The present disclosure generally relates to techniques and assemblies for joining components.
Casting may be used to form metal or alloy components. However, casting relatively large articles or articles having a relatively complex geometry in a single operation may be difficult, or result in deviation of a cast article from specifications or tolerance. When forming articles from superalloys including a single crystal, casting may be difficult, leading to relatively high rejection rates due to defects in the cast article. For example, nozzle guide vanes for gas turbine engines may be cast as a single crystal, and this may restrict design complexity of the nozzle guide vanes. Instead of casting or otherwise forming large or complex articles as a single piece or component, such articles may be cast or otherwise fabricated in the form of separate components, which may be joined to form an assembly.
The disclosure describes example assemblies and techniques for joining components, for example, metal or alloy components or ceramic-based components.
In some examples, the disclosure describes an example technique including positioning a first component and a second component adjacent to each other to define a joint region between adjacent portions of the first component and the second component. The joint region defines a joint surface. The example technique further includes positioning a braze in the joint region. An adhesion resistant material present between the braze material and the joint surface. The adhesion resistant material is configured to resist adherence of the braze material to the joint surface. The example technique further includes heating the braze material to a processing temperature to form an at least softened material in the joint region. The example technique further includes cooling the at least softened material to form a mechanical interlock including the braze material in the joint region joining the first and second components. The braze material does not metallurgically bond to the joint surface.
In some examples, the disclosure describes an example assembly including a first component and a second component. The first component and second component are positioned adjacent to each other to define a joint region between adjacent portions of the first component and the second component. The joint region defines a joint surface. The example assembly includes a mechanical interlock including braze material disposed in the joint region. The assembly also include an adhesion resistant material between the braze material and the joint surface. The adhesion resistant material is configured to resist adherence of the braze material to the joint surface. The braze material is configured to form an at least softened material in the joint region in response to heating the braze material to a processing temperature. The at least softened material is configured to form the mechanical interlock in the joint region mechanically joining the first and second components in response to cooling. The braze material is not metallurgically bonded to the first component or the second component.
The details of one or more examples are set forth in the accompanying drawings and the description below. Other features, objects, and advantages will be apparent from the description and drawings, and from the claims.
The disclosure describes assemblies, systems, articles, and techniques for joining a first component and a second component using a braze material that does not metallurgically bond the first component to the second component. The first component and the second component define a joint region defining a joint surface. An adhesion resistant material is present between the joint surface and the braze material and is configured to resist adherence of the braze material to the joint surface. At least one of the first or the second component may include a metal, an alloy, or a ceramic-based structure, for example, a ceramic matrix composite.
In some example techniques, the braze material is heated to a processing temperature to form an at least softened material, which may flow, occupy, or otherwise at least partially conform to the joint region (e.g., may conform to or nearly conform to at least a portion of the joint region). The at least softened material may cool to form a mechanical interlock in the joint region, restraining the first component relative to the second component. In some examples, the mechanical interlock may at least partially surround one or both of the first component or the second component. The mechanical may mechanically secure the first component relative to the second component. The first or second components may include components or a gas turbine engine, for example, a high-pressure nozzle guide vane and shroud. In some example, the components may include any components benefitting from a close fitting (relatively low leakage) structural connection in high-temperature operating conditions.
While techniques such as bi-casting may be used to produce an integrally formed metallic joint or “clip” to structurally connect components, bi-casting may require a casting foundry, including, for example, separate furnace preheat and furnace (liquid metal) pouring operations with elaborate tooling (while needing close monitoring and control in various stages of the process). In order to integrally form a bi-cast joint or clip, a metal or alloy may need to be fully molten or liquid and superheated to a temperature well above the melting point of components being joined. Moreover, any significant leakage of molten metal or alloy during the bi-casting process may affect the integrity of components being joined or of surrounding furnace tooling, which may be costly and difficult to replace.
In contrast, example techniques and assemblies according to the disclosure may be deployed using treatment temperatures and durations that may substantially maintain the integrity of the components being joined and tooling or support components used for joining the components. Some example techniques and assemblies according to the disclosure may result in a relatively low leakage structural connection between components operating in high temperature environments. In some examples, a plurality of pairs of components may be joined at the same time using a batch process, in contrast with a bi-casting process in which a single pair of first and second components and is processed at a time and processing multiple pairs of components requires multiple processings. In some examples, the braze material may include wide gap braze alloy, a pre-sintered preform (PSP) or another composition having predetermined ratios of braze alloy to superalloy powder as described elsewhere in the disclosure.
