Patent Grant
11808634
This is the National Stage of PCT international application PCT/JP2019/044907 filed on Nov. 15, 2019, the content of which is incorporated herein by reference in its entirety.
The present invention relates to a temperature sensor in which an element of the temperature sensor is accommodated inside a protective tube, and a space between the protective tube and the element is filled with a filling body comprising a resin material.
Conventionally, a temperature sensor has been known which accommodates a sensor element provided with a thermosensitive body inside a protective tube. One end of the protective tube closed and the other end is opened. The protective tube is provided with a filling body comprising a resin material inside the protective tube to hold the sensor element.
This temperature sensor comprises the protective tube of a metal material having a higher thermal conductivity than the filling body in order to rapidly transmit a peripheral temperature to the thermosensitive body. In addition, the filling body inside the protective tube surrounds the sensor element to protect the sensor element from the peripheral atmosphere. The protective tube also protects the sensor element from the peripheral atmosphere.
In a temperature sensor that is used in a wet atmosphere with a large amount of moisture, the moisture can enter into the inside even through a minute clearance. If this moisture reaches between the pair of electric wires which are connected to the thermosensitive body, an electric short circuit is caused.
Patent Literature 1 proposes a temperature sensor that can suppress a short circuit even when being used in the wet atmosphere. The temperature sensor of Patent Literature 1 is provided with a first covering layer and a second covering layer. The first covering layer comprises a first electrical insulator and covers a portion from the thermosensitive body to predetermined positions of a pair of electric wires. The second covering layer comprises a second electrical insulator and covers the first covering layer. In the temperature sensor of Patent Literature 1, the first covering layer is provided with a region in which the first covering layer covers the pair of electric wires, specifically, covers a pair of lead wires connected to the thermosensitive body in a bundle, and a region in which the first covering layer individually covers each of the pair of lead wires.
The temperature sensor of Patent Literature 1 is provided with a region in which the covering layer covers the pair of lead wires in a bundle, and a region in which the covering layer individually covers each of the pair of lead wires. According to the temperature sensor of Patent Literature 1, a creepage distance between the pair of lead wires becomes long, and a short circuit between the pair of lead wires can be suppressed.
An object of the present invention is to reduce a possibility of a short circuit in a site different from that in Patent Literature 1, by elongating the creepage distance of the site.
The temperature sensor of the present invention comprises: a sensor element including a thermosensitive body and a pair of electric wires that are electrically connected to the thermosensitive body; a protective tube for accommodating the sensor element; and a filling body that lies between the protective tube and the sensor element inside the protective tube.
The pair of electric wires comprises a pair of first electric wires that are connected to the thermosensitive body, and a pair of second electric wires that are connected to the pair of first electric wires, respectively.
Insulation coverings of the pair of second electric wires are separated from each other, on the front side at which the pair of second electric wires are connected to the pair of first electric wires.
A distance between the pair of second electric wires in the present invention preferably becomes narrow as the distance becomes apart from the front side, and the pair of second electric wires come in contact with each other at a predetermined position.
The pair of second electric wires in the present invention are preferably drawn out of the protective tube, and come in contact with each other at a predetermined position in drawn-out portions of the pair of second electric wires.
In the inside of the protective tube in the present invention, preferably, the filling body lies between the pair of second electric wires which are separated from each other.
The filling body in the present invention preferably comprises a first covering layer, a second covering layer, and a third covering layer.
The first covering layer comprises a first electrical insulator, and covers a portion from the thermosensitive body to predetermined positions of the pair of first electric wires. The second covering layer comprises a second electrical insulator, and covers the first covering layer. The third covering layer comprises a third electrical insulator, and covers the second covering layer and the pair of second electric wires. The second covering layer lies between the pair of second electric wires that are separated from each other, as a filling body.
The first covering layer in the present invention preferably comprises first regions that cover the pair of first electric wires in a bundle, and second regions that are integrally connected to the first regions and individually cover each of the pair of first electric wires. The second covering layer lies between the pair of first electric wires that are separated from each other, as the filling body.
The present invention also provides a sensor element as a single unit, which is applied to a temperature sensor. The sensor element comprises a thermosensitive body, and a pair of electric wires which are electrically connected to the thermosensitive body. The pair of electric wires comprises a pair of first electric wires which are connected to the thermosensitive body, and a pair of second electric wires which are connected to the pair of first electric wires, respectively. Insulation coverings of the pair of second electric wires are separated from each other, on the front side in which the pair of second electric wires are connected to the pair of first electric wires.
