • 5. The system of claim 1, wherein the shunt conduit is configurable in a closed loop arrangement with the SMP during the regeneration phase only.
  • 6. A system for regenerating a sorbent material of a scrubber configured for scrubbing a contaminant from indoor air from an enclosed space comprising: a sorbent material portion (SMP) including a sorbent material, the SMP configured to be cycled between at least two operational phases including: an adsorption phase for adsorbing a contaminant from indoor air, anda regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof via temperature swing adsorption into a purging airflow, the purging airflow configured to flow over and/or through the sorbent material during the regeneration cycle;a heater configured to heat at least one of the sorbent material and the purging airflow to a regeneration temperature;a heat exchanger configured to transfer heat from the purging airflow exiting the SMP after flowing over and/or through the sorbent material to an incoming fresh purging airflow;an air inlet configured to receive the purging airflow at a first temperature, anda conduit configurable during the regeneration phase only to establish a closed loop or shunt arrangement with the SMP,wherein: the system is configured to operate in one operational phase at a time;the received purging airflow is heated directly and/or indirectly by the heater from the first temperature to at least the regeneration temperature, andthe conduit is configurable to establish the closed loop or shunt arrangement with the SMP such that during at least an initial phase of the regeneration phase, the purging airflow exiting from the SMP is directed back to an inlet of the SMP to be flowed over and/or through the sorbent material again.
  • 7. The system of claim 6, wherein the heater is selected from the group consisting of: an electrical coil, a hot fluid coil, a furnace, and a solar heating device.
  • 8. The system of claim 6, wherein configuration of the heat exchanger is selected from the group consisting of: a shell and tube configuration, an air coil configuration, a plate configuration, a counter-flow configuration, and a fin configuration.
  • 9. The system of claim 6, further comprising an incoming purging airflow conduit and an exhausted purging airflow conduit, wherein the heat exchanger is configured to transfer heat from the exhausted purging airflow to the incoming purging airflow via thermal communication between the exhausted purging airflow conduit and the incoming purging airflow conduit.
  • 10. A system for regenerating a sorbent material of a scrubber configured for scrubbing a contaminant from indoor air from an enclosed space comprising: a sorbent material portion (SMP) including a sorbent material, the SMP configured to be cycled between at least two operational phases including: an adsorption phase for adsorbing a contaminant from indoor air, anda regeneration phase configured for releasing at least a portion of the contaminant adsorbed by the sorbent material during the adsorption phase thereof via temperature swing adsorption into a purging airflow; anda shunt conduit configurable in a closed loop arrangement with the SMP, such that during at least a first phase of the regeneration phase, the purging airflow exiting from the SMP is directed back to an inlet of the SMP to be flowed over and/or through the sorbent material again,wherein during a second phase of the regeneration phase, the shunt conduit is closed off by one or more dampers and the purging air flow is exhausted to the outdoor environment.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 15/022,800, filed Mar. 17, 2016, now U.S. Pat. No. 9,919,257, which is a National Stage Entry entitled to and hereby claiming priority under 35 U.S.C. §§ 365 and 371 to corresponding PCT Application No. PCT/US2014/056097, filed Sep. 17, 2014, entitled “Systems And Methods For Efficient Heating Of Sorbents In An Indoor Air Scrubber”, which in turn claims priority to U.S. Provisional Patent Application No. 61/879,099, filed Sep. 17, 2013, and entitled “Indoor Air Scrubber with a Heat Exchanger”. The disclosure of each of the above applications is incorporated herein by referenced in its entirety.

