Thermoplastic films are a common component in various commercial and consumer products. For example, grocery bags, trash bags, sacks, and packaging materials are products that are commonly made from thermoplastic films. Additionally, feminine hygiene products, baby diapers, adult incontinence products, and many other products include thermoplastic films to one extent or another.
The cost to produce products including thermoplastic film is directly related to the cost of the thermoplastic film. Recently the cost of thermoplastic materials has risen. In response, one or more attempt to control manufacturing costs by decreasing the amount of thermoplastic material in a product. One-way manufacturers may attempt to reduce production costs is to stretch the thermoplastic film, thereby increasing its surface area and reducing the amount of thermoplastic film needed to produce a product of a given size.
While thinner gauge materials can represent cost savings to the manufacturer, the use of thinner gauge films can result in lower durability. Although one or more recent technology may, in one or more cases at least, result in relatively thinner gauge films that may be as strong as their thicker counterparts, customers naturally sense from prior experience that thinner gauge materials are lower in quality and durability.
For example, one or more cues to a customer of lower quality and durability of a film are how thick or thin the film feels and how thin or weak the film “looks.” Customers tend to view thin looking or feeling films as having relatively low strength. Thus, even though one or more mechanisms can improve one or more aspects of film strength while using a thinner gauge, the look and feel of such films tend to cause customers to believe the film is nevertheless low quality. To provide additional strength and flexibility, one or more manufacturers seek to provide thermoplastic films with elastic-like behavior by adding elastic materials or using specialized processing of the films.
Accordingly, there are various considerations to be made with regard to thermoplastic films and products formed therefrom.
Embodiments of the present disclosure provide benefits and/or solve one or more problems in the art with thermoplastic films and bags that have enhanced dart impact resistance over conventional films and bags. For example, in one or more embodiments, the disclosed thermoplastic bags include deformations arranged in patterns that provide increased strength to withstand impacts and reduce creation of holes and tears. In one or more embodiments, the pattern of raised rib-like elements and web areas comprises a first motif of deformations that repeats in the pattern and a second motif of deformations interspersed with the first motif of deformations within the pattern. In one or more embodiments, the web areas lack sharp corners. The interspersed motifs and/or the lack of sharp corners in the web areas serve to increase dart impact resistance of the thermoplastic bags.
For example, one or more implementations of the present disclosure includes a thermoplastic bag including a plurality of raised rib-like elements extending in a direction perpendicular to a main surface of the thermoplastic film or bag. The thermoplastic film or bag further includes a plurality of web areas positioned about the plurality of raised rib-like elements. The plurality of raised rib-like elements and the plurality of web areas are sized and positioned to create a pattern of raised rib-like elements comprising first and second motifs of raised rib-like elements that repeat within the pattern such that the second motifs of raised rib-like elements are interspersed with the first motif of raised rib-like elements within the pattern. The interspersed motifs serve to increase dart impact resistance of the thermoplastic bags.
One or more implementations of the present disclosure includes a thermoplastic bag including a plurality of raised rib-like elements and a plurality of web areas positioned about the plurality of raised rib-like elements. The plurality of raised rib-like elements and the plurality of web areas are sized and positioned such that the web areas lack sharp corners. The lack of sharp corners can reduce stress concentrations or weak points formed in the individual films during formation of the deformations, thereby increasing the strength of the thermoplastic bags by helping prevent holes and tears.
The following description sets forth additional features and advantages of one or more embodiments of the disclosed thermoplastic films and bags. In one or more cases, such features and advantages are evident to a skilled artisan having the benefit of this disclosure or may be learned by the practice of the disclosed embodiments.
In order to describe the manner in which the above recited and other advantages and features of the present disclosure can be obtained, a more particular description of the present disclosure briefly described above will be rendered by reference to specific implementations thereof which are illustrated in the appended drawings. It should be noted that the figures are not drawn to scale, and that elements of similar structure or function are generally represented by like reference numerals for illustrative purposes throughout the figures. Understanding that these drawings depict only typical implementations of the present disclosure and are not therefore to be considered to be limiting of its scope, the present disclosure will be described and explained with additional specificity and detail through the use of the accompanying drawings in which:
One or more implementations of the present disclosure include thermoplastic films and bags with patterns of structural elastic-like film (SELF'ing) deformations. As described below, the patterns of SELF'ing deformations provide thermoplastic films—and products made therefrom—with various advantages. For example, the disclosed patterns of SELF'ing deformations can provide enhanced dart impact resistance over existing thermoplastic films.
