Systems and methods for improving quenched coke recovery

Information

  • Patent Grant
  • 10323192
  • Patent Number
    10,323,192
  • Date Filed
    Monday, December 4, 2017
    7 years ago
  • Date Issued
    Tuesday, June 18, 2019
    5 years ago
Abstract
The present technology is generally directed to systems and methods for improving quenched coke recovery. More specifically, some embodiments are directed to systems and methods utilizing one or more of a screen, barrier, or reflector panel to contain or redirect coke during or after quenching. In a particular embodiment, a quench car system for containing coke includes a quench car having a base, a plurality of sidewalls, and a top portion. The system can further include a permeable barrier covering at least a portion of the top of the quench car, wherein the permeable barrier has a plurality of apertures therethrough.
Description
TECHNICAL FIELD

The present technology is generally directed to systems and methods for improving quenched coke recovery. More specifically, some embodiments are directed to systems and methods utilizing one or more of a screen, barrier, or reflector panel to contain or redirect coke during or after quenching.


BACKGROUND

Quenching is an important step in many types of mineral processing, including coke processing. During quenching, a quench tower releases a large amount of water onto heated coke in a quench car in order to quickly cool the coke. The pre-quench coke is extremely hot, sometimes having a temperature greater than 2,000 degrees Fahrenheit. Once the coke is cooled, it can be handled on transfer belts and be screened and sent to the customer.


Traditionally, a large amount of coke is lost in the quenching process. More specifically, the combination of the force of the quench spray and the expansion of the quench water as it forms steam causes some of the coke to pop or fly out of the top and upper side edges of the quench car. This coke then falls by the wayside or is passed into a collecting water pit. To recover this coke, the water pit must be dredged, a costly and time-consuming process. The coke recovered from the pit is high in moisture and requires drying and sieving to reclaim, as the coke must have a relatively low moisture content to be useful to many customers. Therefore, there exists a need to improve coke recovery during the quench process.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is an isometric, partial cut-away view of a quench car that is entering a quench tower and is configured in accordance with embodiments of the technology.



FIG. 2A is an isometric view of a quench car that has side containment plates for channeling quenched coke onto a quench wharf and is configured in accordance with embodiments of the technology.



FIG. 2B is an isometric, partial cut-away view of a quench car having a tailgate containment plate configured in accordance with embodiments of the technology.



FIG. 3 is a partially schematic illustration of a quench car positioned in a quench tower that has coke retaining features and is configured in accordance with embodiments of the technology.



FIG. 4 is a partially schematic illustration of a quench car positioned in a quench tower that has coke retaining features and is configured in accordance with further embodiments of the technology.



FIG. 5 is a front view of a quench car having coke retaining features configured in accordance with embodiments of the technology.





DETAILED DESCRIPTION

The present technology is generally directed to systems and methods for improving quenched coke recovery. More specifically, some embodiments are directed to systems and methods utilizing one or more of a screen, barrier, or reflector panel to contain or redirect coke during or after quenching. In a particular embodiment, a quench car system for containing coke includes a quench car having a base, a plurality of sidewalls, and a top portion. The system can further include a permeable barrier covering at least a portion of the top of the quench car, where the permeable barrier has a plurality of apertures therethrough.


In another embodiment, a coke quenching system includes a quench car having a plurality of sidewalls for containing coke and a quench tower configured to supply fluid for quenching the coke. The quench tower includes a deflection barrier positioned over the quench car and configured to contain coke in the car.


In another embodiment, a coke quench car includes a base and a plurality of sidewalls extending generally orthogonally upward from the base and surrounding a central region configured to contain coke. Individual sidewalls can comprise a lower portion adjacent to the base and an upper portion opposite the lower portion. The upper portion of at least one sidewall can be angled laterally inward toward the central region.


Specific details of several embodiments of the technology are described below with reference to FIGS. 1-5. Other details describing well-known structures and systems often associated with coal processing and/or quenching have not been set forth in the following disclosure to avoid unnecessarily obscuring the description of the various embodiments of the technology. Many of the details, dimensions, angles, and other features shown in the Figures are merely illustrative of particular embodiments of the technology. Accordingly, other embodiments can have other details, dimensions, angles, and features without departing from the spirit or scope of the present technology. A person of ordinary skill in the art, therefore, will accordingly understand that the technology may have other embodiments with additional elements, or the technology may have other embodiments without several of the features shown and described below with reference to FIGS. 1-5.



FIG. 1 is an isometric, partial cut-away view of a quench car 100 that is entering a quench tower 104 and is configured in accordance with embodiments of the technology. The quench car 100 includes a plurality of sidewalls 102 arranged to enclose or at least partially surround a space configured to contain coke in a coke processing system. In further embodiments, the quench car 100 can be used in other mineral processing systems. While the car 100 is described herein as a “quench” car, it can comprise a “hot” car configured to receive coke from a coke oven, a quench train, a coke-moving car, a combined hot/quench car, or other container.


The quench car 100 includes a permeable deflection barrier 106 having a top portion 108 and one or more sidewall portions 110. In some embodiments, the barrier 106 comprises only one of a top portion 108 or sidewall portion 110, or extends across only a portion of the top of the quench car 100. In various embodiments, the top portion 108 is integral with the sidewall portions 110 or can be detachably coupled to the sidewall portions 110 or to the sidewalls 102. While the barrier sidewall portion 110 is illustrated as occupying only an upper portion of the sidewalls 102, in further embodiments more or less of the sidewalls 102 can comprise the permeable barrier. For example, including apertures or a permeable barrier on a lower portion of the sidewalls 102 can allow quench water to exit the car 100 after the quench and prevent the coke from sitting in quench fluid.


The permeable barrier 106 can be removably or permanently coupled to the quench car 100, or it can be spaced apart from (e.g., positioned above) the quench car 100. For example, as will be discussed in further detail below, the barrier 106 can be held above the car 100 by the quench tower 104 or other structure. In embodiments where the permeable barrier 106 is removably coupled to the quench car 100, the permeable barrier can be latched, friction fit, draped over, or held by cords, chains, hinges, or hooks to the car 100. For example, the barrier 106 can be coupled to the car 100 (e.g., to a sidewall 102) with a hinge or similar device and can open like an automobile hood. In some embodiments, the barrier 106 can have a lock or latch to fix the barrier 106 in a closed or open configuration. In some embodiments, the permeable barrier 106 can lift or otherwise be moved during car loading or unloading. In further embodiments, other attachment mechanisms can be used. The barrier 106 can be angled or generally horizontal. In some embodiments, the car 100 can include quench spray nozzles under the barrier 106 that can provide all or a portion of the quench fluid.


