Systems and methods for sanitizing pool and spa water

Information

  • Patent Grant
  • 12157686
  • Patent Number
    12,157,686
  • Date Filed
    Friday, February 26, 2021
    3 years ago
  • Date Issued
    Tuesday, December 3, 2024
    a month ago
Abstract
Systems and methods for sanitizing pool and spa water are provided. An electrolytic chlorinator is provided which includes a combined flow, temperature, and salt concentration sensor. The electrolytic chlorinator could include an acid tank for in-situ cleaning of the electrolytic chlorinator or acidification of pool/spa water where needed. A delayed polarity reversal technique is provided for de-scaling and managing passivation of the blades of an electrolytic chlorinator. The electrolytic chlorinator could include a sacrificial anode for protecting components of the chlorinator as well as other pool/spa components. The electrolytic chlorinator could include an integral, electrically-controlled acid generator, a brine tank for periodically superchlorinating and/or shocking pool/spa water, and/or a plurality of chemical tanks/feeds for periodically injecting chemicals into the chlorinator. A combined ultraviolet (UV)/Ozone and salt (electrolytic) chlorine generator is provided, as well as: filters having integral UV sanitizers; reflective linings for UV sanitization systems; means for injecting bubbles into pool/spa water; and a system for acquiring and analyzing samples of pool/spa water using an unmanned aircraft (drone).
Description
BACKGROUND
Field of the Disclosure

The present disclosure relates generally to the field of pool and spa equipment. More particularly, the present disclosure relates to systems and methods for sanitizing pool and spa water.


Related Art

Fluid sanitization systems have been provided in the past for sanitizing pool and spa water. For example, assemblies for sanitizing and/or disinfecting water have been developed. Fluid (e.g., water) sanitization assemblies are useful in a myriad of different environments for various uses/applications, such as commercial and/or industrial applications. While such systems have various features and advantages, there is a constant need to improve the effectiveness of such systems. Accordingly, this and other needs are addressed by the systems and methods for sanitizing pool and spa water, of the present disclosure.


SUMMARY

Provided herein are systems and methods for sanitizing pool and spa water. In one embodiment, an electrolytic chlorinator (sometimes referred to herein as a salt cell) is provided which includes a combined flow, temperature, and salt concentration sensor. In another embodiment, the electrolytic chlorinator includes an acid tank for in-situ cleaning of the electrolytic chlorinator or acidification of pool/spa water where needed. In another embodiment, a delayed polarity reversal technique is provided for de-scaling and managing passivation of the blades of an electrolytic chlorinator. In still another embodiment, the electrolytic chlorinator includes a sacrificial anode for protecting components of the chlorinator as well as other pool/spa components. In yet another embodiment, the electrolytic chlorinator includes an integral, electrically-controlled acid generator. In another embodiment, the electrolytic chlorinator includes a brine tank for periodically superchlorinating and/or shocking pool/spa water. In still another embodiment, the chlorinator includes a plurality of chemical tanks/feeds for periodically injecting chemicals into the chlorinator. In another embodiment, a combined ultraviolet (UV)/Ozone and salt (electrolytic) chlorine generator is provided. In other embodiments, filters having integral UV sanitizers are provided. In still further embodiments, reflective linings are provided for UV sanitization systems. In another embodiment, a UV/Ozone sanitizer having means for injecting bubbles into pool/spa water is provided. In another embodiment, a system for acquiring and analyzing samples of pool/spa water using an unmanned aircraft (drone) is provided. Potential applications for the technologies disclosed herein include, but are not limited to, pools, spas, hot tubs, cooling towers, mister systems, secondary and tertiary waste water, rainwater, drinking water, industrial water treatment, aquaculture, and agriculture.





BRIEF DESCRIPTION OF THE DRAWINGS

The foregoing features of the disclosure will be apparent from the following Detailed Description, taken in connection with the accompanying drawings, in which:



FIG. 1 is a diagram illustrating an electrolytic chlorinator having an combined flow and salt concentration sensor;



FIG. 2 is a diagram illustrating the combined flow and salt concentration sensor of FIG. 1 in greater detail;



FIG. 3 is a diagram illustrating an electrolytic chlorinator having an acid tank for in-situ cleaning of the chlorinator and/or acid introduction into pool/spa water;



FIGS. 4A-4B are diagrams illustrating a delayed polarity reversal technique in accordance with the system of the present disclosure;



FIGS. 5A-5B are diagrams illustrating an electrolytic chlorinator having an integral sacrificial anode;



FIGS. 6A-6B are diagrams illustrating an electrolytic chlorinator having an integral, electronically-controlled acid generator;



FIG. 7 is a diagram illustrating an electrolytic chlorinator having a brine tank for shocking and/or superchlorinating pool/spa water;



FIG. 8 is a diagram illustrating an electrolytic chlorinator having a plurality of chemical tanks and/or feeders for periodically introducing chemicals into the chlorinator;



FIG. 9 is a diagram of a conventional ultraviolet sanitizer;



FIG. 10 is a diagram of a conventional ultraviolet/ozone sanitizer;



FIGS. 11-12 are diagrams of an ultraviolet/ozone sanitizer and electrolytic chlorine generator in accordance with the present disclosure;



FIGS. 13A-13B are diagrams illustrating filtration systems having integral UV sanitizers in accordance with the present disclosure;



FIGS. 14A-14B are diagrams illustrating reflective inner surfaces for UV sanitizers;



FIG. 15 is a diagram illustrating a UV/Ozone sanitizer having bubble generation capability; and



FIG. 16 is a diagram illustrating a system for obtaining samples of pool/spa water using unmanned aerial vehicles (drones).





DETAILED DESCRIPTION

The present disclosure relates to systems and methods for sanitizing pool/spa water, as described in detail below in connection with FIGS. 1-16.



FIG. 1 is a diagram illustrating an electrolytic chlorinator 10 in accordance with the present invention. The chlorinator 10 can operate with a pumping system of a pool and/or spa, and sanitizes water of the pool and/or spa by converting salt within the water to free chlorine via electrolysis. The chlorinator 10 includes a body 12, a combined flow, temperature, and salt sensor 14 that is removably installed in an aperture 16 in the body and extends into a chamber 18 of the body, a forward portion 20 which includes a plurality of electrolytic plates 22, and ports 24, 26. It is noted that the combined flow and salt sensor 14 is installed in the aperture 16 in the general direction shown by the arrow in FIG. 1.



FIG. 2 is a diagram illustrating the combined flow, temperature, and salt sensor 14 in greater detail. The sensor 14 includes a body 30 having a generally cylindrical outer wall 32 and a peripheral shoulder 34, a chamber 36 that receives a circuit board and/or electronics, potting compound 36 which encapsulates the circuit board and/or electronics, a recessed portion 38, a paddle wheel 40 which is at least partially positioned in the recessed portion 38, and a plurality of electrodes (pins) 42. As can be seen, 4 pins 42 are provided, but other quantities of pins could be provided without departing from the spirit or scope of the present disclosure. The paddle wheel 40 is in mechanical communication with a flow meter forming part of the sensor 14, and rotates whenever water flows past the sensor 14 to measure the rate of water flow past the sensor 14.


The sensor 14 measures the salt concentration in pool/spa water, as well as water's conductivity. Unlike 2-pin sensors, there is no interference from ‘fouling’ (e.g. scaling) and no calibration is required for the sensor 14. The sensor 14 can be located inside a salt cell (electrolytic chlorinator or other piece of pool equipment—e.g. pump, heater, etc.). Locating the sensor 14 inside a salt cell (or other pool equipment) eliminates the need for the sensor to be plumbed somewhere else in the system. Also, it allows the salt cell to intelligently know to shut itself off—it can do this because a change of conductivity occurs when water stops flowing and the gasses generated by the salt cell start to void the cell of liquid. When the sensor 14 stops being surrounded by water, the conductivity changes dramatically and can be detected and used for salt cell control (to control the chlorinator 10).


The sensor 14 can be used for cell health monitoring and diagnostics. The measured salt level from the sensor 14 can be compared with a calculated salt level based on an algorithm involving cell voltage, cell amperage and water temperature. In the comparison between ‘measured’ and ‘calculated’ salt, it is possible to discern how the salt cell is performing versus how it should be performing—the difference can intelligently inform if the cell is dirty (and needs to be cleaned) or if the cell is permanently degraded (and how much lifetime remains). Another advantage of the sensor 14 is that it can be used, in combination with the volume of pool or spa water, to inform the user of the actual pounds (or kilograms) of salt that needs to be added to the pool/spa in order to raise the salt concentration to a target level. Further, the salt concentration measured by the sensor can be compared to an impedance of plates of an electrolytic chlorinator in which the sensor is installed to determine a difference, and a condition of the electrolytic chlorinator can be determined based on the difference (which can be monitored over time).