US Referenced Citations (242)
Number Name Date Kind
1522480 Allen Jan 1925 A
1836301 Bechtold Dec 1931 A
2633928 Chamberlain Apr 1953 A
3042497 Johnson et al. Jul 1962 A
3107641 Haynes Oct 1963 A
3344050 Mayland et al. Sep 1967 A
3511595 Fuchs May 1970 A
3594983 Yearout Jul 1971 A
3619130 Ventriglio et al. Nov 1971 A
3702049 Morris, Jr. Nov 1972 A
3751848 Ahlstrand Aug 1973 A
3751878 Collins Aug 1973 A
3795090 Barnebey Mar 1974 A
3808773 Reyhing et al. May 1974 A
3885927 Sherman et al. May 1975 A
3885928 Wu May 1975 A
4182743 Rainer et al. Jan 1980 A
4228197 Means Oct 1980 A
4249915 Sircar et al. Feb 1981 A
4292059 Kovach Sep 1981 A
4322394 Mezey et al. Mar 1982 A
4325921 Aiken et al. Apr 1982 A
4409006 Mattia Oct 1983 A
4433981 Slaugh et al. Feb 1984 A
4451435 Holter et al. May 1984 A
4472178 Kumar et al. Sep 1984 A
4530817 Hölter et al. Jul 1985 A
4551304 Holter et al. Nov 1985 A
4559066 Hunter et al. Dec 1985 A
4711645 Kumar Dec 1987 A
4810266 Zinnen et al. Mar 1989 A
4816043 Harrison Mar 1989 A
4863494 Hayes Sep 1989 A
4892719 Gesser Jan 1990 A
4917862 Kraw et al. Apr 1990 A
4976749 Adamski et al. Dec 1990 A
4987952 Beal et al. Jan 1991 A
5046319 Jones Sep 1991 A
5087597 Leal et al. Feb 1992 A
5109916 Thompson May 1992 A
5137548 Grenier et al. Aug 1992 A
5149343 Sowinski Sep 1992 A
5186903 Cornwell Feb 1993 A
5194158 Matson Mar 1993 A
5221520 Cornwell Jun 1993 A
5231063 Fukumoto et al. Jul 1993 A
5281254 Birbara et al. Jan 1994 A
5290345 Osendorf et al. Mar 1994 A
5292280 Janu et al. Mar 1994 A
5322473 Hofstra et al. Jun 1994 A
5352274 Blakley Oct 1994 A
5376614 Birbara et al. Dec 1994 A
5389120 Sewell et al. Feb 1995 A
5407465 Schaub et al. Apr 1995 A
5443625 Schaffhausen Aug 1995 A
5464369 Federspiel Nov 1995 A
5471852 Meckler Dec 1995 A
5492683 Birbara et al. Feb 1996 A
5584916 Yamashita et al. Dec 1996 A
5614000 Kalbassi Mar 1997 A
5646304 Acharya et al. Jul 1997 A
5672196 Acharya et al. Sep 1997 A
5675979 Shah Oct 1997 A
5702505 Izumi et al. Dec 1997 A
5707005 Ketler et al. Jan 1998 A
5827355 Wilson Oct 1998 A
5869323 Horn Feb 1999 A
5876488 Birbara et al. Mar 1999 A
5904896 High May 1999 A
5948355 Fujishima et al. Sep 1999 A
5964927 Graham et al. Oct 1999 A
5984198 Bennett et al. Nov 1999 A
6024781 Bulow et al. Feb 2000 A
6027550 Vickery Feb 2000 A
6102793 Hansen Aug 2000 A
6123617 Johnson Aug 2000 A
6113674 Graham et al. Sep 2000 A
6120581 Markovs Sep 2000 A
6187596 Dallas et al. Feb 2001 B1
6254763 Izumi Jul 2001 B1
6280691 Homeyer et al. Aug 2001 B1
6364938 Birbara et al. Apr 2002 B1
6375722 Henderson et al. Apr 2002 B1
6402809 Monereau et al. Jun 2002 B1
6428608 Shah et al. Aug 2002 B1
6432367 Munk Aug 2002 B1
6432376 Choudhary et al. Aug 2002 B1
6533847 Seguin et al. Mar 2003 B2
6547854 Gray et al. Apr 2003 B1
6605132 Fielding Aug 2003 B2
6623550 Shah Sep 2003 B2
6711470 Hartensten et al. Mar 2004 B1
6726558 Meirav Apr 2004 B1
6773477 Lindsay Aug 2004 B2
6796896 Laiti Sep 2004 B2
6797246 Hopkins Sep 2004 B2
6866701 Meirav Mar 2005 B2
6908497 Sirwardane Jun 2005 B1
6916239 Siddaramanna et al. Jul 2005 B2
6916360 Seguin et al. Jul 2005 B2
6930193 Yaghi et al. Aug 2005 B2
6964692 Gittleman et al. Nov 2005 B2
