Patent Application
20150017467
The present invention relates to an elongated steel element adapted for the reinforcement of rubber products. The present invention also relates to a process for manufacturing such an elongated steel element.
Elongated steel elements such as brass coated steel wires and steel cords are widely used to reinforce rubber products such as tires. In order to have a good adhesion formation and to reduce the rate of degradation of adhesion, particularly due to ageing in hot humid conditions, cobalt complexes are added to the rubber compound. However, cobalt is considered to be a poison for the rubber since, like most transition metals, it is an oxidation catalyst. As a result, oxidation of diene rubber molecules is accelerated, which leads to early rubber ageing. Moreover, cobalt also speeds up crack growth rate of the rubber.
In addition to the above disadvantage there is also the following problem: Cobalt is a strategic material and it is quite expensive. By adding cobalt to the whole rubber compound, one adds too much cobalt since it has only a positive function at the brass surface. Generally, it is considered that only 20% of the cobalt added to the rubber is used effectively.
The prior art has already recognized one or more of these problems. A lot of attempts have been made to concentrate the cobalt there where it belongs, namely in or on the coating of the steel wires or steel cords.
Yet in 1936 there was an attempt to completely replace the brass coating by a pure cobalt coating on articles for reinforcing rubber (U.S. Pat. No. 2,240,805).
U.S. Pat. No. 4,255,496 (Bekaert) discloses the use of a ternary alloy copper-cobalt-zinc coating instead of a binary alloy copper-zinc (=brass) coating. With this ternary alloy, the rate of bond degradation due to aging in hot humid conditions can be significantly reduced.
U.S. Pat. No. 4,265,678 (Tokyo Rope) teaches the use of a ternary alloy copper-zinc-cobalt coating with excellent drawability and adhesion properties.
GB-A-2 076 320 (Sodétal) teaches a thin layer of cobalt on top of a brass coating followed by a wire drawing so that there is a high gradient of cobalt on top of the brass coating.
EP-A1-0 175 632 (Goodyear) teaches a quaternary alloy coating copper-zinc-nickel-cobalt on steel elements.
Finally, WO-A1-2011/076746 discloses a steel cord with a ternary or quaternary alloy coating and with a zinc gradient. Although giving improvement with respect to adhesion, this zinc gradient involves a post-treatment of the wire or cord, meaning an extra operation step in the process.
It is an object of the present invention to avoid the drawbacks of the prior art.
It is also an object of the present invention to stir the adhesion performance of ternary alloy or quaternary alloy coated elongated steel elements, particularly after steam and cured humidity ageing.
It is yet another object of the present invention to avoid from using extra operation steps in the manufacturing process.
According to a first aspect of the present invention, there is provided an elongated steel element adapted for the reinforcement of rubber products. This elongated steel element is covered with a ternary or quaternary alloy of copper-M-zinc coating.
M is one or two metals selected out of the group consisting of cobalt, nickel, tin, indium, manganese, iron, bismuth and molybdenum.
The copper content inside this coating ranges from 58 weight percent to 75 weight percent, e.g. from 61 wt % to 70 wt %.
The content of the one or two metals inside the coating ranges from 0.5 weight percent to 10 weight percent, e.g. 2 wt % to 8 wt %. The one or two metals are present throughout the coating, and are not only present at the immediate surface.
The remainder is zinc and unavoidable impurities, e.g. impurities in quantities lower than 0.1 wt %.
The thickness of the coating ranges from 0.05 μm to 0.50 μm, e.g. from 0.12 μm to 0.40 μm.
The weight percentages of copper, the one or two metals, and the balance of zinc may be measured by an analytical dissolution technique and with X-ray fluorescence (XRFS), Inductively Coupled Plasma (ICP) or Atomic Absorption Spectroscopy (AAS). These measurements are also suitable to obtain the coating weight and the coating thickness.
