Thermoform windshield stack with integrated formable mold

Information

  • Patent Grant
  • 12085731
  • Patent Number
    12,085,731
  • Date Filed
    Friday, November 3, 2023
    a year ago
  • Date Issued
    Tuesday, September 10, 2024
    2 months ago
Abstract
Manufacturing a pre-molded stack of one or more lenses to be installable on a curved substrate such as a vehicle windshield includes placing a moldable stack of one or more lenses and adhesive layer(s) on a mold, applying heat and pressure to the moldable stack to produce a pre-molded stack of one or more lenses from the moldable stack, and removing the pre-molded stack from the mold. The pre-molded stack may have a compound curvature, which may match a curvature of the curved substrate. The mold may be formed using three-dimensional shape data derived from the curved substrate, such as by optically scanning the curved substrate.
Description
STATEMENT RE: FEDERALLY SPONSORED RESEARCH/DEVELOPMENT

Not Applicable


BACKGROUND
1. Technical Field

The present disclosure relates generally to transparent coverings for windows and, more particularly, to transparent coverings having multiple lenses stacked one over the other and adhered together by adhesive.


2. Related Art

There may be various advantages to affixing transparent lenses to curved substrates such as windshields (also referred to as windscreens). Such coverings may provide protection from pitting and cracking, tinting (e.g., for privacy), thermal insulation, blocking of ultraviolet (UV) radiation, and/or decoration. A stack of such transparent lenses may allow for easy tear-away as the outermost lens becomes dirty and obstructs the driver's vision, such as might occur in vehicles for off-road use.


While the surface of a typical windshield usually exhibits a compound curvature, the transparent lenses may themselves be flat, such as in the case of polyethylene terephthalate (PET) films manufactured in a roll-to-roll process. In order to install a flat film to a compound curved windshield surface, the film may be drape formed over the windshield, e.g., by laying the film over the windshield and applying heat to the uppermost surface to shrink or stretch the film to take the shape of the windshield. However, this process may result in uneven heating or overheating, which may cause optical distortion in the film and may result in areas where the film is not adequately adhered to the windshield. In addition, the efforts of the installer to apply pressure to the film with a card or squeegee may result in permanently scratching the visible surface during installation.


BRIEF SUMMARY

The present disclosure contemplates various systems and methods for overcoming the above drawbacks accompanying the related art. One aspect of the embodiments of the present disclosure is a method of installing a stack of two or more lenses on a curved substrate. The method may include placing a moldable covering on a curved substrate, the moldable covering including a stack of two or more lenses, an adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses, and a sacrificial layer disposed on an outermost lens of the stack, the sacrificial layer including a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack. The method may include applying heat and pressure to the sacrificial layer and peeling off the sacrificial layer to reveal the stack of two or more lenses.


The curved substrate may be a compound curved substrate. The curved substrate may be a windshield.


The sacrificial layer may be more heat resistant than the outermost lens of the stack.


The sacrificial layer may be less scratch resistant than the outermost lens of the stack.


The sacrificial lens may comprise a biaxially oriented polyethylene terephthalate film. The biaxially oriented polyethylene terephthalate film may be able to withstand temperatures between room temperature and 220° C. for two hours.


The sacrificial lens may comprise an opaque polyester film. The outermost lens of the stack may comprise a transparent polyethylene terephthalate film.


Another aspect of the embodiments of the present disclosure is a moldable covering affixable to a curved substrate, the moldable covering may include a stack of two or more lenses, an adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses, and a sacrificial layer disposed on an outermost lens of the stack, the sacrificial layer including a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack, the sacrificial layer being more heat resistant than the outermost lens of the stack.


The sacrificial lens may comprise a biaxially oriented polyethylene terephthalate film. The biaxially oriented polyethylene terephthalate film may be able to withstand temperatures between room temperature and 220° C. for two hours.


The sacrificial lens may comprise an opaque polyester film. The outermost lens of the stack may comprise a transparent polyethylene terephthalate film.


Another aspect of the embodiments of the present disclosure is a moldable covering affixable to a curved substrate. The moldable covering may include a stack of two or more lenses, an adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses, and a sacrificial layer disposed on an outermost lens of the stack, the sacrificial layer including a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack, the sacrificial layer being less scratch resistant than the outermost lens of the stack.


The sacrificial lens may comprise a biaxially oriented polyethylene terephthalate film. The biaxially oriented polyethylene terephthalate film may be able to withstand temperatures between room temperature and 220° C. for two hours.


The sacrificial lens may comprise an opaque polyester film. The outermost lens of the stack may comprise a transparent polyethylene terephthalate film.


Another aspect of the embodiments of the present disclosure is a method of manufacturing a pre-molded stack of lenses to be installable on a curved substrate. The method may comprise placing a moldable stack of lenses on a mold, the moldable stack of lenses including two or more lenses and an adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses. The method may further comprise applying heat and pressure to the moldable stack of lenses to produce a pre-molded stack of lenses from the moldable stack of lenses and removing the pre-molded stack of lenses from the mold.


Another aspect of the embodiments of the present disclosure is a method of manufacturing a pre-molded stack of one or more lenses to be installable on a curved substrate. The method may comprise placing a moldable stack of one or more lenses on a mold, the moldable stack including one or more lenses and one or more adhesive layers provided respectively thereon. The method may further comprise applying heat and pressure to the moldable stack to produce a pre-molded stack of one or more lenses from the moldable stack of one or more lenses and removing the pre-molded stack of one or more lenses from the mold.


Either of the preceding two methods may comprise deriving three-dimensional shape data from the curved substrate and forming the mold using the three-dimensional shape data. The deriving of the three-dimensional shape data may include optically scanning the curved substrate. The curved substrate and the mold may be windshields of the same type. The mold may comprise a compound curved surface.


The applying of heat and pressure may include arranging a plurality of heaters on a frame positioned to direct the heaters toward the moldable stack. The applying of heat and pressure may include pressing the moldable stack with one or more rollers.


The moldable stack may include a sacrificial layer disposed on an outermost lens of the stack. The sacrificial layer may include a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack. The sacrificial layer may be more heat resistant than the outermost lens of the stack. The sacrificial layer may be less scratch resistant than the outermost lens of the stack. The sacrificial lens may comprise a biaxially oriented polyethylene terephthalate film. The biaxially oriented polyethylene terephthalate film may be able to withstand temperatures between room temperature and 220° C. for two hours. The sacrificial lens may comprise an opaque polyester film. The outermost lens of the stack may comprise a transparent polyethylene terephthalate film.


Another aspect of the embodiments of the present disclosure is a pre-molded stack of two or more lenses installable on a curved substrate. The pre-molded stack may comprise a stack of two or more lenses and an adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses. The pre-molded stack may have a compound curvature.


Each of the two or more lenses may comprise a biaxially oriented polyethylene terephthalate film.





BRIEF DESCRIPTION OF THE DRAWINGS

These and other features and advantages of the various embodiments disclosed herein will be better understood with respect to the following description and drawings, in which like numbers refer to like parts throughout, and in which:



FIG. 1 is schematic side view of a moldable covering according to an embodiment of the present disclosure;



FIG. 2 shows the moldable covering placed on a windshield at the beginning of a process of applying heat and pressure to a sacrificial layer of the moldable covering;



FIG. 3 shows the moldable covering on the windshield at the end of the process of applying heat and pressure;



FIG. 4 shows the moldable covering on the windshield as the sacrificial layer is being peeled off to reveal a stack of transparent lenses;



FIG. 5 shows the stack of transparent lenses after they have been trimmed to fit the windshield;



FIG. 6 shows an example operational flow according to an embodiment of the present disclosure;



FIG. 7 shows a moldable stack of one or more lenses according to another embodiment of the present disclosure, together with a mold for producing a pre-molded stack of lenses and a frame for positioning a plurality of heaters and/or rollers;



FIG. 8 shows an example operational flow according to another embodiment of the present disclosure; and



FIG. 9 shows an example sub-operational flow of step 840 in FIG. 8.





DETAILED DESCRIPTION

The present disclosure encompasses various embodiments of a moldable covering including a stack of two or more lenses and an installation method thereof, as well as various embodiments of a pre-molded lens stack and method of manufacture thereof. The detailed description set forth below in connection with the appended drawings is intended as a description of several currently contemplated embodiments and is not intended to represent the only form in which the disclosed invention may be developed or utilized. The description sets forth the functions and features in connection with the illustrated embodiments. It is to be understood, however, that the same or equivalent functions may be accomplished by different embodiments that are also intended to be encompassed within the scope of the present disclosure. It is further understood that relational terms such as first and second and the like are used solely to distinguish one from another entity without necessarily requiring or implying any actual such relationship in order between such entities.



FIG. 1 is schematic side view of a moldable covering 100 according to an embodiment of the present disclosure. The moldable covering 100 may be affixed to a curved substrate 10 such as a windshield as part of the process of installing a stack of lenses 110a, 110b, . . . 110n (collectively lenses 110). The installed stack of lenses 110 may provide the substrate 10 with protection, tinting, thermal insulation, blocking ultraviolet (UV) radiation, decoration, and/or the ability to peel away and discard the outermost layer 110n (and thereafter any newly revealed layers 110) as needed during the lifetime of the product. In addition to the lenses 110, the moldable covering 100 may include adhesive layers 120a, 120b, . . . 120n (collectively adhesive layers 120) provided respectively on each lens 110, such that an adhesive layer 120 is interposed between each pair of adjacent lenses 110 of the stack. On the outermost lens 110n of the stack of lenses 110, a sacrificial layer 130 may be provided to allow for an improved process of installing the stack of lenses 110 to the substrate 10. The sacrificial layer 130 may include a sacrificial lens 132 and a sacrificial adhesive 134 interposed between the sacrificial lens 132 and the outermost lens 110n of the stack of lenses 110. When installing the stack of lenses 110, heat and pressure may be applied to the sacrificial layer 130 to conform the stack of lenses 110 to the shape of the curved substrate 10. Thereafter, the sacrificial layer 130 may be peeled away to reveal the final product 140 including the installed lenses 110.


