The present invention relates to a method and a plant for capturing CO2 that may be implemented on an existing gas turbine power plant. The invention also relates to a gas turbine power plant including the inventive CO2 capturing, or CO2 abatement, plant.
The last years, or the last decade, the increasing concentration of CO2 in the atmosphere due to increased combustion of fossil fuel, has caused great concern. The increased greenhouse effect caused by the increasing concentration of CO2 is expected to cause a substantial temperature increase at the planet earth and an enormous environmental impact in the next few decades.
Actions therefore have to be taken to stabilize the CO2 concentration in the atmosphere. A substantial part of the man made CO2 emission is a result of power generation from oil, gas or coal. Accordingly, substantial efforts have been made to develop thermal power plants including capturing of CO2. Captured CO2 may be safely deposited into geological formations such as e.g. depleted oil or gas wells, or may be used as pressure support for increasing the production of oil or gas.
The suggestions for CO2 capture mainly follow three lines of development:
Much effort has been done on post-combustion absorption of CO2, both due to the fact that this technology is most developed and that the degree of integration with the power plant is small. Post combustion systems may be implemented on existing plants.
The very low partial pressure of CO2 in the exhaust gas from a thermal power plant is, however, a major problem in making the CO2 capture economically acceptable. Absorbers become much larger than can be guaranteed with current technology, impeding the absorbent distribution in the absorber column and thus reducing the absorption efficiency. Additionally, the residual O2 concentration in the exhaust gas of most fossil fuel based thermal power plants is relatively high. This causes degradation problems for the required organic absorbent in the CO2 capturing system and, depending on the absorbent selectivity, potential contamination of the CO2 product.
Pre-combustion conversion of fossil fuel to hydrogen is attractive because the reforming products are pressurized with high concentration of CO2. The CO2 is therefore much easier to capture than in post combustion systems. Conventional pressurized absorption columns may be employed. Disadvantages with the process include very complex processes for coal gasification, and the need to develop gas turbines for hydrogen fuel.
Similar to the pre-combustion conversion of fossil fuel, oxy-fuel systems produce relatively high partial pressures of CO2. The CO2 therefore becomes much easier to capture than for post combustion systems. Disadvantages with the system include the need for very large and expensive air separation units, high energy requirement for oxygen production, and the new technologies required to use CO2 instead of nitrogen to cool flame temperatures. New gas turbines are also required when CO2 replaces nitrogen in the motive fluid. Risks of leaks and fire involving pure oxygen from the oxygen production unit will require large spatial separation between the oxygen plant and the power plant. This requirement increases the total area needed and will in particular increase the cost of offshore applications. Furthermore, the produced CO2 will contain unburned oxygen. This oxygen must be separated from the CO2 prior to for example injection in oil fields for enhanced oil recovery.
WO 2004/001301, which is included as reference in the present application, relates to a low CO2 emission thermal power plant. CO2 is absorbed from the combustion gas from a combustion chamber in an absorber, wherein a liquid absorbent flows countercurrent to the combustion gas. This enriches the absorbent in CO2. The rich absorbent is regenerated by heating and stripping in a regeneration column by countercurrent flow to steam generated in a reboiler connected to the lower part of the regeneration column, to produce a stream of CO2 that is exported from the plant for deposition, and regenerated absorbent that is returned to the absorber. The partial pressure of CO2 is increased and the volume flow of flue gas to be purified is decreased, relative to the power produced, by substantially complete combustion of both oxygen and fuel in a pressurized combustion chamber. This improves the capture of CO2, which occurs at high pressure. WO 2004/001301 is, however, suitable either for thermal power plants having a pressurised combustion chamber for production of steam, or for new plants.
WO 2005/045316 relates to a purification works for a thermal power plant, where the combustion gas from an existing thermal power plant is used as all, or a substantial part of, the oxygen containing gas that is introduced into a plant built at the basic principle of WO 2004/001301, to capture the CO2 from both plants and increase the total production of electrical power, at the same time. A highly efficient gas turbine is used as a primary power plant. Air is first compressed in a primary power plant compressor, then heated and expanded to atmospheric pressure. A secondary power plant provides additional power and carries out CO2 capture under pressure. The main shortcoming of this technology is the need to re-compress the gas from the primary unit. Such re-compression requires significant work and causes loss of thermal efficiency.
There is, however, need for a system which as far as possible uses the advantages of the highly efficient, high temperature gas turbines in combination with pressurized CO2 capture, without the need to re-compress gas from atmospheric pressure.
An objective is therefore to provide an improved method and plant for capturing CO2 from a gas turbine. It is also an objective to provide solution that is suitable for post-installation for an existing gas turbine or combined cycle power plant.
