Patent Application
20220360045
A plasmonic laser is a type of laser that confines light at a sub-wavelength scale by storing some of the light energy through electron oscillations in metallic layers, referred to as surface plasmon polaritons (“SPPs”). Plasmonic lasers are lasers that lead to stimulated emission of SPPs.
Quantum cascade lasers (“QCLs”) are nanostructured semiconductor lasers that emit in the mid- to far-infrared portion of the electromagnetic spectrum. QCLs relate to the gain medium used. Unlike typical inter-band semiconductor lasers that emit electromagnetic radiation through the recombination of electron—hole pairs across the material band gap, QCLs are unipolar, and laser emission is achieved through the use of inter-sub-band transitions.
Technologies are disclosed for a plasmonic laser array device. The device may comprise a first microcavity element. The first microcavity may have a first radiating end facet and a second radiating end facet opposite the first radiating end facet in a longitudinal direction of the device. The device may comprise a second microcavity element. The second microcavity may have a third radiating end facet and a fourth radiating end facet opposite the third radiating facet in the longitudinal direction of the device. One or more microcavity elements may be added to the arrangement in a similar manner.
The device may comprise a first microcavity gap. The first microcavity gap may be configured to separate the first microcavity element and the second microcavity element in the longitudinal direction of the device. The device may comprise a bottom (e.g., metal) layer. The bottom layer may be configured to underly the first microcavity element, the second microcavity element, and the first microcavity gap.
The device may comprise an arrangement of the first microcavity element and the second microcavity element on the bottom layer. The arrangement may be configured such that the second radiating end facet is opposite the third radiating end facet across the first microcavity gap. The arrangement may place at least the first microcavity element and the second microcavity element into a phase-locked orientation for a phased-locked operation of the plasmonic laser array device.
The elements and other features, advantages and disclosures contained herein, and the manner of attaining them, will become apparent and the present disclosure will be better understood by reference to the following description of various examples of the present disclosure taken in conjunction with the accompanying drawings, wherein:
For the purposes of promoting an understanding of the principles of the present disclosure, reference will now be made to the examples illustrated in the drawings, and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of this disclosure is thereby intended.
Plasmonic lasers suffer from low output power and divergent beams due to their subwavelength metallic cavities. A new phase-locking scheme is developed for such lasers to significantly enhance their radiative efficiency and beam quality. An array of metallic microcavities is longitudinally coupled through traveling plasmon waves, which leads to radiation in a single spectral mode and a diffraction limited single-lobed beam in the surface normal direction. The scheme is implemented for terahertz plasmonic quantum-cascade lasers (QCLs). Peak output power in excess of 2 W is measured for a single-mode 3.3 THz QCL radiating in a narrow single-lobed beam, when operated at 58 K in a compact Stirling cooler. An order of magnitude increase in power and thirty-times higher average intensity is thereby demonstrated for monolithic single-mode terahertz QCLs compared to prior work. The number of photons radiated from the cavity significantly outnumber those absorbed within its claddings and semiconductor medium, which is the first report of >50% radiative efficiency in any single-mode mid-infrared or terahertz QCL.
High-power sources of terahertz radiation are desired for applications in chemical and biomolecular sensing and spectroscopy such as non-destructive evaluation and detection of explosives and drugs, biomedical imaging, and remote-sensing in astronomy to understand star and galaxy formation among many others. Terahertz semiconductor quantum-cascade lasers (QCLs) are closer than ever to target many of such applications with vast scope for commercialization similar to that witnessed by mid-infrared QCLs. Multi-mode terahertz QCLs with Fabry-Perot cavities with output power in the range of hundreds of mill-Watt to multi-Watt have been reported in recent years; however, such lasers show multi-mode spectral output with poor radiation patterns. Stable single-mode operation in a narrow far-field beam is a consistent requirement across many of such applications.