The present invention provides a method for manufacturing a temperature sensor which comprises: a sensor element including a thermosensitive body and a pair of electric wires that are electrically connected to the thermosensitive body; a protective tube for accommodating a portion of the thermosensitive body of the sensor element; and a filling body that lies between the protective tube and the sensor element inside the protective tube. The pair of electric wires in the present invention comprises a pair of first electric wires which are connected to the thermosensitive body, and a pair of second electric wires which are connected to the pair of first electric wires, respectively. The manufacturing method of the present invention comprises a step (A) of connecting the pair of second electric wires to the pair of first electric wires which are connected to the thermosensitive body, on the front side at which the pair of second electric wires are to be connected to the pair of first electric wires, in a state in which the insulation coverings of the pair of second electric wires are separated from each other. After the step (A), the step (B) is performed that lays the filling body between the protective tube and the sensor element, while maintaining the state in which the insulation coverings of the pair of second electric wires are separated from each other.
The step (B) in the present invention preferably includes the following steps (a), (b), and (c).
Step (a): forming the first covering layer that comprises the first electrical insulator and covers a portion from the thermosensitive body to predetermined positions of the pair of first electric wires.
Step (b): forming the second covering layer that comprises the second electrical insulator and covers the first covering layer.
Step (c): forming the third covering layer comprising the third electrical insulator by inserting the sensor element into the inside of the protective tube in which an uncured resin material is accommodated, from a side on which the second covering layer is formed.
In the step (a), the first covering layer is formed in a state in which the restraining member is kept interposed between the pair of second electric wires, the insulation coverings of which are separated from each other.
In the step (b), the second covering layer is formed while avoiding the restraining member which is interposed between the pair of second electric wires.
In the step (c), the third covering layer is formed by inserting the sensor element into the inside of the protective tube, in a state in which the restraining member is removed or the restraining member is kept interposed between the pair of second electric wires.
In the temperature sensor according to the present invention, the insulation coverings of the pair of second electric wires are separated from each other on the front side, and accordingly the creepage distance between the core wires of the pair of second electric wires can be increased. Accordingly, the temperature sensor of the present invention can suppress a short circuit between the core wires of the pair of second electric wires even when being used in a wet atmosphere.
Hereinafter, a temperature sensor 1 according to a preferred embodiment of the present invention and a manufacturing method thereof will be described with reference to the drawings.
As shown in
In the temperature sensor 1, the creepage distance between the core wires 17A and 17A of the pair of second electric wires 17 and 17 is increased, so that a short circuit between the core wires 17A and 17A can be suppressed even when being used under a wet environment.
In the following, components of the temperature sensor 1 are described, and the manufacturing procedure of the temperature sensor 1 is then described.
<Sensor Element 10>
As illustrated in
Note that, in the temperature sensor 1, a side on which the thermosensitive body 11 is provided is defined as a front F, and a side on which the second electric wires 17 is drawn out is defined as a rear B, as illustrated in
[Thermosensitive Body 11]
As the thermosensitive body 11, for example, a thermistor is preferably used. The thermistor is an abbreviation of a thermally sensitive resistor, and is a metal oxide that uses change of electrical resistance according to temperature, to measure the temperature.
The thermistor is classified into an NTC (negative temperature coefficient) thermistor and a PTC (positive temperature coefficient) thermistor, and any of the thermistors can be used in the present invention.
As the NTC thermistor, an oxide sintered body that includes, as a basic composition, a manganese oxide (Mn3O4) including a typical spinel structure can be used for the thermosensitive body 11. An oxide sintered body can also be used for the thermosensitive body 11, which has a composition of MxMn3-xO4 in which an M element (one or more of Ni, Co, Fe, Cu, Al and Cr) is added to the basic structure. Furthermore, one or two or more kinds of V, B, Ba, Bi, Ca, La, Sb, Sr, Ti, and Zr can be added thereto.
In addition, as the PTC thermistor, a composite oxide including a typical perovskite structure, for example, an oxide sintered body which has YCrO3 as a basic composition can be used for the thermosensitive body 11.
[Protective Layer 13]
As illustrated in
Note that it is only a preferred embodiment in the present invention to provide the protective layer 13 made of glass, and that it is optional to provide the protective layer 13.