The flow sensor of the sensor 14 can measure the presence of flowing water and the actual water flow rate. Installation of flow sensor in a salt cell or other piece of pool equipment (e.g. pump, heater) eliminates the need for a separate flow switch to be plumbed somewhere else in the system. The rotation of the paddle wheel 40 can be bidirectional, permitting flow detection and measurement in either flow direction. Magnets on the end of each rotary vane of the paddle wheel 40 can be detected by electronics in potted housing 36. The force required to rotate the paddle wheel 40 is very small, permitting detection of very low flow rates (e.g. <10 GPM). The paddle wheel 40 is scalable and can be used in small pipe and large pipe diameters (e.g. ½ inch pipe to 8 inch pipe and beyond). Further, paddle wheel 40 eliminates failure modes that falsely report flow. Calculation of pool turnover (i.e. how many gallons of water was processed in a 24 hour period divided by the volume of the pool) is also possible using flow measurements. Calibration of pump RPM and pump energy consumption to the flow rate for a given pool pad arrangement can also be performed, allowing for the calculation of electrical energy used to operate pool daily/weekly, annually, etc.


Additionally, calculation of optimal mixing and turnover rates for improved chemical sensing and dosing algorithms (e.g. prevent over oscillation) can be performed. A display could be provided for displaying flow rate and historical flow rates in a chlorinator (or a pump or a heater). Further, sensor 14 eliminates filter schedules by filtering as long as needed to meet specific water turnover goals and at the best energy level (e.g. run as slow and as long as you allow the pool to run). The sensor 14 enables a combination of flow rate (and flow history) with pump power sensing to predict whether there is a system leak. If pool plumbing has a significant leak then pump energy could decrease dramatically at constant flow rate or pump energy could remain constant yet there be a dramatic increase in flow rate. Additionally, the sensor 14 enables a combination of flow sensing and pump relay in order to 1) build a hydraulic curve for the plumbing, 2) determine practical maximum flow rate, 3) determine turnover schedule requirements, and 4) sense the filter media health. Still further, the sensor 14 enables a combination of flow sensing and certain controlled equipment in order to dynamically set the correct flow to meet 1) heater requirements when heating, 2) chlorinator needs when chlorinating, 3) adequate mixing of dosed chemicals such as acid or liquid chlorine when dosing.



FIG. 3 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, wherein an electrolytic chlorinator (salt cell) 110 with periodic in-situ acid cleaning capability is provided. In this embodiment, the chlorinator 110 is fed acid from an acid tank 128 via tubing 129 in fluid communication with a port 116 in the housing 112 of the chlorinator. A ‘cell cleaning cycle’ could be provided which automatically injects some (or all of the acid) that is expected to be needed (in a given week, for example) by the pool based on the salt chlorinator runtime and pool size directly into the salt cell to permit cleaning of scale from the salt cell. The system could inject a small amount of acid directly into cell 110 just prior to a pump turning on (e.g. 1 hour before), so as to take advantage of the high acid level on the electrodes yet rinsing it clean after this short exposure time. Alternatively, the system could inject a small amount of acid directly into cell after the pump has turned off to allow acid to soak inside cell and remove scale.



FIGS. 4A-4B are diagrams illustrating a polarity reversal delay technique in accordance with the system of the present disclosure. The polarity reversal technique allows for removal of oxygen 134 from pores/cracks 138 in the surface 132 of a cathode coating formed on a titanium electrolytic chlorinator blade 130 (which could include a layer of titanium dioxide 136). FIG. 4A illustrates the condition of the blade 130 prior to polarity reversal, and FIG. 4B illustrates the condition of the blade 130 after polarity reversal. Most salt cells are controlled in such a way that the polarity is reversed at some frequency (e.g., every 1, 2, 3, 4, 8 hours) in order to allow for self-cleaning. The very act of switching the polarity causes an anode to become a cathode and vice versa. The chemistry switches also, because an anode has an acidic surface environment (i.e., chlorine gas production) and the cathode has an alkaline surface environment (i.e., hydroxide ion production). This aids in self-cleaning as calcium scale will precipitate on the alkaline cathode but gets dissolved by the acid environment when it becomes an anode. Another aspect of polarity reversal has to do with how much time delay, if any, occurs when the polarity is switched. It is advantageous to build in a time delay between the polarity switch (as opposed to a hard switch over with no time delay) because the cathode also produces a small amount of oxygen gas 134 that can combine with the underlying titanium substrate 130 to form a passivated titanium oxide layer 136, which is non-conductive. The titanium passivation 136 (titanium converting to titanium dioxide) permanently prevents the electrode from functioning. The act of introducing a time delay is to allow the oxygen time to diffuse (convect) away so when the electrode becomes energized again there is less oxygen present to potentially form the oxide layer. A 1-minute delay between switching (with switching occurring every 3 hours) has been found to be sufficient, such that there is no detriment to overall chlorine production with a few minutes of downtime per day. It is possible that longer delays are better (e.g. 2 minutes, 4 minutes, 10 minutes) in that such delays would extend the life of the salt cell. These longer delays could be factory set or adjustable in the chlorinator control center by the end user.


Alternatively, a learning algorithm can be employed whereby the monitoring of the output of the cell intelligently informs the controller as to how long it is taking for the cell to become dirty with scale. A controller can then decide as to the frequency of the polarity reversals. For example, if the cell is not scaling much (due to low hardness water), then the controller does not demand polarity reversal every “x” hours. Instead, it learns how often to reverse based on how quickly the cell is scaling.



FIGS. 5A-5B illustrate another embodiment of the sanitization system of the present disclosure, wherein a chlorinator 210 includes a sacrificial anode 229. The sacrificial anode 229 could be attached to a plug 228 which inserts into an aperture 216 formed in a housing 212 of the chlorinator 210, such that the anode 229 extends into a chamber 218 formed in the chlorinator 210. Water flows into the chamber 218 in the general direction indicated by arrow B, past the sacrificial anode 229, and past electrolytic plates of the chlorinator 210. Of course, it is noted that flow direction could be reversed (in a direction opposite arrow B), if desired. Sacrificial zinc anodes can be used to help mitigate the galvanic corrosion damage done by stray currents that may exist in the water due to insufficient equipment bonding or insufficient pool grounding to earth. They can be also used to prevent a battery-like environment created between two dissimilar metals in contact with the conductive water (cathodic protection). Sacrificial anodes are wearable items and, after 6-months, 1 year, 2 years or more, the anode will need to be replaced as the zinc will have dissolved away. Zinc is used as sacrificial anodes in marine application extensively (e.g. to protect the hull of ships in salt/brackish water). Zinc happens to have some algistatic properties as well so its dissolution is desirable not only from the sacrificial anode standpoint but from the aspect that it provide an algistat to the pool water.



FIGS. 6A-6B illustrate another embodiment of the sanitization system of the present disclosure, wherein a chlorinator 312 includes an integrated acid generator 329. The acid generator 329 could be attached to a plug 328 which inserts into an aperture 316 formed in a housing 312 of the chlorinator 310 (in the general direction indicated by arrow C), such that the acid generator 329 extends into a chamber 318 formed in the housing 312 of the chlorinator 310. The acid generator 329 could be powered by a power supply 330 in electrical communication with the anodes 329. Salt chlorine generators naturally cause an increase in the pH of the water due to the net chemical reaction: 2NaCl+2H2Ocustom characterCl2+2NaOH+2H2. To counteract the pH increase due to the sodium hydroxide production (i.e. NaOH), the acid generator 329 generates an acid (i.e. protons—aka H+—aka H3O+), and could be formed from a pair of electrodes that can fit inside the chlorinator 310. The acid generator 329 operates when the salt cell is operating in order to neutralize the pH change. Alternatively, or additionally, the acid generator 329 can be turned on just prior to the pump so the cell can be soaked in acid and cleaned of scale. Alternatively, or additionally, the acid generator 329 can be turned on after the pump shuts off so the cell can be soaked in acid and cleaned of scale. The acid generator 329 can be intelligently matched to the salt cell operation so that the NaOH is precisely neutralized. The acid generator 329 can also operate independent of the cell to lower the pH of the pool water when desired.



FIG. 7 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, wherein a chlorinator 410 is provided which is fed by a brine tank 428 in fluid communication with the chlorinator 410 via a tube 429 to provide for superchlorination when needed. The tube 429 is in fluid communication with a port 416 formed in a housing 412 of the chlorinator 410, such that brine is periodically injected into a chamber 418 of the chlorinator 410. Pools and spas occasionally require a shock of chlorine (aka-superchlorination) to oxidize contaminants (e.g. organics, dead bacteria, metals, combined chlorine)). Salt chlorine generators generally do not make good superchloriantors because they generate chlorine too slowly. For example, a typical salt generator will make 1-2 lbs of chlorine per day but the superchlorination of a pool calls for raising the chlorine level to 10 ppm rapidly. A 40,000 gallon pool would need about 4 lbs of chlorine to raise it to 10 ppm (from 0 ppm) but that cannot be done quickly with a salt system. In order to enable the salt system to produce more chlorine, a higher salt level can be used. Raising the salt level in the entire pool would be undesirable. The brine tank 428 provides a high salt concentration into the salt cell so the cell can make more chlorine without needing to raise the salt level of the entire pool. The brine tank 428 (containing dissolved salt at a concentration similar to ocean water—30,000 ppm—or even higher—up to saturation level of salt in water at room temperature) is fed directly into the salt cell while the flow rate through the cell is reduced (this is to keep from diluting the introduced salt solution yet allowing flow to carry away chlorine gas). The higher salt concentration will allow the salt cell to make more chlorine and the salt cell can then serve as a means of superchlorinating the pool/spa.