However, progress in improvement of key characteristics of terahertz QCLs has somewhat stagnated in the past decade, in particular with their maximum operating temperature as well as output power. Specifically, the output power of monolithic single-mode terahertz QCLs has not increased much beyond hundred milli-Watt, which was a level reached seven years ago. Some recent results include terahertz QCLs with hybrid second- and fourth-order distributed-feedback (DFB) that achieved 170 mW optical power at 62 K, terahertz QCLs with sampled gratings in the top metal layers with 186 mW output power at 10 K, and terahertz QCLs with quasi-crystalline DFB structure with peak output power of 190 mW at 20 K. The recent development of external-cavity terahertz QCLs is promising as it significantly enhanced the optical power from single-mode terahertz QCLs to the level of a Watt, albeit with the added cost of increased complexity and loss of flexibility and versatility afforded by monolithic chip-based lasers sources.
Phase-locking of an array of optical cavities is a long established method to scale up the outcoupled optical power as well as beam-shaping of conventional semiconductor lasers that continues to be further developed today. It could be all the more relevant for plasmonic lasers that confine long-range surface-plasmon-polariton (SPP) modes at subwavelength dimensions leading to poor radiation patterns and low output power. Terahertz QCLs are also a class of plasmonic lasers that overwhelmingly use parallel-plate metallic cavities, which have excellent mode confinement but poor radiative outcoupling and divergent beams. Different mechanisms for phase-locking of multicavity arrays of metal cavities have been reported for terahertz QCLs toward improvement in their output power, radiative efficiency, and far-field radiation patterns. However, prior phase-locking schemes have not yielded better results for output power when compared to DFB methods.
Described herein are one or more new phase-locking schemes for subwavelength metal cavities in a single-mode terahertz plasmonic QCL to achieve a large radiative efficiency and high-power output in a narrow single-lobed far-field beam. The parallel metallic plates in the cavities sandwich a 10 μm thick quantum-cascade GaAs/AlGaAs superlattice active medium with spectral gain at v˜3.2-3.4 THz (λ˜88-94 μm). Hence, the cavities are subwavelength in the dimension orthogonal to metal plates of the resonant optical cavities, but are kept larger in the other two dimensions. Whereas previously reported phase-locking schemes for semiconductor lasers in the literature primarily relied on lateral coupling of cavities, our method implements a novel longitudinal coupling mechanism by way of single-sided SPP waves that are established on top of metal claddings of the cavities and propagate in the surrounding medium as surface-waves.
The mechanisms of generation of surface-waves and their role in operation of the QCL may differ significantly since they are not the primary contributor to radiation from the phase-locked array. The specific periodicity and dimensions of the short cavities in the multicavity array leads to establishment of an intense in-plane electric-field that radiates and interferes constructively in the surface-normal direction. Based on the scheme, record-highest peak output power (2.03 W), slope-efficiency (1.57 W/A), as well as peak wall-plug efficiency (2.3%) are reported for single-mode terahertz QCLs. A large differential quantum-efficiency of 115 photons per electron is realized for the detected radiation for a fraction of the laser's dynamic range, which is 52% of maximum theoretical limit in the QCL superlattice medium that has 221 repeated stages.
When accounting for optical transmission loss through the cryostat window as well as the laser's internal transition efficiency, the outcoupling (radiative) efficiency of the QCL is estimated to be ≳60%, which indicates approximately 50% more photons are radiated from the cavity compared to those absorbed within its claddings and the semiconductor medium. In contrast, the differential quantum-efficiency for all single-mode QCLs in literature including mid-infrared QCLs has remained below 38% of the theoretical limit.
The radiation loss coefficient (in units of per unit length) for a Fabry-Perot laser cavity is expressed as:
where L is the length of the cavity, and R is the reflectivity of each of two end-facets of the cavity for the guided wave propagating along its length. The coefficient for total optical loss in the cavity can be written as αtot=αrad+αcav, where αcav is the optical loss coefficient due to cavity itself (e.g., that includes absorption losses in the claddings as well as the gain medium). The radiative (outcoupling) efficiency of the laser can then be defined as the ratio ηrad=αrad/αtot that determines the radiative fraction of the total number of photons generated in the gain medium of the laser. High-power lasers typically have large dimensions including longer cavities to generate more photons. However, increasing L reduces ηrad since αrad ∝1/L, which leads to diminishing returns in the net optical power if the cavity is made too long. For monolithic terahertz QCLs, the best radiative efficiencies have therefore been demonstrated in the surface-emitting configuration when αrad is no longer dependent on the cavity dimensions to a first-order, and is instead dependent on design of periodic photonic structures within the cavity and/or its claddings.
