The present invention, in particular, relates to a thermal device for a refrigerant or heat transfer fluid.
Such a device already exists. EP 0076884 or US 2005/167169 has one of them, which comprises, like the one from the present application:
It is specified that a phase change material—or PCM—will mean any material capable of changing physical state in a limited temperature range. The heat storage can take place by using the Latent Heat (LH) thereof: the material can thus store or transfer energy by simply changing state, while preserving a substantially constant temperature, that of the state change.
Yet, the industry is asked to accelerate the placing on the market of new technologies which could reduce pollutant emissions, smooth out possible specific increases in loads in relation to a nominal sizing functioning, but also to propose solutions to stagger the release, over time, of energy available at another time.
Yet, PCMs, in their current implementation, in particular so as to produce the structural environment in which they are arranged, do not seem to be able to meet the expectations of the market.
An efficiency of the heat rate in the exchange within the store and heat exchanger and therefore an industrial implementation, specific to enabling to adapt the store and heat exchanger to the needs of the client (exchange rate/capacity by volume/bulk) are met.
It is therefore in this context that it is proposed here that the thermal device presented above is such:
The term “baffles” is to be understood as indicating the presence in the store and heat exchanger of means which oppose the natural progression of the fluid in said interior volume, by ensuring a certain turbulence to this fluid then in heat exchange with said elements that store and release energy. These baffles can, in particular, impose on the fluid, in the store/exchanger, a circulation path which will weave, such as a zig-zag path.
Relating to what is outlined above, it is also proposed that the elements that store and release thermal energy are individualised structures that have exterior surfaces formed to keep a space between them, in which a fluid can circulate.
Even then, the implementation of these elements will facilitate (handling/storage/production/maintenance/adaptation to needs), along with the rate of heat exchanges.
Controlling the heat exchanges between the/each interior volume of the store and heat exchanger and the exterior of the device has also been considered.
Once again, to be able to control the expected efficiency of the heat exchanges, internal to the device, in particular, within the/each interior volume, it is recommended:
The thermally-insulating material of the second layer will not, therefore, be a PCM, but an insulator, such as a glass wool, a porous insulator, a polyurethane or polyisocyanurate foam, or even more favourably, a porous thermally-insulating material arranged in a vacuum chamber, to define at least one vacuum insulation panel, VIP.
Also, it is proposed that the thermally-insulating material is porous and that at least the second layer containing this thermally-insulating material is contained in an envelope sealed to said material and airtight, such that with an air gap being created in said material, a VIP panel is constituted.
The thermally-insulating material of the second layer will have a lower thermal conductivity than the PCM.
With a VIP (vacuum insulation panel), the efficiency of the heat management will be optimised, even the whole weight decreased in relation to another insulator.
By “VIP”, this means a vacuum partial air structure (internal pressure between 10 and 104 Pa) containing at least one thermally-insulating material, porous in principle.
“Porous” here will mean a material that has gaps enabling air to pass. Porous materials, with open cells, therefore include foams, but also fibrous materials (such as glass wool or rock wool). The passage gaps that can be qualified as pores are smaller than 1 or 2 mm, and preferably smaller than 1 micron, and more preferably, smaller than 10−9 m (nanoporous structure), for specific questions regarding ageing and therefore, possibly weaker depression in the VIP envelope.
Actually, the VIP panels used will preferably be thermal insulators, in which porous material cores, for example, a silica gel or silicic acid powder (SiO2), will be able to have been flattened and each surrounded, under vacuum, by a gas-tight surrounding sheet, for example, made from a plastic and/or laminated aluminium material. The gap obtained, with a residual pressure which can be less than 1 mbar, will enable to favourably lower the thermal conductivity to less than around 0.015/0.020 W/(m·K) under conditions of use.
Yet, in at least some applications or functioning applications to be anticipated, it can be necessary to reach a thermal insulation efficiency via said “second layer”, in particular superior to that of more conventional insulating materials, such as those mentioned above. Typically, a thermal conductivity λ of less than 0.008/0.01 W/m·K can be expected.
Concerning these VIP panels, it has further been noted that in addition, they do not seem to meet the market expectations up to now. In particular, their implementations in the field is a problem, in particular, their processing.
Also, it is proposed:
Countersinking the first and second layers in the polymer material should be considered as a favourable solution.