[First Electric Wire 15]
As illustrated in
As each of the first electric wires 15 and 15, Dumet wire that has a linear expansion efficient similar to that of glass is used, because the first electric wires 15 and 15 are sealed by the protective layer 13. Note that the Dumet wire is an electric wire in which an alloy mainly containing iron and nickel is used as a core wire which is an electric conductor, and the conductor is covered with copper. The first electric wires 15 and 15 do not include electrical insulation coverings thereon, and the core wires which are the electric conductor are exposed. Therefore, if moisture enters, a short circuit may occur. In the present embodiment, as will be described later, the creepage distance between the first electric wires 15 and 15 is increased.
One example of linear expansion coefficients of the respective components of the temperature sensor 1 is described below.
Linear Expansion Coefficient
Silicone rubber: 2.0 to 4.0×10−4 (/° C.)
Epoxy resin: 5.0 to 8.0×10−5 (/° C.)
Copper: 16.5 to 16.8×10−6 (/° C.)
Dumet wire: 4.5 to 6.0×10−7 (/° C.)
Glass: 9.1×10−6 (/° C.)
As illustrated in
In order to adjust the distance between the first regions 15A and the distance between the third regions 15C, the first electric wires 15 and 15 includes the second regions 15B between the first regions 15A and the third regions 15C. In the second regions 15B, the first electric wires 15 and 15 are separated by a considerable distance therebetween.
[Second Electric Wire 17]
As illustrated in
Each of the second electric wires 17 is not restricted in linear expansion coefficient unlike the first electric wires 15, and any material can be selected for the second electric wires 17 as long as the material includes predetermined thermal resistance and predetermined durability.
The core wires 17A and 17A of the pair of second electric wires 17 and 17 include portions that are exposed and at which the core wires 17A and 17A are connected to the first electric wires 15 and 15. Therefore, short circuit may occur between the core wires 17A and 17A. In the present embodiment, the core wires 17A and 17A of the second electric wires 17 and 17 are selected as targets to increase creepage distance.
In the pair of second electric wires 17 and 17, usually, the pair of insulation coverings 17B and 17B are integrally formed and are in contact with each other. The insulation coverings 17B and 17B according to the present embodiment, however, are separated from each other on the front side, as illustrated in
In this way, the insulation coverings 17B and 17B have a configuration such that the distance between the insulation coverings 17B and 17B becomes narrower as being apart from the front side toward the rear side. Therefore, the load on the terminal portion of the V-shape is small. In contrast, it is necessary to bend the terminal portion into an L shape in order to have the same distance on the front side through to the terminal portion on the rear side. In this case, the load on this bent portion is large. Therefore, according to the present embodiment, it is possible to reduce the stress which remains in the second electric wires 17 and 17.
Further, the second electric wires 17 and 17 are drawn to the outside from the protective tube 30, as illustrated in
[Protective Tube 30]
Next, as illustrated in
The protective tube 30 is a cylindrical member including one end that is closed as a closed end 31, and the other end that is open as an open end 33. The protective tube 30 has the closed end 31 located on the front side and the open end 33 arranged on the rear side, and supports the sensor element 10 inside the protection tube 30 with the filling body 40.
In
[Filling Body 40]
Next, the filling body 40 comprises a first covering layer 41, a second covering layer 43, and a third covering layer 45, as illustrated in
As a preferred embodiment of the present invention, the first covering layer 41 that directly covers the thermosensitive body 11 comprises a material which deforms more easily than materials for the second covering layer 43 and the third covering layer 45.
Hereinafter, the first covering layer 41, the second covering layer 43, and the third covering layer 45 are sequentially described in a more specific manner.
[First Covering Layer 41]
As illustrated in
The second covering layer 43 comprising an epoxy resin, which is described later, functions as an insulator similarly to the first covering layer 41. Even so, the first covering layer 41 comprising the silicone rubber is provided, because the silicone rubber has a small tensile modulus of elasticity and high elasticity. Specifically, the tensile moduli of elasticity of the silicone rubber and the epoxy resin are shown in comparison in the following. The silicone rubber has a significantly lower elastic modulus than the epoxy resin, and easily deforms even with a small load.
Tensile Modulus of Elasticity
Silicone rubber: 0.01 to 20 (N/mm2)
Epoxy resin: 2000 to 5000 (N/mm2)
When the temperature sensor 1 is used under an environment in which temperature difference occurs, the elements constituting the temperature sensor 1, for example, the first electric wires 15 and 15 and the first covering layer 41 that covers the first electric wires 15 and 15 repeat expansion and contraction. Because the linear expansion coefficients of the first electric wires 15 and 15 and the first covering layer 41 are considerably different from each other, when the expansion and contraction are repeated in a considerable temperature difference, peeling may occur between the first electric wires 15 and 15 and the first covering layer 41. The silicone rubber constituting the first covering layer 41, however, has a small elastic modulus as described below, and thus can deform easily when a load is applied thereto, and absorb the expansion and contraction.
