The disclosure relates to pull-tab sealing members for sealing the mouth of a container, and more particularly, to pull-tab sealing members having a tab with enhanced gripping functionality.
It is often desirable to seal the opening of a container using a removable or peelable seal, sealing member, or inner seal. Often a cap or other closure is then screwed or placed over the container opening capturing the sealing member therein. In use, a consumer typically removes the cap or other closure to gain access to the sealing member and then removes or otherwise peels the seal from the container in order to dispense or gain access to its contents.
Initial attempts at sealing a container opening utilized an induction- or conduction-type inner seal covering the container's opening where the seal generally conformed to the shape of the opening such that a circular container opening was sealed with a round disk approximately the same size as the opening. These prior seals commonly had a lower heat activated sealing layer to secure a periphery of the seal to a rim or other upper surface surrounding the container's opening. Upon exposing the seal to heat, the lower layer bonded to the container's rim. In many cases, these seals included a foil layer capable of forming induction heat to activate the lower heat seal layer. These prior seals tended to provide good sealing, but were often difficult for a consumer to remove because there was nothing for the consumer to grab onto in order to remove the seal. Often, the consumer needed to pick at the seal's edge with a fingernail because there was little or no seal material to grasp.
Other types of seals for containers include a side tab or other flange that extended outwardly from a peripheral edge of the seal. These side tabs are generally not secured to the container rim and provide a grasping surface for a consumer to hold and peel off the seal. These side tabs, however, extend over the side of the container rim and often protrude into a threaded portion of the closure. If the side tab is too large, this configuration may negatively affect the ability of the seal to form a good heat seal. The side tabs (and often the seal itself) can be deformed or wrinkled when the closure or other cap is placed on the container due to contact between the closure (and threads thereof) and tabbed part of the seal. To minimize these concerns, the side tabs are often very small; thus, providing little surface area or material for a consumer to grasp in order to remove the seal.
Yet other types of seals include a sealing member having a tab defined on the top of the seal. One approach of these prior seals includes a partial layer of coated pressure sensitive adhesive to secure the tab to a layer of metal foil. The tab was formed by a full layer extending across the entire surface of the sealing member, but the full layer was only bonded to half of the seal to form the tab. This type of top-tabbed seal offered the advantage of a larger tab, which provided more grasping area for the consumer to hold and peel off the seal, but required a full additional layer of material in order to form the tab. In other approaches, the seal may include a tab formed from the additional full layer of film combined with an additional full layer of adhesive utilizing a part paper or part polymer layer, called a tab stock, to form the tab. This part layer is inserted between the additional full layer of adhesive and lower seal portions to prevent the tab from sticking to the layers below, which formed the tab.
However, even in these tabbed forms, the tab may still be difficult for a user to grasp to remove the seal. For example, the tab itself may be slippery, thin, and/or not provide appropriate surface area for a user to maintain sufficient grip. This is especially problematic when all of these issues combine, such as in the case of a small container and/or tab along with a tab including materials with lower coefficients of friction. If a user cannot quickly and safely remove the tab, but instead must use some other means of removing the seal, the main function of the tab is lost.
Various enhancements of tabbed seals are provided herein with enhanced grasping functionality. The below described embodiments may be used separately or may be used with two or more of the enhancements in combination with one another.
In one form, the tabbed seal includes a greater surface area for the gripping tab than in many previous forms. However, prior seals that have attempted to incorporate larger free tabs have encountered difficulties such as the tab moving during cap installation and/or sealing. In this regard, the tab can fold on itself, crease, or otherwise move. This can deform the tab, make sealing difficult, and/or make cap installation difficult. To overcome these difficulties, a new tab has been configured such that the overall gripping tab is larger, but a portion thereof is temporarily adhered to the lower laminate, such as during seal and/or cap installation. Instead, the gripping tab includes a small free portion and then a second, temporarily bonded portion that can either release or rupture, permitting the overall grippable portion of the tab to be large. In some forms, the gripping tab portion may be at least 50% of the overall diameter, width, and/or upper surface area of the seal. In other forms, the gripping tab portion may be larger, such as 70%, 80%, and 90% or more. The remaining portion of the upper laminate may be more permanently adhered to the lower laminate so that the seal may be removed from the container.
According to one form, a tabbed sealing member for sealing to a rim surrounding a container opening is provided. The sealing member includes a lower laminate portion, an upper laminate portion, a release layer, a tab layer, and a bonding layer. The lower laminate portion includes a sealant layer for sealing to the rim of the container and a support layer above the sealant layer. The bonding layer partially bonds the upper laminate portion to the lower laminate portion to form a gripping tab, the gripping tab configured for removing the sealing member from the container opening. The gripping tab is formed having a first free portion defined by at least a portion of the tab layer, a second temporarily bonded portion, and a third permanently bonded portion. The second temporarily bonded portion is formed by at least a portion of the release layer and configured to release from one of the upper and lower laminate portions or rupture, permitting a user to grasp the first free portion and the second temporarily bonded portion to remove the tabbed sealing member from the container.
In accordance with one form, a tabbed sealing member for sealing to a rim surrounding a container opening is provided. The tabbed sealing member has an upper surface area. Further, the tabbed sealing member includes a lower laminate portion, an upper laminate portion, a release layer, and a bonding layer. The lower laminate portion includes a sealant layer for sealing to the rim of the container and a support layer above the sealant layer. The bonding layer partially bonds the upper laminate portion to the lower laminate portion to form a gripping tab. The gripping tab is configured for removing the sealing member from the container opening. The gripping tab is formed having a first free portion with an area less than 50% of the upper surface area, a second temporarily bonded portion, and a third permanently bonded portion. The second temporarily bonded portion is defined by at least a portion of the release layer. The first free portion and the second temporarily bonded portion have an area greater than 50% of the upper surface area, whereby a user can grasp the first free portion and the second temporarily bonded portion to remove the tabbed sealing member from the container.
According to one form, a laminate for forming a tabbed sealing member for sealing to a rim surrounding a container opening is provided. The laminate includes a lower laminate portion, an upper laminate portion, a release layer, a tab layer, and a bonding layer. The lower laminate portion includes a sealant layer for sealing to the rim of the container and a support layer above the sealant layer. The bonding layer partially bonds the upper laminate portion to the lower laminate portion to form a gripping tab when the laminate is formed into the tabbed sealing member. The gripping tab is configured for removing the sealing member from the container opening. The laminate has a width with a first portion of the width having the upper and lower laminate portions being unbonded to one another adjacent a portion of the tab layer, a second portion of the width where the upper and lower laminate portions are temporarily bonded to one another via at least a portion of the release layer, and a third portion of the width where the upper and lower laminate portions are permanently bonded to one another via at least a portion of the bonding layer.