6974496 Wegeng et al. Dec 2005 B2
7288136 Gray et al. Oct 2007 B1
7407533 Steins Aug 2008 B2
7407633 Potember et al. Aug 2008 B2
7449053 Hallam Nov 2008 B2
7472554 Vosburgh Jan 2009 B2
7645323 Massenbauer-Strafe et al. Jan 2010 B2
7662746 Yaghi et al. Feb 2010 B2
7666077 Thelen Feb 2010 B1
7802443 Wetzel Sep 2010 B2
7846237 Wright et al. Dec 2010 B2
7891573 Finkam et al. Feb 2011 B2
8157892 Meirav Apr 2012 B2
8210914 McMahan et al. Jul 2012 B2
8317890 Raether et al. Nov 2012 B2
8398753 Sergi et al. Mar 2013 B2
8491710 Meirav Jul 2013 B2
8690999 Meirav et al. Apr 2014 B2
8734571 Golden et al. May 2014 B2
9316410 Meirav et al. Apr 2016 B2
9328936 Meirav et al. May 2016 B2
9399187 Meirav et al. Jul 2016 B2
9566545 Meirav et al. Feb 2017 B2
9802148 Meirav et al. Oct 2017 B2
9919257 Meirav Mar 2018 B2
9939163 Meirav et al. Apr 2018 B2
9950290 Meirav et al. Apr 2018 B2
9976760 Meirav et al. May 2018 B2
9987584 Meirav et al. Jun 2018 B2
10046266 Meirav et al. Aug 2018 B2
10086324 Meirav Oct 2018 B2
10281168 Meirav et al. May 2019 B2
10525401 Meirav et al. Jan 2020 B2
20010021363 Poles et al. Sep 2001 A1
20010054415 Hanai et al. Dec 2001 A1
20020056373 Fielding May 2002 A1
20020078828 Kishkovich et al. Jun 2002 A1
20020083833 Nalette et al. Jul 2002 A1
20020147109 Branover et al. Oct 2002 A1
20020183201 Barnwell et al. Dec 2002 A1
20020193064 Michalakos et al. Dec 2002 A1
20030037672 Sircar Feb 2003 A1
20030097086 Gura May 2003 A1
20030188745 Deas et al. Oct 2003 A1
20040005252 Siess Jan 2004 A1
20040020361 Pellegrin Feb 2004 A1
20040069144 Wegeng et al. Apr 2004 A1
20040118287 Jaffe et al. Jun 2004 A1
20050133196 Gagnon et al. Jun 2005 A1
20050147530 Kang et al. Jul 2005 A1
20050191219 Uslenghi et al. Sep 2005 A1
20050262869 Tongu et al. Dec 2005 A1
20050284291 Alizadeh-Khiavi et al. Dec 2005 A1
20050288512 Butters Dec 2005 A1
20060032241 Gontcharov et al. Feb 2006 A1
20060054023 Raetz et al. Mar 2006 A1
20060079172 Fleming et al. Apr 2006 A1
20060112708 Reaves Jun 2006 A1
20060148642 Ryu et al. Jul 2006 A1
20060225569 Schmidt et al. Oct 2006 A1
20060236867 Neary Oct 2006 A1
20060249019 Roychoudhury et al. Nov 2006 A1
20080119356 Ryu et al. Mar 2008 A1
20080078289 Sergi et al. Apr 2008 A1
20080127821 Noack et al. Jun 2008 A1
20080135060 Kuo et al. Jun 2008 A1
20080173035 Thayer et al. Jul 2008 A1
20080182506 Jackson et al. Jul 2008 A1
20080210768 You Sep 2008 A1
20080216653 Paton-Ash et al. Sep 2008 A1
20080293976 Olah et al. Nov 2008 A1
20090000621 Haggblom et al. Jan 2009 A1
20090044704 Shen et al. Feb 2009 A1
20090071062 Hedman Mar 2009 A1
20090120288 Lackner et al. May 2009 A1
20090188985 Scharing et al. Jul 2009 A1
20090220388 Monzyk et al. Sep 2009 A1
20090260372 Skinner et al. Oct 2009 A1
20100076605 Harrod et al. Mar 2010 A1
20100154636 Liu et al. Jun 2010 A1
20100224565 Dunne et al. Sep 2010 A1
20100254868 Obee et al. Oct 2010 A1
20100262298 Johnson et al. Oct 2010 A1
20100275775 Griffiths et al. Nov 2010 A1
20100278711 Find Nov 2010 A1
20110064607 Hedman Mar 2011 A1
20110079143 Marotta et al. Apr 2011 A1
20110085933 Mazyek et al. Apr 2011 A1
20110146494 Desai et al. Jun 2011 A1
20110179948 Choi et al. Jul 2011 A1
20110189075 Wright et al. Aug 2011 A1
