Patent Grant
12110250
The present disclosure relates to a deadfront article for display methods and apparatus for providing improved visual and optionally tactile features on a substrate. More particularly, the disclosure relates to deadfront articles with a tactile feel on the front surface of the deadfront article.
In recent years, consumer products, including automobile interior components, have been incorporating more touch screen and deadfront type control displays and less push-button and knob oriented controls. A deadfront article includes a surface that exhibits a deadfront effect in which the surface disguises or masks underlying display features from a viewer when the article is not backlit, but permits the display features to be viewed when the article is backlit.
Accordingly, a need exists for innovations in touch screen and deadfront type control displays.
The present disclosure is related to deadfront articles for consumer products that provide a decorative surface with a tactile feel. Disclosed deadfront articles may be incorporated into a consumer product to provide a surface with a decorative appearance (e.g., stainless steel, wood, etc.), a tactile feel, and underlying control features (e.g., display buttons/icons). Disclosed deadfront articles may be used to make sleek, lightweight, strong, decorative, and functional surfaces with a tactile feel in various industries. For example, disclosed deadfront articles may be used in the automotive industry to provide a deadfronted control display with a haptic features for automobile interiors.
In a first aspect a deadfront article is described, the deadfront article including a substrate having a first surface and a second surface opposite the first surface; a visual element disposed on the second surface of the substrate and/or within the substrate such that the visual element may be viewed through the first surface, the visual element including a graphic that may be viewed through the first surface; at least one tactile element formed on the first surface of the substrate, the at least one tactile element comprising one or more surface roughness portions, where at least one of the one or more surface roughness portions is positioned on the first surface of the substrate in a complimentary fashion to the graphic; a semi-transparent layer disposed on at least a first portion of the second surface of the substrate, the semi-transparent layer having a region of a solid color or of a design of two or more colors; and a contrast layer disposed on at least a portion of the region, the contrast layer configured to enhance visibility of the color of the region or to enhance contrast between the colors of the design of the region on the portion of the region on which the contrast layer is disposed.
In a second aspect, the deadfront article according to aspects of the preceding paragraph may include one or more surface roughness portions are defined by one of: (i) an area of relatively higher surface roughness bordered by at least one area of relatively lower surface roughness, and (ii) an area of relatively lower surface roughness bordered by at least one area of relatively higher surface roughness.
In a third aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a graphic that includes an icon.
In a forth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include one or more surface roughness portions that include an etched portion of the first surface of the substrate.
In a fifth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a first surface where the majority of the total surface area of the first surface of the substrate includes a first surface roughness, and the one or more surface roughness portions of the tactile element cover a minority of the total surface area of the first surface and comprise a second surface roughness, which is different from the first surface roughness. In some embodiments, the second surface roughness may be relatively rougher than the first surface roughness. In some embodiments, the second surface roughness may have a Ra surface roughness of greater than about 80 nm. In some embodiments, the first surface roughness may be relatively rougher than the second surface roughness. In some embodiments, the first surface roughness may have a Ra surface roughness of greater than about 80 nm.
In a sixth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a substrate that includes a material selected from the group of: a glass, a glass ceramic, and a polymer.
In a seventh aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a substrate that includes strengthened glass.
In an eighth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a high optical density layer disposed onto at least a portion of the contrast layer such that the contrast layer is located between the high optical density layer and the semi-transparent layer. In some embodiments, the high optical density layer at least in part defines the graphic.
In a ninth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a color layer disposed in regions of the visual element such that, in at least a portion of the visual element defined by the high optical density layer, the contrast layer is located between the semi-transparent layer and the color layer.
In a tenth aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a semi-transparent layer that has a design of two or more colors, the design including at least one of a leather grain pattern, a wood grain pattern, a fabric pattern, a brushed metal finish pattern, and a logo.
In a eleventh aspect, the deadfront article according to aspects of any of the preceding paragraphs may include a touch panel located behind the visual element, the touch panel configured to respond to a touch by a user.
In a twelfth aspect, an automobile interior is described, the automobile interior including a deadfront article including a substrate having a first surface and a second surface opposite the first surface; a visual element disposed on the second surface of the substrate and/or within the substrate such that the visual element may be viewed through the first surface, the visual element including a graphic that may be viewed through the first surface; at least one tactile element formed on the first surface of the substrate, the at least one tactile element comprising one or more surface roughness portions, where at least one of the one or more surface roughness portions is positioned on the first surface of the substrate in a complimentary fashion to the graphic; a semi-transparent layer disposed on a second surface of the substrate layer; a contrast layer disposed on at least a portion of the semi-transparent layer; and a high optical density layer disposed on at least a portion of the contrast layer, the high optical density layer at least in part defining the graphic; and a touch panel located behind the visual element, the touch panel configured to respond to a touch by a user.
In a thirteenth aspect, the automobile interior according to aspects of the preceding paragraph may include a graphic that is an icon and the touch panel is configured to respond to a user's touch of the icon.
In a fourteenth aspect, the automobile interior according to aspects of either of the two preceding paragraphs may include a semi-transparent layer that has a region of a solid color or of a design of two or more colors, the design including at least one of a leather grain pattern, a wood grain pattern, a fabric pattern, a brushed metal finish pattern, and a logo.
In a fifteenth aspect, the automobile interior according to aspects of any of the three preceding paragraphs may include a high optical density layer disposed onto at least a portion of the contrast layer such that the contrast layer is located between the high optical density layer and the semi-transparent layer.
In a sixteenth aspect, the automobile interior according to aspects of any of the four preceding paragraphs may include a color layer disposed in regions of the visual element such that, in at least a portion of the visual element defined by the high optical density layer, the contrast layer is located between the semi-transparent layer and the color layer.
In a seventeenth aspect, a method of forming a tactile element on a deadfront article is described, the method including forming at least one tactile element on a first surface of a substrate in a complimentary fashion to a graphic defined by a visual element disposed on a second surface of the substrate opposite the first surface and/or within the substrate such that the graphic may be viewed through the first surface, where the at least one tactile element is formed by a process including at least one of etching, sandblasting, polishing, and engraving.
In an eightieth aspect, the method according to aspects of the preceding paragraph may include forming the at least one tactile element by an etching process. In some embodiments, the etching process may include etching the first surface with a first etching solution; disposing a mask over the first surface after etching the first surface with the first etching solution, the mask comprising a shape corresponding to the shape of the graphic; and etching an unmasked region of the first surface with a second etching solution. In some embodiments, the first etching solution may include hydrofluoric acid, ammonium fluoride, and a water miscible organic solvent, and the second etching solution may include hydrofluoric acid.
Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the embodiments as described herein, including the detailed description which follows, the claims, as well as the appended drawings.
It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understanding the nature and character of the claims. The accompanying drawings are included to provide a further understanding, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and operation of the various embodiments.
Referring generally to the figures, vehicle interior systems may include a variety of different flat or curved surfaces that are designed to be transparent, such as flat or curved display surfaces, and the present disclosure provides articles and methods for forming these flat or curved surfaces. In one or more embodiments, such surfaces are formed from glass materials or from plastic materials. Forming curved or flat vehicle surfaces from a glass material may provide a number of advantages compared to the typical curved or flat plastic panels that are conventionally found in vehicle interiors. For example, glass is typically considered to provide enhanced functionality and user experience for many flat or curved cover material applications, such as display applications and touch screen applications, compared to plastic cover materials.
Further, it is considered desirable in many applications to equip displays, and particularly displays for vehicle interior systems, with a deadfront appearance. In general, a deadfront appearance blocks visibility of underlying display components, icons, graphics, etc. when the display is off, but allows display components to be easily viewed when the display is on or activated (in the case of a touch-enabled display). In addition, an article that provides a deadfront effect (i.e., a deadfront article) can be used to match the color or pattern of the article to adjacent components to eliminate the visibility of transitions from the deadfront article to the surrounding components. This can be especially useful when the deadfront article is a different material from the surrounding components (e.g., the deadfront article is formed from a glass material but surrounded by a leather-covered center console). For example, a deadfront article may have a wood grain pattern or a leather pattern can be used to match the appearance of the display with surrounding wood or leather components of a vehicle interior system (e.g., a wood or leather dashboard) in which the display is mounted.
Various embodiments of the present disclosure relate to the formation of a curved glass-based deadfront article utilizing a cold-forming or cold-bending process. As discussed herein, curved glass-based deadfront articles and processes for making the same are provided that avoid the deficiencies of the typical glass hot-forming process. For example, hot-forming processes are energy intensive and increase the cost of forming a curved glass component, relative to the cold-bending processes discussed herein. In addition, hot-forming processes typically make application of glass coating layers, such as deadfront ink or pigment layers, more difficult. For example, many ink or pigment materials cannot be applied to a flat piece of glass material prior to the hot-forming process because the ink or pigment materials typically will not survive the high temperatures of the hot-forming process. Further, application of an ink or pigment material to surfaces of a curved glass article after hot-bending is substantially more difficult than application to a flat glass article.
Various embodiments of the present disclosure relate to deadfronted articles with areas of tactile feel on the front surface. As the use of touch screen and deadfront types displays increases, the importance of aesthetic features and the integration of form and function, also increases. A deadfront article that facilitates both visual and tactile interaction with a user makes interaction with article more convenient for a user. A deadfront article with areas of tactile fell can create “invisible” controls for a user on a decorated surface having the appearance of any material imagined (e.g., carbon fiber, stainless steel, wood, etc.) when the deadfront article is off.
The embodiments of the deadfront articles described herein can be used in any or all of vehicle interior systems 100, 200 and 300. While
Referring to
As will be discussed in more detail below, deadfront article 400 provides this differential icon display by utilizing one or more colored layers disposed between an outer substrate and a light source. The optical properties of the colored layers are designed such that when the light source is turned off the borders of the icons or other display structures beneath the colored layer are not visible, but when the light source is on, graphics 410 and/or icons 430 are visible. In various embodiments, the deadfront articles discussed herein are designed to provide a high quality deadfront appearance, including high contrast icons with the light source on, combined with a uniform deadfront appearance when the light is off. Further, these various deadfront articles may be formed using materials suitable for cold forming to curved shapes, including complex curved shapes, as discussed below.
Referring now to
The substrate 450 has an outer surface 480 facing a viewer and an inner surface 490 upon which the semi-transparent layer 460 and/or the contrast layer 470 are, at least in part, disposed. As used herein, the term “dispose” includes coating, depositing and/or forming a material onto a surface using any known method in the art. The disposed material may constitute a layer, as defined herein. As used herein, the phrase “disposed on” includes the instance of forming a material onto a surface such that the material is in direct contact with the surface and also includes the instance where the material is formed on a surface, with one or more intervening material(s) is between the disposed material and the surface. The intervening material(s) may constitute a layer, as defined herein. The term “layer” may include a single layer or may include one or more sub-layers. Such sub-layers may be in direct contact with one another. The sub-layers may be formed from the same material or two or more different materials. In one or more alternative embodiments, such sub-layers may have intervening layers of different materials disposed therebetween. In one or more embodiments a layer may include one or more contiguous and uninterrupted layers and/or one or more discontinuous and interrupted layers (i.e., a layer having different materials formed adjacent to one another). A layer or sub-layers may be formed by any known method in the art, including discrete deposition or continuous deposition processes. In one or more embodiments, the layer may be formed using only continuous deposition processes, or, alternatively, only discrete deposition processes.
While the specifics of the substrate 450 will be discussed in greater detail below, in some embodiments the substrate 450 has a thickness of from 0.05 to 2.0 mm (millimeters). In one or more embodiments, the substrate may be a transparent plastic, such as PMMA, polycarbonate and the like, or may include glass material (which may be optionally strengthened). As will also be discussed more fully below, in some embodiments the semi-transparent layer 460 is printed onto at least a portion of the inner surface 490 of the substrate 450. In other embodiments, the semi-transparent layer 460 is deposited using non-conductive vacuum metallization. Further, in some embodiments, the contrast layer 470 is printed onto at least a portion of the inner surface 490 of the substrate 450 and/or onto at least a portion of the semi-transparent layer 460.