In one form, the tab layer includes a tab stock having a release coating, the tab layer bonded to at least part of at least one of the upper and lower laminate portions.
In accordance with one form, the release layer forms part of at least one of the upper and lower laminate portions.
According to one form, the bonding layer forms part of at least one of the upper and lower laminate portions.
In one form, at least a portion of the release layer ruptures such that portions of the release layer remain with both of the upper and lower laminate portions.
In accordance with one form, at least a portion of the release layer separates from one of the upper and lower laminate portions.
According to one form, the tabbed sealing member further includes a foil layer and wherein the sealant layer is a heat seal layer.
In one form, the first free portion and the second temporarily bonded portion together define at least 50% of an upper surface area of the tabbed seal.
In accordance with one form, the first free portion and the second temporarily bonded portion together define at least 75% of an upper surface area of the tabbed seal.
These and other aspects may be understood more readily from the following description and the appended drawings.
For the purpose of facilitating an understanding of the subject matter sought to be protected, there are illustrated in the accompanying drawings embodiments thereof, from an inspection of which, when considered in connection with the following description, the subject matter sought to be protected, its construction and operation, and many of its advantages should be readily understood and appreciated.
A pull tab sealing member for a container is described herein containing an upper laminate portion having a pull tab bonded with the upper laminate portion at least partially bonded to a lower laminate. The pull tab sealing member capable of being sealed to a container's mouth or opening, such as via a heat seal, pressure seal, and the like.
For simplicity, this disclosure generally may refer to a container or bottle, but the sealing members herein may be applied to any type of container, bottle, package or other apparatus having a rim or mouth surrounding an access opening to an internal cavity. In this disclosure, reference to upper and lower surfaces and layers of the components of the sealing member refers to an orientation of the components as generally depicted in the figures and when the sealing member is in use with a container in an upright position and having an opening at the top of the container. Different approaches to the sealing member will first be generally described, and then more specifics of the various constructions and materials will be explained thereafter. It will be appreciated that the sealing members described herein, in some cases, function in both a one-piece or two-piece sealing member configuration. A one-piece sealing member generally includes just the sealing member bonded to a container rim. A cap or closure may be also used therewith. A two-piece sealing member includes the sealing member temporarily bonded to a liner. In this construction, the sealing member is bonded to a container's rim, and the liner is configured to separate from the sealing member during heating to be retained in a cap or other closure used on the container. In a two-piece construction, a wax layer, for example, may be used to temporarily bond the sealing member to a liner. Other types of releasable layers may also be used to provide a temporary bond between the seal and liner, but the releasable layers are generally heat activated.
As discussed above, tabbed seals can suffer from problems associated with a user's ability to properly grasp the tab. Tabbed sealing members have been modified as described herein to improve functionality beyond the current product lines offered. In some forms, the feel or gripability of the tab is important. Prior tab offerings oftentimes include a tab that is plastic, which can be slippery to the touch especially in wet environments as refrigerated products can accumulate condensation, or simply from cooking and washing hands the interaction with the tab can be slippery. This can be exacerbated by the use of release coatings or specialty plastic films that promote release from the foil or high-density polyethylene (HDPE) film layers below the tab. With this knowledge it is important to design tab features that reduce slippage on the tab or otherwise increase the tab surface area to provide an enhanced grip.
Referring to
The upper laminate 24 may include other layers, such as support layer 30 and tab layer 32. Support layer 30 may take a variety of forms, such as a paperboard layer, a polymer film layer, a polymer foam layer, and the like. In one form, where support layer 30 is a paperboard layer, the adhesive layer 28 can be absorbed by the paperboard such that the support layer 30 separates from the bonding layer 26. In this form, the seal is considered a two-piece structure. In another form, the support layer 30 can be a polymer film and/or polymer foam that remains adhered to the bonding layer 26 and to the lower laminate portion 22. Tab layer 32 may be formed from a variety of materials, such as tab stock materials, polymers, and the like. Generally the tab layer 32 provides an area that separates the upper laminate portion 24 from the lower laminate portion 22 such that at least a portion of the tab layer 32 can be graspable. The tab layer 32 may also include a release coating, such as a silicon coating, to prevent the tab layer 32 from sticking to the lower laminate portion 22. It should be appreciated that the upper laminate portion 24 may also include additional layers and/or combinations of the above described layers.
The lower laminate portion 22 can include a variety of layers including, but not limited to a sealant layer 34. The sealant layer 34 is configured to adhere the sealing member 20 to a container (not shown). The sealant layer 34 can take a variety of forms, such as a heat seal, pressure sensitive adhesive, and the like. When configured as a heat seal, the sealant 34 can be heated in a variety of manners, such as conduction, convention, induction heating, and the like. For example, the lower laminate can include a membrane layer 36, such as a foil layer, that can be used in an induction heating process to provide heat to the sealant layer 34.
The lower laminate portion 22 can also include a polymer layer, such as polymer film layer 38. The lower laminate can also include adhesive layers 40,42 to adhere the various layers together. In other forms, the various layers can be extruded or otherwise directly applied to one another such that one or more of the adhesive layers are not needed in the lower laminate portion 22. Other layers such as polymer foam layers (not shown) can also be included. Further, the relative positions of the layers in the lower laminate can be modified. For instance, the membrane layer 36 can be positioned closer to the sealant layer 34, such as being swapped with the polymer film layer 38.
The sealing member 20 can also include a release layer 50. As shown in
For example, in one form, the bonding layer 26 and the release layer 36 can each be a polyethylene terephthalate and ethylene vinyl acetate co-extruded layer. In this form, the bonding layer 26 and the release layer can be temporarily bonded to one another, but release as a user pulls on the free tab portion. In another form, the release layer 50 can be a paper-based layer such that the release layer 50 ruptures and separates over at least a portion of the layer.
As shown in
In general, the free tab is loose and has air beneath since it is void of lamination. This results in movement while cutting during the closure lining process and can cause liner jams and rough edges on the perimeter of the cut liner. Minimizing the tab size relative to the liner's overall size is an advantage, but not practical for functionality. A novel way of eliminating this issue is to design a liner that seats flat and is peeled up or is extended by the consumer as the liner is lifted from the package. Large tabs have been known to twist during closure application at the filling process. Such a design could allow for a tab system to be greater than 50%. Such a design can result in a different removal dynamic which could be a benefit as consumers often tend to pull prior tabs in this manner.