According to a first embodiment, the present invention relates a method for separation of CO2 from the combustion gas of a gas turbine where carbonaceous fuel and compressed oxygen containing gas are combusted, and the combustion gas is expanded over a turbine to produce electrical power in a generator before the expanded combustion gas is released into the atmosphere, the method additionally comprises the steps of:
Withdrawing partly expanded gas from an intermediate level of the turbine and introduction of the partly expanded, gas that are still at an elevated pressure, into the burner for a second combustion, allows for a combustion and succeeding CO2 capture at an elevated pressure. Additionally, the heat and pressure energy of the gas that is withdrawn is at least partly conserved and is used by reheating of the CO2 lean gas and expanding the same over the turbine,
According to one embodiment, the method additionally comprises the step of cooling the withdrawn combustion gas of step a) before the gas is introduced into the burner in step b). Cooling of the gas before it is introduced into to burner reduces the temperature of the flare in the burner, as the flare otherwise may become too hot and produce high levels of NOx. Additionally high temperatures may result in problems related to the materials of the components of the plant.
The secondary combustion in the burner adds mass to the total gas flow to substitute the mass of CO2 that is removed from the total mass of gas. Performing this combustion and the CO2 capture downstream of the burner reduces the oxygen level in the gas and increases the CO2 level, which both are important for the efficiency of the capturing process. Re-heating of the CO2 depleted gas and expanding the gas over the turbine increases the energy efficiency of the plant considerably.
According to a second aspect, the present invention relates to a plant for generation of power comprising a gas turbine, and a generator operated by the gas turbine, wherein the plant additionally comprises a gas side draw unit for withdrawal of partly expanded gas from an intermediate stage of the turbine, a burner for a secondary combustion of fuel, using the partly expanded gas and additional air as sources for oxygen, one or more heat exchanger(s) for cooling the combustion gas from the secondary combustion, CO2 separation unit for separation of the cooled combustion gas into a CO2 rich gas that is treated further and exported from the plant, and a CO2 lean gas, one or more heat exchanger(s) for reheating the CO2 lean gas, and gas a gas return line and a turbine inlet unit for introduction of the heated CO2 lean gas at an intermediate level of the turbine for further expansion.
The terms “carbonaceous fuel” or “fuel” are in the present invention used for fuel suitable for a gas turbine such as natural gas, fluid hydrocarbons and oxygenated hydrocarbons such as methanol, ethanol etc., that will be in gas phase in the combustion chamber of a gas turbine, or gasified fuels such as gasified coal, gasified coke, gasified organic materials etc.
Air is introduced into the compressor 2 through an air inlet line 3. The compressed air from the compressor 2 is introduced into a combustion chamber 8 via a compressed air line 7. Fuel, such as e.g. natural gas, is introduced into the combustion chamber through a gas line 9. Combustion gas from the combustion chamber is led through a combustion gas line 10 and is expanded over a turbine 4 before the expanded gas is released through an exhaust gas line 12.
As indicated in the figure, the compressor 2, turbine 4 and a generator 5 for production of electric power, are arranged on a common shaft 11.
The exhaust gas in the exhaust gas line 12 is still hot, typically from 500 to 600° C., and is cooled by means of one or more heat exchanger(s) 13 to produce steam and cooled exhaust gas that is released into the surroundings through an exhaust outlet 12′.
The steam produced in the heat exchanger(s) 13 is led in a steam line 14 into a steam turbine 15 where the steam is expanded. A generator 16 is connected to the steam turbine for production of electrical power.
The expanded steam is led in an expanded steam line 17, cooled on a cooler 18, suitably against water, to condense the steam. The condensate is pumped by means of a pump 19 trough a water line 20 and is reintroduced into the heat exchanger(s) 13.
Typically, about 75 to 80% of the electrical power from a combined cycle power plant is generated in the generator 5 operated by the turbine 4 and the rest in generator 16, operated by the steam turbine 15.
Parts corresponding to parts described with reference to
The turbine 4 normally comprises a high pressure turbine 4′ and a low pressure turbine 4″. According to the present invention, partly expanded combustion gas is withdrawn from the turbine at an intermediate level of expansion, suitably between the high pressure 4′ and low pressure 4″ turbines, into a gas withdrawal line 20. A gas side draw unit 21 is preferably inserted at the shaft 11, after the high pressure turbine to facilitate the withdrawal of the partly expanded gas. The pressure at the point of gas withdrawal is for example in the range from 6 to 16 bara, such as 10 to 14 bara.
The partly expanded gas in line 20 is combined with pressurized and heated air and introduced into a cooling chamber, where the combined gas is cooled by heating steam and/or generating of steam in a heating tube 22 in a primary cooling chamber 23. The gas mixture entering the cooling chamber has a temperature of about 1000° C. and is cooled therein to a temperature of about 400 to 500° C. The combined and cooled gas in cooling chamber 23 is then introduced to a secondary cooling chamber 24 through a burner 25 where the combined gas is mixed with fuel gas that is introduced through a secondary fuel line 26. Air enters through an air supply line 52 and is compressed in a compressor 53 operated by means of an electric motor 54.