If one were to only drape form the stack of lenses 110 on the curved substrate 10 without the sacrificial layer 130, the process could result in uneven heating or overheating as explained above, as well as the possibility of permanently scratching the outermost lens 110n with a card or squeegee. The inventor has found that these difficulties stem largely from the lack of a female mold cavity to apply pressure as the stack of lenses 110 conforms to the male surface represented by the curved substrate 10. As a result, neither heat nor pressure is evenly distributed when the installer attempts to mold the stack of lenses 110 to the curved substrate 10, resulting in the stated difficulties. By providing the sacrificial layer 130 to serve as the missing female mold cavity, the disclosed moldable covering 100 may overcome these deficiencies in at least two ways. First, the sacrificial layer 130 may allow the installer to apply heat and pressure without fear of scratching or otherwise damaging the end product. The sacrificial layer 130 may simply be discarded along with any surface damage, while the underlying outermost lens 110n of the stack of lenses 110 remains unblemished. Second, as heat and pressure are applied to the stack of lenses 110 through the intervening sacrificial layer 130, the sacrificial layer 130 may serve to distribute the heat and pressure over a wider area, resulting in a more even application of heat and pressure as the sacrificial layer 130 and underlying stack of lenses 110 together conform to the shape of the curved substrate 10.


The lenses 110 may comprise a transparent polyethylene terephthalate (PET) film such as a biaxially-oriented polyethylene terephthalate (BoPET) and may be fabricated from sheets of polyester film sold under the registered trademark Mylar owned by the DuPont Company. The thickness of each lens 110 may be between 0.5 mil and 7 mil (1 mil is 0.001″), for example, 2 mil. Even after the adhesive material of the adhesive layers 120 is applied to a 2-mil thickness lens 110, the combined thickness of the 2-mil thickness lens 110 and adhesive layer 120 may still be 2 mil due to the adhesive layer 120 having only a nominal thickness.


The adhesive used in the adhesive layers 120 may be applied, for example, in selective areas around the periphery of the moldable covering 100 as described in U.S. Pat. No. 6,536,045 to Wilson, issued Mar. 25, 2003 and entitled “Tear-off Optical Stack Having Peripheral Seal Mount,” the entire contents of which is expressly incorporated herein by reference. The adhesive layers 120 may be made of a clear optical low tack material and may comprise a water-based acrylic optically clear adhesive or an oil-based clear adhesive. The adhesive layer 120a used to affix the moldable covering 100 to the substrate 10 may be the same as or different from (e.g., stronger than) that of the adhesive layers 120b, . . . 120n interposed between each pair of adjacent lenses 110 of the stack. A stronger adhesive may be used, for example, in a case where individual lenses 110 are to be torn off without removing the entire stack of lenses 110 from the substrate 10 during use. Along the same lines, the adhesive used for the adhesive layers 120b, . . . 120n interposed between each pair of adjacent lenses 110 may be stronger than the sacrificial adhesive 134 of the sacrificial layer 130, such that the sacrificial layer 130 may be torn off without removing the outermost lens 110n from the stack of lenses 110. The sacrificial adhesive 134 may similarly be a low tack material and may comprise a water-based acrylic optically clear adhesive or an oil-based clear adhesive. However, in the case of the sacrificial adhesive 134, an opaque adhesive may be used instead since the sacrificial adhesive 134 is removed in the final product 140.


The lenses 110 may be optimized for scratch resistance and/or blocking (absorbing or reflecting) UV radiation. For example, an exterior side of each lens 110 may be deposited, sprayed, laminated, or otherwise coated with a coating (e.g., silicon ester acrylate oligomer and/or acrylated urethane polyol) that is optimized for scratch resistance and/or blocking UV radiation as desired for properties suitable to the finished product 140. These properties may be relaxed in the fabrication of the sacrificial layer 130, since the sacrificial layer 130 will not be present after the installation is complete. Thus, for example, the sacrificial layer 130 may be less scratch resistant than the outermost lens 120n of the stack of lenses 120. Meanwhile, the sacrificial layer 130 may be optimized for heat resistance, for example, coated with a coating (e.g., silicon ester acrylate oligomer and/or acrylated urethane polyol) that is optimized for heat resistance, since the sacrificial layer 130 may be heated directly as part of thermoforming the moldable covering 100 to the shape of the curved substrate 10. Such heat resistance properties may be relaxed in the underlying stack of lenses 100 as these lenses may only be subjected to the heat indirectly through the sacrificial layer 130. Thus, for example, the sacrificial layer 130 may be more heat resistant than the outermost lens 110n of the stack of lenses 100.


The sacrificial layer 130 may be made of a high temperature PET, for example, one that is able to withstand temperatures between room temperature and 220° C. for two hours (e.g., without deteriorating). The high temperature PET may be a clear BoPET, allowing for observation of the underlying stack of lenses 110 during the molding process, and may, for example, be a polyester film sold under the tradename Hostaphan RBB by the Mitsubishi Polyester Film Group. Such a high temperature BoPET may be preferred when using hot air to heat the sacrificial layer 130 during the molding process. Alternatively, the sacrificial layer 130 may be made of an opaque (e.g., white) polyester film such as one sold under the tradename Hostaphan WIN by the Mitsubishi Polyester Film Group. Such an opaque polyester film may provide increased thermal uniformity when using infrared heaters to heat the sacrificial layer 130 during the molding process.


While the sacrificial layer 130 (e.g., the sacrificial lens 132 and/or the sacrificial adhesive 134) may be optimized to withstand the heat of the installation process and to evenly distribute heat and pressure to the underlying stack of lenses 110, it is generally unnecessary for the sacrificial layer 130 to meet the more stringent performance standards of the underlying stack of lenses 110. For example, the stack of lenses may be designed to meet federal standards for visible light transmission (e.g., 70%), such as may be set forth in the American National Standards Institute (ANSI) standards Z26.1-1966 and Z26.1a-1969, as well as to resist scratching (e.g., by windshield wipers) as described above and/or to absorb or reflect UV light to protect the lenses 110 from sun damage. By relaxing these requirements in the sacrificial layer 130, while at the same time providing a more robust surface for applying heat and pressure without worry during installation, the moldable covering 100 may allow for a more efficient method of installing the stack of lenses 110. With the sacrificial layer 130 acting as a female mold cavity, the layers of lenses 110 and adhesive 120 are held, form, and cure better to the curved substrate 10 and never get scratched during the installation process.



FIG. 2 shows the moldable covering 100 placed on a windshield of a car 20, the windshield serving as the substrate 10, at the beginning of a process of applying heat and pressure to the sacrificial layer 130 of the moldable covering 100. The moldable covering 100 may be adhered to the windshield by a dry mount adhesive 120a (see FIG. 1) as disclosed, for example, in U.S. Pat. No. 9,295,297 to Wilson, issued Mar. 29, 2016 and entitled “Adhesive Mountable Stack of Removable Layers,” the entire contents of which is expressly incorporated herein by reference. Alternatively, a wet mount adhesive 120a may be used as disclosed, for example, in U.S. Pat. No. 9,128,545 to Wilson, issued Sep. 8, 2015 and entitled “Touch Screen Shield,” the entire contents of which is expressly incorporated herein by reference. Since the moldable covering 100 may be flat (e.g., having been manufactured in a roll-to-roll process), the moldable covering 100 may not initially conform to the curved shape of the windshield, resulting in regions of greater or less adhesion and pockets/bubbles of air between the moldable covering 100 and the windshield. Therefore, in order to conform the moldable covering 100 to the shape of the windshield, heat and pressure may be applied using a heater 30 such as a hot air source (e.g., a heat gun or blow dryer) or an infrared heater. At the same time, pressure may be applied to the moldable covering 100 using a card or squeegee. As the installer heats and presses down on the sacrificial layer 130 of the moldable covering 100, the sacrificial layer 130 may shrink and stretch to take on the contour of the opposing curved substrate 10 (the windshield) with the stack of lenses 110 therebetween. In this way, the sacrificial layer 130 may act as a female mold cavity to thermoform the underlying stack of lenses 110 to the shape of the windshield, evenly distributing the heat and pressure to shrink and stretch the lenses 110 to the correct shape and cure the adhesive layers 120.



FIG. 3 shows the moldable covering 100 on the windshield at the end of the process of applying heat and pressure. At this stage, the moldable covering 100, including the sacrificial layer 130 as well as the underlying lenses 110, is molded to the curved shape of the windshield without air pockets/bubbles. The upper surface of the sacrificial layer 130 may have various scratches and other blemishes caused by the installer as the installer applied pressure to the moldable covering 100 using a squeegee or card. However, the underlying lenses 110 have been protected by the sacrificial layer 130 and are thus untouched.



FIG. 4 shows the moldable covering 100 on the windshield as the sacrificial layer 130 is being peeled off to reveal the stack of transparent lenses 110. Remaining on the windshield is the final product 140 (see FIG. 1) including the stack of lenses 110 and adhesive layers 120. The final product 140 may meet performance standards as described above, including federal standards for visible light transmission (e.g., 70%), as well as scratch resistance and/or UV absorption or rejection. The lenses 110 of the final product 140 may be accurately conformed to the shape of the windshield and may be free of blemishes, even on the outermost lens 110n. The peeled off sacrificial layer 130 may simply be discarded.



FIG. 5 shows the final product 140 including the stack of transparent lenses 110 after the stack of transparent lenses 110 has been trimmed to fit the windshield serving as the substrate 10. The stack of transparent lenses 110 may be trimmed using a knife such as a utility knife or box cutter with a stainless-steel blade (a carbon blade may damage the windshield). The trimming may be done after the sacrificial layer 130 has been removed from the moldable covering 100 as shown in FIG. 5, such that only the revealed final product 140 is trimmed. Alternatively, the trimming may be done prior to the removal of the sacrificial layer 130, once the moldable covering 100 has been conformed to the shape of the windshield as shown in FIG. 3. In either case, the resulting trimmed final product 140 may effectively be invisible as it matches the shape of the windshield beneath (though it may alter the coloring of the windshield as in the case of window tinting).



FIG. 6 shows an example operational flow according to an embodiment of the present disclosure. The operational flow of FIG. 6 may serve as an example method of installing the final product 140 including the stack of lenses 110 shown in FIG. 1. First, the moldable covering 100, including both the final product 140 and the sacrificial layer 130, may be placed on a curved substrate 10 such as the windshield of the car 20 shown in FIG. 2 (step 610), with the adhesive layer 120a on the windshield and the sacrificial layer 130 facing outward away from the windshield. For easier installation, the moldable covering 100 may be rough cut (e.g., using an electric film cutter) so as not to extend too far outside the windshield. The operational flow may continue with applying heat and pressure to the sacrificial layer 130 of the moldable covering 100 as described in relation to FIGS. 2 and 3 in order to thermoform the moldable covering 100 to the curved shape of the windshield (step 620). After allowing the moldable covering 100 to cool down, the operational flow may conclude with peeling off the sacrificial layer 130 to reveal the final product 140 as described in relation to FIG. 4 (step 630) and performing a final trim as described in relation to FIG. 5 (step 640). As noted above, steps 630 and 640 may be performed in the order shown in FIG. 6 or in reverse order. The final product 140 including the stack of lenses 110 is now uniformly formed and affixed to the windshield surface.