In this way, the first covering layer 41 comprising the silicone rubber functions as the insulator, and also serves as a cushioning function of preventing peeling between the first electric wires 15 and 15 and the first covering layer 41 due to thermal stress accompanying rise and fall of temperature.
This cushioning function, however, is not always required when the degrees of the rise and fall of the temperature are small, and the covering layer comprising the silicone rubber is only a preferred form in the present invention.
As illustrated in
In other words, in the temperature sensor 1, the first covering layer 41 does not exist between the first electric wires 15 and 15 in the second regions 15B and 15B in which each of the regions is individually covered with the first covering layer 41. Accordingly, the creepage distance in the third regions 15C and 15C of the first electric wires 15 and 15 is 2×L1 as illustrated in
When 2×L1 and L2 are compared, it can be easily understood that the creepage distance can be considerably increased by individually covering each of the first electric wires 15 and 15. Accordingly, the temperature sensor 1 can suppress a short circuit occurring between the first electric wires 15 and 15, even if moisture has entered into the region.
The thickness of the first covering layer 41 is optional as long as the thickness achieves the intended purpose, but as one guideline, when the layer has a thickness of 0.1 mm or larger, the function of the insulator can be achieved.
[Second Covering Layer 43]
Next, as illustrated in
The second covering layer 43 covers a region from the front end of the first covering layer 41 to a predetermined position of the insulation coverings 17B and 17B of the second electric wires 17 and 17, and the whole of the first covering layer 41 is covered with the second covering layer 43.
The second covering layer 43 is formed through dipping and curing treatment, as is described later. At the time of the dipping, the liquid epoxy resin enters into a space between the first electric wires 15 and 15, and also into a space between the second electric wires 17 and 17. Thus, the second covering layer 43 after the curing treatment lies between the first electric wires 15 and 15 which are separated from each other, and between the insulation coverings 17B and 17B of the second electric wires 17 and 17, which are separated from each other, as illustrated in
In
In the present embodiment, an adhesive force between the silicone rubber constituting the first covering layer 41 and the epoxy resin constituting the second covering layer 43 is weak. If the first covering layer 41 is brought into direct contact with the third covering layer 45 without providing the second covering layer 43 therebetween, an entry path for moisture tends to be easily formed between the first covering layer 41 and the third covering layer 45, because the adhesive force between both of the covering layers is insufficient. On the other hand, by providing the second covering layer 43, an effect of preventing the formation of the entry path for moisture can be expected.
Specifically, the entry path for moisture is not easily formed between the first covering layer 41 and the second covering layer 43, even if the adhesive force between the silicone rubber and the epoxy resin is weak, because the second covering layer 43 covers and seals the whole of the first covering layer 41. On the other hand, the adhesive force between the epoxy resins is strong, accordingly, the second covering layer 43 and the third covering layer 45 are strongly bonded to each other, and the entry path for moisture is not easily formed between the second covering layer 43 and the third covering layer 45.
In addition, a linear expansion coefficient of the silicone rubber which constitutes the first covering layer 41 is one order larger than that of the epoxy resin, as described previously. If the first covering layer 41, and in addition, the second covering layer 43 and the third covering layer 45 also comprise silicone rubber, a thermal stress applied to the thermosensitive body 11 and the protective tube 30 increases due to the expansion and contraction inside the protective tube 30. Thus, the second covering layer 43 and the third covering layer 45 comprise the epoxy resin having a linear expansion coefficient smaller than that of the silicone rubber, and as a result can reduce the thermal stress which is applied to the protective tube 30.
Meanwhile, suppose that the first covering layer 41 comprises an epoxy resin having large elastic modulus. The epoxy resin shows a smaller difference in the linear expansion coefficient from Dumet wire than the silicone rubber, but the epoxy resin has considerably larger elastic modulus than the silicone rubber. Accordingly, depending on the degrees of the rise and fall of temperature, peeling tends to easily occur between the first covering layer 41 and the first electric wires 15 and 15 due to the expansion and contraction.
The thickness of the second covering layer 43 is optional as long as the thickness achieves the intended purpose, but as one guideline, when the layer has a thickness of 0.3 mm or larger, the function of the insulator can be achieved.