FIG. 8 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, wherein a chlorinator 510 is in fluid communication with a plurality of chemical feeders 528a-528c via fluid lines 529a-529c. The fluid lines 529a-529c inject fluids from the feeders 528a-528c into a chamber 518 formed in the housing 512 of the chlorinator 510. Many different chemicals are available to add to pools to control water quality issues such as high metals content, high phosphate levels, high organic load, high or low pH, high or low alkalinity, low cyanuric acid, low hardness, foaming, etc. All of these chemicals can be introduced in liquid form into the port 516 of the electrolytic chlorinator 512. The chemical types and their functions could include, but are not limited to, the following:















Sequesterants
Remove metals


Chelating agents
Bind metals, bind cations (e.g.



calcium)


Defoamers
Reduce foaming


Fragrances
Improve water odor


Acid (e.g. muriatic)
Lower pH, lower alkalinity


Sodium carbonate solution
Raise pH


Sodium bicarbonate solution
Raise alkalinity


Cyanuric acid
Chlorine stabilizer


Calcium chloride solution
Increase water hardness


Sodium bisulfite solution
Reduce excess chlorine levels


Sodium bromide solution
Algicide


Hydrogen peroxide
Oxidizer


Metals solution (e.g. silver nitrate,
Algistat, algicide, bacteriostat,


copper sulfate, zinc nitrate)
bacteriocide


Chemical that acts as solar blanket
Solar blanket-keeps heat in water and


on surface of the water
prevent heat escape


Enzyme solutions
Eats organic matter


Phosphate removers
Reduces phosphate levels that can



promote algae


Algicides
Prevent or kill algae


Liquid Chlorine
Sanitizer and oxidizer









It is noted that a manifold could be constructed so that multiple feed tanks can feed into the same port 516 on the chlorinator 512.



FIG. 9 is a diagram illustrating a conventional ultraviolet (UV) sanitization system, indicated generally at 600. UV, Ozone and salt chlorine generation systems are all well-known methods to sanitize pool water. These technologies can be employed individually on a pool or spa in combination with each other. Some systems have been reported that combine UV and ozone into a single system using a UV lamp that serves as both the source of UV light for water treatment and ozone generation for water treatment. One example of such a system is shown in FIG. 10 at 700, which depicts an ultraviolet sanitizer system 704 that has ozone generation capabilities. Ozone is generated by the ultraviolet light of the sanitizer system 704, is siphoned via a tube 706, and is fed into pool/spa water to be treated using a venturi 702. Such systems (shown in FIGS. 9 and 10) could be further modified to include a salt chlorine generator, as indicated at 800 in FIG. 11. Such a system 800 includes an ultraviolet and/or UV/Ozone generator 802, and a salt chlorine (electrolytic) generator 806 in fluid communication with the generator 802 by piping 804 and/or tubing 808. It is noted that the salt cell (i.e. chlorine generating electrodes) can be placed directly inside the UV and/or UV/Ozone vessel, if desired. The advantages may include a smaller equipment footprint on the pool pad and the use of a single electronic controller. Since neither UV nor ozone can be used as a stand-alone sanitizer due lack of a lasting chemical residual, chlorine is required with either a UV or UV/Ozone system-hence, integration into a single product makes sense.



FIG. 12 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, indicated generally at 900. In this embodiment, the sanitization system 900 includes an ultraviolet/ozone (UV/O3) sanitization system 902 in fluid communication with an electrolytic chlorinator 908. The electrolytic chlorinator could be controlled by an electronic controller 910. The UV/O3 sanitization system 902 could include a venture assembly 904 which feeds ozone into water to be treated. Such ozone could be supplied via a tube 906 which draws ozone generated from ultraviolet lamps in the system 902. A big benefit of using a UV and/or a UV/ozone and/or an Ozone generator with a chlorine source for pool and or spa water treatment is that the amount of chlorine needed can be much less-on the order of 50% less. Due to the lower chlorine output needed, the end user has at least 2 options when paring these systems with a salt water chlorinator: reduce the operating time of an existing salt system (say by 50% for example) and, as a result, extend the duration of the use of a salt cell by a factor of 2, or, pair the UV, UV/Ozone, or Ozone system with a LOW SALT chlorine generator. The lower salt level will: 1) reduce the chlorine output of the salt chlorine generator; and 2) will lower the risk for corrosion of pool decking, pool equipment and poolside furniture. LOW SALT is defined as being less than 2500 ppm, preferably less than 2000 ppm and most preferably less than 1500 ppm.



FIGS. 13A-13B are diagrams illustrating another embodiment of the sanitization system of the present disclosure. As shown in FIG. 13A, the system 1000 includes a filter 1002 and an ultraviolet sanitization system 1004 positioned within the filter 1002. A manifold 1006 could control water flow through the filter 1002, and could provide a mounting point from which the ultraviolet sanitization system is suspended. As shown in FIG. 13B, the system of FIG. 13A is expanded (indicated generally at 1100) to also include an ozone feeder system that includes a venturi assembly 1108 and a tube 1110 for feeding ozone into water to be filtered. The ozone could be supplied by an ultraviolet assembly 1104 positioned within the filter 1102 and suspended from a manifold 1106.


Manways or “manhole covers” can be placed on filter housings for easy access to media servicing or replacement (e.g., as in sand filters). The manway can serve as the access point for the insertion of one or more UV lamps. The only requirement of the final system is that the water is filtered prior to passing the UV lamps—this is because UV works best when the water is clear. Furthermore, filtered water is less likely to foul the glass sleeve that is placed around the lamp.



FIGS. 14A-14B are diagrams illustrating ultraviolet sanitization systems which include reflective liners. As shown in FIG. 14A, the sanitizer 1200 includes an ultraviolet lamp 1204 and reflective liner 1202 which reflects light into the sanitizer 1200 as indicated by arrows D. A conventional sanitizer 1300 is shown in FIG. 14B, which lacks a reflective liner. As can be appreciated, only direct light emanating from the lamp 1304 is available to sanitize water, as indicated by arrows E. UV reflective surfaces allow a portion of the UV light to return to the water column where it can provide additional benefit in the way of microbial inactivation. Some UV reflective materials that could be utilized for the liner 1202 are listed below:
















Material
UV Reflectivity









Plastic
10%



Polished stainless steel (SS)
30%



Polished aluminum
60%



Teflon (PTFE)
>99% 










No system exists whereby a highly reflective coating (i.e. greater than polished SS) has been added to the vessel wall of a UV/ozone water treatment system. Such a system has the benefit of the returned UV light to the water column where it can convert ozone to hydroxyl radicals—or at the very least—destroy the ozone so it does not return to the pool or spa where off-gassing of the ozone can harm bathers



FIG. 15 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, indicated generally at 1400, which introduces air or gas bubbles into water to be treated. In this embodiment, the sanitization system 1400 includes a combined UV/O3 sanitization system 1402, a venture assembly 1404, and an external supply 1406 of air or another gas for sanitizing water being fed into the system 1400. The addition of an air bubble (irrespective of the gas composition in that bubble), causes the UV light to reflect/diffract off the bubble surface thereby increasing the mean path length through the water column before the UV hits the reactor wall where the majority of its energy is lost as heat.



FIG. 16 is a diagram illustrating another embodiment of the sanitization system of the present disclosure, which includes an unmanned aerial vehicle (UAV) or drone 1500 that can fly toward a body of water such as a pool or spa 1512 (in the direction indicated by arrow F) and periodically obtain a sample of water 1510 from the body of water. The drone 1500 could include a body 1502, propellers 1504 for propelling the drone 1500, and a water sampling device 1506 for obtaining samples of the water 1510. The drone 1500 could transport the sample of water to a testing facility whereby the water is tested for various characteristics such as water quality, pH, chlorine levels, bromine levels, etc. Alternatively, the drone 1500 could include sensors for automatically testing such characteristics on-board the drone 1500, so that the drone need not fly to a testing facility.