20110192172 Delacruz Aug 2011 A1
20110198055 Meirav et al. Aug 2011 A1
20110206572 McKenna et al. Aug 2011 A1
20110250121 Schmidt Oct 2011 A1
20110262327 Dillon et al. Oct 2011 A1
20110265648 Meirav Nov 2011 A1
20110269919 Min et al. Nov 2011 A1
20110277490 Meirav Nov 2011 A1
20110296872 Eisenberger Dec 2011 A1
20120004092 Raatschen et al. Jan 2012 A1
20120012005 Burke Jan 2012 A1
20120052786 Clawsey Mar 2012 A1
20120076711 Gebald et al. Mar 2012 A1
20120129267 Daly May 2012 A1
20120137876 Miller Jun 2012 A1
20120148858 Wu Jun 2012 A1
20120152116 Barclay et al. Jun 2012 A1
20120168113 Karamanos Jul 2012 A1
20120216676 Addiego et al. Aug 2012 A1
20120222500 Riess et al. Sep 2012 A1
20120271460 Rognili Oct 2012 A1
20120272966 Ando et al. Nov 2012 A1
20120311926 Mittelmark Dec 2012 A1
20120321511 Lorcheim Dec 2012 A1
20130052113 Molins et al. Feb 2013 A1
20130291732 Meirav Nov 2013 A1
20130331021 Rodell Dec 2013 A1
20140013956 Ericson et al. Jan 2014 A1
20140242708 Lundgren Aug 2014 A1
20140298996 Meirav et al. Oct 2014 A1
20140326428 Meirav et al. Nov 2014 A1
20150078964 Meirav et al. Mar 2015 A1
20150321135 Meirav et al. Nov 2015 A1
20160271556 Okano Sep 2016 A1
20160363333 Meirav et al. Dec 2016 A1
20170227241 Claesson et al. Aug 2017 A1
20180147526 Meirav et al. May 2018 A1
20180187907 Meirav et al. Jul 2018 A1
20180207574 Meirav et al. Jul 2018 A1
20180236396 Meirav et al. Aug 2018 A1
20180339261 Meirav et al. Nov 2018 A1
20180339262 Perl-Olshvang et al. Nov 2018 A1
20190143258 Meirav et al. May 2019 A1
20190186762 Meirav et al. Jun 2019 A1
20190247782 Meirav et al. Aug 2019 A1
20190262761 Meirav Aug 2019 A1
20190299154 Meirav et al. Oct 2019 A1
20190344211 Meirav et al. Nov 2019 A1
20190346161 Meirav et al. Nov 2019 A1
Foreign Referenced Citations (68)
Number Date Country
2640152 Apr 2010 CA
2141873 Sep 1993 CN
2612444 Apr 2004 CN
2729562 Sep 2005 CN
1872388 Dec 2006 CN
101001767 Jul 2007 CN
101072620 Nov 2007 CN
101199913 Jun 2008 CN
101444693 Jun 2009 CN
101500704 Aug 2009 CN
101564634 Oct 2009 CN
201363833 Dec 2009 CN
201618493 Nov 2010 CN
102233217 Nov 2011 CN
202032686 Nov 2011 CN
202270445 Jun 2012 CN
103119376 May 2013 CN
102006048716 Feb 2008 DE
0 475 493 Mar 1992 EP
2 465 596 Jun 2012 EP
2387791 Apr 1983 ES
2387791 Oct 2012 ES
56-158126 Dec 1981 JP
59-225232 Dec 1984 JP
60194243 Oct 1985 JP
02-092373 Mar 1990 JP
03-207936 Sep 1991 JP
5-161843 Jun 1993 JP
06-031132 Feb 1994 JP
08-114335 May 1996 JP
09085043 Mar 1997 JP
200291978 Oct 2000 JP
2001-170435 Jun 2001 JP
2001232127 Aug 2001 JP
3207936 Sep 2001 JP
2005-090941 Apr 2005 JP
2006275487 Oct 2006 JP
2009-150623 Jul 2009 JP
2009-202137 Sep 2009 JP
2010-149086 Jul 2010 JP
WO 88805693 Aug 1988 WO
WO 2002008160 Jan 2002 WO
WO 200212796 Feb 2002 WO
WO 2006016345 Feb 2006 WO
WO 2007128584 Nov 2007 WO
WO 2008155543 Dec 2008 WO
WO 2009126607 Oct 2009 WO
WO 2010091831 Aug 2010 WO
WO 2010124388 Nov 2010 WO
WO 2011114168 Sep 2011 WO
WO 2011146478 Nov 2011 WO
WO 2012071475 May 2012 WO
WO 2012100149 Jul 2012 WO
WO 2012120173 Sep 2012 WO
WO 2012145303 Oct 2012 WO
WO 2012134415 Oct 2012 WO
WO 2012152930 Nov 2012 WO
WO 2012158911 Nov 2012 WO
WO 2013012622 Jan 2013 WO
WO 2013074973 May 2013 WO
