The present disclosure is generally related to the combining of particulate material and liquid.
Fly ash represents the major by-product of burning coal for power generation. It is collected by scrubbing the effluent gases from the combustion furnaces, and presents a significant disposal issue on account of its volume and composition, which includes significant amounts of inert silicaceous material as well as heavy metals that can be a major environmental hazard if inadequately contained or disposed of. The composition of fly ash is dependent on the type of coal burned, with bituminous coal fly ash comprising mainly silica and iron oxide, alumina, and varying amounts of carbon. Subbituminous coal fly ash, in comparison, has significantly greater silica and alumina content and lower iron oxide levels.
A proportion of fly ash waste generated by power plants is stabilized and incorporated into cement and concrete based products that provide little environmental damage. The bulk of fly ash, however, is deposited in landfill. The ash can be delivered to local landfill sites as a freely flowing pumped slurry, or transported as dry powder to distant sites. Due to the possible toxicity of fly ash, and especially the health hazards of fine ash having a high silica content, it is undesirable to deposit dry ash material directly into a landfill thereby creating uncontrolled wind dispersal of the light-weight substance. It is necessary, therefore, to moisten the ash for distribution at a landfill site.
Landfill sites provide a constant effluent stream known as leach out, or leachate, that is highly variable in composition depending on the nature of the material deposited in the landfill. The water content derives from rainwater passing through the fill, and from the decomposition chemically or microbially of the organic material in the waste. Typically, leachates include dissolved methane, carbon dioxide, organic acids, aldehydes, alcohols, and simple sugars derived from carbonaceous sources, as well as iron aluminum, zinc, and ammonia, heavy metals leached into the liquid due to the initial acidity of the leachate, PCB's, dioxanes and the like.
While older and poorly regulated landfills may discharge leachate into the surroundings where it can readily enter the groundwater, more typically the leachate is drained from the landfill and stored before treatment to reduce the environmental impact, especially to the water supply. There would be advantages, therefore, in being able to reuse the leachate for redeposit back into the landfill, reducing treatment costs.
Systems, apparatuses and processes involved with hydrating particulate material are provided. In this regard, an exemplary embodiment of a process comprises: delivering a pressurized stream of dry particulate material; spreading the stream of dry particulate material outwardly from an axis; spraying a pressurized aqueous liquid into the spread dry particulate material such that the particulate material is hydrated; moving the hydrated particulate material along a helical path; increasing the velocity of the hydrated particulate material; and directing the hydrated particulate material to a depository.
An exemplary embodiment of a particulate material hydrating apparatus comprises: a housing having a side wall with an upper end and a lower end, the housing defining, in series, an inlet, a hydration section, a mixing chamber and an accelerating chamber; the inlet being located at the upper end of the housing, the inlet being operative to admit a particulate material into the hydration section for movement through the housing; a conical spreader positioned within the housing and located toward the upper end of the hydration section in coaxial alignment with the inlet, the conical spreader being operative to spread particulate material received through the inlet outwardly therefrom; a first liquid spray nozzle with a nozzle outlet positioned within the hydration section such that the nozzle outlet is oriented between the conical spreader and the mixing chamber, the first liquid spray nozzle being operative to discharge a liquid spray toward the particulate material as the particulate material moves downstream from the conical spreader; a first vane positioned within the mixing chamber, the first vane being operative to impart a rotation to the particulate material after being hydrated as the hydrated particulate material moves downstream from the hydration section; the accelerating chamber being operative to increase flow velocity of the hydrated particulate material; and an outlet communicating with the accelerating chamber and being operative to deliver hydrated particulate material received from the accelerating chamber.
Another example of the process of hydrating a particulate material is collecting leachate from a landfill and using the leachate as or in a hydrating liquid for hydrating fly ash and similar particulate matter. The hydrated material may be deposited in a landfill, or re-deposited in the landfill from which the leachate was collected.