The permeable barrier 106 can comprise one or more of a screen, curtain, mesh, or other structure configured to contain coke during the quench process while allowing quench fluid to pass therethrough and reach the contained coke. In particular embodiments, the permeable barrier 106 comprises a screen having apertures therein. In some embodiments, the apertures have a diameter of approximately 0.25 inch to about 0.75 inch. In another particular embodiment, the apertures have dimensions of about 1.6 inch by about 0.56 inch. In still further embodiments, different portions of the barrier 106 can have different size apertures. For example, in some embodiments, one sidewall portion 110 can have larger apertures than an opposing sidewall portion 110. In another embodiment, an aperture pattern on the barrier 106 can match or complement a nozzle pattern in the quench tower 104. For example, the barrier 106 can have larger apertures on regions of the top portion 108 that are positioned under nozzles in the quench tower 104. These larger apertures can better receive quench water. In still further embodiments, apertures are exclusively placed under quench tower nozzles. In other embodiments, other aperture patterns are used to optimize quench water distribution in the quench car 100. Further, the apertures can have different shapes in different embodiments of the technology.


In some embodiments, the barrier 106 comprises stainless steel, high-carbon steel, AR400-AR500 steel, or other suitable material that can withstand the temperature and humidity conditions of the quench process. In a particular embodiment, a chain-link-fence type of material can be used as a barrier 106. In another embodiment, steel chains can be used. The barrier 106 can be flexible or rigid.


In some embodiments, the quench car 100 includes a deflection or containment plate 112 coupled to the sidewall 102. In various embodiments, as will be described in further detail below, one or more containment plates 112 can be coupled to other sidewalls, quench car gates, the barrier 106, or the base of the quench car 100. In particular embodiments, the containment plate 112 can be positioned at a junction or corner between two sidewalls or between a sidewall and a top or base portion of the car 100. The containment plate 112 can overlap at least a portion of a sidewall 102 or car base.


The containment plate 112 can have different shapes in various embodiments of the technology. For example, the containment plate 112 can be shaped as a rectangle, circle, triangle, or other shape. The containment plate 112 can be curved or otherwise shaped to complement the shape of the quench car 100 or can be shaped to achieve a funneling or confining effect on the coke during processing. For example, as will be described in further detail below with reference to FIG. 2, the containment plate 112 shown in FIG. 1 is shaped as a fin extending along an edge of the sidewall 102. In some embodiments, the containment plate 112 can fit against the car 100 tightly enough to contain coke while allowing used quench water to pass out of the car 100 to prevent the contained coke from sitting in water. The containment plate 112 can be on an internal or external surface of the quench car 100, or it can extend from an internal to an external portion. The containment plate 112 can be a solid surface or can have apertures therein.


In operation, the barrier 106 can serve to contain coke and/or reflect “popping” coke back into the quench car 100 during quenching. More specifically, the barrier 106 can be sufficiently permeable to allow quench fluid to pass through and reach the coke while having small enough apertures to prohibit coke from jumping or popping from the car 100. The barrier 106 further allows quench steam to escape the car. The barrier sidewall portions 110 can further allow a cross-breeze to flow over the cooling coke.



FIG. 2A is an isometric view of a quench car 200 having side containment plates 212 configured to channel quenched coke onto a quench wharf 220 after the coke has been quenched in a quench tower 204. As described above with reference to FIG. 1, the quench car 200 can have containment plates 212 coupled to a sidewall 202 of the car 200. In the illustrated embodiment, the sidewall 202 functions as a dump gate; when the car 200 is tilted toward the wharf and the sidewall gate 202 is open, the quenched coke is funneled by the containment plates 212 onto the wharf 220 to reduce side spillage. In further embodiments, the containment plates 212 can serve to contain the coke during quenching or can prevent the coke from spilling out of the car 200 at junction points (i.e., the junction between two adjacent sidewalls or a sidewall and the base of the car 200).



FIG. 2B is an isometric partial cut-away view of a quench car 250 having a tailgate containment plate 262 configured in accordance with embodiments of the technology. The tailgate containment plate 262 functions generally in the manner of the containment plates 212 described above with reference to FIG. 2A. More specifically, the tailgate containment plate 262 can bridge space between a base 264 of the car 250 and a sidewall gate 252. In several embodiments, the tailgate containment plate 262 is inclined relative to the base 264 of the car 250 and the sidewall gate 252. When the gate 252 is open, the tailgate containment plate 262 can prevent coke from falling between an opening between the base 264 and the gate 252. The tailgate containment plate 262 can further inhibit coke from building up at this junction and preventing the gate 252 from opening and closing. In several embodiments, the tailgate containment plate 262 is movable relative to the sidewall gate 252 and/or the base 264 such that the tailgate containment plate 262 assumes different positions depending on whether the sidewall gate 252 is open or closed.



FIG. 2B also illustrates that the gate 252 can have a solid lower portion and a permeable upper portion. In further embodiments, the gate 252 can be fully solid or fully permeable, or the lower portion can be permeable and the upper portion can be solid. In still further embodiments, the gate 252 can comprise multiple, separate portions (e.g., an upper portion and a lower portion) that can move independently of each other. In still further embodiments, the upper portion can be fixed (e.g., fixed to the car sidewalls) and the lower portion can be movable (i.e., open and close on a hinge) relative to the fixed upper portion. The upper and lower portions can be any combination of permeable and impermeable surfaces. In embodiments where at least a portion of the gate 252 is solid, the solid portion can help contain or channel quench steam. In some embodiments, the gate 252 joins or can be sealed against a top portion (e.g., the top portion 108 shown in FIG. 1) when the gate 252 is in a closed configuration.



