THERMOPLASTIC POLYMER COMPOSITION AND PROCESSING STABILISER

Abstract

The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphoric compound, compound (9) which is compound (9a) represented by CmH2mOm wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR26 wherein R26 is a C1-12 alkyl group, and a thermoplastic polymer, and a processing stabilizer containing a particular phenol compound or organic phosphoric compound, and compound (9). A combined use of a particular phenol compound or organic phosphoric compound and compound (9) can improve processing stability of a thermoplastic polymer composition.

Description

TECHNICAL FIELD

The present invention relates to a thermoplastic polymer composition superior in the processing stability. Moreover, the present invention also relates to a processing stabilizer.

BACKGROUND ART

Since thermoplastic polymers are superior in transparency and show good impact resistance, they are widely used for food packaging containers, convenience goods and the like. For the production of such products, thermoplastic polymers are used as compositions containing additives. As additives for thermoplastic polymers, 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate, 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine (which is also called 6-t-butyl-4-[3-[(2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]propyl]-2-methylphenol), octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate, 3,9-bis[2-{3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], tris(2,4-di-t-butylphenyl)phosphite and the like are known (patent documents 1-6).

DOCUMENT LIST

Patent Documents

• patent document 1: JP-A-1-168643
• patent document 2: JP-A-10-273494
• patent document 3: U.S. Pat. No. 3,330,859
• patent document 4: U.S. Pat. No. 3,644,482
• patent document 5: JP-A-59-25826
• patent document 6: JP-A-51-109050

SUMMARY OF THE INVENTION

Problems to be Solved by the Invention

There is a demand for a thermoplastic polymer composition showing further improved processing stability.

Means of Solving the Problems

The present inventors have conducted intensive studies in an attempt to solve the aforementioned problems and found that a thermoplastic polymer composition containing the following compound represented by the formula (1), the following compound represented by the formula (2), 25 at least one selected from the group consisting of the following compounds represented by the formulas (3)-(7), or the following compound represented by the formula (8), compound (9), and a thermoplastic polymer shows superior processing stability. They have reached the following invention based on such findings.

[1] A thermoplastic polymer composition comprising a compound represented by the formula (1):

wherein in the formula (1),

each R¹ and/or each R² are/is independently a C_1-8 alkyl group, a C_6-12 aryl group or a C_7-18 aralkyl group,

R³ is a hydrogen atom or a C_1-3 alkyl group, and

R⁴ is a hydrogen atom or a methyl group,

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group, and

a thermoplastic polymer.

[2] The thermoplastic polymer composition of the above-mentioned [1], wherein the total amount of the compound represented by the formula (1) and compound (9) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.[3] A processing stabilizer comprising

a compound represented by the formula (1) and

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group.

[4] The processing stabilizer of the above-mentioned [3], wherein the compound represented by the formula (1) is at least one selected from the group consisting of 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate and 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate.[5] The processing stabilizer of the above-mentioned [3] or [4], wherein m is 6.[6] The processing stabilizer of the above-mentioned [5], wherein compound (9) is methyl α-D-glucopyranoside.[7] The processing stabilizer of any one of the above-mentioned [3]-[6], wherein the content of compound (9) is 0.1-95 wt % of the total of a compound represented by the formula (1) and compound (9).[8] The processing stabilizer of any one of the above-mentioned [3]-[7], further comprising a compound represented by the formula (2):

wherein in the formula (2),

each R⁵ and/or each R⁶ are/is independently a hydrogen atom or a C_1-6 alkyl group,

L¹ is an n-valent C_1-24 alcohol residue optionally containing a hetero atom,

n is an integer of 1-4, and

the alcohol residue here is a residue obtained by removing a hydrogen atom from the hydroxy group of the alcohol.

[9] The processing stabilizer of any one of the above-mentioned [3]-[8], further comprising at least one selected from the group consisting of the compounds represented by the formulas (3)-(7):

wherein in the formula (3), each R⁷ and/or each R⁸ are/is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

wherein in the formula (4), each R⁹ is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

wherein in the formula (5), each R¹⁰ is independently a C_1-18 alkyl group or a phenyl group optionally substituted by at least one selected from the group consisting of a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_5-12 alkylcycloalkyl group and a C_7-12 aralkyl group,

wherein in the formula (6),

each R¹¹ and/or each R¹² are/is independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_8-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

each L² is independently a single bond, a sulfur atom or a divalent group represented by the formula (6a):

wherein in the formula (6a), R¹³ and R¹⁴ are each independently a hydrogen atom or a alkyl group, and the total carbon number of R¹³ and R¹⁴ is not more than 7, and

each L³ is independently a C_2-8 alkylene group,

wherein in the formula (7),

each R¹⁵ and/or each R¹⁶ are/is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

R¹⁷ is a C_1-8 alkyl group or a phenyl group optionally substituted by at least one selected from the group consisting of a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group and a C_7-12 aralkyl group, and

L⁴ is a single bond, a sulfur atom or a divalent group represented by the formula (7a):

wherein in the formula (7a), R¹⁸ and R¹⁹ are each independently a hydrogen atom or a alkyl group, and the total carbon number of R¹⁸ and R¹⁹ is not more than 7.[10] The processing stabilizer of any one of the above-mentioned [3]-[8], further comprising a compound represented by the formula (3).[11] A method of producing a thermoplastic polymer composition comprising mixing the processing stabilizer of any one of the above-mentioned [3]-[10] and a thermoplastic polymer.[12] Use of the processing stabilizer of any one of the above-mentioned [3]-[10] for improving the processing stability of a thermoplastic polymer composition.[13] A thermoplastic polymer composition comprising

a compound represented by the formula (8):

wherein in the formula (8),

each R²⁰ and/or each R²¹ are/is independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

R²³ and R²⁴ are each independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group,

each R²² is independently a hydrogen atom or a C_1-8 alkyl group,

L⁵ is a single bond, a sulfur atom or a divalent group represented by the formula (8a):

wherein in the formula (8a), R²⁵ is a hydrogen atom, a C_1-8 alkyl group or a C_5-8 cycloalkyl group,

L⁶ is a C_2-8 alkylene group or a divalent group represented by the formula (8b):

wherein in the formula (8b), L⁷ is a single bond or a C_1-8 alkylene group, and * shows bonding to the oxygen atom side, and

one of Z¹ and Z² is a hydroxy group, a C_1-8 alkyl group, a C_1-8 alkoxy group or a C_7-12 aralkyloxy group, and the other is a hydrogen atom or a C_1-8 alkyl group,

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group, and

a thermoplastic polymer.

[14] The thermoplastic polymer composition of the above-mentioned [13], wherein the total amount of the compound represented by the formula (8) and compound (9) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.[15] A processing stabilizer comprising

a compound represented by the formula (8), and compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group.

[16] The processing stabilizer of the above-mentioned [15], wherein the compound represented by the formula (8) is 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine.[17] The processing stabilizer of the above-mentioned [15] or [16], wherein m is 6.[18] The processing stabilizer of the above-mentioned [17], wherein compound (9) is methyl α-D-glucopyranoside.[19] The processing stabilizer of any one of the above-mentioned [15]-[18], wherein the content of compound (9) is 0.1-95 wt % of the total of a compound represented by the formula (8) and compound (9).[20] The processing stabilizer of any one of the above-mentioned [15]-[19], further comprising a compound represented by the formula (2).[21] The processing stabilizer of any one of the above-mentioned [15]-[20], further comprising at least one selected from the group consisting of the compounds represented by the formulas (3)-(7).[22] The processing stabilizer of any one of the above-mentioned [15]-[20], further comprising a compound represented by the formula (3).[23] A method of producing a thermoplastic polymer composition comprising mixing the processing stabilizer of any one of the above-mentioned [15]-[22] and a thermoplastic polymer.[24] Use of the processing stabilizer of any one of the above-mentioned [15]-[22] for improving the processing stability of a thermoplastic polymer composition.[25] A thermoplastic polymer composition comprising

a compound represented by the formula (2),

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group, and

a thermoplastic polymer.

[26] The thermoplastic polymer composition of the above-mentioned [25], wherein the total amount of the compound represented by the formula (2) and compound (9) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.[27] The thermoplastic polymer composition of the above-mentioned [25] or [26], wherein the thermoplastic polymer is a styrene-butadiene block copolymer.[28] A processing stabilizer comprising

a compound represented by the formula (2), and

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group.

[29] A processing stabilizer consisting of

a compound represented by the formula (2), and

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group.