For the vast majority of pool and spa owners, a proper water analysis is conducted by the end user bringing a water sample to a local retail or service store where specialized equipment is available to evaluate the water quality. Water quality parameters such as pH, free chlorine, total chlorine, combined chlorine, bromine, calcium hardness, total alkalinity, total dissolved solids, cyanuric acid, phosphate levels, metals (such as Fe, Mn, Cu and Ag), and salt (i.e. sodium chloride), are commonly measured. Many of these measurements are beyond the scope (and affordability—as analytical equipment can be expensive for a homeowner) of what is available to the consumer to perform at their home. Most consumers, if they make measurement themselves will use simple test strips or simple dropper kits. The tests trips measure free chlorine, total chlorine, pH, total alkalinity, total hardness, cyanuric acid and pH whereas the dropper kits typically are limited to pH and free and total chlorine. The inconvenience of bringing a water sample to a store can be alleviated by the use of the drone 1500 which flies to the location of the pool and/or spa and gathers a water sample. The drone is outfitted with a means to gather and store a volume of water, typically 2 mL or more, preferably 5 mL or more, and most preferably 10 mL or more. The collected water sample can be brought back to a water testing location for analysis or, given sufficient onboard sensors, the drone could analyze the water, including temperature, at the point of pick up. In either case, the results can be sent to the homeowner or a service company for immediate action should any of the water quality parameters fall outside of recommended guidelines. The drone could be outfitted with GPS or equivalent to locate the body of water. Furthermore, the drone can have onboard sensors, protected from the elements within its housing, that detect whether the pool or spa has a cover on it and whether or not there are active bathers in the water. In the event of active bathers, an audible alarm could warn of the impending water landing, or alternatively, the drone can ‘reschedule’ its visit or manage to descend without approaching closer than 10 feet to a bather. Finally, the drone can have communication capability (WiFi or other) that allow it to be manually guided or rerouted as deemed necessary by the sending party. We can imagine that the sender is managing the flight of the drones in a manner similar to the tracking of airline flights by air traffic control. Additionally, the onboard communication of the drone can alert the end user (by text or email) when it intends to be at their location and can then communicate the results of its findings. On-board sensors could also be part of the drone that enable it to test turbidity and sense physical debris in the water, using cameras for example, so it can alert appropriate parties as to the need for added filtration or filtration maintenance as well as pool cleaning services. The drone could direct an automatic pool cleaner to certain top, side and bottom locations for debris removal as well as instruct a pool automation system on filtration cycle management, chlorination output, heater control, etc.


Additional features of could be provided in accordance with the present disclosure as follows.


If a salt chlorine generator output varies with salt level, water temperature, current supplied or other external variable, then a fixed amount of chlorine per day can be maintained by sensing chlorine generator amperage versus the amount of chlorine generator runtime and then keeping the filter running (or intentionally shortening its on-cycle) to match the targeted daily chlorine dosage. A system could be provided wherein chlorine generator production rate is modified with water temperature to match higher chlorine demand in hotter water versus lower chlorine demand in colder water. Such a system could combine amperage utilization by chlorinator with pump schedule to predict chlorine dose provided by the schedule. Further, such a system could modify chlorine dosing (salt system or liquid or tablet chlorine feeder) with weather reports and geographies (e.g. hot in AZ combined with wind creates more dust in pool; anticipate temp at night to assess overall chlorine demand).


In a salt chlorine generator, a system could be provided wherein the generator modifies polarity reversal rates of the chlorine generator based on water hardness, water temperature, age of salt cell and flow rate.


Various smart sensing and control techniques could be implemented in accordance with the present disclosure. For example, such techniques could involve the use of predictive trends of water quality data (e.g. pH trend line) to determine dosing regimen rather than simple timeout features (Example of old method: Acid feeder is activated due to high pH. After several hours the pH target still not met so a timeout alarm is used to stop what may be a bad pH probe and overdosing of acid. Example of new method: Acid feeder is activated due to high pH. After several hours the pH target still not met but the pH trend line is going as expected and so dosing continues). Such a method eliminates false alarms and inconvenient timeouts. Additionally, the system could modify/compensate ORP set point with measured pH value. Since ORP drops as pH increases, a potential exists to continue adding chlorine when in fact ORP only dropped due to pH and not due to insufficient chlorine. The issue of falling ORP with rising pH is currently problematic with salt chlorinators managed by ORP sensing because the pH will rise as the chlorine generator operates, causing a lowering of the ORP and the potential for the ORP not to hit its set point, calling for more chlorine when in fact there is plenty. Still further, the system could modify/compensate ORP set point with sunlight. UV/visible rays have a pronounced effect on ORP if cyanuric acid is used. For example, at the same chlorine level, water exposed to darkness will have a higher ORP than the same body of water exposed to sunlight (because cyanuric acid will bind the chlorine more tightly in the sun—has to do with the binding strength between the chlorine molecule and cyanuric acid molecule as a function of UV/visible light).


The system could also be embedded with a reminder system in the equipment (chlorinator, pump, etc.) to recommend manual water tests. A calculator/wizard could be used to recommend ORP set points and chlorine dosing based on manual water tests. Further, the system can calculate acid needed to offset pH rise when using a salt chlorinator as a function of water chemistry parameters, chlorinator runtime, geography and weather reports. For example, the pH rise in a given week/month associated with specific chlorinator usage can be predicted for a given pool given its volume and water chemistry. If however, acid rain occurs, the need for additional acid may be nil in any given period. Other water parameters that could be sensed include alkalinity, cyanuric acid levels, and calcium hardness levels.


Additionally, further improvements can be made to salt chlorinators in accordance with the present disclosure, as follows. Salt chlorine generators typically are designed to shut off when the water flow stops. That is, they are controlled by a flow switch that triggers the shut off. In doing so, a high concentration of chlorine exists inside the cell which can diffuse upstream and chemically attack heaters and other pool equipment. For this reason, a check valve is often used upstream of the chlorinator to prevent this backflow. A better solution is to simply have the chlorinator shut off 1 or 2 minutes before the pump—in this way, the salt cell has been flushed of the high concentration of chlorine and only normal pool water chlorine levels exist inside the cell-therefore no check valve is needed. Note that the volume of a salt cell is small compared to the volume of water flowing through it so only a few seconds of ‘flushing’ is needed after the cell shuts off.


The systems of the present disclosure could also include the ability to predict the need to shock or superchlorinate a pool or spa. Shocking or superchlorination of pool water is periodically required to oxidize bather waste. The system can anticipate the need to shock based on weather (e.g. sunlight, rainfall), bather load, turbidity, seasonality and combined chlorine level.


Additionally, in accordance with the present disclosure, the various UV/Ozone systems disclosed herein could also be modified to function as bromine generators. Bromine is commonly used in hot tubs because it does not form bromamines, unlike chlorine which forms malodorous chloramines. Bromine can be added to a hot tub by 1) bromine tablets, 2) by the generation of bromine using a salt bromine generator (starting with NaBr instead of NaCl as is done with chlorine) or 3) by generating the bromine in situ using ozone (a strong oxidizer) to convert bromide salt to bromine (Note: ozone will convert bromide to bromine. Bromides are introduced into hot tub as the NaBr salt). The hydroxyl radicals generated from a UV/Ozone system can be used to convert the bromides salt to bromine. The use of a UV/Ozone system not only regenerates bromine form the bromide ions but it reduces the amount of bromine needed to the overall sanitizing and oxidizing power of the UV/Ozone combination.


Still, further, in accordance with the present disclosure, pool lights or wall fittings can serve as turbidity and bather sensors. A pool light by definition is a transmitter of light. A pool light or wall sensor that contains a ‘light receiver’ can be calibrated using ‘clear’ water and the change in light intensity can be used to monitor the presence of bathers and/or changes in the turbidity of the water.


Having thus described the invention in detail, it is noted that the foregoing description is not intended to limit the spirit or scope of the present invention. Accordingly, what is desired to be protected by Letters Patent is set forth in the following claims.

Claims
  • 1. A sanitization system, comprising: an electrolytic chlorinator having a plurality of electrolytic plates for generating free chlorine from salt through electrolysis; anda replaceable sacrificial anode removably positioned in a chamber of the electrolytic chlorinator, the sacrificial anode mitigating against galvanic corrosion damage to a pool or spa component, wherein the replaceable sacrificial anode comprises a removable plug removably positionable within the chamber of the electrolytic chlorinator through an aperture formed in the electrolytic chlorinator.
  • 2. The sanitization system of claim 1, wherein the sacrificial anode is formed from zinc.
  • 3. The sanitization system of claim 2, wherein the zinc provides an algistat to water of a pool or a spa.
  • 4. The sanitization system of claim 1, wherein the sacrificial anode mitigates against corrosion caused by stray currents in water of the pool or spa.
  • 5. The sanitization system of claim 4, wherein the stray currents are caused by insufficient equipment bonding.
  • 6. The sanitization system of claim 4, wherein the stray currents are caused by insufficient grounding.
  • 7. The sanitization system of claim 1, wherein the sacrificial anode provides cathodic protection for a pool or a spa.
  • 8. The sanitization system of claim 1, wherein water flows past the sacrificial anode prior to flowing past electrolytic plates of the electrolytic chlorinator.
  • 9. The sanitization system of claim 1, wherein water flows past electrolytic plates of the electrolytic chlorinator prior to flowing past the sacrificial anode.
RELATED APPLICATIONS

The present application is continuation of U.S. patent application Ser. No. 15/927,412, now U.S. Pat. No. 10,934,184, filed Mar. 21, 2018, which claims priority to U.S. Provisional Application Ser. No. 62/474,333 filed on Mar. 21, 2017, the entire disclosures of both of which are expressly incorporated by reference herein.