Phosphorus is present on the coating in an amount of more than 1 milligram per square meter of the coating. Preferably this amount is limited to 4 milligram per square meter, e.g. limited to 3 milligram per square meter. This phosphorus amount may be present in the form of inorganic or organic phosphorus such as phosphates. The phosphorus amount may be measured by means of an Inductively Coupled Plasma technique or by means of an ultraviolet-visible spectroscopy. The coating or the surface of the coating is further having residues of compounds that complex with the copper in the coating to form an insoluble film. These compounds include triazoles, imidazoles and indazoles. Such compounds include those having the following structural formula:
where the adjacent carbon atoms are joined to form a benzene or naphthylene ring, said ring being substituted or unsubstituted and wherein A and B are selected from a group consisting of —N— or —CH—, with A and B never being simultaneously equal to —CH—. Examples of such compounds are benzotriazole, tolyltriazole, benzimidazole, indazole, naphthatriazole. The presence or residues of one or more of these compounds may be measured by a Time of Flight—Secondary Ion Mass Spectrometery (ToF-SIMS) technique.
This technique provides information on the atomic and molecular composition of the uppermost 1-3 monolayers with sensitivities at ppm level and lateral resolutions down to 100 nm.
ToF-SIMS is not an inherently quantitative technique because the detected intensities depend on the chemical composition of the ambient material (“matrix effect”). Semi-quantitative information can be obtained if the chemical environment of the samples to be compared is similar.
In spectrometry mode a total mass spectrum of a surface region of interest is acquired. These spectra are usually recorded with high mass resolution and a low number of used primary ions. The high mass resolution is necessary for a reliable identification of secondary ion signals and corresponding sum formulas. The limited number of primary ions guarantees that the detected signals are representative for the original chemical composition of the sample surface (Static SIMS limit).
For the ToF-SIMS measurements of the present invention, an ION-TOF “TOF-SIMS IV” SIMS instrument was used. Ion bombardment of the surface was performed using bismuth ions at 25 keV in a bunched mode. Analysis current is 0.2 pA and the analysed area is 100×100 μm2.
The elongated steel element may be a steel wire or a steel cord. In case of a steel cord, the invention is not limited to a particular type of construction.
The terms “adapted for the reinforcement of rubber products” refer to steel wires and steel cords with a suitable wire or filament diameter, a suitable steel composition and a suitable tensile strength.
A suitable steel composition is e.g. a minimum carbon content of 0.65%, a manganese content ranging from 0.10% to 0.70%, a silicon content ranging from 0.05% to 0.50%, a maximum sulphur content of 0.03%, a maximum phosphorus content of 0.03%, even of 0.02%, all percentages being percentages by weight. There are only traces of copper, nickel and/or chromium. The remainder is always iron.
Micro-alloyed steel compositions may also be suitable such as compositions further comprising one or more of following elements:
Within the context of the present invention low-carbon steel compositions such as disclosed in EP-A-2 268 839 are not excluded. Such a steel compositions has a carbon content of less than 0.20%. An example is a carbon content ranging between 0.04% and 0.08%, a silicon content of 0.166%, a chromium content of 0.042%, a copper content of 0.173%, a manganese content of 0.382%, a molybdenum content of 0.013%, a nitrogen content of 0.006%, a nickel content of 0.077%, a phosphorus content of 0.007%, a sulphur content of 0.013%, all percentages being percentages by weight.
The diameter of individual steel wires or steel filaments of elongated steel elements adapted for reinforcement of rubber products usually ranges from 0.03 mm to 1.20 mm, e.g. from 0.10 mm to 0.80 mm, e.g. from 0.15 mm to 0.60 mm.
The levels of roughness Ra measured on the individual steel wires vary from 0.10 μm to 2.0 μm, e.g. from 0.10 μm to 1.0 μm, e.g. from 0.10 μm to 0.30 μm.
The tensile strength of elongated steel elements adapted for the reinforcement of rubber products largely depends upon the diameter and usually ranges from 1500 MPa to 4500 MPa, e.g. from 2000 MPa to 4000 MPa.
