This application claims the benefit of Japanese Priority Patent Application JP 2022-023668 filed on Feb. 18, 2022, the entire contents of which are incorporated herein by reference.
The present disclosure relates to a thermal spraying apparatus, a method of detecting a molten adhered substance in the thermal spraying apparatus, and an electrode for the thermal spraying apparatus.
A thermal spraying apparatus forms a film on a target by thermally spraying a powder by plasma generated between electrodes. When the powder is thermally sprayed, a melt may adhere to the electrodes.
One object of the present disclosure is to provide a thermal spraying apparatus capable of detecting adhesion of a melt of a conductive powder at an early stage, a method capable of detecting adhesion of a melt of a conductive powder at an early stage in the thermal spraying apparatus, and an electrode for the thermal spraying apparatus capable of shortening a maintenance time of the thermal spraying apparatus even when the melt adheres.
According to one aspect,
provided is a thermal spraying apparatus that forms a film on a target by thermally spraying a conductive powder by plasma, the thermal spraying apparatus including:
a first electrode provided with a first cavity through which the conductive powder from a powder supplier passes; and
a second electrode provided with a second cavity through which the conductive powder from the first electrode passes,
in which the plasma is generated between the first electrode and the second electrode,
the second electrode includes:
an electrode body; and
a muzzle portion provided with the second cavity through which the conductive powder from the first electrode passes, the muzzle portion being attachable to and detachable from the electrode body,
the muzzle portion includes:
one or more insulating members; and
a plurality of conductive members insulated from each other by the one or more insulating members, and
the thermal spraying apparatus includes an adhered substance detector that detects adhesion of a melt of the conductive powder according to whether or not two or more conductive members among the plurality of conductive members are conductive.
The electrode body may be provided with a third cavity into which the muzzle portion is fitted, and
the muzzle portion may be detachably fitted into the third cavity.
A screw hole penetrating from an outer surface of the electrode body to an inner surface of the third cavity may be provided, and
the muzzle portion fitted into the third cavity of the electrode body through the screw hole may be screwed.
A female screw may be provided on the inner surface of the third cavity, and
a male screw may be provided on a side surface of the muzzle portion.
The muzzle portion may include:
a fitting portion provided with the male screw; and
a sensor attached to a lower end surface of the fitting portion, the sensor including the one or more insulating members and the plurality of conductive members.
A distal end surface of the muzzle portion may have an annular shape, and the distal end surface may include:
the plurality of insulating members extending in a radial direction from an inner periphery to an outer periphery of the distal end surface; and
the plurality of conductive members provided between the plurality of insulating members.
A distal end surface of the muzzle portion may have an annular shape, and the distal end surface may include:
an annular portion that is one of the plurality of conductive members and is provided with a recess on an inner peripheral surface;
an electrode portion that is another conductive member among the plurality of conductive members and is provided within the recess; and
the one or more insulating members provided within the recess so as to insulate the annular portion and the electrode portion from each other.
The conductive members may include copper, tungsten, or tantalum, and
the one or more insulating members may include ceramic.
According to another aspect,
provided is a method of detecting adhesion of a melt of a conductive powder to an electrode for a thermal spraying apparatus,
the electrode including:
an electrode body; and
a muzzle portion attachable to and detachable from the electrode body,
the muzzle portion including:
an insulating member; and
a plurality of conductive members insulated from each other by the insulating member,
the molten adhered substance detecting method including
detecting adhesion of the melt of the conductive powder depending on whether or not two or more conductive members among the plurality of conductive members are conductive.
According to another aspect,
provided is an electrode for a thermal spraying apparatus, the electrode including:
an electrode body; and
a muzzle portion attachable to and detachable from the electrode body,
in which the muzzle portion includes:
an insulating member; and
a plurality of conductive members insulated from each other by the insulating member.
The adhesion of the melt of the conductive powder can be detected early. Furthermore, even when the melt adheres, the maintenance time of the thermal spraying apparatus can be shortened.
Hereinafter, embodiments according to the present disclosure will be specifically described with reference to the drawings.
The powder conveyance gas supplier 1 supplies a powder conveyance gas to the powder feeder 2. The powder conveyance gas is, for example, argon or nitrogen, and may be the same as or different from a plasma generation support gas described later.
The powder feeder 2 supplies the conductive powder using the powder conveyance gas. A material derived from the conductive powder is deposited on the target T. As an example, the conductive powder is a copper powder, and a copper thin film is formed on the target T.