Because the braze materials described herein may possess mechanical and chemical properties (e.g., mechanical strength and high temperature oxidation resistance) that make the material suitable for use in high temperature oxidative environments, the braze materials may facilitate manufacture of articles for high temperature mechanical systems in multiple components, which are then joined using the braze materials. This may reduce cost of manufacture due to lower defect levels in the components, facilitate more complex geometry, or the like. In some examples, the braze materials including a PSP also may provide advantages compared to powder braze materials. For example, the PSP materials may result in reduced porosity in joints compared to joints formed using a braze powder, which may improve mechanical properties of the braze joint. Further, the PSP materials may be easier to position in the joint region and result in a more uniform joint.
The adhesion-resistant material is selected to resist the formation of a metallurgical bond between the mechanical interlock formed by the braze material and the joint surfaces. For example, the adhesion resistant material may include a coating that may act as a leave-in-place “stop-off”, substantially preventing the formation of a metallurgical bond, while avoiding or substantially preventing introducing a gap (as contrasted with a stop-off removed after application). As another example, the adhesion resistant material may include a superalloy foil or a superalloy powder present between the braze material and the joint surfaces. The superalloy foil or superalloy powder may be selected to have a melting point above the processing temperature to which the braze material is heated, such that the superalloy foil or superalloy powder does not melt during processing of the braze material to form the mechanical interlock. Avoiding the formation of a metallurgical bond may help maintain the integrity of the mechanical interlock and the joint region, for example, in response to mechanical and thermal stresses applied to the components and the mechanical interlock, by allowing constrained relaxation of the components and the mechanical interlock.
Additionally, in some examples, the superalloy foil or superalloy powder may have relatively lower levels of melting point depressants, such as boron or silicon, than the braze material. The superalloy foil or superalloy powder thus may act as a melting point depressant sink into which the melting point depressants may diffuse from the braze material during the processing of the braze material. This may result in the melting point of the braze material being raised to provide improve high temperature capabilities to the resulting joint.
Each of components 12a and 12b may include a metal or alloy, or a ceramic. In some examples, components 12a and 12b include substantially the same (e.g., the same or nearly the same) metal or alloy. In other examples, components 12a and 12b include different metals or alloys. In some examples, one or both of components 12a and 12b may include a Ni-, Co-, or Fe-based superalloy, or the like. The superalloy may include other additive elements to alter its mechanical and chemical properties, such as toughness, hardness, temperature stability, corrosion resistance, oxidation resistance, and the like. Any useful superalloy may be utilized in first or second components 12a or 12b, including, for example, Ni-based alloys available from Martin-Marietta Corp., Bethesda, MD, under the trade designation MAR-M246, MAR-M247; Ni-based alloys available from Cannon-Muskegon Corp., Muskegon, MI, under the trade designations CMSX-3, CMSX-4, CMSX-10, and CM-186; Co-based alloys available from Martin-Marietta Corp., Bethesda, MD, under the trade designation MAR-M509; and the like. The compositions of CMSX-3 and CMSX-4 are shown below in Table 1.
One or both of components 12a and 12b may be made using at least one of casting, forging, powder metallurgy, molding, or additive manufacturing. In some examples, components 12a and 12b are made using the same process, while in other examples, components 12a and 12b are made using different processes.
In some examples, one or both of components 12a or 12b may include a ceramic or ceramic-matrix composite (CMC). The ceramic or CMC may include any useful ceramic material, including, for example, silicon carbide, silicon nitride, alumina, silica, and the like. The CMC may further include any desired filler material, and the filler material may include a continuous reinforcement or a discontinuous reinforcement. For example, the filler material may include discontinuous whiskers, platelets, or particulates. As another example, the filler material may include a continuous monofilament or multifilament weave. In some examples, the CMC may include a SiC/SiC CMC, or an oxide/oxide CMC. For example, an SiC/SiC or oxide/oxide CMC component may be joined to a metal or alloy component or another SiC/SiC or oxide/oxide CMC component.
Although
First component 12a defines at least one joining region 16a defining a joint surface 18a. Similarly, second component 12b defines at least one joining region 16b defining a joint surface 18b. In some examples, first and second joint surfaces 18a and 18b (also referred to as “joint surfaces 18a and 18b”) may define complementary shapes.