At least one useful and/or effective way to increase radiative efficiency for an overall large (long) cavity is by coherently combining radiation from several short-length Fabry-Perot cavities, each of which have a large αrad as per equation Eq. (1). A large number of such cavities in a multicavity array would then lead to large optical power.
These waves are a combination of long-range SPPs as well as short-range quasi-cylindrical waves sustained on top of metal films. Radiative apertures (rectangular slits in
The length of microcavities in the multicavity array is chosen on basis of one or two considerations, for example. First, the length is such that in-plane (Ex) electric-field has same phase at the locations of both end-facets where it is most intense. This allows for constructive interference and radiation in surface-normal dimension for the array. Second, the cavities are kept short enough to keep αrad large, with a goal of realizing αrad˜αcav to achieve an overall large ηrad. For Fabry-Perot terahertz parallel-plate metallic cavities at 3-4 THz, αrad is in the range 2-3 cm−1 for a 1 mm long cavity. The coefficient for total optical loss in the cavity αtot has been experimentally measured in the range ˜10-15 cm−1 for plasmonic QCLs operating from 3-4 THz based on resonant-phonon QCL active regions, which means that αtot is almost entirely comprised of αcav with a minimal radiative component and ηrad<<1. The cavity lengths in the array were thus chosen to be approximately a third of 1 mm with a goal to realize αrad˜10 cm−1 for the desired lowest-loss resonant optical mode of the phase-locked array.
The specific design of the phase-locked array and its operational principle are shown with an illustrative diagram in
As shown subsequently, the experimental lasing frequency of a QCL with this periodicity matches that predicted by results of the FEM simulation. The distance between neighboring cavities dair˜λSPP ensures the hybrid SPP mode is periodic from one microcavity to another that allows for phase-locking of the hybrid SPP surface-waves to guided SPP modes within the cavities. Slit-like apertures are left open in the top metal cladding at locations where vertical electric-field Ez has a null for standing-wave inside cavities, and hence, the in-plane field Ex has a maxima leading to large diffractive outcoupling from the apertures. The periodicity of aperture locations is kept at ˜3λ/neff that is approximately an integer multiple of wavelength of guided SPPs within the semiconductor (=λ/neff) where neff is effective propagation index of guided SPPs (≲3.6 in GaAs). The hybrid SPP mode on top of the metal cladding automatically adjusts its shape to comply with such a periodicity such that λSPP˜3λ/neff for the global phase-locked resonant optical mode in the multicavity array. In that sense, there is no single parameter that exclusively determines the wavelength λ of resonant-mode of the multicavity array. Length of individual microcavities, inter-cavity/microcavity gap distance dair, or spacing between adjacent apertures could each be changed individually in the array for lithographic tuning of λ.
Experimental results for tuning of the resonant-frequency of the array by lithographic variation of the dair/Λ parameter within a range of ˜4 μm (as described herein) shows robustness of the design scheme to withstand variations in cavity dimensions that might arise due to fabrication with conventional lithography techniques.
The simulated structure of the phase-locked array has periodicity of Λ=324 μm for microcavity placement along the longitudinal (x) dimension and an inter-cavity spacing dair=Λ/4. The two-dimensional (2D) simulation effectively solves for cavities of infinite width (along y dimension), which is a good approximation for wide (>>λ) cavities used in experimental implementation. The occurrence of band-gaps in the resonant-mode spectra is indicative of a distributed-feedback (DFB) effect arising due to the periodicity of the overall array that results in coupling of forward and backward propagating hybrid SPP surface-waves.