WO 2013106573 Jul 2013 WO
WO 2014015138 Jan 2014 WO
WO 2014047632 Mar 2014 WO
WO 2014078708 May 2014 WO
WO 2014153333 Sep 2014 WO
WO 2014176319 Oct 2014 WO
WO 2015042150 Mar 2015 WO
WO 2015123454 Aug 2015 WO
Non-Patent Literature Citations (44)
Entry
Gesser, H.D., “The Reduction of Indoor Formaldehyde Gas and that Emanating from Urea Formaldehyde Foam Insulation (UFFI)”, Environmental International, vol. 10, pp. 305-308, 1984.
Goeppert et al., “Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent,” J. Am. Chem. Soc., vol. 133, No. 50, Nov. 21, 2011 (Nov. 21, 2011) pp. 20164-20167 entire document.
Gray, M. L. et al., “Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide”, International Journal of Greenhouse Gas Control, vol. 2, Issue 1, Jan. 2008, pp. 3-8.
International Preliminary Report on Patentability, dated Apr. 2, 2015 for PCT/US2013/061422.
International Preliminary Report on Patentability, dated Jan. 29, 2015 for PCT/US2013/051077.
International Preliminary Report on Patentability, dated Jul. 23, 2015, for International Application No. PCT/US2014/011078.
International Preliminary Report on Patentability, dated May 28, 2015 for PCT/US2013/070383.
International Preliminary Report on Patentability, dated Nov. 29, 2012, for PCT/US2011/036801.
International Preliminary Report on Patentability, dated Oct. 23, 2014, for International Application No. PCT/US2013/035933.
International Search Report and the Written Opinion of the International Searching Authority for International Application No. PCT/US2012/024333 dated Sep. 5, 2012.
International Search Report and Written Opinion, dated Aug. 15, 2014 for PCT/US2014/031009.
International Search Report and Written Opinion, dated Dec. 20, 2013 for PCT/US2013/051077.
International Search Report and Written Opinion, dated Dec. 19, 2013 for PCT/US2013/061422.
International Search Report and Written Opinion, dated Jan. 28, 2013, for PCT/US2012/038343.
International Search Report and Written Opinion, dated Jan. 3, 2014 for PCT/US2013/042239.
International Search Report and Written Opinion, dated Jul. 10, 2014 for PCT/US2014/023488.
International Search Report and Written Opinion, dated Mar. 17, 2014 for PCT/US2013/070383.
International Search Report and Written Opinion, dated Mar. 22, 2013 for PCT/US2012/065600.
International Search Report and Written Opinion, dated Mar. 29, 2013 for PCT/US2013/021033.
International Search Report and Written Opinion, dated May 15, 2015, for PCT/US2015/015690.
International Search Report and Written Opinion, dated May 5, 2014, for PCT/US2014/011078.
International Search Report and Written Opinion, dated Nov. 24, 2014, for International Application No. PCT/US2014/056097.
International Search Report and Written Opinion, dated Nov. 24, 2014 for PCT/US2014/056097.
International Search Report and Written Opinion, dated Sep. 2, 2014, for PCT/US2014/035114.
International Search Report dated Jul. 25, 2013 for International Application No. PCT/US2013/035933, filed Apr. 10, 2013.
Jones, Christopher W., “CO2 Capture from Dilute Gases as a Component of Modern Global Carbon Management”, Annual Review of Chemical and Biomolecular Engineering, vol. 2, pp. 31-52, 2011.
