The subject disclosure relates to battery packs. More specifically, the disclosure relates to lithium-ion battery packs having improved thermal resilience.
Lithium-ion batteries are used in a variety of applications, from electric vehicles to residential batteries to grid-scale applications. In general, the term lithium-ion battery refers to a wide array of battery chemistries that each charge and discharge using reactions from a lithiated metal oxide cathode and a graphite anode. Two of the more commonly used lithium-ion chemistries are nickel manganese cobalt (NMC) and lithium iron phosphate (LFP). In general, lithium-ion batteries have better performance when operating between a low temperature (i.e., temperatures above approximately 10 degrees Celsius) and a high temperature (i.e., temperatures below approximately 40 degrees Celsius).
Accordingly, it is desirable to provide a Lithium-ion battery pack that is capable of dissipating heat generated by the Lithium-ion battery cells and which is capable of being heated.
In one exemplary embodiment, a battery pack having a plurality of battery modules is provided. Each of the plurality of battery modules includes a thermally conductive frame having a plurality of apertures, a plurality of battery cells, wherein each of the plurality of battery cells is disposed in one of the plurality of apertures and a first potting material disposed in each of the plurality of apertures between each of the plurality of battery cells and the thermally conductive frame.
In addition to one or more of the features described herein, the plurality of apertures comprises a first set of apertures that are disposed on an interior portion of the thermally conductive frame and a second set of apertures that are disposed on an exterior portion of the thermally conductive frame and wherein a distance between adjacent apertures of the first set of apertures is less than a distance between apertures of the second set of apertures and an edge of the thermally conductive frame.
In addition to one or more of the features described herein, the distance between apertures of the second set of apertures and an edge of the thermally conductive frame is at least four time greater than the distance between adjacent apertures of the first set of apertures.
In addition to one or more of the features described herein, each of the plurality of battery cells comprises a vented end and a non-vented end and wherein the non-vented end is covered by the first potting material.
In addition to one or more of the features described herein, a second potting material is disposed on the vented end of each of the plurality of battery cells.
In addition to one or more of the features described herein, the vented end of each of the plurality of battery cells includes a fuse that is in contact with a tab portion of a current collector plate and wherein the second potting material is disposed above the tab.
In addition to one or more of the features described herein, the second potting material does not extend above a body portion of the current collector plate.
In addition to one or more of the features described herein, the thermally conductive frame has a thermal mass of at least 850 joule per kilogram per kelvin (J/kg/K) and a thermal conductivity of at least 175 Watts per meter-Kelvin (W/m/K).
In addition to one or more of the features described herein, each of the plurality of battery modules comprises a first cell holder disposed on a first side of the thermally conductive frame and a second cell holder disposed on a second side of the thermally conductive frame opposite the first side.
In addition to one or more of the features described herein, the first potting material has a thermal conductivity that is lower than a thermal conductivity of the thermally conductive frame.
In another exemplary embodiment, a method for forming a battery module is provided. The method includes inserting each of a plurality of battery cells into one of a plurality of apertures of a thermally conductive frame and affixing a first cell holder to a first side of the thermally conductive frame. The method also includes affixing a second cell holder to a second side of the thermally conductive frame opposite the first side and connecting a first current collector plate to a first electrode disposed on a first end of each of the plurality of battery cells disposed on the first side of the thermally conductive frame. The method further includes connecting a second current collector plate to a second electrode disposed on a second end of each of the plurality of battery cells disposed on the second side of the thermally conductive frame and injecting a first potting material in between each of the plurality of battery cells and the plurality of apertures.
In addition to one or more of the features described herein, the method further includes covering a non-vented end of each of the plurality of battery cells with the first potting material.
In addition to one or more of the features described herein, the method further includes depositing a second potting material above the first tab on a vented end of each of the plurality of battery cells.
In addition to one or more of the features described herein, the second potting material does not extend above a body portion of the first current collector plate or the second current collector plate.
In addition to one or more of the features described herein, the second potting material is deposited in a spiral manner extending from a center of each of the plurality of battery cells to an edge of each of the plurality of battery cells.
