The present invention relates to a thermal type flowmeter that measures a flow by a heating resistor body installed in a fluid to be measured, and in particular, to a compact thermal type flowmeter that is suitable for measuring an exhaust gas flow and an intake air flow of an internal combustion engine of an automobile.
A thermal type air flowmeter capable of directly measuring a mass flow is mainly used as an air flowmeter that detects an intake air amount of an internal combustion engine of an automobile or the like.
Recently proposed is a thermal type air flowmeter in which a sensor element thereof is manufactured on a semiconductor substrate of silicon (Si) or the like by using MEMS technology. In such a semiconductor type sensor element, a hollow portion is formed by removing a rectangular portion of a semiconductor substrate, and a heating resistor body is formed on an electrical insulating film of several microns formed in the hollow portion. By forming a pair of temperature sensors (temperature-sensing resistor bodies) at an upstream side and a downstream side in the vicinity of the heating resistor body, a flow can be detected from a temperature difference between the upstream side and the downstream side of the heating resistor body which is caused by an air flow. Also, according to this method, a forward flow and a reverse flow can be determined. Also, since the size of the heating resistor body is as minute as several hundred micrometers and is formed in the shape of a thin film, the heating resistor body has a small thermal capacity and can implement fast response, low power consumption and compactness.
The technology related to the compactness of a sensor element is described in PTL 1 and PTL 2. In PTL 1, a semiconductor sensor element, a control circuit chip, and a terminal material are integrated by molding, thereby promoting component count reduction and low cost. Also, in PTL 2, a plurality of heating resistor elements, a temperature detector element, and a control circuit are integrally formed on a chip, thereby promoting compactness.
The integration of a sensor element and a control circuit on the same semiconductor substrate as in PTL 2 can be implemented because the sensor element is a MEMS that is manufactured by using a semiconductor process. However, in a process of manufacturing a sensor element of a thermal type flowmeter, in order to provide a good property of a resistor body formed in the sensor element, an annealing process is performed to thermally treat the resistor body placed in a high-temperature furnace body in a wafer state. Therefore, when a sensor element and a semiconductor integrated circuit are integrated, the sensor element and the semiconductor integrated circuit are simultaneously exposed to a high temperature. Since a MOS (Metal Oxide Semiconductor) transistor is used inmost semiconductor integrated circuits, the MOS transistor is exposed to a high temperature for a long time, thereby causing property variation and malfunction.
In this case, required is a partial annealing method that confines an annealing region to a region in which the sensor element is formed. For example, as described in PTL 3, there is a local annealing method that energizes and heats a gate electrode of a field-effect transistor and anneals a doped region of the field-effect transistor by the heat.
PTL 1: JP 11-6752 A
PTL 2: JP 8-29224 A
PTL 3: JP 11-26391 A
However, in addition to semiconductor materials such as doped monocrystalline silicon and doped polycrystalline silicon, metal materials such as platinum, tungsten, tantalum, and molybdenum are used as materials for the resistor body formed in the sensor element. For example, in the case of polycrystalline silicon doped with a dopant such as phosphorus, a long-time high-temperature thermal treatment is required to thermally diffuse the dopant. Also, in the case of platinum and molybdenum as metal materials, in order to grow a crystal grain, an annealing treatment needs to be performed at a temperature of 800° C. to 1000° C. for several minutes after film formation.
In the case of energizing and partially heating an electrode formed in an annealing region by using a technique described in PTL 3, when long-time high-temperature heating is performed for an annealing treatment, not only the annealing region but also the periphery thereof and a portion in which a semiconductor integrated circuit is formed are heated to a high temperature by thermal conduction, thus causing the malfunction and the property variation of the semiconductor integrated circuit. Therefore, in an integrated structure of the sensor element and the semiconductor integrated circuit, the technique described in PTL 3 is insufficient to partially anneal a sensor element portion.
Therefore, in order to solve the above problem, an object of the invention is to provide a compact thermal type flowmeter that can perform a partial thermal treatment on a sensor element portion without affecting other elements and can improve the reliability of a sensor element while improving the sensitivity of the sensor element.
In order to achieve the above object, the thermal type flowmeter of the invention includes a hollow portion which is formed in a semiconductor substrate, a thin film portion which is formed by insulating films provided to cover the hollow portion, and a heating resistor body and temperature-measuring resistor body which are formed between the insulating films, wherein a thermal treatment is performed to grow a crystal grain size of the heating resistor body and a crystal grain size of the temperature-measuring resistor body by heating the thin film portion after forming the thin film portion.
According to the invention, it is possible to provide a compact thermal type flowmeter that can perform a partial thermal treatment on a sensor element portion without affecting other elements and can improve the reliability of a sensor element while improving the sensitivity of the sensor element.