Another form of a tabbed sealing member 60 is shown in
More specifically, a free tab portion is the surface area between lines I and J as the tab layer 32 is separate and free from the bonding layer 26. In this form, the free tab area is less than 50% of the overall surface area of the sealing member 70. As a user pulls on the free tab area, the release layer 50 can separate from the bonding layer 26 and/or internally rupture. In this form, the graspable portion of the tab is between lines I and L. The area between lines I and K generally represents 50% of the overall surface area of the sealing member 70 such that the graspable area of the tab between lines I and L is greater than 50% of the overall surface area. It should be appreciated that the overall graspable area of the tab, such as when the release layer 50 has released and/or ruptured, is greater than 70%, greater than 75%, greater than 80%, greater than 85%, greater than 90%, or more of the overall surface area of the sealing member. In such forms, the graspable area of the tab is significantly larger than other tabs, but is also relatively secured during installation and sealing. This can help prevent tab movement as the free area of the tab during installation is 50% or less, 30% or less, 20% or less of the overall surface area.
In this form, the area between lines A and B forms a free tab while the area between lines B and C forms a releasable portion of the tab. The area between lines C and D is also releasable as the tamper indicating structure can rupture at least in the area between lines C and D. For example, the tamper indicating layer 92 can include paper and/or a hologram such that the layer will rupture. Therefore, a user can visually determine that at least the area between lines C and D appears different from other areas on the sealing member, such as between lines B and C.
Further, as shown in
As shown in
It should be appreciated that in some forms, all or nearly all of the sealing member may be fully removed from the container. For example, all of the layers of the sealing member may release from the container. In other forms, only the sealant layer or a portion thereof may remain on the container.
In one form, the three tabbing components are pre-constructed, slit and then applied to the base laminate Al/PET/Sealant. Peelability from the sub tab layer allows independence of the sub tab from the required bond strength of the tab.
It has been noted that the removal force of a sealing members is much lower when the peel is initiated as a chord further away from the traditional 50% tab or saddle peel of the traditional Lift N Peel™ or Top Tab™ half-moon tab designs. In testing the concept relative to weld seal or the new “Pharma peel” technology, data shows that both the consistency and force are improved considerably by positioning the peel initiation in this manner.
Pharma peel generally refers to technology discussed in PCT/US2017/058521. Such technology involves tabbed seals that may include features such as tamper indicating features. These tamper indicating features may include holograms and may also include constructions whereby a portion of the seal remains on the container rim. The seal can be configured such that this portion of the seal is fairly clean and generally limited to the container such that a large portion of the container opening is not obstructed by debris.
For example, such sealing members may eliminate the excessive debris left by prior tamper evident top-tabbed type inner seals. In one aspect, the sealing members are arranged and configured to isolate the residual debris, after removal of the sealing member from the container via the tab, to the land region of the container rim independent of the size or positioning of the tab on the top surface of the sealing member. In another aspect, the tabbed sealing members herein utilize a unique layered assembly to aid in achieving the isolated debris left as a ring of sealant and aluminum layer on the container rim.
It was determined that a 50% percent tab induction sealed in a 38 mm HDPE container with a trial version of Pharma Peel 17A120 at 1.5 seconds dwell time produced seals that functioned properly only 30% of the time when sampling 25 sealed containers. A further improvement to 50% success could be achieved by elevating the induction dwell from 1.5 to 1.8 seconds, however, the liner begins to show signs of thermal stress at this point. When producing a seal with a 70% tab (changing the physical position of the liner from diameter to a chord), the result was a 100% success rate in intended removal characteristics. Overall the seal removal force is greatly reduced, thus allowing easy entry to a package while maintaining tamper evidence.
Tab extension allows for additional tamper indicating attributes to be applied to the liner's functionality. Examples have been designed using paper similar in nature to Selig Sealing Products' Sure Tab™ technology, holograms, and other peelable technologies such as peel able co-ex technology. This additional layer allows for tab extension and during the peel up of the tab adds a second level of tamper indication.
In field applications there are situations whereby a standard 50% tab will twist and distort during closure application or removal. This can be attributed to the frictional resistance between the inside of the closure and the top side of the free tab. This issue is seen in higher frequency when there is a reseal liner housed in the closure such as a molded reseal liner or a traditional foam reseal gasket that does not contain adequate slip properties. A reduction in the size of the free tab to 30% has been used as a method of eliminating tab twisting. The technology presented herein would allow a 50% tab with only a 30% free tab.
The lower laminate portion and upper laminate portion may include a variety of different materials and layers. For instance, the lower laminate portion may include a metal foil, and the top surface of the lower laminate portion may be the metal foil. The lower laminate portion may also include a foamed polymer, or the top surface of the lower seal portion may be a polymer film selected from polyolefin materials and polyester materials.
Additional layers may be included in the upper and/or lower laminate portions such as polyethylene terephthalate (PET), nylon, or other structural polymer layer and may be, in some approaches, about 0.5 to about 1 mil thick. In some approaches, additional layers may be included in the lower laminate. It should be appreciated that the lower laminate may include any number of other layers, such as polymer layers, adhesives, polymer films, polymer foams and the like.
The lower sealant layer or heat seal layer may be composed of any material suitable for bonding to the rim of a container, such as, but not limited to, induction, conduction, or direct bonding methods. Suitable adhesives, hot melt adhesives, or sealants for the heat sealable layer include, but are not limited to, polyesters, polyolefins, ethylene vinyl acetate, ethylene-acrylic acid copolymers, surlyn, and other suitable materials. By one approach, the heat sealable layer may be a single layer or a multi-layer structure of such materials about 0.2 to about 3 mils thick. By some approaches, the heat seal layer is selected to have a composition similar to and/or include the same polymer type as the composition of the container. For instance, if the container includes polyethylene, then the heat seal layer would also contain polyethylene. If the container includes polypropylene, then the heat seal layer would also contain polypropylene. Other similar materials combinations are also possible.
The polymer layers used in the upper and/or lower laminates may take a variety of forms such as coatings, films, foams, and the like. Suitable polymers include but are not limited to, polyethylene, polypropylene, ethylene-propylene copolymers, blends thereof as well as copolymers or blends with higher alpha-olefins. By one approach, one or more of the polymer layers may be a blend of polyolefin materials, such as a blend of one or more high density polyolefin components combined with one or more lower density polyolefin components. In one form, one polymer layer may be a polyethylene film while another polymer layer may be a PET film. According to one form, the polyethylene film may have a thickness of about 5 to about 20 microns while the PET film may have a thickness of about 5 to about 20 microns.