Further aspects of the present disclosure will be more readily appreciated upon review of the detailed description of its various embodiments, described below, when taken in conjunction with the accompanying drawings.
The details of some exemplary embodiments are set forth in the description below. Other features and/or advantages of the disclosure may be and/or may become apparent to one of skill in the art upon examination of the following description, drawings, examples and claims. It is intended that all such features and/or advantages be included within this description, be within the scope of the present disclosure, and be protected by the accompanying claims.
Before several exemplary embodiments are described in greater detail, it is to be understood that this disclosure is not limited to the particular embodiments described, and as such may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting, since the scope of the present disclosure will be limited only by the appended claims.
As will be apparent to those of skill in the art upon reading this disclosure, each of the individual embodiments described and illustrated herein has discrete components and features which may be readily separated from or combined with the features of any of the other several embodiments without departing from the scope or spirit of the present disclosure.
It must be noted that, as used in the specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to “a support” includes a plurality of supports. In this specification and in the claims that follow, reference will be made to a number of terms that shall be defined to have the following meanings unless a contrary intention is apparent.
As used herein, the following terms have the meanings ascribed to them unless specified otherwise. In this disclosure, “comprises,” “comprising,” “containing” and “having” and the like can have the meaning ascribed to them in U.S. patent law and can mean “includes,” “including,” and the like; “consisting essentially of” or “consists essentially” or the like. “Consisting essentially of” or “consists essentially” or the like, when applied to process and compositions encompassed by the present disclosure have the meaning ascribed in U.S. patent law and the term is open-ended, allowing for the presence of more than that which is recited so long as basic or novel characteristics of that which is recited is not changed by the presence of more than that which is recited, but excludes prior art embodiments.
It should be emphasized that the embodiments of the present disclosure, particularly, any “preferred” embodiments, are merely possible examples of the implementations, merely set forth for a clear understanding of the principles of the disclosure. Many variations and modifications may be made to the described embodiments without departing substantially from the spirit and principles of the disclosure. All such modifications and variations are intended to be included herein within the scope of this disclosure and protected by the following claims.
The present disclosure provides systems, apparatuses and processes involved with hydrating particulate material. In some embodiments, the particulate material, flowing in a gas stream, is combined with a liquid, whereby the liquid may contact and coat the particles to increase their density and to promote aggregation into larger bodies. Dispersal of the hydrated and/or aggregated particles results in reduced fine particle dispersion that may represent a hazard to operators or the environment. In some embodiments, the hydration of the fine particulate material known as fly ash that is a by-product of the process for burning coal for energy can be accomplished.
Briefly described, embodiments of this disclosure, among others, encompass an apparatus for the hydration of high volumes of pressurized dry finely powdered materials. In an exemplary apparatus, hydration is achieved by passing a pressurized stream of dry powdered or particulate material through a liquid spray and through a mixing chamber that imparts a vortex motion to the stream, ensuring adequate mixing of the liquid and the particles. The product that exits the hydration apparatus has increased density due to hydration and aggregation of the fine particulate material, and resists uncontrolled dispersal when deposited onto a site such as a landfill.
An exemplary embodiment of a system for hydration of a particulate material comprises a system for delivery of the fine dry particulate material under pressure to a hydration apparatus, a source of a pressurized aqueous liquid deliverable to the hydration apparatus, and the hydration apparatus. In some embodiments, such a system may further comprise a depositor for receiving the hydrated material for storage or transport to a site distant from the hydrating apparatus.
Another embodiment involves a hydrating apparatus for mixing a dry particulate material with a liquid, preferably a liquid having flow characteristics similar to water, to generate a moist product that may be dispersed in a controlled manner, but which does not flow freely such as in a stream of liquid. In some embodiments, the hydrating apparatus comprises a spreader to ensure that the incoming particulate material is well distributed in a thinner stream throughout the apparatus, liquid spray nozzles for delivering the aqueous liquid into the thin particulate stream, and a mixing mechanism that generates a rotary motion to the particulate material and the liquid spray to ensure thorough mixing and moistening of the material. The flow rates of the particulate material and the liquid spray may be adjusted to provide a moist aggregated product substantially free of dry powder or free liquid.