In this case, the desired mode (with the desired periodicity of the phase-locked SPP modes as illustrated in
This is evident from the intensity of the field radiated in surface-normal direction shown in
In
An active-medium of the THz-QCLs based on a three-well resonant-phonon design with GaAs/Al0.15Ga0.85As superlattice (design RT3W221YR16A, MBE wafer VB841) is used for experimental implementation of the laser array, with a layer sequence of 57/18.5/31/9/28.5/16.5 (starting from the injector barrier) where the thicknesses are in monolayers (MLs; 1 ML=2.825 Å), and was grown by molecular-beam epitaxy, with 221 cascaded periods, leading to an overall thickness of 10 μm. The design is similar to other QCL designs with minor modifications to achieve peak gain centered around a frequency of 3.3 THz. The QCL superlattice has an average n-doping of 5.7e15 cm−3 and surrounded by 0.1 μm and 0.05 μm thick highly-doped GaAs contact layers doped at 5e18 cm−3 on either sides of the superlattice. A 200 nm thick Al0.55Ga0.45As layer was grown as an etch-stop layer preceding the entire stack.
The fabrication process described herein. Metallic waveguides were fabricated using standard thermocompression wafer bonding techniques. Following wafer-bonding and substrate removal, positive-resist lithography was used to selectively etch away the 0.1 μm thick highly-doped GaAs layer from almost all locations where top-metal cladding would exist on individual cavities by H2SO4:H2O2:H2O etchant in 1:8:80 concentration. A 10 μm to 15 μm wide highly-doped GaAs layer below the top-metal cladding was left unetched at the regions close to lateral facets of each microcavity and both longitudinal and lateral facets of the bonding pads, serving as the longitudinal and lateral absorbing boundary to ensure the excitation of the desired mode as the lowest-loss lasing mode.
A sequence of Ti/Cu/Au were deposited as top (20/200/100 nm) metallic layers, in which an image-reversal lithography was implemented to form metallic gratings. Phase-lock array cavities then were processed by inductively coupled plasma (ICP) dry etching using BCl3, Cl2 and Ar etchant in 20 sccm, 5 sccm and 5 sccm (cubic centimeters per minute at STP) with SiO2 as mask. The substrate was then mechanically polished down to a thickness of 300 μm to improve heat-sinking. A Ti/Cu/Au (20/250/100 nm) contact was also used as the backside-metal contact for the finally fabricated QCL chips to assist in soldering.
Experimental results from a representative terahertz QCL implemented with the phase-locking scheme in pulsed mode of operation are shown in
Under the similar condition but without 1000 Hz electric gate (0.4% duty-cycle), the absolute power was calibrated using a thermopile power meter (Scientech AC2500 with AC25H) as is reported without any corrections nor focusing optics were used in this process. Peak optical power of 2030±10 mW was detected for the QCL at 58 K, which evaluates to a peak wall-plug efficiency of 2.3% for corresponding bias conditions. A slope-efficiency (SE) of 1566±10 mW/A is estimated from the slope of approximately the first-half dynamic range at 58 K in which the L-I is linear. To understand the significance of this result, a discussion about SE of a QCL may be useful. The SE of a QCL is expressed as:
In Eq. 2, Pout is the output power, I is the bias current, −hω is the photon energy, q is the fundamental electronic charge, Np is the number of repeat stages in the QCL, ηi is the internal quantum-efficiency of the QCL superlattice that is affected by the injection efficiency as well as the radiative transition efficiency in the QCL superlattice, and ηrad=αrad/(αrad+αcav) is the aforementioned radiative efficiency of the cavity. The slope of the L-I reduces at higher bias currents, which is likely due to a reduction in ηi as the electron-gas becomes hotter in the quantum-wells of the superlattice, which reduces the lifetime of the upper radiative sub-band due to thermally activated phonon scattering.