A support layer may be optional in the laminate. If included, it may be polyethylene terephthalate (PET), nylon, or other structural polymer layer and may be, in some approaches, about 0.5 to about 1 mil thick.
The membrane layer may be one or more layers configured to provide induction heating and/or barrier characteristics to the seal. A layer configured to provide induction heating is any layer capable of generating heat upon being exposed to an induction current where eddy currents in the layer generate heat. By one approach, the membrane layer may be a metal layer, such as, aluminum foil, tin, and the like. In other approaches, the membrane layer may be a polymer layer in combination with an induction heating layer. The membrane layer may also be or include an atmospheric barrier layer capable of retarding the migration of gases and moisture at least from outside to inside a sealed container and, in some cases, also provide induction heating at the same time. Thus, the membrane layer may be one or more layers configured to provide such functionalities. By one approach, the membrane layer is about 0.3 to about 2 mils of a metal foil, such as aluminum foil, which is capable of providing induction heating and to function as an atmospheric barrier.
In some forms, the seals may include an insulation layer or a heat-redistribution layer. In one form, the insulation layer may be a foamed polymer layer. Suitable foamed polymers include foamed polyolefin, foamed polypropylene, foamed polyethylene, and polyester foams. In some forms, these foams generally have an internal rupture strength of about 2000 to about 3500 g/in. In some approaches, the foamed polymer layer 106 may also have a density less than 0.6 g/cc and, in some cases, about 0.4 to less than about 0.6 g/cc. In other approaches, the density may be from about 0.4 g/cc to about 0.9 g/cc. The foamed polymer layer may be about 1 to about 5 mils thick.
In other approaches, a non-foam heat distributing or heat re-distributing layer may be included. In such approach, the non-foam heat distributing film layer is a blend of polyolefin materials, such as a blend of one or more high density polyolefin components combined with one or more lower density polyolefin components. Suitable polymers include but are not limited to, polyethylene, polypropylene, ethylene-propylene copolymers, blends thereof as well as copolymers or blends with higher alpha-olefins. By one approach, the non-foam heat distributing polyolefin film layer is a blend of about 50 to about 70 percent of one or more high density polyolefin materials with the remainder being one or more lower density polyolefin materials. The blend is selected to achieve effective densities to provide both heat sealing to the container as well as separation of the liner from the seal in one piece.
The heat-activated bonding layer may include any polymer materials that are heat activated or heated to achieve its bonding characteristics or application to the seal. By one approach, the heat-activated bonding layer may have a density of about 0.9 to about 1.0 g/cc and a peak melting point of about 145° F. to about 155° F. A melt index of the bonding layer 26 may be about 20 to about 30 g/10 min. (ASTM D1238). Suitable examples include ethylene vinyl acetate (EVA), polyolefin, 2-component polyurethane, ethylene acrylic acid copolymers, curable two-part urethane adhesives, epoxy adhesives, ethylene methacrylate copolymers and the like bonding materials.
The adhesives useful for any of the adhesive or tie layers described herein include, for example, ethylene vinyl acetate (EVA), polyolefins, 2-component polyurethane, ethylene acrylic acid copolymers, curable two-part urethane adhesives, epoxy adhesives, ethylene methacrylate copolymers and the like bonding materials. Other suitable materials may include low density polyethylene, ethylene-acrylic acid copolymers, and ethylene methacrylate copolymers. By one approach, any optional adhesive layers may be a coated polyolefin adhesive layer. If needed, such adhesive layers may be a coating of about 0.2 to about a 0.5 mil (or less) adhesive, such as coated ethylene vinyl acetate (EVA), polyolefins, 2-component polyurethane, ethylene acrylic acid copolymers, curable two-part urethane adhesives, epoxy adhesives, ethylene methacrylate copolymers and the like bonding materials.
In one aspect, the tab may be formed by a full layer or partial layer of material combined with a partial width composite adhesive structure that includes a polyester core with upper and lower adhesives on opposite sides thereof. This partial composite adhesive structure bonds the upper laminate to the lower laminate to form the gripping tab.
In other aspects of this disclosure, the upper laminate of the seal does not extend the full width of the sealing member in order to define the gripping tab. To this end, the pull-tab sealing members herein may also combine the advantages of a tabbed sealing member with a large gripping tab defined completely within the perimeter of the seal, but achieve such functionality with less material (in view of the part layers of the upper laminate) and permit such a tab structure to be formed on many different types of pre-formed lower laminates. The partial upper laminate structure is advantageous, in some approaches, for use with a seal configured for large or wide mouth containers, such as containers with an opening from about 30 to about 100 mm (in other approaches, about 60 to about 100 mm). These seals may also be used with 38 mm or 83 mm container openings, or can be used with any sized container.
In further aspects of this disclosure, the sealing members herein may include a pull or grip tab defined in the upper laminate portion wholly within a perimeter or circumference of the sealing member wherein an upper surface of the sealing member is partially defined by the upper laminate portion and partially defined by the lower laminate portion. The seals of this aspect allow consumers to remove the sealing member using the tab (as in a conventional pull-tab seal) and/or puncture the sealing member by piercing the exposed lower laminate portion to provide push/pull functionality depending on the preference of the consumer.
In the various embodiments, the seals of the present disclosure defining a tab wholly within a perimeter or circumference of the seal (formed by a full or partial layer) also provide an improved ability for the tabbed sealing member to function in a two-piece seal and liner combination. In a two-piece seal and liner combination, the tabbed sealing member is temporarily adhered across its top surface to a liner. After container opening and removal of a cap or closure, the sealing member stays adhered to the container mouth and the liner separates and remains in the container's cap.
In some prior versions of two-piece seal and liner assemblies, the bottom layer of the sealing member is a heat seal layer that is activated by heating, such as by induction or conduction heating, in order to adhere or bond an outer periphery of the sealing member to a rim surrounding the mouth of a container. In the two-piece seal and liner combination, an upper surface of the sealing member is temporarily adhered to a lower surface of the liner by a release layer, which is often a heat-activated release layer, such as an intervening wax layer. During heating to bond the sealing member to the container, heat not only activates the lower heat seal layer, but also travels upwardly through the seal to melt the intervening wax across the entire surface of the sealing member to separate the liner from the sealing member. Often, the melted wax is absorbed by the liner in order to permit easy liner separation from the sealing member. As can be appreciated, for this sealing member and liner combination to function properly, the intervening wax layer needs to be melted across the entire surface of the sealing member. If the wax is not melted evenly all the way across the sealing member upper surface, the liner may not properly separate from the lower seal portion.