[30] The processing stabilizer of the above-mentioned [28] or [29], wherein the compound represented by the formula (2) is at least one selected from the group consisting of octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate, 3,9-bis[2-{3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate].[31] The processing stabilizer of any one of the above-mentioned [28]-[30], wherein m is 6.[32] The processing stabilizer of the above-mentioned [31], wherein compound (9) is methyl α-D-glucopyranoside.[33] The processing stabilizer of any one of the above-mentioned [28]-[32], wherein the content of compound (9) is 0.1-95 wt % of the total of a compound represented by the formula (2) and compound (9).[34] A method of producing a thermoplastic polymer composition comprising mixing the processing stabilizer of any one of the above-mentioned [28]-[33] and a thermoplastic polymer.[35] Use of the processing stabilizer of any one of the above-mentioned [28]-[33] for improving the processing stability of a thermoplastic polymer composition.[36] A thermoplastic polymer composition comprising compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group,

a thermoplastic polymer, and

at least one selected from the group consisting of the compounds represented by the formulas (3)-(7).

[37] The thermoplastic polymer composition of the above-mentioned [36], wherein the total amount of compound (9) and the compound selected from the group consisting of the compounds represented by the formulas (3)-(7) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.[38] The thermoplastic polymer composition of the above-mentioned [36] or [37], wherein the thermoplastic polymer is a styrene-butadiene block copolymer.[39] A processing stabilizer comprising

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR²⁶ wherein R²⁶ is a C_1-12 alkyl group, and

at least one selected from the group consisting of the compounds represented by the formulas (3)-(7).

[40] A processing stabilizer consisting of

compound (9) which is compound (9a) represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR⁶ wherein R²⁶ is a C_1-12 alkyl group, and

at least one selected from the group consisting of the compounds represented by the formulas (3)-(7).

[41] The processing stabilizer of the above-mentioned [39] or [40], wherein at least one selected from the group consisting of the compounds represented by the formulas (3)-(7) is the compound represented by the formula (3).[42] The processing stabilizer of the above-mentioned [41], wherein the compound represented by the formula (3) is tris(2,4-di-t-butylphenyl) phosphite.[43] A method of producing a thermoplastic polymer composition comprising mixing the processing stabilizer of any one of the above-mentioned [39]-[42] and a thermoplastic polymer.[44] Use of the processing stabilizer of any one of the above-mentioned [39]-[42] for improving the processing stability of a thermoplastic polymer composition.

In the present invention, the “C_a-b” means that the carbon number is not less than a and not more than b. In the following, the “compound represented by the formula (1)” and the like are sometimes abbreviated as “compound (1)” and the like. Similarly, the “divalent group represented by the formula (6a)” and the like are sometimes abbreviated as “divalent group (6a)” and the like.

Effect of the Invention

By using compound (1), compound (2), at least one selected from the group consisting of compounds (3)-(7) or compound (8) in combination with compound (9), the processing stability of a thermoplastic polymer composition can be improved.

DESCRIPTION OF EMBODIMENTS

The present invention is explained successively in the following. In the following, the thermoplastic polymer composition of the present invention and the processing stabilizer of the present invention, which contain compound (1) and compound (9) as essential components, are sometimes referred to as “the first thermoplastic polymer composition” and “the first processing stabilizer”, respectively.

In addition, the thermoplastic polymer composition of the present invention and the processing stabilizer of the present invention, which contain compound (8) and compound (9) as essential components, are sometimes referred to as “the second thermoplastic polymer composition” and “the second processing stabilizer”, respectively.

Furthermore, the thermoplastic polymer composition of the present invention and the processing stabilizer of the present invention, which contain compound (2) and compound (9) as essential components, are sometimes referred to as “the third thermoplastic polymer composition” and “the third processing stabilizer”, respectively.

Moreover, the thermoplastic polymer composition of the present invention and the processing stabilizer of the present invention, which contain compound (9) and at least one selected from the group consisting of compounds (3)-(7) as essential components, are sometimes referred to as “the fourth thermoplastic polymer composition” and “the fourth processing stabilizer”, respectively.

Here, the “processing stabilizer” means an agent used for improving the processing stability of the thermoplastic polymer composition. The processing stability of the thermoplastic polymer composition can be evaluated by the method described in the below-mentioned Examples.

The thermoplastic polymer composition of the present invention characteristically contains the processing stabilizer of the present invention (i.e., compound (1), compound (2), at least one selected from the group consisting of the compounds represented by the formulas (3)-(7), or compound (8), and compound (9)). The processing stabilizer of the present invention is explained in the following.

The first processing stabilizer contains compound (1) as one of the characteristics. Only one kind of compound (1) may be used or two or more kinds thereof may be used in combination. In the following, compound (1) is explained successively.

Each R¹ and/or each R² in the formula (1) are/is independently a C_1-6 alkyl group, a C_6-12 aryl group or a C_7-18 aralkyl group. While there are two R¹, they may be the same or different, and they are preferably the same. The same applies to R².

The C_1-8 alkyl group may be a chain or a cyclic group, preferably a chain (linear or branched chain), more preferably a branched chain. The C_1-8 alkyl group includes a linear C_1-8 alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group (to be also referred to as an amyl group) and the like), a branched chain C_3-8 alkyl group (e.g., an isopropyl group, an isobutyl group, a sec-butyl group, a t-butyl group, a t-pentyl group, a 2-ethylhexyl group and the like), and a cyclic C_3-8 alkyl group (i.e., a C_3-6 cycloalkyl group, for example, a cyclopentyl group, a cyclohexyl group and the like). Examples of the C_6-12 aryl group include a phenyl group, a 1-naphthyl group, a 2-naphthyl group and the like. Examples of the C_7-18 aralkyl group include a benzyl group, a 1-phenylethyl group, a 2-phenylethyl group and the like.

Preferably, each R¹ and/or each R² are/is independently a branched chain C_3-8 alkyl group, more preferably a C_4-8 alkyl group having a tertiary carbon atom, still more preferably a t-butyl group or a t-pentyl group, particularly preferably a t-pentyl group.

R³ in the formula (1) is a hydrogen atom or a C_1-3 alkyl group. The C_1-3 alkyl group may be a linear or branched chain. Examples of the C_1-3 alkyl group include a methyl group, an ethyl group, a propyl group and an isopropyl group. R³ is preferably a hydrogen atom or a methyl group.

R⁴ in the formula (1) is a hydrogen atom or a methyl group, preferably a hydrogen atom.

Examples of compound (1) include 2,4-di-t-butyl-6-[1-(3,5-di-t-butyl-2-hydroxyphenyl)ethyl]phenyl(meth)acrylate, 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl(meth)acrylate, 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl(meth)acrylate, 2,4-di-t-butyl-6-(3,5-di-t-butyl-2-hydroxy-benzyl)phenyl(meth)acrylate, 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-ethylphenyl(meth)acrylate, 2-t-pentyl-6-(3-t-pentyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl(meth)acrylate and the like. Here, the “(meth)acrylate” means “acrylate and methacrylate”.

Preferable compound (1) is 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate (hereinafter sometimes to be abbreviated as “compound (1-1)”), and 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (hereinafter sometimes to be abbreviated as “compound (1-2)”). Compound (1-1) is commercially available as Sumilizer (registered trade mark) GS(F) (manufactured by Sumitomo Chemical Company, Limited), and compound (1-2) is commercially available as Sumilizer (registered trade mark) GM (manufactured by Sumitomo Chemical Company, Limited).

As compound (1), a commercially available product can be used, or it can be produced according to a known method (e.g., the method described in JP-A-1-168643 or JP-A-58-84835).

The first processing stabilizer contains compound (9) as one of the characteristics. Compound (9) is a compound in which at least one hydroxy group of compound (9a) has been replaced by an alkoxy group (—OR²⁶; R²⁶ is a C_1-12 alkyl group). Compound (9) may be a hydrate or an anhydrate.

Compound (9a) is a monosaccharide represented by C_mH_2mO_m wherein m is an integer of not less than 3 and not more than 10, and having hydroxy groups in the number of m−1. Compound (9a) is triose (m=3), tetrose (m=4), pentose (m=5), hexose (m=6), heptose (m=7), octose (m=8), nonose (m=9) or decose (m=10). m is preferably not less than 4 (more preferably not less than 5), preferably not more than 8 (more preferably not more than 7), still more preferably 6.

Compound (9a) may be a cyclic compound or a chain compound, preferably a cyclic compound. Cyclic compound (9a) may be of a pyranose type or furanose type, preferably a pyranose type. Compound (9a) may be a D-form or L-form, preferably D-form. Furthermore, compound (9a) may be an aldose having an aldehyde group (also called formyl group), or a ketose having a ketone group (also called carbonyl group), preferably aldose. Compound (9a) may be a mixture of those mentioned above.

Examples of the aldose include aldotriose (glyceraldehyde); aldotetrose (erythrose, threose); aldopentose (ribose, arabinose, xylose, lyxose); aldohexose (glucose, mannose, galactose, allose, altrose, gulose, idose, talose); and aldoheptose (for example, D-glycero-D-galacto-heptose and the like).