In addition to one or more of the features described herein, the second potting material is thixotropic and wherein the second potting material fills an opening above the vented end of each of the plurality of battery cells.
In addition to one or more of the features described herein, the plurality of apertures comprises a first set of apertures that are disposed on an interior portion of the thermally conductive frame and a second set of apertures that are disposed on an exterior portion of the thermally conductive frame and wherein a distance between adjacent apertures of the first set of apertures is less than a distance between apertures of the second set of apertures and an edge of the thermally conductive frame.
In addition to one or more of the features described herein, the distance between apertures of the second set of apertures and an edge of the thermally conductive frame is at least four time greater than the distance between adjacent apertures of the first set of apertures.
In addition to one or more of the features described herein, the first cell holder and the second cell holder each include one or more vents configured to allow air to escape during the injecting.
In addition to one or more of the features described herein, one or more seals are configured to prevent the first potting material from covering a vented end of each of the plurality of battery cells during the injecting.
The above features and advantages, and other features and advantages of the disclosure are readily apparent from the following detailed description when taken in connection with the accompanying drawings.
Other features, advantages and details appear, by way of example only, in the following detailed description, the detailed description referring to the drawings in which:
The following description is merely exemplary in nature and is not intended to limit the present disclosure, its application or uses. Various embodiments of the disclosure are described herein with reference to the related drawings. Alternative embodiments of the disclosure can be devised without departing from the scope of the claims. Various connections and positional relationships (e.g., over, below, adjacent, etc.) are set forth between elements in the following description and in the drawings. These connections and/or positional relationships, unless specified otherwise, can be direct or indirect, and the present disclosure is not intended to be limiting in this respect. Accordingly, a coupling of entities can refer to either a direct or an indirect coupling, and a positional relationship between entities can be a direct or indirect positional relationship.
Turning now to an overview of the aspects of the disclosure, embodiments of the disclosure include lithium-ion battery packs having improved thermal resilience. The lithium-ion battery packs include a heating element disposed on one side of the battery pack and a cooling plate disposed on the opposing side of the battery pack. The battery packs include a plurality of battery modules that each include a thermally conductive frame that is configured to dissipate heat generated by the battery cells in each battery module. In exemplary embodiments, the battery packs include a first potting material that is disposed between the battery cells and the thermally conductive frame. The first potting material is configured to limit the heat transfer between adjacent battery cells of the battery module to prevent a thermal runaway of one battery cell from affecting adjacent battery cells.
In exemplary embodiments, the battery packs are configured to be used in a vehicle that operates under extreme conditions. In one example, the vehicle is configured to be used in outer space, such as in a lunar rover. In one embodiment, the battery pack is designed with a passive cooling system, (i.e., no cooling fluid is circulated through the battery pack to provide heating and cooling to the battery pack). The battery pack is designed such that a battery module of the battery pack will remain functional after a thermal runaway event by one of the battery cells in the battery module.
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In exemplary embodiments, each of the plurality of apertures 209 are configured to receive a battery cell 208. In one embodiment, each of the plurality of apertures 209 is cylindrical in shape and has a diameter that is approximately one to two millimeters larger than the diameter of the battery cells 208. As a result, when a battery cell 208 is inserted into an aperture 209, there is a circumferential space of approximately one-half to one millimeter between the battery cell 208 and a sidewall of the aperture 209.
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In an exemplary embodiment, the battery module 500 includes a first potting material 509 that is disposed between the battery cell and the thermally conductive frame 506. In one embodiment, the first potting material 509 is also disposed between the battery cell 502 and the first cell holder 504-1 and the second cell holder 504-2. In one embodiment, the first potting material 509 is one of an epoxy, polyurethane, silicone, Polyamide, bismaleimide, benzoxizine, or polyester. The first potting material is configured to thermally insulate the battery cells 502 from heat generated by adjacent battery cells and to prevent a thermal runaway event in an adjacent battery cell from damaging the battery cell 502. The first potting material 509 is further configured to conduct heat from a normally operating battery cell 502 to the ribbon,
In an exemplary embodiment, the battery module 500 includes a first current collector plate 508-1 that is configured to electrically connect to an electrode 503 disposed on a vented end 502-1 of the battery cell 502. The battery module 500 also includes a second current collector plate 508-2 that is configured to electrically connect to the non-vented end 502-2 of the battery cell 502. In exemplary embodiments, the non-vented end 502-2 of the battery cell 502 is covered by the first potting material 509 and the first potting material 509 encapsulates at least a portion of the second current collector plate 508-2.