For the QCL in
Hence, a conservative estimate of ηrad˜0.60 is obtained for the shown terahertz QCL. This result demonstrates that the radiative outcoupling from the cavity as characterized by αrad exceeds the optical loss coefficient in the cavity αcav by about 50%. In the fabricated QCL, the αrad could easily be different from that predicted in FEM simulations by several cm−1, especially since it depends sensitively on width of apertures and overall extent of the metal claddings on top the QCL cavities. An exact estimate of absolute value of αrad may be relatively difficult to obtain for the fabricated QCLs.
The power output of this device was also measured with a much larger duty cycle of 4% (a pulse of 400 ns duration with 100 kHz signal cycle). Peak output power of 1990 mW was detected at 58 K, which is slightly lower than the power measurement with 0.4% duty cycle and is may be due to a stronger electrothermal effect for a higher duty cycle and/or power dissipation in the microcavity array.
Experimental far-field beam pattern for the phased-locked array QCL is shown in
The full-width half-maximum (FWHM) for the QCL presented in
As described herein, a phase-locking scheme for metallic subwavelength cavities in a plasmonic laser may achieve large radiative efficiency and output power. When implemented for terahertz plasmonic QCLs, record-highest peak output power is reported for single-mode terahertz QCLs, and record highest radiative efficiency is estimated among many/all single-mode QCLs (including mid-infrared QCLs) as published to-date. The method leads to stable single-mode spectral operation and a diffraction-limited single-lobed far-field beam for the laser. There are at least two unique aspects to the scheme. First, it leads to longitudinal phase-locking of a multicavity array, which differs distinctly from other phase-locking schemes for semiconductor lasers in literature that predominantly rely on lateral coupling of multiple cavities. Second, it generates coherent single-sided SPPs propagating as surface-waves in surrounding medium of the metal cavities with large vertical spatial extent, which could lead to development of new modalities for spectroscopic sensing and wavelength tunability due to access of a coherent SPP wave on top of the plasmonic laser's cavity.
Peak output power of 2.03 W is detected for a surface-emitting 3.3 THz QCL operating at 58 K in pulsed mode of operation. The QCL radiates in a single-lobed far-field beam with FWHM divergence of 3.2°×11.5°. Owing to high power and narrow beam, the average intensity within the FWHM contour at a fixed distance for this QCL is ˜40 times the previous best achieved for a DFB terahertz QCL, and ˜30 times that estimated for a phased-locked array terahertz QCL. A slope-efficiency of up to 1.57 W/A was measured that corresponds to a differential quantum-efficiency of 115 photons reaching the detector per electron transported through the QCL superlattice, which is 52% of the maximum theoretical limit for the QCL.
The radiative efficiency, which is the fraction of total generated photons that are radiated to free-space, is expected to be even higher (≳60%). This result makes it the first single-mode QCL (including mid-infrared QCLs) in which more photons are radiated than those absorbed as optical losses within the cavity. Finally, robust single-mode operation and lithographic tuning across a bandwidth of ˜140 GHz is demonstrated for a range of QCLs fabricated on the same semiconductor chip. The advantage of the scheme lies in ease of implementation that does not require tight tolerances for fabrication, as well as the possibility to further scale optical power output by increasing lateral size of the cavities as well as number of elements in the multicavity array.
In
There are also some other modifications for the other phase-lock schemes for air-guided THz plasmonic modes in surface-emitting configuration. In at least one phase-locking scheme, index perturbation happens every multiple wavelength for the terahertz wave propagating inside & outside the active medium. So that the facets and apertures implemented lithographically could interfere constructively in the far field region to form single-lobe far field beam pattern. In some cases, edge-emitting lasers but not surface-emitting lasers that may have some specific application like self-mixing so that two end-facets emission is highly desired.
The design of phase-locked scheme for air-guided THz plasmonic modes in edge-emitting configuration with 6 microcavities (6-patch) and Λ=5×dair is selected for experimental implementation. Experimental results from representative terahertz QCLs implemented with 6-patch phase-locked scheme in pulsed mode of operation and mounted inside a Stirling cooler are shown in
The subject matter of this disclosure, and components thereof, can be realized by instructions that upon execution cause one or more processing devices to carry out the processes and/or functions described herein. Such instructions can, for example, comprise interpreted instructions, such as script instructions, e.g., JavaScript or ECMAScript instructions, or executable code, and/or other instructions stored in a computer readable medium.