Examples of the ketose include ketotriose (dihydroxyacetone); ketotetrose (erythrulose); ketopentose (ribulose, xylulose); ketohexose (psicose, fructose, sorbose, tagatose); and ketoheptose (for example, sedoheptulose, D-manno-heptulose and the like).

Compound (9a) is preferably hexose, more preferably aldohexose, still more preferably glucose. Aldohexose is preferably of a pyranose type. In the following, “a compound wherein hydroxy group of hexose is replaced by —OR²⁶ group” and the like are sometimes referred to as “hexose-compound (9)” and the like.

The number of —OR²⁶ groups in compound (9) is preferably not more than 5, more preferably not more than 3, still more preferably 1. When plural —OR²⁶ groups are present, each R²⁶ may be the same or different, preferably the same. The —OR²⁶ group is preferably bonded to the 1-position carbon atom of compound (9a). When —OR²⁶ group is bonded to the 1-position carbon atom of cyclic compound (9a), the binding direction of —OR²⁶ group may be α or β, preferably α. The indication of the binding direction and the position number follows the standard of monosaccharides.

R²⁶ is a C_1-12 alkyl group. The C_1-12 alkyl group may be chain or a cyclic group, preferably chain (linear or branched chain), more preferably linear chain. The carbon number of the C_1-12 alkyl group is preferably not less than 1 and not more than 8. Examples of the C_1-12 alkyl group include linear C_1-12 alkyl group (methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group), branched chain C_3-12 alkyl group (for example, isopropyl group, isobutyl group, sec-butyl group, t-butyl group, isopentyl group, neopentyl group, t-pentyl group and the like), cyclic C_3-12 alkyl group (i.e. C_3-12 cycloalkyl group, for example, cyclopentyl group, cyclohexyl group and the like). The C_1-12 alkyl group is preferably methyl group, ethyl group or octyl group, more preferably methyl group.

Compound (9) is preferably hexose-compound (9), more preferably aldohexose-compound (9) (i.e., glucose-compound (9), mannose-compound (9), galactose-compound (9), allose-compound (9), altrose-compound (9), gulose-compound (9), idose-compound (9), or talose-compound (9)). The aforementioned aldohexose is preferably of a pyranose type.

Examples of the glucose-compound (9) include methyl α-D-glucopyranoside, ethyl α-D-glucopyranoside, propyl α-D-glucopyranoside, butyl α-D-glucopyranoside, pentyl α-D-glucopyranoside, hexyl α-D-glucopyranoside, heptyl α-D-glucopyranoside, octyl α-D-glucopyranoside, nonyl α-D-glucopyranoside, decyl α-D-glucopyranoside, undecyl α-D-glucopyranoside, dodecyl α-D-glucopyranoside and the like.

Examples of the mannose-compound (9) include methyl α-D-mannopyranoside, ethyl α-D-mannopyranoside, propyl α-D-mannopyranoside, butyl α-D-mannopyranoside, pentyl α-D-mannopyranoside, hexyl α-D-mannopyranoside, heptyl α-D-mannopyranoside, octyl α-D-mannopyranoside, nonyl α-D-mannopyranoside, decyl α-D-mannopyranoside, undecyl α-D-mannopyranoside, dodecyl α-D-mannopyranoside and the like.

Examples of the galactose-compound (9) include methyl α-D-galactopyranoside, ethyl α-D-galactopyranoside, propyl α-D-galactopyranoside, butyl α-D-galactopyranoside, pentyl α-D-galactopyranoside, hexyl α-D-galactopyranoside, heptyl α-D-galactopyranoside, octyl α-D-galactopyranoside, nonyl α-D-galactopyranoside, decyl α-D-galactopyranoside, undecyl α-D-galactopyranoside, dodecyl α-D-galactopyranoside and the like.

Examples of the allose-compound (9) include methyl α-D-allopyranoside, ethyl α-D-allopyranoside, propyl α-D-allopyranoside, butyl α-D-allopyranoside, pentyl α-D-allopyranoside, hexyl α-D-allopyranoside, heptyl α-D-allopyranoside, octyl α-D-allopyranoside, nonyl α-D-allopyranoside, decyl α-D-allopyranoside, undecyl α-D-allopyranoside, dodecyl α-D-allopyranoside and the like.

Examples of the altrose-compound (9) include methyl α-D-altropyranoside, ethyl α-D-altropyranoside, propyl α-D-altropyranoside, butyl α-D-altropyranoside, pentyl α-D-altropyranoside, hexyl α-D-altropyranoside, heptyl α-D-altropyranoside, octyl α-D-altropyranoside, nonyl α-D-altropyranoside, decyl α-D-altropyranoside, undecyl α-D-altropyranoside, dodecyl α-D-altropyranoside and the like.

Examples of the gulose-compound (9) include methyl α-D-gulopyranoside, ethyl α-D-gulopyranoside, propyl α-D-gulopyranoside, butyl α-D-gulopyranoside, pentyl α-D-gulopyranoside, hexyl α-D-gulopyranoside, heptyl α-D-gulopyranoside, octyl α-D-gulopyranoside, nonyl α-D-gulopyranoside, decyl α-D-gulopyranoside, undecyl α-D-gulopyranoside, dodecyl α-D-gulopyranoside and the like.

Examples of the idose-compound (9) include methyl α-D-idopyranoside, ethyl α-D-idopyranoside, propyl α-D-idopyranoside, butyl α-D-idopyranoside, pentyl α-D-idopyranoside, hexyl α-D-idopyranoside, heptyl α-D-idopyranoside, octyl α-D-idopyranoside, nonyl α-D-idopyranoside, decyl α-D-idopyranoside, undecyl α-D-idopyranoside, dodecyl α-D-idopyranoside and the like.

Examples of the talose-compound (9) include methyl α-D-talopyranoside, ethyl α-D-talopyranoside, propyl α-D-talopyranoside, butyl α-D-talopyranoside, pentyl α-D-talopyranoside, hexyl α-D-talopyranoside, heptyl α-D-talopyranoside, octyl α-D-talopyranoside, nonyl α-D-talopyranoside, decyl α-D-talopyranoside, undecyl α-D-talopyranoside, dodecyl α-D-talopyranoside and the like.

The aforementioned specific examples include compound (9) wherein —OR²⁶ group shows a bonding direction of α. In addition, aldohexose-compound (9) having the same —OR²⁶ group and the bonding direction of β can also be recited as a specific example. In the following, the “compound (9) wherein —OR²⁶ group shows a bonding direction of α” and the like may be abbreviated as “α-form” and the like. Similarly, the aforementioned specific examples include D-form. An L-form having the same —OR²⁶ group can also be recited as a specific example.

Of the aldohexose-compound (9), glucose-compound (9) is preferable, C_1-12 alkyl D-glucopyranoside (both α-form and β-form) is more preferable, methyl α-D-glucopyranoside (hereinafter sometimes abbreviated as “compound (9-1)”) and octyl β-D-glucopyranoside (hereinafter sometimes abbreviated as “compound (9-2)”) are still more preferable, and compound (9-1) is particularly preferable.

Only one kind of compound (9) may be used, or mixture of two or more kinds thereof may be used. Examples of the mixture of compound (9) include a mixture of compound (9) obtained by a known production method from an equilibrium mixture of compound (9a) (for example, glycerose which is an equilibrium mixture of glyceraldehyde and dihydroxyacetone), and the like. In addition, a mixture of α-form and β-form, and a mixture of D-form and L-form can also be used.

Compound (9) can be produced by a known method (e.g., the method described in SHIN JIKKEN KAGAKU KOZA (New Courses in Experimental Chemistry) 14, Synthesis And Reaction Of Organic Compound V (Maruzen Company, Limited, published in Jul. 20, 1978) page 2426). For example, (i) a method of alkoxylating compound (9a) by dissolving compound (9a) (i.e. monosaccharide) in alkanol corresponding to —OR²⁶ group, and flowing a hydrogen chloride gas through the solution at −10° C.-room temperature; (ii) a method of alkoxylating compound (9a) by heating under reflux a mixed solution of compound (9a), alkanol corresponding to —OR²⁶ group and hydrochloric acid; and the like can be mentioned. Compound (9) is commercially available. For example, compound (9-1) and compound (9-2) are available from Tokyo Chemical Industry Co., Ltd.

The content of compound (9) in the first processing stabilizer is preferably not less than 0.1 wt % (more preferably not less than 1 wt %, still more preferably not less than 2 wt %, particularly preferably not less than 5 wt %), preferably not more than 95 wt % (more preferably not more than 90 wt %, still more preferably not more than 75 wt %, particularly preferably not more than 50 wt %), of the total of compound (1) and compound (9).

The first processing stabilizer may consist of compound (1) and compound (9), or may contain other component. For example, the first processing stabilizer may contain compound (2). Only one kind of compound (2) may be used or two or more kinds thereof may be used in combination. In the following, compound (2) is explained successively.