In exemplary embodiments, the battery module 500 also includes a second potting material 510 that is disposed above a vented end 502-1 of the battery cell 502. The second potting material 510 is one of an epoxy, polyurethane, silicone, Polyamide, bismaleimide, benzoxizine, or polyester. In exemplary embodiments, the second potting material 510 is disposed above an upper portion of the electrode 503 and on top of a tab portion 505-2 of the first current collector plate 508-1. The second potting material 510 encapsulates a fuse 505-3 that connects the tab portion 505-2 and the body portion 505-1 of the first current collector plate 508-1. The second potting material 510 does not extend above a body portion 505-1 of the first current collector plate 508-1. As a result, the second potting material 510 does not obstruct a vent of the battery cell 502. In exemplary embodiments, the second potting material 510 is configured to adhere to the tab portion 505-2 of the first current collector plate 508-1. It is also adhered to 504-1, but in a manner such that it does provide significant resistance to the vent opening because too high of a bond will prevent the cell from venting properly and too weak of a bond and the potting will not be secure to shock and vibration. In exemplary embodiments, the second potting material 510 is configured to separate from the tab portion 505-2 of the first current collector plate 508-1 based on an increase in pressure between the second potting material 510 and the battery cell 502, this increase in pressure may be caused by gasses emitted by a vent of the battery cell 502. In exemplary embodiments, the battery module 500 also includes a third potting material 511 that is disposed on the first cell holder 504-1 and that is configured to at least partially encapsulate a body portion 505-1 of the first current collector plate 508-1.
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In exemplary embodiments, the battery module includes an aperture 616 disposed on an exterior portion of the battery module. The aperture 616 is configured to receive a first potting material 609 which is injected into the battery module. In exemplary embodiments, the first potting material 609 fills the space between the battery cells 602 and the thermally conductive frame 606 by flowing through the openings 613. The first potting material 609 also covers the non-vented end 602-2 of the battery cells 602. In exemplary embodiments, a plurality of stops 620 are disposed adjacent to the vented ends 602-1 of the battery cells 602 that prevent the first potting material 609 from covering the vented ends 602-1 of the battery cells 602. In exemplary embodiments, one or more of the cell holders 604 include channels 624 that are configured to direct and control the flow of the first potting material around the non-vented end 602-2 of the battery cells 602. In addition, the cell holders 604 may include a vent hole 622 that is configured to allow air to escape from the battery module while the first potting material 609 is being injected into the battery module.
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In exemplary embodiments, the second potting material 705 is a thixotropic material that has a lower viscosity when being applied to the vented end of the battery cell and a higher viscosity after it has been applied to the vented end of the battery cell. In exemplary embodiments, the second potting material 705 is applied to the vented end of the battery cell such that the second potting material 705 does not obstruct a vent disposed on the vented end of the battery cell. In one embodiment, as best shown in
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In exemplary embodiments, the battery module 810 also includes a plurality of wires 817 that are connected to sensors disposed on one or more of the battery cells 812. The sensors may be configured to monitor the temperature and/or the voltage level of the battery cells 812. The battery module 810 also includes a first potting material 818 that is disposed between the battery cell 802 and the thermally conductive frame 815. The first potting material 818 may encapsulate at least a portion of the plurality of wires 817. In exemplary embodiments, the first potting material 818 is configured to provide thermal insulation between the adjacent battery cells 812.
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At block 904, the method 900 includes inserting each of a plurality of battery cells into one of the plurality of apertures. In exemplary embodiments, each of the plurality of battery cells includes a vented end and a non-vented end. Next, at block 906, the method 900 includes affixing a first cell holder to a first side of the thermally conductive frame. At block 908, the method 900 includes affixing a second cell holder to a second side of the thermally conductive frame opposite the first side. Next, at block 910, the method 900 includes affixing a heating element to a top of the thermally conductive frame. The method 900 concludes at block 912 with affixing a cooling plate to a bottom of the thermally conductive frame.
