Thermodynamic metal treating apparatus and method

Information

  • Patent Application
  • 20080011394
  • Publication Number
    20080011394
  • Date Filed
    July 14, 2006
    18 years ago
  • Date Published
    January 17, 2008
    17 years ago
Abstract
A thermodynamic metal treating apparatus and process describes utilizing a quenchant mixture of liquid and gas in a cell. Heated metal is passed over the heated quenchant mixture which contains a liquid and a gas such as air bubbled through the liquid at a desired rate. The process is particularly suited for improving the breaking, tensile strength and ductility of steel wire as is used in belted vehicle tires. A series of quenching cells allow for fast, uniform treatment of the metal wire.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 demonstrates a schematic representation of the apparatus used in the thermodynamic metal treating process;



FIG. 2 shows an enlarged view of one of the apparatus cells as seen in FIG. 1;



FIG. 3 illustrates a graph of convection coefficient of air/water volume percentages of quenchant mixtures;



FIG. 4 depicts a typical TTT curve for SAE 1080 steel;



FIG. 5 pictures another TTT curve for eutectoid steel;



FIG. 6 demonstrates a first TTT curve for SAE 1070 steel;



FIG. 7 shows a second TTT curve for SAE 1070 steel; and



FIG. 8 illustrates a third TTT curve for SAE 1070 steel.





DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS AND OPERATION OF THE INVENTION

For a better understanding of the invention and its operation, turning now to the drawings, FIG. 1 demonstrates preferred treating apparatus 10 in schematic representation. As seen, treating apparatus 10 comprises standard oven 12, preferably a Thermcraft 6′ long, 1600° C. tube furnace manufactured by Thermcraft, Inc. of Winston Salem, N.C. 27177-2037. To measure wire 11 exiting oven 12 a pyrometer (700-1400° C.) from Pyrometer Instrument Company of Windsor, N.J., 08561-0479 with five (5) consecutive cells 20, 21, 22, 23 and 24, each including heat source 50 having a conventional electric immersion heater (rated at 240V, 4.5 kw, 3 phase), and air regulator 51 (seen in FIG. 2 in greater detail) Air regulator 51 is preferably a Dwyer Air Flow meter rated 0-50 L/min from Dwyer Instruments, Inc. of Michigan City, Ind. In the preferred treatment method a coil of wire 11, conventional steel wire designated 1090 having a nominal diameter of 2.0 mm, or alternatively 1070 (not seen) having a nominal diameter of 1.2 mm is mounted above floor 40 as in a typical industrial treatment operation. Wire 11 is fed through oven 12 for heating purposes, preferably to about 930-1020° C. Heated wire 11 is then directed by front roller guides 57, 57′ slightly above first cell 20, where quenchant mixture 45 (FIG. 2) is displaced over the top of first cell 20 by introduction of gas 55 to liquid 53 resulting in vapor or foam 56 which completely covers wire 11. Wire 11 continuously travels through vapors across the top of cells 20-24 and dries by evaporation through the air to form created wire 34 which passes through rear roller guides 58, 58′ and is wound onto reel 35 at the terminal end of treating apparatus 10. While only five cells 20-24 are shown herein, more or less cells could be used depending on the particular manufacturer's circumstances and treatment operation. Each cell 20-24 includes a thermometer such as a Raytex 500-1100° C. close focus fiber optical type from Raytex Equipment Company, Houston, Tex. In addition, only one wire 11 is shown but typically bundles of wires having 5-90 wires per bundle would be processed simultaneously during normal production. Other metal strand materials could likewise be treated.


In schematic FIG. 2, cell 20 is seen enlarged as removed from apparatus 10. Heat source 50 is in communication with cell 20 to heat and re-circulate quenchant mixture 45 contained in cell 20. Cell 20 includes a liquid circulation pump (not seen) such as a Bell & Gossett NBF-220 110° C., 15PASI, 115V, 2 watt (P83033 model) recirculating pump. Standard air speed regulator 51 is in communication with gas supply 54 having an ACSI digital pressure meter (part No: 1200-0030,602056) rated at .XXPSI, a 0-200 PSF air gauge at Ashcroft.com (Ashcroft, Inc.) and a speedaire 2Z767D, 200PSI 125° F. air regulator (as sold at Grainger.com) containing gas 55 and supply line 52 also in communication with cell 20 to provide gas 55 to liquid 53 thereby forming quenchant mixture 45. As would be understood, schematic FIG. 2 does not fully demonstrate mechanical, electrical or other components as used herein. Heat source 50 and air regulator 51 are conventional in the trade and can vary in size, shape and efficiency depending on their particular requirements.