Hereinafter, embodiments of the invention will be described.
A first embodiment of the invention will be described below.
A configuration of a sensor element 1 of a thermal type flowmeter according to this embodiment will be described with reference to
A heating resistor body 5 is formed on a surface near the center of the electrical insulating film 3a on the diaphragm 4. A heating temperature sensor 7 detecting a heating temperature of the heating resistor body 5 is formed around the heating resistor body 5 to surround the heating resistor body 5. The temperature of the heating resistor body 5 is detected by the heating temperature sensor 7, and the heating resistor body 5 is heated and controlled such that the temperature of the heating resistor body 5 is higher than the temperature of an air flow 6 by a predetermined temperature. Also, upstream side temperature sensors 8a and 8b and downstream side temperature sensors 9a and 9b are formed on both sides of the heating temperature sensor 7. The upstream side temperature sensors 8a and 8b are disposed on the upstream side of the heating resistor body 5, and the downstream side temperature sensors 9a and 9b are disposed on the downstream side of the heating resistor body 5. The outermost surface of the sensor element 1 is covered by an electrical insulating film 3b. In addition to performing electrical insulation, the electrical insulating film 3b serves as a protection film. Temperature-sensing resistor bodies 10, 11 and 12 having a resistance value changing according to the temperature of the air flow 6 are disposed on the electrical insulating film 3a outside the diaphragm 4.
The heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, the downstream side temperature sensors 9a and 9b, and the temperature-sensing resistor bodies 10, 11 and 12 are formed of materials having relatively great resistance temperature coefficients, which have resistance values changing according to the temperature. For example, the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, the downstream side temperature sensors 9a and 9b, and the temperature-sensing resistor bodies 10, 11 and 12 may be formed of semiconductor materials such as doped monocrystalline silicon and doped polycrystalline silicon, and metal materials such as platinum, molybdenum, tungsten, and nickel alloy. Also, the electrical insulating films 3a and 3b are formed of silicon dioxide (SiO2) and silicon nitride (Si3N4) into a thin film having a thickness of about 2 microns, and have a structure capable of obtaining a sufficient thermal insulation effect.
As described above, like the temperature-sensing resistor bodies 10, 11 and 12, the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, and the downstream side temperature sensors 9a and 9b are also temperature-sensing resistor bodies.
Also, an electrode pad portion 13 is provided at an end portion of the sensor element 1, and an electrode for connecting each resistor body constituting the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, the downstream side temperature sensors 9a and 9b, and the temperature-sensing resistor bodies 10, 11 and 12 to a driving/detecting circuit, is formed in the electrode pad portion 13. Also, the electrode is formed of aluminum and the like.
The thermal type flowmeter according to an embodiment of the invention operates as follows.
A temperature distribution 14 illustrated together with the cross-sectional configuration of the sensor element 1 illustrated in
Next, the driving/detecting circuit of the sensor element 1 will be described.
Also, a bridge circuit is constructed by connecting in parallel a serial circuit including the upstream side temperature sensor 8a and the downstream side temperature sensor 9a and a serial circuit including the downstream side temperature sensor 9b and the upstream side temperature sensor 8b, and the reference voltage Vref is applied to the respective serial circuits. When a temperature difference occurs between the upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b due to the air flow, a voltage difference occurs due to a change in the resistance balance of the bridge circuit. An output corresponding to the air flow is obtained from the voltage difference by an amplifier 17.
Next,
Next, a method for manufacturing the sensor element 1 of the thermal type flowmeter according to this embodiment will be described with reference to
[Process of
A semiconductor substrate of monocrystalline silicon (Si) or the like is used as a substrate 2. On the surface of the substrate 2 serving as a base, an electrical insulating film 3a is formed of silicon dioxide (SiO2) and silicon nitride (Si3N4) to a predetermined thickness of about 1 μm by thermal oxidation, CVD, or the like.
[Process of
Next, a semiconductor thin film 26 used as a resistor body and formed of polycrystalline silicon (Si) to a thickness of about 1 μm is stacked by CVD or the like. Dopant diffusion is performed on the polycrystalline silicon (Si) semiconductor thin film, and high-concentration doping is performed to provide a predetermined specific resistance. In the conventional doping/dopant diffusion process, a thermal treatment of injecting a sensor element into a heating furnace of about 900° C. to about 1000° C. for one hour or more is performed to improve a resistance temperature coefficient of the semiconductor thin film 26, thereby achieving a good property of a resistor body used as a temperature sensor. However, in the case where a MOS (Metal Oxide Semiconductor) transistor is formed as a semiconductor integrated circuit on the substrate 2 in advance (not illustrated), when a thermal treatment of 900° C. to 1000° C. is performed, a malfunction occurs in the semiconductor integrated circuit due to a property variation of the MOS transistor (for example, expansion of a source/drain region). Therefore, for example, in a CMOS process with a gate length of about 1 μm, a restriction is put to provide a thermal treatment condition in which a property variation of the MOS transistor does not occur at 900° C. or less for up to about several minutes. Thus, in this process, the semiconductor thin film 26 is kept in the state of insufficient dopant diffusion and low resistance temperature coefficient. Herein, the thermal treatment condition, in which a property variation of the MOS transistor does not occur, is not uniformly determined but changes according to the degree of miniaturization of semiconductors or the like.
