Systems, devices, and methods for starting plasma

Information

  • Patent Grant
  • 11963287
  • Patent Number
    11,963,287
  • Date Filed
    Monday, September 20, 2021
    2 years ago
  • Date Issued
    Tuesday, April 16, 2024
    a month ago
Abstract
Some embodiments herein are directed to devices and methods for automatically starting a plasma utilizing a wand. In some embodiments, the wand may be used to start a plasma in a plasma torch such as, for example, a microwave plasma torch or an induction plasma torch, as discussed below. The wand may comprise an elongate, hollow wand member comprising a closed distal end, a proximal end, and one or more apertures extending from a hollow interior of the wand member to an exterior surface of the wand member; and an elongate wire member positioned within the hollow interior of the wand member and extending along at least a portion of a length of the wand member, wherein the wire member is configured to be placed in operable communication through the aperture with a power source, such that the power source can be activated to in turn start the plasma within the plasma torch. The plasma torches discussed herein may be used in various applications including, for example, high volume synthesis of advanced materials such as nano-materials, micro-powders, coatings, alloy compositions for additive manufacturing.
Description
BACKGROUND
Field of the Invention

The disclosure herein relates to devices and methods for starting a plasma and, in particular, to devices and methods for automatically starting a plasma.


Description of the Related Art

Plasma torches generate and provide high temperature directed flows of plasma for a variety of purposes. The two main types of plasma torches are induction plasma torches and microwave plasma torches. Although there are several distinct differences between these two types of torches, they both provide high temperature plasmas.


These high temperature plasmas may, for example, enable processing of a variety of materials that are exposed to or fed into the plasma. One such type of processing is taking one or more materials of a particular size and shape and, after exposing or feeding it into the plasma, process or transform the one or more materials into a different size or shape.


Initially igniting or “starting” a plasma typically is done manually by exposing a particular material into the plasma torch which sparks to ignite the plasma. This procedure can be dangerous to an operator and typically contaminates the process with excess material from the material used to create the spark.


It therefor would be desirable to provide a method and device for overcoming the problems with existing processes.


SUMMARY

For purposes of this summary, certain aspects, advantages, and novel features of the invention are described herein. It is to be understood that not all such advantages necessarily may be achieved in accordance with any particular embodiment of the invention. Thus, for example, those skilled in the art will recognize that the invention may be embodied or carried out in a manner that achieves one advantage or group of advantages as taught herein without necessarily achieving other advantages as may be taught or suggested herein.


Some embodiments herein are related to a device for starting a plasma of a plasma torch, the device comprising: an elongate, hollow wand member comprising a closed distal end, a proximal end, and one or more apertures extending from a hollow interior of the wand member to an exterior surface of the wand member; and an elongate wire member comprising one or more wires positioned within the hollow interior of the wand member and extending along at least a portion of a length of the wand member, wherein the wire member is configured to be placed in operable communication through the aperture with a power source, such that the power source can be activated to in turn start the plasma within the plasma torch, wherein the wire member is configured to remain substantially within the hollow interior of the wand member when the plasma is started.


In some embodiments, the power source comprises a microwave generator, and wherein a length of the wire member comprises ¼ of a wavelength or longer of a microwave generated by the microwave generator.


In some embodiments, the wand member comprises one aperture. In some embodiments, the wand member comprises between 1 and 100 apertures. In some embodiments, the wire member comprises one wire. In some embodiments, the wire member comprises more than one wire. In some embodiments, wand member comprises quartz. In some embodiments, the wand member comprises a microwave-transparent material. In some embodiments, the wire member comprises a metal. In some embodiments, the wire member comprises a metal alloy. In some embodiments, the wand member comprises an open proximal end.


In some embodiments, at least one of the one or more apertures is located proximate the closed distal end of the wand member. In some embodiments, the wire member extends at least from a position proximate the closed distal end to a position outside of the proximal end. In some embodiments, the wand member comprises a plurality of apertures proximate the closed distal end of the hollow wand member. In some embodiments, the wire member is fused to the hollow interior of the wand member. In some embodiments, the wand member is in operable communication with a motor. In some embodiments, the motor is configured to impart motion on the wand member to place the wand member within the plasma torch, such that the wire member is configured to be placed in operable communication through the aperture with the power source and the heated gas flow. In some embodiments, the motor is configured to move the device into a gas flow of the plasma torch. In some embodiments, moving the device into the gas flow places the wire member in operable communication through the aperture with the power source. In some embodiments, the motor is configured to move the device out of the gas flow of the plasma torch. In some embodiments, the motor is in operable communication with a control unit, the control unit programmed to provide one or more control signals to the motor. In some embodiments, the control unit is configured to transmit an instruction to the power source to start the plasma of the plasma torch. In some embodiments, the wand member is in operable communication with a limit switch comprising an actuator for determining a location of the wand member.


Some embodiments herein are related to a system for starting a plasma of a plasma torch, the system comprising: an elongate, hollow wand member comprising a closed distal end, a proximal end, and one or more apertures extending from a hollow interior of the wand member to an exterior surface of the wand member; an elongate wire member positioned within the hollow interior of the wand member and extending along at least a portion of a length of the wand member, wherein the wire member can be placed in operable communication through the aperture with a power source and a heated gas flow, such that the power source can be activated to start the plasma within the plasma torch; a motor in operable communication with the wand member, the motor configured to impart motion on the wand member to place the wand member within the plasma torch, such that the wire member is configured to be placed in operable communication through the aperture with the power source and the heated gas flow; and a control unit in communication with the motor and programmed to provide one or more control signals to the motor.


In some embodiments, the power source comprises a microwave generator, and wherein a length of the wire member comprises ¼ of a wavelength or longer of a microwave generated by the microwave generator. In some embodiments, the wand member comprises one aperture. In some embodiments, the wand member comprises between 1 and 100 apertures. In some embodiments, the wire member comprises one wire. In some embodiments, the wire member comprises more than one wire. In some embodiments, the wand member comprises quartz. In some embodiments, the wand member comprises a microwave-transparent material. In some embodiments, the wire member comprises a metal. In some embodiments, the wire member comprises a metal alloy. In some embodiments, the wand member comprises an open proximal end. In some embodiments, at least one of the one or more apertures is located proximate the closed distal end of the wand member. In some embodiments, the wire member extends at least from a position proximate the closed distal end to a position outside of the proximal end. In some embodiments, the wand member comprises a plurality of apertures proximate the closed distal end of the hollow wand member. In some embodiments, the wire member is fused to the hollow interior of the wand member.


In some embodiments, the system further comprises a limit switch comprising an actuator for determining a location of the wand member. In some embodiments, the system further comprises the plasma torch.


Some embodiments herein relate to a method of automatically starting a plasma of a plasma torch, the method comprising: transmitting, via a control unit, an instruction to start the plasma of the plasma torch; moving, using a motor in communication with the control unit, a device for starting the plasma into a gas flow of the plasma torch, the device comprising: an elongate, hollow wand member, the wand member comprising a closed distal end, a proximal end, and one or more apertures extending from a hollow interior of the wand member to an exterior surface of the wand member; and an elongate wire member positioned within the hollow interior of the wand member and extending along at least a portion of a length of the wand member, wherein moving the device into the gas flow places the wire member in operable communication through the aperture with a power source; and activating the power source to start the plasma within the plasma torch.


In some embodiments, the method further comprises moving, using the motor, the device out of the gas flow of the plasma torch. In some embodiments, the power source comprises a microwave generator, and wherein a length of the wire member comprises ¼ of a wavelength or longer of a microwave generated by the microwave generator. In some embodiments, the wand member comprises one aperture. In some embodiments, the wand member comprises between 1 and 100 apertures. In some embodiments, the wire member comprises one wire. In some embodiments, the wire member comprises more than one wire. In some embodiments, the wand member comprises quartz. In some embodiments, the wand member comprises a microwave-transparent material. In some embodiments, the wire member comprises a metal. In some embodiments, the wire member comprises a metal alloy. In some embodiments, the wand member comprises an open proximal end. In some embodiments, at least one of the one or more apertures is located proximate the closed distal end of the wand member. In some embodiments, the wire member extends at least from a position proximate the closed distal end to a position outside of the proximal end. In some embodiments, the wand member comprises a plurality of apertures proximate the closed distal end of the hollow wand member. In some embodiments, the wire member is fused to the hollow interior of the wand member.





BRIEF DESCRIPTION OF THE DRAWINGS

The drawings are provided to illustrate example embodiments and are not intended to limit the scope of the disclosure. A better understanding of the systems and methods described herein will be appreciated upon reference to the following description in conjunction with the accompanying drawings, wherein:



FIG. 1 illustrates an embodiment of a top feeding microwave plasma torch that can be used in the production of powders, according to embodiments of the present disclosure.



FIGS. 2A-2B illustrate embodiments of a microwave plasma torch that can be used in the production of powders, according to a side feeding hopper embodiment of the present disclosure.



FIG. 3 illustrates an embodiment of an autostrike wand mechanism for striking a microwave plasma torch, according to embodiments of the present disclosure.



FIG. 4 illustrates a cross-sectional view of an embodiment of an autostrike wand mechanism for striking a microwave plasma torch, according to embodiments of the present disclosure.



FIG. 5 illustrates an embodiment of a motor and friction roller mechanism for controlling the motion of an autostrike wand, according to embodiments of the present disclosure.



FIG. 6 illustrates an embodiment of an upper limit switch mechanism for use in a microwave plasma torch with an autostrike wand, according to embodiments of the present disclosure.



FIG. 7 illustrates an embodiment of an autostrike wand for striking a plasma torch, according to embodiments of the present disclosure.



FIG. 8 illustrates another embodiment of an autostrike wand for striking a plasma torch, according to embodiments of the present disclosure.





DETAILED DESCRIPTION

Although certain preferred embodiments and examples are disclosed below, inventive subject matter extends beyond the specifically disclosed embodiments to other alternative embodiments and/or uses and to modifications and equivalents thereof. Thus, the scope of the claims appended hereto is not limited by any of the particular embodiments described below. For example, in any method or process disclosed herein, the acts or operations of the method or process may be performed in any suitable sequence and are not necessarily limited to any particular disclosed sequence. Various operations may be described as multiple discrete operations in turn, in a manner that may be helpful in understanding certain embodiments; however, the order of description should not be construed to imply that these operations are order dependent. Additionally, the structures, systems, and/or devices described herein may be embodied as integrated components or as separate components. For purposes of comparing various embodiments, certain aspects and advantages of these embodiments are described. Not necessarily all such aspects or advantages are achieved by any particular embodiment. Thus, for example, various embodiments may be carried out in a manner that achieves or optimizes one advantage or group of advantages as taught herein without necessarily achieving other aspects or advantages as may also be taught or suggested herein.


Certain exemplary embodiments will now be described to provide an overall understanding of the principles of the structure, function, manufacture, and use of the devices and methods disclosed herein. One or more examples of these embodiments are illustrated in the accompanying drawings. Those skilled in the art will understand that the devices and methods specifically described herein and illustrated in the accompanying drawings are non-limiting exemplary embodiments and that the scope of the present invention is defined solely by the claims. The features illustrated or described in connection with one exemplary embodiment may be combined with the features of other embodiments. Such modifications and variations are intended to be included within the scope of the present technology.


Igniting, “striking” or “starting” a plasma previously was done manually by exposing a particular material, usually metal, into the plasma torch which sparks to ignite the plasma. Sometimes, a microwave plasma torch with a microwave generator may be initialized at low power, followed by insertion, by a human operator, of a metal material through a port of the plasma torch, into the gas flow of the plasma torch. The metal material may initiate a spark, which ignites the plasma torch. Upon ignition, the human operator may manually withdraw the metal material through the port. This procedure can be dangerous to an operator and typically contaminates the process with excess material from the metal material used to create the spark. This contamination can affect the temperature and processing conditions within the plasma torch, as well as the quality of a final product produced using the plasma torch. Thus, novel methods and devices for overcoming the problems with existing plasma striking processes are desired.