FIG. 3 is a partially schematic illustration of a quench car 300 positioned in a quench tower 304 that has coke retaining features and is configured in accordance with embodiments of the technology. The quench tower 304 can be a byproduct quench tower, heat recovery quench tower, or any other similar system. The quench tower 304 includes a barrier 306 coupled thereto. The barrier 306 can be attached to any portion of the quench tower 304 framework and in various embodiments can be positioned above or below an array 370 of quench nozzles. In embodiments where the barrier 306 is below the nozzle array 370, the barrier 306 can be permeable to allow quench fluid to flow through. In embodiments where the barrier 306 is coplanar or above the nozzle array 370, the barrier 306 can be permeable or impermeable. In any of these embodiments, the barrier 306 can serve to reflect or contain coke in the quench car 300 in the manner described above with reference to FIG. 1. In still further embodiments, as discussed above with reference to FIG. 1, the nozzle array 370 and barrier 306 can be positioned on the quench car 300 (either in addition to or lieu of placement on the tower 304).


In several embodiments, the barrier 306 can further comprise one or more sidewall portions 372 that extend downward from the generally horizontal plane. In further embodiments, the barrier 306 exclusively has sidewall portions 372 and not an upper portion. The sidewall portions 372 can be rigid or flexible curtains and can channel coke that flies during the quench process back into the quench car 300. In various embodiments, the sidewall portions 372 can comprise numerous generally adjacent panels/chains or a single continuous panel. In still further embodiments, the sidewall portions 372 can be positioned on a track, rod, or other similar system to extend along or around the quench car 300 and then move away from the car 300 when not in use. In various embodiments, the barrier 306 or sidewall portions 372 are permanent in their placement relative to the quench tower 304 or can be retracted upward into the quench tower 304 and drop downward over the car 300. In other embodiments, the barrier 306 can be dropped over the car 300 and/or retracted upward outside of the quench tower 304 by a crane or other lifting/dropping device. In further embodiments, the barrier 306 can detach from the quench tower 304. In some embodiments, a bottom portion of the sidewall portions 372 can be positioned in the interior portion of the car 300, such that any coke that hits the sidewall portions 372 will slide back into the car 300. In further embodiments, a bottom portion of the sidewall portions 372 is exterior of the car 300.



FIG. 4 is a partially schematic illustration of a quench car 400 positioned in a quench tower 404 having coke reclaim plates 472 configured in accordance with further embodiments of the technology. In the illustrated embodiment, the reclaim plates 472 extend downward and slope laterally inward toward the quench car 400. In other embodiments, the reclaim plates 472 can have different angles either more or less directed inward toward the car 400. The reclaim plates 472 can channel coke that flies during the quench process back into the quench car 400 to increase coke recovery and reduce build-up at the base of the quench tower 404. In further embodiments, the reclaim plates 472 are coupled to the car 400 instead of or in addition to being coupled to the quench tower 404. Further, in some embodiments, the reclaim plates 472 can be movable to adjust their angle with reference to the quench tower 404. This adjustability can be useful to vary the coke diversion characteristics of the reclaim plates 472 or to accommodate different sizes of quench cars 400 or movement of the car 400 with reference to the quench tower 404 (e.g., the reclaim plates 472 can fold away while the car 400 is driving into or out of the quench tower 404). While the illustrated embodiment shows the reclaim plates 472 below a nozzle array 470, in further embodiments the reclaim plates 472 are above or coplanar with the nozzle array 470.



FIG. 5 is a front view of a quench car 500 having containment plates 572 configured in accordance with embodiments of the technology. The containment plates 572 can extend upward from sidewalls 502 of the car 500 and reflect coke back into the car 500 during the quench process. The containment plates 572 can comprise any permeable or impermeable material, or a combination of these materials. For example, in a particular embodiment, a portion of the containment plates 572 closest to the sidewalls 502 is solid and impermeable while a portion of the containment plates 572 that extends farthest into the center of the car 500 is permeable. All or only some of the sidewalls 502 may include containment plates 572. For example, in some embodiments, only two opposing sidewalls 502 have containment plates thereon. In particular embodiments, the containment plates 572 are on one or more drain or dump gates on the car 500.


While the sidewalls 502 can be generally orthogonal to the base of the car 500, the containment plates 572 can be angled inward at angle θ such that flying coke hits the bottom of the containment plates 572 and deflects downward. The angle θ can vary in alternate embodiments of the technology or can be adjustable (e.g., the containment plates 572 can be on hinges). In particular embodiments, the angle θ can be from about 10 degrees to about 90 degrees relative to a vertical plane. The containment plates 572 can reduce coke breeze from moving downstream or clogging process flow. In some embodiments, the car 500 can further include a top portion, such as the top portion 108 described above with reference to FIG. 1, that extends between sidewalls 502 (e.g., between the containment plates 572. The containment plates 572 can be used alone or in conjunction with any of the top portions (solid or permeable) described above.


Examples

1. A quench car system for containing coke prepared for quenching at a quenching site, the quench car system comprising:

    • a quench car having a base and a plurality of sidewalls defining an opening, the quench car having a top; and
    • a permeable barrier covering at least a portion of the top of the quench car, the permeable barrier having a plurality of apertures therethrough.


2. The quench car system of example 1 wherein the permeable barrier is removably coupled to the quench car.


3. The quench car system of example 1 wherein the permeable barrier extends across the top of the quench car and at least one sidewall.


4. The quench car system of example 1 wherein the individual apertures have a diameter from about ¼ inch to about ¾ inch.


5. The quench car system of example 1 wherein the quench car further comprises a containment plate coupled to one or more sidewalls and configured to contain or funnel coke or quench water.


6. The quench car system of example 5 wherein an individual sidewall comprises a movable gate, and wherein the containment plate extends along the gate and is movable between a first position when the gate is open and a second position when the gate is closed.


7. The quench car system of example 5 wherein two sidewalls meet at a corner, and wherein the containment plate is positioned adjacent to the corner and overlaps at least one of the sidewalls.


8. The quench car system of example 1 wherein the permeable barrier is permanently coupled to the quench car.


9. The quench car system of example 1 wherein the permeable barrier comprises stainless steel.


10. The quench car system of example 1 wherein the permeable barrier is spaced apart from the top of the quench car.


11. The quench car system of example 1, further comprising a quench tower having a nozzle positioned above the quench car, wherein an individual aperture generally vertically aligned with the nozzle has a diameter larger than a diameter of another individual aperture.


12. A coke quenching system, comprising:

    • a quench car having a plurality of sidewalls for containing coke; and
    • a quench tower configured to supply fluid for quenching coke, wherein the quench tower includes a deflection barrier positioned over the quench car and configured to contain coke in the car.


13. The coke quenching system of example 12 wherein the quench tower includes a nozzle, and wherein the deflection barrier comprises an angled deflection plate coupled to or positioned below the nozzle.