As will be explained hereinafter, the amounts of phosphorus on the coating together with the presence of triazole residues lead to improved adhesion results after cured humidity (CH) and after steam ageing (SA). Cured humidity (CH) is when samples of regular cure (RC) are held at a temperature in a range from 70° C. to 93° C. in a 95% relative humidity environment for three, seven, or fourteen or even more days. Steam ageing (SA) is when samples of regular cure (RC) are steam cooked at a temperature in a range from 105° C. to 121° C. for a few hours until one or two days. Regular cure (RC) is TC90 time plus five minutes. TC90 is the time where the rubber reaches 90% of its maximum torque on a rheometer curve taken at vulcanisation temperature. With amounts of phosphorus below 1 mg/m2, lower adhesion performance is noticed.
Both the phosphates at the surface and the triazole residues on the surface passivate the brass alloy coating to a little extent. Hence, they slow down the adhesion build-up, as adhesion build-up is an oxy-sulfidation reaction of copper and zinc. They also slow down adhesion degradation in hot and humid environment, via a slowdown of the dezincification mechanism.
EP-A1-0 257 667 discloses a brass alloy coating for steel elements for rubber reinforcement, where the brass alloy coating contains small amounts of phosphorus. The phosphorus is described as improving the adhesion between the rubber and the brass. However, the amount of phosphorus is higher than in the present invention and neither the presence nor the effect of triazoles are mentioned in EP-A1-0 257 667.
According to a second aspect of the present invention, there is provided process for manufacturing an elongated steel element. This process comprising the following steps:
The aqueous lubricant may be an emulsion or a dispersion.
The phosphorus amount is preferably less than 4 milligram per square meter, e.g. less than 3.5 milligram per square meter, e.g. less than 3.0 milligram per square meter. The reason is that too high phosphorus amounts may have a negative effect on initial adhesion.
The phosphorus amount is measured by means of an Inductively Coupled Plasma technique.
The lubricant further has one or more compounds that complex with the copper in the coating to form an insoluble film. These compounds include triazoles, imidazoles and indazoles.
As mentioned, the amounts of phosphorus and the triazole compounds lead to an improved adhesion behaviour both after cured humidity and after steam ageing. Since the phosphorus and the triazole compounds are added to the ternary or quaternary alloy coating by means of the wet wire drawing lubricant, no additional process step is required to achieve this improved adhesion.
The invention also relates to a rubber product reinforced with an elongated steel element with the features as disclosed here above.
Two sample steel wires with a diameter of 1.98 mm are provided with a ternary alloy coating as follows:
i) pickling in a H2504 solution to clean the surface of the steel wire;
ii) electroplating with copper from a Cu2P207 solution; solution contains 25 g/l copper and 180 g/l pyrophosphate; current density is 8.6 A/dm2 or higher for higher copper content;
iii) electroplating cobalt from a CoSO4 solution; solution contains 40 g/l cobalt and current density is 22 A/dm2;
iv) electroplating with zinc from a ZnSO4 solution; solution contains 50 g/l zinc and current density is 8.8 A/dm2 or lower for lower zinc content;
v) applying a thermal diffusion process to create the ternary alloy Cu—Co—Zn;
vi) removing excess of ZnO formed during diffusion process via a dip in an acid;
vii) rinsing and drying.
Steel wire 1 has following coating composition: 63.5 wt % Cu, 4.0 wt % Co, the remainder being Zn.
Steel wire 2 has following coating composition: 67.0 wt % Cu, 4.0 wt % Co, the remainder being Zn.
A third sample steel wire is provided without the ternary alloy coating, but with the more common brass coating copper-zinc. Steel wire 3 has following coating composition: about 64 wt % Cu, the remainder being Zn.
The steel wires are subjected to a final reduction in diameter during a wet wire drawing operation.
Three different lubricants are used: R-I1-I2.