[Process of
After a resist is formed into a predetermined shape by photolithography, the polycrystalline silicon (Si) semiconductor thin film is patterned by reactive ion etching or the like, thereby obtaining a predetermined heating resistor body 5, a heating temperature sensor 7, upstream side temperature sensors 8a and 8b, downstream side temperature sensors 9a and 9b, and an interconnection portion 30.
[Process of
In a subsequent process, like the electrical insulating film 3a, an electrical insulating film 3b serving as a protection film is formed of silicon dioxide (SiO2) and silicon nitride (Si3N4) to a thickness of about 1 micron by CVD or the like.
[Process of
Next, after a portion of the electrical insulating film 3b is removed, an electrode pad portion 13 serving as a terminal for connection with an external circuit is formed of a metal material such as aluminum.
[Process of
Next, an etching mask material is patterned into a predetermined shape on the back surface of the monocrystalline silicon (Si) semiconductor substrate 2, and an etchant such as potassium hydroxide (KOH) is used to perform anisotropic etching to form a hollow portion, thereby forming a diaphragm 4.
[Process of
Next, a probe 28 is brought into contact with the electrode pad portion 13, and a current is supplied from a power supply 27 through the probe 28. By electrically connecting the interconnection portion 30 to the heating resistor body 5 (not illustrated), the heating resistor body 5 is heated by the current supplied from the power supply 27. At this time, the current of the power supply 27 is adjusted such that the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, and the downstream side temperature sensors 9a and 9b are heated at 900° C. or more (preferably at about 1000° C.) for 60 minutes or more.
By the thermal treatment described above, an insufficient thermal treatment can be performed in the process of
Also, when a current is applied to the heating resistor body 5 in this process, a current also flows through the interconnection 30 and heating occurs. However, since it is located on the substrate 2, heat radiates into the substrate 2 and a temperature increase does not occur. A portion heated above 900° C. can be limited to a portion of the diaphragm 4 that is thermally insulated. Therefore, the invention is characterized in that the thermal treatment is performed by energizing the heating resistor body 5 after forming the diaphragm 4.
Also, since a region on the substrate 2, in which a MOS (Metal Oxide Semiconductor) transistor is formed as a semiconductor integrated circuit, is not heated to a high temperature in advance, the malfunction and the property variation of the MOS transistor do not occur.
By the above processes, the sensor element 1, or the sensor element 1 including the semiconductor integrated circuit is completed.
The property of the sensor element 1 manufactured by this embodiment will be described in detail.
The heating temperature sensor 7 and the interconnection portions 30e and 30h are originally formed of the same semiconductor thin film 26. However, since the heating temperature sensor 7 formed on the diaphragm 4 is thermally treated by the process of
Also, in
The upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b illustrated in
The upstream side temperature sensors 8a and 8b and the interconnection portions 30a, 30b, 30c and 30d are originally formed of the same semiconductor thin film 26. However, since the upstream side temperature sensors 8a and 8b formed on the diaphragm 4 are thermally treated by the process of
Therefore, the resistance temperature coefficients of the upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b are improved by the process of
This is the same for the heating resistor body illustrated in
According to this embodiment, even when the sensor element and the semiconductor integrated circuit are provided on the substrate 2 formed of a semiconductor, the property of the sensor element is not degraded. Also, the compactness/high accuracy of the thermal type flowmeter can be implemented without causing the malfunction and the property variation of the semiconductor integrated circuit.
In this embodiment, the diaphragm 4 is obtained by removing all of the substrate 2. However, the effect is obtained even when a portion of the substrate 2 is not removed. That is, when the film thickness of the substrate 2 is different between the portion that is thermally treated and the portion that is not thermally treated, a partial high-temperature thermal treatment is possible and this can also be applied to the thermal treatment of other semiconductor elements, the sensor element, or the like.
A second embodiment of the invention will be described below.
A configuration of a sensor element 29 of a thermal type flowmeter according to this embodiment will be described with reference to
The temperature-sensing resistor bodies 10, 11 and 12 formed on the diaphragm 31 are resistor bodies that constitute a bridge circuit and the heating temperature sensor 7 in the driving circuit illustrated in
A third embodiment of the invention will be described below.