Various implementations include thermoplastic films with strainable networks created by a SELF'ing process. The strainable network can comprise a plurality of raised rib-like elements extending in a direction perpendicular to a main surface of the thermoplastic film. In one or more embodiments, the raised rib-like elements are surrounded by a plurality of web areas. The raised rib-like elements and web areas can comprise a strainable network that provides the thermoplastic film with an elastic-like behavior. In particular, when subjected to an applied load, the raised rib-like elements can initially undergo a substantially geometric deformation before undergoing substantial molecular-level deformation when subjected to an applied load. On the other hand, the web areas can undergo a substantially molecular-level and geometric deformation in response to the applied strain. U.S. Pat. Nos. 5,518,801 and 5,650,214 each disclose processes for forming strainable networks using SELF'ing processes. The contents of each of the aforementioned patents are incorporated in their entirety by reference herein.
In addition to the elastic-like characteristics mentioned above and the other benefits described in the above incorporated patents, implementations of the present disclosure include sized, shaped, and positioned strainable networks in patterns that provide previously unrealized film properties and characteristics. For example, one or more implementations include shaping, sizing, and positioning the plurality of raised rib-like elements and the plurality of web areas such that, when subjected to an impact (e.g., by a sharp object), the thermoplastic film has an increased tendency to withstand the impact and a reduced tendency to puncture.
For instance, in one or more embodiments of the present disclosure, a thermoplastic film includes a strainable network in a pattern of raised rib-like elements and web areas with a first motif of deformations and a second motif of deformations. More particularly, in one or more embodiments, the first motif of deformations repeats in the pattern, and the second motif of deformations is interspersed with the first motif of deformations within the pattern. As described in additional detail below, in one or more embodiments, the first motif includes a macro pattern of deformations and the second motif includes a micro pattern of deformations (or vice versa). Alternatively, in one or more embodiments, the first motif and the second motif both include a macro pattern of deformations (e.g., deformations of comparable size).
Moreover, in one or more implementations of the present disclosure, a thermoplastic film includes a strainable network of deformations in a pattern of raised rib-like elements and web areas separating repeat units of the raised rib-like elements. More particularly, in one or more embodiments, the web areas lack sharp corners. For example, the web areas lack corners, or the corners of the web areas are rounded. In one or more implementations, the absence of sharp corners in the web areas helps reduce or mitigate potential stress concentrations in the thermoplastic film, thereby improving the thermoplastic film's dart impact resistance.
One or more implementations of the present disclosure include products made from or with such thermoplastic films with SELF'ing patterns. For example, such products include, but are not limited to, grocery bags, trash bags, sacks, packaging materials, feminine hygiene products, baby diapers, adult incontinence products, or other products. For ease in description, the figures and bulk of the following disclosure focuses on films and bags. One will appreciate that the teachings and disclosure herein equally applies to other products.
As an initial matter, the thermoplastic material of the films of one or more implementations of the present disclosure may include thermoplastic polyolefins, including polyethylene and copolymers thereof and polypropylene and copolymers thereof. The olefin-based polymers may include ethylene or propylene based polymers such as polyethylene, polypropylene, and copolymers such as ethylene vinyl acetate (EVA), ethylene methyl acrylate (EMA) and ethylene acrylic acid (EAA), or blends of such polyolefins.
Other examples of polymers suitable for use as films in accordance with the present disclosure may include elastomeric polymers. Suitable elastomeric polymers may also be biodegradable or environmentally degradable. Suitable elastomeric polymers for the film include poly(ethylene-butene), poly(ethylene-hexene), poly(ethylene-octene), poly(ethylene-propylene), poly(styrene-butadiene-styrene), poly(styrene-isoprene-styrene), poly(styrene-ethylene-butylene-styrene), poly(ester-ether), poly(ether-amide), poly(ethylene-vinylacetate), poly(ethylene-methylacrylate), poly(ethylene-acrylic acid), oriented poly(ethylene-terephthalate), poly(ethylene-butylacrylate), polyurethane, poly(ethylene-propylene-diene), ethylene-propylene rubber, nylon, etc.
One or more of the examples and description herein below refer to films formed from linear low-density polyethylene. The term “linear low density polyethylene” (LLDPE) as used herein is defined to mean a copolymer of ethylene and a minor amount of an olefin containing 4 to 10 carbon atoms, having a density of from about 0.910 to about 0.930, and a melt index (MI) of from about 0.5 to about 10. For example, one or more examples herein use an octene comonomer, solution phase LLDPE (MI=1.1; ρ=0.920). Additionally, other examples use a gas phase LLDPE, which is a hexene gas phase LLDPE formulated with slip/AB (MI=1.0; ρ=0.920). Still further examples use a gas phase LLDPE, which is a hexene gas phase LLDPE formulated with slip/AB (MI=1.0; ρ=0.926). One will appreciate that the present disclosure is not limited to LLDPE, and can include “high density polyethylene” (HDPE), “low density polyethylene” (LDPE), and “very low density polyethylene” (VLDPE). Indeed, films made from any of the previously mentioned thermoplastic materials or combinations thereof can be suitable for use with the present disclosure.