As described above, aspects of the disclosed subject matter may produce a moldable covering 100 including a stack of lenses 110 that is molded in place on the end user's vehicle windshield or other curved substrate 10. To this end, the moldable covering 100 may include a sacrificial layer 130 that protects the underlying the stack of lenses 110 and servers as a female mold cavity, allowing for the easy and effective molding of the stack of lenses 110 by the installer using commonplace equipment (e.g., blow dryer and card) without risk of uneven heating or damage to the lenses 110. Whereas these aspects may be of great benefit to a user wishing to install the stack of lenses 110 him/herself with minimal risk as described above, there may be instances where further simplification of the installation process is desirable. For example, a user may be unable or unwilling (or simply lack confidence) to apply the necessary heat and pressure to mold the moldable covering 100 to the shape of his/her windshield 10 (step 620 of FIG. 6) or to subsequently trim the moldable covering (step 640 of FIG. 6). Therefore, to further ease the burden on the installer, additional aspects of the disclosed subject matter relate to the manufacture of a pre-molded stack of lenses 110 that is already molded into the shape of the vehicle windshield or other curved substrate 10 (and optionally already trimmed). The installer can simply apply the pre-molded stack of lenses 110 to the curved substrate 10 (e.g., by revealing and/or activating the adhesive layer 120a and placing the stack of lenses 110 on the curved substrate 10) without worrying about molding and/or trimming the lenses 110 to fit the curved substrate 10.


With reference to FIGS. 1 and 7, the pre-molded stack of lenses 110 may be produced from a moldable stack 700 that may be identical to the moldable covering 100 as shown in FIG. 1 or to the previously described unmolded final product 140 thereof (i.e., the moldable covering 100 but without the sacrificial layer 130). That is, just as described above in relation to the moldable covering 100, the moldable stack 700 may include two or more lenses 110 and an adhesive layer 120 interposed between each pair of adjacent lenses from among the two or more lenses 110. (It is also noted that the final product 140 of FIG. 1 may likewise represent the pre-molded stack of lenses 110, i.e., the moldable stack 700 after it has undergone deformation as described herein.) As described in more detail below, the moldable stack 700 may typically be professionally molded to fit the curved substrate 10, using specialized equipment and a degree of expertise that poses less of a risk of uneven heating/pressure or scratching of the outermost lens 110n. Thus, the sacrificial layer 130 described above may typically be omitted. However, it is also contemplated that the sacrificial layer 130 may be included, with the moldable stack 700 thus being the same as the moldable covering 100 shown in FIG. 1.


Referring to FIG. 7, the moldable stack 700 may be placed on an appropriately shaped mold 40, in particular, one that matches the curvature (typically a compound curve) of the vehicle windshield or other substrate 10 on which the pre-molded stack of lenses 110 will eventually be installed. The mold 40 may serve as a lower (convex) mold and may comprise a compound curved surface. The mold 40 may, for example, be a windshield of the same type (e.g., model, shape, dimensions) as the substrate 10 on which the pre-molded stack of lenses 110 will be installed. In this regard, the manufacturer of the pre-molded stack of lenses 110 may maintain a variety of windshields currently available on the market to be used as respective molds 40. When an order is placed for a pre-molded stack of lenses 110, the order may include an indication of which type of windshield the stack of lenses 110 should be pre-molded to fit. The moldable stack 700 may then be molded into the pre-molded stack of lenses 110 using, as the mold 40, a windshield of the same type. Alternatively, the mold 40 may be formed using three-dimensional shape data of the windshield or other curved substrate 10 on which the pre-molded stack of lenses 110 will be installed. For example, the curved substrate 10 may be optically scanned to derive three-dimensional shape data such as a polygonal model (e.g., a wireframe), and the mold 40 may be formed to match the substrate 10 using the derived three-dimensional shape data. In this way, the mold 40 may be custom-formed to match the customer's windshield exactly.


Various techniques may be used to evenly apply heat and pressure to the moldable stack 700 while the moldable stack 700 is on the mold 40. FIG. 7 illustrates the use of a frame 50 (e.g., an aluminum truss or other lightweight support structure) that may be provided in proximity to the mold 40 and may support a plurality of heaters 60 for heating the moldable stack 700. The heaters 70 (e.g., hot air sources and/or infrared heaters) may be arranged on the frame 50 and directed toward the moldable stack 700. It is contemplated, for example, that the frame 50 may define a grid of attachment points, such as may be provided along the illustrated horizontal and vertical bars making up the example frame 50, with the heaters 60 being freely attachable to the frame 50 so as to be evenly spaced over the moldable stack 700 as desired. The exact positioning of the heaters 60 may be adjusted as needed depending on the size and shape of the mold 40, for example. While heating the moldable stack 700 with the heaters 60, the moldable stack 700 may be pressed with one or more rollers 70, which may likewise be attached to the frame 50, for example, on one or more tracks and/or pivot points. The rollers 70 may be made of a high-density foam and may typically comprise a pair of rollers 70 that press down on the moldable stack 700 at the middle and roll outward away from each other (in the direction of the arrows in FIG. 7) in order to press the moldable stack 700 downward against the mold 40 while allowing the material of the lenses 110 to deform outward.



FIG. 8 shows an example operational flow according to another embodiment of the present disclosure, with FIG. 9 showing an example sub-operational flow of step 840 in FIG. 8. The operational flow of FIGS. 8 and 9 may serve as an example method of manufacturing a pre-molded stack of lenses 110 to be installable on a curved substrate 10. The operational flow may begin with deriving three-dimensional shape data associated with the curved substrate 10 on which the pre-molded stack of lenses 110 will eventually be installed (step 810), for example, by optically scanning the substrate 10, and forming a mold 40 (see FIG. 7) using the three-dimensional shape data (step 820). If the mold 40 is instead formed in advance, such as in a case where a variety of known windshield types are used as molds 40 as described above, steps 810 and 820 may be omitted. In this case, the mold 40 may simply be selected according to the particular curved substrate 10 on which the pre-molded stack of lenses 110 is intended to be installed. In either case, the operational flow may continue with placing the moldable stack 700 (having the lenses 110) on the mold 40 (step 830). As explained above, the moldable stack 700 may be identical to the moldable covering 100 shown in FIG. 1 or may omit the sacrificial layer 130.


Once the moldable stack 700 is on the mold 40, the operational flow of FIG. 8 may continue with applying heat and pressure to the moldable stack 700, thus producing the pre-molded stack of lenses 110 (step 840). In some cases, the process of applying heat and pressure may proceed in exactly the same was as described above in relation to FIGS. 2-5, except that the mold 40 is used instead of the actual substrate 10 where the pre-molded stack of lenses 110 will eventually be installed. In the case of using a simple handheld heat source and a squeegee or card to apply pressure, it may likewise be beneficial to the manufacturer of the pre-molded stack of lenses 110 for the moldable stack 700 to include the sacrificial layer 130. Preferably, however, specialized equipment may be used to ensure even heating and safe application of pressure without scratching of the outermost lens 110, rendering the sacrificial layer 130 unnecessary. For example, referring to the sub-operational flow of FIG. 9, the application of heat and pressure may be achieved by arranging heaters 60 on a frame 50 to direct the heaters 60 toward the moldable stack 700 as shown in FIG. 7 (step 842) and, further, by pressing the moldable stack 700 with one or more rollers 70 (step 844). In this way, heat and pressure may be evenly applied to the moldable stack 700 to promote the needed shrinking and stretching of the lenses 110 and curing of the adhesive layers 120.


After adequate heat and pressure has been applied to conform the moldable stack 700 to the shape of the mold 40, and typically following cooling and trimming of excess material around the mold 40 as described in relation to FIG. 5, above (as well as peeling off of the sacrificial layer 130, if applicable), the resulting pre-molded stack of lenses 110 may be removed from the mold 40 (step 850). The pre-molded stack of lenses 110 may then be shipped or otherwise delivered to the customer, who may install it on his/her own windshield or other curved substrate 10 with minimal effort (step 860). For example, a release liner or backing film may be provided on the innermost adhesive layer 120a of the pre-molded stack of lenses 110 during delivery, or the adhesive layer 120a may otherwise be in an inactive state. The customer may simply remove the release liner and place the stack of lenses 110 on his/her windshield 10, or may simply place the stack of lenses 110 on the windshield 10 and activate the adhesive layer 120a (e.g., by pressing the stack of lenses 110 against the windshield 10 in the case of a pressure sensitive adhesive). Because the stack of lenses 110 has been pre-molded (and optionally pre-trimmed) to fit the windshield 10, the customer need not concern him/herself with the process of molding the lenses 110 and requires no expertise or special equipment.


In the example of FIG. 1, which may illustrate both the moldable covering 100 and equally the moldable stack 700 (or pre-molded stack after deformation), three lenses 110 are shown. However, it is contemplated that the moldable covering 100, moldable stack 700, or pre-molded stack of lenses 110 may include a stack of four or more lenses 110, or a stack of two lenses 110 or even a single lens 110, with the number of lenses 110 depending on the particular application. Counterintuitively, the inventor has found that a stack of multiple lenses 110 is easier to thermoform to a curved substrate 10 (or to a mold 40) than a stack having a single lens 110.


Throughout this disclosure, the word “transparent” is used broadly to encompass any materials that can be seen through. The word “transparent” is not intended to exclude translucent, hazy, frosted, colored, or tinted materials.


The coatings described throughout this disclosure may be applied according to known methods such as spin coating, dip coating, or vacuum deposition.


The above description is given by way of example, and not limitation. Given the above disclosure, one skilled in the art could devise variations that are within the scope and spirit of the invention disclosed herein. Further, the various features of the embodiments disclosed herein can be used alone, or in varying combinations with each other and are not intended to be limited to the specific combination described herein. Thus, the scope of the claims is not to be limited by the illustrated embodiments.