The various layers of the sealing member are assembled via coating adhesives, applying films, and/or a heat lamination process forming a sheet of the described layers. Extrusion lamination may also be used. The resulting laminate sheet of the sealing members can be cut into appropriate sized disks or other shapes as needed to form a vessel closing assembly or tabbed sealing member. The cut sealing member is inserted into a cap or other closure which, in turn, is applied to the neck of a container to be sealed. The screw cap can be screwed onto the open neck of the container, thus sandwiching the sealing member between the open neck of the container and the top of the cap. The sealing layer may be a pressure sensitive adhesive, the force of attaching the closure to the container can activate the adhesive.
Various enhancements of tabbed seals are provided herein with enhanced grasping functionality. The below described embodiments may be used separately or may be used in combination with one another and with the features described above.
In one form, the tabbed seal includes an anti-slip coating that is positioned on at least one of a top and a bottom surface of the gripping tab. Previously, some tabs included release coatings to prevent the tab from adhering to the lower laminate and preventing the user from grasping the seal. An anti-slip coating may be applied to at least a portion of the gripping tab to enhance a user's ability to grasp and maintain a hold of the gripping tab.
Such anti-slip coatings can include a variety of materials including, but not limited to materials having increased coefficients of friction, such as rubber or rubberized materials and the like. The anti-slip coatings may also include a combination of materials. The anti-slip coating may also be used in a variety of thicknesses, as desired, and in view of the number and thicknesses of other coatings used in the seal.
In a similar form, the gripping tab may include a polymer adhesive layer on at least a portion of at least one of an upper and a lower surface of the gripping tab. The polymer adhesive layer may provide a tackier gripping surface so that the gripping tab is less slippery. However, the polymer adhesive layer should also be configured such that it does not prevent the gripping tab from releasing from the lower laminate portion. The polymer adhesive layer on the underside of the tab stock may be formed from a variety of different materials. Such materials include, but are not limited to, EVA and other modified co-polymers that are tackier or more grippable than release coatings and therefore a structure made in this manner leaves the underside of the tab less slippery.
In yet another form, the gripping tab may be enhanced by including embossing and/or texturizing. This type of enhancement can be positioned on at least one of an upper and a lower surface of the gripping tab. In yet another portion, this type of enhancement may be configured to extend entirely through the gripping tab from the upper surface to the lower surface. For example, the gripping tab may be embossed in a process such that the entire structure of the gripping tab includes a texture.
Texturization or embossing of one or more layers in the upper laminate, such as the insulating layer, imparts a textured surface to the liner. Depending on the depth and geometry of the embossed pattern various degrees of grip enhancement can be imparted. The depth and geometry of the pattern can be varied, as desired. The depth may also be varied depending on the overall desired thickness of the seal, the thickness of the layers in the tab, the grip of the tab, and the like.
For example, one or more of polymer layers can be embossed or otherwise be provided with a surface roughness. By embossing the polymer layer(s), the non-smooth resulting surface may help impart desired roll release properties to the laminate and help minimize blocking when it is unwound prior to cutting into individual seals. Further, the grain or surface roughness, in some approaches, tends to reduce the surface contact between the outer layer and any liner or cap applied over the sealing member. This grain or surface roughness tends to result in a reduction in removal force of a cap or adjacent liner (in a two-piece seal) in view of the decreased surface contact between the outer layer and any adjacent surface cap or liner surface. Therefore, the embossed surface cannot only enhance the user's ability to grasp the tab, but may also enhance other production processes, as described above.
Further enhancements may also be utilized, such as by thickening various locations of the tab. In these forms, a much thicker portion of the tab is provided to help a user grasp the gripping tab. Adding a much thicker component to the end of the tab would provide the consumer with a physical stop to aid in gripping and removing the liner system. The thickened portion can be positioned to be toward an outer edge as well as an inner portion. Further, the thick portion can be positioned above and/or below various layers in the upper laminate. It should be appreciated that the thickened portion can also be positioned between other layers in the upper laminate.