Each R⁵ and/or each R⁶ in the formula (2) are/is independently a hydrogen atom or a C_1-6 alkyl group. When n is two or more, R⁵ may be the same as or different from each other, and they are preferably the same. The same applies to R⁶. The C_1-6 alkyl group may be a chain or a cyclic group, and the chain may be a linear or branched chain. The C_1-6 alkyl group includes a linear C_1-6 alkyl group (a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group), a branched chain C_3-6 alkyl group (e.g., an isopropyl group, an isobutyl group, a t-butyl group, an isopentyl group, a t-pentyl group, a t-hexyl group), and a cyclic C_3-6 alkyl group (i.e., a C_3-6 cycloalkyl group, for example, a cyclopentyl group, a cyclohexyl group). Preferably, each R⁵ and/or each R⁶ are/is independently a linear C_1-6 alkyl group or branched chain C_3-6 alkyl group, more preferably a methyl group or a t-butyl group. Still more preferably, each R⁵ and each R⁶ are t-butyl groups.

L¹ in the formula (2) is an n-valent C_1-24 alcohol residue optionally containing a hetero atom, and n is an integer of 1-4. Examples of the hetero atom include an oxygen atom, a sulfur atom, a nitrogen atom and the like. These hetero atoms may be replaced with the carbon atom of the n-valent C_1-24 alcohol residue. That is, the n-valent C_1-24 alcohol residue may have —O—, —S—, —NR— wherein R is a hydrogen atom or other substituent (e.g., a C_1-6 alkyl group)) and the like. As the hetero atom, an oxygen atom is preferable.

The n-valent C_1-24 alcohol residue (n=1-4) may be a chain or a cyclic residue, or a combination of these. The chain may be a linear or branched chain.

Examples of the monovalent C_1-24 alcohol residue include the residues of methanol, ethanol, propanol, isopropanol, butanol, t-butanol, hexanol, octanol, decanol, dodecanol, tetradecanol, hexadecanol, octadecanol and the like.

Examples of the divalent C_1-24 alcohol residue include the residues of ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, 1,12-dodecanediol, 1,14-tetradecanediol, 1,16-hexadecanediol, diethylene glycol, triethylene glycol, 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane and the like.

Examples of the trivalent C_1-24 alcohol residue include the residues of glycerol and the like.

Examples of the tetravalent C_1-24 alcohol residue include the residues of erythritol, pentaerythritol and the like.

Examples of compound (2) include ester of 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid, 3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionic acid or 3-(3,5-dicyclohexyl-4-hydroxyphenyl)propionic acid and a monovalent or polyvalent alcohol. Examples of the aforementioned monovalent or polyvalent alcohol include methanol, ethanol, octanol, octadecanol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, neopentylglycol, diethylene glycol, thioethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2,2,2]octane, 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane, a mixture thereof and the like.

Preferable compound (2) is octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (hereinafter sometimes to be abbreviated as “compound (2-1)”), 3,9-bis[2-{3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane (hereinafter sometimes to be abbreviated as “compound (2-2)”) and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate] (hereinafter sometimes to be abbreviated as “compound (2-3)”). Compound (2-1) is commercially available as “Irganox (registered trade mark) 1076” (manufactured by BASF), compound (2-2) is commercially available as “Sumilizer (registered trade mark) GA-80” (manufactured by Sumitomo Chemical Company, Limited), and compound (2-3) is commercially available as “Irganox (registered trade mark) 1010” (manufactured by BASF).

As compound (2), a commercially available product can be used, or it can be produced according to a known method (e.g., the method described in U.S. Pat. No. 3,330,859, U.S. Pat. No. 3,644,482 or JP-A-59-25826).

The first processing stabilizer may further contain at least one selected from the group consisting of compounds (3)-(7). Only one kind of compounds (3)-(7) may be used or two or more kinds thereof may be used in combination. In the following, compounds (3)-(7) are explained successively.

Each R⁷ and/or each R⁸ in the formula (3) are/is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-6 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. While there are three R⁷, they may be the same as or different from each other, and they are preferably the same. The same applies to R⁸. The positions of R⁷ and R⁸ are preferably the 2-position and the 4-position.

The C_1-9 alkyl group may be a linear or branched chain. The carbon number of the C_1-9 alkyl group is preferably not less than 3 and not more than 5. Examples of the C_1-9 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, a t-butyl group, a pentyl group, a t-pentyl group, a 2-ethylhexyl group, a nonyl group and the like.

The C_5-8 cycloalkyl group includes a cyclopentyl group, a cyclohexyl group, a cycloheptyl group and a cyclooctyl group.

Examples of the C_6-12 alkylcycloalkyl group include a 1-methylcyclopentyl group, a 2-methylcyclopentyl group, a 1-methylcyclohexyl group, a 2-methylcyclohexyl group, a 1-methyl-4-isopropylcyclohexyl group and the like.

Examples of the C_7-12 aralkyl group include a benzyl group, an α-methylbenzyl group (also to be referred to as a 1-phenylethyl group), an α,α-dimethylbenzyl group (also to be referred to as a 1-methyl-1-phenylethyl group or a cumyl group) and the like.

Preferably, each R⁷ and/or each R⁸ are/is independently a hydrogen atom or a C_1-9 alkyl group, more preferably a hydrogen atom, a t-butyl group or a nonyl group, still more preferably a t-butyl group.

Examples of compound (3) include tris(2,4-di-t-butylphenyl)phosphite (hereinafter sometimes to be abbreviated as “compound (3-1)”), triphenyl phosphite, tris(4-nonylphenyl)phosphite, tris(2,4-dinonylphenyl)phosphite and the like. Of these, compound (3-1) is preferable. Compound (3-1) is commercially available as “Irgafos (registered trade mark) 168” (manufactured by BASF).

Each R⁹ in the formula (4) is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_8-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. While there are four R⁹, they may be the same as or different from each other, and they are preferably the same. Examples of the C_1-9 alkyl group, C_5-8 cycloalkyl group, C_8-12 alkylcycloalkyl group and C_7-12 aralkyl group for R⁹ include those mentioned above. Each R⁹ is preferably independently a hydrogen atom or a C_1-9 alkyl group, more preferably a hydrogen atom.

Examples of compound (4) include tetrakis(2,4-di-t-butylphenyl)-4,4-biphenylene diphoshonite (hereinafter sometimes to be abbreviated as “compound (4-1)”), tetrakis(2,4-di-t-butyl-5-methylphenyl)-4,4-biphenylene diphoshonite (hereinafter sometimes to be abbreviated as “compound (4-2)”) and the like. Of these, compound (4-1) is preferable. Compound (4-1) is commercially available as “Sandostab (registered trade mark) P-EPQ” (manufactured by Clariant), and compound (4-2) is commercially available as “Yoshinox (registered trade mark) GSY-P101” (manufactured by API).

Each R¹⁰ in the formula (5) is independently a C_1-18 alkyl group or a phenyl group. The phenyl group for R¹⁰ may have, as a substituent, at least one selected from the group consisting of a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group and a C_7-12 aralkyl group. Examples of these substituents for phenyl group include those mentioned above. In addition, while there are two R¹⁰, they may be the same as or different from each other, and they are preferably the same.

The C_1-18 alkyl group may be a linear or branched chain. The carbon number of the C_1-18 alkyl group is preferably not less than 12 and not more than 18. Examples of the C_1-18 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a t-butyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, a tetradecyl group, a hexadecyl group, an octadecyl group and the like.

Examples of the phenyl group substituted by a C_1-9 alkyl group include a 2-methylphenyl group, a 4-methylphenyl group, a 2-t-butylphenyl group, a 4-t-butylphenyl group, a 2-nonylphenyl group, a 4-nonylphenyl group, a 2,4-di-t-butylphenyl group, a 2,4-di-nonylphenyl group, a 2,6-di-t-butylphenyl group, a 2-t-butyl-4-methylphenyl group, a 2-t-butyl-4-ethylphenyl group, a 2,5-di-t-butylphenyl group, a 2,6-di-t-butyl-4-methylphenyl group and the like.

Examples of the phenyl group substituted by a C_6-6 cycloalkyl group include a 2-cyclopentylphenyl group, a 2-cyclohexylphenyl group, a 4-cyclohexylphenyl group, a 2,4-dicyclohexylphenyl group and the like.

Examples of the phenyl group substituted by a C_6-12 alkylcycloalkyl group include a 2-(2-methylcyclohexyl)phenyl group, a 4-(2-methylcyclohexyl)phenyl group, a 2,4-di-(2-methylcyclohexyl)phenyl group and the like.

Examples of the phenyl group substituted by a C_7-12 aralkyl group include a 2-benzylphenyl group, a 2-cumylphenyl group, a 4-cumylphenyl group, a 2,4-dicumylphenyl group and the like.