In certain embodiments, such as shown in
As will be discussed more fully below, the opaque layer 510 has high optical density in order to block light transmittance. As used herein, “opaque layer” is used interchangeably with “high optical density layer.” In some embodiments, the opaque layer 510 is used to block light from transmitting through certain regions of the deadfront article 400. In certain embodiments, the opaque layer 510 obscures functional or non-decorative elements provided for the operation of the deadfront article 400. In other embodiments, the opaque layer 510 is provided to outline backlit icons and/or other graphics (such as the graphic 410 and/or power button 420 shown in
The opaque layer 510 can be any color; in particular embodiments, though, the opaque layer 510 is black or gray. In some embodiments, the opaque layer 510 is applied via screen printing or inkjet printing over the semi-transparent layer 460 and/or over the inner surface 490 of the substrate 450. Generally, the thickness of an inkjet-printed opaque layer 510 is from 1 μm to 5 μm (micrometers, microns), whereas the thickness of a screen-printed opaque layer 510 is from 5 μm to 20 μm. Thus, a printed opaque layer 510 can have a thickness in the range of from 1 μm to 20 μm. However, in other embodiments, the opaque layer 510 is a metal layer deposited via physical vapor deposition and/or is an optical stack produced using the high/low-index stacking discussed above for color matching.
In some embodiments, the optical densities of the layers are tailored to enhance the visibility of the graphics 410, power button 420, and/or icons 430 when the deadfront article 400 is backlit. In particular embodiments, the combined optical density of the semi-transparent layer 460 and the contrast layer 470 in illuminated regions (i.e., the graphic 410, the power button 420, and/or the icons 430) is from 1.0 to 2.1. In other embodiments, the combined optical density is 1.2 to 1.6, and in still other embodiments, the combined optical density is about 1.4. In providing the optical density of the illuminated regions, the optical density of the contrast layer 470 is from 0.9 to 2.0 in some embodiments, and the optical density of the semi-transparent layer 460 is 0.1 to 0.5 in some embodiments. In the non-illuminated regions (i.e., the regions surrounding the graphic 410, the power button 420, and/or the icons 430), the combined optical density of the semi-transparent layer 460, the contrast layer 470, and the opaque layer 510 is at least 3.4. In providing the optical density of the non-illuminated regions, the optical density of the contrast layer 470 is from 0.9 to 2.0 in some embodiments, the optical density of the semi-transparent layer 460 is from 0.1 to 0.5 in some embodiments, and the optical density of the opaque layer 510 is at least 2.4 in some embodiments. In exemplary embodiments, the optical density of the color layer 650 is from 0.3 to 0.7. Further, in some embodiments, the optical density of a particular layer can vary across the layer to provide enhanced contrast or to conserve the ink or material comprising the layer. For example, the optical density of the contrast layer 470 can be lower in illuminated regions than in non-illuminated regions. Additionally, the optical density of the color layer 650 can be lower (or zero) in non-illuminated regions than in illuminated regions.
As shown in
In certain embodiments, the deadfront article 400 is provided with touch functionality as shown in
Upon activation of a toggle switch (e.g., by touching the deadfront article 400 in the region of the transparent conductive film 550), a light source 570 is activated or deactivated 570. In the embodiment of
While the exemplary embodiment of a power button 420 for a display 530 was provided, the touch-functionality is suitable for other features. Continuing with the example of a vehicle, the touch-functionality is suitable for use in controlling a variety of vehicle systems, such as climate control (i.e., heating and air conditioning) systems, radio/entertainment systems, dashboard display panels (for, e.g., speedometer, odometer, trip odometer, tachometer, vehicle warning indicators, etc.), and center console display panels (for, e.g., GPS displays, in-vehicle information, etc.), among others. In
In particular embodiments, the substrate 450 is treated (e.g., via sandblasting, etching, engraving, etc.) in the area of a button to provide tactile feedback to a user's finger. In this way, the user can feel the deadfront article 400 for the button without removing his or her eyes from the road (in road vehicle settings). Further, in some embodiments, the toggle switch 560 is provided with a delay of, e.g., one to three seconds so as to avoid accidental activation of the toggle switch 560.
Having described generally the structure of the deadfront article 400, attention will be turned to the semi-transparent layer 460 and the contrast layer 470. As mentioned above, the semi-transparent layer 460 and the contrast layer 470 are disposed on the substrate 450. In some embodiments, the semi-transparent layer 460 is printed onto the substrate using a CMYK color model. In some embodiments in which the contrast layer is not white, such as gray, the CMYK color model can also be used to print the contrast layer 470. In other embodiments in which the contrast layer 470 is white, color models that incorporate white ink can be used for printing the contrast layer 470. The printed semi-transparent layer 460 and the printed contrast layer 470 may each have a thickness of from 1 μm to 6 μm. In some embodiments, the color layer 650 also has a thickness of from 1 μm to 6 μm. Further, in some embodiments, the color layer 650 is printed onto the opaque layer 510 and/or the contrast layer 470. In certain embodiments, the color layer 650 is printed onto the opaque layer 510 and/or contrast layer 470 using the CMYK color model.
The ink used for printing the semi-transparent layer 460, the contrast layer 470, and/or the color layer 650 can be thermal or UV cured ink. In particular, the ink is composed of at least one or more colorants and a vehicle. The colorants can be soluble or insoluble in the vehicle. In some embodiments, the colorants are dry colorants in the form of a fine powder. Such fine powders have particles that are, in some embodiments, from 10 nm to 500 nm in size. Using the CMYK color model, the colorant provides cyan, magenta, yellow, and/or key (black) colors. For white inks, the colorant can be any of a variety of suitable pigments, such as TiO2, Sb2O3, BaSO4, BaSO4:ZnS, ZnO, and (PbCO3)2:Pb(OH)2. The colorants are dissolved or suspended in the vehicle.
The vehicle can serve as a binder to create adhesion to the surface upon which the ink is applied. Further, in some embodiments, additives are included in the vehicle specifically for the purpose of improving adhesion to glass/plastic surfaces. Non-limiting examples of vehicles for the colorant include propylene glycol monomethyl ether, diethylene glycol diethyl ether, dimethylacetamide, and toluene. Generally, such vehicles solidify at temperatures from 80° C. to 200° C. In some embodiments, the ink includes from 0.5%-6% by volume of the colorant and 94%-99.5% by volume of the vehicle.
As shown in
The thickness and composition of the contrast layer 470 is tunable to exhibit a particular transmittance in the visible and infrared wavelength range.
Referring to
As shown in
Curved deadfront article 2000 includes a deadfront colored layer 2020 (e.g., the ink/pigment layer(s), as discussed above) located along an inner, major surface of curved outer glass substrate 2010. In general, deadfront colored layer 2020 is printed, colored, shaped, etc. to provide a wood-grain design, a leather-grain design, a fabric design, a brushed metal design, a graphic design, a solid color and/or a logo. However, embodiments of the invention are not limited to these designs or patterns. Curved deadfront article 2000 also may include any of the additional layers 2030 (e.g., high optical density layers, light guide layers, reflector layers, display module(s), display stack layers, light sources, touch panels, etc.) as discussed above or that otherwise may be associated with a display or vehicle interior system as discussed herein.
As will be discussed in more detail below, in various embodiments, curved deadfront article 2000 including glass substrate 2010 and colored layer 2020 may be cold-formed together to a curved shape, as shown in
Referring to
As shown in
In one or more embodiments, outer glass substrate 2010 has a thickness (t) that is in a range from 0.05 mm to 2 mm. In various embodiments, outer glass substrate 2010 has a thickness (t) that is about 1.5 mm or less. For example, the thickness may be in a range from about 0.1 mm to about 1.5 mm, from about 0.15 mm to about 1.5 mm, from about 0.2 mm to about 1.5 mm, from about 0.25 mm to about 1.5 mm, from about 0.3 mm to about 1.5 mm, from about 0.35 mm to about 1.5 mm, from about 0.4 mm to about 1.5 mm, from about 0.45 mm to about 1.5 mm, from about 0.5 mm to about 1.5 mm, from about 0.55 mm to about 1.5 mm, from about 0.6 mm to about 1.5 mm, from about 0.65 mm to about 1.5 mm, from about 0.7 mm to about 1.5 mm, from about 0.1 mm to about 1.4 mm, from about 0.1 mm to about 1.3 mm, from about 0.1 mm to about 1.2 mm, from about 0.1 mm to about 1.1 mm, from about 0.1 mm to about 1.05 mm, from about 0.1 mm to about 1 mm, from about 0.1 mm to about 0.95 mm, from about 0.1 mm to about 0.9 mm, from about 0.1 mm to about 0.85 mm, from about 0.1 mm to about 0.8 mm, from about 0.1 mm to about 0.75 mm, from about 0.1 mm to about 0.7 mm, from about 0.1 mm to about 0.65 mm, from about 0.1 mm to about 0.6 mm, from about 0.1 mm to about 0.55 mm, from about 0.1 mm to about 0.5 mm, from about 0.1 mm to about 0.4 mm, or from about 0.3 mm to about 0.7 mm.
In one or more embodiments, outer glass substrate 2010 has a width (W) in a range from about 5 cm to about 250 cm, from about 10 cm to about 250 cm, from about 15 cm to about 250 cm, from about 20 cm to about 250 cm, from about 25 cm to about 250 cm, from about 30 cm to about 250 cm, from about 35 cm to about 250 cm, from about 40 cm to about 250 cm, from about 45 cm to about 250 cm, from about 50 cm to about 250 cm, from about 55 cm to about 250 cm, from about 60 cm to about 250 cm, from about 65 cm to about 250 cm, from about 70 cm to about 250 cm, from about 75 cm to about 250 cm, from about 80 cm to about 250 cm, from about 85 cm to about 250 cm, from about 90 cm to about 250 cm, from about 95 cm to about 250 cm, from about 100 cm to about 250 cm, from about 110 cm to about 250 cm, from about 120 cm to about 250 cm, from about 130 cm to about 250 cm, from about 140 cm to about 250 cm, from about 150 cm to about 250 cm, from about 5 cm to about 240 cm, from about 5 cm to about 230 cm, from about 5 cm to about 220 cm, from about 5 cm to about 210 cm, from about 5 cm to about 200 cm, from about 5 cm to about 190 cm, from about 5 cm to about 180 cm, from about 5 cm to about 170 cm, from about 5 cm to about 160 cm, from about 5 cm to about 150 cm, from about 5 cm to about 140 cm, from about 5 cm to about 130 cm, from about 5 cm to about 120 cm, from about 5 cm to about 110 cm, from about 5 cm to about 100 cm, from about 5 cm to about 90 cm, from about 5 cm to about 80 cm, or from about 5 cm to about 75 cm.
