Patent Application
20050025896
The invention relates to a method of thermal spraying a stream of high melting point metal onto an low heat resistant substrate, such as wood, plastic, foam, rapid prototype and similar materials. The metal-adhesive process can be used to metalize parts and other articles for various applications.
Examples of thermal spray methods that are useful for producing metal coated parts are arc wire spray, flame spray, HVOF, plasma spray, D-gun, cold spray and the like. Generally a method used to apply a metal coating on a low temperature substrate consists of applying a layer of metal filled epoxy to the substrate then machining the epoxy and then applying a thermal spray material. This method is time consuming and can leave defects in the surface. Other alternatives for this problem are vacuum metalizing, metal sleeves, covers or electroplating.
The use of zinc alloy has been sprayed on such low heat resistant materials, however, the resulting tool formed is relatively soft. It is known that pseudo-alloy can be thermally sprayed on low heat resistant materials such as wood, plastic and the like to produce a tool that is relatively hard compared to zinc layered low heat resistant materials.
Thermal metal spray requires a large energy input, which is typically manifest as heat energy, to moltenize and make the metal sprayable. Because of the high temperature of the metal when it strikes the substrate (part/component), the substrate has typically been required to be constructed from high heat material, such as metal or ceramic, in order to survive the spraying of such molten metal.
It is an object of the present invention to provide a new process for spraying metal directly on a low heat resistant substrate thereby eliminating the conventional multi-step process using metal filled epoxy applied before the thermal spray process or using high temperature substrates or plating or vacuum metalizing.
In at least one embodiment, the present invention relates to a method for applying a high melting point thermal spray material onto a substrate having a distortion temperature below the temperature of the hot coating material at the surface of the substrate comprising:
Preferably, for most applications, after step (a) a layer of a bonding material, such as zinc, copper, nickel, chrome, molybdenum, aluminum, compounds thereof and alloys thereof, is applied to the adhesive promoter layered substrate to increase the bonding and increase the adhesive characteristics of the material in step (b). The adhesive promoter should be a material that has an adequate thermal and chemical characteristics that are compatible with the sprayed material and not effectively reduce surface contour and details of the low heat resistant substrate. For other applications, the adhesive promoter may be a release agent so that the substrate can be removed from the metal sprayed deposit. Suitable adhesive and release agents can be selected from the group comprising epoxies, silicones, urethanes, cyanoacrylates, polyvinyl acetate (PVA) and the like. Suitable solvents can be used to create a better tacky surface. The preferred adhesives are polyurethane, polyvinyl acetate (PVA) and, epoxies. For most applications, the thickness of the adhesive layer can vary between 0.0001 inch and 0.020 inch, preferably between 0.0005 inch 0.005 inch. The bonding layer, if required, is applied to provide better adhesion and increase the bonding for the thermal spray material. The thermal spray material can be applied with a high gun-to-substrate linear velocity to balance the thermal input to the substrate. High linear velocity will create thin low stress layers. Typically the linear velocity is greater than 0.5 m/s or a power input factor from 0.5 to 45 watts/mm. The lower the melting point of the substrate will require the linear speed of the spray to be increased. The thickness of the coated layers could be between 00001 inch and 1.0 inch, preferably between 0001 inch and 002 inch. The material of the coated layer is preferably metal and can be selected from the group consisting of nickel, steel, stainless steel, chrome, tungten, aluminum, alloys thereof, pseudoalloys thereof, and compounds thereof.
In preferred applications, the adhesive promoter material would not be a release agent but have good adhesive characteristics that would bond and secure the outer spray layer to provide a finish article. For example, the finish article could be selected from the group comprising printing polls (ucarlox), aircraft skins, electronic circuit boards, any plastic or composite part exposed to wear or erosion.
Essentially, almost any metal or alloy which can be made into wire can be arc wire sprayed, including steels, nickel, copper and aluminum. From a practical standpoint, the current spray metal process utilizes zinc. Materials with melting points higher than this (770° F. or 410° C.) overheat most conventional substrates and distort, crack or warp upon application. Zinc, on the other hand, when applied, has unique characteristics which reproduce the substrate surface exactly, has low shrinkage or warpage, maintains a temperature warm to the touch, and can be applied at rates up to five square feet of pattern per hour. If a softer surface is produced (melting point 400° F. or 204° C.) then in some cases this could limit the application to which the part can be used, especially where higher temperatures and pressures are required.
The Arc Wire Spray gun is similar in size and appearance to those used for paint spraying. Wires are fed automatically. Although metal particles impacting the surface are in a molten state, a significant characteristic is that the substrate undergoes only a small temperature rise. The system is very simple to use, 3 KVA of power and 35 cfm of 80 psi compressed air are supplied to preset automatic controls which essentially eliminate operator judgment relative to spraying parameters. Once the electric system is energized only one button is pushed to start and stop the preset rate of wire feed. The power supply automatically maintains the proper wire intersection geometry by maintaining the arc voltage constant to give a consistent controllable spray jet with a cone diameter of approximately three inches at an eight-inch standoff distance. All systems are generally made up of modular units which can be interchanged in a number of permutations and combinations. A system can be simply altered on a tailor-made basis to provide optimal coatings with any material of interest. When making a sprayed metal layer the Arc Wire Spray gun can operate in the range of 25 to 1500 amps at 20 to 40 volts. The spray rate depends on amperage, which is essentially power, since the voltage is constant. When spraying small pieces, or when starting (to achieve the best surface texture) high pressures are used. The constant voltage power supply automatically increases or decreases the amperage to track wire feed rate, thereby, keeping wire tip melt geometry constant. The wires tend to move closer together when the wire feed rate is increased. This feature maintains a constant atomization characteristic and a uniform metal particle size distribution and spray pattern. The spray rate can be measured by reading the amperage. At 100 amps, 20 lbs/hr of zinc is melted, as the amperage is increased or decreased proportionately more or less is melted.
The invention will be described with reference to the accompanying drawing which is a cross-section view showing a composite printing roll with high melting point metal. The spray metal thickness for printing rolls can preferably be from 0.0001 to 1.0 inch.
As shown in the drawing, the basic steps of the method comprise:
For better adhesive for the top coat, a bonding material can be deposited over the adhesive layer. Preferably the thickness of the bonding material (layer) is between about 0.0005 inch ands about 0.050 inch and more preferably about 0.005 inch. Preferably the bonding material is selected from the group comprising zinc, nickel, steel, chromium, aluminum and alloys of such materials.
Zinc is the preferred material because of its melting point, expansion characteristics, hardness and cost. If the zinc surface, as produced, is not compatible with the application, nickel or aluminum can be used to improve adhesion in some applications.
Other variations of the disclosed method are within the intended scope of this invention as claimed below. As previously stated, detailed embodiments of the present invention are disclosed herein; however, it is to be understood that disclosed embodiments are merely exemplary of the invention that may be embodied in various forms.
