Claims
- 1. A process for the production of polyurethanes by the polyisocyanate polyaddition process comprising reacting a polyisocyanate with an isocyanate-reactive compound in the presence of the tertiary amine produced by reacting
- a) a polyol represented by the formula
- Q(OH).sub.n (I)
- in which
- Q represents the residue obtained by removing n-hydroxyl groups from a n-hydric aliphatic alcohol having a molecular weight in the range from 90 to 400,
- and
- n represents 2 or 3, and
- b) an amine corresponding to the formula ##STR3## in which A represents the residue of a divalent, aliphatic hydrocarbon having from 2 to 6 carbon atoms in which at least 2 carbon atoms are present between the nitrogen atoms which appear in Formula (II),
- R.sup.1 and R.sup.2 each represent an alkyl residue having from 1 to 4 carbon atoms or together with the nitrogen atom to which each is bonded form a saturated heterocyclic 5- or 6-membered ring which heterocyclic ring is inert with respect to carbonic acid derivatives,
- with
- c) a carbonic acid derivative selected from the group consisting of
- 1) carbonates corresponding to the formula ##STR4## in which R.sup.3 each represents a phenyl residue, an alkyl residue having from 1 to 4 carbon atoms or together form an alkylene residue having 2 or 3 carbon atoms,
- 2) urea,
- 3) phosgene and
- 4) bis-chlorocarbonates of polyols represented by Formula (I), in amounts such that the molar ratio of hydroxyl groups from a) to primary amino groups of b) is from about 4:1 to about 16:1, about 0.5 moles of carbonic acid derivative c) are present for each mole of amine b) and, from about 0.2 to about 0.5 moles of carbonic acid derivative c) are present for each mole of hydroxyl groups in a) to form carbonate and urethane groups.
- 2. A process for the production of polyurethanes by the polyisocyanate polyaddition process comprising reacting a polyisocyanate with an isocyanate-reactive compound in the presence of the tertiary amine produced by reacting
- a) a polyol represented by the formula
- Q(OH).sub.n (I)
- in which
- Q represents the residue obtained by removing n-hydroxyl groups from an n-hydric aliphatic alcohol having a molecular weight in the range from 90 to 400 and
- n represents 2 or 3,
- b) an amine corresponding to the formula ##STR5## in which A represents the residue of a divalent, aliphatic hydrocarbon having from 2 to 6 carbon atoms in which at least 2 carbon atoms are present between the nitrogen atoms which appear in Formula (II),
- R.sup.1 and R.sup.2 each represent an alkyl residue having from 1 to 4 carbon atoms or together with the nitrogen atom to which each is bonded form a saturated heterocyclic 5- or 6-membered ring which heterocyclic ring is inert with respect to carbonic acid derivatives,
- and
- c) a carbonic acid derivative selected from the group consisting of
- 1) carbonates corresponding to the formula ##STR6## in which R.sup.3 each represents a phenyl residue, an alkyl residue having from 1 to 4 carbon atoms or together form an alkylene residue having 2 or 3 carbon atoms,
- 2) urea,
- 3) phosgene and
- 4) bis-chlorocarbonates of polyols represented by Formula (I), in a manner such that polyol a) and carbonic acid derivative c) react to form a polycarbonate having hydroxyl groups and in amounts such that the molar ratio of hydroxy) groups from a) to primary amino groups of b) is from about 4:1 to about 16:1, the molar ratio of primary amino groups of b) to carbonate groups of the polycarbonate having hydroxyl groups is maintained at from about 0.2:1 to about 0.5:1, about 0.5 moles of carbonic acid derivative c) are present for each mole of amine b) and from about 0.2 to about 0.5 moles of carbonic acid derivative c) are present for each mole of hydroxyl groups in a) to form carbonate and urethane groups.
- 3. A process for the production of a composite of a plastic film and polyurethane foam comprising applying a foam forming-mixture made up of a polyisocyanate, and isocyanate-reactive compound and a tertiary amine produced by reacting
- a) a polyol represented by the formula
- Q(OH).sub.n (I)
- in which
- Q represents the residue obtained by removing n-hydroxyl groups from an n-hydric aliphatic alcohol having a molecular weight in the range from 90 to 400,
- and
- n represents 2 or 3,
- and
- b) an amine corresponding to the formula ##STR7## in which A represents the residue of a divalent, aliphatic hydrocarbon having from 2 to 6 carbon atoms in which at least 2 carbon atoms are present between the nitrogen atoms which appear in Formula (II),
- R.sup.1 and R.sup.2 each represent an alkyl residue having from 1 to 4 carbon atoms or together with the nitrogen atom to which each is bonded form a saturated heterocyclic 5- or 6-membered ring which heterocyclic ring is inert with respect to carbonic acid derivatives,
- with
- c) a carbonic acid derivative selected from the group consisting of
- 1) carbonates corresponding to the formula ##STR8## in which R.sup.3 each represents a phenyl residue, an alkyl residue having from 1 to 4 carbon atoms or together form an alkylene residue having 2 or 3 carbon atoms,
- 2) urea,
- 3) phosgene and
- 4) bis-chlorocarbonates of polyols represented by Formula (I), in amounts such that the molar ratio of hydroxyl groups from a) to primary amino groups of b) is from about 4:1 to about 16:1, about 0.5 moles of carbonic acid derivative c) are present for each mole of amine b) and from about 0.2 to about 0.5 moles of carbonic acid derivative c) are present for each mole of hydroxyl groups in a) to form carbonate and urethane groups, to the back side of a plastic film and allowing the foam-forming mixture to react.
Parent Case Info
This application is a division, of application Ser. No. 08/510,830 filed Aug. 3, 1995, now U.S. Pat. No. 5,705,672.
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Muskat et al. |
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CAX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
510830 |
Aug 1995 |
|