In one or more embodiments, outer glass substrate 2010 has a length (L) in a range from about 5 cm to about 250 cm, from about 10 cm to about 250 cm, from about 15 cm to about 250 cm, from about 20 cm to about 250 cm, from about 25 cm to about 250 cm, from about 30 cm to about 250 cm, from about 35 cm to about 250 cm, from about 40 cm to about 250 cm, from about 45 cm to about 250 cm, from about 50 cm to about 250 cm, from about 55 cm to about 250 cm, from about 60 cm to about 250 cm, from about 65 cm to about 250 cm, from about 70 cm to about 250 cm, from about 75 cm to about 250 cm, from about 80 cm to about 250 cm, from about 85 cm to about 250 cm, from about 90 cm to about 250 cm, from about 95 cm to about 250 cm, from about 100 cm to about 250 cm, from about 110 cm to about 250 cm, from about 120 cm to about 250 cm, from about 130 cm to about 250 cm, from about 140 cm to about 250 cm, from about 150 cm to about 250 cm, from about 5 cm to about 240 cm, from about 5 cm to about 230 cm, from about 5 cm to about 220 cm, from about 5 cm to about 210 cm, from about 5 cm to about 200 cm, from about 5 cm to about 190 cm, from about 5 cm to about 180 cm, from about 5 cm to about 170 cm, from about 5 cm to about 160 cm, from about 5 cm to about 150 cm, from about 5 cm to about 140 cm, from about 5 cm to about 130 cm, from about 5 cm to about 120 cm, from about 5 cm to about 110 cm, from about 5 cm to about 100 cm, from about 5 cm to about 90 cm, from about 5 cm to about 80 cm, or from about 5 cm to about 75 cm.
As shown in
In specific embodiments, outer glass substrate 2010 is shaped to the curved shape shown in
In some such embodiments in which outer glass substrate 2010 is unstrengthened, the first major surface 2050 and the second major surface 2060 exhibit no appreciable compressive stress, prior to cold-forming. In some such embodiments in which outer glass substrate 2010 is strengthened (as described herein), the first major surface 2050 and the second major surface 2060 exhibit substantially equal compressive stress with respect to one another, prior to cold-forming. In one or more embodiments, after cold-forming (shown, for example, in
Without being bound by theory, the cold-forming process increases the compressive stress of the glass substrate being shaped to compensate for tensile stresses imparted during bending and/or forming operations. In one or more embodiments, the cold-forming process causes the second major surface 2060 to experience compressive stresses, while the first major surface 2050 (e.g., the convex surface following bending) experiences tensile stresses. The tensile stress experienced by surface 2050 following bending results in a net decrease in surface compressive stress, such that the compressive stress in surface 2050 of a strengthened glass sheet following bending is less than the compressive stress in surface 2050 when the glass sheet is flat.
Further, when a strengthened glass substrate is utilized for outer glass substrate 2010, the first major surface and the second major surface (2050,2060) are already under compressive stress, and thus first major surface 2050 can experience greater tensile stress during bending without risking fracture. This allows for the strengthened embodiments of outer glass substrate 2010 to conform to more tightly curved surfaces (e.g., shaped to have smaller R1 values).
In various embodiments, the thickness of outer glass substrate 2010 is tailored to allow outer glass substrate 2010 to be more flexible to achieve the desired radius of curvature. Moreover, a thinner outer glass substrate 2010 may deform more readily, which could potentially compensate for shape mismatches and gaps that may be created by the shape of a support or frame (as discussed below). In one or more embodiments, a thin and strengthened outer glass substrate 2010 exhibits greater flexibility especially during cold-forming. The greater flexibility of the glass substrate discussed herein may allow for consistent bend formation without heating.
In various embodiments, outer glass substrate 2010 (and consequently deadfront article 2000) may have a compound curve including a major radius and a cross curvature. A complexly curved cold-formed outer glass substrate 2010 may have a distinct radius of curvature in two independent directions. According to one or more embodiments, the complexly curved cold-formed outer glass substrate 2010 may thus be characterized as having “cross curvature,” where the cold-formed outer glass substrate 2010 is curved along an axis (i.e., a first axis) that is parallel to a given dimension and also curved along an axis (i.e., a second axis) that is perpendicular to the same dimension. The curvature of the cold-formed outer glass substrate 2010 can be even more complex when a significant minimum radius is combined with a significant cross curvature, and/or depth of bend.
Referring to
In various embodiments, the systems and methods described herein allow for formation of deadfront article 2000 to conform to a wide variety of curved shapes that frame 2110 may have. As shown in
In one or more embodiments, deadfront structure 2000 (and specifically outer glass substrate 2010) is shaped to have a first radius of curvature, R1, of about 60 mm or greater. For example, R1 may be in a range from about 60 mm to about 1500 mm, from about 70 mm to about 1500 mm, from about 80 mm to about 1500 mm, from about 90 mm to about 1500 mm, from about 100 mm to about 1500 mm, from about 120 mm to about 1500 mm, from about 140 mm to about 1500 mm, from about 150 mm to about 1500 mm, from about 160 mm to about 1500 mm, from about 180 mm to about 1500 mm, from about 200 mm to about 1500 mm, from about 220 mm to about 1500 mm, from about 240 mm to about 1500 mm, from about 250 mm to about 1500 mm, from about 260 mm to about 1500 mm, from about 270 mm to about 1500 mm, from about 280 mm to about 1500 mm, from about 290 mm to about 1500 mm, from about 300 mm to about 1500 mm, from about 350 mm to about 1500 mm, from about 400 mm to about 1500 mm, from about 450 mm to about 1500 mm, from about 500 mm to about 1500 mm, from about 550 mm to about 1500 mm, from about 600 mm to about 1500 mm, from about 650 mm to about 1500 mm, from about 700 mm to about 1500 mm, from about 750 mm to about 1500 mm, from about 800 mm to about 1500 mm, from about 900 mm to about 1500 mm, from about 9500 mm to about 1500 mm, from about 1000 mm to about 1500 mm, from about 1250 mm to about 1500 mm, from about 60 mm to about 1400 mm, from about 60 mm to about 1300 mm, from about 60 mm to about 1200 mm, from about 60 mm to about 1100 mm, from about 60 mm to about 1000 mm, from about 60 mm to about 950 mm, from about 60 mm to about 900 mm, from about 60 mm to about 850 mm, from about 60 mm to about 800 mm, from about 60 mm to about 750 mm, from about 60 mm to about 700 mm, from about 60 mm to about 650 mm, from about 60 mm to about 600 mm, from about 60 mm to about 550 mm, from about 60 mm to about 500 mm, from about 60 mm to about 450 mm, from about 60 mm to about 400 mm, from about 60 mm to about 350 mm, from about 60 mm to about 300 mm, or from about 60 mm to about 250 mm.
In one or more embodiments, support surface 2130 has a second radius of curvature of about 60 mm or greater. For example, the second radius of curvature of support surface 2130 may be in a range from about 60 mm to about 1500 mm, from about 70 mm to about 1500 mm, from about 80 mm to about 1500 mm, from about 90 mm to about 1500 mm, from about 100 mm to about 1500 mm, from about 120 mm to about 1500 mm, from about 140 mm to about 1500 mm, from about 150 mm to about 1500 mm, from about 160 mm to about 1500 mm, from about 180 mm to about 1500 mm, from about 200 mm to about 1500 mm, from about 220 mm to about 1500 mm, from about 240 mm to about 1500 mm, from about 250 mm to about 1500 mm, from about 260 mm to about 1500 mm, from about 270 mm to about 1500 mm, from about 280 mm to about 1500 mm, from about 290 mm to about 1500 mm, from about 300 mm to about 1500 mm, from about 350 mm to about 1500 mm, from about 400 mm to about 1500 mm, from about 450 mm to about 1500 mm, from about 500 mm to about 1500 mm, from about 550 mm to about 1500 mm, from about 600 mm to about 1500 mm, from about 650 mm to about 1500 mm, from about 700 mm to about 1500 mm, from about 750 mm to about 1500 mm, from about 800 mm to about 1500 mm, from about 900 mm to about 1500 mm, from about 9500 mm to about 1500 mm, from about 1000 mm to about 1500 mm, from about 1250 mm to about 1500 mm, from about 60 mm to about 1400 mm, from about 60 mm to about 1300 mm, from about 60 mm to about 1200 mm, from about 60 mm to about 1100 mm, from about 60 mm to about 1000 mm, from about 60 mm to about 950 mm, from about 60 mm to about 900 mm, from about 60 mm to about 850 mm, from about 60 mm to about 800 mm, from about 60 mm to about 750 mm, from about 60 mm to about 700 mm, from about 60 mm to about 650 mm, from about 60 mm to about 600 mm, from about 60 mm to about 550 mm, from about 60 mm to about 500 mm, from about 60 mm to about 450 mm, from about 60 mm to about 400 mm, from about 60 mm to about 350 mm, from about 60 mm to about 300 mm, or from about 60 mm to about 250 mm.
In one or more embodiments, deadfront structure 2000 is cold-formed to exhibit a first radius curvature, R1, that is within 10% (e.g., about 10% or less, about 9% or less, about 8% or less, about 7% or less, about 6% or less, or about 5% or less) of the second radius of curvature of support surface 2130 of frame 2110. For example, support surface 2130 of frame 2110 exhibits a radius of curvature of 1000 mm, deadfront article 2000 is cold-formed to have a radius of curvature in a range from about 900 mm to about 1100 mm.
In one or more embodiments, first major surface 2050 and/or second major surface 2060 of glass substrate 2010 includes a functional coating layer as described herein. The functional coating layer may cover at least a portion of first major surface 2050 and/or second major surface 2060. Exemplary functional coatings include at least one of a glare reduction coating or surface, an anti-glare coating or surface, a scratch resistance coating, an anti-reflection coating, a half-mirror coating, or easy-to-clean coating.
Referring to
At step 2220, the method includes securing the curved deadfront article to the support causing the deadfront article to bend into conformity (or conform) with the curved surface of the support. In this manner, a curved deadfront article 2000, as shown in
In some embodiments, the force applied in step 2210 and/or step 2220 may be air pressure applied via a vacuum fixture. In some other embodiments, the air pressure differential is formed by applying a vacuum to an airtight enclosure surrounding the frame and the deadfront article. In specific embodiments, the airtight enclosure is a flexible polymer shell, such as a plastic bag or pouch. In other embodiments, the air pressure differential is formed by generating increased air pressure around the deadfront article and the frame with an overpressure device, such as an autoclave. Air pressure provides a consistent and highly uniform bending force (as compared to a contact-based bending method) which further leads to a robust manufacturing process. In various embodiments, the air pressure differential is between 0.5 and 1.5 atmospheres of pressure (atm), specifically between 0.7 and 1.1 atm, and more specifically is 0.8 to 1 atm.
At step 2230, the temperature of the deadfront article is maintained below the glass transition temperature of the material of the outer glass layer during steps 2210 and 2220. As such, method 2200 is a cold-forming or cold-bending process. In particular embodiments, the temperature of the deadfront article is maintained below 500 degrees C., 400 degrees C., 300 degrees C., 200 degrees C. or 100 degrees C. In a particular embodiment, the deadfront article is maintained at or below room temperature during bending. In a particular embodiment, the deadfront article is not actively heated via a heating element, furnace, oven, etc. during bending, as is the case when hot-forming glass to a curved shape.
As noted above, in addition to providing processing advantages such as eliminating expensive and/or slow heating steps, the cold-forming processes discussed herein are believed to generate curved deadfront articles with a variety of properties that are believed to be superior to those achievable via hot-forming processes. For example, for at least some glass materials, heating during hot-forming processes decreases optical properties of curved glass substrates, and thus, the curved glass-based deadfront articles formed utilizing the cold-bending processes/systems discussed herein provide for both curved glass shape along with improved optical qualities not believed achievable with hot-bending processes.
Further, many materials used for the various coatings and layers (e.g., easy-to-clean coatings, anti-reflective coatings, etc.) are applied via deposition processes, such as sputtering processes that are typically ill-suited for coating on to a curved surface. In addition, many coating materials, such as the deadfront ink/pigment materials, also are not able to survive the high temperatures associated with hot-bending processes. Thus, in particular embodiments discussed herein, layer 2020 is applied to outer glass substrate 2010 prior to cold-bending. Thus, the processes and systems discussed herein allow for bending of glass after one or more coating material has been applied to the glass, in contrast to typical hot-forming processes.