The thickened portion can be made from a variety of different materials, including, but not limited to, any of the various materials for any of the layers described herein. Further, the thickness of the thickened material can vary as needed to provide the desired overall tab thickness.
The matter set forth in the foregoing description and accompanying drawings is offered by way of illustration only and not as a limitation. While particular embodiments have been shown and described, it will be apparent to those skilled in the art that changes and modifications may be made without departing from the broader aspects of Applicant's contribution. The actual scope of the protection sought is intended to be defined in the following claims when viewed in their proper perspective based on the prior art.
This application is a U.S. national phase application filed under 35 U.S.C. § 371 of International Application Number PCT/US2019/041038, filed Jul. 9, 2019, designating the United States which claims benefit of U.S. Provisional Application No. 62/695,277, filed Jul. 9, 2018, which is hereby incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2019/041038 | 7/9/2019 | WO |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2020/014252 | 1/16/2020 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
1818379 | Cain | Aug 1931 | A |
2768762 | Guinet | Oct 1956 | A |
3235165 | Jackson | Feb 1966 | A |
3292828 | Stuart | Dec 1966 | A |
3302818 | Balocca et al. | Feb 1967 | A |
3460310 | Adcock et al. | Aug 1969 | A |
3556816 | Nughes | Jan 1971 | A |
3964670 | Amneus | Jun 1976 | A |
3990603 | Brochman | Nov 1976 | A |
4133796 | Bullman | Jan 1979 | A |
4206165 | Dukess | Jun 1980 | A |
4266687 | Cummings | May 1981 | A |
4396655 | Graham | Aug 1983 | A |
4556590 | Martin | Dec 1985 | A |
4582735 | Smith | Apr 1986 | A |
4588099 | Diez | May 1986 | A |
4595116 | Carlsson | Jun 1986 | A |
4596338 | Yousif | Jun 1986 | A |
4636273 | Wolfersperger | Jan 1987 | A |
4666052 | Ou-Yang | May 1987 | A |
4693390 | Hekal | Sep 1987 | A |
4735335 | Torterotot | Apr 1988 | A |
4741791 | Howard | May 1988 | A |
4762246 | Ashley | Aug 1988 | A |
4770325 | Gordon | Sep 1988 | A |
4771903 | Levene | Sep 1988 | A |
4781294 | Croce | Nov 1988 | A |
4801647 | Wolfe, Jr. | Jan 1989 | A |
4811856 | Fischman | Mar 1989 | A |
4818577 | Ou-Yang | Apr 1989 | A |
4837061 | Smits | Jun 1989 | A |
4863061 | Moore | Sep 1989 | A |
4867881 | Kinzer | Sep 1989 | A |
4889731 | Williams | Dec 1989 | A |
4917949 | Yousif | Apr 1990 | A |
4934544 | Han | Jun 1990 | A |
4938390 | Markva | Jul 1990 | A |
4960216 | Giles | Oct 1990 | A |
4961986 | Galda | Oct 1990 | A |
5004111 | McCarthy | Apr 1991 | A |
5012946 | McCarthy | May 1991 | A |
5015318 | Smits | May 1991 | A |
5053457 | Lee | Oct 1991 | A |
5055150 | Rosenfeld | Oct 1991 | A |
5057365 | Finkelstein | Oct 1991 | A |
5071710 | Smits | Dec 1991 | A |
5089320 | Straus | Feb 1992 | A |
5098495 | Smits | Mar 1992 | A |
RE33893 | Elias | Apr 1992 | E |
5106124 | Volkman | Apr 1992 | A |
5125529 | Torterotot | Jun 1992 | A |
5131556 | Iioka | Jul 1992 | A |
5149386 | Smits | Sep 1992 | A |
5178967 | Rosenfeld | Jan 1993 | A |
5197618 | Goth | Mar 1993 | A |
5217790 | Galda | Jun 1993 | A |
5226281 | Han | Jul 1993 | A |
5261990 | Galda | Nov 1993 | A |
5265745 | Pereyra | Nov 1993 | A |
5433992 | Galda | Jul 1995 | A |
5513781 | Ullrich | May 1996 | A |
5514442 | Galda | May 1996 | A |
5560989 | Han | Oct 1996 | A |
5598940 | Finkelstein | Feb 1997 | A |
5601200 | Finkelstein | Feb 1997 | A |
5615789 | Finkelstein | Apr 1997 | A |
5618618 | Murschall | Apr 1997 | A |
5669521 | Wiening | Sep 1997 | A |
5683774 | Faykish | Nov 1997 | A |
5702015 | Giles | Dec 1997 | A |
5709310 | Kretz | Jan 1998 | A |
5776284 | Sykes | Jul 1998 | A |
5851333 | Fagnant | Dec 1998 | A |
5860544 | Brucker | Jan 1999 | A |
5871112 | Giles | Feb 1999 | A |
5887747 | Burklin | Mar 1999 | A |
5915577 | Levine | Jun 1999 | A |
5975304 | Cain | Nov 1999 | A |
5976294 | Fagnant | Nov 1999 | A |
6056141 | Navarini | May 2000 | A |
6082566 | Yousif | Jul 2000 | A |
6096358 | Murdick | Aug 2000 | A |
6131754 | Smelko | Oct 2000 | A |
6139931 | Finkelstein | Oct 2000 | A |
6158632 | Ekkert | Dec 2000 | A |
6194042 | Finkelstein | Feb 2001 | B1 |
6234386 | Drummond | May 2001 | B1 |
6290801 | Krampe | Sep 2001 | B1 |
6312776 | Finkelstein | Nov 2001 | B1 |
6361856 | Wakai | Mar 2002 | B1 |
6378715 | Finkelstein | Apr 2002 | B1 |
6458302 | Shifflet | Oct 2002 | B1 |
6461714 | Giles | Oct 2002 | B1 |
6544615 | Otten | Apr 2003 | B2 |
6548302 | Mao | Apr 2003 | B1 |
6602309 | Vizulis | Aug 2003 | B2 |
6627273 | Wolf | Sep 2003 | B2 |
6635137 | Giles | Oct 2003 | B2 |
6669046 | Sawada | Dec 2003 | B1 |
6699566 | Zeiter | Mar 2004 | B2 |
6705467 | Kancsar | Mar 2004 | B1 |
6722272 | Jud | Apr 2004 | B2 |
6767425 | Meier | Jul 2004 | B2 |
6790508 | Razeti | Sep 2004 | B2 |
6866926 | Smelko | Mar 2005 | B1 |
6902075 | Obrien | Jun 2005 | B2 |
6916516 | Gerber | Jul 2005 | B1 |