[Third Covering Layer 45]
As illustrated in
As a preferable example, the third covering layer 45 comprises the epoxy resin similarly to the second covering layer 43, secures an adhesive force between itself and the second covering layer 43, and at the same time secures the adhesive force between itself and the inner wall of the protective tube 30. Thus, the entry path for moisture is not easily formed inside the protective tube 30. The epoxy resin constituting the third covering layer 45 constitutes the third electrical insulator of the present invention.
An epoxy resin is used for both the third covering layer 45 and the second covering layer 43. It is preferable, however, that the third covering layer 45 comprises a material having a higher thermal conductivity than that of the second covering layer 43, in view of a main purpose of the third covering layer 45 that the third covering 42 conducts heat of a peripheral temperature toward the thermosensitive body 11. On the other hand, it is preferable that the second covering layer 43 comprises a material with which the dipping, described later, can be performed soundly.
In the present embodiment, an example of the filling body 40 has been described that comprises the three layers of the first covering layer 41, the second covering layer 43, and the third covering layer 45. The filling body in the present invention, however, is not limited to this. The filling body 40 may comprise only one layer, or the filling body 40 may comprise two layers or four or more layers, depending on a rising and falling temperature, atmosphere and the like. In addition, in the present invention, the filling body 40 may comprise an electrical insulator other than the silicone rubber and the epoxy resin.
<Method for Manufacturing Temperature Sensor 1>
Next, a procedure for manufacturing the temperature sensor 1 is described with reference to
[First Intermediate Body]
First, as shown in
As well known, the pair of second electric wires 17 and 17 are manufactured integrally with the insulation coverings 17B and 17B. In the present embodiment, before the pair of second electric wires 17 and 17 are connected to the first electric wires 15 and 15, portions corresponding to the front side of the insulation coverings 17B and 17B are cut, so that the pair of second electric wires 17 and 17 can be separated on the front side. Then, the first electric wires 15 and 15 are electrically connected to the core wires 17A and 17A of the second electric wires 17 and 17, and subsequently the distance between the insulation coverings 17B and 17B on the front side is widened to separate the second electric wires 17 and 17 the front side into a V shape.
[Second Intermediate Body]
Next, as illustrated in
The first covering layer 41 is formed by dipping a side of the thermosensitive body 11 (protective layer 13) in liquid silicone rubber. At this time, it is preferable to consider that the portions which cover the first electric wires 15 and 15 individually cover the first electric wires 15 and 15, respectively. The first covering layer 41 which individually covers each of the first electric wires 15 and 15 can be formed, for example, by performing predetermined control when the sensor element 10 is immersed in the liquid silicone rubber and is then pulled up.
The dipping is one of the coating methods of immersing the thermosensitive body 11 and the protective layer 13 which are the objects to be covered, into a liquid covering material, here a liquid silicone rubber.
During the dipping, the insulation coverings 17B and 17B can be mechanically restrained in order to maintain a distance between the insulation coverings 17B and 17B. The maintenance of the distance by the mechanical restraint can be performed in a process for obtaining the second intermediate body 10B, but can also be performed in a process for obtaining the sensor element 10 which is the next third intermediate body. Specific examples of the mechanical restraint will be described in the next paragraph of the third intermediate body.
[Third Intermediate Body]
Next, as shown in
The second covering layer 43 can be formed by dipping a side of the thermosensitive body 11 (protective layer 13) on which the first covering layer 41 has been formed, into a liquid epoxy resin in the same manner as in the first covering layer 41.
At the time of the dipping, it is preferable to mechanically restrain the portion at which the insulation coverings 17B and 17B are separated in order to maintain the state in which the insulation coverings 17B and 17B are separated at a portion on the front side thereof. In order to mechanically restrain the separated portion, as illustrated in
In order to cure the epoxy resin to be used for dipping, such curing treatment is performed as to keep the epoxy resin at a temperature, for example, in a temperature range of 100 to 150° C., for a predetermined time period. The restraining member 50 is interposed between the insulation coverings 17B and 17B until the curing treatment is finished. After that, the restraining member 50 may be removed from the space between the insulation coverings 17B and 17B, before the third intermediate body, in other words, the sensor element 10 is sealed in the protective tube 30, or the sensor element 10 may be sealed in the protective tube 30 with the restraining member kept interposed between the insulation coverings 17B and 17B.
The curing treatment is similarly applied also in the step of producing the second intermediate body 10B.