Components 12a and 12b are positionable such that joining regions 16a and 16b are adjacent to each other and define a joint region (not shown in
In some examples, although not shown in
In some examples, braze material 14 may include a Ni-based or Co-based wide gap braze alloy. Braze material 14 may include greater amounts of alloying elements that some other braze materials used in braze foils, which may contribute to improved mechanical properties, chemical properties, or both compared to some other braze materials used in braze foils. For example, braze material 14 may possess sufficient mechanical strength and high temperature oxidation resistance to be used in a nozzle guide vane in a gas turbine engine.
In some examples, braze material 14 may include both a braze alloy powder (a low-melt powder composition) and a superalloy powder (a high-melt powder composition). The low-melt alloy powder composition is an alloy, or a mixture of alloys, that substantially melts below a braze or joining temperature (hence the name “low-melt” or “braze powder”). In contrast, the high-melt alloy powder composition is an alloy, or a mixture of alloys, that remains substantially unmelted at the braze temperature, because the composition has a melting temperature above the braze temperature (hence the name “high-melt” or “superalloy powder”). In some implementations, the braze alloy powder and the superalloy powder may have specific powder mesh sizes, and may be produced by induction melting the braze alloy or the superalloy powder, respectively, in vacuum or an argon atmosphere, followed by argon gas atomization. Each individual powder component used in braze material 14 may be analyzed to confirm the particle size and chemical compositions.
In some examples, the low-melt powder composition includes an alloy or a mixture of alloys that melt at a temperature below about 1260° C. (about 2300° F.). The high-melt alloy powder composition may include a single high-melt alloy or a mixture of alloys that melts at a temperature of greater than about 1315° C. (about 2400° F.).
In some examples, the low-melt powder composition may include one or more alloy powders and includes between about 50 wt. % and about 70 wt. % Ni, between about 8 wt. % and about 20 wt. % Cr, between about 8 wt. % and about 15 wt. % Ta, between about 4 wt. % and about 10 wt. % Co, between about 2 wt. % and about 7 wt. % Al, up to about 2.25 wt. % B, and up to about 2.25 wt. % Si, and has a compositional melting range of between about 1093° C. (about 2000° F.) and about 1204° C. (about 2200° F.). In some examples, the low-melt powder composition also includes up to about 1 wt. % each of at least one of Ti, W, Mo, Re, Nb, Hf, Pd, Pt, Jr, Ru, C, Si, P, Fe, Ce, La, Y, or Zr. In some examples the low-melt alloy powder comprises a mixture of two or more low-melt alloys. For example, a low-melt alloy powder may include (a) about 35% of a first low-melt powder including about 74 wt. % Ni, about 6 wt. % Cr, about 6 wt. % Al, about 12 wt. % Co, and about 2 wt. % B, with a liquidus temperature of about 1121° C. (about 2050° F.); (b) about 45% of a second low-melt powder including about 42 wt. % Ni, about 31 wt. % Cr, about 26 wt. % Ta, and about 1 wt. % B, with a liquidus temperature of about 1232° C. (about 2250° F.); and (c) about 20 wt. % of a third low-melt powder including about 64 wt. % Ni, about 6 wt. % Al, about 8 wt. % Co, about 4 wt. % W, about 4 wt. % Ta, about 3 wt. % Si, about 1 wt. % Re, about 1 wt. % Nb, and about 1 wt. % B, with a liquidus temperature of about 1093° C. (about 2000° F.).
In some examples, the high-melt powder composition may include an alloy or mixture of alloys with a chemistry that is the similar to or substantially the same (e.g., the same or nearly the same) as the alloy in first component 12, second component 14, or both. For example, in some implementations, to join a first component 12 and a second component 14 that include Ni-based superalloy components such as those made of MAR-M246 or 247, or CMSX-3 or -4, the high-melt powder composition may include between about 50 wt. % and about 70 wt. % Ni, between about 2 wt. % and about 10 wt. % Cr, between about 2 wt. % and about 10 wt. % Ta, between about 5 wt. % and about 15 wt. % Co, between about 2 wt. % and about 10 wt. % Al, between about 2 wt. % and about 10 wt. % W, between about 2 wt. % and about 4 wt. % Re, up to about 3 wt. % Mo, and up to about 3 wt. % Hf. In some examples, the high-melt powder composition also may include up to about 1 wt. % each of at least one of Ti, Nb, C, B, Si, or Zr. In some examples, the high-melt powder composition includes between about 55 wt. % and about 60 wt. % Ni, about 7 wt. % Cr, about 6 wt. % Ta, about 12 wt. % Co, about 6 wt. % Al, about 3 wt. % Re, about 1.5 wt. % Hf, and about 5 wt. % W.