14. The coke quenching system of example 12 wherein the quench tower includes a plurality of nozzles directed toward the quench car, and wherein the deflection barrier is positioned above the nozzles.


15. The coke quenching system of example 12 wherein the deflection barrier comprises a permeable barrier.


16. The coke quenching system of example 12 wherein the deflection barrier comprises a plurality of vertical draping barriers.


17. The coke quenching system of example 12 wherein the deflection barrier comprises a movable barrier.


18. The coke quenching system of example 12, wherein deflection barrier comprises a plurality of confining plates.


19. The coke quenching system of example 18 wherein the confining plates extend laterally inward toward an interior portion of the quench tower and are angled relative to a horizontal plane.


20. The coke quenching system of example 12 wherein the quench tower includes a plurality of nozzles directed toward the quench car, and wherein the deflection barrier comprises a permeable barrier positioned at or below the nozzles.


21. The coke quenching system of example 12 wherein the deflection barrier comprises a chain mesh.


22. A coke quench car, comprising:

    • a base; and
    • a plurality of sidewalls extending generally orthogonally upward from the base and surrounding a central region configured to contain coke, wherein the individual sidewalls comprise a lower portion adjacent to the base and an upper portion opposite the lower portion, and wherein the upper portion of at least one sidewall is angled laterally inward toward the central region.


23. The coke quench car of example 22 wherein the upper portion comprises a solid barrier.


24. The coke quench car of example 22 wherein the upper portion is angled inward at an angle from about 10 degrees to about 90 degrees relative to a vertical plane.


25. The coke quench car of example 22 wherein the upper portions of two opposing sidewalls are angled laterally inward toward the central region.


26. The coke quench car of example 22 wherein the upper portions are movable between a first angle and a second angle.


27. The coke quench car of example 22 wherein two sidewalls meet at a corner, and wherein the quench car further comprises a laterally extending fin that is coupled to the car adjacent to the corner and is configured to contain or funnel coke or quench water.


28. The coke quench car of example 22 wherein the upper portion comprises an at least partially permeable barrier.


29. The coke quench car of example 22, further comprising a top portion configured to extend across at least a portion of the central region, wherein the top portion comprises an at least partially permeable barrier.


From the foregoing it will be appreciated that, although specific embodiments of the technology have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the technology. Further, certain aspects of the new technology described in the context of particular embodiments may be combined or eliminated in other embodiments. Moreover, while advantages associated with certain embodiments of the technology have been described in the context of those embodiments, other embodiments may also exhibit such advantages, and not all embodiments need necessarily exhibit such advantages to fall within the scope of the technology. Accordingly, the disclosure and associated technology can encompass other embodiments not expressly shown or described herein. Thus, the disclosure is not limited except as by the appended claims.

Claims
  • 1. A coke quenching system, comprising: a quench car having an open upper end portion and a plurality of sidewalls for containing coke; anda quench tower configured to supply fluid for quenching coke, wherein the quench tower includes a deflection barrier having a free distal end portion that is positioned over the quench car, adjacent but in a spaced-apart relationship with the open upper end portion of the quench car, and having an opposing portion, opposite the free distal end portion, that is coupled directly to a wall of the quench tower, wherein the deflection barrier comprises a permeable barrier and is configured to deflect particulate coke that exits the quench car back into the quench car.
  • 2. The coke quenching system of claim 1 wherein the quench tower includes a nozzle, and wherein the deflection barrier comprises an angled deflection plate coupled to or positioned below the nozzle.
  • 3. The coke quenching system of claim 1 wherein the quench tower includes a plurality of nozzles directed toward the quench car, and wherein the deflection barrier is positioned above the nozzles.
  • 4. The coke quenching system of claim 1 wherein the deflection barrier comprises a plurality of vertical draping barriers.
  • 5. The coke quenching system of claim 1 wherein the deflection barrier comprises a movable barrier.
  • 6. The coke quenching system of claim 1, wherein deflection barrier comprises a plurality of confining plates.
  • 7. The coke quenching system of claim 6 wherein the confining plates extend laterally inward toward an interior portion of the quench tower and are angled relative to a horizontal plane.
  • 8. The coke quenching system of claim 1 wherein the quench tower includes a plurality of nozzles directed toward the quench car, and wherein the deflection barrier comprises a permeable barrier positioned at or below the nozzles.
  • 9. The coke quenching system of claim 1 wherein the deflection barrier comprises a chain mesh.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 14/952,267, filed Nov. 25, 2015, which is a continuation of U.S. patent application Ser. No. 13/730,598, filed Dec. 28, 2012, the disclosure of which is incorporated by reference in their entirety.