Examples of the phenyl group substituted by a C_1-9 alkyl group and a C_5-8 cycloalkyl group include a 2-methyl-4-cyclohexylphenyl group and the like. Examples of the phenyl group substituted by a C_1-9 alkyl group and a C_6-12 alkylcycloalkyl group include a 2-methyl-4-(2-methylcyclohexyl)phenyl group and the like. Examples of the phenyl group substituted by a C_1-9 alkyl group and a C_7-12 aralkyl group include a 2-benzyl-4-methylphenyl group and the like.

Each R¹⁰ is preferably independently an octadecyl group (also to be referred to as a stearyl group), a 2,6-di-t-butyl-4-methylphenyl group, a 2,4-di-t-butylphenyl group or a 2,4-dicumylphenyl group.

Examples of compound (5) include bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite (hereinafter sometimes to be abbreviated as “compound (5-1)”), bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite (hereinafter sometimes to be abbreviated as “compound (5-2)”), bis(2,4-dicumylphenyl)pentaerythritol diphosphite (hereinafter sometimes to be abbreviated as “compound (5-3)”), distearylpentaerythritol diphosphite (hereinafter sometimes to be abbreviated as “compound (5-4)”), diisodecylpentaerythritol diphosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, bis(2,4-di-t-butyl-6-methylphenyl)pentaerythritol diphosphite, bis(2,4,6-tri-t-butylphenyl)pentaerythritol diphosphite and the like. Of these, compound (5-1), compound (5-2) and compound (5-3) are preferable. Compound (5-1) is commercially available as “Adekastab (registered trade mark) PEP-36” (manufactured by ADEKA), compound (5-2) is commercially available as “Ultranox (registered trade mark) 626” (manufactured by GE Plastics), compound (5-3) is commercially available as “Doverphos S9228T” (manufactured by Dover Chemical Corporation), and compound (5-4) is commercially available as “Adekastab (registered trade mark) PEP-8” (manufactured by ADEKA).

Each R¹¹ and/or each R¹² in the formula (6) are/is independently a hydrogen atom, a C_1-9 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. Examples of the C_1-9 alkyl group, C_5-8 cycloalkyl group, C_6-12 alkylcycloalkyl group and C_7-12 aralkyl group for R¹¹ or R¹² include those mentioned above. While there are six R¹¹, they may be the same as or different from each other, and they are preferably the same. The same applies to R¹². The positions of R¹¹ and R¹² are preferably the 3-position and the 5-position, when the position of the carbon atom on the benzene ring to which L² is bonded is the 1-position. Preferably, each R¹¹ and/or each R¹² are/is independently a C_1-9 alkyl group, more preferably a t-butyl group.

Each L² in the formula (6) is independently a single bond, a sulfur atom or a divalent group represented by the formula (6a). The total carbon number of R¹³ and R¹⁴ in the formula (6a) is not more than 7, and R¹³ and R¹⁴ are each independently a hydrogen atom or a C_1-7 alkyl group. While there are three L², they may be the same as or different from each other, and they are preferably the same.

The C_1-7 alkyl group may be a linear or branched chain. The carbon number of the C_1-7 alkyl group is preferably not less than 1 and not more than 3. The total carbon number of R¹³ and R¹⁴ is preferably not more than 3. Examples of the C_1-7 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, a t-butyl group, a pentyl group, an isopentyl group, a neopentyl group, a t-pentyl group, a hexyl group, a heptyl group and the like.

Examples of the divalent group (6a) include —CH₂—, —CH(CH₃)—, —CH(C₂H₅)—, —C(CH₃)₂—, —CH(n-C₃H₇)— and the like.

Each L² is preferably —CH₂— or a single bond, more preferably a single bond.

Each L³ in the formula (6) is independently a C_2-8 alkylene group. While there are three L³, they may be the same as or different from each other, and they are preferably the same.

Examples of the C_2-8 alkylene group include an ethylene group, a propylene group (—CH(CH₃) CH₂—, —CH₂CH(CH₃)—), a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, an octamethylene group, a 2,2-dimethyl-1,3-propylene group and the like.

Each L³ is preferably independently an ethylene group or a trimethylene group, more preferably an ethylene group.

As compound (6), 6,6′,6″-[nitrilotris(ethyleneoxy)]tris(2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine) (hereinafter sometimes to be abbreviated as “compound (6-1)”) is preferable. Compound (6-1) is commercially available as “Irgafos (registered trade mark) 12” (manufactured by BASF).

Each R¹⁵ and/or each R¹⁶ in the formula (7) are/is independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. Examples of the alkyl group, C_5-8 cycloalkyl group, C_6-12 alkylcycloalkyl group and C_7-12 aralkyl group for R¹⁵ or R¹⁶ include those mentioned above. While there are two R¹⁵, they may be the same as or different from each other, and they are preferably the same. The same applies to R¹⁶. The positions of R¹⁵ and R¹⁶ are preferably the 3-position and the 5-position, when the position of the carbon atom on the benzene ring to which L⁴ is bonded is the 1-position. That is, when the position of the carbon atom on the benzene ring to which O is bonded is the 1-position, respectively, the 2-position and the 4-position are preferable. Preferably, each R¹⁵ and/or each R¹⁶ are/is independently a C_1-9 alkyl group, more preferably a t-butyl group.

R¹⁷ in the formula (7) is a C_1-8 alkyl group or a phenyl group. The phenyl group for R¹⁷ may have, as a substituent, at least one selected from the group consisting of a alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group and a C_7-12 aralkyl group. Examples of the alkyl group and the phenyl group having a substituent for R¹⁷ include those mentioned above. The carbon number of the C_1-8 alkyl group for R¹⁷ is preferably not less than 4 and not more than 8. R¹⁷ is preferably a C_1-6 alkyl group, more preferably an octyl group.

L⁴ in the formula (7) is a single bond, a sulfur atom or is a divalent group represented by the formula (7a). The total carbon number of R¹⁶ and R¹⁹ in the formula (7a) is not more than 7, and R¹⁸ and R¹⁹ are each independently a hydrogen atom or a C_1-7 alkyl group. Examples of the C_1-7 alkyl group for R¹⁸ or R¹⁹ include those mentioned above. The total carbon number for R¹⁸ or R¹⁹ is preferably not more than 3. Specific examples of the divalent group (7a) include those recited for the divalent group (6a). L⁴ is preferably —CH₂— or a single bond, more preferably —CH₂—.

Examples of compound (7) include 2,2-methylenebis(4,6-di-t-butylphenyl)octyl phosphite (hereinafter sometimes to be abbreviated as “compound (7-1)”) and 2,2′-methylenebis(4,6-di-t-butylphenyl) 2-ethylhexyl phosphite. Of these, compound (7-1) is preferable. Compound (7-1) is commercially available as “Adekastab (registered trade mark) HP-10” (manufactured by ADEKA).

Among compounds (3)-(7), compound (3) is preferable, and compound (3-1) is more preferable.

When the first processing stabilizer contains at least one of compound (2)-compound (7), the content of each of compound (2)-compound (7) is preferably not less than 0.1 part by weight (more preferably not less than 10 parts by weight, still more preferably not less than 20 parts by weight), preferably not more than 200 parts by weight (more preferably not more than 90 parts by weight, still more preferably not more than 80 parts by weight), relative to 100 parts by weight of the total of compound (1) and compound (9).

Next, the second processing stabilizer is explained. The second processing stabilizer contains compound (8) as one of the characteristics. Only one kind of compound (8) may be used or two or more kinds thereof may be used in combination. In the following, compound (8) is explained successively.

Each R²⁰ and/or each R²¹ in the formula (8) are/is independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. R²³ and R²⁴ in the formula (8) are each independently a hydrogen atom, a C_1-8 alkyl group, a C_5-8 cycloalkyl group, a C_6-12 alkylcycloalkyl group, a C_7-12 aralkyl group or a phenyl group. While there are two R²⁰, they may be the same as or different from each other, and they are preferably the same. The same applies to R²¹.

The C_1-8 alkyl group may be a linear or branched chain. The carbon number of the C_1-8 alkyl group is preferably not less than 1 and not more than 5. Examples of the C_1-8 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, a t-butyl group, a t-pentyl group, an isooctyl group (also to be referred to as a 6-methylheptyl group), a t-octyl group (also to be referred to as a 1,1,3,3-tetramethylbutyl group), a 2-ethylhexyl group and the like.

The C_5-8 cycloalkyl group includes a cyclopentyl group, a cyclohexyl group, a cycloheptyl group and a cyclooctyl group.

Examples of the C_6-12 alkylcycloalkyl group include a 1-methylcyclopentyl group, a 2-methylcyclopentyl group, a 1-methylcyclohexyl group, a 2-methylcyclohexyl group, a 1-methyl-4-isopropylcyclohexyl group and the like.