The low-melt powder composition and the high-melt powder composition may be combined in any selected ratio. In some examples, braze material 14 may include a powder mixture consisting of between about 20 wt. % and about 80 wt. % low-melt powder composition and a balance high-melt powder composition (a ratio of between about 1:4 and about 4:1 low-melt:high-melt powder). In some cases, braze alloy powder may be a mixture of more than one braze alloys which are all powder. In some examples, the ratio may be between about 1:3 and about 3:1 low-melt:high-melt powder, such as a ratio between about 1:2 and about 2:1 low-melt:high-melt powder, or a ratio between about 1:1 and about 1:1.5 low-melt:high-melt powder. For example, braze material 14 may include between about 40 wt. % and about 50 wt. % low-melt alloy powder and between about 50 wt. % and about 60 wt. % high-melt powder, such as about 45 wt. % low-melt alloy powder and about 55 wt. % high-melt powder.
Hence, in some examples, braze material 14 may include between about 50 wt. % and about 90 wt. % Ni, up to about 15 wt. % Cr, up to about 10 wt. % Ta, up to about 10 wt. % Co, up to about 7 wt. % Al, up to about 4 wt. % W, up to about 2 wt. % Re, up to about 1 wt. % Mo, up to about 1 wt. % Hf, and, optionally, up to about 0.5 wt. % Nb, up to about 3 wt. % Si, and up to about 3 wt. % B. In some examples, braze material 14 may include between about 50 wt. % and about 70 wt. % Ni, between about 10 wt. % and about 15 wt. % Cr, between about 8 wt. % and about 10 wt. % Ta, between about 8 wt. % and about 10 wt. % Co, between about 4 wt. % and about 7 wt. % Al, between about 2 wt. % and about 4 wt. % W, between about 1 wt. % and about 2 wt. % Re, about 1 wt. % Mo, about 1 wt. % Hf, and, optionally, up to about 1% each at least one of Ti, Nb, Pd, Pt, Jr, Ru, C, B, Si, P, Mn, Fe, Ce, La, Y, or Zr. In some examples, braze material 14 may include between about 50 wt. % and about 70 wt. % Ni, between about 10 wt. % and about 15 wt. % Cr, between about 8 wt. % and about 10 wt. % Ta, between about 8 wt. % and about 10 wt. % Co, between about 4 wt. % and about 7 wt. % Al, between about 2 wt. % and about 4 wt. % W, between about 1 wt. % and about 2 wt. % Re, between about 0.5 wt. % and about 1 wt. % Mo, between about 0.5 wt. % and about 1 wt. % Hf, between about 0.1 wt. % and about 0.5 wt. % Nb, between about 0.05 wt. % and about 3 wt. % Si, and between about 0.5 wt. % and about 2 wt. % B. In some examples, braze material 14 may include about 58 wt. % Ni, about 11 wt. % Cr, about 9 wt. % Ta, about 9 wt. % Co, about 5 wt. % Al, about 3 wt. % W, about 1 wt. % Mo, about 1 wt. % Re, and about 1 wt. % Hf; or may include between about 10.2 wt. % and about 11.3 wt. % Cr, between about 4.8 wt. % and about 5.1 wt. % Al, between about 9.1 wt. % and about 9.8 wt. % Co, between about 2.8 wt. % and about 3.3 wt. % W, between about 0.7 wt. % and about 0.9 wt. % Mo, between about 8.2 wt. % and about 8.8 wt. % Ta, between about 0.6 wt. % and about 0.8 wt. % B, about 0.3 wt. % Si, between about 1.5 wt. % and about 1.8 wt. % Re, between about 0.8 wt. % and about 0.9 wt. % Hf, between about 0.1 wt. % and about 0.2 wt. % Nb, and a balance Ni.
In selecting the proportions of components used in braze material 14, higher weight percentages of high-melt powder may provide better mechanical properties in view of their reduced levels of melting point depressants such as boron, silicon, or both. Conversely, higher percentages of low-melt powders that include higher levels of melting point depressants such as boron, silicon, or both may provide improved braze flow. A proper balance between mechanical properties and braze flow should be selected, for example, to promote flow of the braze material to ultimately at least partially conform to joint region 15, while yet retaining sufficient strength or rigidity to mechanically secure components 12a and 12b relative to each other.