US Referenced Citations (312)
Number Name Date Kind
425797 Hunt Apr 1890 A
469868 Osbourn Mar 1892 A
845719 Schniewind Feb 1907 A
976580 Krause Jul 1909 A
1140798 Carpenter May 1915 A
1424777 Schondeling Aug 1922 A
1430027 Plantinga Sep 1922 A
1486401 Van Ackeren Mar 1924 A
1572391 Klaiber Feb 1926 A
1677973 Marquard Jul 1928 A
1721813 Geipert Jul 1929 A
1818370 Wine Aug 1931 A
1818994 Kreisinger Aug 1931 A
1848818 Becker Mar 1932 A
1955962 Jones Apr 1934 A
2075337 Burnaugh Mar 1937 A
2394173 Harris et al. Feb 1946 A
2424012 Bangham et al. Jul 1947 A
2649978 Such Aug 1953 A
2667185 Beavers Jan 1954 A
2723725 Keiffer Nov 1955 A
2756842 Chamberlin et al. Jul 1956 A
2827424 Homan Mar 1958 A
2873816 Emil et al. Feb 1959 A
2902991 Whitman Sep 1959 A
2907698 Schulz Oct 1959 A
3015893 McCreary Jan 1962 A
3033764 Hannes May 1962 A
3462345 Kernan Aug 1969 A
3511030 Brown et al. May 1970 A
3542650 Kulakov Nov 1970 A
3545470 Paton Dec 1970 A
3592742 Thompson Jul 1971 A
3616408 Hickam Oct 1971 A
3623511 Levin Nov 1971 A
3630852 Nashan et al. Dec 1971 A
3652403 Knappstein et al. Mar 1972 A
3676305 Cremer Jul 1972 A
3709794 Kinzler et al. Jan 1973 A
3710551 Sved Jan 1973 A
3746626 Morrison, Jr. Jul 1973 A
3748235 Pries Jul 1973 A
3784034 Thompson Jan 1974 A
3806032 Pries Apr 1974 A
3811572 Tatterson May 1974 A
3836161 Pries Oct 1974 A
3839156 Jakobi et al. Oct 1974 A
3844900 Schulte Oct 1974 A
3857758 Mole Dec 1974 A
3875016 Schmidt-Balve Apr 1975 A
3876143 Rossow et al. Apr 1975 A
3876506 Dix et al. Apr 1975 A
3878053 Hyde Apr 1975 A
3894302 Lasater Jul 1975 A
3897312 Armour et al. Jul 1975 A
3906992 Leach Sep 1975 A
3912091 Thompson Oct 1975 A
3917458 Polak Nov 1975 A
3928144 Jakimowicz Dec 1975 A
3930961 Sustarsic et al. Jan 1976 A
3957591 Riecker May 1976 A
3959084 Price May 1976 A
3963582 Helm et al. Jun 1976 A
3969191 Bollenbach Jul 1976 A
3975148 Fukuda et al. Aug 1976 A
3984289 Sustarsic et al. Oct 1976 A
4004702 Szendroi Jan 1977 A
4004983 Pries Jan 1977 A
4025395 Ekholm et al. May 1977 A
4040910 Knappstein et al. Aug 1977 A
4045299 McDonald Aug 1977 A
4059885 Oldengott Nov 1977 A
4067462 Thompson Jan 1978 A
4083753 Rogers et al. Apr 1978 A
4086231 Ikio Apr 1978 A
4093245 Connor Jun 1978 A
4100033 Holter Jul 1978 A
4111757 Carimboli Sep 1978 A
4124450 MacDonald Nov 1978 A
4135948 Mertens et al. Jan 1979 A
4141796 Clark et al. Feb 1979 A
4145195 Knappstein et al. Mar 1979 A
4147230 Ormond et al. Apr 1979 A
4162546 Shortell et al. Jul 1979 A
4181459 Price Jan 1980 A
4189272 Gregor et al. Feb 1980 A
4194951 Pries Mar 1980 A
4196053 Grohmann Apr 1980 A
4211608 Kwasnoski et al. Jul 1980 A
4213489 Cain Jul 1980 A
4213828 Calderon Jul 1980 A
4222748 Argo et al. Sep 1980 A
4222824 Flockenhaus et al. Sep 1980 A
4224109 Flockenhaus et al. Sep 1980 A
4225393 Gregor et al. Sep 1980 A
4235830 Bennett et al. Nov 1980 A
4239602 La Bate Dec 1980 A
4248671 Belding Feb 1981 A
4249997 Schmitz Feb 1981 A
4263099 Porter Apr 1981 A
4284478 Brommel Aug 1981 A
4285772 Kress Aug 1981 A
4287024 Thompson Sep 1981 A
4289584 Chuss et al. Sep 1981 A
4289585 Wagener et al. Sep 1981 A
4296938 Offermann et al. Oct 1981 A
4302935 Cousimano Dec 1981 A
4303615 Jarmell et al. Dec 1981 A
4307673 Caughey Dec 1981 A
4314787 Kwasnik et al. Feb 1982 A
4330372 Cairns et al. May 1982 A
4334963 Stog Jun 1982 A
4336843 Petty Jun 1982 A
4340445 Kucher et al. Jul 1982 A
4342195 Lo Aug 1982 A
4344820 Thompson Aug 1982 A
4344822 Schwartz et al. Aug 1982 A
4366029 Bixby et al. Dec 1982 A
4373244 Mertens et al. Feb 1983 A
4375388 Hara et al. Mar 1983 A
4391674 Velmin et al. Jul 1983 A
4392824 Struck et al. Jul 1983 A
4394217 Holz et al. Jul 1983 A
4395269 Schuler Jul 1983 A
4396394 Li et al. Aug 1983 A
4396461 Neubaum et al. Aug 1983 A
4431484 Weber et al. Feb 1984 A
4439277 Dix Mar 1984 A
4440098 Adams Apr 1984 A
4445977 Husher May 1984 A
4446018 Cerwick May 1984 A
4448541 Lucas May 1984 A
4452749 Kolvek et al. Jun 1984 A
4459103 Gieskieng Jul 1984 A
4469446 Goodboy Sep 1984 A
4474344 Bennett Oct 1984 A
4487137 Horvat et al. Dec 1984 A
4498786 Ruscheweyh Feb 1985 A
4506025 Kleeb et al. Mar 1985 A
4508539 Nakai Apr 1985 A
4527488 Lindgren Jul 1985 A
4568426 Orlando Feb 1986 A
4570670 Johnson Feb 1986 A
4614567 Stahlherm et al. Sep 1986 A
4643327 Campbell Feb 1987 A
4645513 Kubota et al. Feb 1987 A
4655193 Blacket Apr 1987 A
4655804 Kercheval et al. Apr 1987 A
4666675 Parker et al. May 1987 A
4680167 Orlando Jul 1987 A
4704195 Janicka et al. Nov 1987 A
4720262 Durr et al. Jan 1988 A
4726465 Kwasnik et al. Feb 1988 A
4793981 Doyle et al. Dec 1988 A
4824614 Jones et al. Apr 1989 A
4889698 Moller et al. Dec 1989 A
4919170 Kallinich et al. Apr 1990 A
4929179 Breidenbach et al. May 1990 A
4941824 Holter et al. Jul 1990 A