In exemplary embodiments, the thermally conductive frame includes a plurality of cooling ribbons that are disposed between at least two of the plurality of apertures. Each of the plurality of cooling ribbons extends from the top of the thermally conductive frame to the bottom of the thermally conductive frame. In one embodiment, each of the ribbons extends from the first side of the thermally conductive frame to the second side of the thermally conductive frame. In another embodiment, at least one of the ribbons extends from one of the first side of the thermally conductive frame and the second side of the thermally conductive frame less than half the width of the thermally conductive frame.
In exemplary embodiments, the plurality of apertures are divided into sub-groups that each consist of three of the plurality of apertures. The sub-groups are arranged in columns that extend from the top of the thermally conductive frame to the bottom of the thermally conductive frame. In one embodiment, each of the plurality of cooling ribbons is disposed between adjacent columns. In exemplary embodiments, a first column includes sub-groups arranged in a first pattern and a second column, adjacent to the first column, includes sub-groups arranged in a second pattern that is different than the first pattern.
In exemplary embodiments, each of the sub-groups is formed by forming the three of the plurality of apertures in a triangular arrangement and forming a central aperture in a center of the triangular arrangement. In one embodiment, the central aperture at least partially overlaps each of the three of the plurality of apertures.
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At block 1004, the method 1000 also includes affixing a first cell holder to a first side of the thermally conductive frame. Next, at block 1006, the method 1000 includes affixing a second cell holder to a second side of the thermally conductive frame opposite the first side. Also, at block 1008, the method 1000 includes connecting a first current collector plate to a fuse disposed on the first end of each of the plurality of battery cells disposed on the first side of the thermally conductive frame. Next, at block 1010, the method 1000 includes connecting a second current collector plate to an electrode disposed on the second end of each of the plurality of battery cells disposed on the second side of the thermally conductive frame. At block 1012, the method 1000 includes injecting a first potting material in between each of the plurality of battery cells and the plurality of apertures. In exemplary embodiments, the first cell holder and the second cell holder each include one or more vents configured to allow air to escape during the injecting.
In exemplary embodiments, at block 1014, the method 1000 also includes covering a non-vented end of each of the plurality of battery cells with the first potting material. The method 1000 further includes depositing a second potting material above the fuse on a vented end of each of the plurality of battery cells, at block 1016. In exemplary embodiments, the second potting material does not extend above a body portion of the first current collector plate or the second current collector plate. In one embodiment, the second potting material is deposited in a spiral manner extending from the center of each of the plurality of battery cells to the edge of each of the plurality of battery cells.
In exemplary embodiments, the plurality of apertures comprises a first set of apertures that are disposed on an interior portion of the thermally conductive frame and a second set of apertures that are disposed on an exterior portion of the thermally conductive frame. The distance between adjacent apertures of the first set of apertures is less than the distance between the apertures of the second set of apertures and an edge of the thermally conductive frame. In one embodiment, the distance between the apertures of the second set of apertures and an edge of the thermally conductive frame is at least four times greater than the distance between adjacent apertures of the first set of apertures.
The terms “a” and “an” do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced item. The term “or” means “and/or” unless clearly indicated otherwise by context. Reference throughout the specification to “an aspect”, means that a particular element (e.g., feature, structure, step, or characteristic) described in connection with the aspect is included in at least one aspect described herein, and may or may not be present in other aspects. In addition, it is to be understood that the described elements may be combined in any suitable manner in the various aspects.
When an element such as a layer, film, region, or substrate is referred to as being “on” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
Unless specified to the contrary herein, all test standards are the most recent standard in effect as of the filing date of this application, or, if priority is claimed, the filing date of the earliest priority application in which the test standard appears.
Unless defined otherwise, technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this disclosure belongs.
While the above disclosure has been described with reference to exemplary embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from its scope. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the disclosure without departing from the essential scope thereof. Therefore, it is intended that the present disclosure not be limited to the particular embodiments disclosed, but will include all embodiments falling within the scope thereof.