In some examples, the sintered powder may then be cut or machined into a predetermined shape. For example, the predetermined shape may correspond to a shape of joint region 15. As described above, joint region 15 may include a relatively simple geometry as shown in
For example, furnace 22 may be used to heat braze material 14 to a predetermined processing temperature to form an at least softened material (for example, a material that is relatively softer than braze material 14, or a partially, substantially, or completely melted material, or a flowable material). Furnace 22 may include a combustion, infrared, electric, induction, or any suitable source of thermal energy. In some examples, furnace 22 may include a furnace, for example, a vacuum furnace. While furnace 22 may be used to heat braze material 14, in some examples, furnace 22 may not be used, and instead, a different source of thermal energy may be used to heat braze material 14, for example, an external heat source. The at least softened material may flow, migrate, or otherwise at least partially occupy joint region 15, and on cooling, form a mechanical interlock in joint region 15.
While adhesion resistant coating 19 resists adherence or metallurgical bonding of the mechanical interlock formed from brazing material 14 to surfaces of joint region 15, the mechanical interlock still secures first component 12a to second component 12b or restrains first component 12a relative to second component 12b. For example, the shape and geometry of the mechanical interlock (for example, substantially conforming to joint region 15) may mechanically lock or secure a portion of first component 12a relative to a respective portion of second component 12b. In some examples, the mechanical interlock at least partially surrounds at least one of first component 12a or second component 12b. For example, the mechanical interlock may surround a perimeter subtending an angle greater than 180°, or greater than 210°, or greater than 240°, or greater than 270°, or greater than 300°, or substantially 360° (for example, within 1°, 5°, or 10° of 360°) about a central axis defined respectively by first component 12a or second component 12b. In some examples, the mechanical interlock may form a ring, or a sleeve, surrounding one or both of components 12a or 12b. In some examples, the mechanical interlock may be exterior to an exterior surface defined by one of components 12a or 12b, and interior to an interior surface defined by the other of components 12a or 12b. For example, in the examples shown in
The mechanical interlock ultimately formed from braze material 14 may possess sufficient mechanical strength and high temperature oxidation resistance to be utilized in a high temperature mechanical system, such as a nozzle guide vane in a gas turbine engine. Further, by utilizing a PSP in some examples, the joint may include reduced porosity compared to a joint formed using a braze powder, and positioning of a PSP may be easier and more precise than with a braze powder. In this way, a PSP may facilitate the formation of an article from multiple, smaller components, easing or reducing the cost of forming the article.
Thus, braze material 14 can be formed into structures or otherwise introduced into joint region 15, while having the ability to change shape or “morph” during a high temperature furnace operation from a pliable or ductile green state (or even a semi-rigid state when pre-sintered) into a state that further softens and has the ability to substantially conform to the shape of joint region 15 or a cavity or channel in which braze material 14 is placed. Such deforming of braze material 14 may be accomplished at a temperature well below the melting point of components 12a or 12b, for example, without braze material 14 itself melting into a full liquid state (in contrast with bi-casting, which may require a liquid molten state). However, in other examples, while braze material 14 may be molten or heated to a liquid state, components 12a or 12b themselves may be maintained in a solid state, retaining the integrity of components 12a and 12b. In some examples, as described elsewhere in the disclosure, braze material 14 may be formed into multiple sections placed adjacent to each other in joint region 15. In such a configuration, the multiple sections will securely bond and fuse to each other during a high temperature furnace operation.
In some examples, the melting characteristics of braze material 14 may change in response to high temperature exposure. For example, braze material 14 may include a relatively small percentage of a low melting component, for example, brazing powder, and a relatively higher percentage of a high melting component, for example, superalloy. The low melting component may include an alloy additive that depresses the melting point of the low melting component, causing the low melting component to liquefy at this lower temperature, causing braze material 14 to soften and slip (and unite if more than one strip is used) during the furnace operation. However, the alloy addition that depresses the melting point of the low melting component may diffuse during the furnace operation (or during a post-furnace diffusion heat treatment) into the larger volume of high melting component, for example, superalloy. Such diffusion may raise the re-melt temperature of the mechanical interlock ultimately formed from braze material 14, such that the mechanical interlock (morphed and fused) material formed from braze material 14 transforms into a rigid metallic structure, (for example a “ring”) after the furnace operation and when in subsequent use at high temperature operating conditions.