5052922 Stokman et al. Oct 1991 A
5062925 Durselen et al. Nov 1991 A
5078822 Hodges et al. Jan 1992 A
5087328 Wegerer et al. Feb 1992 A
5114542 Childress et al. May 1992 A
5213138 Presz May 1993 A
5227106 Kolvek Jul 1993 A
5228955 Westbrook, III Jul 1993 A
5318671 Pruitt Jun 1994 A
5423152 Kolvek Jun 1995 A
5480594 Wilkerson et al. Jan 1996 A
5542650 Abel et al. Aug 1996 A
5622280 Mays et al. Apr 1997 A
5659110 Herden et al. Aug 1997 A
5670025 Baird Sep 1997 A
5687768 Albrecht et al. Nov 1997 A
5752548 Matsumoto et al. May 1998 A
5787821 Bhat et al. Aug 1998 A
5810032 Hong et al. Sep 1998 A
5816210 Yamaguchi Oct 1998 A
5857308 Dismore et al. Jan 1999 A
5928476 Daniels Jul 1999 A
5968320 Sprague Oct 1999 A
6017214 Sturgulewski Jan 2000 A
6059932 Sturgulewski May 2000 A
6139692 Tamura et al. Oct 2000 A
6152668 Knoch Nov 2000 A
6187148 Sturgulewski Feb 2001 B1
6189819 Racine Feb 2001 B1
6290494 Barkdoll Sep 2001 B1
6412221 Emsbo Jul 2002 B1
6596128 Westbrook Jul 2003 B2
6626984 Taylor Sep 2003 B1
6699035 Brooker Mar 2004 B2
6758875 Reid et al. Jul 2004 B2
6907895 Johnson et al. Jun 2005 B2
6946011 Snyder Sep 2005 B2
6964236 Schucker Nov 2005 B2
7056390 Fratello Jun 2006 B2
7077892 Lee Jul 2006 B2
7314060 Chen et al. Jan 2008 B2
7331298 Barkdoll et al. Feb 2008 B2
7433743 Pistikopoulos et al. Oct 2008 B2
7497930 Barkdoll et al. Mar 2009 B2
7611609 Valia et al. Nov 2009 B1
7644711 Creel Jan 2010 B2
7722843 Srinivasachar May 2010 B1
7727307 Winkler Jun 2010 B2
7785447 Eatough et al. Aug 2010 B2
7803627 Hodges et al. Sep 2010 B2
7823401 Takeuchi et al. Nov 2010 B2
7827689 Crane Nov 2010 B2
7998316 Barkdoll Aug 2011 B2
8071060 Ukai et al. Dec 2011 B2
8079751 Kapila et al. Dec 2011 B2
8080088 Srinivasachar Dec 2011 B1
8152970 Barkdoll et al. Apr 2012 B2
8236142 Westbrook Aug 2012 B2
8266853 Bloom et al. Sep 2012 B2
8398935 Howell et al. Mar 2013 B2
8647476 Kim et al. Feb 2014 B2
8956996 Masatsugu et al. Feb 2015 B2
8980063 Kim et al. Mar 2015 B2
9039869 Kim et al. May 2015 B2
9057023 Reichelt et al. Jun 2015 B2
9193915 West et al. Nov 2015 B2
9238778 Quanci et al. Jan 2016 B2
9243186 Quanci et al. Jan 2016 B2
9249357 Quanci et al. Feb 2016 B2
9359554 Quanci et al. Jun 2016 B2
20020170605 Shiraishi et al. Nov 2002 A1
20030014954 Ronning et al. Jan 2003 A1
20030015809 Carson Jan 2003 A1
20030057083 Eatough et al. Mar 2003 A1
20050087767 Fitzgerald et al. Apr 2005 A1
20060102420 Huber et al. May 2006 A1
20060149407 Markham et al. Jul 2006 A1
20070116619 Taylor et al. May 2007 A1
20070251198 Witter Nov 2007 A1
20080028935 Andersson Feb 2008 A1
20080179165 Chen et al. Jul 2008 A1
20080257236 Green Oct 2008 A1
20080271985 Yamasaki Nov 2008 A1
20080289305 Girondi Nov 2008 A1
20090007785 Kimura et al. Jan 2009 A1
20090152092 Kim et al. Jun 2009 A1
20090162269 Barger et al. Jun 2009 A1
20090217576 Kim et al. Sep 2009 A1
20090283395 Hippe Nov 2009 A1
20100095521 Kartal et al. Apr 2010 A1
20100113266 Abe et al. May 2010 A1
20100115912 Worley May 2010 A1
20100196597 Di Loreto Aug 2010 A1
20100287871 Bloom et al. Nov 2010 A1
20100300867 Kim et al. Dec 2010 A1
20100314234 Knoch et al. Dec 2010 A1
20110048917 Kim et al. Mar 2011 A1
20110120852 Kim May 2011 A1
20110144406 Masatsugu et al. Jun 2011 A1
20110168482 Merchant et al. Jul 2011 A1
20110174301 Haydock et al. Jul 2011 A1
20110192395 Kim Aug 2011 A1
20110198206 Kim et al. Aug 2011 A1
20110223088 Chang et al. Sep 2011 A1
20110253521 Kim Oct 2011 A1
20110315538 Kim et al. Dec 2011 A1
20120024688 Barkdoll Feb 2012 A1
20120030998 Barkdoll et al. Feb 2012 A1
20120152720 Reichelt et al. Jun 2012 A1
20120180133 Ai-Harbi et al. Jul 2012 A1
20120228115 Westbrook Sep 2012 A1
20120247939 Kim et al. Oct 2012 A1
20120305380 Wang et al. Dec 2012 A1
20130045149 Miller Feb 2013 A1
20130216717 Rago et al. Aug 2013 A1
20130220373 Kim Aug 2013 A1
20130306462 Kim et al. Nov 2013 A1
20140033917 Rodgers et al. Feb 2014 A1
20140039833 Sharpe, Jr. et al. Feb 2014 A1
20140061018 Sarpen et al. Mar 2014 A1
20140083836 Quanci et al. Mar 2014 A1
20140182195 Quanci et al. Jul 2014 A1
20140182683 Quanci et al. Jul 2014 A1
20140183023 Quanci et al. Jul 2014 A1
20140183024 Chun et al. Jul 2014 A1
20140224123 Walters Aug 2014 A1
20140262139 Choi et al. Sep 2014 A1
20140262726 West et al. Sep 2014 A1
20150122629 Freimuth et al. May 2015 A1
20150219530 Li et al. Aug 2015 A1
20150247092 Quanci et al. Sep 2015 A1
20150328576 Quanci et al. Sep 2015 A1
20150287026 Quanci et al. Oct 2015 A1
20160032193 Sarpen et al. Feb 2016 A1
20160060532 Quanci et al. Mar 2016 A1
20160060533 Quanci et al. Mar 2016 A1
20160060534 Quanci et al. Mar 2016 A1
20160060536 Quanci et al. Mar 2016 A1
20160149944 Obermeier et al. May 2016 A1
20160152897 Quanci et al. Jun 2016 A1