Claims
  • 1. A pre-molded stack of two or more lenses installable on a curved substrate, the pre-molded stack comprising: a stack of two or more lenses not including or affixed to the curved substrate; andan adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses;wherein the pre-molded stack has a compound curvature.
  • 2. The pre-molded stack of claim 1, wherein each of the two or more lenses comprises a biaxially oriented polyethylene terephthalate film.
  • 3. The pre-molded stack of claim 1, further comprising a sacrificial layer disposed on an outermost lens of the stack, the sacrificial layer including a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack.
  • 4. The pre-molded stack of claim 3, wherein the sacrificial layer is more heat resistant than the outermost lens of the stack.
  • 5. The pre-molded stack of claim 4, wherein the sacrificial layer is less scratch resistant than the outermost lens of the stack.
  • 6. The pre-molded stack of claim 3, wherein the sacrificial layer is less scratch resistant than the outermost lens of the stack.
  • 7. The pre-molded stack of claim 3, wherein the sacrificial lens comprises a biaxially oriented polyethylene terephthalate film.
  • 8. The pre-molded stack of claim 7, wherein the biaxially oriented polyethylene terephthalate film can withstand temperatures between room temperature and 220° C. for two hours.
  • 9. The pre-molded stack of claim 3, wherein the sacrificial lens comprises an opaque polyester film.
  • 10. The pre-molded stack of claim 9, wherein the outermost lens of the stack comprises a transparent polyethylene terephthalate film.
  • 11. A pre-molded stack of two or more lenses installable on a windshield, the pre-molded stack comprising: a stack of two or more lenses not including or affixed to the windshield; andan adhesive layer interposed between each pair of adjacent lenses from among the two or more lenses;wherein the pre-molded stack has a compound curvature.
  • 12. The pre-molded stack of claim 11, wherein each of the two or more lenses comprises a biaxially oriented polyethylene terephthalate film.
  • 13. The pre-molded stack of claim 11, further comprising a sacrificial layer disposed on an outermost lens of the stack, the sacrificial layer including a sacrificial lens and a sacrificial adhesive interposed between the sacrificial lens and the outermost lens of the stack.
  • 14. The pre-molded stack of claim 13, wherein the sacrificial layer is more heat resistant than the outermost lens of the stack.
  • 15. The pre-molded stack of claim 14, wherein the sacrificial layer is less scratch resistant than the outermost lens of the stack.
  • 16. The pre-molded stack of claim 13, wherein the sacrificial layer is less scratch resistant than the outermost lens of the stack.
  • 17. The pre-molded stack of claim 13, wherein the sacrificial lens comprises a biaxially oriented polyethylene terephthalate film.
  • 18. The pre-molded stack of claim 17, wherein the biaxially oriented polyethylene terephthalate film can withstand temperatures between room temperature and 220° C. for two hours.
  • 19. The pre-molded stack of claim 13, wherein the sacrificial lens comprises an opaque polyester film.
  • 20. The pre-molded stack of claim 19, wherein the outermost lens of the stack comprises a transparent polyethylene terephthalate film.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a division of U.S. patent application Ser. No. 17/813,494, filed Jul. 19, 2022 and entitled “Thermoform Windshield Stack With Integrated Formable Mold,” which is a continuation-in-part of U.S. patent application Ser. No. 16/778,928, filed Jan. 31, 2020, now U.S. Pat. No. 11,524,493, issued Dec. 13, 2022 and entitled “Thermoform Windshield Stack With Integrated Formable Mold,”, which relates to and claims the benefit of U.S. Provisional Application No. 62/799,880, filed Feb. 1, 2019 and entitled “Thermoform Windshield Stack With Integrated Formable Mold,” the entire contents of each of which is expressly incorporated herein by reference.