Examples of the C_7-12 aralkyl group include a benzyl group, α-methylbenzyl group (also to be referred to as a 1-phenylethyl group), an α,α-dimethylbenzyl group (also to be referred to as a 1-methyl-1-phenylethyl group or a cumyl group) and the like.

Preferably, each R²⁰ and/or R²³ are/is independently a C_1-8 alkyl group (more preferably a C_4-8 alkyl group having a tertiary carbon atom), a C_5-8 cycloalkyl group (more preferably a cyclohexyl group) or a C_8-12 alkylcycloalkyl group (more preferably a 1-methylcyclohexyl group). As the C_4-8 alkyl group having a tertiary carbon atom, a t-butyl group, a t-pentyl group and a t-octyl group are still more preferable.

Each R²¹ is preferably independently a alkyl group, a C_5-8 cycloalkyl group or a C_6-12 alkylcycloalkyl group, more preferably a C_1-5 alkyl group. The C_1-5 alkyl group may be a linear or branched chain. Examples of the C_1-5 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, a t-butyl group, a t-pentyl group and the like. More preferably, each R²¹ is independently a methyl group, a t-butyl group or a t-pentyl group.

R²⁴ is preferably a hydrogen atom or a C_1-5 alkyl group, more preferably a hydrogen atom or a methyl group. Examples of the C_1-5 alkyl group for R²⁴ include those mentioned above.

Each R²² in the formula (8) is independently a hydrogen atom or a alkyl group. While there are two R²², they may be the same as or different from each other, and they are preferably the same. Each R²² is preferably a hydrogen atom or a C_1-5 alkyl group, more preferably a methyl group or a hydrogen atom. Examples of the C_1-8 alkyl group and C_1-5 alkyl group for R²² include those mentioned above.

L⁵ in the formula (8) is a single bond, a sulfur atom or a divalent group represented by the formula (8a). R²⁵ in the formula (8a) is a hydrogen atom, a C_1-8 alkyl group or a C_5-8 cycloalkyl group. R²⁵ is preferably a hydrogen atom or a C_1-5 alkyl group. Examples of the C_1-8 alkyl group, C_1-5 alkyl group and C_5-8 cycloalkyl group for R²⁵ include those mentioned above. L⁵ is preferably a single bond or the divalent group (8a), more preferably a single bond.

L⁶ in the formula (8) is a C_2-8 alkylene group or a divalent group represented by the formula (8b). L⁷ in the formula (8b) is a single bond or a C_1-8 alkylene group. The C_2-8 alkylene group and C_1-8 alkylene group may be each a linear or branched chain. Examples of the C_2-8 alkylene group include an ethylene group, a propylene group (—CH(CH₃)CH₂—, —CH₂CH(CH₃)—), a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, an octamethylene group, a 2,2-dimethyl-1,3-propylene group and the like. Examples of the C_1-8 alkylene group include a methylene group, the aforementioned C_2-8 alkylene group and the like.

L⁶ is preferably a C_2-8 alkylene group, the divalent group (8b) wherein L⁷ is a single bond (i.e., a carbonyl group), or the divalent group (8b) wherein L⁷ is an ethylene group; more preferably a C_2-8 alkylene group; and still more preferably a trimethylene group.

One of Z¹ and Z² in the formula (8) is a hydroxy group, a C_1-8 alkyl group, a C_1-8alkoxy group or a C_7-12 aralkyloxy group, and the other is a hydrogen atom or a C_1-8 alkyl group. Examples of the C_1-8 alkyl group for Z¹ and Z² include those mentioned above.

The C_1-8 alkoxy group may be a linear or branched chain. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, an isobutoxy group, a sec-butoxy group, a t-butoxy group, a t-pentyloxy group, an isooctyloxy group (also to be referred to as a 6-methylheptyloxy group), a t-octyloxy group (also to be referred to as a 1,1,3,3-tetramethylbutyloxy group), a 2-ethylhexyloxy group and the like.

Examples of the C_7-12 aralkyloxy group include a benzyloxy group, an α-methylbenzyloxy group, an α,α-dimethylbenzyloxy group and the like.

Preferably, one of Z¹ and Z² is a hydroxy group, and the other is a hydrogen atom.

A preferable combination of the substituents is a combination wherein each R²⁰ and/or R²³ are/is independently a C_4-8 alkyl group having a tertiary carbon atom, cyclohexyl or a 1-methylcyclohexyl group, each R²¹ is independently a C_1-5 alkyl group, each R²² is independently a hydrogen atom or a alkyl group, R²⁴ is a hydrogen atom or a C_1-5 alkyl group, L⁵ is a single bond, L⁶ is a C_2-8 alkylene group, and one of Z¹ and Z² is a hydroxy group and the other is a hydrogen atom. In this preferable combination, each R²⁰ is more preferably the same. The same applies to each R²¹ and each R²². In addition, in this preferable combination, each R²⁰, each R²² and R²³ are all still more preferably t-butyl groups or t-pentyl groups (particularly t-butyl groups).

Examples of compound (8) include 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine, 2,10-dimethyl-4,8-di-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propoxy]-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propoxy]dibenzo[d,f][1,3,2]dioxaphosphepine, 2,4,8,10-tetra-t-pentyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propoxy]-12-methyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,10-dimethyl-4,8-di-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-pentyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-12-methyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-dibenzo[d,f][1,3,2]dioxaphosphepine, 2,10-dimethyl-4,8-di-t-butyl-6-(3,5-di-t-butyl-4-hydroxybenzoyloxy)-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-butyl-6-(3,5-di-t-butyl-4-hydroxybenzoyloxy)-12-methyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,10-dimethyl-4,8-di-t-butyl-6-[3-(3-methyl-4-hydroxy-5-t-butylphenyl)propoxy]-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propoxy]-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,10-diethyl-4,8-di-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propoxy]-12H-dibenzo[d,g][1,3,2]dioxaphosphocin, 2,4,8,10-tetra-t-butyl-6-[2,2-dimethyl-3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-dibenzo[d,f][1,3,2]dioxaphosphepine and the like.

Of compound (8), 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine (hereinafter sometimes to be abbreviated as “compound (8-1)”) is preferable. Compound (8-1) is commercially available as “Sumilizer (registered trade mark) GP” (manufactured by Sumitomo Chemical Company, Limited).

As compound (8), a commercially available product can be used, or it can be produced according to a known method (e.g., the method described in JP-A-10-273494).

The second processing stabilizer contains compound (9) as one of the characteristics. Explanations of compound (9) are the same as those mentioned above.

The content of compound (9) in the second processing stabilizer is preferably not less than 0.1 wt % (more preferably not less than 1 wt %, still more preferably not less than 2 wt %, particularly preferably not less than 5 wt %), preferably not more than 95 wt % (more preferably not more than 90 wt %, still more preferably not more than 75 wt %, particularly preferably not more than 50 wt %), of the total of compound (8) and compound (9).

The second processing stabilizer may consist of compound (8) and compound (9), or may contain other component. For example, the second processing stabilizer may further contain compound (2). Only one kind of compound (2) may be used or two or more kinds thereof may be used in combination. Explanations of compound (2) are the same as those mentioned above.

The second processing stabilizer may further contain at least one selected from the group consisting of compounds (3)-(7). Only one kind of compounds (3)-(7) may be used or two or more kinds thereof may be used in combination. Explanations of compounds (3)-(7) are the same as those mentioned above.

When the second processing stabilizer contains at least one of compound (2)-compound (7), the content of each of compound (2)-compound (7) is preferably not less than 0.1 part by weight (more preferably not less than 10 parts by weight, still more preferably not less than 20 parts by weight), preferably not more than 200 parts by weight (more preferably not more than 90 parts by weight, still more preferably not more than 80 parts by weight), relative to 100 parts by weight of the total of compound (8) and compound (9).

Next, the third processing stabilizer is explained. The third processing stabilizer contains compound (2) as one of the characteristics. Only one kind of compound (2) may be used or two or more kinds thereof may be used in combination. Explanations of compound (2) are the same as those mentioned above.

The third processing stabilizer contains compound (9) as one of the characteristics. Explanations of compound (9) are the same as those mentioned above.

The content of compound (9) in the third processing stabilizer is preferably not less Than 0.1 wt % (more preferably not less than 1 wt %, still more preferably not less than 2 wt %, particularly preferably not less than 5 wt %), preferably not more than 95 wt % (more preferably not more than 90 wt %, still more preferably not more than 75 wt %, particularly preferably not more than 50 wt %), of the total of compound (2) and compound (9).

The third processing stabilizer may consist of compound (2) and compound (9), or may contain other component. For example, the third processing stabilizer may contain compound (1). Only one kind of compound (1) may be used or two or more kinds thereof may be used in combination. Explanations of compound (1) are the same as those mentioned above.

The third processing stabilizer may further contain at least one selected from the group consisting of compounds (3)-(7). Only one kind of compounds (3)-(7) may be used or two or more kinds thereof may be used in combination. Explanations of compounds (3)-(7) are the same as those mentioned above.