Heat source 50 recirculates quenchant mixture 45 within cell 20 while maintaining its temperature at approximately 100° C. In a typical installation, liquid 53 shown would consist of preferably typical conventional RAQ-TWT quenching solution sold by Richards Apex, Inc. of Philadelphia, Pa. RAQ-TWT is a proprietary formula containing: polyalkylene glycol—45.5%; polyethylene glycol ester—12%; a proprietary metal working fluid additive—12%, a defoamer—0.5%, and water—30%, with a typical pH of 3-9%. This quenchant solution is diluted to 10% by volume with water prior to use. Other commercial quenching liquids or water could also be used.


Gas 55 contained within gas supply 54 is preferably air but other gases may be used to form quenchant mixture 45. Mixture 45 can be varied by the air flow rate and volume percentage to change the forced convective heat transfer coefficient as shown schematically in FIG. 3 where pure air is estimated to be 0.5 W/(sq.m*K) and pure water is estimated to be 10,000 W/(sq.m*K). The forced convective heat transfer coefficient varies linearly with combinations of air and water as shown in FIG. 3.



FIG. 4 shows a typical Time, Temperature, Transformation (TTT) curve for SAE 1080 steel. The optimal structure developed by the heat treating process for industrial drawing is obtained by cooling 1080 steel wire from the austenization temperature (930-1020° C.) to 540° C. very rapidly (about 1 second) on the left of FIG. 4 at point A on line B and holding the 1080 steel wire at 540° C. until both the midline and line E are crossed (about 6 seconds).



FIG. 5 shows a schematic of eutectoid steel (iron/carbon steel with 0.8 to 0.83 carbon) TTT curve indicating where three different forced convective heat transfer coefficients are required to produce the proper microstructure, forced convective heat transfer coefficient 60 to reduce the wire temperature from about 930-1020° C. to 540° C., forced convective heat transfer coefficient 61 to hold the wire at temperature during the exothermic reaction from austenite to pearlite and forced convective heat transfer coefficient 62 to cool the wire to a safe operating temperature.


Examples for the thermodynamic wire transformation process for SAE 1090 steel are provided in Table 1 below.









TABLE 1







experimental data for 1090 steel, nominal 2.0 mm diameter

















Tensile



Flow Rate liters per minute
Percent Air

Breaking
Strength




















Example
Cell 20
Cell 21
Cell 22
Cell 23
Cell 24
Cell 20
Cell 21
Cell 22
Cell 23
Cell 24
Diameter (mm)
Load (N)
(Mpa)