US Referenced Citations (567)
Number Name Date Kind
1337036 Bergmann Apr 1920 A
1366907 Dunand Feb 1921 A
2138086 Blodjer Nov 1938 A
2248331 Blodjer Jul 1941 A
2328687 Serr Sep 1943 A
2339280 Madson Jan 1944 A
2354415 Woodard Jul 1944 A
2461604 Huntsman Feb 1949 A
2511329 Craig Jun 1950 A
2546117 Whelan Mar 1951 A
2563125 Malcom, Jr. Aug 1951 A
2569715 Green Oct 1951 A
2640068 Schaefer et al. May 1953 A
2736109 Scholl Feb 1956 A
2923944 Lindblom Feb 1960 A
2963708 Herbine et al. Dec 1960 A
3095575 Radov Jul 1963 A
3298031 Morgan Jan 1967 A
3475766 Raschke Nov 1969 A
3577565 Feldmann et al. May 1971 A
3605115 Bohner Sep 1971 A
3685054 Raschke Aug 1972 A
3774239 Kotzar Nov 1973 A
3785102 Amos Jan 1974 A
3797042 Gager Mar 1974 A
3810815 Welhart et al. May 1974 A
3868293 Selph Feb 1975 A
3937863 Moore Feb 1976 A
3948662 Alston et al. Apr 1976 A
3950580 Boudet Apr 1976 A
3987569 Chase Oct 1976 A
4063740 Mader Dec 1977 A
4076373 Moretti Feb 1978 A
4090464 Bishopp et al. May 1978 A
D249597 Dillon Sep 1978 S
4138746 Bergmann Feb 1979 A
D254638 Bay, Jr. Apr 1980 S
4204231 Permenter May 1980 A
4248762 Hornibrook et al. Feb 1981 A
4248918 Hornibrook et al. Feb 1981 A
4268134 Gulati et al. May 1981 A
4273098 Silverstein Jun 1981 A
4301193 Zuk Nov 1981 A
4332861 Franz et al. Jun 1982 A
4333983 Allen Jun 1982 A
4380563 Ayotte Apr 1983 A
4528701 Smith Jul 1985 A
4557980 Hodnett, III Dec 1985 A
4582764 Allerd et al. Apr 1986 A
4625341 Broersma Dec 1986 A
4658515 Oatman Apr 1987 A
4696860 Epperson Sep 1987 A
4701965 Landis Oct 1987 A
4716601 Mcneal Jan 1988 A
4726074 Baclit et al. Feb 1988 A
4729179 Quist, Jr. Mar 1988 A
4769265 Coburn, Jr. Sep 1988 A
D299767 Hsin Feb 1989 S
4842919 David et al. Jun 1989 A
4850049 Landis et al. Jul 1989 A
4852185 Olson Aug 1989 A
4852186 Landis Aug 1989 A
4853974 Olim Aug 1989 A
4856535 Forbes Aug 1989 A
4864653 Landis Sep 1989 A
4867178 Smith Sep 1989 A
4884296 Nix, Jr. Dec 1989 A
4884302 Foehl Dec 1989 A
4889754 Vargas Dec 1989 A
D306363 Stackhouse et al. Feb 1990 S
4907090 Ananian Mar 1990 A
4911964 Corbo Mar 1990 A
D307065 Friedman Apr 1990 S
4920576 Landis May 1990 A
4934792 Tovi Jun 1990 A
4945573 Landis Aug 1990 A
4950445 Salce et al. Aug 1990 A
D311263 Russell Oct 1990 S
4964171 Landis Oct 1990 A
4965887 Paoluccio et al. Oct 1990 A
4973511 Farmer et al. Nov 1990 A
4975981 Ray Dec 1990 A
5000528 Kawakatsu Mar 1991 A
5002326 Spicer et al. Mar 1991 A
D318147 Russell Jul 1991 S
5035004 Koester Jul 1991 A
D319449 Millar Aug 1991 S
5046195 Koritan Sep 1991 A
D321268 Nix, Jr. Oct 1991 S
5052054 Birum Oct 1991 A
5054480 Bare et al. Oct 1991 A
5067475 Posnansky Nov 1991 A
5071206 Hood et al. Dec 1991 A
H1023 Wiseman Mar 1992 H
5104929 Bilkadi Apr 1992 A
5113528 Burke, Jr. et al. May 1992 A
D331820 Scanlon Dec 1992 S
D333366 Brown Feb 1993 S
5183700 Austin Feb 1993 A
5194293 Foster Mar 1993 A
5201077 Dondlinger Apr 1993 A
5206956 Olson May 1993 A
5208916 Kelman May 1993 A
5239406 Lynam Aug 1993 A
5318685 O'Shaughnessy Jun 1994 A
D349177 Russell Jul 1994 S
D349178 Russell Jul 1994 S
5327180 Hester, III et al. Jul 1994 A
D349362 Russell Aug 1994 S
5364671 Gustafson Nov 1994 A
5365615 Piszkin Nov 1994 A
D353691 Scanlon Dec 1994 S
D354588 Russell Jan 1995 S
D354589 Russell Jan 1995 S
5420649 Lewis May 1995 A
D359586 Lofton Jun 1995 S
D361160 Russell Aug 1995 S
5443877 Kramer et al. Aug 1995 A
D362086 Russell Sep 1995 S
5468247 Matthai et al. Nov 1995 A
5471036 Sperbeck Nov 1995 A
5473778 Bell Dec 1995 A
5486883 Candido Jan 1996 A
5507332 McKinnon Apr 1996 A
5510173 Pass et al. Apr 1996 A
5512116 Campfield Apr 1996 A
5523132 Zhang et al. Jun 1996 A
RE35318 Warman Aug 1996 E
5544361 Fine et al. Aug 1996 A
5553608 Reese et al. Sep 1996 A
5555570 Bay Sep 1996 A
5557683 Eubanks Sep 1996 A
5584130 Perron Dec 1996 A
5592698 Woods Jan 1997 A
5593786 Parker et al. Jan 1997 A
5622580 Mannheim Apr 1997 A
5633049 Bilkadi et al. May 1997 A
5668612 Hung Sep 1997 A
5671483 Reuber Sep 1997 A
5673431 Batty Oct 1997 A
5687420 Chong Nov 1997 A
5694650 Hong Dec 1997 A
5702415 Matthai et al. Dec 1997 A
5709825 Shih Jan 1998 A
5740560 Muoio Apr 1998 A
5792535 Weder Aug 1998 A
5806102 Park Sep 1998 A
5815848 Jarvis Oct 1998 A
5819311 Lo Oct 1998 A
5846659 Lower et al. Dec 1998 A
D404849 Desy Jan 1999 S
5885704 Peiffer et al. Mar 1999 A
5896991 Hippely et al. Apr 1999 A
5924129 Gill Jul 1999 A
5937596 Leeuwenburgh et al. Aug 1999 A
5956175 Hojnowski Sep 1999 A
5972453 Akiwa et al. Oct 1999 A
5991072 Solyntjes et al. Nov 1999 A
5991081 Haaland et al. Nov 1999 A
5991930 Sorrentino Nov 1999 A
D418256 Caruana Dec 1999 S
6008299 Mcgrath et al. Dec 1999 A
6049419 Wheatley et al. Apr 2000 A
6085358 Cogan Jul 2000 A
6173447 Arnold Jan 2001 B1
6217099 Mckinney et al. Apr 2001 B1
6221112 Snider Apr 2001 B1
6237147 Brockman May 2001 B1
6250765 Murakami Jun 2001 B1
6305073 Badders Oct 2001 B1
6347401 Joyce Feb 2002 B1
6375865 Paulson et al. Apr 2002 B1
6378133 Daikuzono Apr 2002 B1
6381750 Mangan May 2002 B1
6385776 Linday May 2002 B2
6388813 Wilson et al. May 2002 B1
6403005 Mientus et al. Jun 2002 B1
6416872 Maschwitz Jul 2002 B1
6432522 Friedman et al. Aug 2002 B1
6461709 Janssen et al. Oct 2002 B1
6469752 Ishikawa et al. Oct 2002 B1
6481019 Diaz et al. Nov 2002 B2
6491390 Provost Dec 2002 B1
6506496 Frugier et al. Jan 2003 B1
6531180 Takushima et al. Mar 2003 B1
6536045 Wilson et al. Mar 2003 B1
6536589 Chang Mar 2003 B2
6555235 Aufderheide et al. Apr 2003 B1
6559902 Kusuda et al. May 2003 B1
6576349 Lingle et al. Jun 2003 B2
6584614 Hogg Jul 2003 B2
6592950 Toshima et al. Jul 2003 B1
6614423 Wong et al. Sep 2003 B1
6622311 Diaz et al. Sep 2003 B2
D480838 Martin Oct 2003 S
6654071 Chen Nov 2003 B2
6660389 Liu et al. Dec 2003 B2
6662371 Shin Dec 2003 B2
6667738 Murphy Dec 2003 B2
6739718 Jung May 2004 B1
6745396 Landis et al. Jun 2004 B1
6750922 Benning Jun 2004 B1
6773778 Onozawa et al. Aug 2004 B2
6773816 Tsutsumi Aug 2004 B2
6777055 Janssen et al. Aug 2004 B2
6800378 Hawa et al. Oct 2004 B2
6811857 Bravet et al. Nov 2004 B1
6838610 De Moraes Jan 2005 B2
6841190 Liu et al. Jan 2005 B2
6847492 Wilson et al. Jan 2005 B2
6864882 Newton Mar 2005 B2
6870686 Wilson et al. Mar 2005 B2
6879319 Cok Apr 2005 B2
6907617 Johnson Jun 2005 B2
6911593 Mazumder et al. Jun 2005 B2
6922850 Arnold Aug 2005 B1
6952950 Doe et al. Oct 2005 B2
6967044 O'Brien Nov 2005 B1
D512797 Canavan et al. Dec 2005 S
6973677 Diaz et al. Dec 2005 B2
6995976 Richardson Feb 2006 B2
7070837 Ross Jul 2006 B2
7071927 Blanchard Jul 2006 B2
D526446 Cowan et al. Aug 2006 S
7097080 Cox Aug 2006 B2
7101810 Bond et al. Sep 2006 B2
7103920 Otterson Sep 2006 B1
7143979 Wood et al. Dec 2006 B2
7184217 Wilson et al. Feb 2007 B2
D541991 Lawrence May 2007 S
7215473 Fleming May 2007 B2
7226176 Huang Jun 2007 B1
7238401 Dietz Jul 2007 B1
7311956 Pitzen Dec 2007 B2
D559442 Regelbrugge et al. Jan 2008 S
7344241 Baek Mar 2008 B2
7351470 Draheim et al. Apr 2008 B2
D569557 Cho May 2008 S
7389869 Mason, Jr. Jun 2008 B2
7410684 Mccormick Aug 2008 B2
7425369 Oakey et al. Sep 2008 B2
D586052 Elias Feb 2009 S
7495895 Carnevali Feb 2009 B2
7597441 Farwig Oct 2009 B1
7629052 Brumwell Dec 2009 B2
7631365 Mahan Dec 2009 B1
7663047 Hanuschak Feb 2010 B2
7709095 Persoone et al. May 2010 B2
7722921 Shimoda et al. May 2010 B2
7727615 Kato et al. Jun 2010 B2
7735156 VanDerWoude et al. Jun 2010 B2
7752682 Vanderwoude et al. Jul 2010 B2
7812077 Borade et al. Oct 2010 B2
7858001 Qin et al. Dec 2010 B2
7937775 Manzella, Jr. et al. May 2011 B2
7957524 Chipping Jun 2011 B2
8011137 Durfield et al. Sep 2011 B2
8024818 Davenport Sep 2011 B1
8044942 Leonhard et al. Oct 2011 B1
8101277 Logan et al. Jan 2012 B2
8234722 VanDerWoude et al. Aug 2012 B2
8261375 Reaux Sep 2012 B1
8282234 VanDerWoude et al. Oct 2012 B2
8292347 Drake Oct 2012 B1
8294843 Hollaway Oct 2012 B2
8316470 McNeal et al. Nov 2012 B2
8361260 Wilson et al. Jan 2013 B2
8407818 VanDerWoude et al. Apr 2013 B2
D683077 Klotz et al. May 2013 S
8455105 Hobeika et al. Jun 2013 B2
8487277 Labrot et al. Jul 2013 B2
8519362 Labrot et al. Aug 2013 B2
D692187 Isobe Oct 2013 S
D692189 Isobe Oct 2013 S
8567596 Mason, Jr. Oct 2013 B1
8693102 Wilson et al. Apr 2014 B2
8734953 Sablayrolles et al. May 2014 B2
8819869 VanDerWoude et al. Sep 2014 B2
8859080 Thellier et al. Oct 2014 B2
8889801 Liao et al. Nov 2014 B2
8918198 Atanasoff Dec 2014 B2
8974620 Wilson et al. Mar 2015 B2
D726378 Wako Apr 2015 S
8999509 Port et al. Apr 2015 B2
9023162 Mccormick et al. May 2015 B2
9104256 Wilson et al. Aug 2015 B2
9128545 Wilson et al. Sep 2015 B2
9150763 Lopez et al. Oct 2015 B2
9161858 Capers et al. Oct 2015 B2
9170415 Mansuy Oct 2015 B2
9173437 VanDerWoude et al. Nov 2015 B2
9204823 Derenne et al. Dec 2015 B2
9274625 Wilson Mar 2016 B2
9295297 Wilson Mar 2016 B2
D759900 Cummings et al. Jun 2016 S
9442306 Hines et al. Sep 2016 B1
9471163 Wilson et al. Oct 2016 B2
9477022 Laluet et al. Oct 2016 B2
9526290 Wilson Dec 2016 B2
9575231 Chu et al. Feb 2017 B2
D781507 Huh Mar 2017 S
D781508 Huh Mar 2017 S
9629407 Foster Apr 2017 B2
9671622 Vetrini et al. Jun 2017 B1
9706808 Sclafani et al. Jul 2017 B2
9726940 Tomiyasu Aug 2017 B2
D805256 Yang Dec 2017 S
9846265 Ehrensperger et al. Dec 2017 B2
9905297 Best Feb 2018 B2
D815190 Dellemann Apr 2018 S
9968155 Wilson May 2018 B2