One or more implementations of the present disclosure may include any flexible or pliable thermoplastic material that may be formed or drawn into a web or film. Furthermore, the thermoplastic materials may include a single layer or multiple layers. The thermoplastic material may be opaque, transparent, translucent, or tinted. Furthermore, the thermoplastic material may be gas permeable or impermeable.
As used herein, the term “flexible” refers to materials that are capable of being flexed or bent, especially repeatedly, such that they are pliant and yieldable in response to externally applied forces. Accordingly, “flexible” is substantially opposite in meaning to the terms inflexible, rigid, or unyielding. Materials and structures that are flexible, therefore, may be altered in shape and structure to accommodate external forces and to conform to the shape of objects brought into contact with them without losing their integrity. In accordance with further prior art materials, web materials are provided which exhibit an “elastic-like” behavior in the direction of applied strain without the use of added traditional elastic materials. As used herein, the term “elastic-like” describes the behavior of web materials which when subjected to an applied strain, the web materials extend in the direction of applied strain, and when the applied strain is released the web materials return, to a degree, to their pre-strained condition.
As used herein, the term “substantially,” in reference to a given parameter, property, or condition, means to a degree that one of ordinary skill in the art would understand that the given parameter, property, or condition is met within a degree of variance, such as within acceptable manufacturing tolerances. By way of example, depending on the particular parameter, property, or condition that is substantially met, the parameter, property, or condition may be at least 70.0% met, at least 80.0%, at least 90% met, at least 95.0% met, at least 99.0% met, or even at least 99.9% met.
Additional additives that may be included in one or more implementations include slip agents, anti-block agents, voiding agents, or tackifiers. Additionally, one or more implementations of the present disclosure include films that are devoid of voiding agents. One or more examples of inorganic voiding agents, which may further provide odor control, include the following but are not limited to: calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, magnesium sulfate, barium sulfate, calcium oxide, magnesium oxide, titanium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, talc, clay, silica, alumina, mica, glass powder, starch, charcoal, zeolites, any combination thereof, etc. Organic voiding agents, polymers that are immiscible in the major polymer matrix, can also be used. For instance, polystyrene can be used as a voiding agent in polyethylene and polypropylene films.
One of ordinary skill in the art will appreciate in view of the present disclosure that manufacturers may form the films or webs to be used with the present disclosure using a wide variety of techniques. For example, a manufacturer can form precursor mix of the thermoplastic material and one or more additives. The manufacturer can then form the film(s) from the precursor mix using conventional flat or cast extrusion or co-extrusion to produce monolayer, bilayer, or multilayer films. Alternatively, a manufacturer can form the films using suitable processes, such as, a blown film process to produce monolayer, bilayer, or multilayer films. If desired for a given end use, the manufacturer can orient the films by trapped bubble, tenterframe, or other suitable process. Additionally, the manufacturer can optionally anneal the films thereafter.
An optional part of the film-making process is a procedure known as “orientation.” The orientation of a polymer is a reference to its molecular organization, i.e., the orientation of molecules relative to each other. Similarly, the process of orientation is the process by which directionality (orientation) is imposed upon the polymeric arrangements in the film. The process of orientation is employed to impart desirable properties to films, including making cast films tougher (higher tensile properties). Depending on whether the film is made by casting as a flat film or by blowing as a tubular film, the orientation process can require different procedures. This is related to the different physical characteristics possessed by films made by conventional film-making processes (e.g., casting and blowing). Generally, blown films tend to have greater stiffness and toughness. By contrast, cast films usually have the advantages of greater film clarity and uniformity of thickness and flatness, generally permitting use of a wider range of polymers and producing a higher quality film.
When a film has been stretched in a single direction (mono-axial orientation), the resulting film can exhibit strength and stiffness along the direction of stretch, but can be weak in the other direction, i.e., across the stretch, often splitting when flexed or pulled. To overcome this limitation, two-way or biaxial orientation can be employed to more evenly distribute the strength qualities of the film in two directions. Most biaxial orientation processes use apparatus that stretches the film sequentially, first in one direction and then in the other.