At step 2220, the curved deadfront article is attached or affixed to the curved support. In various embodiments, the attachment between the curved deadfront article and the curved support may be accomplished via an adhesive material. Such adhesives may include any suitable optically clear adhesive for bonding the deadfront article in place relative to the display assembly (e.g., to the frame of the display). In one example, the adhesive may include an optically clear adhesive available from 3M Corporation under the trade name 8215. The thickness of the adhesive may be in a range from about 200 μm to about 500 μm.
The adhesive material may be applied in a variety of ways. In one embodiment, the adhesive is applied using an applicator gun and made uniform using a roller or a draw down die. In various embodiments, the adhesives discussed herein are structural adhesives. In particular embodiments, the structural adhesives may include an adhesive selected from one or more of the categories: (a) Toughened Epoxy (Masterbond EP21TDCHT-LO, 3M Scotch Weld Epoxy DP460 Off-white); (b) Flexible Epoxy (Masterbond EP21TDC-2LO, 3M Scotch Weld Epoxy 2216 B/A Gray); (c) Acrylic (LORD Adhesive 410/Accelerator 19 w/LORD AP 134 primer, LORD Adhesive 852/LORD Accelerator 25 GB, Loctite HF8000, Loctite AA4800); (d) Urethanes (3M Scotch Weld Urethane DP640 Brown); and (e) Silicones (Dow Corning 995). In some cases, structural glues available in sheet format (such as B-staged epoxy adhesives) may be utilized. Furthermore, pressure sensitive structural adhesives such as 3M VHB tapes may be utilized. In such embodiments, utilizing a pressure sensitive adhesive allows for the curved deadfront article to be bonded to the frame without the need for a curing step.
In one or more embodiments, the method includes step 2240 in which the curved deadfront is secured to a display. In one or more embodiments, the method may include securing the display to the deadfront article before step 2210 and curving both the display and the deadfront article in step 2210. In one or more embodiments, the method includes disposing or assembling the curved deadfront and display in a vehicle interior system 100, 200, 300.
Referring to
Substrate Materials
The various substrates of the deadfront articles discussed herein may be formed from any transparent material such as a polymer (e.g., PMMA, polycarbonate and the like) or glass. Suitable glass compositions include soda lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.
In some embodiments, a substrate discussed herein may be formed of a “glass-ceramic” material produced through controlled crystallization of glass. In such embodiments, glass-ceramics have about 30% to about 90% crystallinity. Non-limiting examples of glass ceramic systems that may be used include Li2O×Al2O3×nSiO2 (i.e. LAS system), MgO×Al2O3×nSiO2 (i.e. MAS system), and ZnO×Al2O3×nSiO2 (i.e. ZAS system).
Unless otherwise specified, the glass compositions disclosed herein are described in mole percent (mol %) as analyzed on an oxide basis.
In one or more embodiments, the glass composition may include SiO2 in an amount in a range from about 66 mol % to about 80 mol %, from about 67 mol % to about 80 mol %, from about 68 mol % to about 80 mol %, from about 69 mol % to about 80 mol %, from about 70 mol % to about 80 mol %, from about 72 mol % to about 80 mol %, from about 65 mol % to about 78 mol %, from about 65 mol % to about 76 mol %, from about 65 mol % to about 75 mol %, from about 65 mol % to about 74 mol %, from about 65 mol % to about 72 mol %, or from about 65 mol % to about 70 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition includes Al2O3 in an amount greater than about 4 mol %, or greater than about 5 mol %. In one or more embodiments, the glass composition includes Al2O3 in a range from greater than about 7 mol % to about 15 mol %, from greater than about 7 mol % to about 14 mol %, from about 7 mol % to about 13 mol %, from about 4 mol % to about 12 mol %, from about 7 mol % to about 11 mol %, from about 8 mol % to about 15 mol %, from 9 mol % to about 15 mol %, from about 9 mol % to about 15 mol %, from about 10 mol % to about 15 mol %, from about 11 mol % to about 15 mol %, or from about 12 mol % to about 15 mol %, and all ranges and sub-ranges therebetween. In one or more embodiments, the upper limit of Al2O3 may be about 14 mol %, 14.2 mol %, 14.4 mol %, 14.6 mol %, or 14.8 mol %.
In one or more embodiments, glass layer(s) herein are described as an aluminosilicate glass article or including an aluminosilicate glass composition. In such embodiments, the glass composition or article formed therefrom includes SiO2 and Al2O3 and is not a soda lime silicate glass. In this regard, the glass composition or article formed therefrom includes Al2O3 in an amount of about 2 mol % or greater, 2.25 mol % or greater, 2.5 mol % or greater, about 2.75 mol % or greater, about 3 mol % or greater.
In one or more embodiments, the glass composition comprises B2O3 (e.g., about 0.01 mol % or greater). In one or more embodiments, the glass composition comprises B2O3 in an amount in a range from about 0 mol % to about 5 mol %, from about 0 mol % to about 4 mol %, from about 0 mol % to about 3 mol %, from about 0 mol % to about 2 mol %, from about 0 mol % to about 1 mol %, from about 0 mol % to about 0.5 mol %, from about 0.1 mol % to about 5 mol %, from about 0.1 mol % to about 4 mol %, from about 0.1 mol % to about 3 mol %, from about 0.1 mol % to about 2 mol %, from about 0.1 mol % to about 1 mol %, from about 0.1 mol % to about 0.5 mol %, and all ranges and sub-ranges therebetween. In one or more embodiments, the glass composition is substantially free of B2O3.
As used herein, the phrase “substantially free” with respect to the components of the composition means that the component is not actively or intentionally added to the composition during initial batching, but may be present as an impurity in an amount less than about 0.001 mol %.
In one or more embodiments, the glass composition optionally comprises P2O5 (e.g., about 0.01 mol % or greater). In one or more embodiments, the glass composition comprises a non-zero amount of P2O5 up to and including 2 mol %, 1.5 mol %, 1 mol %, or 0.5 mol %. In one or more embodiments, the glass composition is substantially free of P2O5.
In one or more embodiments, the glass composition may include a total amount of R2O (which is the total amount of alkali metal oxide such as Li2O, Na2O, K2O, Rb2O, and Cs2O) that is greater than or equal to about 8 mol %, greater than or equal to about 10 mol %, or greater than or equal to about 12 mol %. In some embodiments, the glass composition includes a total amount of R2O in a range from about 8 mol % to about 20 mol %, from about 8 mol % to about 18 mol %, from about 8 mol % to about 16 mol %, from about 8 mol % to about 14 mol %, from about 8 mol % to about 12 mol %, from about 9 mol % to about 20 mol %, from about 10 mol % to about 20 mol %, from about 11 mol % to about 20 mol %, from about 12 mol % to about 20 mol %, from about 13 mol % to about 20 mol %, from about 10 mol % to about 14 mol %, or from 11 mol % to about 13 mol %, and all ranges and sub-ranges therebetween. In one or more embodiments, the glass composition may be substantially free of Rb2O, Cs2O or both Rb2O and Cs2O. In one or more embodiments, the R2O may include the total amount of Li2O, Na2O and K2O only. In one or more embodiments, the glass composition may comprise at least one alkali metal oxide selected from Li2O, Na2O and K2O, wherein the alkali metal oxide is present in an amount greater than about 8 mol % or greater.
In one or more embodiments, the glass composition comprises Na2O in an amount greater than or equal to about 8 mol %, greater than or equal to about 10 mol %, or greater than or equal to about 12 mol %. In one or more embodiments, the composition includes Na2O in a range from about from about 8 mol % to about 20 mol %, from about 8 mol % to about 18 mol %, from about 8 mol % to about 16 mol %, from about 8 mol % to about 14 mol %, from about 8 mol % to about 12 mol %, from about 9 mol % to about 20 mol %, from about 10 mol % to about 20 mol %, from about 11 mol % to about 20 mol %, from about 12 mol % to about 20 mol %, from about 13 mol % to about 20 mol %, from about 10 mol % to about 14 mol %, or from 11 mol % to about 16 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition includes less than about 4 mol % K2O, less than about 3 mol % K2O, or less than about 1 mol % K2O. In some instances, the glass composition may include K2O in an amount in a range from about 0 mol % to about 4 mol %, from about 0 mol % to about 3.5 mol %, from about 0 mol % to about 3 mol %, from about 0 mol % to about 2.5 mol %, from about 0 mol % to about 2 mol %, from about 0 mol % to about 1.5 mol %, from about 0 mol % to about 1 mol %, from about 0 mol % to about 0.5 mol %, from about 0 mol % to about 0.2 mol %, from about 0 mol % to about 0.1 mol %, from about 0.5 mol % to about 4 mol %, from about 0.5 mol % to about 3.5 mol %, from about 0.5 mol % to about 3 mol %, from about 0.5 mol % to about 2.5 mol %, from about 0.5 mol % to about 2 mol %, from about 0.5 mol % to about 1.5 mol %, or from about 0.5 mol % to about 1 mol %, and all ranges and sub-ranges therebetween. In one or more embodiments, the glass composition may be substantially free of K2O.
In one or more embodiments, the glass composition is substantially free of Li2O. In one or more embodiments, the amount of Na2O in the composition may be greater than the amount of Li2O. In some instances, the amount of Na2O may be greater than the combined amount of Li2O and K2O. In one or more alternative embodiments, the amount of Li2O in the composition may be greater than the amount of Na2O or the combined amount of Na2O and K2O.
In one or more embodiments, the glass composition may include a total amount of RO (which is the total amount of alkaline earth metal oxide such as CaO, MgO, BaO, ZnO and SrO) in a range from about 0 mol % to about 2 mol %. In some embodiments, the glass composition includes a non-zero amount of RO up to about 2 mol %. In one or more embodiments, the glass composition comprises RO in an amount from about 0 mol % to about 1.8 mol %, from about 0 mol % to about 1.6 mol %, from about 0 mol % to about 1.5 mol %, from about 0 mol % to about 1.4 mol %, from about 0 mol % to about 1.2 mol %, from about 0 mol % to about 1 mol %, from about 0 mol % to about 0.8 mol %, from about 0 mol % to about 0.5 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition includes CaO in an amount less than about 1 mol %, less than about 0.8 mol %, or less than about 0.5 mol %. In one or more embodiments, the glass composition is substantially free of CaO.
In some embodiments, the glass composition comprises MgO in an amount from about 0 mol % to about 7 mol %, from about 0 mol % to about 6 mol %, from about 0 mol % to about 5 mol %, from about 0 mol % to about 4 mol %, from about 0.1 mol % to about 7 mol %, from about 0.1 mol % to about 6 mol %, from about 0.1 mol % to about 5 mol %, from about 0.1 mol % to about 4 mol %, from about 1 mol % to about 7 mol %, from about 2 mol % to about 6 mol %, or from about 3 mol % to about 6 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition comprises ZrO2 in an amount equal to or less than about 0.2 mol %, less than about 0.18 mol %, less than about 0.16 mol %, less than about 0.15 mol %, less than about 0.14 mol %, less than about 0.12 mol %. In one or more embodiments, the glass composition comprises ZrO2 in a range from about 0.01 mol % to about 0.2 mol %, from about 0.01 mol % to about 0.18 mol %, from about 0.01 mol % to about 0.16 mol %, from about 0.01 mol % to about 0.15 mol %, from about 0.01 mol % to about 0.14 mol %, from about 0.01 mol % to about 0.12 mol %, or from about 0.01 mol % to about 0.10 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition comprises SnO2 in an amount equal to or less than about 0.2 mol %, less than about 0.18 mol %, less than about 0.16 mol %, less than about 0.15 mol %, less than about 0.14 mol %, less than about 0.12 mol %. In one or more embodiments, the glass composition comprises SnO2 in a range from about 0.01 mol % to about 0.2 mol %, from about 0.01 mol % to about 0.18 mol %, from about 0.01 mol % to about 0.16 mol %, from about 0.01 mol % to about 0.15 mol %, from about 0.01 mol % to about 0.14 mol %, from about 0.01 mol % to about 0.12 mol %, or from about 0.01 mol % to about 0.10 mol %, and all ranges and sub-ranges therebetween.