Some embodiments herein are directed to devices and methods for automatically starting a plasma utilizing a wand. In some embodiments, the wand may be used to start a plasma in a plasma torch such as, for example, a microwave plasma torch or an induction plasma torch, as discussed below. The plasma torches discussed herein may be used in various applications including, for example, high volume synthesis of advanced materials such as nano-materials, micro-powders, coatings, alloy compositions for additive manufacturing. For example, the auto-strike wands discussed herein may be used in UniMelt® systems by 6K Inc., with an address of 32 Commerce Way, North Andover, Massachusetts, 01845. Such systems are capable of continuous-flow production of advanced materials with high volume, low porosity, and enhanced sphericity to comparable systems. Such systems function by combining highly reactive ions with designed chemistries under high heat to create a continuous-flow, high-throughput production environment. In some embodiments, such systems may operate at atmospheric pressure. Microwave-engineered plasma provides a thermal production zone of extreme uniformity, such that each particle is introduced to the same thermal kinetics.


In some embodiments, the wand may be used to automatically start a plasma such that an operator is not required to manually introduce a material into a torch flow in order to start the plasma. Instead, the wand may be introduced into a plasma torch using a remote process and/or a controller. After ignition of the plasma, a stable and continuous operation of the plasma is possible and the plasma torch can be used for various applications, including production of powders or other advanced materials. As such, the embodiments herein utilize a plasma physics theory to implement a plasma-starting mechanism, which provides a high efficiency, high success-rate, and long-lasting plasma starting structure.


In some embodiments, the wand may comprise quartz and/or other microwave-transparent materials, such as glasses or alumina. In some embodiments, the wand may also comprise an enclosed antenna comprising one or more metal wires. In some embodiments, this structure contains the wire, which minimizes the risk of having the antenna slip free. In some embodiments, the metal antenna may be fused to an interior surface of the wand to keep the antenna fixed in place. The length of the metal wire may also be varied. For example, in some embodiments, the metal wire may extend the entire length of the wand. Alternatively, in some embodiments, the metal wire may extend only partially along the length of the wand. For example, the metal wire may be provided only at the location of one or more apertures in the wand, as described in detail below. In some embodiments, the antenna length may correspond to a wavelength of an electromagnetic wave used in the microwave plasma torch. For example, the antenna length may comprise about ¼ the length of the wavelength of the microwave of the plasma torch, or a multiple of ¼ the length of the wavelength. In some embodiments, the antenna length may comprise about ⅛, about ¼, about ⅜, about ½, about ¾, about ⅞, about 1 wavelength or longer than the microwave of the plasma torch.


The wand may comprise one or more apertures, cuts, or slots (hereinafter “apertures”), which extend from an exterior surface of the wand to the one or more metal wires. In some embodiments, the single or multiple wire antenna is located on the interior of the wand in communication with the one or more apertures in the wand to achieve a high successful rate of starting plasma. Without being limited to any specific theory, the presence of the apertures in the wand allow electrons to migrate from the metal wire into a gas flow. This flow of electrons may initialize a cascade of ionization in the gas species, which “strikes” the plasma in the plasma torch. In some embodiments, the one or more apertures on the wand may minimize contamination of wire vaporization within the plasma torch. Furthermore, in some embodiments, if the feed stock of the plasma torch is a metal, the antenna material can be formed of the same metal as the feed stock, such that contamination is substantially eliminated. As such, applying the wand and antenna structure into an auto-striking plasma torch to automatically start plasma provides benefit in the manufacture of materials with plasma processes.


In some embodiments, the number, placement, and orientation of the apertures may be varied to optimize the efficiency of the striking mechanism and to minimize contamination of the metal wire into the plasma torch.


The wand may be capable of striking plasma in many different gas species including, for example, N2, Ar, H2, hydrocarbons, other nobles gases, and other gas mixtures (e.g. 90% Ar, 10% H2). It will be understood that the above recited gases are exemplary in nature and that any gas may be used as a plasma gas species depending on the specific application.


In some embodiments, a motor may be used, in combination with friction rollers and an upper limit switch, to control the motion of the wand into and out of the gas flow within the plasma torch. The friction rollers, driven by the motor, move the wand, including the one or metal wires inside, up and down using friction force. The upper limit switch senses the wand location and ensures that the wand does not extend beyond its intended range of motion. The limit switch may be used as part of a control system, as a safety interlock, and/or to count the number of times the wand has been used to strike the plasma.


The devices and methods described herein have a high successful rate of starting a plasma in a plasma chamber or torch. An operator of a plasma torch can use the devices and methods to start a plasma at a distance to improve the safety of the operator. Furthermore, the wand described herein may increase the life of the striking wand and metal wires, such that the components need replacement less frequently. Furthermore, the wand design minimalizes contamination of the antenna material in the process chamber.


Plasma Torches



FIG. 1 illustrates an exemplary top feed microwave plasma torch that can be used in the production of powders, according to embodiments of the present disclosure. In some embodiments, feed materials 9, 10 can be introduced into a microwave plasma torch 3, which sustains a microwave generated plasma 11. In one example embodiment, an entrainment gas flow and a sheath flow (downward arrows) may be injected through inlets 5 to create flow conditions within the plasma torch prior to ignition of the plasma 11 via microwave radiation source 1. The feed materials 9 are introduced axially into the microwave plasma torch, where they are entrained by a gas flow that directs the materials toward the plasma. As discussed above, the gas flows can consist of a noble gas column of the periodic table, such as helium, neon, argon, etc.


Within the microwave generated plasma, the feed materials are melted in order to spheroidize the materials. Inlets 5 can be used to introduce process gases to entrain and accelerate particles 9, 10 along axis 12 towards plasma 11. First, particles 9 are accelerated by entrainment using a core laminar gas flow (upper set of arrows) created through an annular gap within the plasma torch. A second laminar flow (lower set of arrows) can be created through a second annular gap to provide laminar sheathing for the inside wall of dielectric torch 3 to protect it from melting due to heat radiation from plasma 11. In exemplary embodiments, the laminar flows direct particles 9, 10 toward the plasma 11 and hot zone 6 along a path as close as possible to axis 12, exposing them to a substantially uniform temperature within the plasma. In some embodiments, suitable flow conditions are present to keep particles 10 from reaching the inner wall of the plasma torch 3 where plasma attachment could take place. Particles 9, 10 are guided by the gas flows towards microwave plasma 11 were each undergoes homogeneous thermal treatment.


Various parameters of the microwave generated plasma, as well as particle parameters, may be adjusted in order to achieve desired results. These parameters may include microwave power, feed material size, feed material insertion rate, gas flow rates, plasma temperature, residence time and cooling rates. As discussed above, in this particular embodiment, the gas flows are laminar; however, in alternative embodiments, swirl flows or turbulent flows may be used to direct the feed materials toward the plasma.



FIGS. 2A-B illustrate an exemplary microwave plasma torch that includes a side feeding hopper rather than the top feeding hopper shown in the embodiment of FIG. 1 thus allowing for downstream feeding. Thus, in this implementation the feedstock is injected after the microwave plasma torch applicator for processing in the “plume” or “exhaust” of the microwave plasma torch. Thus, the plasma of the microwave plasma torch is engaged at the exit end of the plasma torch to allow downstream feeding of the feedstock, as opposed to the top-feeding (or upstream feeding) discussed with respect to FIG. 1. This downstream feeding can advantageously extend the lifetime of the torch as the hot zone is preserved indefinitely from any material deposits on the walls of the hot zone liner. Furthermore, it allows engaging the plasma plume downstream at temperature suitable for optimal melting of powders through precise targeting of temperature level and residence time. For example, there is the ability to dial the length of the plume using microwave powder, gas flows, and pressure in the quenching vessel that contains the plasma plume.


Generally, the downstream spheroidization method can utilize two main hardware configurations to establish a stable plasma plume which are: annular torch, such as described in U.S. Pat. Pub. No. 2018/0297122, now U.S. Pat. No. 10,987,735, or swirl torches described in U.S. Pat. Nos. 8,748,785 B2 and 9,932,673 B2. Both FIG. 2A and FIG. 2B show embodiments of a method that can be implemented with either an annular torch or a swirl torch. A feed system close-coupled with the plasma plume at the exit of the plasma torch is used to feed powder axisymmetrically to preserve process homogeneity. Other feeding configurations may include one or several individual feeding nozzles surrounding the plasma plume.


The feed materials 314 can be introduced into a microwave plasma torch 302. A hopper 306 can be used to store the feed material 314 before feeding the feed material 314 into the microwave plasma torch 302, plume, or exhaust. In alternative embodiments, the feedstock can be injected along the longitudinal axis of the plasma torch. The microwave radiation can be brought into the plasma torch through a waveguide 304. The feed material 314 is fed into a plasma chamber 310 and is placed into contact with the plasma generated by the plasma torch 302. When in contact with the plasma, plasma plume, or plasma exhaust, the feed material melts. While still in the plasma chamber 310, the feed material 314 cools and solidifies before being collected into a container 312. Alternatively, the feed material 314 can exit the plasma chamber 310 while still in a melted phase and cool and solidify outside the plasma chamber. In some embodiments, a quenching chamber may be used, which may or may not use positive pressure. While described separately from FIG. 1, the embodiments of FIGS. 2A-2B are understood to use similar features and conditions to the embodiment of FIG. 1.


Autostrike Devices and Methods



FIG. 3 illustrates an embodiment of an autostrike wand mechanism for striking a microwave plasma torch, according to embodiments of the present disclosure. The autostrike wand mechanism 400 may be utilized to strike a plasma torch without manual operation by an operator. The plasma torch may be any induction or electromagnetic wave plasma torch, including the microwave plasma torch 3 of FIG. 1 and the microwave plasma torch 302 of FIGS. 2A-2B. The autostrike wand mechanism 400 may be remotely controlled via an operator or via a computerized controller. The function of the autostrike wand mechanism may be insertion of an autostrike wand 402 into a plasma torch gas flow to start the plasma torch. The wand 402 may comprise an outer shell of quartz, glass, and/or other microwave-transparent materials, as described in detail below in reference to FIG. 7. The wand 402 may also comprise a hollow core in which a metal wire antenna may be located. One or more open apertures may be cut into the wand 402 to allow the metal wire antenna to directly contact a plasma torch gas flow under high heat in order to strike the plasma torch. The wand 402 may be inserted into the plasma torch gas flow in an orientation parallel to, perpendicular to, or at another angle with respect to the gas flow. After striking the plasma torch, the wand 402 may be retracted from the plasma torch gas flow to minimize contamination of the metal wire into the plasma torch and products, and to preserve the wand 402 for repeated use.


The wand 402 may be inserted into and retracted from the plasma torch gas flow using a motor 404 to drive one or more friction rollers 406, as shown in FIG. 4. In some embodiments, the motor 404 and therefore friction rollers 406 may be controlled remotely via an operator or a computerized, automated controller. Thus, the autostrike wand mechanism 400 may be used to start plasma torch with no human operator present in proximity to the plasma torch for enhanced safety. The autostrike wand 402 may also be supported within the autostrike wand mechanism 400 by one or more wand bearings 408, which maintain the orientation and integrity of the autostrike wand 402. A limit switch 410 may be used to sense the wand 402 at a home position.



FIG. 4 illustrates a cross-sectional view of an embodiment of an autostrike wand mechanism for striking a microwave plasma torch, according to embodiments of the present disclosure. The illustrated cross-section of FIG. 4 shows friction rollers 406, driven by motor 404. In the illustrated embodiment, the friction rollers 406 may be driven by motor 404 to move or translate wand 402 vertically up and down. Wand bearing 408 may secure the orientation of wand 402 within the autostrike wand mechanism 400.



FIG. 5 illustrates an embodiment of a motor and friction roller mechanism for controlling the motion of an autostrike wand, according to embodiments of the present disclosure. In the illustrated embodiment, motor 404 is connected to friction rollers 406 via a driveshaft 412, which transmits torque and rotation from motor 404 to friction rollers 406. In such a way, friction rollers 406 may convey wand 402 into and out of a plasma torch in order to ignite the torch. In some embodiments, friction rollers 406 may be housed within a wand mechanism body 414, which may be connected to a wand housing 416, where the wand bearing 408 is located. In some embodiments, the wand housing 416 and/or the wand mechanism body 414 may be vacuum sealed from the motor and other components.