Thus, after the completion of the thermal cycle (and after an optional diffusion heat treat cycle) braze material 14 may transform into an integrally shaped and consolidated mechanical interlock (in some examples, a “ring”) trapped in cavities or channels bridging between components 12a and 12b. The mechanical interlock formed from braze material 14 may thus function as a high strength, high temperature capable (closely conforming) structural member with material properties similar to a high temperature superalloy, for example, superalloy constituent(s) used in the formulation of braze material 14.
In some examples, the example technique of
Although not shown in
The technique of
In some examples, the example technique of
The technique of
In some examples, the positioning of components 12a and 12a (32) occurs prior to the disposing braze material 14 in joint region 15 (36). In some such examples, braze material 14 may be introduced into joint region 15 through or via an opening defined by joint region 15, for example, opening 11 shown in
The technique of
Regardless of the heat treatment used for melting or softening at least a portion of braze material 14 (38), braze material 14 may be allowed to cool to ambient temperature to form a solid (for example, the mechanical interlock) and join components 12a and 12b (39). The cooling of braze material 14 (39) may include one or both of active cooling, where forced convection, or conduction by contact with a relatively cooler medium may be used to ultimately draw away heat from braze material 14 or passive cooling, where braze material 14 may be allowed to cool by releasing heat to the ambient environment and components 12a and 12b. In examples in which assembly 10 is heated in furnace 22, assembly 10 may be removed from furnace 22 before cooling braze material 14 (39).
Thus, the example technique of
For example,
In the example illustrated in
As shown in
Such a relatively wider opening may provide a “trench” to expose partial access to joint region 57 for installing braze material in joint region 55 surrounding component 52b. Braze material may be introduced through opening 57 into joint region 55 in one or more forms or states, as described with reference to
Thus, a mechanical interlock formed from braze material may be used to mechanically join components having relatively complex geometries and defining relatively complex joint regions without forming metallurgical bonds with the components.
In some examples, instead of or in addition to using an adhesion resistant coating to prevent metallurgical bonding between a braze material and adjacent components, a superalloy foil or powder may be used as an adhesion resistant material. The superalloy foil or powder may be positioned between the braze material and surfaces of the components to be mechanically joined. The superalloy foil or powder may be selected to have a melting temperature higher than the processing temperature to which the braze material is heated, such that the superalloy foil or powder does not melt during the formation of the mechanical interlock from the braze material. As such, the superalloy foil or powder forms a physical barrier between the braze material and the components to prevent a metallurgical bond from forming between the braze material and the components.
Assembly 90 of
Unlike assembly 10 of
In some examples, as shown in
Superalloy foil or braze 21 can be positioned between braze material 14 and joint surfaces 18a and 18b at any one or more of multiple times throughout the joining process of components 12a and 12b. Superalloy foil or braze 21 can be applied, for example, before coating joint surfaces 18a and 18b with an adhesion resistant coating (30), after coating joint surfaces 18a and 18b with an adhesion resistant coating (30), before positioning first and second components 12a and 12b adjacent to each other (32), after positioning first and second components 12a and 12b adjacent to each other (32), before positioning braze material 14 in the joint region (36), or after before positioning braze material 14 in the joint region (36) in the technique of
In some examples, superalloy foil or powder 21 includes a lower concentration of melting point depressants, such as silicon or boron, than braze material 14. As such, during heating of braze material 14 to form the mechanical interlock, at least some of the melting point depressants, such as silicon or boron, may diffuse into the superalloy foil or powder 21, reducing the concentration of these species in braze material 14. This may raise a melting temperature of braze material 14, improving mechanical properties of the mechanical interlock.
In some examples, an assembly may include a melting point depressant sink in addition to, or instead of, superalloy foil or powder 21.
Unlike assembly 10, assembly 100 includes a wire 17 embedded in braze material 14. Wire 17 may include any suitable superalloy, such as a Ni- or Co-based superalloy. For example, wire 17 may include Ni-based alloys available from Martin-Marietta Corp., Bethesda, MD, under the trade designation MAR-M246, MAR-M247; Ni-based alloys available from Cannon-Muskegon Corp., Muskegon, MI, under the trade designations CMSX-3, CMSX-4, CMSX-10, and CM-186; Co-based alloys available from Martin-Marietta Corp., Bethesda, MD, under the trade designation MAR-M509; or the like. The superalloy of wire 17 may be selected to have a melting temperature that is greater than the processing temperature to which braze material 14 is heated when forming the mechanical interlock.