The thermal spraying nozzle 3 is also called a thermal spray gun, and melts and sprays (thermally sprays) the conductive powder to the target T. The thermal spraying nozzle 3 includes a housing 30, a cathode 31 (first electrode), and an anode 32 (second electrode).
The housing 30 houses the cathode 31 and the anode 32. A powder guide path 21 that guides the powder from the powder feeder 2 to the cathode 31 penetrates an upper surface of the housing 30. Furthermore, an opening is provided on a lower surface of the housing 30 and faces the holder 6.
The cathode 31 is disposed on a downstream side (lower side) of the powder feeder 2. A cavity (first cavity) is formed inside the cathode 31, and the conductive powder from the powder feeder 2 passes through the cavity via the powder guide path 21.
The anode 32 is disposed downstream (below) of the cathode 31 and spaced apart from the cathode 31. A cavity (second cavity) is formed inside the anode 32. This cavity is located below the cavity of the cathode 31 and above the opening in the lower surface of the housing 30. Then, the conductive powder from the cathode 31 passes through the inside of the cavity in the anode 32. Details of the configuration of the anode 32 will be described later.
The plasma generation support gas supplier 4 supplies the plasma generation support gas into the housing 30 of the thermal spraying nozzle 3. The plasma generation support gas is, for example, argon or a gas obtained by adding hydrogen to argon.
The chamber 5 is disposed below the thermal spraying nozzle 3. An opening is provided on an upper surface of the chamber 5, and is aligned with the opening of the lower surface of the housing 30 in the thermal spraying nozzle 3. The holder 6 that holds the target T is disposed below the opening. The holder 6 is placed on an XY slider 61 (stage), and the XY slider 61 can move the holder 6 in a horizontal plane. Furthermore, the holder 6 is provided with a thermocouple 62 to monitor a temperature of the XY slider 61 and a temperature of the target T.
In particular, since the target T is destroyed by heat when the temperature of the target T becomes too high, the temperature of the target T is monitored by the thermocouple 62 so as not to reach a temperature Tmax at which the target T is destroyed. Actually, a temperature Ts lower than Tmax is set in consideration of safety, and control to stop plasma spraying is performed when the temperature of the thermocouple 62 reaches Ts. Furthermore, in a case where the film formation by plasma spraying is halfway, it is necessary to restart plasma spraying. Therefore, a reference temperature Ti for restarting the plasma spraying is set, the temperature of the target T is monitored by the thermocouple 62, and the plasma spraying is restarted when the temperature decreases to the reference temperature Ti.
The chamber 5 is connected to the pressure adjustment gas supplier 7, the exhaust pump 8, and the cooling air supplier 9 in order to appropriately control the thermal spray environment at the time of thermally spraying the melted conductive powder onto the target T. The pressure adjustment gas supplier 7 supplies a pressure adjustment gas such as argon or a gas obtained by adding hydrogen to argon into the chamber 5, and maintains a pressure in the chamber 5 at a constant value (for example, 300 Torr). The exhaust pump 8 evacuates the inside of the chamber 5. The cooling air supplier 9 supplies cooling air to a cooling plate 51 disposed in the chamber 5.
Note that the plasma generation support gas may be gas other than argon or a gas obtained by adding hydrogen to argon. For example, the gas may be a gas required for use in a process, such as neon, helium, or nitrogen.
In such a thermal spraying apparatus, a voltage is applied such that a high potential difference is generated between the cathode 31 and the anode 32 in a state where the plasma generation support gas is supplied into the housing 30 of the thermal spraying nozzle 3. As a result, arc discharge occurs between the cathode 31 and the anode 32. Plasma is generated between the cathode 31 and the anode 32 due to the arc discharge, and the conductive powder from the powder feeder 2 is melted (liquefied) by the heat. The melted conductive powder (liquid powder) is sprayed onto the target T to form a film.
Here, when the conductive powder is thermally sprayed, the melt may adhere to the anode 32. If the adhered substance is small, there is no problem. However, for example, if a large melt adheres to the cavity of the anode 32, a thermal spray amount is not stabilized, and the film thickness formed on the target T may vary. Moreover, if the melt adheres to such an extent as to close the cavity of the anode 32, thermal spraying may not be possible. In such a case, if the entire thermal spraying nozzle 3 has to be replaced, it takes time to maintain the thermal spraying apparatus.