FIG. 6 illustrates an embodiment of an upper limit switch mechanism for use in a microwave plasma torch with an autostrike wand, according to embodiments of the present disclosure. In some embodiments, limit switch 410 may be used as part of a wand control system, as a safety interlock, or to sense a home position of the wand 402, outside of a plasma torch gas flow. A limit switch is an electromechanical device that consists of an actuator mechanically linked to a set of contacts. When the wand 402 contacts the actuator, the limit switch 410 operates the contacts to make or break an electrical connection, which can be transmitted to a controller.



FIG. 7 illustrates an embodiment of an autostrike wand for striking a plasma torch, according to embodiments of the present disclosure. The wand 402 may comprise an elongate, hollow wand member made substantially of quartz or another microwave transparent material, having a closed distal end 421 and an open proximal end and one or more apertures 420 extending from a hollow interior 422 of the wand member to an exterior 424 of the wand member, the one or more apertures having a predetermined shape and size that can vary as required, the hollow wand member being designed for operable communication with a plasma torch.


The wand 402 may also comprise an elongate wire member or antenna 426 positioned within the interior 422 of the hollow wand member 402 and extending at least from a position proximate the closed distal end 421 and the one or more openings 420 to a position outside of the open proximal end, wherein the wire member or antenna 426 is designed for operable communication through the one or more apertures 420 with a particular power source, such as a microwave generator, such that the power source can be activated to in turn start the plasma within a microwave plasma torch.


In some embodiments, the wand 402 may comprise quartz and/or other microwave-transparent materials, such as glasses. In some embodiments, the antenna 426 may comprise one or more metal wires. The wand 402 may enclose the one or more wires except at the one or more apertures, which minimizes the risk of having the one or more wires slip free and contaminate the plasma torch. In some embodiments, the antenna may comprise a metal or a metal alloy. In some embodiments, the antenna 426 may be fused to the interior 422 of the wand 402 to keep the antenna fixed in place. For example, the antenna 425 may be fused by a glass-to-metal oxide bond to the interior 422. The length of the antenna 426 may also be varied. For example, in some embodiments, the metal wire may extend the entire length of the wand 402. Alternatively, in some embodiments, the antenna 426 may extend only partially along the length of the wand 402. For example, the metal wire may be provided only at the location of one or more apertures 420 in the wand. In some embodiments, the antenna length may correspond to a wavelength of an electromagnetic wave used in the microwave plasma torch. For example, the antenna length may comprise about ¼ the length of the wavelength of the microwave of the plasma torch, or a multiple of ¼ the length of the wavelength. In some embodiments, the antenna length may comprise about ⅛, about ¼, about ⅜, about ½, about ¾, about ⅞, about 1 wavelength or longer than the microwave of the plasma torch. Without being limited by theory, an antenna length of about ¼ the length of the wavelength or more generates a maximum voltage across the antenna. Higher voltage will increase the amount of electrons emitted by wire into the gas flow of the plasma torch, such that ionization of gas is maximized to start a chain reaction, such that the plasma is ignited. In some embodiments, a shorter antenna length may be used depending on the properties of the specific metals used in the antenna.


In some embodiments, the number of apertures 420 may not be limited. In some embodiments, the number, placement, and orientation of the apertures 420 may be varied to optimize the efficiency of the striking mechanism and to minimize contamination of the antenna 426 into the plasma torch.



FIG. 8 illustrates another embodiment of an autostrike wand for striking a plasma torch, according to embodiments of the present disclosure. As noted above, the size orientation and number of apertures 420 may be varied according to the desired process condition. The apertures 420 may be circular in shape, as illustrated in FIG. 8.


Additional Embodiments

In the foregoing specification, the invention has been described with reference to specific embodiments thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the invention. The specification and drawings are, accordingly, to be regarded in an illustrative rather than restrictive sense.


Indeed, although this invention has been disclosed in the context of certain embodiments and examples, it will be understood by those skilled in the art that the invention extends beyond the specifically disclosed embodiments to other alternative embodiments and/or uses of the invention and obvious modifications and equivalents thereof. In addition, while several variations of the embodiments of the invention have been shown and described in detail, other modifications, which are within the scope of this invention, will be readily apparent to those of skill in the art based upon this disclosure. It is also contemplated that various combinations or sub-combinations of the specific features and aspects of the embodiments may be made and still fall within the scope of the invention. It should be understood that various features and aspects of the disclosed embodiments can be combined with, or substituted for, one another in order to form varying modes of the embodiments of the disclosed invention. Any methods disclosed herein need not be performed in the order recited. Thus, it is intended that the scope of the invention herein disclosed should not be limited by the particular embodiments described above.


It will be appreciated that the systems and methods of the disclosure each have several innovative aspects, no single one of which is solely responsible or required for the desirable attributes disclosed herein. The various features and processes described above may be used independently of one another, or may be combined in various ways. All possible combinations and subcombinations are intended to fall within the scope of this disclosure.


Certain features that are described in this specification in the context of separate embodiments also may be implemented in combination in a single embodiment. Conversely, various features that are described in the context of a single embodiment also may be implemented in multiple embodiments separately or in any suitable subcombination. Moreover, although features may be described above as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination may in some cases be excised from the combination, and the claimed combination may be directed to a subcombination or variation of a subcombination. No single feature or group of features is necessary or indispensable to each and every embodiment.


It will also be appreciated that conditional language used herein, such as, among others, “can,” “could,” “might,” “may,” “e.g.,” and the like, unless specifically stated otherwise, or otherwise understood within the context as used, is generally intended to convey that certain embodiments include, while other embodiments do not include, certain features, elements and/or steps. Thus, such conditional language is not generally intended to imply that features, elements and/or steps are in any way required for one or more embodiments or that one or more embodiments necessarily include logic for deciding, with or without author input or prompting, whether these features, elements and/or steps are included or are to be performed in any particular embodiment. The terms “comprising,” “including,” “having,” and the like are synonymous and are used inclusively, in an open-ended fashion, and do not exclude additional elements, features, acts, operations, and so forth. In addition, the term “or” is used in its inclusive sense (and not in its exclusive sense) so that when used, for example, to connect a list of elements, the term “or” means one, some, or all of the elements in the list. In addition, the articles “a,” “an,” and “the” as used in this application and the appended claims are to be construed to mean “one or more” or “at least one” unless specified otherwise. Similarly, while operations may be depicted in the drawings in a particular order, it is to be recognized that such operations need not be performed in the particular order shown or in sequential order, or that all illustrated operations be performed, to achieve desirable results. Further, the drawings may schematically depict one more example processes in the form of a flowchart. However, other operations that are not depicted may be incorporated in the example methods and processes that are schematically illustrated. For example, one or more additional operations may be performed before, after, simultaneously, or between any of the illustrated operations. Additionally, the operations may be rearranged or reordered in other embodiments. In certain circumstances, multitasking and parallel processing may be advantageous. Moreover, the separation of various system components in the embodiments described above should not be understood as requiring such separation in all embodiments, and it should be understood that the described program components and systems may generally be integrated together in a single software product or packaged into multiple software products. Additionally, other embodiments are within the scope of the following claims. In some cases, the actions recited in the claims may be performed in a different order and still achieve desirable results.


Further, while the methods and devices described herein may be susceptible to various modifications and alternative forms, specific examples thereof have been shown in the drawings and are herein described in detail. It should be understood, however, that the invention is not to be limited to the particular forms or methods disclosed, but, to the contrary, the invention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the various implementations described and the appended claims. Further, the disclosure herein of any particular feature, aspect, method, property, characteristic, quality, attribute, element, or the like in connection with an implementation or embodiment can be used in all other implementations or embodiments set forth herein. Any methods disclosed herein need not be performed in the order recited. The methods disclosed herein may include certain actions taken by a practitioner; however, the methods can also include any third-party instruction of those actions, either expressly or by implication. The ranges disclosed herein also encompass any and all overlap, sub-ranges, and combinations thereof. Language such as “up to,” “at least,” “greater than,” “less than,” “between,” and the like includes the number recited. Numbers preceded by a term such as “about” or “approximately” include the recited numbers and should be interpreted based on the circumstances (e.g., as accurate as reasonably possible under the circumstances, for example ±5%, ±10%, ±15%, etc.). For example, “about 3.5 mm” includes “3.5 mm.” Phrases preceded by a term such as “substantially” include the recited phrase and should be interpreted based on the circumstances (e.g., as much as reasonably possible under the circumstances). For example, “substantially constant” includes “constant.” Unless stated otherwise, all measurements are at standard conditions including temperature and pressure.


As used herein, a phrase referring to “at least one of” a list of items refers to any combination of those items, including single members. As an example, “at least one of: A, B, or C” is intended to cover: A, B, C, A and B, A and C, B and C, and A, B, and C. Conjunctive language such as the phrase “at least one of X, Y and Z,” unless specifically stated otherwise, is otherwise understood with the context as used in general to convey that an item, term, etc. may be at least one of X, Y or Z. Thus, such conjunctive language is not generally intended to imply that certain embodiments require at least one of X, at least one of Y, and at least one of Z to each be present. The headings provided herein, if any, are for convenience only and do not necessarily affect the scope or meaning of the devices and methods disclosed herein.


Accordingly, the claims are not intended to be limited to the embodiments shown herein, but are to be accorded the widest scope consistent with this disclosure, the principles and the novel features disclosed herein.

Claims
  • 1. A device for starting a plasma of a plasma torch, the device comprising: an elongate, hollow wand member located within a plasma chamber of the plasma torch, the wand member comprising a closed distal end, a proximal end, and one or more apertures proximate to the closed distal end extending from a hollow interior of the wand member to an exterior surface on a lateral side of the wand member; andan elongate wire member comprising one or more wires positioned within the hollow interior of the wand member and extending along at least a portion of a length of the wand member, wherein the wire member is configured to be placed in operable communication through the one or more apertures with a power source, such that the power source is activated to in turn start the plasma within the plasma torch,wherein the wire member is configured to remain within the hollow interior of the wand member when the plasma is started, andwherein the wand member encloses the wire member within the plasma torch except at the one or more apertures.
  • 2. The device of claim 1, wherein the power source comprises a microwave generator, and wherein a length of the wire member comprises ¼ of a wavelength or longer of a microwave generated by the microwave generator.
  • 3. The device of claim 1, wherein the wand member comprises between 1 and 100 apertures.
  • 4. The device of claim 1, wherein the wire member comprises one wire.
  • 5. The device of claim 1, wherein the wire member comprises more than one wire.
  • 6. The device of claim 1, wherein the wand member comprises quartz or another microwave-transparent material.
  • 7. The device of claim 1, wherein the wire member comprises a metal or metal alloy.
  • 8. The device of claim 1, wherein the wand member comprises an open proximal end.
  • 9. The device of claim 1, wherein the wire member extends at least from a position proximate the closed distal end to a position outside of the proximal end.
  • 10. The device of claim 1, wherein the wand member comprises a plurality of apertures proximate the closed distal end of the hollow wand member.
  • 11. The device of claim 1, wherein the wire member is fused to the hollow interior of the wand member.
  • 12. The device of claim 1, wherein the wand member is in operable communication with a motor and a gas flow of the plasma torch.
  • 13. The device of claim 12, wherein the motor is configured to impart motion on the wand member to place the wand member within the plasma torch, such that the wire member is configured to be placed in operable communication through the aperture with the power source and the gas flow.
  • 14. The device of claim 12, wherein the motor is configured to move the device into the gas flow of the plasma torch.
  • 15. The device of claim 14, wherein moving the device into the gas flow places the wire member in operable communication through the aperture with the power source.
  • 16. The device of claim 12, wherein the motor is configured to move the device out of the gas flow of the plasma torch.
  • 17. The device of claim 12, wherein the motor is in operable communication with a control unit, the control unit programmed to provide one or more control signals to the motor.
  • 18. The device of claim 17, wherein the control unit is configured to transmit an instruction to the power source to start the plasma of the plasma torch.
  • 19. The device of claim 1, wherein the wand member is in operable communication with a limit switch comprising an actuator for determining a location of the wand member.
INCORPORATION BY REFERENCE TO ANY PRIORITY APPLICATIONS

This application claims the priority benefit under 35 U.S.C. § 119(e) of U.S. Provisional Application No. 63/082,919, filed Sep. 24, 2020, the entire disclosure of which is incorporated herein by reference. Any and all applications for which a foreign or domestic priority claim is identified in the Application Data Sheet as filed with the present application are hereby incorporated by reference under 37 CFR 1.57.