In one or more embodiments, the glass composition may include an oxide that imparts a color or tint to the glass articles. In some embodiments, the glass composition includes an oxide that prevents discoloration of the glass article when the glass article is exposed to ultraviolet radiation. Examples of such oxides include, without limitation oxides of: Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Ce, W, and Mo.
In one or more embodiments, the glass composition includes Fe expressed as Fe2O3, wherein Fe is present in an amount up to (and including) about 1 mol %. In some embodiments, the glass composition is substantially free of Fe. In one or more embodiments, the glass composition comprises Fe2O3 in an amount equal to or less than about 0.2 mol %, less than about 0.18 mol %, less than about 0.16 mol %, less than about 0.15 mol %, less than about 0.14 mol %, less than about 0.12 mol %. In one or more embodiments, the glass composition comprises Fe2O3 in a range from about 0.01 mol % to about 0.2 mol %, from about 0.01 mol % to about 0.18 mol %, from about 0.01 mol % to about 0.16 mol %, from about 0.01 mol % to about 0.15 mol %, from about 0.01 mol % to about 0.14 mol %, from about 0.01 mol % to about 0.12 mol %, or from about 0.01 mol % to about 0.10 mol %, and all ranges and sub-ranges therebetween.
Where the glass composition includes TiO2, TiO2 may be present in an amount of about 5 mol % or less, about 2.5 mol % or less, about 2 mol % or less or about 1 mol % or less. In one or more embodiments, the glass composition may be substantially free of TiO2.
An exemplary glass composition includes SiO2 in an amount in a range from about 65 mol % to about 75 mol %, Al2O3 in an amount in a range from about 8 mol % to about 14 mol %, Na2O in an amount in a range from about 12 mol % to about 17 mol %, K2O in an amount in a range of about 0 mol % to about 0.2 mol %, and MgO in an amount in a range from about 1.5 mol % to about 6 mol %. Optionally, SnO2 may be included in the amounts otherwise disclosed herein.
Strengthened Substrate
In one or more embodiments, the substrate includes a glass material (such as outer glass substrate 2010 or other glass substrate) of any of the deadfront article embodiments discussed herein. In one or more embodiments, such glass substrates may be strengthened. In one or more embodiments, the glass substrate may be strengthened to include compressive stress that extends from a surface to a depth of compression (DOC). The compressive stress regions are balanced by a central portion exhibiting a tensile stress. At the DOC, the stress crosses from a positive (compressive) stress to a negative (tensile) stress.
In one or more embodiments, the glass substrates used in the deadfront articles discussed herein may be strengthened mechanically by utilizing a mismatch of the coefficient of thermal expansion between portions of the glass to create a compressive stress region and a central region exhibiting a tensile stress. In some embodiments, the glass substrate may be strengthened thermally by heating the glass to a temperature above the glass transition point and then rapidly quenching.
In one or more embodiments, the glass substrate used in the deadfront articles discussed herein may be chemically strengthening by ion exchange. In the ion exchange process, ions at or near the surface of the glass substrate are replaced by—or exchanged with—larger ions having the same valence or oxidation state. In those embodiments in which the glass substrate comprises an alkali aluminosilicate glass or soda lime silicate glass, ions in the surface layer of the article and the larger ions are monovalent alkali metal cations, such as Li+, Na+, K+, Rb+, and Cs+. Alternatively, monovalent cations in the surface layer may be replaced with monovalent cations other than alkali metal cations, such as Ag+ or the like. In such embodiments, the monovalent ions (or cations) exchanged into the glass substrate generate a stress.
Ion exchange processes are typically carried out by immersing a glass substrate in a molten salt bath (or two or more molten salt baths) containing the larger ions to be exchanged with the smaller ions in the glass substrate. It should be noted that aqueous salt baths may also be utilized. In addition, the composition of the bath(s) may include more than one type of larger ion (e.g., Na+ and K+) or a single larger ion. It will be appreciated by those skilled in the art that parameters for the ion exchange process, including, but not limited to, bath composition and temperature, immersion time, the number of immersions of the glass substrate in a salt bath (or baths), use of multiple salt baths, additional steps such as annealing, washing, and the like, are generally determined by the composition of the glass substrate (including the structure of the substrate and any crystalline phases present) and the desired DOC and CS of the substrate that results from strengthening.
Exemplary molten bath composition may include nitrates, sulfates, and chlorides of the larger alkali metal ion. Typical nitrates include KNO3, NaNO3, LiNO3, NaSO4 and combinations thereof. The temperature of the molten salt bath typically is in a range from about 380° C. up to about 450° C., while immersion times range from about 15 minutes up to about 100 hours depending on the glass thickness, bath temperature and glass (or monovalent ion) diffusivity. However, temperatures and immersion times different from those described above may also be used.
In one or more embodiments, the glass substrate used to in the deadfront articles may be immersed in a molten salt bath of 100% NaNO3, 100% KNO3, or a combination of NaNO3 and KNO3 having a temperature from about 370° C. to about 480° C. In some embodiments, the glass substrate of a deadfront article may be immersed in a molten mixed salt bath including from about 5% to about 90% KNO3 and from about 10% to about 95% NaNO3. In one or more embodiments, the glass substrate may be immersed in a second bath, after immersion in a first bath. The first and second baths may have different compositions and/or temperatures from one another. The immersion times in the first and second baths may vary. For example, immersion in the first bath may be longer than the immersion in the second bath.
In one or more embodiments, the glass substrate used to form the deadfront articles may be immersed in a molten, mixed salt bath including NaNO3 and KNO3 (e.g., 49%/51%, 50%/50%, 51%/49%) having a temperature less than about 420° C. (e.g., about 400° C. or about 380° C.). for less than about 5 hours, or even about 4 hours or less.
Ion exchange conditions can be tailored to provide a “spike” or to increase the slope of the stress profile at or near the surface of the resulting glass substrate of a deadfront article. The spike may result in a greater surface CS value. This spike can be achieved by single bath or multiple baths, with the bath(s) having a single composition or mixed composition, due to the unique properties of the glass compositions used in the glass substrate of a deadfront article described herein.
In one or more embodiments, where more than one monovalent ion is exchanged into the glass substrate used in the deadfront articles, the different monovalent ions may exchange to different depths within the glass substrate (and generate different magnitudes stresses within the glass substrate at different depths). The resulting relative depths of the stress-generating ions can be determined and cause different characteristics of the stress profile.
CS is measured using those means known in the art, such as by surface stress meter (FSM) using commercially available instruments such as the FSM-6000, manufactured by Orihara Industrial Co., Ltd. (Japan). Surface stress measurements rely upon the accurate measurement of the stress optical coefficient (SOC), which is related to the birefringence of the glass. SOC in turn is measured by those methods that are known in the art, such as fiber and four-point bend methods, both of which are described in ASTM standard C770-98 (2013), entitled “Standard Test Method for Measurement of Glass Stress-Optical Coefficient,” the contents of which are incorporated herein by reference in their entirety, and a bulk cylinder method. As used herein CS may be the “maximum compressive stress” which is the highest compressive stress value measured within the compressive stress layer. In some embodiments, the maximum compressive stress is located at the surface of the glass substrate. In other embodiments, the maximum compressive stress may occur at a depth below the surface, giving the compressive profile the appearance of a “buried peak.”
DOC may be measured by FSM or by a scattered light polariscope (SCALP) (such as the SCALP-04 scattered light polariscope available from GlasStress Ltd., located in Tallinn Estonia), depending on the strengthening method and conditions. When the glass substrate is chemically strengthened by an ion exchange treatment, FSM or SCALP may be used depending on which ion is exchanged into the glass substrate. Where the stress in the glass substrate is generated by exchanging potassium ions into the glass substrate, FSM is used to measure DOC. Where the stress is generated by exchanging sodium ions into the glass substrate, SCALP is used to measure DOC. Where the stress in the glass substrate is generated by exchanging both potassium and sodium ions into the glass, the DOC is measured by SCALP, since it is believed the exchange depth of sodium indicates the DOC and the exchange depth of potassium ions indicates a change in the magnitude of the compressive stress (but not the change in stress from compressive to tensile); the exchange depth of potassium ions in such glass substrate is measured by FSM. Central tension or CT is the maximum tensile stress and is measured by SCALP.
In one or more embodiments, the glass substrate used to form the deadfront articles maybe strengthened to exhibit a DOC that is described a fraction of the thickness t of the glass substrate (as described herein). For example, in one or more embodiments, the DOC may be equal to or greater than about 0.05 t, equal to or greater than about 0.1 t, equal to or greater than about 0.11 t, equal to or greater than about 0.12 t, equal to or greater than about 0.13 t, equal to or greater than about 0.14 t, equal to or greater than about 0.15 t, equal to or greater than about 0.16 t, equal to or greater than about 0.17 t, equal to or greater than about 0.18 t, equal to or greater than about 0.19 t, equal to or greater than about 0.2 t, equal to or greater than about 0.21 t. In some embodiments, The DOC may be in a range from about 0.08 t to about 0.25 t, from about 0.09 t to about 0.25 t, from about 0.18 t to about 0.25 t, from about 0.11 t to about 0.25 t, from about 0.12 t to about 0.25 t, from about 0.13 t to about 0.25 t, from about 0.14 t to about 0.25 t, from about 0.15 t to about 0.25 t, from about 0.08 t to about 0.24 t, from about 0.08 t to about 0.23 t, from about 0.08 t to about 0.22 t, from about 0.08 t to about 0.21 t, from about 0.08 t to about 0.2 t, from about 0.08 t to about 0.19 t, from about 0.08 t to about 0.18 t, from about 0.08 t to about 0.17 t, from about 0.08 t to about 0.16 t, or from about 0.08 t to about 0.15 t. In some instances, the DOC may be about 20 μm or less. In one or more embodiments, the DOC may be about 40 μm or greater (e.g., from about 40 μm to about 300 μm, from about 50 μm to about 300 μm, from about 60 μm to about 300 μm, from about 70 μm to about 300 μm, from about 80 μm to about 300 μm, from about 90 μm to about 300 μm, from about 100 μm to about 300 μm, from about 110 μm to about 300 μm, from about 120 μm to about 300 μm, from about 140 μm to about 300 μm, from about 150 μm to about 300 μm, from about 40 μm to about 290 μm, from about 40 μm to about 280 μm, from about 40 μm to about 260 μm, from about 40 μm to about 250 μm, from about 40 μm to about 240 μm, from about 40 μm to about 230 μm, from about 40 μm to about 220 μm, from about 40 μm to about 210 μm, from about 40 μm to about 200 μm, from about 40 μm to about 180 μm, from about 40 μm to about 160 μm, from about 40 μm to about 150 μm, from about 40 μm to about 140 μm, from about 40 μm to about 130 μm, from about 40 μm to about 120 μm, from about 40 μm to about 110 μm, or from about 40 μm to about 100 μm.
In one or more embodiments, the glass substrate used to form the deadfront articles may have a CS (which may be found at the surface or a depth within the glass article) of about 200 MPa or greater, 300 MPa or greater, 400 MPa or greater, about 500 MPa or greater, about 600 MPa or greater, about 700 MPa or greater, about 800 MPa or greater, about 900 MPa or greater, about 930 MPa or greater, about 1000 MPa or greater, or about 1050 MPa or greater.