Regarding this thermal management around the internal volume(s), in which the storage and heat exchanges are carried out between said elements housed there and the fluid circulating along them, it is proposed, for the reasons stated below:
The first option will enable to individualise the thermal management of the store and heat exchanger and to adapt the base solution more easily, here presented in the current industrial environment of clients, with their immediate bulk limitations, of producing structures surrounding or completing the present device.
The second option will facilitate the modularity and a mainly series production of the store and heat exchanger and therefore the longer-term development of the solution stated here.
In addition to the device which has just been presented, here in particular, two industrial applications are concerned (although not exclusively):
In the first application, the circuit mentioned above is a circuit for cooling, by a heat transfer liquid, such as water, an engine in a vehicle, the circuit comprising a liquid circulation path and, arranged on the path:
In this case, it can be useful, in a developed version, that in the protective casing, a connection column for the fluid, extends outside of the modules and is equipped with valves.
Thus, modularity, rate efficiency and industrial production will be associated mainly in series of the store/exchanger, with the first option and therefore the longer-term development of said second solution stated here.
In the second application, a thermal device is proposed, to respond to the problems above, therefore for a refrigerant or heat transfer fluid, the device comprising a circulation circuit, in which a fluid circulates over time at different temperatures, and which, on a vehicle engine, is a lubrication circuit whereon are arranged, in fluid communication, functional components of the engine to be lubricated, a lubricant crankcase (engine sump) and a thermal store and heat exchanger, which includes:
Favourably:
Thus, a single structure will be created to be directly returned under the engine block.
But, as explained later, there can be problems with bulk or volume imposed by a manufacturer.
That is why, it can advantageously be provided:
Such a volume V2/V1 ratio, typically between 1.1 and 1.5, associated with the baffling and the peripheral thermal management provided will enable the aim to be achieved, for example, during an engine restart of a car, reheating the engine lubricant in a few minutes, to a temperature higher than 15° C. while the outside temperature is very cold, for example, −5 to −10° C., and while the vehicle has been stopped, sitting at this temperature, for example, for 6 to 8 hours, even 10 to 12 hours.
If necessary, the different aspects of the invention will be best understood and other characteristics, details and advantages of it will again appear upon reading the description will follows, produced as a non-exhaustive example and in reference to the appended drawings wherein:
and
The diagram in
The device 1 comprises:
The store and heat exchanger (or unit that stores and releases energy) 10 is a unit which will store thermal energy through phase change(s) of at least one PCM, then later, release a part at least of this energy through new phase change(s) (at least some) of this/these PCM(s).
The store and heat exchanger 10 therefore encloses an interior volume 7, in which the fluid 9 circulates and in which are arranged elements 13 having PCM that store and release thermal energy, and which are in contact with the fluid, for heat exchanges.
The interior volume 7 of the store and heat exchanger is provided with baffles. To define them, the store and heat exchanger 9 can have, on the fluid path, a series of partitions 29, as in
The fluid 9 circulating in and between the (sub)volumes can be liquid (water, oil) or gaseous (such as air).
So that the figures are legible,
Each module 3 is constituted by a lateral peripheral wall 5 that completes the bored base 29.
Each transversal wall 29 and the crossing passage 30 thereof, thus form a decelerator to the free circulation of the fluid between the inlet 33 thereof and the outlet 35 thereof. Preferably, two successive passages 30 will be laterally offset as schematised. Opposite the base, each module is open, in 31, such that, exiting a passage 30, the fluid arrives directly in the interior volume of the adjacent module. The circulation in the store/exchanger, between the sub-volumes, can be in series or in parallel.
In the variant in
In each case, as constituting the elements 13, a rubber composition such as defined in EP2690137 or in EP2690141 can be provided, namely in the second case, a crosslinked composition with the basis of at least one “RTV” (room temperature vulcanisation) silicone elastomer and comprising at least one phase change material (PCM), said at least one silicone elastomer having a viscosity measured at 25° C. according to the standard ISO 3219 which is less than or equal to 5000 mPa·s.
In this composition, the elastomer matrix will mainly be constituted of one or several “RTV” silicone elastomers. The thermal phase change material (PCM) can be constituted of n-hexadecane, or of a lithium salt, all having melting points of less than 40° C.
As an alternative, the PCM of the elements 13 could be fatty acid-based, paraffin-based, or eutectic or hydrated salt-based, or even fatty alcohol-based, for example.