US Referenced Citations (539)
Number Name Date Kind
1699205 Podszus et al. Jul 1925 A
2892215 Naeser et al. Jun 1959 A
3293334 Bylund et al. Aug 1962 A
3290723 Jacques et al. Dec 1966 A
3466165 Rhys et al. Feb 1967 A
3434831 Knopp et al. Mar 1969 A
RE26879 Kelso May 1970 E
3652259 Knopp Mar 1972 A
3802816 Kaufmann Apr 1974 A
3845344 Rainer Oct 1974 A
3909241 Cheney et al. Sep 1975 A
3966374 Honnorat et al. Jun 1976 A
3974245 Cheney et al. Aug 1976 A
4076640 Forgensi et al. Feb 1978 A
4177026 Honnorat et al. Dec 1979 A
4212837 Oguchi et al. Jul 1980 A
4221554 Oguchi et al. Sep 1980 A
4221775 Anno Sep 1980 A
4265730 Hirose et al. May 1981 A
4423303 Hirose et al. Dec 1983 A
4431449 Dillon et al. Feb 1984 A
4439410 Santen et al. Mar 1984 A
4544404 Yolton et al. Oct 1985 A
4569823 Westin Feb 1986 A
4599880 Stepanenko et al. Jul 1986 A
4611108 Leprince et al. Sep 1986 A
4670047 Kopatz et al. Jun 1987 A
4692584 Caneer, Jr. Sep 1987 A
4705560 Kemp, Jr. et al. Nov 1987 A
4711660 Kemp, Jr. et al. Dec 1987 A
4711661 Kemp, Jr. et al. Dec 1987 A
4714587 Eylon et al. Dec 1987 A
4731110 Kopatz et al. Mar 1988 A
4731111 Kopatz et al. Mar 1988 A
4772315 Johnson et al. Sep 1988 A
4778515 Kemp, Jr. et al. Oct 1988 A
4780131 Kemp, Jr. et al. Oct 1988 A
4783216 Kemp, Jr. et al. Nov 1988 A
4783218 Kemp, Jr. et al. Nov 1988 A
4787934 Johnson et al. Nov 1988 A
4802915 Kopatz et al. Feb 1989 A
4836850 Kemp, Jr. et al. Jun 1989 A
4859237 Johnson et al. Aug 1989 A
4923509 Kemp, Jr. et al. May 1990 A
4923531 Fisher May 1990 A
4943322 Kemp, Jr. et al. Jul 1990 A
4944797 Kemp et al. Jul 1990 A
4952389 Szymanski et al. Aug 1990 A
5022935 Fisher Jun 1991 A
5041713 Weidman Aug 1991 A
5095048 Takahashi et al. Mar 1992 A
5114471 Johnson et al. May 1992 A
5131992 Church et al. Jul 1992 A
5200595 Boulos et al. Apr 1993 A
5290507 Runkle Mar 1994 A
5292370 Tsai et al. Mar 1994 A
5376475 Ovshinsky et al. Dec 1994 A
5395453 Noda Mar 1995 A
5411592 Ovshinsky et al. May 1995 A
5431967 Manthiram et al. Jul 1995 A
5518831 Tou et al. May 1996 A
5671045 Woskov et al. Sep 1997 A
5676919 Kawamura et al. Oct 1997 A
5750013 Lin May 1998 A
5776323 Kobashi Jul 1998 A
5909277 Woskov et al. Jun 1999 A
5958361 Laine et al. Sep 1999 A
5980977 Deng et al. Nov 1999 A
5989648 Phillips Nov 1999 A
6027585 Patterson et al. Feb 2000 A
6221125 Soda et al. Apr 2001 B1
6261484 Phillips et al. Jul 2001 B1
6274110 Kim et al. Aug 2001 B1
6329628 Kuo et al. Dec 2001 B1
6334882 Aslund Jan 2002 B1
6362449 Hadidi et al. Mar 2002 B1
6376027 Lee et al. Apr 2002 B1
6409851 Sethuram et al. Jun 2002 B1
6428600 Flurschutz et al. Aug 2002 B1
6543380 Sung-Spritzl Apr 2003 B1
6551377 Leonhardt Apr 2003 B1
6569397 Yadav et al. May 2003 B1
6579573 Strutt et al. Jun 2003 B2
6589311 Han et al. Jul 2003 B1
6607693 Saito et al. Aug 2003 B1
6652822 Phillips et al. Nov 2003 B2
6676728 Han et al. Jan 2004 B2
6689192 Phillips et al. Feb 2004 B1
6752979 Talbot et al. Jun 2004 B1
6755886 Phillips et al. Jun 2004 B2
6780219 Singh et al. Aug 2004 B2
6793849 Gruen et al. Sep 2004 B1
6805822 Takei et al. Oct 2004 B2
6838072 Kong et al. Jan 2005 B1
6869550 Dorfman et al. Mar 2005 B2
6902745 Lee et al. Jun 2005 B2
6919257 Gealy et al. Jul 2005 B2
6919527 Boulos et al. Jul 2005 B2
6989529 Wiseman Jan 2006 B2
7066980 Akimoto et al. Jun 2006 B2
7091441 Kuo Aug 2006 B1
7108733 Enokido Sep 2006 B2
7125537 Liao et al. Oct 2006 B2
7125822 Nakano et al. Oct 2006 B2
7175786 Celikkaya et al. Feb 2007 B2
7182929 Singhal et al. Feb 2007 B1
7220398 Sutorik et al. May 2007 B2
7235118 Bouaricha et al. Jun 2007 B2
7285194 Uno et al. Oct 2007 B2
7285307 Hohenthanner et al. Oct 2007 B2
7297310 Peng et al. Nov 2007 B1
7297892 Kelley et al. Nov 2007 B2
7344776 Kollmann et al. Mar 2008 B2
7357910 Phillips et al. Apr 2008 B2
7368130 Kim et al. May 2008 B2
7374704 Che et al. May 2008 B2
7375303 Twarog May 2008 B2
7381496 Onnerud et al. Jun 2008 B2
7431750 Liao et al. Oct 2008 B2
7442271 Asmussen et al. Oct 2008 B2
7491468 Okada et al. Feb 2009 B2
7517513 Sarkas et al. Apr 2009 B2
7524353 Johnson, Jr. et al. Apr 2009 B2
7534296 Swain et al. May 2009 B2
7572315 Boulos et al. Aug 2009 B2
7622211 Vyas et al. Nov 2009 B2
7629553 Fanson et al. Dec 2009 B2
7700152 Laine et al. Apr 2010 B2
7776303 Hung et al. Aug 2010 B2
7806077 Lee et al. Oct 2010 B2
7828999 Yubuta et al. Nov 2010 B2
7901658 Weppner et al. Mar 2011 B2
7931836 Xie et al. Apr 2011 B2
7939141 Matthews et al. May 2011 B2
8007691 Sawaki et al. Aug 2011 B2
8043405 Johnson, Jr. et al. Oct 2011 B2
8092941 Weppner et al. Jan 2012 B2
8101061 Suh et al. Jan 2012 B2
8168128 Seeley et al. May 2012 B2
8178240 Wang et al. May 2012 B2
8192865 Buiel et al. Jun 2012 B2
8193291 Zhang Jun 2012 B2
8211388 Woodfield et al. Jul 2012 B2
8268230 Cherepy et al. Sep 2012 B2
8283275 Heo et al. Oct 2012 B2
8303926 Luhrs et al. Nov 2012 B1
8329090 Hollingsworth et al. Dec 2012 B2
8329257 Larouche et al. Dec 2012 B2
8338323 Takasu et al. Dec 2012 B2
8389160 Venkatachalam et al. Mar 2013 B2
8420043 Gamo et al. Apr 2013 B2
8439998 Ito et al. May 2013 B2
8449950 Shang et al. May 2013 B2
8478785 Jamjoom et al. Jul 2013 B2
8492303 Bulan et al. Jul 2013 B2
8529996 Bocian et al. Sep 2013 B2
8592767 Rappe et al. Nov 2013 B2
8597722 Albano et al. Dec 2013 B2
8623555 Kang et al. Jan 2014 B2
8658317 Weppner et al. Feb 2014 B2
8685593 Dadheech et al. Apr 2014 B2
8728680 Mikhail et al. May 2014 B2
8735022 Schlag et al. May 2014 B2
8748785 Jordan et al. Jun 2014 B2
8758957 Dadheech et al. Jun 2014 B2
8784706 Shevchenko et al. Jul 2014 B2
8822000 Kumagai et al. Sep 2014 B2
8840701 Borland et al. Sep 2014 B2
8877119 Jordan et al. Nov 2014 B2
8911529 Withers et al. Dec 2014 B2
8919428 Cola et al. Dec 2014 B2
8945431 Schulz et al. Feb 2015 B2
8951496 Hadidi et al. Feb 2015 B2
8956785 Dadheech et al. Feb 2015 B2
8968587 Shin et al. Mar 2015 B2
8968669 Chen Mar 2015 B2
8980485 Lanning et al. Mar 2015 B2
8999440 Zenasni et al. Apr 2015 B2
9023259 Hadidi et al. May 2015 B2
9065141 Merzougui et al. Jun 2015 B2
9067264 Moxson et al. Jun 2015 B2
9079778 Kelley et al. Jul 2015 B2
9085490 Taylor et al. Jul 2015 B2
9101982 Aslund Aug 2015 B2
9136569 Song et al. Sep 2015 B2
9150422 Nakayama et al. Oct 2015 B2
9193133 Shin et al. Nov 2015 B2
9196901 Se-Hee et al. Nov 2015 B2
9196905 Tzeng et al. Nov 2015 B2
9206085 Hadidi et al. Dec 2015 B2
9242224 Redjdal et al. Jan 2016 B2
9259785 Hadidi et al. Feb 2016 B2
9293302 Risby et al. Mar 2016 B2
9321071 Jordan et al. Apr 2016 B2
9322081 McHugh et al. Apr 2016 B2
9352278 Spatz et al. May 2016 B2
9356281 Verbrugge et al. May 2016 B2
9368772 Chen et al. Jun 2016 B1
9412998 Rojeski et al. Aug 2016 B2
9421612 Fang et al. Aug 2016 B2
9425463 Hsu et al. Aug 2016 B2
9463435 Schulz et al. Oct 2016 B2
9463984 Sun et al. Oct 2016 B2
9520593 Sun et al. Dec 2016 B2
9520600 Dadheech et al. Dec 2016 B2
9624565 Lee et al. Apr 2017 B2
9630162 Sunkara et al. Apr 2017 B1
9643891 Hadidi et al. May 2017 B2
9700877 Kim et al. Jul 2017 B2
9705136 Rojeski Jul 2017 B2
9718131 Boulos et al. Aug 2017 B2
9735427 Zhang Aug 2017 B2
9738788 Gross et al. Aug 2017 B1
9751129 Boulos et al. Sep 2017 B2
9768033 Ranjan et al. Sep 2017 B2
9776378 Choi Oct 2017 B2
9782791 Redjdal et al. Oct 2017 B2
9782828 Wilkinson Oct 2017 B2
9796019 She et al. Oct 2017 B2
9796020 Aslund Oct 2017 B2
9831503 Sopchak Nov 2017 B2
9871248 Rayner et al. Jan 2018 B2
9879344 Lee et al. Jan 2018 B2
9899674 Hirai et al. Feb 2018 B2
9917299 Behan et al. Mar 2018 B2
9932673 Jordan et al. Apr 2018 B2
9945034 Yao et al. Apr 2018 B2
9947926 Kim et al. Apr 2018 B2
9981284 Guo et al. May 2018 B2
9991458 Rosenman et al. Jun 2018 B2
9999922 Struve Jun 2018 B1
10011491 Lee et al. Jul 2018 B2
10050303 Anandan et al. Aug 2018 B2
10057986 Prud'Homme et al. Aug 2018 B2
10065240 Chen Sep 2018 B2
10079392 Huang et al. Sep 2018 B2
10116000 Federici et al. Oct 2018 B1
10130994 Fang et al. Nov 2018 B2
10167556 Ruzic et al. Jan 2019 B2
10170753 Ren et al. Jan 2019 B2
10193142 Rojeski Jan 2019 B2
10244614 Foret Mar 2019 B2
10283757 Noh et al. May 2019 B2
10319537 Claussen et al. Jun 2019 B2
10333183 Sloop Jun 2019 B2
10350680 Yamamoto et al. Jul 2019 B2
10411253 Tzeng et al. Sep 2019 B2
10439206 Behan et al. Oct 2019 B2
10442000 Fukada et al. Oct 2019 B2
10461298 Herle Oct 2019 B2
10477665 Hadidi Nov 2019 B2
10493524 She et al. Dec 2019 B2
10522300 Yang Dec 2019 B2
10526684 Ekman et al. Jan 2020 B2
10529486 Nishisaka Jan 2020 B2
10543534 Hadidi et al. Jan 2020 B2
10593985 Sastry et al. Mar 2020 B2
10610929 Fang et al. Apr 2020 B2
10637029 Gotlib Vainshtein et al. Apr 2020 B2
10638592 Foret Apr 2020 B2
10639712 Barnes et al. May 2020 B2
10647824 Hwang et al. May 2020 B2
10655206 Moon et al. May 2020 B2
10665890 Kang et al. May 2020 B2
10668566 Smathers et al. Jun 2020 B2