Ma, Chanjuan et al., “Removal of low-concentration formaldehyde in air by adsorption on activated carbon modified by hexamethylene diamine”, Carbon, vol. 49, pp. 2869-2877, 2011.
Machine-generated English translation of JP 06-031132 A, published Feb. 1994.
Nuckols, M. L. et al., “Technical Manual: Design Guidelines for Carbon Dioxide Scrubbers”, Naval Coastal Systems Center, vol. 4110, pp. 1-83, Revision A, Jul. 1985.
Serna-Guerrero, Rodrigo et al., “Triamine-grafted pore-expanded mesoporous silica for CO2 capture: Effect of moisture and adsorbent regeneration strategies”, Adsorption, vol. 16, pp. 567-575, 2010.
Sidheswaran, Meera A. et al., “Energy efficient indoor VOC air cleaning with activated carbon filter (ACF) filters”, Building and Environment, vol. 47, Apr. 2011, pp. 357-367.
United States Environmental Protection Agency, “Carbon Adsorption for Control of VOC Emissions: Theory and Full Scale System Performance”, vol. 450, pp. 88-012, Jun. 1988.
Zorflex® ACC, 100% Activated Woven Carbon Cloth, Calgon Carbon Corporation, 2008, www.calgoncarbon.com, 2 pages.
Zorflex® ACC, 100% Activated Woven Carbon Cloth, Calgon Carbon Corporation, 2011, www.calgoncarbon.com, 2 pages.
Ashrae. ANSI/ASHRAE Standard 62.1-2013 Ventilation for Acceptable Indoor Air Quality. American Society of Heating, Refrigerating and Air-Conditioning Engineers, Inc., Atlanta, GA; 2013, 58 pages.
Bennett, D. et al. (Oct. 2011) Indoor Environmental Quality and Heating, Ventilating, and Air Conditioning Survey of Small and Medium Size Commercial Buildings: Field Study. California Energy Commission. CEC-500-2011-043, 233 pages.
Chinese Application No. 201480056951.9: First Office Action with Search Report, dated Feb. 6, 2017, with English translation, 31 total pages.
Hodgson, A.T. and Levin, H. (Apr. 21, 2003) Volatile Organic Compounds in Indoor Air: A Review of Concentrations Measured in North America Since 1990. Report LBNL-51715. Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 31 pages.
Hotchi, T. et al. (Jan. 2006) “Indoor Air Quality Impacts of a Peak Load Shedding Strategy for a Large Retail Building” Report LBNL-59293. Berkeley, California: Environmental Energy Technologies Division, E.O. Lawrence Berkeley National Laboratory; 17 pages.
Kang, D-H. et al. (Jun. 14, 2007) “Measurements of VOCs emission rate from building materials during bakeout with passive sampling methods” Clima 2007 WellBeing Indoors, REHVA World Congress, Jun. 10-14, 2007, Helsinki, Finland. O. Seppänen and J. Säteri (Eds.) FINVAC [online]. Retrieved from: http://www.inive.org/members_area/medias/pdf/Inive%5Cclima2007%5CA12%5CA12C1334.pdf, 6 pages.
Non-Final Office Action dated Aug. 11, 2017, for U.S. Appl. No. 15/022,800, 8 pages.
Offerman, F.J. et al. (1991) “A Pilot Study to Measure Indoor Concentrations and Emmission Rates of Polycyclic Aromatic Hydrocarbons” Indoor Air, 4:497-512.
United States Environmental Protection Agency, “EPA Ventilation and Air Quality in Offices, Fact Sheet” Air and Radiation (6609J), 402-F-94-003, Revised Jul. 1990, 4 pages.
Wu, X. et al. (2011) “Volatile Organic Compounds in Small- and Medium-Sized Commercial Buildings in California. Suporting Information” Environ Sci Technol, 45(20):S1-S29 [online]. Retrieved from: https://pubs.acs.org/doi/suppl/10.1021/es202132u/suppl_file/es202132u_si_001.pdf.
Related Publications (1)
Number Date Country
20180264396 A1 Sep 2018 US
Provisional Applications (1)
Number Date Country
61879099 Sep 2013 US
Continuations (1)
Number Date Country
Parent 15022800 US
Child 15892044 US