Wire 17, as shown in
Wire 17 may include a lower concentration of melting point depressants, such as silicon or boron, than braze material 14. As such, during heating of braze material 14 to form the mechanical interlock, at least some of the melting point depressants, such as silicon or boron, may diffuse into the wire 17, reducing the concentration of these species in braze material 14. This may raise a re-melting temperature of braze material 14, improving mechanical properties of the mechanical interlock ultimately formed from braze material 14.
Various examples have been described. These and other examples are within the scope of the following claims.
This application is a continuation of U.S. patent application Ser. No. 16/294,415 filed on Mar. 6, 2019, which claims the benefit of U.S. Provisional Patent Application No. 62/640,349, filed Mar. 8, 2018, the entire contents of which are incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
3024109 | Hoppin, III et al. | Mar 1962 | A |
3517428 | Gadd | Jun 1970 | A |
3706203 | Goldberg et al. | Dec 1972 | A |
3806276 | Aspinwall | Apr 1974 | A |
3906617 | Behringer et al. | Sep 1975 | A |
4695247 | Enzaki et al. | Sep 1987 | A |
4980241 | Hoffmueller | Dec 1990 | A |
5100050 | Krueger et al. | Mar 1992 | A |
5332360 | Correia et al. | Jul 1994 | A |
5640767 | Jackson et al. | Jun 1997 | A |
5797725 | Rhodes | Aug 1998 | A |
5976337 | Korinko et al. | Nov 1999 | A |
6003754 | Rhodes | Dec 1999 | A |
6172327 | Aleshin et al. | Jan 2001 | B1 |
6199746 | Dupree et al. | Mar 2001 | B1 |
6213714 | Rhodes | Apr 2001 | B1 |
6214248 | Browning et al. | Apr 2001 | B1 |
6575702 | Jackson et al. | Jun 2003 | B2 |
6602053 | Subramanian et al. | Aug 2003 | B2 |
6837417 | Srinivasan | Jan 2005 | B2 |
7051435 | Subramanian et al. | May 2006 | B1 |
7080971 | Wilson et al. | Jul 2006 | B2 |
7146725 | Kottilingam et al. | Dec 2006 | B2 |
7484928 | Arness et al. | Feb 2009 | B2 |
7731809 | Hu | Jun 2010 | B2 |
7761989 | Lutz et al. | Jul 2010 | B2 |
7810237 | Lange et al. | Oct 2010 | B2 |
7966707 | Szela et al. | Jun 2011 | B2 |
8052391 | Brown | Nov 2011 | B1 |
8070450 | Ryznic et al. | Dec 2011 | B1 |
8087565 | Kottilingam et al. | Jan 2012 | B2 |
8247733 | Zhu | Aug 2012 | B2 |
8356409 | Perret | Jan 2013 | B2 |
8528208 | Rebak et al. | Sep 2013 | B2 |
8539659 | Szela et al. | Sep 2013 | B2 |
8555500 | Vossberg et al. | Oct 2013 | B2 |
8739404 | Bunker et al. | Jun 2014 | B2 |
8800298 | Ladd et al. | Aug 2014 | B2 |
8875392 | Richter | Nov 2014 | B2 |
9003657 | Bunker et al. | Apr 2015 | B2 |
9085980 | Mittendorf et al. | Jul 2015 | B2 |
9174312 | Baughman et al. | Nov 2015 | B2 |
9228958 | Shirkhodaie et al. | Jan 2016 | B2 |
9254537 | Li et al. | Feb 2016 | B2 |
9476306 | Bunker | Oct 2016 | B2 |
9751147 | Rhodes et al. | Sep 2017 | B2 |
9810069 | Dubs et al. | Nov 2017 | B2 |
9863249 | Shinn et al. | Jan 2018 | B2 |
10450871 | Henderkott et al. | Oct 2019 | B2 |
10689984 | Varney | Jun 2020 | B2 |
10766105 | Henderkott et al. | Sep 2020 | B2 |
11338396 | Bulgrin et al. | May 2022 | B2 |
20030026697 | Subramanian et al. | Feb 2003 | A1 |
20040086635 | Grossklaus et al. | May 2004 | A1 |
20050217110 | Topal | Oct 2005 | A1 |
20060120869 | Wilson et al. | Jun 2006 | A1 |
20070044306 | Szela et al. | Mar 2007 | A1 |