US Referenced Citations (415)
Number Name Date Kind
D138325 Pool Jul 1944 S
2436077 Robertson Feb 1948 A
2644700 Woodling Jul 1953 A
3079498 Ruffin Feb 1963 A
3162470 Davidson et al. Dec 1964 A
3336099 Czulak et al. Aug 1967 A
3632498 Beer Jan 1972 A
3803573 Schonger Apr 1974 A
3929151 Rubin Dec 1975 A
3933616 Beer Jan 1976 A
D242618 Milo Dec 1976 S
4085028 McCallum Apr 1978 A
4100052 Stillman Jul 1978 A
4107452 Razvi Aug 1978 A
4141830 Last Feb 1979 A
4179616 Coviello et al. Dec 1979 A
D254266 Tableriou Feb 1980 S
4214971 Heikel et al. Jul 1980 A
4230571 Dadd Oct 1980 A
4250910 King Feb 1981 A
4290873 Weaver Sep 1981 A
4409081 Terrase Oct 1983 A
4435095 Jones et al. Mar 1984 A
4510487 Wolfe et al. Apr 1985 A
4535247 Kurtz Aug 1985 A
4752401 Bodenstein Jun 1988 A
4774977 Cohen Oct 1988 A
4781810 Tucker Nov 1988 A
4842723 Parks et al. Jun 1989 A
4849115 Cole et al. Jul 1989 A
4856348 Hall Aug 1989 A
4900432 Arnold et al. Feb 1990 A
4940946 Nazaryan Jul 1990 A
4959142 Dempo Sep 1990 A
5034110 Glore Jul 1991 A
5055183 Buchan Oct 1991 A
5059296 Sherman Oct 1991 A
D326309 Kendrick May 1992 S
5115222 Peralta et al. May 1992 A
5124032 Newhard Jun 1992 A
5124960 Miller et al. Jun 1992 A
5152610 Hallett Oct 1992 A
5169236 Iest Dec 1992 A
5189350 Mallett Feb 1993 A
5217261 DeWitt et al. Jun 1993 A
5221444 Silveri Jun 1993 A
5228964 Middleby Jul 1993 A
5234563 Arai et al. Aug 1993 A
5247710 Carder et al. Sep 1993 A
5254226 Williams et al. Oct 1993 A
5266215 Engelhard Nov 1993 A
5279748 Hackett Jan 1994 A
5302298 Leitzke Apr 1994 A
5314589 Hawley May 1994 A
5326481 Alwerud Jul 1994 A
5362368 Lynn et al. Nov 1994 A
5401373 Silveri Mar 1995 A
5422014 Allen et al. Jun 1995 A
5422487 Sauska et al. Jun 1995 A
5434419 Decupper Jul 1995 A
5460706 Lisboa Oct 1995 A
5498333 Canther Mar 1996 A
5518635 Kohlman May 1996 A
D371824 Price et al. Jul 1996 S
5546982 Clark et al. Aug 1996 A
5580438 Silveri Dec 1996 A
5590390 Maarschalkerweerd Dec 1996 A
5649560 Lenney et al. Jul 1997 A
5681110 Burzacchi Oct 1997 A
5695644 Buchanan et al. Dec 1997 A
5709799 Engelhard Jan 1998 A
5730861 Sterghos et al. Mar 1998 A
5752282 Silveri May 1998 A
5788826 Nyberg Aug 1998 A
5810999 Bachand et al. Sep 1998 A
5893977 Pucci Apr 1999 A
5915622 Foote Jun 1999 A
5925572 Byrne et al. Jul 1999 A
5932093 Chulick Aug 1999 A
5985154 Agree et al. Nov 1999 A
5985155 Maitland Nov 1999 A
5993669 Fulmer Nov 1999 A
5996138 Kentch Dec 1999 A
6001242 England et al. Dec 1999 A
6007693 Silveri Dec 1999 A
6013918 Bushnell et al. Jan 2000 A
6027642 Prince et al. Feb 2000 A
D422676 Conover et al. Apr 2000 S
6071473 Darwin Jun 2000 A
6096202 Fulmer Aug 2000 A
6099735 Kelada Aug 2000 A
6099799 Anderson Aug 2000 A
6113858 Tang et al. Sep 2000 A
6120691 Mancil Sep 2000 A
RE36896 Maarschalkerweerd Oct 2000 E
D432206 Stoltz et al. Oct 2000 S
6125481 Sicilano Oct 2000 A
6125778 Rodden Oct 2000 A
6126810 Fricker et al. Oct 2000 A
6129850 Martin et al. Oct 2000 A
6132629 Boley Oct 2000 A
6149343 Lewis et al. Nov 2000 A
6171452 Michael Jan 2001 B1
RE37055 Silveri Feb 2001 E
6193894 Hollander Feb 2001 B1
D439313 Wey et al. Mar 2001 S
6200487 Denkewicz, Jr. et al. Mar 2001 B1
6210566 King Apr 2001 B1
6217754 Ros Apr 2001 B1
6221257 Grim Apr 2001 B1
6223359 Oltmanns et al. May 2001 B1
6225900 Keon et al. May 2001 B1
6228272 Gola May 2001 B1
6231820 Wedekamp May 2001 B1
6235188 Nakamura et al. May 2001 B1
6238553 Lin May 2001 B1
6238555 Silveri et al. May 2001 B1
6270680 Silveri et al. Aug 2001 B1
6274052 Hartwig Aug 2001 B1
6277288 Gargas Aug 2001 B1
6287466 Yassin Sep 2001 B1
6294086 Reeves Sep 2001 B1
6299761 Wang Oct 2001 B1
6309538 Khan Oct 2001 B1
6340431 Khan Jan 2002 B2
6391167 Grannersberger May 2002 B1
6402966 Taira Jun 2002 B1
6444129 Collins Sep 2002 B1
6447720 Horton, III et al. Sep 2002 B1
6447721 Horton, III et al. Sep 2002 B1
6456197 Lauritsen et al. Sep 2002 B1
6476721 Diebold Nov 2002 B1
6488841 Glasgow Dec 2002 B2
6541771 Iwabuchi et al. Apr 2003 B2
6570173 Kunkel et al. May 2003 B1
6579446 Teran et al. Jun 2003 B1
D479475 Dermikaelien-Covault et al. Sep 2003 S
6620315 Martin Sep 2003 B2
6620318 Neofotistos et al. Sep 2003 B1
6623647 Martin Sep 2003 B2
6625824 Lutz et al. Sep 2003 B1
6653842 Mosley et al. Nov 2003 B2
6685825 Chang Feb 2004 B1
6697706 Gardner, Jr. Feb 2004 B2
6713298 McDevitt et al. Mar 2004 B2
6716345 Snyder Apr 2004 B2
D489431 Antunez May 2004 S
6749759 Denes et al. Jun 2004 B2
6756907 Hollaway Jun 2004 B2
6761827 Coffey Jul 2004 B2
6792956 Bredo et al. Sep 2004 B2
6797970 Gatter et al. Sep 2004 B1
6814095 King Nov 2004 B2
6824693 Sauska et al. Nov 2004 B1
6827847 Chauvier Dec 2004 B1
6895307 Gardner, Jr. May 2005 B2
6932903 Chang Aug 2005 B2
6948510 King Sep 2005 B2
6958693 Rothgeb et al. Oct 2005 B2
6991735 Martin Jan 2006 B2
7014753 Holstein et al. Mar 2006 B2
7022225 Clawson et al. Apr 2006 B1
7037038 Haski et al. May 2006 B1
D526382 Thompson Aug 2006 S
D537913 Biberger et al. Mar 2007 S
7211176 Hin et al. May 2007 B2
7238278 Coffey et al. Jul 2007 B2
7292898 Clark et al. Nov 2007 B2
D559943 Mercer Jan 2008 S
7329343 Barnes Feb 2008 B1
7390399 Dennis, II et al. Jun 2008 B2
7393450 Silveri Jul 2008 B2
7402252 Kadlec et al. Jul 2008 B2
7409853 Biberger et al. Aug 2008 B2
7472434 Moldthan et al. Jan 2009 B1
7507323 Eyal Mar 2009 B1
7511281 Cooper Mar 2009 B2
7612492 Lestician Nov 2009 B2
7641868 Jang Jan 2010 B2
7655116 Tilsner Feb 2010 B1
7658824 Bremauer Feb 2010 B2
7662293 Brolin et al. Feb 2010 B2
7681436 Biberger Mar 2010 B2
7687785 Chen Mar 2010 B2
7691343 Ueberall Apr 2010 B2
7695613 Doyle et al. Apr 2010 B2
7722746 Eyal May 2010 B1
7741617 Matthews et al. Jun 2010 B2
7752893 Biberger Jul 2010 B2
7754090 Berg Jul 2010 B1
7767067 Silveri Aug 2010 B2
7767168 Namespetra et al. Aug 2010 B2
7794608 Denkewicz, Jr. et al. Sep 2010 B2
7867401 Dennis, II et al. Jan 2011 B2
7879208 Wu et al. Feb 2011 B2
7883622 Barnes Feb 2011 B1
7901620 Taguchi et al. Mar 2011 B2
8007653 Porat Aug 2011 B2
8043070 Stiles, Jr. et al. Oct 2011 B2
8043500 Murg Oct 2011 B2
8048316 Denkewicz, Jr. Nov 2011 B2
8066940 Denkewicz, Jr. et al. Nov 2011 B2
8066941 Denkewicz, Jr. et al. Nov 2011 B2
8075751 Xie et al. Dec 2011 B2
8123956 King et al. Feb 2012 B2
8241586 Burris et al. Aug 2012 B2
8246839 Jeberall Aug 2012 B2
8343342 Foret Jan 2013 B2
8367007 Otero et al. Feb 2013 B2
8414839 Barnes Apr 2013 B1
8459100 Biberger Jun 2013 B2
8475725 Antipenko et al. Jul 2013 B1
8481985 Neister Jul 2013 B2
8487267 Abe et al. Jul 2013 B2
8491775 Barnes Jul 2013 B1
8492736 Wang et al. Jul 2013 B2
8496610 Levenson et al. Jul 2013 B2
8506886 Owen et al. Aug 2013 B2
8519356 Boyle Aug 2013 B2
8529770 Yencho Sep 2013 B2
8591730 Yong et al. Nov 2013 B2
8603331 Koble Dec 2013 B1
8883079 Clark Nov 2014 B2
8887556 Silveri Nov 2014 B2
8920615 Davidson et al. Dec 2014 B2
8961753 Perry Feb 2015 B2
8963736 Millar Feb 2015 B2
9031702 Pruchniewski et al. May 2015 B2
9034193 Shalon May 2015 B2
9097234 Breau et al. Aug 2015 B2
9102536 Cannavino et al. Aug 2015 B2
9581478 Smith Feb 2017 B1
9631388 Hui et al. Apr 2017 B2
D789221 Miller et al. Jun 2017 S