The third processing stabilizer may further contain compound (8). Only one kind of compound (8) may be used or two or more kinds thereof may be used in combination. Explanations of compound (8) are the same as those mentioned above.

Of compound (1) and compounds (3)-(8) usable for the third processing stabilizer, compound (1), compound (3) and compound (8) are preferable, compound (1) and compound (8) are more preferable, and compound (1) is still more preferable.

When the third processing stabilizer contains at least one of compound (1), compound (3)-compound (8), the content of each of compound (1), compound (3)-compound (8) is preferably not less than 0.1 part by weight (more preferably not less than 10 parts by weight, still more preferably not less than 20 parts by weight), preferably not more than 200 parts by weight (more preferably not more than 90 parts by weight, still more preferably not more than 80 parts by weight), relative to 100 parts by weight of the total of compound (2) and compound (9).

Next, the fourth processing stabilizer is explained. The fourth processing stabilizer contains at least one selected from the group consisting of compounds (3)-(7) (i.e., organic phosphorous compound) as one of the characteristics. Only one kind of compounds (3)-(7) may be used or two or more kinds thereof may be used in combination. Explanations of compounds (3)-(7) are the same as those mentioned above.

The fourth processing stabilizer contains compound (9) as one of the characteristics. Explanations of compound (9) are the same as those mentioned above.

The weight ratio of the compound selected from the group consisting of compounds (3)-(7) and compound (9) in the fourth processing stabilizer (i.e., compound selected from the group consisting of compounds (3)-(7):compound (9)) is preferably 1000:1-0.05:1. The compound selected from the group consisting of compounds (3)-(7):compound (9) is more preferably 1000:1-0.1:1 from the aspect of processing stability of a thermoplastic polymer composition, and still is more preferably 1000:1-0.5:1, particularly preferably 1000:1-1:1, from the aspect of suppression of color change of a thermoplastic polymer composition.

The fourth processing stabilizer may consist of compound (9) and at least one selected from the group consisting of compounds represented by the formulas (3)-(7), or may contain other component. Here, “the fourth processing stabilizer consist of compound (9) and at least one selected from the group consisting of the compounds represented by the formulas (3)-(7)” means “the total amount of compound (9) and the compound selected from the group consisting of compound (3)-compound (7) is not less than 99 wt % of the fourth processing stabilizer”.

The fourth processing stabilizer may further contain at least one selected from the group consisting of compound (1), compound (2) and compound (8). Only one kind of each of compound (1), compound (2) and compound (8) may be used or two or more kinds thereof may be used in combination. Explanations of compound (1), compound (2) and compound (8) are the same as those mentioned above.

The content of each of compound (1), compound (2) and compound (8), which can be used in combination in the fourth processing stabilizer is preferably 0-90 wt %, more preferably 0.1-80 wt %, of the fourth processing stabilizer.

The processing stabilizer of the present invention (i.e., the first-fourth processing stabilizers) may contain additives other than the above-mentioned components (hereinafter to be abbreviated as “other additives”). Only one kind of other additives may be used or two or more kinds thereof may be used in combination. Examples of other additive include antioxidant, UV absorber, light stabilizer, stabilizer, lubricant, metal deactivator, nucleating agent, antistatic agent, flame-retardant, filler, pigment, inorganic filler and the like.

Examples of the antioxidant include phenol antioxidant (excluding compound (1) and compound (2)), sulfur antioxidant, phosphorus antioxidant (excluding compounds (3)-(8)), hydroquinone antioxidant and the like.

Examples of the phenol antioxidant include those described in the following [1]-[16] and the like.

[1] alkylated monophenol such as 2,6-di-t-butyl-4-methylphenol, 2,4,6-tri-t-butylphenol, 2,6-di-t-butylphenol, 2-t-butyl-4,6-dimethylphenol, 2,6-di-t-butyl-4-ethylphenol, 2,6-di-t-butyl-4-n-butylphenol, 2,6-di-t-butyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2-(α-methylcyclohexyl)-4,6-dimethylphenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-t-butyl-4-methoxymethylphenol, 2,6-di-nonyl-4-methylphenol, 2,4-dimethyl-6-(1′-methylundecyl-1′-yl)phenol, 2,4-dimethyl-6-(1′-methylheptadecyl-1′-yl)phenol, 2,4-dimethyl-6-(1′-methyltridecyl-1′-yl)phenol and the like.[2] alkylthiomethylphenol such as 2,4-bis(octylthiomethyl)-6-t-butylphenol, 2,4-bis(octylthiomethyl)-6-methylphenol, 2,4-bis(octylthiomethyl)-6-ethylphenol, 2,6-bis(dodecylthiomethyl)-4-nonylphenol and the like.[3] alkylidene bisphenol and derivatives thereof such as 2,2′-methylenebis(4-methyl-6-t-butylphenol), 2,2′-methylenebis(4-ethyl-6-t-butylphenol), 2,2′-methylenebis[4-methyl-6-(α-methylcyclohexyl)phenol], 2,2′-methylenebis(4-methyl-6-cyclohexylphenol), 2,2′-methylenebis(4-methyl-6-nonylphenol), 2,2′-methylenebis(4,6-di-t-butylphenol), 2,2′-ethylidenebis(4,6-di-t-butylphenol), 2,2′-ethylidenebis(4-isobutyl-6-t-butylphenol), 2,2′-methylenebis[6-(α-methylbenzyl)-4-nonylphenol], 2,2′-methylenebis[6-(α,α-dimethylbenzyl)-4-nonylphenol], 4,4′-methylenebis(6-t-butyl-2-methylphenol), 4,4′-methylenebis(2,6-di-t-butylphenol), 4,4′-butylidenebis(3-methyl-6-t-butylphenol), 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(5-t-butyl-4-hydroxy-2-methylphenyl)butane, 2,6-bis(3-t-butyl-5-methyl-2-hydroxybenzyl)-4-methylphenol, 1,1,3-tris(5-t-butyl-4-hydroxy-2-methylphenyl)butane, 1,1-bis(5-t-butyl-4-hydroxy-2-methylphenyl)-3-n-dodecylmercaptobutane, ethylene glycol bis[3,3-bis(3′-t-butyl-4′-hydroxyphenyl)butyrate], bis(3-t-butyl-4-hydroxy-5-methylphenyl)dicyclopentadiene, bis[2-(3′-t-butyl-2′-hydroxy-5′-methylbenzyl)-6-t-butyl-4-methylphenyl]terephthalate, 1,1-bis(3,5-dimethyl-2-hydroxyphenyl)butane, 2,2-bis(3,5-di-t-butyl-4-hydroxyphenyl)propane, 2,2-bis(5-t-butyl-4-hydroxy-2-methylphenyl)-4-n-dodecylmercaptobutane, 1,1,5,5-tetra(5-t-butyl-4-hydroxy-2-methylphenyl)pentane and the like.[4] acylaminophenol derivative such as 4-hydroxylauryl anilide, 4-hydroxystearic anilide, octyl-N-(3,5-di-t-butyl-4-hydroxyphenyl)carbamate and the like.[5] ester of β-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid and a monovalent or polyvalent alcohol (e.g., methanol, ethanol, octanol, octadecanol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, neopentylglycol, diethylene glycol, thioethylene glycol, spiroglycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2,2,2]octane or a mixture thereof and the like).[6] bis(hydroxyphenyl)sulfide such as 2,2′-thiobis(6-t-butylphenol), 2,2′-thiobis(4-methyl-6-t-butylphenol), 2,2′-thiobis(4-octylphenol), 4,4′-thiobis(2-methyl-6-t-butylphenol), 4,4′-bis(2,6-dimethyl-4-hydroxyphenyl)sulfide and the like.[7] 0-benzyl derivative, N-benzyl derivative and S-benzyl derivative such as 3,5,3′,5′-tetra-t-butyl-4,4′-dihydroxydibenzyl ether, octadecyl 4-hydroxy-3,5-dimethylbenzylmercaptoacetate, tris(3,5-di-t-butyl-4-hydroxybenzyl)amine, bis(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)dithioterephthalate, bis(3,5-di-t-butyl-4-hydroxybenzyl)sulfide, isooctyl 3,5-di-t-butyl-4-hydroxybenzylmercaptoacetate and the like.[8] triazine derivative such as 2,4-bis(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-triazine, 2-n-octylthio-4,6-bis(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-triazine, 2-n-octylthio-4,6-bis(4-hydroxy-3,5-di-t-butylphenoxy)-1,3,5-triazine, 2,4,6-tris(3,5-di-t-butyl-4-phenoxy)-1,3,5-triazine, tris(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, 2,4,6-tris(3,5-di-t-butyl-4-hydroxyphenylethyl)-1,3,5-triazine, 2,4,6-tris(3,5-di-t-butyl-4-hydroxyphenylpropyl)-1,3,5-triazine, tris(3,5-dicyclohexyl-4-hydroxybenzyl)isocyanurate, tris[2-(3′,5′-di-t-butyl-4′-hydroxycinnamoyloxy)ethyl]isocyanurate and the like.[9] hydroxybenzylated malonate derivative such as dioctadecyl 2,2-bis(3,5-di-t-butyl-2-hydroxybenzyl)malonate, dioctadecyl 2-(3-t-butyl-4-hydroxy-5-methylbenzyl)malonate, didodecylmercaptoethyl 2,2-bis(3,5-di-t-butyl-4-hydroxybenzyl)malonate, bis[4-(1,1,3,3-tetramethylbutyl)phenyl] 2,2-bis(3,5-di-t-butyl-4-hydroxybenzyl)malonate and the like.[10] aromatic hydroxybenzyl derivative such as 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, 1,4-bis(3,5-di-t-butyl-4-hydroxybenzyl)-2,3,5,6-tetramethylbenzene, 2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)phenol and the like.[11] benzylphosphonate derivative such as dimethyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, diethyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, dioctadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, dioctadecyl 5-t-butyl-4-hydroxy-3-methylbenzylphosphonate, calcium salt of 3,5-di-t-butyl-4-hydroxybenzylphosphonic acid monoester and the like.[12] ester of β-(5-t-butyl-4-hydroxy-3-methylphenyl)propionic acid and a monovalent or polyvalent alcohol (e.g., methanol, ethanol, octanol, octadecanol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, neopentylglycol, diethylene glycol, thioethylene glycol, spiroglycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2,2,2]octane or a mixture thereof and the like).[13] ester of β-(3,5-dicyclohexyl-4-hydroxyphenyl)propionic acid and a monovalent or polyvalent alcohol (e.g., methanol, ethanol, octanol, octadecanol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, neopentylglycol, diethylene glycol, thioethylene glycol, spiroglycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2,2,2]octane or a mixture thereof and the like).[14] ester of 3,5-di-t-butyl-4-hydroxyphenylacetic acid and a monovalent or polyvalent alcohol (e.g., methanol, ethanol, octanol, octadecanol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, neopentylglycol, diethylene glycol, thioethylene glycol, spiroglycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2,2,2]octane or a mixture thereof).[15] amide of β-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid such as N,N′-bis[3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionyl]hydrazine, N,N′-bis[3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionyl]hexamethylenediamine, N,N′-bis[3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionyl]trimethylenediamine and the like.[16] tocopherols such as α-tocopherol, β-tocopherol, γ-tocopherol, δ-tocopherol and the like.