A configuration of a sensor element 32 of a thermal type flowmeter according to this embodiment will be described with reference to
By the above configuration, the region in which the thermal treatment heater 33 is formed can be widened, and the diaphragm 4 can be heated at a uniform temperature distribution. That is, the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, and the downstream side temperature sensors 9a and 9b can be thermally treated at the same temperature. In the first embodiment, since a thermal treatment is performed by heating the heating resistor body 5, the temperature of the resistor body located outside in the diaphragm 4 is lowered, so that it cannot be heated to the optimal temperature. Thus, the temperatures of the upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b are lowered, so that a sufficient thermal treatment cannot be implemented. According to this embodiment, the temperatures in the diaphragm 4 can be made uniform, and the upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b located in the diaphragm 4 can be thermally treated at the optimal temperature. That is, as compared to the case of the first embodiment, the resistance temperature coefficients of the upstream side temperature sensors 8a and 8b and the downstream side temperature sensors 9a and 9b are improved, and a high-accuracy thermal type flowmeter is obtained.
The thermal treatment heater 33 may be formed of a polycrystalline Si film as in the first embodiment, or may be formed of other materials. For example, the thermal treatment heater 33 may be formed of metal materials such as platinum, tungsten, tantalum, and molybdenum that have an excellent heat resistance. When the thermal treatment heater 33 is formed of the metal materials, the thermal conductivity is increased, so that a more uniform temperature distribution can be achieved. Thus, the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, and the downstream side temperature sensors 9a and 9b can be simultaneously heated to the optimal temperature, and the thermal treatment can be performed more simply and easily.
In this embodiment, the thermal treatment heater is provided at the diaphragm 4 illustrated in the first embodiment, but this may also be applied in the region in which the temperature-sensing resistor bodies 10, 11 and 12 illustrated in the second embodiment are formed. Specifically, the thermal treatment heater is formed through the electrical insulating film 3c under the temperature-sensing resistor bodies 10, 11 and 12. A diaphragm 31 is formed by removing a portion of a substrate 2 corresponding to a region in which the temperature-sensing resistor bodies 10, 11 and 12 are formed. Thereafter, the temperature-sensing resistor bodies 10, 11 and 12 are thermally treated by heating the thermal treatment heater.
Accordingly, the thermal treatment temperatures of the temperature-sensing resistor bodies 10, 11 and 12 are made uniform, so that the resistance temperature coefficients of the temperature-sensing resistor bodies 10, 11 and 12 can be made more consistent. Accordingly, a variation in the resistance balance of the bridge circuit including the heating temperature sensor 7 and the temperature-sensing resistor bodies 10, 11 and 12 is reduced, so that the temperature of the heating resistor body 5 can be controlled with a high accuracy.
A fourth embodiment of the invention will be described below.
A configuration of a sensor element 36 of a thermal type flowmeter according to this embodiment will be described with reference to
In the first embodiment, as illustrated in
The mold material 40 is formed of an epoxy-based resin and is manufactured by known injection molding. Also, the mold material 40 is formed to avoid a diaphragm 4 of the sensor element 36 such that the diaphragm 4 is exposed to air. Also, on the back side of the sensor element 36, a through-hole 42 is formed in the lead frame 41 and the mold material 40 such that the back side of the diaphragm 4 is not sealed up.
Since the injection molding can provide a small shape variation in the mold material and enables low-cost manufacturing, a variation in the installation of the sensor element can be reduced. Since the manufacturing variation is small, the size of the sensor element can be reduced.
A fifth embodiment of the invention will be described below.
In this embodiment, configurations different from the first embodiment will be described, and the other configurations are the same as the first embodiment.
The resistor bodies of the heating resistor body 5, the heating temperature sensor 7, the upstream side temperature sensors 8a and 8b, and the downstream side temperature sensors 9a and 9b are formed of polycrystalline Si in the first embodiment, but they may also be formed of other materials.
The resistor body formed in the sensor element may be formed of semiconductor materials such as doped monocrystalline silicon and doped polycrystalline silicon, and metal materials such as platinum, tungsten, tantalum, and molybdenum. The resistance temperature coefficient of the metal materials is 2000 ppm/° C. or more, and a high-sensitivity sensor element is obtained. Since platinum as the metal material starts crystal growth at 800° C. or more, it requires a thermal treatment of 800° C. or more. A resistor body with a good property is obtained by performing the thermal treatment preferably at 900° C. Also, since molybdenum starts crystal growth at 700° C. or more, it requires a thermal treatment of 700° C. or more. A resistor body with a high resistance temperature coefficient is obtained by performing the thermal treatment preferably at 1000° C.
Therefore, when the metal material is used, the thermal treatment temperature in the process illustrated in
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2011/001197 | 3/2/2011 | WO | 00 | 8/9/2013 |