9815719 Sayre et al. Nov 2017 B2
9834451 Miller et al. Dec 2017 B2
9858792 Fernandes et al. Jan 2018 B2
9885193 Chen et al. Feb 2018 B2
10102585 Bryant et al. Oct 2018 B1
10106442 Martin et al. Oct 2018 B2
10127362 Bennett et al. Nov 2018 B2
10156081 Chen et al. Dec 2018 B2
10378544 Rejniak et al. Aug 2019 B2
10479705 Rochelle Nov 2019 B2
10618136 Bauckman et al. Apr 2020 B2
10737951 Miller et al. Aug 2020 B2
10934184 Denkewicz, Jr. et al. Mar 2021 B2
10989200 Rejniak et al. Apr 2021 B2
11100465 Le Burge Aug 2021 B1
20010010296 Hirota et al. Aug 2001 A1
20010045380 Khan Nov 2001 A1
20020035403 Clark et al. Mar 2002 A1
20020108913 Collins Aug 2002 A1
20020125716 Rochelle Sep 2002 A1
20020152036 Martin Oct 2002 A1
20020195403 Takeda et al. Dec 2002 A1
20030160005 Martin Aug 2003 A1
20030168389 Astle et al. Sep 2003 A1
20030227394 Rothgeb et al. Dec 2003 A1
20040031329 Carpenter et al. Feb 2004 A1
20040050781 Coffey et al. Mar 2004 A1
20040066313 Ong et al. Apr 2004 A1
20040197229 Runyon Oct 2004 A1
20040204779 Mueller et al. Oct 2004 A1
20040206706 Costa et al. Oct 2004 A1
20040208499 Grober Oct 2004 A1
20040249579 Centanni Dec 2004 A1
20050009192 Page Jan 2005 A1
20050051741 Hallett et al. Mar 2005 A1
20050109793 Thomas May 2005 A1
20050137118 Silveri Jun 2005 A1
20050139530 Heiss Jun 2005 A1
20050162273 Yoon et al. Jul 2005 A1
20050207939 Roussi et al. Sep 2005 A1
20050220169 McGowan-Scanlon Oct 2005 A1
20050222786 Tarpo et al. Oct 2005 A1
20050225766 Hansen et al. Oct 2005 A1
20050274965 Phillips et al. Dec 2005 A1
20050279677 Lin Dec 2005 A1
20060027463 Lavelle et al. Feb 2006 A1
20060054567 Mousseau Mar 2006 A1
20060060512 Astle et al. Mar 2006 A1
20060091002 Hin et al. May 2006 A1
20060096927 Clukies May 2006 A1
20060097878 Von Broembsen May 2006 A1
20060113256 Birkbeck Jun 2006 A1
20060144689 Barnes et al. Jul 2006 A1
20060144691 Barnes et al. Jul 2006 A1
20060169647 Doyle et al. Aug 2006 A1
20060196525 Vrtis et al. Sep 2006 A1
20060249400 Bremauer Nov 2006 A1
20060266682 Kennedy et al. Nov 2006 A1
20060283789 Kadlec et al. Dec 2006 A1
20060283808 Kadlec et al. Dec 2006 A1
20070013381 Biberger Jan 2007 A1
20070061051 Maddox Mar 2007 A1
20070086912 Dowling et al. Apr 2007 A1
20070106403 Emery et al. May 2007 A1
20070144911 Pulis Jun 2007 A1
20070154322 Stiles et al. Jul 2007 A1
20070158274 King Jul 2007 A1
20070181439 Wu et al. Aug 2007 A1
20070181498 Kaas Aug 2007 A1
20070215531 Wawrla et al. Sep 2007 A1
20070244576 Potucek et al. Oct 2007 A1
20070248488 Denkewicz Oct 2007 A1
20080039977 Clark et al. Feb 2008 A1
20080142452 Denkewicz et al. Jun 2008 A1
20080173574 Silveri Jul 2008 A1
20080212782 Brettle et al. Sep 2008 A1
20080237148 Dennis et al. Oct 2008 A1
20080264447 Eyal Oct 2008 A1
20080289706 King et al. Nov 2008 A1
20080291040 Cutsforth Nov 2008 A1
20080311898 Benco et al. Dec 2008 A1
20090060269 Rhoads Mar 2009 A1
20090185953 Hallam et al. Jul 2009 A1
20090200245 Steinbrueck et al. Aug 2009 A1
20090208386 Barsky et al. Aug 2009 A1
20090210081 Sustaeta et al. Aug 2009 A1
20090212782 Silveri Aug 2009 A1
20090218296 King et al. Sep 2009 A1
20090243852 Haupt et al. Oct 2009 A1
20090250512 Deck et al. Oct 2009 A1
20090266231 Franzen et al. Oct 2009 A1
20090269240 Tanaka Oct 2009 A1
20090282627 Porat Nov 2009 A1
20090294381 Coffey et al. Dec 2009 A1
20090303055 Anderson et al. Dec 2009 A1
20100015013 Sutton Jan 2010 A1
20100018930 King et al. Jan 2010 A1
20100025337 Yencho Feb 2010 A1
20100032355 Andrews et al. Feb 2010 A1
20100059455 Hsueh et al. Mar 2010 A1
20100096260 Xie et al. Apr 2010 A1
20100096338 De Wet et al. Apr 2010 A1
20100101010 McCague Apr 2010 A1
20100187122 Zolotarsky et al. Jul 2010 A1
20100206815 Garusi et al. Aug 2010 A1
20100209294 Owen et al. Aug 2010 A1
20100237254 Mason et al. Sep 2010 A1
20100250449 Doyle et al. Sep 2010 A1
20100254825 Stiles, Jr. et al. Oct 2010 A1
20100258508 Levy Oct 2010 A1
20100270228 Teichberg Oct 2010 A1
20100313524 Pape et al. Dec 2010 A1
20100313964 Hin et al. Dec 2010 A1
20110009019 Neira et al. Jan 2011 A1
20110010835 McCague Jan 2011 A1
20110048964 Luebke et al. Mar 2011 A1
20110049060 Uy Mar 2011 A1
20110062086 Burns et al. Mar 2011 A1
20110073488 Hsiang Lin Mar 2011 A1
20110121036 Bassett May 2011 A1
20110210268 Dornseifer Sep 2011 A1
20110214500 Cabrera et al. Sep 2011 A1
20110278158 Briggs Nov 2011 A1
20110290707 Porat Dec 2011 A1
20110318237 Woodling et al. Dec 2011 A1
20120051977 Boodaghians et al. Mar 2012 A1
20120078426 Macey Mar 2012 A1
20120327657 Pickard et al. Dec 2012 A1
20130048545 Shatalov et al. Feb 2013 A1
20130098849 Doyle et al. Apr 2013 A1
20130104321 Michelon May 2013 A1
20130105372 Chen et al. May 2013 A1
20130105373 Chen et al. May 2013 A1
20130105403 Chen et al. May 2013 A1
20130146783 Boodaghians et al. Jun 2013 A1
20130313204 Shalon Nov 2013 A1
20140124454 Nichols et al. May 2014 A1
20140200840 Cox et al. Jul 2014 A1
20140202948 Li Jul 2014 A1
20140216926 Shirato et al. Aug 2014 A1
20140263087 Renaud et al. Sep 2014 A1
20140263091 Carter, III et al. Sep 2014 A1
20140266755 Arensmeier et al. Sep 2014 A1
20140326680 Mastio Nov 2014 A1
20140336821 Blaine et al. Nov 2014 A1
20150092055 Scalisi et al. Apr 2015 A1
20150166368 Braunberger Jun 2015 A1
20150268136 Detweiller et al. Sep 2015 A1
20150308091 Foust et al. Oct 2015 A1
20150310634 Babcock et al. Oct 2015 A1
20160042629 Snyder Feb 2016 A1
20160108531 Shanahan et al. Apr 2016 A1
20160122208 Denkewicz et al. May 2016 A1
20160122210 Cosac Albu May 2016 A1
20160131608 Howes, Jr. May 2016 A1
20160178594 Jarvis et al. Jun 2016 A1
20160186357 Stewart et al. Jun 2016 A1
20160259348 Lewis et al. Sep 2016 A1
20160266577 Kerzner Sep 2016 A1
20170066667 Harris Mar 2017 A1
20170092096 Fernandes et al. Mar 2017 A1
20170170979 Khalid et al. Jun 2017 A1
20170203980 Buzaglo et al. Jul 2017 A1
20170206615 Sloop et al. Jul 2017 A1
20170209338 Potucek et al. Jul 2017 A1
20170212530 Potucek et al. Jul 2017 A1
20170249285 Stewart et al. Aug 2017 A1
20170283279 Pelletier et al. Oct 2017 A1
20170336381 Zeevi Nov 2017 A1
20180118581 Miller et al. May 2018 A1
20180130328 Fernandes et al. May 2018 A1
20180160694 Foret Jun 2018 A9
20180163420 Chen et al. Jun 2018 A1
20180224822 Potucek et al. Aug 2018 A1
20180354833 Van Riper et al. Dec 2018 A1
20180373304 Davis et al. Dec 2018 A1
20190087548 Bennett et al. Mar 2019 A1
20190119937 Chen et al. Apr 2019 A1
20190127253 Thomas et al. May 2019 A1
20200369535 Miller et al. Nov 2020 A1
20210026727 Minehan et al. Jan 2021 A1
Foreign Referenced Citations (37)
Number Date Country
2188767 Feb 1995 CN
1147435 Apr 2004 CN
103245766 Aug 2013 CN
104251730 Dec 2014 CN
204165969 Feb 2015 CN
204495401 Jul 2015 CN
107973368 May 2018 CN
3441535 Jun 1986 DE
19951436 May 2000 DE
19921436 Nov 2000 DE
102004029356 Feb 2006 DE
102006013628 Sep 2007 DE
0821514 Jan 1998 EP
1116077 Oct 2003 EP
1600749 Nov 2005 EP
1602628 Dec 2005 EP
1628179 Feb 2006 EP
1913216 Apr 2008 EP
2567713 Mar 2013 EP
2306463 May 1997 GB
2365122 Feb 2002 GB
2467131 Jul 2010 GB
H11-87770 Mar 1999 JP
03012434 Feb 2003 WO
03087501 Oct 2003 WO
03091668 Nov 2003 WO
2004019295 Mar 2004 WO