10669437 Cox et al. Jun 2020 B2
10688564 Boulos et al. Jun 2020 B2
10707477 Sastry et al. Jul 2020 B2
10717150 Aleksandrov et al. Jul 2020 B2
10727477 Kim et al. Jul 2020 B2
10741845 Yushin et al. Aug 2020 B2
10744590 Maier et al. Aug 2020 B2
10756334 Stowell et al. Aug 2020 B2
10766787 Sunkara et al. Sep 2020 B1
10777804 Sastry et al. Sep 2020 B2
10858255 Koziol et al. Dec 2020 B2
10858500 Chen et al. Dec 2020 B2
10892477 Choi et al. Jan 2021 B2
10930473 Paukner et al. Feb 2021 B2
10930922 Sun et al. Feb 2021 B2
10943744 Sungail et al. Mar 2021 B2
10944093 Paz et al. Mar 2021 B2
10950856 Park et al. Mar 2021 B2
10964938 Rojeski Mar 2021 B2
10987735 Hadidi et al. Apr 2021 B2
10998552 Lanning et al. May 2021 B2
11031641 Gupta et al. Jun 2021 B2
11050061 Kim et al. Jun 2021 B2
11072533 Shevchenko et al. Jul 2021 B2
11077497 Motchenbacher et al. Aug 2021 B2
11077524 Smathers et al. Aug 2021 B2
11108050 Kim et al. Aug 2021 B2
11116000 Sandberg et al. Sep 2021 B2
11130175 Parrish et al. Sep 2021 B2
11130994 Shachar et al. Sep 2021 B2
11133495 Gazda et al. Sep 2021 B2
11148202 Hadidi et al. Oct 2021 B2
11167556 Shimada et al. Nov 2021 B2
11170753 Nomura et al. Nov 2021 B2
11171322 Seol et al. Nov 2021 B2
11183682 Sunkara et al. Nov 2021 B2
11193142 Angelidaki et al. Dec 2021 B2
11196045 Dadheech et al. Dec 2021 B2
11219884 Takeda et al. Jan 2022 B2
11244614 He et al. Feb 2022 B2
11245065 Ouderkirk et al. Feb 2022 B1
11245109 Tzeng et al. Feb 2022 B2
11254585 Ekman et al. Feb 2022 B2
11273322 Zanata et al. Mar 2022 B2
11273491 Barnes et al. Mar 2022 B2
11299397 Lanning et al. Apr 2022 B2
11311938 Badwe et al. Apr 2022 B2
11319537 Dames et al. May 2022 B2
11333183 Desai et al. May 2022 B2
11335911 Lanning et al. May 2022 B2
11350680 Rutkoski et al. Jun 2022 B2
11411253 Busacca et al. Aug 2022 B2
11439206 Santos Sep 2022 B2
11442000 Vaez-Iravani et al. Sep 2022 B2
11461298 Shemmer et al. Oct 2022 B1
11465201 Barnes et al. Oct 2022 B2
11471941 Barnet et al. Oct 2022 B2
11477665 Franke et al. Oct 2022 B2
11577314 Hadidi et al. Feb 2023 B2
11590568 Badwe et al. Feb 2023 B2
11611130 Wrobel et al. Mar 2023 B2
11633785 Badwe et al. Apr 2023 B2
11717886 Badwe et al. Aug 2023 B2
20010016283 Shiraishi et al. Aug 2001 A1
20010021740 Lodyga et al. Sep 2001 A1
20020112794 Sethuram et al. Aug 2002 A1
20030024806 Foret Feb 2003 A1
20030027021 Sharivker et al. Feb 2003 A1
20030129497 Yamamoto et al. Jul 2003 A1
20030172772 Sethuram et al. Sep 2003 A1
20030186128 Singh et al. Oct 2003 A1
20030207978 Yadav et al. Nov 2003 A1
20040013941 Kobayashi et al. Jan 2004 A1
20040045807 Sarkas et al. Mar 2004 A1
20040060387 Tanner-Jones Apr 2004 A1
20040123699 Liao et al. Jul 2004 A1
20050025698 Talbot et al. Feb 2005 A1
20050072496 Hwang et al. Apr 2005 A1
20050163696 Uhm et al. Jul 2005 A1
20050242070 Hammer Nov 2005 A1
20050260786 Yoshikawa et al. Nov 2005 A1
20060040168 Sridhar Feb 2006 A1
20060141153 Kubota et al. Jun 2006 A1
20060145124 Hsiao et al. Jul 2006 A1
20060291827 Suib et al. Dec 2006 A1
20070077350 Hohenthanner et al. Apr 2007 A1
20070089860 Hou et al. Apr 2007 A1
20070209758 Sompalli et al. Sep 2007 A1
20070221635 Boulos et al. Sep 2007 A1
20070259768 Kear et al. Nov 2007 A1
20080029485 Kelley et al. Feb 2008 A1
20080055594 Hadidi et al. Mar 2008 A1
20080182114 Kim et al. Jul 2008 A1
20080220244 Wai et al. Sep 2008 A1
20080286490 Bogdanoff et al. Nov 2008 A1
20080296268 Mike et al. Dec 2008 A1
20080305025 Vitner et al. Dec 2008 A1
20090074655 Suciu Mar 2009 A1
20090093553 Jager et al. Apr 2009 A1
20090155689 Zaghib et al. Jun 2009 A1
20090202869 Sawaki et al. Aug 2009 A1
20090258255 Terashima et al. Oct 2009 A1
20090305132 Gauthier et al. Dec 2009 A1
20100007162 Han et al. Jan 2010 A1
20100096362 Hirayama et al. Apr 2010 A1
20100176524 Burgess et al. Jul 2010 A1
20100219062 Leon Sanchez Sep 2010 A1
20110005461 Vandermeulen Jan 2011 A1
20110006254 Richard et al. Jan 2011 A1
20120015284 Merzougui et al. Jan 2012 A1
20120027955 Sunkara et al. Feb 2012 A1
20120034135 Risby Feb 2012 A1
20120048064 Kasper et al. Mar 2012 A1
20120051962 Imam et al. Mar 2012 A1
20120074342 Kim et al. Mar 2012 A1
20120100438 Fasching et al. Apr 2012 A1
20120112379 Beppu et al. May 2012 A1
20120122017 Mills May 2012 A1
20120224175 Minghetti Sep 2012 A1
20120230860 Ward-Close et al. Sep 2012 A1
20120240726 Kim et al. Sep 2012 A1
20120294919 Jaynes et al. Nov 2012 A1
20130032753 Yamamoto et al. Feb 2013 A1
20130071284 Kano et al. Mar 2013 A1
20130075390 Ashida Mar 2013 A1
20130078508 Tolbert et al. Mar 2013 A1
20130084474 Mills Apr 2013 A1
20130087285 Kofuji et al. Apr 2013 A1
20140048516 Gorodetsky et al. Feb 2014 A1
20140202286 Yokoyama et al. Jul 2014 A1
20140272430 Kalayaraman Sep 2014 A1
20140322632 Sugimoto et al. Oct 2014 A1
20140342093 Hadidi et al. Nov 2014 A1
20140373344 Takada et al. Dec 2014 A1
20150000844 Woo Jan 2015 A1
20150101454 Shimizu et al. Apr 2015 A1
20150167143 Luce et al. Jun 2015 A1
20150171455 Mills Jun 2015 A1
20150255767 Aetukuri et al. Sep 2015 A1
20150259220 Rosocha et al. Sep 2015 A1
20150270106 Kobayashi et al. Sep 2015 A1
20150333307 Thokchom et al. Nov 2015 A1
20160028088 Romeo et al. Jan 2016 A1
20160045841 Kaplan et al. Feb 2016 A1
20160152480 Jang et al. Jun 2016 A1
20160172163 Kaneko et al. Jun 2016 A1
20160189933 Kobayashi et al. Jun 2016 A1
20160209043 Gao et al. Jul 2016 A1
20160284519 Kobayashi et al. Sep 2016 A1
20160285090 Ozkan et al. Sep 2016 A1
20160287113 Hebert et al. Oct 2016 A1
20160308244 Badding et al. Oct 2016 A1
20160332232 Forbes Jones et al. Nov 2016 A1
20160351910 Albano et al. Dec 2016 A1
20160358757 Ikeda et al. Dec 2016 A1
20170009328 Germann et al. Jan 2017 A1
20170070180 Mills Mar 2017 A1
20170113935 Pennington et al. Apr 2017 A1
20170120339 Aslund May 2017 A1
20170125842 Meguro et al. May 2017 A1
20170151609 Elsen et al. Jun 2017 A1
20170176977 Huang et al. Jun 2017 A1
20170179477 Walters et al. Jun 2017 A1
20170368604 Wilkinson Dec 2017 A1
20170373344 Hadidi et al. Dec 2017 A1
20180022928 Blush Jan 2018 A1
20180083264 Soppe Mar 2018 A1
20180104745 L'Esperance et al. Apr 2018 A1
20180114677 Komatsu et al. Apr 2018 A1
20180130638 Ahmad et al. May 2018 A1
20180138018 Voronin et al. May 2018 A1
20180159178 Weisenstein et al. Jun 2018 A1
20180169763 Dorval et al. Jun 2018 A1
20180214956 Larouche et al. Aug 2018 A1
20180218883 Toshihiko Aug 2018 A1
20180226229 Stowell et al. Aug 2018 A1
20180241956 Suzuki Aug 2018 A1
20180248175 Ghezelbash et al. Aug 2018 A1
20180277849 Gayden Sep 2018 A1
20180294143 Chua et al. Oct 2018 A1
20180346344 Chen et al. Dec 2018 A1
20180366707 Johnson et al. Dec 2018 A1
20180375149 Beck et al. Dec 2018 A1
20190001416 Larouche et al. Jan 2019 A1
20190061005 Kelkar Feb 2019 A1
20190069944 Fischer Mar 2019 A1
20190084290 Stoyanov et al. Mar 2019 A1
20190088993 Ohta Mar 2019 A1
20190125842 Grabowski May 2019 A1
20190127835 Yang et al. May 2019 A1
20190157045 Meloni May 2019 A1
20190160528 McGee et al. May 2019 A1
20190165413 Furusawa May 2019 A1
20190173130 Schuhmacher et al. Jun 2019 A1
20190218650 Subramanian et al. Jul 2019 A1
20190271068 Sungail et al. Sep 2019 A1
20190292441 Hill et al. Sep 2019 A1
20190334206 Sastry et al. Oct 2019 A1
20190341650 Lanning et al. Nov 2019 A9
20190348202 Sachdev et al. Nov 2019 A1
20190362936 Van Den Berg et al. Nov 2019 A1
20190389734 Dietz et al. Dec 2019 A1
20200067128 Chmiola et al. Feb 2020 A1
20200136176 Chen Apr 2020 A1
20200153037 Renna et al. May 2020 A1
20200198977 Hof et al. Jun 2020 A1
20200203706 Holman et al. Jun 2020 A1
20200207668 Cavalli et al. Jul 2020 A1
20200215606 Barnes et al. Jul 2020 A1
20200220222 Watarai et al. Jul 2020 A1
20200223704 Neale et al. Jul 2020 A1
20200227728 Huang et al. Jul 2020 A1
20200254432 Shirman et al. Aug 2020 A1
20200276638 King et al. Sep 2020 A1
20200288561 Huh Sep 2020 A1
20200314991 Duanmu et al. Oct 2020 A1
20200335754 Ramasubramanian et al. Oct 2020 A1
20200335781 Oshita et al. Oct 2020 A1
20200346287 Badwe et al. Nov 2020 A1
20200350542 Wrobel et al. Nov 2020 A1
20200350565 Oshita et al. Nov 2020 A1
20200358093 Oshita et al. Nov 2020 A1
20200358096 Paulsen et al. Nov 2020 A1
20200381217 Kraus et al. Dec 2020 A1
20200388857 Sunkara et al. Dec 2020 A1
20200391295 Dorval et al. Dec 2020 A1
20200395607 Tzeng Dec 2020 A1
20200407858 Sano et al. Dec 2020 A1
20210002759 Zhang et al. Jan 2021 A1
20210024358 Chae et al. Jan 2021 A1
20210047186 Ifuku et al. Feb 2021 A1
20210057191 Stowell et al. Feb 2021 A1
20210075000 Holman et al. Mar 2021 A1
20210078072 Barnes et al. Mar 2021 A1
20210085468 Ryd et al. Mar 2021 A1
20210098826 Chung et al. Apr 2021 A1
20210129216 Barnes et al. May 2021 A1
20210139331 Kang et al. May 2021 A1
20210146432 Badwe et al. May 2021 A1