Implementations of the subject matter and/or the functional operations described in this specification and/or the accompanying figures can be provided in digital electronic circuitry, in computer software, firmware, and/or hardware, including the structures disclosed in this specification and their structural equivalents, and/or in combinations of one or more of them. The subject matter described in this specification can be implemented as one or more computer program products, e.g., one or more modules of computer program instructions encoded on a tangible program carrier for execution by, and/or to control the operation of, data processing apparatus.
A computer program (also known as a program, software, software application, script, or code) can be written in any form of programming language, including compiled or interpreted languages, and/or declarative or procedural languages. It can be deployed in any form, including as a stand-alone program or as a module, component, subroutine, and/or other unit suitable for use in a computing environment. A computer program may or might not correspond to a file in a file system. A program can be stored in a portion of a file that holds other programs and/or data (e.g., one or more scripts stored in a markup language document), in a single file dedicated to the program in question, and/or in multiple coordinated files (e.g., files that store one or more modules, sub programs, or portions of code). A computer program can be deployed to be executed on one computer or on multiple computers that may be located at one site or distributed across multiple sites and/or interconnected by a communication network.
The processes and/or logic flows described in this specification and/or in the accompanying figures may be performed by one or more programmable processors executing one or more computer programs to perform functions by operating on input data and/or generating output, thereby tying the process to a particular machine (e.g., a machine programmed to perform the processes described herein). The processes and/or logic flows can also be performed by, and apparatus can also be implemented as, special purpose logic circuitry, e.g., an FPGA (field programmable gate array) and/or an ASIC (application specific integrated circuit).
Computer readable media suitable for storing computer program instructions and/or data may include all forms of non-volatile memory, media and memory devices, including by way of example semiconductor memory devices (e.g., EPROM, EEPROM, and/or flash memory devices); magnetic disks (e.g., internal hard disks or removable disks); magneto optical disks; and/or CD ROM and DVD ROM disks. The processor and/or the memory can be supplemented by, or incorporated in, special purpose logic circuitry.
While this specification and the accompanying figures contain many specific implementation details, these should not be construed as limitations on the scope of any invention and/or of what may be claimed, but rather as descriptions of features that may be specific to described example implementations. Certain features that are described in this specification in the context of separate implementations can also be implemented in combination in perhaps one implementation. Various features that are described in the context of perhaps one implementation can also be implemented in multiple combinations separately or in any suitable sub-combination. Although features may be described above as acting in certain combinations and/or perhaps even (e.g., initially) claimed as such, one or more features from a claimed combination can in some cases be excised from the combination. The claimed combination may be directed to a sub-combination and/or variation of a sub-combination.
While operations may be depicted in the drawings in an order, this should not be understood as requiring that such operations be performed in the particular order shown and/or in sequential order, and/or that all illustrated operations be performed, to achieve useful outcomes. The described program components and/or systems can generally be integrated together in a single software product and/or packaged into multiple software products.
Examples of the subject matter described in this specification have been described. The actions recited in the claims can be performed in a different order and still achieve useful outcomes, unless expressly noted otherwise. For example, the processes depicted in the accompanying figures do not require the particular order shown, and/or sequential order, to achieve useful outcomes. Multi-tasking and parallel processing may be advantageous in one or more scenarios.
While the present disclosure has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only certain examples have been shown and described, and that all changes and modifications that come within the spirit of the present disclosure are desired to be protected.
This application claims the benefit of U.S. Provisional Patent Application No. 63/186,233, filed May 10, 2021, the entire contents of which being hereby incorporated by reference herein, for all purposes.
| Number | Date | Country | |
|---|---|---|---|
| 63186233 | May 2021 | US |