2004071965 Aug 2004 WO
2005008443 Jan 2005 WO
2005105675 Nov 2005 WO
2009006702 Jan 2009 WO
2009013507 Jan 2009 WO
2009052831 Apr 2009 WO
2011009170 Jan 2011 WO
2014115146 Jul 2014 WO
WO-2015179919 Dec 2015 WO
2016001227 Jan 2016 WO
Non-Patent Literature Citations (102)
Entry
Office Action mailed May 25, 2022, issued in connection with U.S. Appl. No. 17/404,893 (26 pages).
Clearwater In-Line Chlorinator Installation Instructions, Waterway Plastics, 2008 (2 pages).
“Disinfection Equipment” AstralPool archived webpage dated Mar. 21, 2017 <http://web.archive.org/web/20170321051150/http:/www.astralpool.com:80/en/products/swimming-pool/disinfection-equipment-1/> (2 pages).
“Jandy Installation and Operation Manual” Zodiac Pool Systems, Inc. 2010 (15 pages).
“Jandy UltraFlex 2 Installation and Maintenance Guide,” Zodiac Pool Systems, Inc., 2009 (23 pages).
“Neolysis Equipment” AstralPool archived webpage dated Apr. 28, 2017 <http://web.archive.org/web/20170428222051/http:/www.astralpool.com/en/products/swimming-pool/disinfection-equipment-1/neolysis-equipment-4/> (1 page).
“Neolysis LS (1.5-3 g/l) + UV for Private Pools” AstralPool archived webpage dated Jul. 9, 2017 <http://web.archive.org/web/20170709212113/http:/www.astralpool.com/en/products/swimming-pool/disinfection-equipment-1/neolysis-equipment-4/private-pools-neolysis-1/> (2 pages).
“Resilience D Chlorine Generator for small to large size swimming pools,” Magen Eco-Energy webpage, believed to be publically accessible prior to Mar. 21, 2017, https://www.magen-ecoenergy.com/resilience_d/ (3 pages).
“Water Chemistry for Swimming Pools”, North Carolina Department of Environment and Natural Resources, Feb. 2001, retreived from the internet archive at <https://web.archive.org/web/20010207022454/http://www.deh.enr.state.nc.us/ehs/quality/wph.htm> (12 pages).
AstralPool, Neolysis Installation and Maintenance Manual, version dated Aug. 8, 2016 (40 pages).
Atmel Corporation, “Crypto Products Customer Guide” dated Jun. 30, 2009, retrieved from website <https://www.mouser.com/catalog/supplier/library/pdf/atmel_crypto-psguide.pdf> on Mar. 24, 2020 (26 pages).
CMP Powerclean Salt Ultra Installation Instructions and Product Manual (Nov. 2018), retrieved from <https://www.c-m-p.com/pool-products/pool-sanitizers/powerclean-salt-systems/manuals-literature/> (24 pages).
D. W. Egles, “RANGER 1: A Self-Propelled Data Buoy,” OCEANS '85—Ocean Engineering and the Environment, IEEE Conference Record, Nov. 1985, vol. 1, pp. 56-61.
Denkewicz, “The Efficacy of a Combined Approach,” Water Quality Products, Water Disinfection, vol. 12, No. 2, Feb. 2007 (3 pages).
Denkewicz, “UV & Ozone Working Together to Improve Water Quality,” Water Quality Products, May 2008 (2 pages).
Denkewicz, et al., “Co-Generation of UV, Ozone, and Hydroxyl Radicals and its Strategic Use for Aquatic Treatment,” PowerPoint presentation presented at World Aquatic Health Conference in Indianapolis, IN, Oct. 18, 2013 (61 pages).
Hayward “Salt and Swim Installation Quick Start Guide,” earliest known date May 28, 2012 (from waybackmachine.com) (2 pages).
INYO Pools Forum, “UV/Ozone/Salt” discussion thread, Dec. 14, 2016, https://www.inyopools.com/Forum/thread/uv-ozone-salt/ (3 pages).
P. Chen et al., “Fuzzy Diagnosis and Fuzzy Navigation for Plant Inspection and Diagnosis Robot”, Proceedings of 1995 IEEE International Conference on Fuzzy Systems, Mar. 1995, vol. 1, pp. 185-192.
William R. Griffen, “Maintaining Swimming Pools, Spas, Whirlpool Tubs, and Saunas” (2001), retrieved from the internet at <http://www.cleaningconsultants.com/pages/articles/poolsspas.html> (8 pages).
International Search Report of the International Searching Authority mailed Sep. 28, 2012, issued in connection with International Patent Application No. PCT/US12/48888 (4 pages).
Written Opinion of the International Searching Authority mailed Sep. 28, 2012, issued in connection with International Patent Application No. PCT/US12/48888 (6 pages).
International Search Report of the International Searching Authority mailed Oct. 1, 2012, issued in connection with International Patent Application No. PCT/US12/48874 (4 pages).
Written Opinion of the International Searching Authority mailed Oct. 1, 2012, issued in connection with International Patent Application No. PCT/US12/48874 (5 pages).
International Search Report of the International Searching Authority mailed Dec. 19, 2012, issued in connection with International Patent Application No. PCT/US12/48891 (5 pages).
Written Opinion of the International Searching Authority mailed Dec. 19, 2012, issued in connection with International Patent Application No. PCT/US12/48891 (6 pages).
International Preliminary Report on Patentability mailed on Feb. 13, 2014 issued in connection with International Application No. PCT/US12/48874 (7 pages).
International Search Report of the International Searching Authority mailed on May 9, 2014, issued in connection with International Application No. PCT/US14/13390 (3 pages).
Written Opinion of the International Searching Authority mailed May 9, 2014, issued in connection with International Patent Application No. PCT/US2014/013390 (8 pages).
Office Action mailed Mar. 31, 2015, issued in connection with U.S. Appl. No. 13/562,043 (13 pages).
Office Action mailed Apr. 28, 2015, issued in connection with U.S. Appl. No. 13/562,128 (18 pages).
Extended European Search Report dated May 7, 2015, issued by the European Patent Office in connection with European Patent Application No. 12820373.4 (5 pages).
Extended European Search Report dated Jul. 1, 2015, issued by the European Patent Office in connection with European Patent Application No. 12820744.6 (7 pages).
Office Action mailed Aug. 24, 2015, issued in connection with U.S. Appl. No. 13/561,836 (12 pages).
Office Action mailed Oct. 2, 2015, issued in connection with U.S. Appl. No. 13/562,043 (11 pages).
Partial Supplementary European Search Report dated Oct. 26, 2015, issued by the European Patent Office in connection with European Patent Application No. 12820228.0 (6 pages).
Office Action mailed Jan. 21, 2016, issued in connection with U.S. Appl. No. 13/562,128 (19 pages).
Extended European Search Report dated Feb. 17, 2016, issued by the European Patent Office in connection with European Patent Application No. 12820228.0 (13 pages).
Patent Examination Report No. 1, dated May 13, 2016, issued in connection with Australian Application No. 2012290215 (4 pages).
Office Action mailed May 25, 2016, issued in connection with U.S. Appl. No. 13/561,836 (14 pages).
Office Action mailed Jun. 22, 2016, issued in connection with U.S. Appl. No. 13/562,043 (16 pages).
Patent Examination Report No. 1, dated Jul. 29, 2016, issued in connection with Australian Application No. 2012290292 (3 pages).
International Preliminary Report on Patentability mailed on Aug. 2, 2016 issued in connection with International Application No. PCT/US14/13390 (9 pages).
Office Action mailed Sep. 12, 2016, issued in connection with U.S. Appl. No. 13/561,836 (22 pages).