10070678 Wilson Sep 2018 B2
10165819 Klotz et al. Jan 2019 B2
10201207 VanDerWoude et al. Feb 2019 B2
10226095 Wilson Mar 2019 B2
10227501 Hwang et al. Mar 2019 B2
D849240 Guo et al. May 2019 S
10300680 Laluet May 2019 B2
D850256 Ryszawy Jun 2019 S
10321731 Wilson Jun 2019 B2
10345934 Wilson et al. Jul 2019 B2
10384084 Isham et al. Aug 2019 B2
10427385 Wilson et al. Oct 2019 B2
10449397 VanDerWoude et al. Oct 2019 B2
10520756 Gallina et al. Dec 2019 B2
10537236 Bennett et al. Jan 2020 B2
D879384 Sato Mar 2020 S
D882182 Fekete Apr 2020 S
10620670 Wilson et al. Apr 2020 B2
10625663 Laluet Apr 2020 B2
10687569 Mcdirmid Jun 2020 B1
10688757 Laluet et al. Jun 2020 B2
10716172 Weissenberger et al. Jul 2020 B2
10716986 Winter et al. Jul 2020 B2
10739669 Schiavoni et al. Aug 2020 B2
10831092 Schiavoni et al. Nov 2020 B2
10874163 VanDerWoude et al. Dec 2020 B2
D907299 Brown, II et al. Jan 2021 S
D907300 Brown, II et al. Jan 2021 S
11027528 Laluet et al. Jun 2021 B2
D925129 Wilson Jul 2021 S
D925834 Babin et al. Jul 2021 S
11090516 VanDerWoude et al. Aug 2021 B2
11141959 Wilson et al. Oct 2021 B2
11147323 Wilson Oct 2021 B1
11307329 Wilson Apr 2022 B1
11480801 Morris et al. Oct 2022 B1
11490667 Wilson Nov 2022 B1
11510718 Childers et al. Nov 2022 B2
11548356 Wilson et al. Jan 2023 B2
11579339 Thothadri et al. Feb 2023 B2
20010035936 Maisnik Nov 2001 A1
20020025441 Hieda et al. Feb 2002 A1
20020036362 Chigira et al. Mar 2002 A1
20020101411 Chang Aug 2002 A1
20020109922 Wilson et al. Aug 2002 A1
20020114934 Liu et al. Aug 2002 A1
20020122925 Liu et al. Sep 2002 A1
20020159159 Wilson et al. Oct 2002 A1
20020195910 Hus et al. Dec 2002 A1
20030012936 Draheim et al. Jan 2003 A1
20030087054 Janssen et al. May 2003 A1
20030110613 Ross Jun 2003 A1
20040004605 David Jan 2004 A1
20040109096 Anderson et al. Jun 2004 A1
20040121105 Janssen et al. Jun 2004 A1
20040139530 Yan Jul 2004 A1
20040202812 Congard et al. Oct 2004 A1
20040227722 Friberg et al. Nov 2004 A1
20040238690 Wood et al. Dec 2004 A1
20040246386 Thomas et al. Dec 2004 A1
20040258933 Enniss et al. Dec 2004 A1
20050002108 Wilson et al. Jan 2005 A1
20050015860 Reaux Jan 2005 A1
20050071909 Diaz et al. Apr 2005 A1
20050133035 Yahiaoui et al. Jun 2005 A1
20050180877 Usami et al. Aug 2005 A1
20050186415 Mccormick et al. Aug 2005 A1
20050188821 Yamashita et al. Sep 2005 A1
20050200154 Barbee et al. Sep 2005 A1
20050249957 Jing et al. Nov 2005 A1
20050260343 Han Nov 2005 A1
20060024494 Amano et al. Feb 2006 A1
20060052167 Boddicker et al. Mar 2006 A1
20060056030 Fukuda et al. Mar 2006 A1
20060057399 Persoone et al. Mar 2006 A1
20060114245 Masters et al. Jun 2006 A1
20060138694 Biernath et al. Jun 2006 A1
20060158609 Heil Jul 2006 A1
20060177654 Shoshi Aug 2006 A1
20060204776 Chen et al. Sep 2006 A1
20060254088 Mccormick Nov 2006 A1
20060285218 Wilson et al. Dec 2006 A1
20070019300 Wilson et al. Jan 2007 A1
20070181456 Kusuda et al. Aug 2007 A1
20070211002 Zehner et al. Sep 2007 A1
20070212508 Mase Sep 2007 A1
20070229962 Mason Oct 2007 A1
20070234592 Crates Oct 2007 A1
20070234888 Rotolo de Moraes Oct 2007 A1
20070286995 Li et al. Dec 2007 A1
20080014446 Donea et al. Jan 2008 A1
20080030631 Gallagher Feb 2008 A1
20080030675 Dillon Feb 2008 A1
20080055258 Sauers Mar 2008 A1
20080118678 Huang et al. May 2008 A1
20080151177 Wang Jun 2008 A1
20080160321 Padiyath et al. Jul 2008 A1
20080176018 Enniss et al. Jul 2008 A1
20080192351 Miyagawa et al. Aug 2008 A1
20080231979 Chen Sep 2008 A1
20080256688 Bruce Oct 2008 A1
20080286500 Sussner et al. Nov 2008 A1
20080292820 Padiyath et al. Nov 2008 A1
20090011205 Thiel Jan 2009 A1
20090026095 Lofland et al. Jan 2009 A1
20090054115 Horrdin et al. Feb 2009 A1
20090086415 Chipping Apr 2009 A1
20090087655 Yamada et al. Apr 2009 A1
20090105437 Determan et al. Apr 2009 A1
20090119819 Thompson May 2009 A1
20090181242 Enniss et al. Jul 2009 A1
20090233032 Craig Sep 2009 A1
20090239045 Kato et al. Sep 2009 A1
20090239048 Sugihara et al. Sep 2009 A1
20100026646 Xiao et al. Feb 2010 A1
20100033442 Kusuda et al. Feb 2010 A1
20100102197 Mcintyre Apr 2010 A1
20100102476 Higgins Apr 2010 A1
20100122402 Tipp May 2010 A1
20100146679 Heil Jun 2010 A1
20100238119 Dubrovsky et al. Sep 2010 A1
20100245273 Hwang et al. Sep 2010 A1
20100270189 Pedersen, II et al. Oct 2010 A1
20110007388 Wilson et al. Jan 2011 A1
20110010994 Wilson et al. Jan 2011 A1
20110012841 Lin Jan 2011 A1
20110013273 Wilson et al. Jan 2011 A1
20110014481 Wilson et al. Jan 2011 A1
20110035936 Lee Feb 2011 A1
20110052864 Son Mar 2011 A1
20110073773 Labrot et al. Mar 2011 A1
20110097574 Faldysta et al. Apr 2011 A1
20110119801 Wright May 2011 A1
20110165361 Sherman et al. Jul 2011 A1
20110168261 Welser et al. Jul 2011 A1
20110267793 Cohen et al. Nov 2011 A1
20110271497 Suh et al. Nov 2011 A1
20110277361 Nichol et al. Nov 2011 A1
20110279383 Wilson et al. Nov 2011 A1
20120003431 Huang Jan 2012 A1
20120030095 Marshall et al. Feb 2012 A1
20120047614 Choi Mar 2012 A1
20120068083 Labrot et al. Mar 2012 A1
20120070603 Hsu Mar 2012 A1
20120081792 Neuffer Apr 2012 A1
20120137414 Saylor Jun 2012 A1
20120180204 Hawkins Jul 2012 A1
20120183712 Leonhard et al. Jul 2012 A1
20120188743 Wilson et al. Jul 2012 A1
20120200816 Krasnov et al. Aug 2012 A1
20120291173 Gleason et al. Nov 2012 A1
20130004719 Thellier et al. Jan 2013 A1
20130045371 O'Donnell Feb 2013 A1
20130083285 McNeal et al. Apr 2013 A1
20130089688 Wilson et al. Apr 2013 A1
20130098543 Reuter et al. Apr 2013 A1
20130141693 McCabe et al. Jun 2013 A1
20130145525 Arenson et al. Jun 2013 A1
20130222913 Tomoda et al. Aug 2013 A1
20130247286 Vanderwoude et al. Sep 2013 A1
20130252001 Sablayrolles et al. Sep 2013 A1
20130293959 Mcdonald Nov 2013 A1
20140020153 Romanski et al. Jan 2014 A1
20140050909 Choi et al. Feb 2014 A1
20140220283 Wilson et al. Aug 2014 A1
20140259321 Arnold Sep 2014 A1
20140289937 Capers et al. Oct 2014 A1
20150033431 Hofer Kraner et al. Feb 2015 A1
20150131047 Saylor et al. May 2015 A1
20150138627 Ehrensperger et al. May 2015 A1
20150192707 Ehrensperger et al. Jul 2015 A1
20150202847 Johnson et al. Jul 2015 A1
20150234209 Miyamoto et al. Aug 2015 A1
20150258715 Ohta Sep 2015 A1
20150294656 Hanuschak Oct 2015 A1
20150309609 Wilson et al. Oct 2015 A1
20150349147 Xi et al. Dec 2015 A1
20150359675 Wilson Dec 2015 A1
20160011414 Joseph Jan 2016 A1
20160023442 Faris Jan 2016 A1
20160050990 Hayes Feb 2016 A1
20160073720 Niedrich Mar 2016 A1
20160231834 Hardi Aug 2016 A1
20160259102 Taka Sep 2016 A1
20160271922 Uzawa et al. Sep 2016 A1
20160291543 Saito Oct 2016 A1
20160318227 Kim et al. Nov 2016 A1
20170052286 Hines et al. Feb 2017 A1
20170071792 Wilson et al. Mar 2017 A1
20170079364 Paulson Mar 2017 A1
20170129219 Uebelacker et al. May 2017 A1
20170173923 Davis et al. Jun 2017 A1
20170192131 Wilson et al. Jul 2017 A1
20170208878 Kakinuma et al. Jul 2017 A1
20170232713 Mannheim Astete et al. Aug 2017 A1
20170281414 Wilson Oct 2017 A1
20170299898 Gallina et al. Oct 2017 A1
20170305245 Lux et al. Oct 2017 A1
20170318877 Yahiaoui et al. Nov 2017 A1
20180029337 Wilson et al. Feb 2018 A1
20180042324 King Feb 2018 A1
20180052334 Repko Feb 2018 A1
20180094164 Ito et al. Apr 2018 A1
20180148578 Ohta et al. May 2018 A1
20180161208 Huh Jun 2018 A1
20180229480 Chung Aug 2018 A1
20180236753 Wykoff, II et al. Aug 2018 A1
20180242403 Weissenberger et al. Aug 2018 A1
20180295925 Gagliardo et al. Oct 2018 A1
20180338550 Boulware et al. Nov 2018 A1
20180370195 Laluet et al. Dec 2018 A1
20190001629 Laluet Jan 2019 A1
20190001870 Laluet Jan 2019 A1
20190021430 Elliott Jan 2019 A1
20190037948 Romanski et al. Feb 2019 A1
20190116300 Okuno Apr 2019 A1
20190118057 Winter et al. Apr 2019 A1
20190209912 Isserow et al. Jul 2019 A1
20190212474 Le Quang et al. Jul 2019 A1
20190346591 Thothadri et al. Nov 2019 A1
20190389182 Wilson et al. Dec 2019 A1
20200012180 Schiavoni et al. Jan 2020 A1
20200100657 Lee et al. Apr 2020 A1
20200115519 Phillips et al. Apr 2020 A1
20200124768 Wilson Apr 2020 A1
20200134773 Pinter et al. Apr 2020 A1
20200154808 Inouye May 2020 A1
20200178622 Jascomb et al. Jun 2020 A1
20200247102 Wilson et al. Aug 2020 A1
20200261055 Zwierstra et al. Aug 2020 A1
20200276792 Laluet et al. Sep 2020 A1
20200281301 Wynalda, Jr. Sep 2020 A1
20200310494 Ahn et al. Oct 2020 A1
20200359718 Jefferis et al. Nov 2020 A1
20200370727 Berard et al. Nov 2020 A1
20200375272 Ulmer et al. Dec 2020 A1
20200384740 Berard et al. Dec 2020 A1
20200384747 Fukuda et al. Dec 2020 A1
20210030095 Reicher Feb 2021 A1
20210162645 Wilson et al. Jun 2021 A1
20210283994 Wilson Sep 2021 A1
20210298380 Brown, II et al. Sep 2021 A1
20210298390 Sup, IV et al. Sep 2021 A1
20210307425 Keim Oct 2021 A1
20210315291 Votolato et al. Oct 2021 A1
20210318553 Gharabegian Oct 2021 A1
20210321692 Wilson Oct 2021 A1
20210321693 Wilson et al. Oct 2021 A1
20210329999 Ackerman Oct 2021 A1
20210368886 Swart et al. Dec 2021 A1
20210386155 Rose Dec 2021 A1
20210393440 Leatt et al. Dec 2021 A1
20210394427 Frisco et al. Dec 2021 A1
20220015472 Boza Jan 2022 A1
20220024186 Tondu et al. Jan 2022 A1
20230106407 Arima et al. Apr 2023 A1
Foreign Referenced Citations (42)
Number Date Country
2005244595 Jul 2006 AU
2015277196 Jan 2017 AU
2386043 Nov 2003 CA
3637188 May 1988 DE
19808535 Sep 1999 DE