20210187607 Badwe et al. Jun 2021 A1
20210187614 Tsubota et al. Jun 2021 A1
20210226302 Lanning et al. Jul 2021 A1
20210252599 Hadidi et al. Aug 2021 A1
20210253430 Zaplotnik et al. Aug 2021 A1
20210273217 Park et al. Sep 2021 A1
20210273292 Yun et al. Sep 2021 A1
20210276094 Sobu et al. Sep 2021 A1
20210296731 Wrobel et al. Sep 2021 A1
20210308753 Larouche et al. Oct 2021 A1
20210310110 Stowell et al. Oct 2021 A1
20210339313 Motchenbacher et al. Nov 2021 A1
20210344059 Ekman et al. Nov 2021 A1
20210367264 Hadidi et al. Nov 2021 A1
20210408533 Holman et al. Dec 2021 A1
20220041457 Pullen et al. Feb 2022 A1
20220118517 Hadidi et al. Apr 2022 A1
20220127145 Ding et al. Apr 2022 A1
20220134431 Badwe et al. May 2022 A1
20220143693 Larouche et al. May 2022 A1
20220209298 Kim et al. Jun 2022 A1
20220223379 Holman et al. Jul 2022 A1
20220228288 Holman et al. Jul 2022 A1
20220267216 Holman et al. Aug 2022 A1
20220288685 Badwe Sep 2022 A1
20220314325 Badwe Oct 2022 A1
20220324022 Badwe Oct 2022 A1
20220352549 Kim et al. Nov 2022 A1
20230001375 Kozlowski et al. Jan 2023 A1
20230001376 Kozlowski et al. Jan 2023 A1
20230032362 Holman et al. Feb 2023 A1
20230144075 Badwe et al. May 2023 A1
20230211407 Hadidi Jul 2023 A1
20230219134 Houshmand et al. Jul 2023 A1
20230247751 Kozlowski et al. Aug 2023 A1
Foreign Referenced Citations (257)
Number Date Country
2003211869 Sep 2003 AU
2014394102 Jun 2020 AU
2947531 Nov 2015 CA
1188073 Jul 1998 CN
1653869 Aug 2005 CN
1675785 Sep 2005 CN
1967911 May 2007 CN
101191204 Jun 2008 CN
101391307 Mar 2009 CN
101728509 Jun 2010 CN
101716686 Feb 2011 CN
102328961 Jan 2012 CN
102394290 Mar 2012 CN
102412377 Apr 2012 CN
102427130 Apr 2012 CN
102664273 Sep 2012 CN
102723502 Oct 2012 CN
102179521 Jan 2013 CN
102867940 Jan 2013 CN
102983312 Mar 2013 CN
103121105 May 2013 CN
103402921 Nov 2013 CN
102554242 Dec 2013 CN
103456926 Dec 2013 CN
103682372 Mar 2014 CN
103682383 Mar 2014 CN
103700815 Apr 2014 CN
103874538 Jun 2014 CN
103956520 Jul 2014 CN
104064736 Sep 2014 CN
104084592 Oct 2014 CN
104209526 Dec 2014 CN
104218213 Dec 2014 CN
204156003 Feb 2015 CN
104485452 Apr 2015 CN
104752734 Jul 2015 CN
103515590 Sep 2015 CN
105514373 Apr 2016 CN
104772473 Sep 2016 CN
106001597 Oct 2016 CN
106159316 Nov 2016 CN
106450146 Feb 2017 CN
106493350 Mar 2017 CN
206040854 Mar 2017 CN
106684387 May 2017 CN
106784692 May 2017 CN
107093732 Aug 2017 CN
107170973 Sep 2017 CN
107579241 Jan 2018 CN
108134104 Jun 2018 CN
108145170 Jun 2018 CN
108217612 Jun 2018 CN
108649190 Oct 2018 CN
108666563 Oct 2018 CN
108672709 Oct 2018 CN
108878862 Nov 2018 CN
108907210 Nov 2018 CN
108933239 Dec 2018 CN
108963239 Dec 2018 CN
109167070 Jan 2019 CN
109301212 Feb 2019 CN
109616622 Apr 2019 CN
109742320 May 2019 CN
109808049 May 2019 CN
109888233 Jun 2019 CN
110153434 Aug 2019 CN
110218897 Sep 2019 CN
110299516 Oct 2019 CN
110790263 Feb 2020 CN
110993908 Apr 2020 CN
111099577 May 2020 CN
111342163 Jun 2020 CN
111370751 Jul 2020 CN
111403701 Jul 2020 CN
111515391 Aug 2020 CN
111970807 Nov 2020 CN
112259740 Jan 2021 CN
112331947 Feb 2021 CN
112397706 Feb 2021 CN
112421006 Feb 2021 CN
112421048 Feb 2021 CN
112447977 Mar 2021 CN
112768709 May 2021 CN
112768710 May 2021 CN
112768711 May 2021 CN
112864453 May 2021 CN
113097487 Jul 2021 CN
113104838 Jul 2021 CN
113764688 Dec 2021 CN
113871581 Dec 2021 CN
114388822 Apr 2022 CN
114744315 Jul 2022 CN
114824297 Jul 2022 CN
115394976 Nov 2022 CN
10335355 Nov 2004 DE
102009033251 Sep 2010 DE
102010006440 Aug 2011 DE
102011109137 Feb 2013 DE
102018132896 Jun 2020 DE
0 256 233 Feb 1988 EP
2 292 557 Mar 2011 EP
3 143 838 Mar 2017 EP
3474978 May 2019 EP
2525122 Oct 1983 FR
2591412 Jun 1987 FR
2595745 Dec 2021 GB
202117004272 Mar 2021 IN
202011017775 Oct 2021 IN
10-172564 Jun 1998 JP
10-296446 Nov 1998 JP
11-064556 Mar 1999 JP
2001-348296 Dec 2001 JP
2002-249836 Sep 2002 JP
2002-332531 Nov 2002 JP
2004-505761 Feb 2004 JP
2004-193115 Jul 2004 JP
2004-311297 Nov 2004 JP
2004-362895 Dec 2004 JP
2004340414 Dec 2004 JP
2005-015282 Jan 2005 JP
2005-072015 Mar 2005 JP
2005-076052 Mar 2005 JP
2005-135755 May 2005 JP
2005-187295 Jul 2005 JP
2005-222956 Aug 2005 JP
2005-272284 Oct 2005 JP
2006-040722 Feb 2006 JP
2007-113120 May 2007 JP
2007-138287 Jun 2007 JP
2007-149513 Jun 2007 JP
2007-238402 Sep 2007 JP
2008-230905 Oct 2008 JP
2008-243447 Oct 2008 JP
2009-187754 Aug 2009 JP
2010-024506 Feb 2010 JP
2010-097914 Apr 2010 JP
2011-108406 Jun 2011 JP
2011-222323 Nov 2011 JP
2011-258348 Dec 2011 JP
2012-046393 Mar 2012 JP
2012-151052 Aug 2012 JP
2012-234788 Nov 2012 JP
2013-062242 Apr 2013 JP
2013-063539 Apr 2013 JP
2013-069602 Apr 2013 JP
2013-076130 Apr 2013 JP
2015-048269 Mar 2015 JP
2015-122218 Jul 2015 JP
2016-029193 Mar 2016 JP
2016-047961 Apr 2016 JP
6103499 Mar 2017 JP
2017-524628 Aug 2017 JP
2018-141762 Sep 2018 JP
2018-190563 Nov 2018 JP
2019-055898 Apr 2019 JP
2019-516020 Jun 2019 JP
2019-520894 Jul 2019 JP
2020-121898 Aug 2020 JP
2021-061089 Apr 2021 JP
2021-061090 Apr 2021 JP
2021-116191 Aug 2021 JP
10-0582507 May 2006 KR
10-2007-0076686 Jul 2007 KR
10-2009-0070140 Jul 2009 KR
10-1133094 Apr 2012 KR
20140001813 Sep 2012 KR
10-1684219 Dec 2016 KR
10-2017-0039922 Apr 2017 KR
10-2017-0045181 Apr 2017 KR
2018-0001799 Jan 2018 KR
10-2018-0035750 Apr 2018 KR
10-1907912 Oct 2018 KR
10-1907916 Oct 2018 KR
10-1923466 Nov 2018 KR
10-2101006 Apr 2020 KR
10-2124946 Jun 2020 KR
10-2020-0131751 Nov 2020 KR
10-2021-0057253 May 2021 KR
2744449 Mar 2021 RU
521539 Feb 2003 TW
200823313 Jun 2008 TW
I329143 Aug 2010 TW
201112481 Apr 2011 TW
201310758 Mar 2013 TW
201411922 Mar 2014 TW
I593484 Aug 2017 TW
0377333 Sep 2003 WO
2004054017 Jun 2004 WO
2004089821 Oct 2004 WO
WO 2005039752 May 2005 WO
2006100837 Sep 2006 WO
2010095726 Aug 2010 WO
2011090779 Jul 2011 WO
WO 2011082596 Jul 2011 WO
2012023858 Feb 2012 WO
2012114108 Aug 2012 WO
WO 2012144424 Oct 2012 WO
2012162743 Dec 2012 WO
2013017217 Feb 2013 WO
2014011239 Jan 2014 WO
2014110604 Jul 2014 WO
2014153318 Sep 2014 WO
WO 2015064633 May 2015 WO
WO 2015174949 Nov 2015 WO
2015187389 Dec 2015 WO
WO 2016048862 Mar 2016 WO
2016091957 Jun 2016 WO
2017074081 May 2017 WO
2017074084 May 2017 WO
2017080978 May 2017 WO
WO 2017091543 Jun 2017 WO
WO 2017106601 Jun 2017 WO
2017118955 Jul 2017 WO
2017130946 Aug 2017 WO
2017158349 Sep 2017 WO
2017178841 Oct 2017 WO
WO 2017177315 Oct 2017 WO
WO 2017223482 Dec 2017 WO
2018133429 Jul 2018 WO
WO 2018141082 Aug 2018 WO
2019052670 Mar 2019 WO
WO 2019045923 Mar 2019 WO
WO 2019095039 May 2019 WO
WO 2019139773 Jul 2019 WO
WO 2019243870 Dec 2019 WO
WO 2019246242 Dec 2019 WO
WO 2019246257 Dec 2019 WO
WO 2020009955 Jan 2020 WO
2020041767 Feb 2020 WO
2020041775 Feb 2020 WO
WO 2020091854 May 2020 WO
WO 2020132343 Jun 2020 WO
WO 2020223358 Nov 2020 WO
WO 2020223374 Nov 2020 WO
2021029769 Feb 2021 WO
WO 2021046249 Mar 2021 WO
2021085670 May 2021 WO
2021115596 Jun 2021 WO
WO 2021118762 Jun 2021 WO
WO 2021127132 Jun 2021 WO
2021159117 Aug 2021 WO
2021191281 Sep 2021 WO
2021245410 Dec 2021 WO
2021245411 Dec 2021 WO
WO 2021263273 Dec 2021 WO
2022005999 Jan 2022 WO
2022032301 Feb 2022 WO
2022043701 Mar 2022 WO
2022043702 Mar 2022 WO
2022043704 Mar 2022 WO
2022043705 Mar 2022 WO
2022067303 Mar 2022 WO
2022075846 Apr 2022 WO
2022107907 May 2022 WO
2022133585 Jun 2022 WO
2022136699 Jun 2022 WO
2023022492 Feb 2023 WO
Non-Patent Literature Citations (107)
Entry
Ajayi, B. P. et al., “Atmospheric plasma spray pyrolysis of lithiated nickel-manganese-cobalt oxides for cathodes in lithium ion batteries”, Chemical Engineering Science, vol. 174, Sep. 14, 2017, pp. 302-310.
Dearmitt, C., “26. Functional Fillers for Plastics”, in Applied Plastics Engineering Handbook—Processing and Materials, ed., Myer Kutz, Elsevier, 2011, pp. 455-468.
Gleiman, S. et al., “Melting and spheroidization of hexagonal boron nitride in a microwave-powered, atmospheric pressure nitrogen plasma”, Journal of Materials Science, Aug. 2002, vol. 37(16), pp. 3429-3440.
Houmes et al., “Microwave Synthesis of Ternary Nitride Materials”, Journal of Solid State Chemistry, vol. 130, Issue 2, May 1997, pp. 266-271.
Majewksi, T., “Investigation of W—Re—Ni heavy alloys produced from plasma spheroidized powders”, Solid State Phenomena, Mar. 2013, vol. 199, pp. 448-453.
Moldover, M. R. et al., “Measurement of the Universal Gas Constant R Using a Spherical Acoustic Resonator”, Physical Review Letters, Jan. 1988, vol. 60(4), pp. 249-252.
Murugan et al. “Nanostructured a/ß-tungsten by reduction of WO3 under microwave plasma”, Int. Journal of Refractory Metals and Hard Materials 29 (2011) 128-133. (Year: 2011).
Nichols, F. A., “On the spheroidization of rod-shaped particles of finite length”, Journal of Materials Science, Jun. 1976, vol. 11, pp. 1077-1082.