In one or more implementations, the films of the present disclosure are blown film, or cast film. Both a blown film and a cast film can be formed by extrusion. The extruder used can be a conventional one using a die, which will provide the desired gauge. One or more useful extruders are described in U.S. Pat. Nos. 4,814,135; 4,857,600; 5,076,988; 5,153,382; each of which are incorporated herein by reference in their entirety. Examples of various extruders, which can be used in producing the films to be used with the present disclosure, can be a single screw type modified with a blown film die, an air ring, and continuous take off equipment.
In one or more implementations, a manufacturer can use multiple extruders to supply different melt streams, which a feed block can order into different channels of a multi-channel die. The multiple extruders can allow a manufacturer to form a film with layers having different compositions. Such multi-layer film may later be provided with a pattern of deformations to provide the benefits of the present disclosure.
In a blown film process, the die can be an upright cylinder with a circular opening. Rollers can pull molten thermoplastic material upward away from the die. An air-ring can cool the film as the film travels upwards. An air outlet can force compressed air into the center of the extruded circular profile, creating a bubble. The air can expand the extruded circular cross section by a multiple of the die diameter. This ratio is called the “blow-up ratio.” When using a blown film process, the manufacturer can collapse the film to double the plies of the film. Alternatively, the manufacturer can cut and fold the film, or cut and leave the film unfolded.
In any event, in one or more implementations, the extrusion process can orient the polymer chains of the blown film. The “orientation” of a polymer is a reference to its molecular organization, i.e., the orientation of molecules or polymer chains relative to each other. In particular, the extrusion process can cause the polymer chains of the blown film to be predominantly oriented in the machine direction. The orientation of the polymer chains can result in an increased strength in the direction of the orientation. As used herein predominately oriented in a particular direction means that the polymer chains are more oriented in the particular direction than another direction. One will appreciate, however, that a film that is predominately oriented in a particular direction can still include polymer chains oriented in directions other than the particular direction. Thus, in one or more implementations the initial or starting films (films before being stretched or bonded or laminated in accordance with the principles described herein) can comprise a blown film that is predominately oriented in the machine direction.
The process of blowing up the tubular stock or bubble can further orient the polymer chains of the blown film. In particular, the blow-up process can cause the polymer chains of the blown film to be bi-axially oriented. Despite being bi-axially oriented, in one or more implementations the polymer chains of the blown film are predominantly oriented in the machine direction (i.e., oriented more in the machine direction than the transverse direction).
The films of one or more implementations of the present disclosure can have a starting gauge between about 0.1 mils to about 20 mils, suitably from about 0.2 mils to about 4 mils, suitably in the range of about 0.3 mils to about 2 mils, suitably from about 0.6 mils to about 1.25 mils, suitably from about 0.9 mils to about 1.1 mils, suitably from about 0.3 mils to about 0.7 mils, and suitably from about 0.3 mils and about 0.6 mils. Additionally, the starting gauge of films of one or more implementations of the present disclosure may not be uniform. Thus, the starting gauge of films of one or more implementations of the present disclosure may vary along the length and/or width of the film.
One or more layers of the films described herein can comprise any flexible or pliable material comprising a thermoplastic material and that can be formed or drawn into a web or film. As described above, the film includes a plurality of layers of thermoplastic films. Each individual film layer may itself include a single layer or multiple layers. In other words, the individual layers of the multi-layer film may each themselves comprise a plurality of laminated layers. Such layers may be significantly more tightly bonded together than the bonding provided by the purposely weak discontinuous bonding in the finished multi-layer film. Both tight and relatively weak lamination can be accomplished by joining layers by mechanical pressure, joining layers with adhesives, joining with heat and pressure, spread coating, extrusion coating, ultrasonic bonding, static bonding, cohesive bonding and combinations thereof. Adjacent sub-layers of an individual layer may be coextruded. Co-extrusion results in tight bonding so that the bond strength is greater than the tear resistance of the resulting laminate (i.e., rather than allowing adjacent layers to be peeled apart through breakage of the lamination bonds, the film will tear).
Films having enhanced dart impact resistance can include a single film formed from one, two, three, or more layers of thermoplastic material.
As shown by
As shown in
As shown by
The rib-like elements 304a/304b can undergo a substantially “geometric deformation” prior to a “molecular-level deformation.” As used herein, the term “molecular-level deformation” refers to deformation that occurs on a molecular level and is not discernible to the normal naked eye. That is, even though one may be able to discern the effect of molecular-level deformation, e.g., elongation or tearing of the film, one is not able to discern the deformation, which allows or causes it to happen. This is in contrast to the term “geometric deformation,” which refers to deformations that are generally discernible to the normal naked eye when a SELF'ed film or articles embodying such a film are subjected to an applied load or force. Types of geometric deformation include, but are not limited to bending, unfolding, and rotating.