202004010014 Apr 2005 DE
202020101562 Apr 2020 DE
202020101794 Apr 2020 DE
192075 Aug 1986 EP
671258 Sep 1995 EP
1471415 Oct 2004 EP
1517791 Mar 2005 EP
1047537 Mar 2010 EP
3157480 Apr 2017 EP
2310862 Sep 1997 GB
2492574 Jan 2013 GB
61017860 Jan 1986 JP
S6117860 Jan 1986 JP
62053832 Mar 1987 JP
04314537 Nov 1992 JP
06143496 May 1994 JP
07021456 Jan 1995 JP
10167765 Jun 1998 JP
2000334812 Dec 2000 JP
2002328613 Nov 2002 JP
2012183822 Sep 2012 JP
2014032222 Feb 2014 JP
2015128896 Jul 2015 JP
6767596 Oct 2020 JP
20120001292 Jan 2012 KR
200700793 Jan 2007 TW
201027992 Jul 2010 TW
0024576 May 2000 WO
03052678 Jun 2003 WO
2009008857 Jan 2009 WO
2015009114 Jan 2015 WO
2015091425 Jun 2015 WO
2015093413 Jun 2015 WO
2015195814 Dec 2015 WO
2019006151 Jan 2019 WO
2019055267 Mar 2019 WO
2021176316 Sep 2021 WO
Non-Patent Literature Citations (133)
Entry
www.wikipedia.org. “Black Body”, Jul. 2009, 11 pages.
www.wikipedia.org. “Infrared”, Jul. 2009, 12 pages.
www.wikipedia.org. “PET Film (biaxially oriented)”, Jul. 2009, 4 pages.
PCT International Application No. PCT/US99/25128 with International Search Report, Date of Completion Jan. 18, 2000, 54 Pages.
English translation of TW201027992, “Monitor Protection Device for a Flat Panel Display”, 11 pgs.
Pulse Racing Innovations, EZ Tear Universal Single Pull Tearoff Ramp, webpage <https://www.pulseracinginnovations.com>, Dec. 30, 2020, 6 pages.
PCT International Search Report and Written Opinion for International Application No. PCT/US20/24639, Jun. 11, 2020, 13 pages.
PCT International Search Report and Written Opinion for International Application No. PCT/US2020/049919; Nov. 27, 2020.
Tian-Chi Chang, Xun Cao, Shan-Hu Bao, Shi=Dong Ji, Hong-Jie Luo, Ping Jin; “Review on Thermochromic Vanadium Dioxide Based Smart Coatings: From Lab to Commercial Application”; Dec. 16, 2017.
PCT International Search Report and Written Opinion for International Application No. PCT/US2020/062230; Feb. 8, 2021.
“Anti-reflective coating,” Wikipedia, last updated Jul. 13, 2017 by Andy Dingley, <https://en.m.wikipedia.org/wiki/Anti-reflective_coating>.
“Monotonic function,” Wikipedia, accessed May 24, 2017, <https://en.wikipedia.org/wiki/Monotonic_function>.
“Thin Film,” Wikipedia, last updated Jun. 20, 2017, <https://en.wikipedia.org/wiki/Thin_film>.
“Tips to Get Quality Anti-Reflection Optical Coatings,” Penn Optical Coatings, accessed May 24, 2017, <http://www.pennoc.com/tipsgetqualityantireflectionopticalcoatings/>.
Langlet, M., “Antireflective Films”, from Chapter 15 of Handbook of Sol-Gel Science and Technology Processing Characterization and Applications, copyright 2005, pp. 332-334, 337, 339-341., taken from website <https://books.google.com/books?id=i9swy1D2HxIC&lpg=PA339&dq=AR%20thick%20film%20coatings&pg=PA339#v=onepage&q=AR%20thick%20film%20coatings&f=false>.
Li, H.-M. et al., “Influence of weight ratio in polymer blend film on the phase separation structure and its optical properties”, The European Physical Journal Applied Physics, 45, 20501, published Jan. 31, 2009, EDP Sciences, 4 pages.
MDS Nordion, “Gamma Compatible Materials,” Datasheet, Aug. 2007, 4 pages, <https://ab-div-bdi-bl-blm.web.cern.ch/Radiation/Gamma_Compatible_Materials_List_company.pdf>, retrieved on Sep. 29, 2021.
Zhang, Xin_Xiang et al., Abstract of “One-step sol-gel preparation of PDMS-silica ORMOSILs as environment-resistant and crack-free thick antireflective coatings,” Journal of Materials Chemistry, Issue 26, 2012, <http://pubs.rsc.org/en/content/articlelanding/2012/m/c2jm31005h#!divAbstract>.
PCT International Search Report and Written Opinion for International Application No. PCT/US2017/044438, dated Oct. 23, 2017, 12 pages.
Chemical Book, “Benzophenone”, https://www.chemicalbook.com/Chemical ProductProperty_EN_CB57 44679.htm, available at least as of 2017, accessed on line on Dec. 15, 2021 (Year: 2017).
Chemical Book, “Polymethylhydrosiloxane”, https://www.chemicalbook.com/Chemical ProductProperty _En_ CB3694969. htm, available at least as of 2017, accessed online on Dec. 15, 2021 (Year: 2017).
Guide Chem, “UV Stabilizer”, https://wap.guidechem.com/trade/uv-stabilizer-uv-absorber-ligh-id3578792.html, available at least as of 2018, accessed online on Dec. 15, 2021 (Year: 2018).
Hostaphan RBB biaxially oriented film data sheet (Year: 2011).
PCT International Search Report and Written Opinion for International Application No. PCT/US2020/024639; Jun. 11, 2020.
PCT International Search Report and Written Opinion for International Application No. PCT/US2021/026165, dated Jul. 9, 2021, 10 pages.
PCT International Search Report and Written Opinion for International Application No. PCT/US21/20421, May 20, 2021, 8 pages.
Wiseman, Sr., United States Statutory Invention Registration No. H1023, published Mar. 3, 1992, 7 pages.
Chemical Book, Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, available online at least as of 2017, https://www.chemicalbook.com/ChemicalProductProperty_EN_CB8121619.htm, accessed online Mar. 15, 2022 (Year: 2017).
Pearson Dental, “UV Protection Face Shields”, https://www.pearsondental.com/catalog/subcat_thumb.asp?majcatid=750&catid=l0149, available online at least as of Jan. 27, 2021 per Internet Archive, accessed online on Sep. 15, 2021. (Year: 2021).
Patent Cooperation Treaty, International Search Report and Written Opinion for International Application No. PCT/US2022/031823, mailed Jul. 14, 2022, 11 pages.
Patent Cooperation Treaty, International Search Report and Written Opinion for International Application No. PCT/US2022/046171, mailed Jan. 18, 2023, 15 pages.
Patent Cooperation Treaty, International Search Report and Written Opinion for International Application No. PCT/US2023/012316, mailed Apr. 14, 2023, 11 pages.
Patent Cooperation Treaty, International Search Report and Written Opinion for International Application No. PCT/US2023/26598, mailed Sep. 12, 2023, 7 pages.
Racing Optics, Inc. v. Aevoe Corp. DBA Moshi; Case 2:15-cv-01774-RCJ-VCF; “Answer to Aevoe's Counterclaims—Jury Trial Demanded”; Nov. 2, 2015; 15 pages.
Gregory Brower et al.; “Complaint for Patent Infringement”; Sep. 15, 2015; 15 pages.
Jeffrey A. Silverstri et al.; “Answer to Complaint for Patent Infringement”; Oct. 7, 2015; 59 pages.
United States Patent and Trademark Office; Office Action for U.S. Appl. No. 15/090,681; Aug. 26, 2016; 8 pages.
U.S. Appl. No. 15/090,681; Receipt date Jun. 30, 2016; 3 pages.
U.S. Appl. No. 15/090,681; Receipt date Apr. 27, 2016; 4 pages.
Examiner's search strategy and results for U.S. Appl. No. 15/090,681; Aug. 21, 2016; 2 pages.
Aevoe Corp. v. Racing Optics, Inc.; Case No. IPR2016-01164; Petition for Inter Partes Review of U.S. Pat. No. 9,104,256 (including Exhibits 1001-1011 and Petitioner Power of Attorney Pursuant to 37 C.F.R. 42. 10(b) for Petition for Inter Partes Review); Jun. 21, 2016.
Aevoe Corp. v. Racing Optics, Inc.; Case No. IPR2016-01165; Petition for Inter Partes Review of U.S. Patent No. 9, 128,545(including Exhibits 1001-1006 and Petitioner Power of Attorney Pursuant to 37 C.F.R. 42. 10(b) for Petition for Inter Partes Review); Jun. 21, 2016.
Aevoe Corp. v. Racing Optics, Inc.; Case No. IPR2016-01166; Petition for Inter Partes Review of U.S. Pat. No. 9,274,625 (including Exhibits 1001-1011 and Petitioner Power of Attorney Pursuant to 37 C.F.R. 42. 10(b) for Petition for Inter Partes Review); Jun. 21, 2016.
Exhibit 1—Invalidity Contentions re: '545 Patent Under LPR 1-8(b)-(d); at least as early as Jul. 1, 2016.
Exhibit 2—Invalidity Contentions re: '256 Patent Under LPR 1-8(b)-(d); at least as early as Jul. 1, 2016.
Exhibit 3—Invalidity Contentions re: '620 Patent Under LPR 1-8(b)-(d); at least as early as Jul. 1, 2016.
Exhibit 4—Invalidity Contentions re: '625 Patent Under LPR 1-8(b)-(d); at least as early as Jul. 1, 2016.
Exhibit 1002—U.S. Pat. No. 5,364,671 to Gustafson; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-6.
Exhibit 1004—U.S. Pat. No. 7,351,470 to Draheim et al; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-15.
Exhibit 1001—U.S. Pat. No. 8,974,620 to Wilson et al.; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-15.
Exhibit 1003—U.S. Pat. No. 6,250,765 to Murakami; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; p. 1-8.
Exhibit 1005—U.S. Pat. No. 7,957,524 to Chipping; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2017; pp. 1-20.
Aevoe Corp., Racing Optics, Inc.; Petition for Inter Partes Review; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-55.
Exhibit 1006—Japanese Application No. JP 2002-328613 to Kitaguchi Translation; IPR2016-01745; at least as early as Sep. 7, 2016; pp. 1-10.
Exhibit 1009—U.S. Appl. No. 13/838,311; Interview Summary; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; p. 1-3.
Exhibit 1010—U.S. Appl. No. 15/838,311; Notice of Allowance; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-8.
Aevoe Corp. v. Racing Optics, Inc.; Declaration of Darran Cairns; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-32.
Aevoe Corp. v. Racing Optics, Inc.; Petitioner's Power of Attorney; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-3.
Exhibit 1007—U.S. Appl. No. 13/838,311; Response to Office Action; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; p. 1-19.