Therefore, in the present embodiment, the adhered substance detector 10 is provided in the thermal spraying apparatus so that the adhesion of the melt of the conductive powder can be detected at an early stage. Furthermore, in the present embodiment, the anode 32 is configured such that the entire thermal spraying nozzle 3 does not need to be replaced even when the melt adheres. Details will be described below.
The anode body 320 has a columnar portion 320b whose inside is a cavity 320a (third cavity). An inner surface of the columnar portion 320b in the anode body 320 is formed of an insulating material 320c, and the other portions are formed of a conductive material such as metal to constitute an electrode.
The muzzle portion 321 is a member provided on a side opposite to the cathode 31 and having an opening portion through which plasma and molten conductive powder are ejected in the cavity 320a of the anode body 320.
The muzzle portion 321 has a substantially cylindrical shape having a cavity 321a (second cavity) inside, and is fitted into the cavity 320a of the anode body 320 (see
The muzzle portion 321 includes an insulating member 321b and a plurality of conductive members 321c insulated from each other by the insulating member 321b. In
A distal end surface 321d (In
It can also be said that each of the insulating members 321b and the conductive members 321c constitutes a part of the inner surface, a part of the outer surface, a part of the lower surface (distal end surface 321d), and a part of the upper surface of the muzzle portion 321. Note that each of the conductive members 321c of the muzzle portion 321 is insulated from the conductive material of the anode body 320 by the insulating materials 320c on the inner surface of the anode body 320.
Specifically, the adhered substance detector 10 includes a conductive wire 11 connected to each of the conductive members 321c and a tester 12 connected to the conductive wire 11 to monitor a conduction state between the conductive members 321c. Note that in
As illustrated in
On the other hand, as illustrated in
As is clear from
As described above, in the first embodiment, the anode 32 includes the anode body 320 and the muzzle portion 321 detachably attached to the anode body, and the plurality of conductive members 321c insulated from each other is provided in the muzzle portion 321. The adhered substance detector 10 that monitors the conduction between the conductive members 321c can detect the adhesion at an early stage when the melt of the conductive powder adheres across the plurality of conductive members 321c. In a case where adhesion is detected, only the muzzle portion 321 of the anode 32 may be replaced instead of the entire thermal spraying nozzle 3, and the maintenance time can be shortened.
A second embodiment to be described next is a modification example of the anode 32 in the first embodiment. Hereinafter, description of common points with the first embodiment may be omitted or simplified.
The anode body 320′ is substantially similar to that described in the first embodiment, but in the present embodiment, a female screw (not illustrated) is provided on an inner surface of the cavity 320a′ (third cavity).
The fitting portion 33 of the muzzle portion 321′ has a substantially cylindrical shape in which the inside is a cavity 33a. A male screw is provided on an upper (cathode side) side surface of the fitting portion 33. Since the fitting portion 33 is a part of the muzzle portion 321′, it can be said that a male screw is provided in the muzzle portion 321′. Then, the fitting portion 33 is screwed into the cavity 320a′ of the anode body 320′, whereby the muzzle portion 321′ is fitted into the cavity 320a′ of the anode body 320′ (see
The sensor 34 of the muzzle portion 321′ has an annular portion 341, and may have a protruding portion 342 protruding in the radial direction from an outer periphery of the annular portion 341.
An outer diameter of the annular portion 341 is substantially the same as an outer diameter of the lower end surface of the fitting portion 33 (see
The annular portion 341 has a cavity 34a (second cavity) inside (an opening is formed), and includes an insulating member 423 and a plurality of conductive members 424 insulated from each other by the insulating member 423. In
Specifically, the annular portion 341 (also referred to as a distal end surface of the muzzle portion 321′) includes a plurality of substantially rectangular insulating members 423 extending in the radial direction from a part of an inner circumference to a part of an outer circumference thereof, a plurality of annular sector conductive members 424 provided between the plurality of insulating members 423, and an insulating member 425 provided on an upper surface of the annular portion 341. It can also be said that each of the insulating members 423 and the conductive members 424 constitutes a part of the inner peripheral surface, a part of the outer peripheral surface, and a part of the lower surface of the annular portion 341, and the insulating member 425 constitutes the upper surface of the annular portion 341. Note that each of the conductive members 424 of the muzzle portion 321′ is insulated from the fitting portion 33 by the insulating member 425. Furthermore, the protruding portion 342 protrudes from each of the conductive members 424.