Thus, upon application of a force, the rib-like elements 304a/304b can undergo geometric deformation before undergoing molecular-level deformation. For example, a strain applied to the film 200 in a perpendicular direction to the major axes of the rib-like elements 304a/304b can pull the rib-like elements 304a/304b back into plane with the web areas 302 prior to any molecular-level deformation of the rib-like elements 304a/304b. Geometric deformation can result in significantly less resistive forces to an applied strain than that exhibited by molecular-level deformation.
As mentioned above, the rib-like elements 304a/304b and the web areas 302 can be sized and positioned so as to create the pattern 220. The pattern can provide one or more of the benefits discussed herein. For example, the pattern can provide a thermoplastic film or multi-layer film structure (e.g., a sidewall of a thermoplastic bag) with increased impact resistance. Specifically, as mentioned previously, a pattern of multiple motifs (e.g., two motifs, three motifs, four motifs). The different motifs interspersed within the pattern of raised-rib like elements spread out and vary the location of stress concentrations, thereby, varying and reducing stress concentrations or weak points formed in the individual films during formation of the deformations, thereby, increasing the strength of the thermoplastic bags by helping prevent holes and tears. Alternatively, or additionally, the plurality of raised rib-like elements and the plurality of web areas are sized and positioned such that the web areas lack sharp corners. The lack of sharp corners reduce stress concentrations or weak points formed in the individual films during formation of the deformations, thereby increasing the strength of the thermoplastic bags by helping prevent holes and tears.
As shown by
As used herein, a web area includes a space between two raised rib-like elements aligned in a row. For example, a web area includes a gap in a SELF'ing pattern left by a notch in a SELF'ing intermeshing roller (e.g., a notch that separates teeth on a single ridge of the intermeshing roller). In the aggregate, web areas include space of undeformed thermoplastic material that separates ribs within a particular shape. Various shapes of raised rib-like elements can be achieved by designing notches in positions of the intermeshing roller that produce the shapes in the thermoplastic film.
As used herein, a motif includes a group of raised rib-like elements formed into a shape or a pattern of shapes. In some embodiments, a motif is completely surrounded by web areas. Alternatively, in some embodiments, a motif is partially surrounded by web areas (e.g., surrounded by web areas in the machine direction) and partially adjacent ribs of another motif (e.g., surrounded by rib-like elements in the transverse direction).
In one or more implementations, the first pattern 310 is visually distinct from the second pattern 312. As used herein, the term “visually distinct” refers to features of the web material which are readily discernible to the normal naked eye when the web material or objects embodying the web material are subjected to normal use.
In one or more embodiments, the first pattern 310 of raised rib-like elements 304a comprises a macro pattern while the second pattern 312 of raised rib-like elements 304b comprises a micro pattern. As used herein a macro pattern is a pattern that is larger in one or more ways than a micro pattern. For example, as shown by
As mentioned above, the raised rib-like elements 304a are longer than the raised rib-like elements 304b. In one or more embodiments, the raised rib-like elements 304a have a length at least 1.5 times the length of the raised rib-like elements 304b. For example, the raised rib-like elements 304a can have a length between 1.5 and 20 times the length of the raised rib-like elements 304b. In particular, the raised rib-like elements 304a can have a length 2, 3, 4, 5, 6, 8, or 10 times the length of the raised rib-like elements 304b.
In one or more implementations, the films with patterns of deformations may comprise two or more distinct thermoplastic films (e.g., two films extruded separately). The distinct thermoplastic films can be non-continuously bonded to one another. For example, in one or more embodiments, two film layers can be passed together through a pair of SELF'ing rollers to produce a multi-layered lightly-bonded laminate film 200 with the pattern 220, as shown in
As used herein, the terms “lamination,” “laminate,” and “laminated film,” refer to the process and resulting product made by bonding together two or more layers of film or other material. The term “bonding”, when used in reference to bonding of multiple layers of a multi-layer film, may be used interchangeably with “lamination” of the layers. According to methods of the present disclosure, adjacent layers of a multi-layer film are laminated or bonded to one another. The bonding purposely results in a relatively weak bond between the layers that has a bond strength that is less than the strength of the weakest layer of the film. This allows the lamination bonds to fail before the film layer, and thus the bond, fails.
The term laminate is also inclusive of co-extruded multilayer films comprising one or more tie layers. As a verb, “laminate” means to affix or adhere (by means of, for example, adhesive bonding, pressure bonding, ultrasonic bonding, corona lamination, static bonds, cohesive bonds, and the like) two or more separately made film articles to one another so as to form a multi-layer structure. As a noun, “laminate” means a product produced by the affixing or adhering just described.