The compressed air is supplied through lines 55 and 55a and used to protect pipes 20 and 39 and to cool the pressure container 50, before flowing to the secondary burner for firing purposes. Some of the air is supplied through line 55b and routed directly to combustor 25. The total amount of air from compressor 53 is adjusted relative to the captured CO2 withdrawn in line 34, so that the volume flow of gas to the gas turbine through line 39 is the same as, or very close to, the volume flow of gas withdrawn from the gas turbine through line 20. The fuel introduced into the secondary burner is adjusted so that the combustion in the secondary combustion chamber 24 is substantially complete, both with regard to oxygen and fuel.
The combustion gases in the secondary cooling chamber are cooled by heating gas in a gas heating tube 27 and by superheating of steam from the heating tube 22 in a superheater tube 28. Heating tube 22 is connected to superheating tube 28 though a line 14a. The superheated steam in the superheating tube 28 is withdrawn through a line 14b and introduced into steam turbine 15 to produce electrical energy, condensed and returned to the heat exchanger 13 as described above with reference to
Exhaust gas from the secondary cooling chamber 24 is withdrawn through an exhaust line 29 and is cooled in a heat exchange assembly 30. Preferably a SCR (Selective Catalytic Reduction unit) or SNCR (Selective Non-Catalytic Reduction unit) 31 is provided in the heat exchange assembly 30 to remove NOx from the exhaust gas.
The cooled gas from the heat exchange assembly 30 is withdrawn through a line 32 and introduced into a CO2 separation unit 33. The CO2 separation unit 33 is a standard unit according to the state of the art, e.g. a separation unit as described in WO 00/57990, where CO2 in the CO2 containing gas is absorbed by countercurrent flow to a liquid absorbent in an absorber to produce a CO2 lean stream that is withdrawn through a line 35. The CO2 loaded absorbent is thereafter regenerated to produce a stream of CO2 that is dried and compressed and is withdrawn through line 34 for export from the plant, and regenerated absorbent that is returned to the absorber. The absorbent may be any conventionally used absorbent, such as aqueous solutions of amines, amino acids, carbonates etc. The CO2 capture unit may also include gas scrubbing and a direct contact gas cooler upstream of the CO2 capture unit.
A pressurized mantle 41 is preferably covering the high pressure and high temperature lines 20, 39. The mantle surrounding lines 20 and 39 is pressurized using air from a branch line 55a dividing from the compressed air line 55. The mantle reduces the pressure difference across the hot inner pipe wall, thus reducing the wall thickness and possibilities for cracks during temperature transients. Heated air from inside the mantle 41 is led from the mantle 41 to the mantle 50 through a line 42.
If necessary, additional air for the combustion in the secondary combustion chamber may be introduced through a second branch line 55b dividing from the compressed air line 55, to deliver additional air to the burner 25. This additional air has higher oxygen content than the air in line 20, and will stabilize the flame in one or more of the burners 25.
The CO2 lean stream in line 35 is compressed in one or more compressor(s) 36 operated by motor(s) 37, and is thereafter heated in the heat exchange assembly 30 towards the warm gas that is introduced through line 29. The heated CO2 lean stream leaves the heat exchange assembly through a line 38 leading to the gas heating tube 27, where the gas is heated by the combustion gases from burner 25. The CO2 lean gas leaves the gas heating tube 27 and is introduced into a gas return line 39 that is connected to a turbine inlet device 40 that is arranged on the shaft 11. The gas introduced to the inlet device 40 is then expanded over the low pressure turbine 4″ and released into the exhaust gas line 12 as described with reference to
Closing valves 45, 46 on lines 20, 39 respectively, and a shortcut line 43 with a shortcut valve 44, are preferably provided to close line 20 and 39 and to allow the flow from the gas side draw unit 21 to flow directly into the gas inlet device 40 if necessary.
To balance the turbine correctly, the pressure, temperature and flow of the gas leaving the high pressure turbine 4′ through line 20 should substantially be the same as the pressure, temperature and flow of the gas entering the low pressure turbine 4″. The combustion in the secondary cooling chamber 24 adds temperature to the total gas, and especially to the CO2 lean stream in line 38, and adds mass to the total gas to at least party compensate for the mass loss due to the removal of CO2. Additionally, heat is added to the steam cycle making it possible to increase the power production from the plant compared with the exemplary combined cycle plant according to
Table 1 illustrates typical temperatures, mass flow and pressure, in addition to produced or consumed power for a typical combined cycle plant producing about 500 MW electrical power according to
12′
Table 2 illustrates typical temperatures, mass flow and pressure, in addition to produced or consumed power for a typical plant with CO2 capture according to the present invention, based on the combined cycle plant illustrated in table 1.
12′
Number | Date | Country | Kind |
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20081051 | Feb 2008 | NO | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/NO2009/000066 | 2/26/2009 | WO | 00 | 11/30/2010 |