As described above, also in the second embodiment, the adhesion of the melt of the conductive powder can be detected at an early stage. In a case where adhesion is detected, it is sufficient to replace not the entire thermal spraying nozzle 3 but only the sensor 34 in the muzzle portion 321′ of the anode 32′, and the maintenance time can be shortened.
A third embodiment described below is another modification example of the anode 32 in the first embodiment. Hereinafter, description of common points between the first embodiment and the second embodiment may be omitted or simplified.
The muzzle portion 321″ has a substantially cylindrical shape whose inside is a cavity 321a″ (second cavity). A male screw is provided on an upper (cathode side) side surface of the muzzle portion 321″. The muzzle portion 321″ is screwed into a cavity 320a″ of the anode body 320″, whereby the muzzle portion 321″ is fitted into the cavity 320a″ of the anode body 320″ (see
The muzzle portion 321″ includes an insulating member 321b″ and a plurality of conductive members 321c″ and 322 insulated from each other by the insulating member 321b″.
As a specific example, the recess 322a has a shape in which a part of a circle is cut out. The insulating member 321b″ is a crescent-shaped sleeve. An outer periphery of the insulating member 321b″ has substantially the same size as an inner diameter of the recess 322a, and is fitted with the inner diameter of the recess 322a. The conductive member 321c″ has a shape in which a part of a circle is cut out linearly. The outer periphery of the conductive member 321c″ has substantially the same size as an inner periphery of the insulating member 321b″, and is fitted to the inner periphery of the insulating member 321b″. The insulating member 321b″ and the conductive member 321c″ in each of the recesses 322a extend to the middle or upper surface of the muzzle portion 321″. The conductive member 322 extends upward and has a columnar shape.
As described above, also in the third embodiment, the adhesion of the melt of the conductive powder can be detected at an early stage. In a case where adhesion is detected, only the muzzle portion 321″ of the anode 32″ may be replaced instead of the entire spray nozzle, and the maintenance time can be shortened.
In each of the embodiments described above, a thermal spraying system as illustrated in
Referring to
In one embodiment, in a case where the measurement result signal from the adhered substance detector 10 indicates that the conductive powder melt adheres to the muzzle portion 321, an alarm may be issued to the control panel. Furthermore, the controller 100 may determine the replacement time of the muzzle portion 321 based on the measurement result signal.
In one example, the controller 100 continuously measures the presence or absence of an adhesion substance in the muzzle portion 321, and controls an amount of applied voltage by which a high potential difference is generated between the cathode 31 and the anode 32 by a feedback loop to control an amount of melting of the conductive powder per unit time.
In one embodiment, after detecting an adhesion substance in the muzzle portion 321 for the first time, the controller 100 stops the supply of the powder conveyance gas and outputs a control signal to the powder conveyance gas supplier 1 so as to stop the thermal spraying. Then, until the second detection of the adhered substance, the controller 100 maintains an applied voltage amount that generates a high potential difference between the cathode 31 and the anode 32 so as to continue melting of the conductive powder. Then, after receiving a second detection signal of the adhered substance from the sensor, the controller 100 may stop the subsequent thermal spraying processing when the processing is continuously performed on the plurality of targets.
As a result, it is possible to distinguish between a case where the adhered substance detector 10 itself malfunctions due to a failure and a case where the adhered substance detector can correctly detect the adhesion of the melt.
In another embodiment, the controller 100 may set an allowable adhesion amount of the adhesion amount in the muzzle portion 321 in advance, determine that the thermal spraying may be continued as it is when the adhesion amount is less than or equal to the allowable value, and control the thermal spraying apparatus to continue the thermal spraying.
Note that, in each of the embodiments described above, the adhesion of the melt of the conductive powder to the muzzle portion is detected depending on whether or not two or more conductive members are conductive. As a modification example, the adhesion of the melt may be detected by a change in capacitance between the conductive members. Hereinafter, the anode 32′ (
The above-described embodiments have been described for the purpose of enabling a person having ordinary knowledge in the technical field to which the present invention belongs to implement the present invention. Various modification examples of the above embodiments can be naturally made by those skilled in the art, and the technical idea of the present invention can be applied to other embodiments. Therefore, the present invention is not limited to the described embodiments, and should be the widest scope according to the technical idea defined by the claims.
Number | Date | Country | Kind |
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2022-023668 | Feb 2022 | JP | national |