20070163684 | Hu | Jul 2007 | A1 |
20080011813 | Bucci et al. | Jan 2008 | A1 |
20090026182 | Hu et al. | Jan 2009 | A1 |
20090194247 | Kriegl | Aug 2009 | A1 |
20090196761 | James | Aug 2009 | A1 |
20090255116 | McMasters et al. | Oct 2009 | A1 |
20090324841 | Arrell et al. | Dec 2009 | A1 |
20100124492 | Tucker | May 2010 | A1 |
20100176097 | Zhu | Jul 2010 | A1 |
20100257733 | Guo et al. | Oct 2010 | A1 |
20110051179 | Iga | Mar 2011 | A1 |
20110185739 | Bronson et al. | Aug 2011 | A1 |
20120179285 | Melzer-Jokisch et al. | Jul 2012 | A1 |
20120222306 | Mittendorf et al. | Sep 2012 | A1 |
20130195674 | Watson et al. | Aug 2013 | A1 |
20140003948 | Dubs et al. | Jan 2014 | A1 |
20140044939 | Hunt et al. | Feb 2014 | A1 |
20140169943 | Bunker et al. | Jun 2014 | A1 |
20140259666 | Baughman et al. | Sep 2014 | A1 |
20140271153 | Uskert et al. | Sep 2014 | A1 |
20140302278 | Bunker | Oct 2014 | A1 |
20150016972 | Freeman et al. | Jan 2015 | A1 |
20150047168 | James et al. | Feb 2015 | A1 |
20150367456 | Ozbaysal et al. | Dec 2015 | A1 |
20150375322 | Salm et al. | Dec 2015 | A1 |
20150377037 | Salm et al. | Dec 2015 | A1 |
20160032766 | Bunker et al. | Feb 2016 | A1 |
20160177749 | Brandl et al. | Jun 2016 | A1 |
20160230576 | Freeman et al. | Aug 2016 | A1 |
20160250725 | Henderkott et al. | Sep 2016 | A1 |
20160339544 | Xu et al. | Nov 2016 | A1 |
20160375461 | Taylor | Dec 2016 | A1 |
20170252870 | Cui et al. | Sep 2017 | A1 |
20180073390 | Varney | Mar 2018 | A1 |
20180073396 | Varney | Mar 2018 | A1 |
20180093354 | Cui et al. | Apr 2018 | A1 |
20190275617 | Bulgrin et al. | Sep 2019 | A1 |
20200368857 | Henderkott et al. | Nov 2020 | A1 |
20230033578 | Bulgrin et al. | Feb 2023 | A1 |
Number | Date | Country |
---|---|---|
105091030 | Nov 2015 | CN |
10319494 | Nov 2004 | DE |
102006005364 | Aug 2007 | DE |
102008007820 | Aug 2009 | DE |
102008058140 | May 2010 | DE |
1503144 | Feb 2005 | EP |
1528322 | May 2005 | EP |
1584702 | May 2005 | EP |
1803521 | Jul 2007 | EP |
1880793 | Jan 2008 | EP |
1884306 | Feb 2008 | EP |
2206575 | Jul 2010 | EP |
2578720 | Apr 2013 | EP |
2700788 | Feb 2014 | EP |
2700788 | Feb 2014 | EP |
2713007 | Apr 2014 | EP |
3061556 | Aug 2016 | EP |
2012092279 | Jul 2012 | WO |
2015147929 | Oct 2015 | WO |
Entry |
---|
Communication pursuant to Article 94(3) EPC from counterpart European Application No. 19160647.4, dated Mar. 2, 2022, 6 pp. |
Extended Search Report from counterpart European Application No. 19160647.4, dated Aug. 2, 2019, 8 pp. |
Prosecution History from U.S. Appl. No. 16/294,415, now U.S. Pat. No. 11,338,396, dated Feb. 23, 2021 through Apr. 14, 2022, 56 pp. |
Response to Extended Search Report dated Aug. 2, 2019, from counterpart European Application No. 19160647.4, filed Feb. 27, 2020, 56 pp. |
Response to Communication pursuant to Article 94(3) EPC dated Mar. 2, 2022, from counterpart European Application No. 19160647.4 filed Jun. 29, 2022, 24 pp. |
Communication pursuant to Article 94(3) EPC from counterpart European Application No. 19160647.4 dated Jan. 30, 2024, 6 pp. |
Number | Date | Country | |
---|---|---|---|
20230033578 A1 | Feb 2023 | US |
Number | Date | Country | |
---|---|---|---|
62640349 | Mar 2018 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 16294415 | Mar 2019 | US |
Child | 17664528 | US |