20160160123 Quanci et al. Jun 2016 A1
20160186063 Quanci et al. Jun 2016 A1
20160186064 Quanci et al. Jun 2016 A1
20160186065 Quanci et al. Jun 2016 A1
20160222297 Choi et al. Aug 2016 A1
20160319197 Quanci et al. Nov 2016 A1
20160319198 Quanci et al. Nov 2016 A1
20170015908 Quanci et al. Jan 2017 A1
20170137714 West et al. May 2017 A1
20170183569 Quanci et al. Jun 2017 A1
20170253803 West et al. Sep 2017 A1
20170253804 Quanci et al. Sep 2017 A1
20170352243 Quanci et al. Dec 2017 A1
Foreign Referenced Citations (132)
Number Date Country
1172895 Aug 1984 CA
2775992 May 2011 CA
2822841 Jul 2012 CA
2822857 Jul 2012 CA
87212113 Jun 1988 CN
87107195 Jul 1988 CN
2064363 Oct 1990 CN
2139121 Jul 1993 CN
1092457 Sep 1994 CN
1255528 Jun 2000 CN
1270983 Oct 2000 CN
2528771 Feb 2002 CN
1358822 Jul 2002 CN
2521473 Nov 2002 CN
1468364 Jan 2004 CN
1527872 Sep 2004 CN
2668641 Jan 2005 CN
1957204 May 2007 CN
101037603 Sep 2007 CN
101058731 Oct 2007 CN
101157874 Apr 2008 CN
201121178 Sep 2008 CN
101395248 Mar 2009 CN
100510004 Jul 2009 CN
101486017 Jul 2009 CN
201264981 Jul 2009 CN
101497835 Aug 2009 CN
101509427 Aug 2009 CN
102155300 Aug 2011 CN
2509188 Nov 2011 CN
202226816 May 2012 CN
202265541 Jun 2012 CN
102584294 Jul 2012 CN
202415446 Sep 2012 CN
103468289 Dec 2013 CN
212176 Jul 1909 DE
1212037 Mar 1966 DE
3231697 Jan 1984 DE
3328702 Feb 1984 DE
3315738 Mar 1984 DE
3329367 Nov 1984 DE
3407487 Jun 1985 DE
19545736 Jun 1997 DE
19803455 Aug 1999 DE
10122531 Nov 2002 DE
10154785 May 2003 DE
102005015301 Oct 2006 DE
102006004669 Aug 2007 DE
102006026521 Dec 2007 DE
102009031436 Jan 2011 DE
102011052785 Dec 2012 DE
0126399 Nov 1984 EP
0208490 Jan 1987 EP
2295129 Mar 2011 EP
2339664 Aug 1977 FR
441784 Jan 1936 GB
606340 Aug 1948 GB
611524 Nov 1948 GB
725865 Mar 1955 GB
871094 Jun 1961 GB
923205 May 1963 GB
S-50148405 Nov 1975 JP
54054101 Apr 1979 JP
S-5453103 Apr 1979 JP
57051786 Mar 1982 JP
57051787 Mar 1982 JP
57083585 May 1982 JP
57090092 Jun 1982 JP
58091788 May 1983 JP
59051978 Mar 1984 JP
59053589 Mar 1984 JP
59071388 Apr 1984 JP
59108083 Jun 1984 JP
59145281 Aug 1984 JP
60004588 Jan 1985 JP
61106690 May 1986 JP
62011794 Jan 1987 JP
62285980 Dec 1987 JP
01103694 Apr 1989 JP
01249886 Oct 1989 JP
H-0319127 Mar 1991 JP
03197588 Aug 1991 JP
04159392 Jun 1992 JP
H-04178494 Jun 1992 JP
H-06264062 Sep 1994 JP
07188668 Jul 1995 JP
07216357 Aug 1995 JP
08104875 Apr 1996 JP
08127778 May 1996 JP
H-10273672 Oct 1998 JP
H-11-131074 May 1999 JP
2000204373 Jul 2000 JP
2001200258 Jul 2001 JP
2002106941 Apr 2002 JP
2003041258 Feb 2003 JP
2003071313 Mar 2003 JP
2003292968 Oct 2003 JP
2003342581 Dec 2003 JP
2005263983 Sep 2005 JP
2006188608 Jul 2006 JP
2007063420 Mar 2007 JP
2008231278 Oct 2008 JP
2009144121 Jul 2009 JP
2010248389 Nov 2010 JP
2012102302 May 2012 JP
2013006957 Jan 2013 JP
2014040502 Mar 2014 JP
1019960008754 Oct 1996 KR
1019990054426 Jul 1999 KR
20000042375 Jul 2000 KR
100296700 Oct 2001 KR
1020050053861 Jun 2005 KR
100737393 Jul 2007 KR
100797852 Jan 2008 KR
20110010452 Feb 2011 KR
101318388 Oct 2013 KR
1535880 Jan 1990 SU
201241166 Oct 2012 TW
WO-9012074 Oct 1990 WO
WO-9945083 Sep 1999 WO
WO-2005023649 Mar 2005 WO
WO-2005115583 Dec 2005 WO
WO-2007103649 Sep 2007 WO
WO-2008034424 Mar 2008 WO
WO-2011000447 Jan 2011 WO
WO-2012029979 Mar 2012 WO
WO-2013023872 Feb 2013 WO
WO-2010107513 Sep 2013 WO
WO-2014021909 Feb 2014 WO
WO2014105064 Jul 2014 WO
WO-2014153050 Sep 2014 WO
WO2016004106 Jan 2016 WO
Non-Patent Literature Citations (39)
Entry
Translation of DE 3407487 C1 obtained from ProQuest.
ASTM D5341-99(2010)e1, Standard Test Method for Measuring Coke Reactivity Index (CRI) and Coke Strength After Reaction (CSR), ASTM International, West Conshohocken, PA, 2010.
Basset et al., “Calculation of steady flow pressure loss coefficients for pipe junctions,” Proc Instn Mech Engrs., vol. 215, Part C. IMechIE 2001.
Beckman et al., “Possibilities and limits of cutting back coking plant output,” Stahl Und Eisen, Verlag Stahleisen, Dusseldorf, DE, vol. 130, No. 8, Aug. 16, 2010, pp. 57-67.
Bloom, et al., “Modular cast block—The future of coke oven repairs,” Iron & Steel Technol, AIST, Warrendale, PA, vol. 4, No. 3, Mar. 1, 2007, pp. 61-64.
Clean coke process: process development studies by USS Engineers and Consultants, Inc., Wisconsin Tech Search, request date Oct. 5, 2011, 17 pages.
“Conveyor Chain Designer Guild”, Mar. 27, 2014 (date obtained from wayback machine), Renold.com, Section 4, available online at: http://www.renold/com/upload/renoldswitzerland/conveyor_chain_-_designer_guide.pdf.
Costa, et al., “Edge Effects on the Flow Characteristics in a 90 deg Tee Junction,” Transactions of the ASME, Nov. 2006, vol. 128, pp. 1204-1217.
Crelling, et al., “Effects of Weathered Coal on Coking Properties and Coke Quality”, Fuel, 1979, vol. 58, Issue 7, pp. 542-546.