In particular, for ease with implementing and optimising exchange surfaces, the elements 13 are here presented as individualised structures that have exterior surfaces, here convex, formed to keep a space 130 between them, in which the fluid can circulate (see
A very favourable solution is thus that these elements 13 are presented as beads. Spherical beads are favoured in the preferred example illustrated. The elements 13 could have crossing passages (bored beads, for example).
In principle, individualised structures 13, here these beads of spheres, will be arranged loosely in the sub-volumes, such as 7a, 7b, etc.
An active thermal barrier (15/23) will favourably ensure a thermal insulation of the store and heat exchanger 10 against the outside.
This active thermal barrier will either be integrated to the lateral peripheral wall 5 (as in
In principle, the second layer 23 will be, there where the two layers exist and if only two such layers exist, arranged around the first layer 15. Thus, it can be arranged such that an excessively cold or hot outside temperature only slightly interferes with that in the volume(s) 7, the first layer 15 acting as an accumulator/delayer in variation of the temperature in this/these volume(s) and within the fluid.
In order to optimise this process, it is recommended that the active thermal barrier comprises at least one VIP panel forming a pocket 19 in a controlled atmosphere, in which will be arranged at least the second layer 23, it will preferably coexist with the PCM layer 15 within the sealed envelope 37.
The second layer 23 will favourably be a porous, thermally-insulating material, against which the envelope 37 will be sealed. Once the air gap is created in the envelope, a VIP panel will be constituted.
The thermally-insulating material 23 will favourably be composed of a nanostructure material, such as a silica powder or an aerogel, confined in a deformable or conformable sheet which will not let water vapour or gases pass through. The VIP obtained will be emptied of the air thereof to obtain, for example, a pressure of a few millibars, then it can be sealed. Typically, the thermal conductivity A of such a VIP will be 0.004/0.008 W/m·K. Using vacuum insultation panels should enable a thermal resistance R=5 m2·K/W to be achieved, with only 20 to 30 mm of insulator.
The example could be applied here, of VIP panels and superinsulation materials, which are supplied in PCT/FR2014/050267 and in WO2014060906 (porous material), respectively.
The solutions presented above must enable, in an acceptable volume and weight, in particular by aircraft or automotive manufacturers, a quick storage of thermal energy available after around 6-10 minutes, maintaining this energy for 12 to 15 hours, before the quick release thereof, typically for a few minutes (in particular, less than 2/3 minutes), for example, to an engine during a cold start phase.
It is also recommended that thus designed, the store/exchangers 10 will favourably meet the need to introduce size parameters such as RTD (resident time distribution) in the blocks and NTU (number of transfer units/blocks) to facilitate a change in scale without modifying the thermal and hydrodynamic elements obtained during a qualification. With an identical reproduction of a flow in volumes 7a, 7b, etc. of different sizes being impossible, except for breaking down a total volume into identical sub-elements, the solutions above can enable to consider without the effects in scales of identical PCM loading and unloading kinetics.
To complete their fulfilment,
Like in the embodiments illustrated, each body 3 will favourably be one-piece. It can be made from plastic, metal (stainless steel, aluminium) or composite, in particular. A moulded production will be preferred. In this case, it is provided that the peripheral wall 5 contains a mouldable polymer material (for example, a polyamide or a poly(p-phenylene sulphide, fibre-charged or not), in which the first and/or second layers 15, 23 can be integrated, as provided in the embodiment in
The reference to a body made from mouldable material covers thermoplastic resins that are fibre-charged and injected, and also thermosetting resins, impregnating a fabric or a material, such as a woven or non-woven fabric.
Integrated or not in the wall of the components 3, at least the second insulating layer 23, and preferably the two layers 15/23, will favourably be vacuum surrounded in one or several pockets 19 therefore known here as “VIP-constituted” (being specified that the partial gap could be replaced by a “controlled atmosphere”: the volume would be filled by a gas that has a thermal conductivity of less than that of ambient air, 26 mW/m·K).
In this regard, pockets, structurally separate from each other, as in
In
Even if one single PCM (based) layer 15 is represented as in
Each pocket 19 comprises:
The sheet(s) or film(s) 49 and 53 can typically be made as a multilayer film comprising polymer films (PE and PET) and aluminium in laminated form, for example (sheet that is around ten micrometres thick) or metal form (vacuum deposit of a film that is a few dozen nanometres thick).