In one or more embodiments, the glass substrate used to form the deadfront articles may have a maximum tensile stress or central tension (CT) of about 20 MPa or greater, about 30 MPa or greater, about 40 MPa or greater, about 45 MPa or greater, about 50 MPa or greater, about 60 MPa or greater, about 70 MPa or greater, about 75 MPa or greater, about 80 MPa or greater, or about 85 MPa or greater. In some embodiments, the maximum tensile stress or central tension (CT) may be in a range from about 40 MPa to about 100 MPa.
Tactile Elements
Substrate 700 includes at least one visual element 710-1, 710-2 disposed on second surface 704 of substrate 700 such that the at least one visual element may be viewed through first surface 702 thereof. Additionally and/or alternatively, at least one visual element 710-1, 710-2 may be disposed within the substrate 700 using known techniques (e.g., using pigmented glass, etc.). Visual element(s) 710-1, 710-2 may be or may include one or more graphics visible through first surface 702. In some embodiments, the one or more graphics may include one or more icons.
In some embodiments, at least one visual element 710-1, 710-2 may be defined in whole or in part by an opaque layer (e.g., opaque layer 510). In some embodiments, the opaque layer may be provided to outline backlit icons and/or other graphics (such as the graphic 410 and/or power button 420 shown in
Visual element(s) 710-1, 710-2 may include one or more visual portions arranged into at least one of: (i) one or more areas of color, (ii) one or more lines, (iii) one or more patterns, (iv) one or more designs, (v) one or more images, (vi) one or more graphics, and (vii) one or more combinations thereof. By way of example only, a first visual element 710-1 may be a circle formed via color, lines, patterns, shading, masking, design, etc., and a second visual element 710-2 may be a triangle formed via color, lines, patterns, shading, masking, design, etc. Those skilled in the art will appreciate that the particular artistic elements comprised within visual element(s) 710-1, 710-2 are numerous, and the illustrated examples are not limiting.
In some embodiments, visual element(s) 710-1, 710-2 may be disposed on second surface 704 of substrate 700, serving as an inner surface of an article (e.g., inner surface 490 of deadfront article 400). Thus, visual element(s) 710-1, 710-2 may be seen by the user through first surface 702 of substrate 700 but the visual element(s) 710-1, 710-2 are protected from wear or damage by way of being disposed on second surface 704 of substrate 700. As noted above, additional and/or alternative embodiments may include the at least one visual element 710-1, 710-2 disposed within substrate 700.
As illustrated in
A surface roughness discussed herein may be quantified, for example, as exhibiting an Ra surface roughness of between about 10 nm and about 80 nm for a relatively smooth surface roughness (including subranges), between about 80 nm and about 300 nm for a relatively moderate surface roughness (including subranges), and greater than about 300 nm for a relatively rough surface roughness. For example, a relatively smooth surface roughness may have a Ra surface roughness of 10 nm, 20 nm, 30 nm, 40 nm, 50 nm, 60 nm, 70 nm, 80 nm, or a Ra surface roughness in a range having any two of these values as endpoints. As another example, a relatively moderate surface roughness may have a Ra surface roughness of 80 nm, 100 nm, 125 nm, 150 nm, 175 nm, 200 nm, 225 nm, 250 nm, 275 nm, or 300 nm, or Ra surface roughness in a range having any two of these values as endpoints. The height difference characteristics of the small surface elements discussed herein may be implemented via relatively small elements extending away from a surface of the substrate and may be quantified, for example, as having a height of between about 10 nm and about 80 nm for a relatively smooth surface roughness, between about 80 nm and about 300 nm for a relatively moderate surface roughness, and greater than about 300 nm for a relatively rough surface roughness.
A surface roughness (Ra) is defined as the arithmetic average of the differences between the local surface heights and the average surface height and can be described by the Equation (1):
where yi is the local surface height relative to the average surface height where the surface roughness (Ra) in at least three sample areas (n) of about 100 μm by 100 μm are measured and averaged. Surface roughness (Ra) may be measured using a surface profilometer available from Zygo Corp.
The aforementioned provision of providing at least one tactile element 712-1, 712-2 in a commentary fashion to at least one visual element 710-1, 710-2 may include providing lines, areas, designs, shapes, patterns, etc. of surface roughness and/or small surface elements on first surface 702 of the substrate 700 that substantially match (e.g., are in registration with) corresponding lines, shapes, patterns, graphics, colors, etc. of at least one visual element 710-1, 710-2.
As used herein, two objects disposed or positioned in a “complimentary fashion” means that the two objects have substantially the same overall shape, perimeter shape, design, and/or pattern, and occupy substantially the same relative surface area on opposing surfaces of a substrate. In embodiments including an object formed within a substrate (e.g., a visual element disposed within a substrate), the overall shape, perimeter shape, design, and/or pattern, and the relative surface area of such an object is the overall shape, perimeter shape, design, and/or pattern, and surface area of that object projected onto a surface of the substrate opposite the surface on which the corresponding object is disposed or positioned in a complimentary fashion.
In some embodiments, desirable visual effects may be obtained without disposing objects in a complementary fashion. In some embodiments, at least one tactile element 712-1, 712-2 may be disposed in a non-commentary fashion (e.g., offset fashion) to at least one visual element 710-1, 710-2 to produce desirable visual effect.
Tactile element(s) 712-1, 712-2 include one or more surface roughness portions and/or small surface elements arranged into at least one of: (i) one or more areas of surface roughness and/or small surface elements, (ii) one or more lines of surface roughness and/or small surface elements, (iii) one or more patterns of surface roughness and/or small surface elements, (iv) one or more designs of surface roughness and/or small surface elements, and (v) one or more combinations thereof. By way of example only, first tactile element 712-1 may be a circle formed via a line of elevated surface roughness and/or small surface elements, or a line of reduced surface roughness and/or small surface elements, and second tactile element 712-2 may be a triangle formed via a line of elevated surface roughness and/or small surface elements, or a line of reduced surface roughness and/or small surface elements. Again, those skilled in the art will appreciate that the particular artistic elements comprised within tactile element(s) 712-1, 712-2 are numerous.
As will be discussed herein, tactile element(s) 712-1, 712-2 may be applied to first surface 702 of substrate 700 in such a way that first surface 702 serves as an outer surface of an article. First surface 702 of substrate 700 may be subject to surface processing in order to provide some level of surface roughening (e.g., a hazing effect) that provides some tactile feedback to the user. As described herein, the level of surface roughness and/or small surface elements may range from a feeling of smooth (very little or no surface roughness and/or small surface elements), to a feeling of velvety softness (moderate levels of surface roughness, such as a matte surface roughness, and/or moderate levels of small surface elements), to a feeling of substantial roughness (higher levels of roughness and/or small surface elements) in order to achieve design goals.
As shown in
In this example, first tactile element 712-1 positioned in a complimentary fashion to first visual element 710-1 may be achieved via a first surface roughness portion (and/or small surface element portion) of first tactile element 712-1 in the form of a line (e.g., a circular outline) of complementary size and shape as the circle of first visual element 710-1. Similarly, second tactile element 712-2 positioned in a complimentary fashion to second visual element 710-2 may be achieved via a second surface roughness portion (and/or small surface element portion) of second tactile element 712-2 in the form of a line (e.g., a triangular outline) of complementary size and shape as the triangle of second visual element 710-2.
The surface roughness portions (and/or small surface element portions) of tactile element(s) 712-1, 712-2 may be achieved in any number of ways. For example, the surface roughness portions (and/or small surface element portion) may be defined by an area (e.g., a circle, a triangle, a circular and/or triangular area) of relatively higher surface roughness (and/or higher surface element height) that is positioned in the visually complimentary fashion with respect to corresponding visual element(s) 710-1 and/or 710-2 bordered by at least one area of relatively lower surface roughness (and/or lower surface element height). One way of achieving such an effect is to provide: (i) a majority of a total surface area of first surface 702 of substrate 700 as a relatively smooth finish of relatively low surface roughness (e.g., ranging from no surface roughness or no surface element height to some low or moderate level of surface roughness, such as a matte finish surface roughness, and/or moderate level of surface element height); and (ii) the area of relatively higher surface roughness, and/or higher surface element height (e.g., the circular and/or triangular outline, circular and/or triangular area) of tactile element(s) 712-1 and/or 712-2 as a minority of the total surface area of first surface 702 and include at least some portions of such circular and/or triangular outline via a surface roughness and/or surface element height that is relatively rougher (e.g., ranging from a moderate level of surface roughness and/or moderate surface element height to a high level of surface roughness and/or high surface element height) as compared with the smooth finish.
Alternatively, the surface roughness portions and/or surface element portions of tactile element(s) 712-1, 712-2 (e.g., in the form of a tringle or triangular outline) may be achieved via an area of relatively lower surface roughness and/or lower surface element height that is positioned in the visually complimentary fashion bordered by at least one area of relatively higher surface roughness. One way of achieving such an effect is to provide: (i) a majority of a total surface area of first surface 702 of substrate 700 as a relatively rough finish (e.g., ranging from some moderate level of surface roughness, such as from rougher than a matte finish surface roughness, and/or some moderate level of surface element height, to some high level of surface roughness and/or some high level of surface element height); and (ii) the area of relatively lower surface roughness and/or relatively lower surface element height (e.g., the circle, the triangle, the circular and/or triangular outline) of tactile element(s) 712-1 and/or 712-2 as a minority of the total surface area of first surface 702 and include at least some portions of such circle, triangle, circular and/or triangular outline, via a surface roughness and/or surface element height that is relatively smoother (e.g., ranging from no surface roughness and/or no surface element height to some low level of surface roughness and/or low level of surface element height) as compared with the rough finish.
A process for achieving the application of at least one tactile element 712-1, 712-2 and at least one visual element 710-1, 710-2 to substrate 700 will be discussed with reference to
For purposes of this example, at least one tactile element 710-1, 710-2 is achieved via surface roughness characteristics. The process disclosed in
At step 750, substantially all of second surface 704 of the substrate 700 is masked with an etch resistant material (e.g., with an etch resistive ink, as shown in black at step 750). Next, at least first surface 702 of substrate 700 is exposed (e.g., dipped, sprayed, etc.) to an acid solution (etching solution) to generate a low to medium level of surface roughness on first surface 702, such as a matte finish surface roughness. The resultant matte finish is shown in grey at step 752 in which the etch resistive ink has been removed to expose the relatively smooth finish of the second surface 704 of the substrate 700 (shown in white at step 752). In some embodiments, second surface 704 of substrate 700 may not be directly masked with an etch resistant material, but instead may be protected from an etching solution in an alternative fashion. For example, step 752 may be performed on a substrate 700 defining a portion of an article (e.g., deadfront article 400), in which case any portions of the article which are not intended to be etched in step 752 may be protected from the etching solution using suitable materials or apparatuses.
In some embodiments, the etching solution used in step 752 may include hydrofluoric acid, ammonium fluoride, and a water miscible organic solvent. In some embodiments, the etching solution in step 752 may include 1-15 wt % (weight percent) hydrofluoric acid, 1-40 wt % ammonium fluoride, 0-35 wt % water miscible organic solvent, and water. In some embodiments, the etching solution in step 752 may comprise 4-10 wt % hydrofluoric acid, 5-30 wt % ammonium fluoride, 0-25 wt % water miscible organic solvent, and water. In some embodiments, the water miscible organic solvent in the etching solution in step 752 may be an alcohol, ethylene glycol, propylene glycol, glycerol, or combinations thereof. Suitable alcohols include ethanol and iso-propanol.