Various ones of the systems, apparatuses and processes may be used to moisten, for example, fly ash for deposit in a landfill in a controlled manner. However, such may be readily adapted for use with other dry powder material and liquid.
In some embodiments, the spreading of the particulate material prior to the wetting of the particulate material assures wetting a greater volume of the particulate material prior to the following steps of the process.
In some embodiments, the lack of moving components ensures a lengthy service life with minimal maintenance other than simple cleaning. By regulating the flows of the input particulate material and the liquid flow, the moisture content of the output product may be adjusted to the requirements of the operator. Because of the pressurized nature of the input and output streams, the moistened product may be ejected for direct deposit at a selected site, or delivered to a transport container for delivery to the final site.
An exemplary embodiment of a particulate material hydrating apparatus for the hydration of bulk quantities of a dry particulate material, and which provides a hydrated mass that is not readily and undesirably dispersed in an uncontrolled manner will now be described in greater detail. The low density of many powders, such as, for example talc, china clay, fly ash and the like results in a high tendency to be dispersed inadvertently. With particulate material such as fly ash, which may include high levels of environmentally undesirable contaminants, disposal processes should keep uncontrolled spread and dispersal by such as wind to a minimum.
Material such as fly ash is most economically transported from a site of generation, such a coal-fired power plant to a landfill or other disposal site, as a dry powder and not in a bulkier and heavier hydrated form that would otherwise increase transport costs. An exemplary embodiment of a hydrating apparatus provides a means of hydrating a dry particulate material to a dampness level that increases the density for controlled dispersal, while not so wet or hydrated that undesirable levels of water are consumed that may damage a landfill or lead to excessive levels of contaminating leach out (“leachate”) from a landfill. A desirable level of hydration of fly ash, for example, may produce a product that may retain shape when compressed, but still have a particulate composition similar to that of dampened sand. The exemplary embodiment of hydrating apparatus (i.e., apparatus 1 of
A particulate material delivery inlet 121 is located at the upper end 60 of the housing 11 for admitting a particulate material into the hydration section 13 for movement downwardly through the housing 11. In this embodiment, the inlet 121 includes a locking feature 125 (e.g., a flanged fitting) for securely attaching the delivery pipe 23 shown in
A material spreader 122 (such as a conical spreader of
At least one liquid spray nozzle 131 traverses the side wall 12 such that at least the outlet of the nozzle extends through the side wall of the housing, with the nozzle being preferably located below the spreader 122 and above the mixing chamber 14. Nozzle 131 is directed so as to discharge a liquid spray towards the longitudinal axis 40 of the housing 11. As shown in
It is further contemplated that a preferred configuration of the hydration chamber 13 may include a plurality of spray nozzles 131, such as four nozzles, each of which is directed toward the axis 40, thereby generating a multiple spray pattern that can provide significant coverage of the cross-section of the tubular housing 11, as shown, for example, in
As shown in
Vanes 141 of the depicted embodiment are attached at their lower ends to the side wall 12 of the housing 11. The opposite, or upper, end of the elongated vanes 141 are attached to a cross-member 142 that, in this embodiment, extends from the side wall 12 radially inwardly toward the longitudinal axis of the mixing chamber 14.
Immediately below, and in communication with the mixing chamber 14, is accelerating chamber 15, which is defined by a converging side wall of the housing 11. Accelerating chamber 15 is operative to increase the flow velocity of the hydrated particulate material descending from the mixing chamber 14.