Park et al. “Preparation of spherical WTaMoNbV refractory high entropy alloy powder by inductively-coupled thermal plasma”, Materials Letters 255 (2019) 126513 (Year: 2019).
Walter et al., “Microstructural and mechanical characterization of sol gel-derived Si—O—C glasses” Journal of the European Ceramic Society, vol. 22, Issue 13, Dec. 2002, pp. 2389-2400.
Zhang, X. et al., “High thickness tungsten coating with low oxygen content prepared by air plasma spray”, Cailliao Gongcheng, 2014, vol. 5, pp. 23-28.
Zhang, Y. S. et al., “Core-shell structured titanium-nitrogen alloys with high strength, high thermal stability and good plasticity”, Scientific Reports, Jan. 2017, vol. 7, in 8 pages.
“Build Boldly”, Technology Demonstration, 6K Additive, [publication date unknown], in 11 pages.
Ajayi, B. et al., “A rapid and scalable method for making mixed metal oxide alloys for enabling accelerated materials discovery”, Journal of Materials Research, Jun. 2016, vol. 31, No. 11, pp. 1596-1607.
Bobzin, K. et al., “Modelling and Diagnostics of Multiple Cathodes Plasma Torch System for Plasma Spraying”, Frontiers of Mechanical Engineering, Sep. 2011, vol. 6, pp. 324-331.
Bobzin, K. et al., “Numerical and Experimental Determination of Plasma Temperature during Air Plasma Spraying with a Multiple Cathodes Torch”, Journal of Materials Processing Technology, Oct. 2011, vol. 211, pp. 1620-1628.
Boulos, M., “The inductively coupled radio frequency plasma”, Journal of High Temperature Material Process, 1997, vol. 1, pp. 17-39.
Boulos, M., “Induction Plasma Processing of Materials for Powders, Coating, and Near-Net-Shape Parts”, Advanced Materials & Processes, Aug. 2011, pp. 52-53, in 3 pages.
Boulos, M., “Plasma power can make better powders”, Metal Powder Report, May 2004, vol. 59(5), pp. 16-21.
Carreon, H. et al., “Study of Aging Effects in a Ti—6Al—4V alloy with Widmanstatten and Equiaxed Microstructures by Non-destructive Means”, AIP Conference Proceedings 1581, 2014 (published online Feb. 17, 2015), pp. 739-745.
Chang, S. et al., “One-Step Fast Synthesis of Li4Ti5O12 Particles Using an Atmospheric Pressure Plasma Jet”, Journal of the American Ceramic Society, Dec. 26, 2013, vol. 97, No. 3, pp. 708-712.
Chen, G. et al., “Spherical Ti—6Al—4V Powders Produced by Gas Atomization”, Key Engineering Materials, vol. 704, Aug. 2016, pp. 287-292. URL: https://www.scientific.net/KEM.704.287.
Chikumba, S. et al., “High Entropy Alloys: Development and Applications”, 7th International Conference on Latest Trends in Engineering & Technology (ICLTET'2015), Nov. 26-27, 2015, Irene, Pretoria (South Africa), pp. 13-17.
Coldwell, D. M. et al., “The reduction of SiO2 with Carbon in a Plasma”, Journal of Electrochemical Society, Jan. 1977, vol. 124, pp. 1686-1689.
Dolbec, R., “Recycling Spherical Powders”, Presented at Titanium 2015, Orlando, FL, Oct. 2015, in 20 pages.
Fuchs, G.E. et al., “Microstructural evaluation of as-solidified and heat-treated y-TiAl based powders”, Materials Science and Engineering, 1992, A152, pp. 277-282.
Gradl, P. et al., “GRCop-42 Development and Hot-fire Testing Using Additive Manufacturing Powder Bed Fusion for Channel-Cooled Combustion Chambers”, 55th AIAA/SAE/ASEE Joint Propulsion Conference 2019, Aug. 2019, pp. 1-26.
He, J. Y. et al., “A precipitation-hardened high-entropy alloy with outstanding tensile properties”, Acta Materialia, 2016, vol. 102, pp. 187-196.
Ivasishin, O. M. et al., “Innovative Process for Manufacturing Hydrogenated Titanium Powder for Solid State Production of P/M Titanium Alloy Components”, Titanium 2010, Oct. 3-6, 2010, in 27 pages.
Jia, H. et al., “Hierarchical porous silicon structures with extraordinary mechanical strength as high-performance lithium-ion battery anodes”, Nature Communications, Mar. 2020, vol. 11, in 9 pages. URL: https://doi.org/10.1038/s41467-020-15217-9.
Ko, M. et al., “Challenges in Accommodating Volume Change of Si Anodes for Li-Ion Batteries”, Chem Electro Chem, Aug. 2015, vol. 2, pp. 1645-1651. URL: https://doi.org/10.1002/celc.201500254.
Kotlyarov, V. I. et al., “Production of Spherical Powders on the Basis of Group IV Metals for Additive Manufacturing”, Inorganic Materials: Applied Research, Pleiades Publishing, May 2017, vol. 8, No. 3, pp. 452-458.
Laine, R. M. et al., “Making nanosized oxide powders from precursors by flame spray pyrolysis”, Key Engineering Materials, Jan. 1999, vol. 159-160, pp. 17-24.
Li, X. et al., “Mesoporous silicon sponge as an anti-pulverization structure for high-performance lithium-ion battery anodes”, Nature Communications, Jul. 2014, vol. 5, Article No. 4105, in 7 pages. URL: https://doi.org/10.1038/ncomms5105.
Li, L. et al., “Spheroidization of silica powders by radio frequency inductively coupled plasma with Ar—H2 and Ar—N2 as the sheath gases at atmospheric pressure”, International Journal of Minerals, Metallurgy, and Materials, Sep. 2017, vol. 24(9), pp. 1067-1074.
Li, Z. et al., “Strong and Ductile Non-Equiatomic High-Entropy Alloys: Design, Processing, Microstructure, and Mechanical Properties”, The Journal of The Minerals, Metals & Materials Society, Aug. 2017, vol. 69(1), pp. 2099-2106. URL: https://doi.org/10.1007/s11837-017-2540-2.
Lin, M., “Gas Quenching with Air Products' Rapid Gas Quenching Gas Mixture”, Air Products, Dec. 31, 2007, in 4 pages. URL: https://www.airproducts.co.uk/-/media/airproducts/files/en/330/330-07-085-US-gas-quenching-with-air-products-rapid-gas-quenching-gas-mixture.pdf.
Moisan, M. et al., “Waveguide-Based Single and Multiple Nozzle Plasma Torches: the Tiago Concept”, Plasma Sources Science and Technology, Jun. 2001, vol. 10, pp. 387-394.
Muoto, C. et al., “Phase Homogeneity in Y2O3—MgO Nanocomposites Synthesized by Thermal Decomposition of Nitrate Precursors with Ammonium Acetate Additions”, Journal of the American Ceramic Society, 2011, vol. 94(12), pp. 4207-4217.
Nyutu, E. et al., “Ultrasonic Nozzle Spray in Situ Mixing and Microwave-Assisted Preparation of Nanocrystalline Spinel Metal Oxides: Nickel Ferrite and Zinc Aluminate”, Journal of Physical Chemistry C, Feb. 1, 2008, vol. 112, No. 5, pp. 1407-1414.
Ohta, R. et al., “Effect of PS-PVD production throughput on Si nanoparticles for negative electrode of lithium ion batteries”, Journal of Physics D: Applied Physics, Feb. 2018, vol. 51(1), in 7 pages.
Or, T. et al., “Recycling of mixed cathode lithium-ion batteries for electric vehicles: Current status and future outlook”, Carbon Energy, Jan. 2020, vol. 2, pp. 6-43. URL: https://doi.org/10.1002/cey2.29.
Popescu, G. et al., “New TiZrNbTaFe high entropy alloy used for medical applications”, IOP Conference Series: Materials Science and Engineering, Mod Tech 2018, Sep. 2018, vol. 400, in 9 pages.
Reig, L. et al., “Microstructure and Mechanical Behavior of Porous Ti—6Al—4V Processed by Spherical Powder Sintering”, Materials, Oct. 23, 2013, vol. 6, pp. 4868-4878.
Sastry, S.M.L. et al., “Rapid Solidification Processing of Titanium Alloys”, Journal of Metals (JOM), Sep. 1983, vol. 35, pp. 21-28.
Savage, S. J. et al., “Production of rapidly solidified metals and alloys”, Journal of Metals (JOM), Apr. 1984, vol. 36, pp. 20-33.
Sheng, Y. et al., “Preparation of Spherical Tungsten Powder by RF Induction Plasma”, Rare Metal Materials and Engineering, Nov. 2011, vol. 40, No. 11, pp. 2033-2037.
Sheng, Y. et al., “Preparation of Micro-spherical Titanium Powder by RF Plasma”, Rare Metal Materials and Engineering, Jun. 2013, vol. 42, No. 6, pp. 1291-1294.
Suryanarayana, C., “Recent Developments in Mechanical Alloying”, Reviews on Advanced Materials Science, Aug. 2008, vol. 18(3), pp. 203-211.
Suryanarayana, C. et al., “Rapid solidification processing of titanium alloys”, International Materials Reviews, 1991, vol. 36, pp. 85-123.
Tang, H. P. et al., “Effect of Powder Reuse Times on Additive Manufacturing of Ti—6Al—4V by Selective Electron Beam Melting”, JOM, Mar. 2015, vol. 67, pp. 555-563.
Van Laar, J. H. et al., “Spheroidisation of Iron Powder in a Microwave Plasma Reactor”, Journal of the Southern African Institute of Mining and Metallurgy, Oct. 2016, vol. 116, No. 10, pp. 941-946.
Veith, M. et al., “Low temperature synthesis of nanocrystalline Y3Al5O12 (YAG) and Cedoped Y3Al5O12 via different sol-gel methods”, The Journal of Materials Chemistry, Jan. 1999, vol. 9, pp. 3069-3079.
Wang, J. et al., “Preparation of Spherical Tungsten and Titanium Powders by RF Induction Plasma Processing”, Rare Metals, Jun. 2015 (published online May 31, 2014), vol. 34, No. 6, pp. 431-435.
Wang, Y. et al., “Developments in Nanostructured Cathode Materials for High-Performance Lithium-Ion Batteries”, Advanced Materials, Jun. 2008, pp. 2251-2269.
Yang, S. et al., “Preparation of Spherical Titanium Powders from Polygonal Titanium Hydride Powders by Radio Frequency Plasma Treatment”, Materials Transactions, Nov. 2013, vol. 54, No. 12, pp. 2313-2316.