As used herein the terms “partially discontinuous bonding” or “partially discontinuous lamination” refers to lamination of two or more layers where the lamination is substantially continuous in the machine direction or in the transverse direction, but not continuous in the other of the machine direction or the transverse direction. Alternately, partially discontinuous lamination refers to lamination of two or more layers where the lamination is substantially continuous in the width of the article but not continuous in the height of the article, or substantially continuous in the height of the article but not continuous in the width of the article. More particularly, partially discontinuous lamination refers to lamination of two or more layers with repeating bonded patterns broken up by repeating unbonded areas in either the machine direction or the transverse direction.
In one or more embodiments, the first and second films 402, 404 may be discontinuously bonded together via one or more of the methods of bonding films together as described in U.S. Pat. No. 8,603,609, the disclosure of which is incorporated in its entirety by reference herein. In particular, the first and second films 402, 404 may be bonded via one or more of MD rolling, TD rolling, DD ring rolling, SELF'ing, pressure bonding, corona lamination, adhesives, or combinations thereof. In one or more implementations, the first and second films 402, 404 may be bonded such that the bonded regions have bond strengths below a strength of the weakest film of the first and second films 402, 404. In other words, the bonded regions may fail (e.g., break apart) before the first or second films 402, 404 fail. As a result, discontinuously bonding the first and second films 402, 404 may also increase or otherwise modify one or more of the tensile strength, tear resistance, impact resistance (e.g., dart impact resistance), or elasticity of the films. Furthermore, the bonded regions between the first and second films 402, 404 may provide additional strength. Such bonded regions may be broken to absorb forces rather than such forces resulting in tearing of the film.
Furthermore, any of the pressure techniques (i.e., bonding techniques) described in U.S. Pat. No. 8,603,609 may be combined with other techniques in order to further increase the strength of the bonded regions while maintaining bond strength below the strength of the weakest layer of the multi-layer laminate film. For example, heat, pressure, ultrasonic bonding, corona treatment, or coating (e.g., printing) with adhesives may be employed. Treatment with a corona discharge can enhance any of the above methods by increasing the tackiness of the film surface so as to provide a stronger lamination bond, but which is still weaker than the tear resistance of the individual layers.
Discontinuously bonding the first and second films 402, 404 together results in un-bonded regions and bonded regions between the first and second films 402, 404. For example, discontinuously bonding the first and second films 402, 404 together may result in un-bonded regions and bonded regions as described in U.S. Pat. No. 9,637,278, the disclosure of which is incorporated in its entirety by reference herein.
As mentioned, in one or more cases, an interspersed pattern of multiple motifs of deformations (e.g., raised rib-like elements) helps to increase the dart impact resistance of a thermoplastic film or thermoplastic bag. For example, alternating or varying motifs in a pattern of deformations in the thermoplastic film can impart added strength to the thermoplastic film that helps to withstand impacts of objects (e.g., sharp objects) onto the thermoplastic film.
Moreover, in one or more embodiments, a first motif comprises a macro pattern of deformations and a second motif comprises a micro pattern of deformations. For instance, as illustrated by
For example, as shown in
Furthermore, and also similar to the thermoplastic film 200e, the web areas in the thermoplastic film 200f lack sharp corners. For example, each corner of the first diamond pattern 310f and the second diamond pattern 312f is rounded. In contrast with the thermoplastic film 200e, the first motif (of the first plurality of raised rib-like elements 304k) and the second motif (of the second plurality of raised rib-like elements 304m) are of comparable size. In particular, the first and second motifs in the thermoplastic film 200f do not comprise a macro pattern and a micro pattern, respectively, but rather comprise raised rib-like elements of the same size. In one or more cases, forming patterns of deformations that have a first motif interspersed with a second motif enhances the dart impact resistance of the thermoplastic film, even if the first motif and the second motif are similarly sized patterns. In other words, a macro pattern and a micro pattern of motifs is not necessary for enhancing dart strength of the thermoplastic film.
As shown by
As mentioned above, one or more implementations of the present disclosure include products made from or with such thermoplastic films having the patterns described herein. For example, such products include, but are not limited to, grocery bags, trash bags, sacks, and packaging materials, feminine hygiene products, baby diapers, adult incontinence products, or other products. The following figures describe various bags including patterns that enhance dart impact resistance, and methods of making the same.
For example,
In one or more implementations, the bottom edge 1210 or one or more of the side edges 1206, 1208 can comprise a fold. In other words, the first and second sidewalls 1202, 1204 may comprise a single unitary piece of material. The top edges 1211 of the first and second sidewalls 1202, 1204 may define an opening 1212 to an interior of the thermoplastic bag 1200. In other words, the opening 1212 may be oriented opposite the bottom edge 1210 of the thermoplastic bag 1200. Furthermore, when placed in a trash receptacle, the top edges 1211 of the first and second sidewalls 1202, 1204 may be folded over the rim of the receptacle.