The pin-shaped restraining member 50 is only one example of mechanically restraining means. In the present invention, the separated state may be maintained by another means, for example, by sandwiching a portion at which the insulation coverings 17B and 17B are separated, by a clip from the top and bottom surfaces. Further, the separated state of the insulation coverings 17B and 17B on the front end may be also maintained by bridging and sticking an adhesive tape having high rigidity on the portions of the separated insulation coverings 17B and 17B.
[Sealing in Protective Tube 30]
Next, the sensor element 10 on which the covering layers up to the second covering layer 43 are formed is sealed in the protective tube 30. Sealing is performed according to the following procedure.
A predetermined amount of liquid, specifically, of an epoxy resin in an uncured state is charged into the inside of the protective tube 30 in such a state that the open end 33 thereof faces upward. The epoxy resin constitutes the third covering layer 45 after the curing treatment. The sensor element 10 is inserted from the front end, into the inside of the protective tube 30 in which the epoxy resin has been charged.
The epoxy resin is subjected to the curing treatment after the sensor element 10 has been inserted, and then the temperature sensor 1 is completed.
As illustrated in
If the restraining member 50 is kept interposed between the insulation coverings 17B and 17B, the sensor element 10 is sealed in the protective tube 30 in such a manner that the site at which the restraining member 50 is provided is set above the open end 33 of the protective tube 30.
[Effect of Temperature Sensor 1]
The effect of the above described temperature sensor 1 is described.
In the temperature sensor 1 according to the present embodiment, as illustrated in
In the above, the preferred embodiment of the present invention has been described, but the configuration described in the above embodiment can be selected or replaced with another configuration, insofar as it does not deviate from the scope of the present invention.
The temperature sensor 1 is shown as an example of a preferable embodiment in which the first covering layer 41 is not laid between the first electric wires 15 and 15 in the second regions 15B and 15B. However, in the present invention, as shown in
In the present embodiment, silicone rubber is used for the preferred first covering layer 41; however, the present invention is not limited thereto. For example, butadiene rubber may be used. The resin material is common with the silicone rubber in electrical insulating properties and water resistance, and in mechanical characteristics of small elastic modules.
Further, in the present embodiment, the epoxy resin is used for the preferable second covering layer 43 and the third covering layer 45; however, the present invention is not limited thereto. For example, in the present invention, a resin material including physical and chemical characteristics equivalent to those of the epoxy resin may be used.
Further, in the present embodiment, the preferable filling body 40 is assumed to have three layers of the first covering layer 41, the second covering layer 43, and the third covering layer 45; however, the present invention is not limited thereto. The filling body 40 may comprise one layer, depending on an environment in which the temperature sensor is used. As illustrated in
Furthermore, the example of the thermistor as the thermosensitive body has been described in the present embodiment; however, the present invention is not limited thereto. For example, an electric resistor using platinum can be used for the thermosensitive body.
Further, the pair of first electric wires 15 and 15 are formed into the V shape in which the distance between the first electric wires 15 and 15 becomes wider from the front side to the rear side; but the present invention is not limited thereto. The invention broadly includes configurations in which the mutual distance becomes wide, for example, such as a U shape. Similarly, the second electric wires 17 and 17 are formed in the V shape in which the distance becomes narrower from the front side toward the rear side; however, the present invention is not limited thereto. The present invention broadly includes configurations in which the mutual distance becomes narrow, for example, such as a U shape.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2019/044907 | 11/15/2019 | WO |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2021/095244 | 5/20/2021 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20160209276 | Noli | Jul 2016 | A1 |
| Number | Date | Country |
|---|---|---|
| 109073480 | Dec 2018 | CN |
| S52-170577 | Dec 1977 | JP |
| S63-031344 | Feb 1988 | JP |
| H05-075630 | Oct 1993 | JP |
| 2010123641 | Jun 2010 | JP |
| 2016133317 | Jul 2016 | JP |
| 6360273 | Jul 2018 | JP |
| 20090025680 | Mar 2009 | KR |
| 20090025680 | Mar 2009 | KR |
| Entry |
|---|
| Office action for CN application No. 201980006790.5 dated Oct. 27, 2020 and translation of the Office action. |
| International Search Report for PCT/JP2019/044907 dated Dec. 10, 2019. |
| Written Opinion for PCT/JP2019/044907 dated Dec. 10, 2019. |
| Number | Date | Country | |
|---|---|---|---|
| 20210404882 A1 | Dec 2021 | US |