At step 754, an etch resistive material (e.g., etch resistive ink mask, shown in black in step 754) is applied to first surface 702 of substrate 700. In particular, the etch resistive material is applied to achieve the aforementioned tactile element(s) 712-1, 712-2 that will eventually be complementary to visual element(s) 710-1, 710-2. Again, substantially all of second surface 704 of substrate 700 may be masked or protected from an etching solution in step 754 (shown in black in step 754). Substrate 700 is again exposed (e.g., dipped, sprayed, etc.) to an acid (etching) solution that is designed to polish (reduce the roughness) of the un-masked regions of first surface 702 of substrate 700. In some embodiments, the acid solution may also reduce the thickness of substrate 700 in the un-masked regions via material removal. The resulting matte finish and tactile elements are shown in step 756 in which the etch resistive material has been removed to expose the previously masked portions of first surface 702 (shown in dark gray at step 756). Notably, the previously masked portions of first surface 702 will thus be of a higher surface roughness than the un-masked regions of the first surface 702, which have been polished and somewhat thinned. In an alternative embodiment, all portions of first surface 702 except those corresponding to the position of tactile element(s) 712-1, 712-2 that will eventually be complementary to visual element(s) 710-1, 710-2 may be masked in step 754. In such embodiments, tactile element(s) 712-1, 712-2 may lower surface roughness than un-masked regions around the tactile element(s) 712-1, 712-2.
In some embodiments, the etching solution used in step 756 may include hydrofluoric acid. In some embodiments, the etching solution used in step 756 may include 1-10 wt % hydrofluoric acid. In some embodiments, the etching solution in step 756 may include 5 wt % hydrofluoric acid.
Skilled artisans will appreciate that although use of acids for etching and/or polishing were described above as being suitable for use in applying and/or modifying the surface roughness or haze of the substrate 700, any other suitable method may be used, for example sand blasting, embossing, rolling, mechanical polishing, engraving, and/or vapor deposition (e.g., chemical or physical vapor deposition). Also, skilled artisans will appreciate that although ink printing was described as one manner of forming the etch masks and/or visual elements, any suitable alternative techniques may be employed, for example, printing, screen printing, doctor blading, gravure printing, photolithography, etc.
In an optional step, substrate 700 may also be exposed to a strengthening process, for example a thermal strengthening process or a chemical strengthening process (known in the art as an ion exchange process). In some embodiments, this optional strengthening process may be performed after step 756.
At step 758, the at least one visual element 710-1, 710-2 is disposed on second surface 704 of substrate 700. This involves disposing at least one visual element 710-1, 710-2 in such a way that it may be viewed through first surface 702 of substrate 700. This may involve ink printing, ink spraying, masking technologies, coating techniques, photolithography, etc., to provide one or more visual portions arranged into at least one of, or defining at least one of: (i) one or more areas of color, (ii) one or more lines, (iii) one or more patterns, (iv) one or more designs, (v) one or more images, (vi) one or more graphics, and (vii) one or more combinations thereof. In some embodiments, step 758 may include disposing one or more layers to form a deadfront article. For example, a semi-transparent layer (e.g., semi-transparent layer 460), a contrast layer (e.g., contrast layer 470), a color layer (e.g., color layer 650), and/or an opaque layer (e.g., opaque layer 510) may be disposed over second surface 704 of substrate 700 in step 758.
At step 760, a process for enhancing the visibility of at least one visual element 710-1, 710-2 through first surface 702 of substrate 700 may be carried out. For example, a bright (and preferably neutral) pigment layer, such as white, may be applied over visual element(s) 710-1, 710-2 on second surface 704 by way of printing, coating, spraying, etc. The bright layer is shown in step 760 as white. In some embodiments, desirable enhancement of the visibility of visual element(s) 710-1, 710-2 may be achieved when the “bright” layer is a shiny black and/or metallic coating applied over visual element(s) 710-1, 710-2 on second surface 704.
An alternative process for achieving the application of at least one tactile element 712-1, 712-2 and at least one visual element 710-1, 710-2 on substrate 700 is illustrated in
At step 780, substantially all of second surface 704 of substrate 700 is masked or protected with an etch resistive material (e.g., with an etch resistive ink, as shown in black at step 780). In some embodiments, second surface 704 of substrate 700 may not be directly masked with an etch resistant material, but instead may be protected from an etching solution in alternative fashion. For example, step 780 may be performed on a substrate 700 defining a portion of an article (e.g., deadfront article 400), in which case any portions of the article which are not intended to be etched in step 780 may be protected from the etching solution using suitable materials or apparatuses.
In addition, an etch resistive material (e.g., etch resistive ink mask, as shown in black at step 780) is applied to first surface 702 of substrate 700. In particular, the etch resistive material is applied to first surface 702 to achieve the aforementioned at least one tactile element 712-1, 712-2.
Next, substrate 700 is exposed (e.g., dipped, sprayed, etc.) to an acid solution to generate a low to medium level of surface roughness on the un-masked portions of first surface 702, such as a matte finish surface roughness. Of course, alternative embodiments may employ the acid solution in such a way to produce higher levels of surface roughness. At step 782, the etch resistive material may then be removed to expose one or more areas, lines, patterns, designs, combinations thereof, etc. that are of a relatively smooth finish (shown in white at step 782) on first surface 702 among the other portions that are of a low to medium level of surface roughness (or alternatively even higher levels of roughness, as shown in grey at step 782).
In some embodiments, the etching solution used in step 782 may include hydrofluoric acid, ammonium fluoride, and a water miscible organic solvent. In some embodiments, the etching solution in step 782 may include 1-15 wt % (weight percent) hydrofluoric acid, 1-40 wt % ammonium fluoride, 0-35 wt % water miscible organic solvent, and water. In some embodiments, the etching solution in step 782 may comprise 4-10 wt % hydrofluoric acid, 5-30 wt % ammonium fluoride, 0-25 wt % water miscible organic solvent, and water. In some embodiments, the water miscible organic solvent in the etching solution in step 782 may be an alcohol, ethylene glycol, propylene glycol, glycerol, or combinations thereof. Suitable alcohols include ethanol and iso-propanol.
In some embodiments, the etching solution used in step 782 may include hydrofluoric acid. In some embodiments, the etching solution used in step 782 may include 1-10 wt % hydrofluoric acid. In some embodiments, the etching solution in step 756 may include 5 wt % hydrofluoric acid.
At step 784, at least one visual element 710-1, 710-2 is disposed on second surface 704 of substrate 700 (as shown by non-white surface 704 at step 782). As previously discussed, this involves applying visual element(s) 710-1, 710-2 in such a way that it may be viewed through first surface 702. This may involve ink printing, ink spraying, masking, coating, photolithography, etc., to provide one or more visual portions arranged into at least one of, or defining at least one of: (i) one or more areas of color, (ii) one or more lines, (iii) one or more patterns, (iv) one or more designs, (v) one or more images, (vi) one or more graphics, and (vii) one or more combinations thereof. In some embodiments, step 784 may include disposing one or more layers to form a deadfront article. For example, a semi-transparent layer (e.g., semi-transparent layer 460), a contrast layer (e.g., contrast layer 470), a color layer (e.g., color layer 650), and/or an opaque layer (e.g., opaque layer 510) may be disposed over second surface 704 of substrate 700 in step 784.
At step 786, a process for enhancing the visibility of at least one visual element 710-1, 710-2 through the first surface 702 of substrate 700 may be carried out. For example, a bright (and preferably neutral) pigment layer, such as white, is applied over at least one visual element 710-1, 710-2 on second surface 704 by way of printing, coating, spraying, etc., as shown by white on second surface 704 at step 786. As mentioned above, desirable enhancement of the visibility of at least one visual element 710-1, 710-2 may alternatively be achieved when the “bright” layer is a shiny black and/or metallic coating applied over at least one visual element 710-1, 710-2 on second surface 704.
Skilled artisans will appreciate that although use of acids for etching and/or polishing were described above as being suitable for use in applying and/or modifying the surface roughness or haze of the substrate 700, any other suitable method may be used, for example sand blasting, embossing, rolling, mechanical polishing, engraving, and/or vapor deposition (e.g., chemical or physical vapor deposition). Also, skilled artisans will appreciate that although ink printing was described as one manner of forming the etch masks and/or visual elements, any suitable alternative techniques may be employed, for example, printing, screen printing, doctor blading, gravure printing, photolithography, etc.
The processes described above with reference to
Further, skilled artisans will appreciate that the processes described above with reference to
For example, step 780 may include the aforementioned printing of substantially all of second surface 704 of substrate 700 and the etch resistive material (mask). However, prior to applying the etch resistive material to first surface 702, substrate 700 may be exposed (e.g., dipped, sprayed, etc.) to an acid solution to generate some level of surface roughness on first surface 702, such as a matte finish surface roughness. Thereafter, the etch resistive material (mask) is applied to first surface 702 of substrate 700 (i.e., over the previously formed matte finish) to achieve the aforementioned at least one tactile element 712-1, 712-2.
Next, substrate 700 is again exposed (e.g., dipped, sprayed, etc.) to an acid solution to generate a further level of surface roughness on the un-masked portions of first surface 702, which is rougher than the previously produced matte finish surface roughness. At step 782, the etch resistive material may then be removed from first surface 702 to expose one or more areas, lines, patterns, designs, combinations thereof, etc. that are of the matte finish surface roughness (represented by the lines in white at steps 782, 784 in
Next, the remainder of the process previously discussed in connection with steps 784 and 786 of
Deadfront article 800 includes a substrate 801. Substrate 801 may be the same as or similar to any substrate discussed herein and includes a first surface 802 a second surface 804 opposite first surface 802. A visual element 810 may be disposed on second surface 804 of substrate 801 and/or within substrate 801 such that visual element 810 may be viewed through first surface 802. Visual element 810 may include one or more graphics 820 that may be viewed through first surface 802 when article 800 is backlit (see
As used herein, an “icon” is an area, line, shape, pattern, design, image, symbol, letter, number, logo, or combination thereof that represents one or more functionalities of a device. When actuated by a user (e.g., via touch) an icon will produce a functional result represented by the icon. For example, an on/off icon will power a device on or off. As another example, a “volume” icon will cause a device to produce more or less sound. An icon may also be called a button.
Article 800 also includes at least one tactile element 830 formed on first surface 802 of substrate 801. As discussed herein, tactile element(s) 830 may include one or more surface roughness portions, with at least one of the one or more surface roughness portions positioned on first surface 802 in a complimentary fashion to all or a portion of visual element 810. For example, tactile element(s) 830 may include one or more surface roughness portions, with at least one of the one or more surface roughness portions positioned on first surface 802 in a complimentary fashion to a graphic 820. Tactile element(s) 830 create a haptic feel for a user touching first surface 802 while preserving the appearance of a deadfronted material imagined on first surface 802 (e.g., carbon fiber, stainless steel, wood, etc.) when article 800 is not backlit. In some embodiments, tactile element(s) 830 may be faintly visible on first surface 802.
As used herein, a first object (e.g., tactile element) “formed on” a surface of a second object (e.g., substrate) means that the first object is directly formed on the surface of the second object. A first object formed on a surface of a second object may be formed by depositing material on the surface, removing material from the surface, and/or chemically altering one or more surface properties of the surface. Suitable methods for forming a first object on the surface of a second object include, but are not limited to, etching (e.g., etching with an acid), polishing, sand blasting, engraving, embossing, rolling, and/or vapor deposition (e.g., chemical or physical vapor deposition). Forming a first object on the surface of a second object may change one or more properties of the surface, including, but not limited to, surface geometry, surface roughness, haze, and reflectivity. In some embodiments, tactile element(s) 830 may be etched surface portions formed by, for example, an etching process described in reference to
Deadfront article 800 also includes a deadfront assembly 840 disposed on second surface 804. Deadfront assembly 840 may include any layers descried herein for forming a deadfront article. For example, deadfront assembly 840 may include a semi-transparent layer (e.g., semi-transparent layer 460), a contrast layer (e.g., contrast layer 470), a color layer (e.g., color layer 650), and/or an opaque layer (e.g., opaque layer 510). As an example,
As another example, deadfront assembly 840 may include a high optical density layer (e.g., opaque layer 510) disposed onto at least a portion of a contrast layer (e.g., contrast layer 470) such that the contrast layer is located between the high optical density layer and the semi-transparent layer. In such embodiments, the high optical density layer may at least in part define one or more graphics 820. In some embodiments, deadfront article 800 may include a touch panel (e.g., touch panel 660) located behind visual element 810, the touch panel configured to respond to a touch by a user (e.g., a touch of one or more graphics 820). In such embodiments, the touch panel may be configured to respond to a user's touch of graphic 820, which may be an icon.