6955736 | Rosenberger | Oct 2005 | B2 |
6959832 | Sawada | Nov 2005 | B1 |
6974045 | Trombach | Dec 2005 | B1 |
6986930 | Giles | Jan 2006 | B2 |
7128210 | Razeti | Oct 2006 | B2 |
7182475 | Kramer | Feb 2007 | B2 |
7217454 | Smelko | May 2007 | B2 |
RE39790 | Fuchs | Aug 2007 | E |
7316760 | Nageli | Jan 2008 | B2 |
7448153 | Maliner | Nov 2008 | B2 |
7531228 | Perre | May 2009 | B2 |
7648764 | Yousif | Jan 2010 | B2 |
7713605 | Yousif | May 2010 | B2 |
7731048 | Teixeira Alvares | Jun 2010 | B2 |
7740730 | Schedl | Jun 2010 | B2 |
7740927 | Yousif | Jun 2010 | B2 |
7757879 | Schuetz | Jul 2010 | B2 |
7789262 | Niederer | Sep 2010 | B2 |
7798359 | Marsella | Sep 2010 | B1 |
7819266 | Ross | Oct 2010 | B2 |
7838109 | Declerck | Nov 2010 | B2 |
7850033 | Thorstensen-Woll | Dec 2010 | B2 |
8025171 | Cassol | Sep 2011 | B2 |
8057896 | Smelko | Nov 2011 | B2 |
8129009 | Morris | Mar 2012 | B2 |
8201385 | Mclean | Jun 2012 | B2 |
8308003 | O'Brien | Nov 2012 | B2 |
8329288 | Allegaert | Dec 2012 | B2 |
8348082 | Cain | Jan 2013 | B2 |
8455071 | Lo | Jun 2013 | B2 |
8541081 | Ranganathan | Sep 2013 | B1 |
8703265 | Thorstensen-Woll | Apr 2014 | B2 |
8715825 | Thorstensen-Woll | May 2014 | B2 |
8852725 | Sachs | Oct 2014 | B2 |
8906185 | Mclean | Dec 2014 | B2 |
8944264 | Frishman | Feb 2015 | B2 |
9028963 | Thorstensen-Woll | May 2015 | B2 |
9102438 | Thorstensen-Woll | Aug 2015 | B2 |
9120289 | Chang | Sep 2015 | B2 |
9193513 | Thorstensen-Woll | Nov 2015 | B2 |
9221579 | Thorstensen-Woll | Dec 2015 | B2 |
9227755 | Thorstensen-Woll | Jan 2016 | B2 |
9278506 | Mclean | Mar 2016 | B2 |
9278793 | Thorstensen-Woll | Mar 2016 | B2 |
9440765 | Thorstensen-Woll | Sep 2016 | B2 |
9440768 | Thorstensen-Woll | Sep 2016 | B2 |
9533805 | Mclean | Jan 2017 | B2 |
9676513 | Thorstensen-Woll | Jun 2017 | B2 |
9834339 | Brucker | Dec 2017 | B2 |
9956741 | Planchard | May 2018 | B2 |
9994357 | Thorstensen-Woll | Jun 2018 | B2 |
10000310 | Thorstensen-Woll | Jun 2018 | B2 |
10150590 | Thorstensen-Woll | Dec 2018 | B2 |
10196174 | Thorstensen-Woll | Feb 2019 | B2 |
10259626 | Thorstensen-Woll | Apr 2019 | B2 |
10556732 | Cassidy | Feb 2020 | B2 |
10604315 | Thorstensen-Woll | Mar 2020 | B2 |
10899506 | Thorstensen-Woll | Jan 2021 | B2 |
10934069 | Clark | Mar 2021 | B2 |
10954032 | Thorstensen-Woll | Mar 2021 | B2 |
11059644 | Cassidy | Jul 2021 | B2 |
20010023870 | Mihalov | Sep 2001 | A1 |
20010031348 | Jud | Oct 2001 | A1 |
20020028326 | Lhila | Mar 2002 | A1 |
20020068140 | Finkelstein | Jun 2002 | A1 |
20030087057 | Blemberg | May 2003 | A1 |
20030108714 | Razeti | Jun 2003 | A1 |
20030168423 | Williams | Sep 2003 | A1 |
20030196418 | O'Brien | Oct 2003 | A1 |
20040013862 | Brebion | Jan 2004 | A1 |
20040028851 | Okhai | Feb 2004 | A1 |
20040043165 | Van Hulle | Mar 2004 | A1 |
20040043238 | Wuest | Mar 2004 | A1 |
20040109963 | Zaggia | Jun 2004 | A1 |
20040197500 | Swoboda | Oct 2004 | A9 |
20040211320 | Cain | Oct 2004 | A1 |
20050003155 | Huffer | Jan 2005 | A1 |
20050048307 | Schubert | Mar 2005 | A1 |
20050100718 | Peiffer | May 2005 | A1 |
20050208242 | Smelko | Sep 2005 | A1 |
20050208244 | Delmas | Sep 2005 | A1 |
20050218143 | Niederer | Oct 2005 | A1 |
20050279814 | Drummond | Dec 2005 | A1 |
20060000545 | Nageli | Jan 2006 | A1 |
20060003120 | Nageli | Jan 2006 | A1 |
20060003122 | Nageli | Jan 2006 | A1 |
20060068163 | Giles | Mar 2006 | A1 |
20060124577 | Ross | Jun 2006 | A1 |
20060151415 | Smelko | Jul 2006 | A1 |
20060278665 | Bennett | Dec 2006 | A1 |
20070003725 | Yousif | Jan 2007 | A1 |
20070007229 | Yousiff | Jan 2007 | A1 |
20070014897 | Ramesh | Jan 2007 | A1 |
20070065609 | Korson | Mar 2007 | A1 |
20070267304 | Portier | Nov 2007 | A1 |
20070298273 | Thies | Dec 2007 | A1 |
20080026171 | Gullick | Jan 2008 | A1 |
20080073308 | Yousif | Mar 2008 | A1 |
20080103262 | Haschke | May 2008 | A1 |
20080135159 | Bries | Jun 2008 | A1 |
20080145581 | Tanny | Jun 2008 | A1 |
20080156443 | Schaefer | Jul 2008 | A1 |
20080169286 | Mclean | Jul 2008 | A1 |
20080231922 | Thorstensen-Woll | Sep 2008 | A1 |
20080233339 | Thorstensen-Woll | Sep 2008 | A1 |
20080233424 | Thorstensen-Woll | Sep 2008 | A1 |
20090078671 | Triquet | Mar 2009 | A1 |
20090208729 | Allegaert | Aug 2009 | A1 |
20090304964 | Sachs | Dec 2009 | A1 |
20100009162 | Rothweiler | Jan 2010 | A1 |
20100030180 | Deckerck | Feb 2010 | A1 |
20100047552 | Mclean | Feb 2010 | A1 |
20100059942 | Rothweiler | Mar 2010 | A1 |
20100116410 | Yousif | May 2010 | A1 |
20100155288 | Harper | Jun 2010 | A1 |
20100170820 | Leplatois | Jul 2010 | A1 |
20100193463 | Obrien | Aug 2010 | A1 |
20100213193 | Helmlinger | Aug 2010 | A1 |
20100221483 | Gonzalez Carro | Sep 2010 | A1 |
20100279041 | Mathew | Nov 2010 | A1 |
20100290663 | Trassl | Nov 2010 | A1 |
20100314278 | Fonteyne | Dec 2010 | A1 |
20110000917 | Wolters | Jan 2011 | A1 |
20110005961 | Leplatois | Jan 2011 | A1 |
20110089177 | Thorstensen-Woll | Apr 2011 | A1 |
20110091715 | Rakutt | Apr 2011 | A1 |
20110100949 | Grayer | May 2011 | A1 |
20110100989 | Cain | May 2011 | A1 |
20110138742 | Mclean | Jun 2011 | A1 |
20110147353 | Kornfeld | Jun 2011 | A1 |