Reference lubricant R is an aqueous emulsion containing more than 90% water, an oil, surfactant, soap, phosphorus compound and a pH buffering system. The pH is also partially buffered by working of amines. More particularly, lubricant R comprises phosphates, sulphates, nitrates, O-containing hydrocarbons and fatty acid residues, N-containing hydrocarbons. The phosphates may be present as PO2 or as PO3− ions.
Lubricants I1 and I2 are lubricants used in the context of the present invention.
Invention lubricant I1 is an aqueous emulsion containing mineral oil, surfactant, soap, phosphorus compound, extreme pressure additive, corrosion inhibitor of the triazole type, e.g. benzotriazole, and a pH buffering system. The pH is also partially buffered by working of amines. More particularly, lubricant I1 contains phosphates, CN/CNO, benzotriazole, hydrocarbons, fatty acids and octylphosphate acid.
Invention lubricant I2 is an aqueous emulsion containing vegetable oil, surfactant, soap, phosphorus compound, extreme pressure additive, corrosion inhibitor of the triazole type, e.g. benzotriazole, and a pH buffering system. The pH is also partially buffered by working of amines. More particularly, lubricant I2 contains phosphates, CN/CNO, benzotriazole, hydrocarbons, fatty acids and octylphosphate acid.
Final steel wire diameter is 0.30 mm. After wet wire drawing the steel wires have been twisted into a 2×0.30 steel cord construction.
Combining the three steel wires 1 and 2 and 3 with the three lubricants R, I1 and I2, gives nine different steel cord samples 1-R, 1-I1, 1-I2, 2-R, 2-I1, 2-I2, 3-R, 3-I1 and 3-I2. These nine different steel samples have been vulcanized in a rubber compound. The pull-out force (POF) and the appearance ratio (APR) or rubber coverage have been measured on these samples.
Table 1 lists, amongst others, the amount of phosphorus on the surface of the ternary alloy coating.
Table 2 mentions the results of the pull-out test (ASTM D2229) and of the appearance ratio test in regular cure (RC) and after steam ageing (SA) obtained in a cobalt-free rubber compound.
The invention samples 1-I1 inv, 1-I2 inv, 2-I1 inv and 2-I2-inv perform better both in -the pull-out test as in the appearance ratio test after steam ageing. The results on SA (steamed adhesion) of the invention samples 1-I1 inv, 1-I2 inv, 2-I1 inv and 2-I2-inv are remarkably better than those of the 3-R-ref, 3-I1-ref and 3-I2-ref samples with the normal brass coating, even in case for the normal brass coating the same lubricant and the same level of phosphorus amount on the surface are applied.
The adhesion behaviour of invention samples 1-I1 inv, 1-I2 inv, 2-I1 inv and 2-I2-inv at under cure (UC) are at an acceptable high level, see Table 3 hereafter.
Under cure (UC) is when the rubber is vulcanised for about half of the regular curing time.
Table 4 hereunder summarizes the results of a ToF-SIMS analysis carried on steel cord sample 2-I2-inv of the invention.
The amounts of benzotriazole found on or in the surface of the invention steel cord sample is clearly above the noise level of the ToF-SIMS analysis technique.
In comparison, the amounts of benzotriazole found on or in the surface of steel cord samples treated with reference lubricant R are ranging from 1.00 to 5.00, amounts which are considered noise level.
Table 5 hereunder mentions two possible tire rubber compound formulations together with its properties where an effective improvement on steam ageing and cured humidity adhesion have been noticed.
Next to the ternary alloy compositions mentioned in Table 1, following compositions have also been tested:
Due to an improved adhesion performance and better rubber compound an increased tire endurance may be noticed.
In addition, the absence of cobalt in the rubber compound reduces the rubber heat ageing.
Finally, a lower rolling resistance of about 2.5% to 4.0% or even higher may be noticed.
| Number | Date | Country | Kind |
|---|---|---|---|
| 12154052.0 | Feb 2012 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/064477 | 7/24/2012 | WO | 00 | 7/30/2014 |