Exhibit 1008—U.S. Appl. No. 13/838,311; Response and Request for Continued Examination; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-21.
Aevoe Corp. v. Racing Optics, Inc.; Mandatory Notices; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-4.
Aevoe Corp. v. Racing Optics, Inc.; Power of Attorney; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 7, 2016; pp. 1-4.
Aevoe Corp v. Racing Optics, Inc.; Notice of Filing Date; Case IPR2016-01745; Inter Partes Review of U.S. Pat. No. 8,974,620; at least as early as Sep. 6, 2016; p. 1-5.
Aevoe Corp v. Racing Optics, Inc.; Decision; Case IPR2016-01164; Inter Partes Review of U.S. Pat. No. 9,104,256; at least as early as Nov. 7, 2016; p. 1-24.
Aevoe Corp v. Racing Optics, Inc.; Decision; Case IPR2016-01166; Inter Partes Review of U.S. Pat. No. 9,274,625; at least as early as Nov. 7, 2016; p. 1-23.
Aevoe Corp v. Racing Optics, Inc.; Decision; Case IPR2016-01165; Inter Partes Review of U.S. Pat. No. 9,128,545; at least as early as Nov. 7, 2016; p. 1-25.
Settlement and License Agreement, Dec. 21, 2007, 28 pgs.
United States Patent and Trademark Office; Office Action dated Dec. 21, 2016 pertaining to U.S. Appl. No. 15/090,681, filed Apr. 5, 2016; 8 pages.
PCT Search Report and Written Opinion for US2020/016245 (Apr. 28, 2020).
Professional Plastics (http://www.professionalplastics.com/MelinexPETFilmDupont) 2012.
Whitney, Frank D., Preliminary Injunction, Aug. 21, 2007, 5 pgs.
Higgins, John P., Answer and Counterclaims to First Amended Complaint, Sep. 4, 2007, 27 pgs.
Ballato, John, Expert Report of John Ballato, Ph.D., Nov. 12, 2007, 5 pgs.
Russell, Geoffrey A., Rebuttal Report of Geoffrey A. Russell, Ph.D., on issues raised in the Export Report of John Ballato, Ph.D., Nov. 21, 2007, 15 pgs.
Higgins, John P., Defendants' Second Supplement to Its Response to Plaintiffs' First Set of Interrogatories, Dec. 7, 2007, 25 pgs.
Barnhardt, John J. III, Redacted Version Defendants' Memorandum in Support of Motion for Partial Summary Judgment, Dec. 3, 2007, 36 pgs.
Higgins, John P., Defendants' Second Supplement to its Response to Plaintiffs' First Set of Interrogatories, Dec. 7, 2007, 26 pgs.
Whitney, Frank D., Consent Judgment Order, Jan. 3, 2008, 5 pgs.
Ballato, John, Supplemental Expert Report of John Ballato, Ph.D., Nov. 19, 2007, 10 pgs.
Moore, Steven D., Plaintiffs' Motion to Strike Defendants' New and Untimely Invalidity Theory, Dec. 19, 2007, 3 pgs.
Moore, Steven D., Plaintiffs' Brief in Support of Motion to Strike Defendants' New and Untimely Invalidity Theory, Dec. 19, 2007, 10 pgs.
Barnhardt, John J. III, Notice Pursuant to 35 U.S.C. 282, Dec. 18, 2007, 3 pgs.
Office Action for Canadian Patent Application No. 2,952,436; Jul. 8, 2020.
Prosecution History of U.S. Re-Examination U.S. Appl. No. 95/002,073 titled Touch Screen Protector; pp. 1-1,980.
www.store.moshimode.com; “iVisor AG for iPad 2 Black”; 2004-2010.
Defendant's Motion for Summary Judgment; Oct. 25, 2013; pp. 1-31.
Jake Gaecke; “Appletell Reviews the iVisor for iPad”; www.appletell.com; Sep. 15, 2010 at 12:32 p.m. www.technologytell.com/apple/60407/appletell-reviews-ag-for-ipad/; 2 pages.
www.nushield.com/technology.php; “What Makes NuShield Screen Protectors Superior”, 2 pages.
www.spigen.com; “Something You Want”; 2 pages.
www.zagg.com; “Apple iPad 2 (Wi-Fi 3G) Screen Protector”; 2 pages.
www.gadgetguard.com; “Invisible Gadget Guard, the Original”; 1 page.
www.incipotech.com; “Protect Your iPhone 4 with Screen Protectors from Incipo”; 3 pages.
www.store.moshimonde.com; “iVisor AG iPad Screen Protector”; Jul. 2010; 7 pages.
www.store.moshimonde.com; “iVisor XT Crystal Clear Protector for iPad”; Aug. 2010; 3 pages.
www.store.moshimonde.com; “iVisor AG for iPad 2 Black”; Mar. 2011; 5 pages.
www.store.moshimonde.com; “iVisor AG for iPad 2 White”; Mar. 2011; 3 pages.
www.store.moshimonde.com; “iVisor AG for iPhone 4/4S Black”; Nov. 2010; 5 pages.
www.store.moshimonde.com; “iVisor AG for iPhone 4/4S White”; May 2010; 4 pages.
Dictionary.com (http://dictionary.reference.com) 2012.
Racing Optics, Inc. v. Aevoe, Inc., d/b/a/ Moshi; Case No. 15-cv-017744-JCM-VCF; Aevoe's Initial Disclosure Non-Infringement, Invalidity and Unenforceability Contentions (Redacted) dated Jan. 7, 2016.
Defendant Aevoe Corp.'s Non-Infringement Contentions and Responses to Racing Optic's Disclosure of Asserted Claims and Infringement Contentions (U.S. Pat. No. 9,128,545) dated Jan. 7, 2016.
Defendant Aevoe Corp.'s Non-Infringement Contentions and Responses to Racing Optic's Disclosure of Asserted Claims and Infringement Contentions (U.S. Pat. No. 9,104,256) dated Jan. 7, 2016.
Defendant Aevoe Corp.'s Non-Infringement Contentions and Responses to Racing Optic's Disclosure of Asserted Claims and Infringement Contentions (U.S. Pat. No. 8,974,620) dated Jan. 7, 2016.
I-Blason LLC v. Aevoe, Inc. and Aevoe Corp.; Case IPR2016-TBA; Petition for Inter Partes Review of U.S. Pat. No. 8,044,942 (including Exhibits 1001-1019).
Dupont Teijin Films, “Mylar Polyester Film—Optical Properties”, Jun. 2003, 2 pages.
https://en.wikipedia.org/wiki/Black_body, “Black Body”, Jul. 2009, 11 pages.
https://en.wikipedia.org/wiki/Infrared, “Infrared”, Jul. 2009, 12 pages.
https://en.wikipedia.org/wiki/BoPET, “PET Film (biaxially oriented)”, Jul. 2009, 4 pages.
Instashield LLC, Bionic Wrench® Inventor Creates Low-Cost Face Shield for Masses, Apr. 15, 2020, 3 pages.
Tom Zillich, Surrey manufacturer hopes to hit home run with face shield that clips to baseball cap, Apr. 29, 2020, 3 pages.
Opentip, Opromo Safety Face Shield Visor for Adult Kids, Protective Cotton Hat with Removable PVC Face Cover <https://www.opentip.com/product.php?products_id=11699030>, May 5, 2020, 3 pages.
Hefute, Hefute 5 PCS Protective Face Cover with Shield Comfortable Full Protection Face Compatiable with Glasses Anti-Droplet Anti-Pollution and Windproof Transparent Safety Face Cover with Shield(Style B) <https://www.amazon.com/dp/B086GSG8DH/ref=sspa_dk_detail_9?psc=1&pd_rd_i=B086GSG8DH&pd_rd_w=Ocdm2&pf_rd_p=48d372c1-f7e1-4b8b-9d02-4bd86f5158c5&pd_rd_wg=qkB2b&pf_rd_r=M%E2%80%A6>, May 6, 2020, 7 pages.
Geanbaye, Geanbaye Safety Full Face Shield Cap Detachable Baseball Cap Anti-Saliva Anti-Spitting Eye Protective Hat Windproof Dustproof <https://www.amazon.com/dp/B086DV32B8/ref=sspa_dk_detail_8?psc=1&pd_rd_i=B086DV32B8&pd_rd_w=MwjfT&pf_rd_p=48d372c1-f7e1-4b8b-9d02-4bd86f5158c5&pd_rd_wg=pxuOs&pf_rd_r=PNDA%E2%80%A6>, May 5, 2020, 8 pages.
Leigh Buchanan, These 2 Companies Are Making Face Shields for Everyone <https://www.inc.com/leigh-buchanan/face-shields-coronavirus-protection-open-source.html>, May 6, 2020, 8 pages.
Brim Shield, photographs, Apr. 21, 2020, 1 pages.
Hatshield, Shield Yourself With The Hatshield <https://www.hat-shield.com/?gclid=CjwKCAjwp-X0BRAFEiwAheRui1u89v_3URuiwEVvBRGa9TaEfWoZVMJXRkWsZgPTUw-0fHJ5HD-8uhoCc84QAvD_BwE>, Apr. 17, 2020, 11 pages.
Eli N. Perencevich, Moving Personal Protective Equipment Into the Community Face Shields and Containment of COVID-19, Apr. 29, 2020, 2 pages.
Chang, Tian-Ci; Cao, Xun; Bao, Shan-Hu; JI, Shi-Dong; Luo, Hong-Jie; Jin, Ping; Review of Thermochromic Vanadium Dioxide Based Smart Coatings: From Lab to Commercial Application; Dec. 16, 2017.
Saudi Basic Industries Corporation (SABIC); “The Department of Transportation [DOT] Guidebook”; Oct. 2016.
Hostaphan RBB, “Transparent, Temperature Stable Polyester Film for Cooking & Roasting Bags” Jul. 2016.
Hostaphan Win, “White, Long-Term Stable, Thermally Stable Polyester Film for PV Back Sheet Laminates”; Jul. 2016.
PCT Search Report & Written Opinion for PCT/US2019/054565 (Dec. 20, 2019).
PCT Search Report & Written Opinion for PCT/US2015/036248 (Sep. 16, 2015).
“Declaration of Jerome Aho”; Filed Aug. 3, 2007; Case 3:07-cv-00221-FDW-DCK; Includes: Exhibit A, Nascar Postcard (1 page), Exhibit B, 50th Anniversary Nascar letter sent Jan. 7, 1998 (1 page), and Exhibit C, Front page of “The Official Nascar Preview and Press Guide” (1 page); 9 pages.
Racing Optics, Inc. v. David Leon O'Neal, Edward M. Wallace and Clear View Racing Optics, LLC; Case 3:07 CV 221; Includes: Exhibit A, Wilson et al. U.S. Pat. No. 6,847,492; and Exhibit B, Wilson et al. U.S. Pat. No. 7,184,217; 34 pages.
International Search Report; International Application No. PCT/US99/95128; Date of Completion: Jan. 18, 2000; 54 pages.
International Search Report; International Application No. PCT/US02/10971; Date of Completion: Nov. 20, 2002; 3 pages.
International Search Report; International Application No. PCT/US03/16284; Date of Completion: Mar. 9, 2004; 3 pages.
European Search Report for Application No. 15809930.9-107 / 3157480 (Dec. 15, 2017).
Canadian Office Action for Application Serial No. 2,952,436 (Nov. 15, 2019).
Canadian Office Action for Application Serial No. 2,952,436 (May 3, 2019).
Australian Examination Report for Application Serial No. 2015277196 (Oct. 18, 2018).
www.wikipedia.org, Refractive Index, Oct. 31, 2014.
Related Publications (1)
Number Date Country
20240069250 A1 Feb 2024 US
Provisional Applications (1)
Number Date Country
62799880 Feb 2019 US
Divisions (1)
Number Date Country
Parent 17813494 Jul 2022 US
Child 18501820 US
Continuation in Parts (1)
Number Date Country
Parent 16778928 Jan 2020 US
Child 17813494 US