Two examples of application will now be given, in line with
Thus, a vehicle 60, such as a car, can be seen in
In the two cases, the circuit 300 defines a path for circulating a fluid whereon are arranged, in fluid communication with each other, an oil crankcase 74 and functional components of the engine to be oiled, such as connecting-rod bearings and crankshaft bearings, but also the camshaft and the drive device 76 thereof. The crankcase 74, of which the tank (metal, in principle) is screwed under the engine block 720, with a seal, contains the oil necessary to lubricate the mobile elements of the bottom-engine and the top-engine. Oil is drawn here by the suction strainer of the oil pump 78 which distributes it under pressure, preferably via an oil filter, to the different components (crankshaft, connecting rods, camshaft, etc.). The oil can then sink simply through gravity; arrows 80.
In the version in
In the second assembly, schematised in
In
The store and heat exchanger is almost that of
Laterally all around, but also under and above it, via, for example, crankcase covers such as that 32 with a single or multiple pocket(s) and VIP-constituted 34 (as in
In principle, the internal volume of the crankcase 74 will be fixed by the manufacturer of the vehicle.
Yet, producing a vehicle lubricant tank which could enable to heat the lubricant while the outside temperature is very cold, for example, −5 to −10° C., and while the vehicle has been stopped, sitting at this temperature, for example, for 6 to 8 hours, was a challenge.
A solution has been given here, by providing both, favourably, and as schematised in
In particular, during an engine start, the PCM(s) of said elements 13 will thus still be hot: they will have kept the latent heat coming from the end of the previous functioning of the engine block provided from said lubricant crankcase. The first lubricant volume (V1) will therefore be hotter than the second (V2), by heat exchange with the elements 13 immersed in it.
But, the second exterior lubricant volume (V2) being constructed bigger than the first volume (V1), it has been chosen to multiply and extend the fluid/PCM exchange zones, from there the baffles 12 via an internal partitioning which is schematised in
In this way, at the time of starting a new cycle (after stopping mentioned above by cold time), by progressive mixing via circulation in the circuit, the total lubricant in circulation (V1+V2) can quickly be hot throughout, with advantages in terms of rate of the engine to be lubricated and limitation of pollutants.
In the enlarged extract in
In
The circuit comprises a path 4 for circulating the liquid and, arranged on the path:
The term radiator includes:
In addition, two assemblies of the circuit are possible:
With the assembly in
With the assembly in
Preferably, the physical parameter to choose in the unit 10 and the radiator to control the loading of thermal units, more or less quickly or completely from the unit 10 will be a temperature in the radiator 8, preferably an exit temperature.
And, favourably, in nominal functioning, the first valve 14 will distribute, between the radiator 8 and said second branch 22, the circulation of the liquid exiting the engine according to temperature data connected to the radiator. A temperature sensor 26 is provided for this (
Furthermore, in nominal functioning, if a power problem occurs on the radiator 8 due to a thermal overload detected by a temperature sensor (such as the sensor 26), the fourth valve 20 will close and the third valve 18 will open, to ensure a circulation of liquid in the unit 10 (via the first branch 12) after passing into the radiator (
Then (see
Concerning the thermal efficiency of the unit 10 in one of the circuits, it will again be noted that the/each unit module can be thermally-insulated from the outside (EXT) by the barrier complex 15/23 favourably comprising an aerogel VIP 23 of thermal conductivity equal to 6-8 mW/mK at 25° C., 15-20 mm thick surrounding an elastomer-based layer 15 loaded with 80-90% by PCM mass, enthalpically microencapsulated equal to 200-240 kJ/kg, 2.5-5.5 mm thick. The initial quantity of stored energy of 1.5-2 MJ for the oil can be maintained with a SOC (state of charge) at 65-75% above 15 hours, thus enabling the release of very efficient new energy. This energy can be released in less than 2/3 minutes to maximise the reduction of CO2 emission in the case of a cold start of the engine, for example.
Regarding
All the superimposed modules 3 (even as here, the functionalised column 88 arranged opposite them), without therefore interfering with their internal volumes, are surrounded by the peripheral wall 500 of a protective casing 96 containing or lined inside, on all faces of the casing and almost continually, for the thermal management complex 15/23 having PCM and VIP pockets in a controlled atmosphere, 19 or 50.
Number | Date | Country | Kind |
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1557837 | Aug 2015 | FR | national |
This application is a national stage International Application No. PCT/FR2016/052094, filed Aug. 19, 2016, which claims the benefit of French Patent Application 1557837, filed Aug. 20, 2015, the contents of each of which are incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/FR2016/052094 | 8/19/2016 | WO | 00 |