Claims
- 1. A curable adhesive composition having enhanced strength and high temperature resistance, comprising:
- (a) a thermoplastic elastomer polymer having grafted thereto a C.sub.3 -C.sub.10 unsaturated mono- or polycarboxylic acid, anhydride or derivative thereof;
- (b) a tackifying resin selected from hydrocarbon resins, polyterpene resins, and cyclopentadiene resins; and
- (c) a crosslinking agent selected from di- or polyamine hydrocarbyl compounds having from 2 to about 20 carbon atoms, wherein said crosslinking agent is encapsulated with polymer containing maleic anhydride groups.
- 2. The composition of claim 1 wherein said cross-linking agent is selected from ethylene, propylene, benzene, toluene and tallow-based di- and polyamine hydrocarbyl compounds.
- 3. The composition of claim 1 wherein said cross-linking agent is selected from diethylene triamine, triethylene tetramine, tetraethylene pentamine, ethylene diamine, and diethyl toluene diamine.
- 4. The composition of claim 1 wherein said cross-linking agent is one of ethylene diamine or dicyandiamine.
- 5. The composition of claim 1, wherein said thermoplastic elastomer is selected from ethylene propylene rubber (EPR), ethylene propylene diene monomer rubber (EPDM), polyisobutylene, butyl rubber, ethylene vinyl acetate copolymer, ethylene acrylic acid copolymer, ethylene methacrylate copolymer, and ethylene methacrylate acrylic acid terpolymer.
- 6. The composition of claim 1 wherein said cross-linking agent is present in said composition from about 0.01 to about 15.0% by weight of said thermoplastic elastomer.
- 7. The composition of claim 6 wherein said cross-linking agent is present from about 0.05% to about 2% by weight of said thermoplastic elastomer.
- 8. The composition of claim 1 wherein said tackifying resin is a cyclopentadiene resin.
- 9. The composition of claim 1 wherein said thermoplastic elastomer is a graft copolymer of ethylene propylene rubber with a C.sub.3 to C.sub.10 unsaturated mono- or polycarboxylic acid anhydride or derivative.
- 10. The composition of claim 9 wherein said graft copolymer is a graft copolymer having an unsaturated mono- or polycarboxylic acid selected from maleic acid, fumaric acid, acrylic acid, hydroxy-C.sub.2 to C.sub.20 alkyl methacrylates, and anhydrides and derivatives thereof.
- 11. The composition of claim 10 wherein said graft copolymer is grafted with maleic acid anhydride.
- 12. The composition of claim 1 comprising about 20 to about 60% by weight of said thermoplastic elastomer, from about 30 to about 70% by weight of said tackifying resin, and from about 0.01 to about 2% by weight of said cross-linking agent.
- 13. The composition of claim 12 wherein said cross-linking agent is ethylene diamine.
- 14. The composition of claim 12 wherein said cross-linking agent is selected from tetraethylene pentamine, triethylene tetraamine, or diethylene triamine.
- 15. The composition of claim 1 wherein there is additionally provided an antioxidant.
- 16. The composition of claim 15 wherein said antioxidant is present at from about 0.01 to about 1 percent by weight.
- 17. The composition of claim 1 further comprising a modifying wax.
- 18. The composition of claim 17 wherein said modifying wax is a microcrystalline wax.
- 19. The composition of claim 18 wherein said microcrystalline wax is present at from about 10 to about 30 percent by weight.
- 20. The composition of claim 1 further comprising an oil component.
- 21. The composition of claim 1 wherein said thermoplastic elastomer is a maleated ethylene propylene rubber copolymer which is present at 20 to about 50 percent by weight, said tackifying resin is a cyclopentadiene resin which is present at 30 to 60 percent by weight, said cross-linking agent is ethylene diamine which is present at from 1 to 15 percent by weight, said composition further comprising a microcrystalline wax which is present at 20 to 30 percent by weight and an antioxidant which is present at from 0.1 to 1 percent by weight.
- 22. The composition of claim 18 having a Brookfield viscosity at 160.degree. C. in the range of about 150,000 to about 250,000 centipoise.
- 23. The composition of claim 12 wherein said adhesive functions as a pressure sensitive adhesive and said thermoplastic elastomer is a maleated ethylene propylene rubber elastomer which is present at from 30 to 60 percent by weight, said tackifying resin is a hydrogenated cyclopentadiene resin which is present at from about 50 to about 70 percent by weight, and said cross-linking agent is ethylene diamine which is present at from about 0.5 to about 5 percent by weight.
- 24. The composition of claim 1 further comprising an alcohol.
- 25. The composition of claim 1, wherein said encapsulating material comprises maleated polypropylene.
- 26. The composition of claim 1 wherein said tackifying resin is hydrogenated.
- 27. An encapsulated di- or polyamine wherein the encapsulating material is a polymer containing maleic anhydride groups.
- 28. The encapsulated di- or polyamine of claim 27 wherein the encapsulating material is maleated polypropylene.
BACKGROUND OF THE INVENTION
This application is a continuation-in-part of U.S. patent application Ser. No. 137,391, filed Dec. 23, 1987 now U.S. Pat. No. 4,839,422.
US Referenced Citations (4)
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
137391 |
Dec 1981 |
|