Downstream of the accelerating chamber 15, the hydrating apparatus 1 further comprises an output tube 17 that is attached to the lower end 61 of the housing 11. In the embodiment depicted in
Referring now to
As illustrated in the exploded view of
In this embodiment, the hydration section 213 comprises a cylindrical side-wall 233 that extends between an upper end 235 and a lower end 236. A conical spreader 222 is positioned at the upper end 235 of the hydration section, and is coaxially aligned with inlet delivery port 221. As shown in
At least one liquid spray nozzle 231 traverses the side wall 233 of the hydration section, and is oriented to deliver a pressurized liquid spray towards the longitudinal axis 240 of the housing 211. The at least one liquid spray nozzle 231 is configured to securely engage with a delivery tube for delivering a pressurized aqueous liquid to the spray nozzle 231. A preferred configuration includes four spray nozzles 231, each of which directs a spray of liquid towards the axis 240, thereby generating a four spray pattern that can provide significant coverage of the cross-section of the housing, as shown, for example in
A third flange 330 disposed at the lower end 236 of the hydration section 213 is configured for securing to a fourth flange 237 of the mixing chamber 214. In this embodiment, bolts (e.g., bolts 236 of
As shown in
Accelerating chamber 215, defined by a converging conical side wall of the housing, is positioned downstream of the mixing chamber 214. Accelerating chamber 215 is operative to increase the flow velocity of the hydrated particulate material descending from the mixing chamber 214.
An output tube 217 is attached to the lower end 261 of the housing 11, and includes an outlet 218 for discharging the hydrated particulate material 219 from the apparatus.
A hydrating apparatus may be constructed of any material able to withstand the abrasive action of the input pressurized particulate material stream, and of the material as it passes through the apparatus. It is contemplated that the conical spreader, the elongated vanes and the outlet may be subjected to significant abrasion. Accordingly, when the particulate material is a mineral such as fly ash, pumice, kaolin or the like, the apparatus is preferably constructed of a material such as, but not limited to, steel, hardened steel, stainless steel, ceramic coated steel, and the like. If the particulate material is soft, such as a talc or an organic or food product, it is contemplated that the hydration apparatus alternatively may be made of material such as a plastic that is able to withstand the pressure and abrasion that even these softer materials may impart to the apparatus. In addition to resistance to wear, the walls of the housing should be sufficiently thick to withstand the internal pressure (e.g., at least about 15 psi) during the operation of the hydration apparatus.
Another aspect of the present disclosure encompasses an integrated system for the delivery, hydration, and disposal of a hydrated particulate material. Referring now to
The particulate material delivery system 2 can be any assemblage of components that can supply a dry stream of particulate material 24 to the inlet 121 of the hydrating apparatus 1. For example, but not limiting, the particulate material delivery system 2 may comprise a hopper vehicle 21 capable of being pressurized to withstand pressure of at least 15 psi, and a pressure hose for delivery of the material 24 to a separate storage container 22 or, optionally, directly communicating with the inlet 121 of the hydrating apparatus 1. It is anticipated that pressure may be applied to the top of the particulate material 24 while in a vehicle hopper 21, but that the material 24 may exit the hopper from below. Such systems are well known and may be found on road and rail vehicles used for transport of particulate material. Depending on the amount of particulate material 24 that is to be hydrated, it may be advantageous to deliver the material 24 from the delivery vehicle 21 to a pressurized storage container 22 (e.g., a silo) operably connected to the inlet 121 of the hydrating apparatus 1.
In operation, top pressure may applied to the particulate material contents of the delivery vehicle 21, and/or the receiving storage container 22 to force said contents along a pressure hose securely attached to inlet 121 of the hydrating apparatus 1. One suitable applied pressure has been found to be about 15 psi, although it is contemplated that this pressure may be varied depending on the nature (density, dryness, etc) or volume of the particulate material 24 to be hydrated.
The system depicted in
The outlet 18 of the hydrating apparatus 1 may be directed to deliver a stream of hydrated particulate material 19 to a depository 4. The depository 4 for use in the system of the disclosure may be, but is not limited to, a trench in the ground, a receiving tank, or a receiving delivery vehicle for removal of the hydrated material to a distant location. Alternatively, the pressurized stream may be directed to spread to an area immediately adjacent the hydrating apparatus.