Patent Examination Report No. 1, dated Sep. 16, 2016, issued in connection with Australian Application No. 2012290213 (5 pages).
Office Action mailed Jan. 5, 2017, issued in connection with U.S. Appl. No. 13/562,128 (19 pages).
Office Action mailed Feb. 14, 2017, issued in connection with U.S. Appl. No. 13/562,043 (19 pages).
Patent Examination Report No. 2, dated Jun. 22, 2017, issued in connection with Australian Application No. 2012290292 (5 pages).
Notice of Allowance dated Jun. 28, 2017 issued in connection with U.S. Appl. No. 13/562,128 (8 pages).
Patent Examination Report No. 2, dated Sep. 4, 2017, issued in connection with Australian Application No. 2012290213 (5 pages).
Patent Examination Report No. 3, dated Sep. 14, 2017, issued in connection with Australian Application No. 2012290213 (5 pages).
Notice of Allowance dated Sep. 14, 2017 issued in connection with U.S. Appl. No. 13/562,128 (8 pages).
Communication Pursuant to Article 94(3) dated Oct. 4, 2017, issued by the European Patent Office in connection with European Patent Application No. 12820373.4 (4 pages).
Office Action mailed Oct. 4, 2017, issued in connection with U.S. Appl. No. 13/562,043 (26 pages).
Notice of Allowance dated Nov. 7, 2017 issued in connection with U.S. Appl. No. 13/562,128 (9 pages).
Patent Examination Report No. 1, dated Nov. 17, 2017, issued in connection with Australian Application No. 2017203145 (4 pages).
Office Action mailed Nov. 20, 2017, issued in connection with U.S. Appl. No. 13/561,836 (29 pages).
Office Action mailed May 7, 2018, issued in connection with U.S. Appl. No. 13/562,043 (31 pages).
Invitation to Pay Additional Fees and, Where Applicable, Protest Fee mailed May 8, 2018, issued in connection with International Patent Application No. PCT/US18/23514 (2 pages).
International Search Report of the International Searching Authority mailed on Jul. 5, 2018, issued in connection with International Application No. PCT/US18/23514 (5 pages).
Written Opinion of the International Searching Authority mailed on Jul. 5, 2018, issued in connection with International Application No. PCT/US18/23514 (6 pages).
Notice of Allowance mailed Aug. 24, 2018, issued in connection with U.S. Appl. No. 13/561,836 (13 pages).
Communication pursuant to Article 94(3) EPC dated Sep. 21, 2018, issued by the European Patent Office in connection with European Patent Application No. 12820744.6 (8 pages).
Examination Report No. 1, dated Dec. 21, 2018, issued in connection with Australian Application No. 2017228646 (4 pages).
Office Action mailed Feb. 28, 2019, issued in connection with U.S. Appl. No. 16/223,500 (16 pages).
Office Action mailed May 7, 2019, issued in connection with U.S. Appl. No. 15/889,849 (14 pages).
Communication Pursuant to Article 94(3) dated Jun. 17, 2019, issued by the European Patent Office in connection with European Patent Application No. 12820228.0 (8 pages).
Office Action mailed Jul. 9, 2019, issued in connection with U.S. Appl. No. 16/223,500 (14 pages).
Communication Pursuant to Article 94(3) dated Jul. 11, 2019, issued by the European Patent Office in connection with European Patent Application No. 12820373.4 (4 pages).
Interview Summary mailed Nov. 8, 2019, issued in connection with U.S. Appl. No. 15/889,849 (2 pages).
Examination Report No. 2, dated Nov. 11, 2019, issued in connection with Australian Application No. 2017228646 (4 pages).
Office Action mailed Dec. 2, 2019, issued in connection with U.S. Appl. No. 15/889,849 (15 pages).
Office Action mailed Dec. 27, 2019, issued in connection with U.S. Appl. No. 15/927,412 (16 pages).
Office Action mailed Jan. 22, 2020, issued in connection with U.S. Appl. No. 16/223,500 (21 pages).
Summons to Attend Oral Proceedings issued Apr. 29, 2020, in connection with European Patent Application No. 12820228.0 (9 pages).
Notice of Allowance mailed May 13, 2020, issued in connection with U.S. Appl. No. 15/927,412 (12 pages).
Examination Report dated May 18, 2020, issued by the European Patent Office in connection with European Patent Application No. 12820744.6 (5 pages).
Office Action mailed Jun. 8, 2020, issued in connection with U.S. Appl. No. 15/889,849 (16 pages).
Partial Supplementary European Search Report dated Jul. 17, 2020, issued by the European Patent Office in connection with European Patent Application No. 18772389.5 (11 pages).
Notice of Allowance mailed Aug. 18, 2020, issued in connection with U.S. Appl. No. 15/927,412 (11 pages).
Extended European Search Report dated Oct. 16, 2020, issued by the European Patent Office in connection with European Patent Application No. 18772389.5 (10 pages).
Notice of Allowance mailed Oct. 20, 2020, issued in connection with U.S. Appl. No. 15/889,849 (7 pages).
Notice of Allowance mailed Dec. 14, 2020, issued in connection with U.S. Appl. No. 15/927,412 (8 pages).
Decision to Refuse mailed on Dec. 22, 2020, in connection with European Patent Application No. 12820228.0 (10 pages).
Notice of Allowance mailed Jan. 29, 2021, issued in connection with U.S. Appl. No. 15/927,412 (8 pages).
Notice of Allowance mailed Feb. 25, 2021, issued in connection with U.S. Appl. No. 15/889,849 (7 pages).
Examiner's Answer to Appeal Brief mailed May 24, 2021, in connection with U.S. Appl. No. 16/223,500 (24 pages).
Examination Report dated May 26, 2021, issued in connection with Australian Application No. 2019283929 (4 pages).
Extended European Search Report dated Jul. 9, 2021, issued in connection with European Application No. 21159572.3 (14 pages).
Office Action mailed Dec. 15, 2021, issued in connection with U.S. Appl. No. 17/404,893 (27 pages).
Examination Report dated May 10, 2022, issued in connection with Australian Application No. 2018239360 (3 pages).
European Office Action dated Aug. 8, 2022, issued in connection with European Patent Application No. 18772389.5 (4 pages).
Decision on Appeal mailed Sep. 27, 2022, issued in connection with U.S. Appl. No. 16/223,500 (9 pages).
Office Action dated Jul. 25, 2023, issued in connection with U.S. Appl. No. 16/223,500 (22 pages).
Office Action dated Mar. 2, 2023, issued in connection with U.S. Appl. No. 17/404,893 (26 pages).
Extended European Search Report dated Mar. 7, 2023, issued in connection with European Application No. 22216525.0 (7 pages).
Office Action dated Aug. 9, 2023, issued in connection with U.S. Appl. No. 17/404,893 (25 pages).
European Office Action dated Feb. 23, 2024, in connection with European Patent Application No. 21159572.3 (10 pages).
Canadian Office Action dated Mar. 5, 2024, in connection with Canadian Patent Application No. 3,057,298 (4 pages).
Office Action dated Feb. 15, 2024, issued in connection with U.S. Appl. No. 17/404,893 (28 pages).
Office Action dated Feb. 22, 2024, issued in connection with U.S. Appl. No. 16/223,500 (22 pages).
Examination Report, dated Aug. 16, 2024, issued in connection with Australian Application No. 2023208121 (4 pages).
Related Publications (1)
Number Date Country
20210179454 A1 Jun 2021 US
Provisional Applications (1)
Number Date Country
62474333 Mar 2017 US
Continuations (1)
Number Date Country
Parent 15927412 Mar 2018 US
Child 17187233 US