In some embodiments, the portion of first surface 802 occupied by tactile element(s) 830 may be relatively rougher (i.e., may have a higher surface roughness) than all or a portion of the remainder of first surface 802. In such embodiments, tactile element(s) 830 may have a Ra surface roughness of greater than about 80 nm.
In some embodiments, the portion of first surface 802 occupied by tactile element(s) 830 may be relatively smoother (i.e., may have a lower surface roughness) than all or a portion of the remainder of first surface 802. In such embodiments, all or a portion of first surface 802 around tactile element(s) 830 may have a Ra surface roughness of greater than about 80 nm.
In some embodiments, deadfront article 800 may be made using a processing including one or more processes described herein in reference to
Aspect (1) of this disclosure pertains to a deadfront article comprising: a substrate comprising: a first surface; and a second surface opposite the first surface; a visual element disposed on the second surface of the substrate and/or within the substrate such that the visual element may be viewed through the first surface, the visual element comprising a graphic that may be viewed through the first surface; at least one tactile element formed on the first surface of the substrate, the at least one tactile element comprising one or more surface roughness portions, wherein at least one of the one or more surface roughness portions is positioned on the first surface of the substrate in a complimentary fashion to the graphic; a semi-transparent layer disposed on at least a first portion of the second surface of the substrate, the semi-transparent layer having a region of a solid color or of a design of two or more colors; and a contrast layer disposed on at least a portion of the region, the contrast layer configured to enhance visibility of the color of the region or to enhance contrast between the colors of the design of the region on the portion of the region on which the contrast layer is disposed.
Aspect (2) of this disclosure pertains to the deadfront article of Aspect (1), wherein the one or more surface roughness portions are defined by one of: (i) an area of relatively higher surface roughness bordered by at least one area of relatively lower surface roughness, and (ii) an area of relatively lower surface roughness bordered by at least one area of relatively higher surface roughness.
Aspect (3) of this disclosure pertains to the deadfront article of Aspect (1) or Aspect (2), wherein the graphic comprises an icon.
Aspect (4) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (3), wherein the one or more surface roughness portions comprises an etched portion of the first surface of the substrate.
Aspect (5) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (4), wherein: a majority of a total surface area of the first surface of the substrate comprises a first surface roughness; and the one or more surface roughness portions of the tactile element cover a minority of the total surface area of the first surface and comprise a second surface roughness, which is different from the first surface roughness.
Aspect (6) of this disclosure pertains to the deadfront article of Aspect (5), wherein the second surface roughness is relatively rougher than the first surface roughness.
Aspect (7) of this disclosure pertains to the deadfront article of Aspect (6), wherein the second surface roughness comprises a Ra surface roughness of greater than about 80 nm.
Aspect (8) of this disclosure pertains to the deadfront article of Aspect (5), wherein the first surface roughness is relatively rougher than the second surface roughness.
Aspect (9) of this disclosure pertains to the deadfront article of Aspect (8), wherein the first surface roughness comprises a Ra surface roughness of greater than about 80 nm.
Aspect (10) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (9), wherein the substrate comprises a material selected from the group consisting of: a glass, a glass ceramic, and a polymer.
Aspect (11) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (10), wherein the substrate comprises strengthened glass.
Aspect (12) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (11), further comprising a high optical density layer disposed onto at least a portion of the contrast layer such that the contrast layer is located between the high optical density layer and the semi-transparent layer.
Aspect (13) of this disclosure pertains to the deadfront article of Aspect (11), wherein the high optical density layer at least in part defines the graphic.
Aspect (14) of this disclosure pertains to the deadfront article of Aspect (13), further comprising a color layer disposed in regions of the visual element such that, in at least a portion of the visual element defined by the high optical density layer, the contrast layer is located between the semi-transparent layer and the color layer.
Aspect (15) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (14), wherein the region of the semi-transparent layer has a design of two or more colors, the design comprising at least one of a leather grain pattern, a wood grain pattern, a fabric pattern, a brushed metal finish pattern, and a logo.
Aspect (16) of this disclosure pertains to the deadfront article of any one of Aspects (1) through (15), further comprising a touch panel located behind the visual element, the touch panel configured to respond to a touch by a user.
Aspect (17) pertains to an automobile interior comprising: a deadfront article comprising: a substrate comprising: a first surface; and a second surface opposite the first surface; a visual element disposed on the second surface of the substrate and/or within the substrate such that the visual element may be viewed through the first surface, the visual element comprising a graphic that may be viewed through the first surface; at least one tactile element formed on the first surface of the substrate, the at least one tactile element comprising one or more surface roughness portions, wherein at least one of the one or more surface roughness portions is positioned on the first surface of the substrate in a complimentary fashion to the graphic; a semi-transparent layer disposed on a second surface of the substrate layer; a contrast layer disposed on at least a portion of the semi-transparent layer; and a high optical density layer disposed on at least a portion of the contrast layer, the high optical density layer at least in part defining the graphic; and a touch panel located behind the visual element, the touch panel configured to respond to a touch by a user.
Aspect (18) pertains to the automobile interior of Aspect (17), wherein the graphic is an icon and wherein the touch panel is configured to respond to a user's touch of the icon.
Aspect (19) pertains to the automobile interior of Aspect (17) or Aspect (18), wherein the semi-transparent layer has a region of a solid color or of a design of two or more colors, the design comprising at least one of a leather grain pattern, a wood grain pattern, a fabric pattern, a brushed metal finish pattern, and a logo.
Aspect (20) pertains to the automobile interior of any one of Aspects (17) through (19), wherein the high optical density layer disposed onto at least a portion of the contrast layer such that the contrast layer is located between the high optical density layer and the semi-transparent layer.
Aspect (21) pertains to the automobile interior of Aspect (20), further comprising a color layer disposed in regions of the visual element such that, in at least a portion of the visual element defined by the high optical density layer, the contrast layer is located between the semi-transparent layer and the color layer.
Aspect (22) pertains to a method of forming a tactile element on a deadfront article, the method comprising: forming at least one tactile element on a first surface of a substrate in a complimentary fashion to a graphic defined by a visual element disposed on a second surface of the substrate opposite the first surface and/or within the substrate such that the graphic may be viewed through the first surface, wherein the at least one tactile element is formed by a process comprising at least one of etching, sandblasting, polishing, and engraving.
Aspect (23) pertains to the method of forming a tactile element on a deadfront article of Aspect (22), wherein the at least one tactile element is formed by an etching process.
Aspect (24) pertains to the method of forming a tactile element on a deadfront article of Aspect (23), wherein the etching process comprises: etching the first surface with a first etching solution; disposing a mask over the first surface after etching the first surface with the first etching solution, the mask comprising a shape corresponding to the shape of the graphic; and etching an unmasked region of the first surface with a second etching solution.
Aspect (25) pertains to the method of forming a tactile element on a deadfront article of Aspect (24), wherein the first etching solution comprises hydrofluoric acid, ammonium fluoride, and a water miscible organic solvent, and wherein the second etching solution comprises hydrofluoric acid.
Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein, the article “a” is intended to include one or more than one component or element, and is not intended to be construed as meaning only one.
It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since modifications, combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.
The term “or,” as used herein, is inclusive; more specifically, the phrase “A or B” means “A, B, or both A and B.” Exclusive “or” is designated herein by terms such as “either A or B” and “one of A or B,” for example.
The indefinite articles “a” and “an” to describe an element or component means that one or at least one of these elements or components is present. Although these articles are conventionally employed to signify that the modified noun is a singular noun, as used herein the articles “a” and “an” also include the plural, unless otherwise stated in specific instances. Similarly, the definite article “the,” as used herein, also signifies that the modified noun may be singular or plural, again unless otherwise stated in specific instances.
As used in the claims, “comprising” is an open-ended transitional phrase. A list of elements following the transitional phrase “comprising” is a non-exclusive list, such that elements in addition to those specifically recited in the list may also be present. As used in the claims, “consisting essentially of” or “composed essentially of” limits the composition of a material to the specified materials and those that do not materially affect the basic and novel characteristic(s) of the material. As used in the claims, “consisting of” or “composed entirely of” limits the composition of a material to the specified materials and excludes any material not specified.
The term “wherein” is used as an open-ended transitional phrase, to introduce a recitation of a series of characteristics of the structure.
Where a range of numerical values is recited herein, comprising upper and lower values, unless otherwise stated in specific circumstances, the range is intended to include the endpoints thereof, and all integers and fractions within the range. It is not intended that the scope of the claims be limited to the specific values recited when defining a range. Further, when an amount, concentration, or other value or parameter is given as a range, one or more preferred ranges or a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether such pairs are separately disclosed. Finally, when the term “about” is used in describing a value or an end-point of a range, the disclosure should be understood to include the specific value or end-point referred to. Whether or not a numerical value or end-point of a range recites “about,” the numerical value or end-point of a range is intended to include two embodiments: one modified by “about,” and one not modified by “about.”
As used herein, the term “about” means that amounts, sizes, ranges, formulations, parameters, and other quantities and characteristics are not and need not be exact, but may be approximate and/or larger or smaller, as desired, reflecting tolerances, conversion factors, rounding off, measurement error and the like, and other factors known to those of skill in the art.
The terms “substantial,” “substantially,” and variations thereof as used herein are intended to note that a described feature is equal or approximately equal to a value or description. For example, a “substantially planar” surface is intended to denote a surface that is planar or approximately planar. Moreover, “substantially” is intended to denote that two values are equal or approximately equal. In some embodiments, “substantially” may denote values within about 10% of each other, such as within about 5% of each other, or within about 2% of each other.
The present embodiment(s) have been described above with the aid of functional building blocks illustrating the implementation of specified functions and relationships thereof. The boundaries of these functional building blocks have been arbitrarily defined herein for the convenience of the description. Alternate boundaries can be defined so long as the specified functions and relationships thereof are appropriately performed.
It is to be understood that the phraseology or terminology used herein is for the purpose of description and not of limitation. The breadth and scope of the present disclosure should not be limited by any of the above-described exemplary embodiments, but should be defined in accordance with the following claims and their equivalents.
This application is a continuation of U.S. patent application Ser. No. 17/897,900 filed on Aug. 29, 2022, which is a continuation of U.S. patent application Ser. No. 16/646,732 filed on Mar. 12, 2020, now patent Ser. No. 11/459,268, granted Oct. 4, 2022, which is a national stage application under 35 U.S.C. § 371 of International Patent Application Serial No. PCT/US2018/050772 filed on Sep. 12, 2018, which claims the benefit of priority under 35 U.S.C. § 119 of U.S. Provisional Application Ser. No. 62/729,695 filed on Sep. 11, 2018, U.S. Provisional Application Ser. No. 62/679,278 filed on Jun. 1, 2018 and U.S. Provisional Application Ser. No. 62/557,502 filed on Sep. 12, 2017, the contents of each is relied upon and incorporated herein by reference in their entirety.
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