20110152821 | Kornfeld | Jun 2011 | A1 |
20120000910 | Ekkert | Jan 2012 | A1 |
20120043330 | Mclean | Feb 2012 | A1 |
20120067896 | Daffner | Mar 2012 | A1 |
20120070636 | Thorstensen-Woll | Mar 2012 | A1 |
20120103988 | Wiening | May 2012 | A1 |
20120111758 | Lo | May 2012 | A1 |
20120241449 | Frischmann | Sep 2012 | A1 |
20120285920 | Mclean | Nov 2012 | A1 |
20120288693 | Stanley | Nov 2012 | A1 |
20120312818 | Ekkert | Dec 2012 | A1 |
20130020324 | Thorstensen-Woll | Jan 2013 | A1 |
20130020328 | Duan | Jan 2013 | A1 |
20130045376 | Chen | Feb 2013 | A1 |
20130121623 | Lyzenga | May 2013 | A1 |
20130177263 | Duan | Jul 2013 | A1 |
20130248410 | Spallek | Sep 2013 | A9 |
20140001185 | Mclean | Jan 2014 | A1 |
20140061196 | Thorstensen-Woll | Mar 2014 | A1 |
20140061197 | Thorstensen-Woll | Mar 2014 | A1 |
20140186589 | Chang | Jul 2014 | A1 |
20140224800 | Thorstensen-Woll | Aug 2014 | A1 |
20140284331 | Thorstensen-Woll | Sep 2014 | A1 |
20140326727 | Jouin | Nov 2014 | A1 |
20150053680 | Masato | Feb 2015 | A1 |
20150131926 | Lux | May 2015 | A1 |
20150158643 | Coker | Jun 2015 | A1 |
20150197385 | Wei | Jul 2015 | A1 |
20150225116 | Thorstensen-Woll | Aug 2015 | A1 |
20150321808 | Thorstensen-Woll | Nov 2015 | A1 |
20160001952 | Kulkarni | Jan 2016 | A1 |
20160159546 | Cassidy | Jun 2016 | A1 |
20160185485 | Thorstensen-Woll | Jun 2016 | A1 |
20160325896 | Thorstensen-Woll | Nov 2016 | A1 |
20170173930 | Mclean | Jun 2017 | A1 |
20170253373 | Thorstensen-Woll | Sep 2017 | A1 |
20170259978 | Zamora | Sep 2017 | A1 |
20170291399 | Bourgeois | Oct 2017 | A1 |
20180079576 | Cassidy | Mar 2018 | A1 |
20180118439 | Thorstensen-Woll | May 2018 | A1 |
20180186122 | Bourgeois | Jul 2018 | A1 |
20190055070 | Brown | Feb 2019 | A1 |
20190092520 | Thorstensen-Woll | Mar 2019 | A1 |
20190225369 | Thorstensen-Woll | Jul 2019 | A1 |
20190276209 | Clark | Sep 2019 | A1 |
20200079561 | Zamora | Mar 2020 | A1 |
20200087056 | Bosetti | Mar 2020 | A1 |
20200216256 | Miozzo | Jul 2020 | A1 |
20200282708 | Leuer | Sep 2020 | A1 |
20210188489 | Thorstensen-Woll | Jun 2021 | A1 |
20210237951 | Ostergren | Aug 2021 | A1 |
20210292060 | Thorstensen-Woll | Sep 2021 | A1 |
Number | Date | Country |
---|---|---|
501393 | Aug 2006 | AT |
11738 | Apr 2011 | AT |
8200231 | Sep 2003 | BR |
0300992 | Nov 2004 | BR |
2015992 | Jan 1991 | CA |
2203744 | Oct 1997 | CA |
2297840 | Feb 1999 | CA |
1301289 | Jun 2001 | CN |
1639020 | Jul 2005 | CN |
103193026 | Jul 2013 | CN |
104853994 | Aug 2015 | CN |
102006030118 | May 2007 | DE |
10204281 | Aug 2007 | DE |
102007022935 | Apr 2009 | DE |
202009000245 | Apr 2009 | DE |
0135431 | Mar 1985 | EP |
0577432 | Jan 1994 | EP |
0668221 | Aug 1995 | EP |
0826598 | Mar 1998 | EP |
0826599 | Mar 1998 | EP |
0905039 | Mar 1999 | EP |
0717710 | Apr 1999 | EP |
0915026 | May 1999 | EP |
0706473 | Aug 1999 | EP |
1075921 | Feb 2001 | EP |
1199253 | Apr 2002 | EP |
0803445 | Nov 2003 | EP |
1462381 | Sep 2004 | EP |
1199253 | Mar 2005 | EP |
1577226 | Sep 2005 | EP |
1814744 | Aug 2007 | EP |
1834893 | Sep 2007 | EP |
1837288 | Sep 2007 | EP |
1839898 | Oct 2007 | EP |
1839899 | Oct 2007 | EP |
1857275 | Nov 2007 | EP |
1873078 | Jan 2008 | EP |
1445209 | May 2008 | EP |
1918094 | May 2008 | EP |
1935636 | Jun 2008 | EP |
1968020 | Sep 2008 | EP |
1992476 | Nov 2008 | EP |
2014461 | Jan 2009 | EP |
2230190 | Sep 2010 | EP |
2292524 | Mar 2011 | EP |
2599735 | Jun 2013 | EP |
2230190 | Aug 2014 | EP |
3278972 | Oct 2020 | EP |
2693986 | Jan 1994 | FR |
2916157 | Nov 2008 | FR |
2943322 | Sep 2010 | FR |
1216991 | Dec 1970 | GB |
2353986 | Mar 2001 | GB |
2501967 | Nov 2013 | GB |
H09110077 | Apr 1997 | JP |
2004212778 | Jul 2004 | JP |
2014015249 | Jan 2014 | JP |
100711073 | Apr 2007 | KR |
100840926 | Jun 2008 | KR |
100886955 | Mar 2009 | KR |
05002905 | Feb 2006 | MX |
2010001867 | Apr 2010 | MX |
201217237 | May 2012 | TW |
9702997 | Jan 1997 | WO |
9905041 | Feb 1999 | WO |
0066450 | Nov 2000 | WO |
2005009868 | Feb 2005 | WO |
2005030860 | Apr 2005 | WO |
2006018556 | Feb 2006 | WO |
2006021291 | Mar 2006 | WO |
2006073777 | Jul 2006 | WO |
2006108853 | Oct 2006 | WO |
2008027029 | Mar 2008 | WO |
2008027036 | Mar 2008 | WO |
2008039350 | Apr 2008 | WO |
2008113855 | Sep 2008 | WO |
2008118569 | Oct 2008 | WO |
2008125784 | Oct 2008 | WO |
2008125785 | Oct 2008 | WO |
2008148176 | Dec 2008 | WO |
2009092066 | Jul 2009 | WO |
2010115811 | Oct 2010 | WO |
2011039067 | Apr 2011 | WO |
2012079971 | Jun 2012 | WO |
2012113530 | Aug 2012 | WO |
2012152622 | Nov 2012 | WO |
2012172029 | Dec 2012 | WO |
2013134665 | Sep 2013 | WO |
2014190395 | Dec 2014 | WO |
2015119988 | Aug 2015 | WO |
2016203251 | Dec 2016 | WO |
2017155946 | Sep 2017 | WO |
2018081419 | May 2018 | WO |
Entry |
---|
Patent Cooperation Treaty, International Search Report and Written Opinion of the International Searching Authority for International Application No. PCT/US2019/041038 dated Sep. 26, 2019, 13 pages. |
Number | Date | Country | |
---|---|---|---|
20210292059 A1 | Sep 2021 | US |
Number | Date | Country | |
---|---|---|---|
62695277 | Jul 2018 | US |