1
25
15
5
5
0
18%
11%
4%
4%
0%
1.9609
3600
1192


2
20
10
10
5
0
14%
 7%
7%
4%
0%
1.9607
3599
1192


3
35
10
5
5
0
25%
 7%
4%
4%
0%
1.9641
3712
1225


4
35
10
10
5
5
25%
 7%
7%
4%
4%
1.9622
3735
1235


5
40
10
10
5
0
28%
 7%
7%
4%
0%
1.9624
3920
1296


6
35
30
0
0
0
25%
21%
0%
0%
0%
1.9625
3947
1305


7
40
25
5
0
0
28%
18%
4%
0%
0%
1.9613
3946
1306


8
35
25
10
5
0
25%
18%
7%
4%
0%
1.9611
3951
1308


9
30
30
5
5
0
21%
21%
4%
4%
0%
1.9613
3955
1309


10
40
20
5
5
5
28%
14%
4%
40% 
4%
1.9637
3989
1317


11
35
25
10
5
0
25%
18%
7%
4%
0%
1.9622
3995
1321


12
35
30
5
5
5
25%
21%
4%
4%
4%
1.9622
3998
1322


13
40
25
5
5
5
28%
18%
4%
4%
4%
1.9620
4003
1324


14
35
25
10
10
0
25%
18%
7%
7%
0%
1.9630
4022
1329


15
40
35
5
5
0
28%
25%
4%
4%
0%
1.9631
4035
1333


16
35
35
10
5
0
25%
25%
7%
4%
0%
1.9621
4055
1341


17
30
30
10
10
5
21%
21%
7%
7%
4%
1.9614
4085
1352


18
40
30
10
5
5
28%
21%
7%
4%
4%
1.9637
4128
1363


19
35
30
10
10
5
25%
21%
7%
7%
4%
1.9624
4162
1376


20
40
30
10
10
5
28%
21%
7%
7%
4%
1.9611
4171
1381









As seen in Table 1, conventional 2 mm SAE 1090 steel wire was processed using a plurality of cells 20-24, containing liquid 53, preferably quenchant RAQ-TWT as described above, diluted to 11 concentration in water by volume. By bubbling gas 55 (preferably air) through liquid 53 at various rates in individual cells 20-24 the breaking loads and tensile strength of wire 11 can be altered.


In Example 1 seen in Table 1, the preferred method utilizes a nominal 2 mm diameter wire (1090 steel) treated with a resulting breaking load of 3600 Newtons (N) and a tensile strength of 1192 Megapascals (MPa). E<ample 6 shows the method with the same 2 mm wire being treated only in cells 20 and 21 and having an increased breaking load of 3947 N with a tensile strength of 1305 MPa. In Example 20, the method employs cells 20, 21, 22, 23 and 24, all utilized with various flow rates and air volumes with the breaking load increasing to 4171 N and a tensile strength increasing to 1381 MPa. All examples shown herein were run at a constant wire speed of 7 meters per minute.


Thus, by increasing the volume or percentage of gas 55 in quenchant mixture 45, improved breaking loads and tensile strengths of 1090 wire can be realized by the described methods.


Examples for the thermodynamic wire transformation process for SAE 1070 steel are provided in Table 2 below while FIGS. 6, 7 and 8 illustrate corresponding TTT curves.









TABLE 2







experimental data for 1070 steel, nominal 1.2 mm diameter

















Tensile


Exam-
Air Flow Rate, liters per minute
Percent Air
Diameter
Breaking
Strength




















ple
Cell 20
Cell 21
Cell 22
Cell 23
Cell 24
Cell 20
Cell 21
Cell 22
Cell 23
Cell 24
(mm)
Load (N)
(Mpa)























A
Round Spray
0
0
0
0
20% 
100%
100%
100%
100%
1.196
1289
1148


B
Flat Spray
15
0
0
0
5%
 11%
100%
100%
100%
1.182
1541
1404


C
Flat Spray
0
0
0
0
5%
100%
100%
100%
100%
1.192
1266
1135


D
Flat Spray
0
2
0
0
5%
 0%
FOAM
 0%
 0%
1.179
1276
1168


E
Flat Spray
2
0
0
0
5%
FOAM
100%
100%
100%
1.191
1352
1214


F
Pipe Spray 2.55 g/m
0
0
0
0
0%
100%
100%
100%
100%
1.197
1287
1143


G
Pipe Spray 3 g/m
0
0
0
0
0%
100%
100%
100%
100%
1.183
1315
1197


H
Pipe Spray 2.55 g/m
20
0
50
0
0%
 14%
100%
 35%
100%
1.183
1267
1153


I
Pipe Spray 3 g/m
20
0
50
50
0%
 14%
100%
 35%
 35%
1.205
1407
1234


J
Pipe Spray 1.5 g/m
0
0
0
0
0%
100%
100%
100%
100%
1.200
1250
1105


K
Pipe Spray 1.5 g/m
0
0
0
0
0%
100%
100%
100%
100%
1.210
1161
1010









As seen in Table 2, conventional 1.2 mm SAE 1070 steel wire was processed in a plurality of cells 20-24, containing liquid 53 preferably quenchant RAQ-TWT as described above diluted to 10% concentration in water by volume with gas 55 combining therewith to form quenchant mixture 45.


In Example A, cell 20 was modified to apply a ⅜ inch round spray perpendicular to the wire.


In Examples B-E, cell 20 was modified to apply a 6 inch flat spray parallel (⅛ inch thick) to the wire.


In Examples F-K, cell 20 was modified to apply a pipe spray in the range of 1.5-3 g/m while the wire was encased in a ⅜ inch thick, 4 inch long pipe at various flow rates.


By bubbling gas 55 (preferably air) through liquid 53 at various rates in individual cells 21-24 the breaking loads and tensile strength of wire 11 can be treated with vapors 56.