Database WPI, Week 199115, Thomson Scientific, Lond, GB; AN 1991-107552.
Diez, et al., “Coal for Metallurgical Coke Production: Predictions of Coke Quality and Future Requirements for Cokemaking”, International Journal of Coal Geology, 2002, vol. 50, Issue 1-4, pp. 389-412.
JP 03-197588, Inoue Keizo et al., Method and Equipment for Boring Degassing Hole in Coal Charge in Coke Oven, Japanese Patent (Abstract Only) Aug. 28, 1991.
JP 04-159392, Inoue Keizo et al., Method and Equipment for Opening Hole for Degassing of Coal Charge in Coke Oven, Japanese Patent (Abstract Only) Jun. 2, 1992.
Kochanski et al., “Overview of Uhde Heat Recovery Cokemaking Technology,” AISTech Iron and Steel Technology Conference Proceedings, Association for Iron and Steel Technology, U.S., vol. 1, Jan. 1, 2005, pp. 25-32.
Practical Technical Manual of Refractories, Baoyu Hu, etc., Beijing: Metallurgical Industry Press, Chapter 6; 2004, 6-30.
Refractories for Ironmaking and Steelmaking: A History of Battles over High Temperatures; Kyoshi Sugita (Japan, Shaolin Zhang), 1995, p. 160, 2004, 2-29.
Rose, Harold J., “The Selection of Coals for the Manufacture of Coke,” American Institute of Mining and Metallurgical Engineers, Feb. 1926, 8 pages.
“Middletown Coke Company HRSG Maintenance BACT Analysis Option 1—Individual Spray Quenches Sun Heat Recovery Coke Facility Process Flow Diagram Middletown Coke Company 100 Oven Case #1 -24.5 VM”, (Sep. 1, 2009), URL: http://web.archive.org/web/20090901042738/http://epa.ohio.gov/portals/27/transfer/ptiApplication/mcc/new/262504.pdf, (Feb. 12, 2016), XP055249803 [X] 1-13 * p. 7 * * pp. 8-11 *.
Waddell, et al., “Heat-Recovery Cokemaking Presentation,” Jan. 1999, pp. 1-25.
Walker D N et al, “Sun Coke Company's heat recovery cokemaking technology high coke quality and low environmental impact”, Revue De Metallurgie—Cahiers D'Informations Techniques, Revue De Metallurgie. Paris, FR, (Mar. 1, 2003), vol. 100, No. 3, ISSN 0035-1563, p. 23.
Westbrook, “Heat-Recovery Cokemaking at Sun Coke,” AISE Steel Technology, Pittsburg, PA, vol. 76, No. 1, Jan. 1999, pp. 25-28.
Yu et al., “Coke Oven Production Technology,” Lianoning Science and Technology Press, first edition, Apr. 2014, pp. 356-358.
“Resources and Utilization of Coking Coal in China,” Mingxin Shen ed., Chemical Industry Press, first edition, Jan. 2007, pp. 242-243, 247.
Canadian Office Action in Canadian Application No. 2,896,473, dated May 5, 2016, 5 pages.
Chinese Office Action in Chinese Application No. 201280077764.X, dated Jun. 27, 2016.
Extended European Search Report in European Application No. 12890832.4, dated Jun. 13, 2016, 7 pages.
International Search Report and Written Opinion of International Application No. PCT/US2012/072166; dated Sep. 25, 2013; 11 pages.
U.S. Appl. No. 15/987,060, filed May 23, 2018, Crum et al.
U.S. Appl. No. 16/000,516, filed Jun. 5, 2018, Quanci.
Boyes, Walt. (2003), Instrumentation Reference Book (3rd Edition)—34.7.4.6 Infrared and Thermal Cameras, Elsevier. Online version available at: https://app.knovel.com/hotlink/pdf/id:kt004QMGV6/instrumentation-reference-2/ditigal-video.
Kerlin, Thomas (1999), Practical Thermocouple Thermometry—1.1 The Thermocouple. ISA. Online version available at https:app.knovel.com/pdf/id:kt007XPTM3/practical-thermocouple/the-thermocouple.
Madias, et al., “A review on stamped charging of coals” (2013). Available at https://www.researchgate.net/publicatoin/263887759_A_review_on_stamped_charging_of coals.
Metallurgical Code MSDS, ArcelorMittal, May 30, 2011, available online at http://dofasco.arcelormittal.com/-/media/Files/A/Arcelormittal-Canada/material-safety/metallurgical-coke.pdf.
U.S. Appl. No. 16/206,363, filed Jul. 3, 2018, Chun et al.
U.S. Appl. No. 16/047,198, filed Jul. 27, 2018, Quanci et al.
Astrom, et al., “Feedback Systems: An Introduction for Scientists and Engineers,” Sep. 16, 2006, available on line at http://people/duke.edu/-hpgavin/SystemID/References/Astrom-Feedback-2006.pdf ; 404 pages.
Industrial Furnace Design Handbook, Editor-in-Chief: First Design Institute of First Ministry of Machinery Industry, Beijing: Mechanical Industry Press, pp. 180-183, Oct. 1981.
“What is dead-band control,” forum post by user “wireaddict” on AllAboutCircuits.com message board, Feb. 8, 2007, accessed Oct. 24, 2018 at https:/forum.allaboutcircuits.com/threads/what-is-dead-band-control.4728/; 8 pages.
Decision of Rejection in Chinese Application No. 201280077764.X; dated Jun. 28, 2018; 18 pages.
Related Publications (1)
Number Date Country
20180155627 A1 Jun 2018 US
Continuations (2)
Number Date Country
Parent 14952267 Nov 2015 US
Child 15830320 US
Parent 13730598 Dec 2012 US
Child 14952267 US