In one or more implementations, the thermoplastic bag 1200 may optionally include a closure mechanism 1214 located adjacent to the top edges 1211 for sealing the top of the thermoplastic bag 1200 to form an at least substantially fully-enclosed container or vessel. As shown in
Although the thermoplastic bag 1200 is described herein as including a closure mechanism 1214 with a draw tape 1216, one of ordinary skill in the art will readily recognize that other closure mechanisms may be implemented into the thermoplastic bag 1200. For example, in one or more implementations, the closure mechanism 1214 may include one or more of flaps, adhesive tapes, a tuck and fold closure, an interlocking closure, a slider closure, a zipper closure, or any other closure structures known to those skilled in the art for closing a bag.
As shown in
For example,
Furthermore, as shown by
Additionally,
In one or more embodiments, a thermoplastic bag has different areas or regions with different measures of dart impact resistance. For example, as shown, the thermoplastic bag 1300 has the pattern 220b in a first region and the pattern 1302 in a second region. In one or more cases, one region of the thermoplastic bag 1300 (e.g., the first region with the pattern 220b) has a higher dart impact resistance than another region of the thermoplastic bag 1300 (e.g., the second region with the pattern 1302).
Experiments of dart impact resistance were performed on thermoplastic films having the pattern 220b shown in
As mentioned, in one or more embodiments, a thermoplastic film has patterns of deformations separated by web areas without sharp corners.
Moreover, the web areas 302c, 302d lack sharp corners, as the first motif and the second motif have rounded corners. As discussed, in one or more cases, the absence of sharp corners in the web areas 302c, 302d can help enhance the dart impact resistance of the thermoplastic bag 1400a. For example, by forming the raised rib-like elements such that the web areas do not have sharp corners, the possibility of stress concentrations in the thermoplastic bag can be avoided or reduced. Thus, the thermoplastic bag 1400a can have enhanced dart impact resistance over, for example, the thermoplastic bag 1300.
Additionally,
Embodiments of the present disclosure can have different regions with different measures of dart impact resistance to provide one or more advantages. For example, by providing the first region with the pattern 220c and the second region with the pattern 1302, the thermoplastic bag 1400a can have tailored strengths based on anticipated use cases of the thermoplastic bag 1400a. For instance, it may be anticipated that a middle portion and/or a bottom portion of the thermoplastic bag 1400a will be more likely to be subjected to contact by sharp objects, whereas a top portion will be less likely to be subjected to contact by sharp objects. Thus, the patterns of deformations can be designed such that the thermoplastic bag 1400a has a relatively higher dart impact resistance in the middle and/or bottom portions than in the top portion of the thermoplastic bag 1400a.
As mentioned, designing the web areas of the patterns of deformations can enhance a thermoplastic film's dart impact resistance (e.g., separately from or in addition to utilizing multiple motifs of deformations). In one or more embodiments, the thermoplastic films and bags of the present disclosure can have a dart impact resistance between 200 grams and 350 grams. More particularly, in one or more embodiments, the thermoplastic films and bags can have a dart impact resistance between 250 grams and 300 grams. In one or more implementations, the thermoplastic films and bags can have a dart impact resistance between 280 grams and 320 grams.
As shown in
In one or more embodiments, a thermoplastic bag has a first region with a pattern of deformations that have web areas that lack sharp corners (such as the patterns 220c and 220g of
While the bags shown and described above include patterns of deformations formed in the entire sidewalls of the bags, one will appreciate in light of the disclosure herein that the present invention is not so limited. In alternative embodiments, the bags can comprise patterns of deformations in zones, regions, or areas so as to tailor the properties of different areas of the bag. For example,
To produce a bag having a pattern or patterns of deformations as described herein, continuous webs of thermoplastic material may be processed through a high-speed manufacturing environment such as that illustrated in
To form a pattern 1968, the processing equipment may include SELF'ing intermeshing rollers 1942, 1943 such as those described herein above. Referring to
In the illustrated implementation, the intermeshing rollers 1942, 1943 may be arranged so that they are co-extensive with or wider than the width 1928 of the folded web 1980. In one or more implementations, the intermeshing rollers 1942, 1943 may extend from proximate the folded edge 1926 to the adjacent edges 1910, 1912. To avert imparting the pattern 1968 onto the portion of the web that includes the draw tape 1932, the corresponding ends 1949 of the rollers 1942, 1943 may be smooth and without the ridges and grooves. Thus, the adjacent edges 1910, 1912 and the corresponding portion of the web proximate those edges that pass between the smooth ends 1949 of the rollers 1942, 1943 may not be imparted with the pattern 1968.