One example of the use of a particulate material hydrating system is the hydration of fly ash delivered from a coal-fired power plant for disposal in a landfill. The material may be transported as a dry powder in, for example, railroad bulk powder trucks holding about 40 tons of material each. The railroad trucks may be brought close to the hydrating apparatus, connected to a storage container or directly to the hydrating apparatus, and pressurized to discharge the dry material. Alternatively, the material may be off-loaded from the railroad vehicles to road hopper trucks for delivery of the particulate material to the site of hydration.
When provided to the hydrating apparatus 1, the fly ash may be pressurized by top pressure, and the material flows as a stream into the hydrating apparatus 1. The amount of material treated per minute will depend on the pressure applied and the physical characteristics of the particles, and the size of the delivery conduits. The dimensions of the hydrating apparatus 1 may be selected according to the amount of material required to be hydrated. A useful top pressure applied to the bulk particulate material has been found to be about 15 psi.
In operation, it is preferred that the aqueous liquid supply to the spray nozzles 131 of the hydrating apparatus 1 be engaged before delivery of the dry particulate material. When the applied top pressure of the incoming particulate material is about 15 psi, a useful liquid pressure has been found to be about 60 psi. However, it is anticipated that the liquid pressure, and the particulate matter flow rates, will be adjusted to achieve a desired degree of hydration of the material. The quality of the hydration of the particulate material may be judged, for example, by observing the output 19 from the hydrating apparatus 1. If there is insufficient hydration, due to an excessive top pressure in the material storage container 22, or too low liquid flow rate, this may be observed as dry particulate material blowing from the outlet 18, in which case the liquid flow rate may be increased. Alternatively, fluid discharging from the outlet 18 will indicate that the spray liquid flow was too great for the particulate flow applied, and the liquid flow rate may be reduced accordingly. It is anticipated that it is more convenient for the system operator to regulate the flow of liquid 35 to the spray nozzles 131, than to reduce or increase the top pressure to the particulate material in the storage container or the delivery vehicles.
An embodiment of a hydration apparatus may be useful for hydrating a particulate material to produce an aggregated material with sufficient moisture content to increase the density of the material, resulting in aggregation of the particles, and thereby allowing distribution of the material without undesirable dispersal in an uncontrolled manner, as is the case with dry powdered particulate material. Accordingly, an exemplary embodiment of a process of hydrating a particulate material, comprises the steps of: (i) delivering a pressurized stream of dry particulate material into a mixing chamber (e.g., by passing the material through a particulate matter inlet port); (ii) spreading the stream of dry particulate material outwardly (e.g., radially outwardly from a longitudinal axis of the mixing chamber) within the mixing chamber; (iii) spraying a pressurized aqueous liquid into the spread dry particulate material in the mixing chamber, whereby the particulate material is hydrated; (iv) moving the hydrated particulate material along a helical path within the mixing chamber; (v) moving the hydrated particulate material from the mixing chamber (e.g., through an accelerating chamber) to increase the velocity of the particulate material and the liquid; and (vi) directing the hydrated particulate material to a depository.
In some embodiments, the step of directing the hydrated particulate material to the depository may comprise directing a stream of the hydrated particulate material through the air to a landfill.
In some embodiments, the process involves an embodiment of a hydration apparatus (such as an embodiment depicted herein). In such an embodiment, the step of spreading the stream of particulate material outwardly within the mixing chamber may comprise directing the particulate material delivered from the particulate matter inlet of the hydration apparatus toward the apex of a conical spreader. The incoming material is distributed radially outwards toward the walls of the apparatus, downwardly through the hydration chamber, and into a spray of aqueous liquid.
In some embodiments, the step of spraying a pressurized aqueous liquid into the spread particulate material in the mixing chamber may comprise directing the liquid into the particulate material as the particulate material is being spread by a conical spreader.