In Example A, as seen in Table 2, the preferred method utilizes a round spray and nominal 1.2 mm diameter wire (1070 steel) treated with a resulting breaking load of 1289 Newtons (N) and a tensile strength of 1148 Megapascals (MPa). Example D shows the flat spray method with the same 1.2 mm wire being treated only in cell 20 and 22 and having an increased breaking load of 1276 N with a tensile strength of 1168 MPa. In Example G, the method employs a Pipe Spray, a method of full liquid immersion where the hot wire is guided through a pipe filled with liquid, at 3 g/m in cell 20 with the breaking load increasing to 1315 N and a tensile strength increasing to 1197 MPa. In Example I, the method of full liquid immersion employs a pipe spray at 3 g/m (cell 20) and varying flows in cells 21-24 with the breaking load increasing to 1407 N and a tensile strength increasing to 1234 MPa. All examples shown herein were run at a constant wire speed of 12.5 meters per minute.


Thus, as illustrated by increasing the volume or percentage of gas 55 in quenching mixture 45 to various rates improved breaking loads and tensile strengths of the 1070 wire can be realized by the described methods.


The illustrations and examples provided herein are for explanatory purposes and are not intended to limit the scope of the appended claims. Other strand materials and metal shapes and sizes could also be accommodated by obvious changes to the apparatus and processing steps, depending on the requirements of the user.

Claims
  • 1. A method of treating metal comprising the steps of: a) heating the metal;b) subjecting the heated metal to a quenchant comprising a liquid and a gas mixture;c) controlling the liquid/gas mixture; andd) removing the treated metal from the quenchant.
  • 2. The method of claim 1 wherein heating the metal comprises the step of passing the metal through an oven.
  • 3. The method of claim 1 wherein heating the metal comprises the step of heating the metal to at least 930° C.
  • 4. The method of claim 1 wherein the step of heating the metal comprises the step of heating a steel wire of 2 mm diameter.
  • 5. The method of claim 1 wherein the step of heating the metal comprises the step of heating a steel wire of 1.2 mm diameter.
  • 6. The method of claim 4 wherein the wire diameter is between 0.90 mm and 3.5 mm.
  • 7. The method of claim 1 wherein the step of heating the metal comprises heating a carbon steel product with a carbon content of at least 0.350 percent by weight.
  • 8. The method of claim 1 wherein the step of heating the metal comprises the step of heating a carbon steel product containing chromium, boron and silicon.
  • 9. The method of claim 1 wherein subjecting the heated metal to a quenchant comprises the step of subjecting the heated metal to a plurality of cells containing liquid and gas mixtures.
  • 10. The method of claim 1 wherein subjecting the heated metal to a quenchant comprises the step of subjecting the heated metal to an aqueous liquid at about 100° C.
  • 11. The method of claim 1 wherein subjecting the heated metal to a quenchant comprises the step of subjecting the metal to a mixture having at least 4% air by volume.
  • 12. The method of claim 1 wherein subjecting the heated metal to a quenchant comprises the step of subjecting the metal to a mixture having at least 0-25% air by volume.
  • 13. The method of claim 1 wherein subjecting the heated metal to a quenchant comprises the step of subjecting the metal to a mixture having air by volume in the range of 4-25%.
  • 14. The method of claim 1 wherein controlling the liquid/gas mixture comprises the step of controlling the flow rate of the gas through the liquid.
  • 15. Apparatus for treating metal comprising: a cell, a heater, said heater communicating with said cell, said heater for maintaining the temperature of a liquid contained within said cell, a gas supply, said gas supply in communication with said cell for supplying gas to said cell.
  • 16. The apparatus of claim 15 further comprising a guide, said guide proximate said cell to direct the metal to said cell.
  • 17. The apparatus of claim 15 further comprising a liquid, said liquid contained within said cell.
  • 18. The apparatus of claim 17 wherein said liquid comprises water.
  • 19. The apparatus of claim 15 further comprising a gas, said gas directed from said gas supply into said cell.
  • 20. The apparatus of claim 19 wherein said gas comprises air.
  • 21. The apparatus of claim 15 further comprising a gas regulator, said gas regulator in communication with said gas supply.
  • 22. A treated metal having an improved tensile strength formed by the process of: a) heating a metal to a selected temperature;b) guiding the heated metal into a liquid and gas mixture to treat the metal; andc) removing the treated metal from the liquid and gas mixture.
  • 23. The metal formed as in claim 22 wherein heating the metal comprises the step of heating the metal to about 930° C.-1050° C.