The processing equipment may include pinch rollers 1962, 1964 to accommodate the width 1958 of the web 1980. To produce the finished bag, the processing equipment may further process the folded web. For example, to form the parallel side edges of the finished bag, the web may proceed through a sealing operation 1970 in which heat seals 1972 may be formed between the folded edge 1926 and the adjacent edges 1910, 1912. The heat seals may fuse together the adjacent halves 1922, 1924 of the folded web. The heat seals 1972 may be spaced apart along the folded web and in conjunction with the folded outer edge 1926 may define individual bags. The heat seals may be made with a heating device, such as a heated knife. A perforating operation 1981 may perforate 1982 the heat seals 1972 with a perforating device, such as a perforating knife so that individual bags 1984 may be separated from the web. In one or more implementations, the webs may be folded one or more times before the folded webs may be directed through the perforating operation. The web 1980 embodying the bags 1984 may be wound into a roll 1986 for packaging and distribution. For example, the roll 1986 may be placed in a box or a bag for sale to a customer.
In one or more implementations of the process, a cutting operation 1988 may replace the perforating operation 1981. The web is directed through a cutting operation 1988 which cuts the webs at location 1990 into individual bags 1992 prior to winding onto a roll 1994 for packaging and distribution. For example, the roll 1994 may be placed in a box or bag for sale to a customer. The bags may be interleaved prior to winding into the roll 1994. In one or more implementations, the web may be folded one or more times before the folded web is cut into individual bags. In one or more implementations, the bags 1992 may be positioned in a box or bag, and not onto the roll 1994.
The use in the foregoing description and in the appended claims of the terms “first,” “second,” “third,” etc., is not necessarily to connote a specific order or number of elements. Generally, the terms “first,” “second,” “third,” etc., are used to distinguish between different elements as generic identifiers. Absent a showing that the terms “first,” “second,” “third,” etc., connote a specific order, these terms should not be understood to connote a specific order. Furthermore, absent a showing that the terms “first,” “second,” “third,” etc., connote a specific number of elements, these terms should not be understood to connote a specific number of elements. For example, a first widget may be described as having a first side and a second widget may be described as having a second side. The use of the term “second side” with respect to the second widget may be to distinguish such side of the second widget from the “first side” of the first widget, and not necessarily to connote that the second widget has two sides.
In the foregoing description, the invention has been described with reference to specific exemplary embodiments thereof. Various embodiments and aspects of the invention(s) are described with reference to details discussed herein, and the accompanying drawings illustrate the various embodiments. The description above and drawings are illustrative of the invention and are not to be construed as limiting the invention. Numerous specific details are described to provide a thorough understanding of various embodiments of the present invention.
The present disclosure may be embodied in other specific forms without departing from its spirit or essential characteristics. For example, the illustrated and described implementations involve non-continuous (i.e., discontinuous or partially discontinuous) lamination to provide weak bonds. In alternative implementations, the lamination may be continuous. For example, multi film layers could be co-extruded so that the layers have a bond strength that provides for delamination prior to film failure to provide similar benefits to those described above. Thus, the described implementations are to be considered in all respects only as illustrative and not restrictive. The scope of the disclosure is, therefore, indicated by the appended claims rather than by the foregoing description. All changes that come within the meaning and range of equivalency of the claims are to be embraced within their scope.
The present application is a continuation-in-part of U.S. patent application Ser. No. 18/525,492 filed Nov. 30, 2023, which is a continuation application of U.S. patent application Ser. No. 18/491,008 filed Oct. 20, 2023, which is a continuation of U.S. patent application Ser. No. 17/933,332 filed on Sep. 19, 2022, which is a continuation of U.S. patent application Ser. No. 16/761,191 filed on May 1, 2020, which is a National Stage Entry of PCT/US2018/058998 filed on Nov. 2, 2018, which claims the benefit of and priority to U.S. Provisional Application No. 62/583,108, filed Nov. 8, 2017 and entitled: THERMOPLASTIC FILMS AND BAGS WITH COMPLEX STRETCH PATTERNS AND METHODS OF MAKING THE SAME. The contents of the above-referenced applications are hereby incorporated by reference in their entirety.
Number | Date | Country | |
---|---|---|---|
62583108 | Nov 2017 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 18491008 | Oct 2023 | US |
Child | 18525492 | US | |
Parent | 17933332 | Sep 2022 | US |
Child | 18491008 | US | |
Parent | 16761191 | May 2020 | US |
Child | 17933332 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 18525492 | Nov 2023 | US |
Child | 18883883 | US |