To deliver the dry particulate material from the delivery system 2 to the hydration apparatus 1, it may be advantageous to apply a pressure to the top of the hoppered or siloed material. Since the material, before entering the apparatus will preferably be in a dry state and of fine particle size, the material should be free-flowing and therefore exit the delivery system as a pressurized stream. In some embodiments of the process, therefore, a desired pressure of the particulate material, as it enters the hydration apparatus is between about 10 psi and about 20 psi. This pressure to be applied, however, should be sufficient to force hydrated material, formed after passage through the spray system of the hydrating apparatus, to exit from the apparatus as a pressurized stream. In some embodiments, the pressure of the stream and of the top pressure applied to the stored dried material is about 15 psi.
In some embodiments, the pressure of the aqueous liquid delivered to the at least one liquid spray nozzle is adjusted whereby the hydrated particulate material is delivered from the hydrating apparatus in a gas/hydrated particulate material stream.
The process may be applied to other dry particulate materials, but the process is particularly useful for the hydration of dry fly ash before depositing in a landfill. Fly ash is one of the residues generated in the combustion of coal and is generally captured from the chimneys of coal-fired power plants. Depending upon the source and makeup of the coal being burned, the components of fly ash vary considerably, but all fly ash usually includes substantial amounts of silicon dioxide (SiO2) (both amorphous and crystalline) and calcium oxide (CaO). Toxic constituents usually include heavy metals such as arsenic, beryllium, boron, cadmium, chromium, chromium VI, cobalt, lead, manganese, mercury, molybdenum, selenium, strontium, thallium, and vanadium, along with toxic organic substances such as dioxins and PAH compounds.
In the U.S.A., fly ash is generally stored at coal power plants or placed in landfills while about 43 percent is recycled, by use as supplements to Portland cement in concrete production, or is used in the synthesis of geopolymers and zeolites.
Fly ash particles are generally spherical in shape and range in size from 0.5 μm to 100 μm. They consist mostly of silicon dioxide (SiO2), which is present in two forms: amorphous, which is rounded and smooth, and crystalline, which is sharp, pointed and hazardous; aluminum oxide (Al2O3) and iron oxide (Fe2O3). Fly ashes are generally highly heterogeneous, consisting of a mixture of glassy particles with various identifiable crystalline phases such as quartz, mullite, and various iron oxides.
Where fly ash is stored in bulk, it is usually stored wet rather than dry, so as to control a dust hazard. These impoundments are typically large and stable for long periods, but any breach of their dams or bunding will be rapid and on a massive scale.
It is, however, further considered within the scope of the present disclosure for the process of hydration (such as those using a disclosed apparatus) to be applicable to any fine (about 0.5 μm to about 100 μm) particulate material that needs to be hydrated. Such particulate material includes, but is not limited to, fly ash, kaolin (china clay), pumice, and the like.
It is further contemplated that such a process may incorporate the use of any aqueous liquid. A particularly advantageous aqueous liquid for use in the process of the disclosure is landfill leachate. This liquid is the result of decomposition within a landfill and leaching of rainwater through the fill, and collects and comprises ammonia, refuse and microbial breakdown products and any other water-soluble compounds deposited in the landfill or produced therein. Accordingly, use may be made of the contaminated water supply usually present at a landfill, and which may be combined with such as fly ash that is to be deposited on the landfill.
It should be emphasized that the embodiments of the present disclosure, particularly, any “preferred” embodiments, are merely possible examples of the implementations, merely set forth for a clear understanding of the principles of the disclosure. Many variations and modifications may be made to the above-described embodiment(s) of the disclosure without departing substantially from the spirit and principles of the disclosure. All such modifications and variations are intended to be included herein within the scope of this disclosure, and the present disclosure and protected by the following claims.
This utility application claims the benefit of and priority to U.S. Provisional Patent Application 61/157,330, filed on Mar. 4, 2009, which is incorporated by reference herein in its entirety.
Number | Date | Country | |
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61157330 | Mar 2009 | US |