Zhang, K., Ph.D., “The Microstructure and Properties of Hipped Powder Ti Alloys”, a thesis submitted to The University of Birmingham, College of Engineering and Physical Sciences, Apr. 2009, in 65 pages.
Zhang, Y. et al., “Microstructures and properties of high-entropy alloys”, Progress in Materials Science, Apr. 2014 (available online Nov. 2013), vol. 61, pp. 1-93.
Zhang, Y. D. et al., “High-energy cathode materials for Li-ion batteries: A review of recent developments”, Science China Technological Sciences, Sep. 2015, vol. 58(11), pp. 1809-1828.
Zielinski, A. et al., “Modeling and Analysis of a Dual-Channel Plasma Torch in Pulsed Mode Operation for Industrial, Space, and Launch Applications”, IEEE Transactions on Plasma Science, Jul. 2015, vol. 43(7), pp. 2201-2206.
International Search Report and Written Opinion, re PCT Application No. PCT/US2021/071519, dated Dec. 10, 2021.
“High-entropy alloy”, Wikipedia, webpage last edited Dec. 29, 2022 (accessed Jan. 17, 2023), in 16 pages. URL: https://en.wikipedia.org/wiki/High-entropy_alloy.
Ali, MY., et al., Spray Flame Synthesis (SFS) of Lihium Lanrthaum Zirconate (LLZO) Solid Electroly, Materials, vol. 14, No. 13, 2021, pp. 1-13.
Barbis et al., “Titanium powders from the hydride-dehydride process.” Titanium Powder Metallurgy. Butterworth-Heinemann, 2015. pp. 101-116.
Bardos, L., et al., “Differences between microwave and RF activation of nitrogen for the PECVD process”, J. Phys. D: Appl. Phys., vol. 15, 1982, pp. 79-82.
Bardos, L., et al., “Microwave Plasma Sources and Methods in Processing Technology”, IEEE Press, 2022, 10 pages.
Choi, S. I., et al., “Continuous process of carbon nanotubes synthesis by decomposition of methane using an arc-jet plasma”, Thin Solid Films, 2006, vol. 506-507, 2006, pp. 244-249.
Collin, J. E., et al., “Ionization of methane and it's electronic energy levels”, Canadian Journal of Chemistry, 2011, vol. 45, No. 16, pp. 1875-1882.
Decker, J., et al., “Sample preparation protocols for realization of reproducible characterization of single-wall carbon nanotubes”, Metrologia, 2009, vol. 46, No. 6, pp. 682-692.
Ding, F., et al., “Nucleation and Growth of Single-Walled Carbon Nanotubes: A Molecular Dynamics Study”, J. Phys. Chem. B, vol. 108, 2004, pp. 17369-17377.
Ding, F., et al., “The Importance of Strong Carbon-Metal Adhesion for Catalytic Nucleation of Single-Walled Carbon Nanotubes”, Nano Letters, 2008, vol. 8, No. 2, pp. 463-468.
Dors, M., et al., “Chemical Kinetics of Methane Pyrolysis in Microwave Plasma at Atmospheric Pressure”, Plasma Chem Plasma Process, 2013, vol. 34, No. 2, pp. 313-326.
Eremin, A., et al., “The Role of Methyl Radical in Soot Formation”, Combustion Science and Technology, vol. 191, No. 12, 2008, pp. 2226-2242.
Finckle, J. R., et al., “Plasma Pyrolysis of Methane to Hydrogen and Carbon Black”, Industrial Engineering and Chemical Research, 2002. vol. 41, No. 6, 2002, pp. 1425-1435.
Fu, D., et al., “Direct synthesis of Y-junction carbon nanotubes by microwave-assisted pyrolysis of methane”, Materials Chemistry and Physics, vol. 118, vol. 2-3, 2009, pp. 501-505.
Grace, J. et al., “Connecting particle sphericity and circularity”, Particuology, vol. 54, 2021, pp. 1-4, ISSN 1674-2001, https://doi .org/10.1016/j.partic.2020.09.006. (Year: 2020).
Haghighatpanah, S., et al., “Computational studies of catalyst-free single walled carbon nanotube growth”, J Chem Phys, vol. 139, No. 5, 10 pages.
Haneklaus, N., et al., “Stop Smoking—Tube-In-Tube Helical System for Flameless Calcination of Minerals,” Processes, vol. 5, No. 4, Nov. 3, 2017, pp. 1-12.
Huo, H., et al., “Composite electrolytes of polyethylene oxides/garnets interfacially wetted by ionic liquid for room-temperature solid-state lithium battery”, Journal of Power Sources, vol. 372, 2017, pp. 1-7.
International Preliminary Report on Patentability and Written Opinion, re PCT Application No. PCT/US2021/071519, dated Apr. 6, 2023.
Irle, S., et al., “Milestones in molecular dynamics simulations of single-walled carbon nanotube formation: A brief critical review”, Nano Research, 2009, vol. 2, No. 10, pp. 755-767.
Jasek, O., et al., “Microwave plasma-based high temperature dehydrogenation of hydrocarbons and alcohols as a single route to highly efficient gas phase synthesis of freestanding graphene”, Nanotechnology, 2021, vol. 32, 11 pages.
Jasinski, M., et al., “Atmospheric pressure microwave plasma source for hydrogen production”, International Journal of Hydrogen Energy, vol. 38, Issue 26, 2013, pp. 11473-11483.
Jasinski, M., et al., “Hydrogen production via methane reforming using various microwave plasma sources”, Chem. Listy, 2008, vol. 102, pp. s1332-s1337.
Kassel, L. S., “The Thermal Decomposition of Methane”, Journal of the American Chemical Society, vol. 54, No. 10, 1932, pp. 3949-3961.
Kerscher, F., et al., “Low-carbon hydrogen production via electron beam plasma methane pyrolysis: Techno-economic analysis and carbon footprint assessment”, International Journal of Hydrogen Energy, vol. 46, Issue 38, 2021, pp. 19897-19912.
Kim, K. S., et al., “Synthesis of single-walled carbon nanotubes by induction thermal plasma”, Nano Research, 2009, vol. 2, No. 10, pp. 800-817.
Kumal, R. R., et al., “Microwave Plasma Formation of Nanographene and Graphitic Carbon Black”, C, 2020, vol. 6, No. 4, 10 pages.
Lee, D. H., et al., “Comparative Study of Methane Activation Process by Different Plasma Sources”, Plasma Chem. Plasma Process., vol. 33, No. 4, 2013, pp. 647-661.
Lee, D. H., et al., “Mapping Plasma Chemistry in Hydrocarbon Fuel Processing Processes”, Plasma Chem. Plasma Process., vol. 33, No. 1, 2013, pp. 249-269.
Liu, Y., et al., “Advances of microwave plasma-enhanced chemical vapor deposition in fabrication of carbon nanotubes: a review”, J Mater Sci., vol. 55, 2021, pp. 12559-12583.
Olsvik, O., et al., “Thermal Coupling of Methane—A Comparison Between Kinetic Model Data and Experimental Data”, Thermochimica Acta., vol. 232, No. 1, 1994, pp. 155-169.
Pulsation Reactors—Thermal Processing for Extraordinary Material Properties, retrieved from https://www.ibu-tec.com/facilities/pulsation-reactors/, retrieved on Mar. 18, 2023, pp. 5.
Seehra, M. S., et al., “Correlation between X-ray diffraction and Raman spectra of 16 commercial graphene-based materials and their resulting classification”, Carbon N Y., 2017, vol. 111, pp. 380-384.
Wang, H., et al., “A detailed kinetic modeling study of aromatics formation in laminar premixed acetylene and ethylene flames” Combustion and Flame, vol. 110, No. 1-2, 1997, pp. 173-221.
Zavilopulo, A. N., et al., “Ionization and Dissociative Ionization of Methane Molecules”, Technical Physics, vol. 58, No. 9, 2013, pp. 1251-1257.
Zeng, X., et al., “Growth and morphology of carbon nanostructures by microwave-assisted pyrolysis of methane”, Physica E., vol. 42, No. 8, 2010, pp. 2103-2108.
Zhang, H., et al., “Plasma activation of methane for hydrogen production in a N2 rotating gliding arc warm plasma: A chemical kinetics study”, Chemical Engineering Journal, vol. 345, 2018, pp. 67-78.
Zhang, J., et al., “Flexible and ion-conducting membrane electrolytes for solid-state lithium batteries: Dispersion of garnet nanoparticles in insulating polyethylene oxide”, Nano Energy, vol. 28, 2016, pp. 447-454.
Zhong, R., et al., “Continuous preparation and formation mechanism of few-layer graphene by gliding arc plasma”, Chemical Engineering Journal, vol. 387, 2020, 10 pages.
6K, “6K Launches World's First Premium Metal Powders for Additive Manufacturing Derived From Sustainable Sources”, Cision PR Newswire, Nov. 4, 2019, in 1 page. URL: https://www.prnewswire.com/news-releases/6k-launches-worlds-first-premium-metal-powders-for-additive-manufacturing-derived-from-sustainable-sources-300950791.html.
Chau, J. L. K. et al. “Microwave Plasma Production of Metal Nanopowders,” Jun. 12, 2014, Inorganics, vol. 2, pp. 278-290 (Year: 2014).
Chen, Z., et al., “Advanced cathode materials for lithium-ion batteries”, MRS Bulletin, vol. 36, No. 7, Jul. 2011, pp. 498-505.
Kim, H., et al., “Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries”, Angewandte Chemie International Edition, vol. 47, No. 2, Dec. 15, 2008, pp. 10151-10154.
Kim, S. et al., “Thermodynamic Evaluation of Oxygen Behavior in Ti Powder Deoxidized by Ca Reductant”, Met. Mater. Int., 2016, vol. 22, pp. 658-662.
Taylor, G., et al.; “Reduction of Metal Oxides by Hydrogen”, 1930, vol. 52 (Year: 1930).
Japanese Office Action, re JP Application No. 2023-518404, dated Jan. 9, 2024, 15 pages.
Related Publications (1)
Number Date Country
20220095445 A1 Mar 2022 US
Provisional Applications (1)
Number Date Country
63082919 Sep 2020 US