Thermoplastic elastomer-asphalt nanocomposite composition

Information

  • Patent Grant
  • 5652284
  • Patent Number
    5,652,284
  • Date Filed
    Thursday, November 9, 1995
    28 years ago
  • Date Issued
    Tuesday, July 29, 1997
    27 years ago
Abstract
A composite material is provided comprising an elastomer, from about 0.1 wt % to about 15 wt. % of a layered mineral based on the weight of the total composition and from about 0.1 wt. % to about 15 wt. % of asphalt based on the weight of the total composition.
Description
Claims
  • 1. A composite, comprising:
  • an elastomer having a Tg of less than 25.degree. C.;
  • a layered mineral in an amount ranging from about 0.5 to about 15 wt % based on the total weight of the composite capable of forming an intercalation compound; and
  • an asphalt in an amount ranging from about 0.1 wt % to about 15 wt % based on the total weight of the composite, wherein the asphalt has a penetration number as determined by ASTM Method D-5 at 25.degree. C. of from about 20 to about 300.
  • 2. The composite of claim 1, wherein the elastomer has a number average molecular weight in the range of about 30,000 to 600,000 gms./mol.
  • 3. The composite of claim 2, wherein the asphalt is sulfonated and neutralized.
  • 4. The composite of claim 1 wherein the layered mineral is selected from the group consisting of smectitic clay, montmorillonite, saporite, beidellite, montronite, hectorite, stensite, vermiculite, and hallosite.
  • 5. The composite of claim 3 wherein the elastomer is a styrene-butadiene copolymer having a styrene content in the range of about 10 wt. % to about 50 wt. %.
  • 6. The composite of claim 4, wherein the asphalt is sulfonated and neutralized.
  • 7. A composite comprising:
  • an elastomer having a Tg of less than 25.degree. C.;
  • a layered mineral in amount ranging from about 0.5 wt % to about 15 wt % based on the total weight of the composite, the layered mineral having been modified with a hydrocarbyl onium ion swelling agent to form an intercalation compound; and
  • from about 0.1 wt % to about 15 wt % based on the total weight of the composition of an asphalt or sulfonated asphalt wherein the asphalt has a penetration number as determined by ASTM Method D-5 at 25.degree. C. of from about 20 to about 300.
US Referenced Citations (1)
Number Name Date Kind
4332620 Quinn Jun 1982
Non-Patent Literature Citations (1)
Entry
"Molecular Weight Determination," Encyclopedia of Polymer Science and Engineering (1987 ed.), pp. 1-3 of vol. 10.