Examples of the sulfur antioxidant include dilauryl 3,3′-thiodipropionate, tridecyl 3,3′-thiodipropionate, dimyristyl 3,3′-thiodipropionate, distearyl 3,3′-thiodipropionate, lauryl stearyl 3,3′-thiodipropionate, neopentanetetrakis(3-lauryl thiopropionate) and the like.

Examples of the phosphorus antioxidant include trilauryl phosphite, trioctadecyl phosphite, tristearylsorbitol triphosphite, 2,2′-ethylidenebis(4,6-di-t-butylphenyl)fluorophosphite, bis(2,4-di-t-butyl-6-methylphenyl)ethyl phosphite, bis(2,4-di-t-butyl-6-methylphenyl)methyl phosphite, 2-(2,4,6-tri-t-butylphenyl)-5-ethyl-5-butyl-1,3,2-oxaphosphorinan and the like.

Examples of the hydroquinone antioxidant include 2,6-di-t-butyl-4-methoxyphenol, 2,5-di-t-butylhydroquinone, 2,5-di-t-pentylhydroquinone, 2,6-diphenyl-4-octadecyloxyphenol, 2,6-di-t-butylhydroquinone, 2,5-di-t-butyl-4-hydroxyanisole, 3,5-di-t-butyl-4-hydroxyphenyl stearate, bis(3,5-di-t-butyl-4-hydroxyphenyl)adipate and the like.

Examples of the UV absorber include those described in the following [1]-[3] and the like.

[1] salicylate derivative such as phenyl salicylate, 4-t-butylphenyl salicylate, 2,4-di-t-butylphenyl 3′,5′-di-t-butyl-4′-hydroxybenzoate, 4-t-octylphenyl salicylate, bis(4-t-butylbenzoyl)resorcinol, benzoylresorcinol, hexadecyl 3′,5′-di-t-butyl-4′-hydroxybenzoate, octadecyl 3′,5′-di-t-butyl-4′-hydroxybenzoate, 2-methyl-4,6-di-t-butylphenyl 3′,5′-di-t-butyl-4′-hydroxybenzoate and the like.[2] 2-hydroxybenzophenone derivative such as 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, bis(5-benzoyl-4-hydroxy-2-methoxyphenyl)methane, 2,2′,4,4′-tetrahydroxybenzophenone and the like.[3] 2-(2′-hydroxyphenyl)benzotriazoles such as 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(3′,5′-di-t-butyl-2′-hydroxyphenyl)benzotriazole, 2-(5′-t-butyl-2′-hydroxyphenyl)benzotriazole, 2-(2′-hydroxy-5′-t-octylphenyl)benzotriazole, 2-(3-t-butyl-2-hydroxy-5-methylphenyl)-5-chlorobenzotriazole, 2-(3′-sec-butyl-2′-hydroxy-5′-t-butylphenyl)benzotriazole, 2-(2′-hydroxy-4′-octyloxyphenyl)benzotriazole, 2-(3′,5′-di-t-pentyl-2′-hydroxyphenyl)benzotriazole, 2-[2′-hydroxy-3′,5′-bis(α,α-dimethylbenzyl)phenyl]-2H-benzotriazole, 2-[(3′-t-butyl-2′-hydroxyphenyl)-5′-(2-octyloxycarbonylethyl)phenyl]-5-chlorobenzotriazole, 2-[3′-t-butyl-5′-[2-(2-ethylhexyloxy)carbonylethyl]-2′-hydroxyphenyl]-5-chlorobenzotriazole, 2-[3′-t-butyl-2′-hydroxy-5′-(2-methoxycarbonylethyl)phenyl]-5-chlorobenzotriazole, 2-[3′-t-butyl-2′-hydroxy-5′-(2-methoxycarbonylethyl)phenyl]benzotriazole, 2-[3′-t-butyl-2′-hydroxy-5-(2-octyloxycarbonylethyl)phenyl]benzotriazole, 2-[3′-t-butyl-2′-hydroxy-5′-[2-(2-ethylhexyloxy)carbonylethyl]phenyl]benzotriazole, 2-[2-hydroxy-3-(3,4,5,6-tetrahydrophthalimidomethyl)-5-methylphenyl]benzotriazole, 2-(3,5-di-t-butyl-2-hydroxyphenyl)-5-chlorobenzotriazole, mixture of 2-(3′-dodecyl-2′-hydroxy-5′-methylphenyl)benzotriazole and 2-[3′-t-butyl-2′-hydroxy-5′-(2-isooctyloxycarbonylethyl)phenyl]benzotriazole, 2,2′-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], 2,2′-methylenebis[4-t-butyl-6-(2H-benzotriazol-2-yl)phenol], condensate of poly(3-11)(ethylene glycol) and 2-[3′-t-butyl-2′-hydroxy-5′-(2-methoxycarbonylethyl)phenyl]benzotriazole, condensate of poly(3-11)(ethylene glycol) and methyl 3-[3-(2H-benzotriazol-2-yl)-5-t-butyl-4-hydroxyphenyl]propionate, 2-ethylhexyl 3-[3-t-butyl-5-(5-chloro-2H-benzotriazol-2-yl)-4-hydroxyphenyl]propionate, octyl 3-[3-t-butyl-5-(5-chloro-2H-benzotriazol-2-yl)-4-hydroxyphenyl]propionate, methyl 3-[3-t-butyl-5-(5-chloro-2H-benzotriazol-2-yl)-4-hydroxyphenyl]propionate, 3-[3-t-butyl-5-(5-chloro-2H-benzotriazol-2-yl)-4-hydroxyphenyl]propionic acid and the like.

Examples of the light stabilizer include those described in the following [1]-[5] and the like.

[1] hindered amine light stabilizer, for example, those described in the following [a]-[c].[a]bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl)succinate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, bis(N-octoxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(N-benzyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(N-cyclohexyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-butylmalonate, bis(1-acryloyl-2,2,6,6-tetramethyl-4-piperidyl) 2,2-bis(3,5-di-t-butyl-4-hydroxybenzyl)malonate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)decanedioate, 2,2,6,6-tetramethyl-4-piperidyl methacrylate, 4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-1-[2-(3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy)ethyl]-2,2,6,6-tetramethylpiperidine, 2-methyl-2-(2,2,6,6-tetramethyl-4-piperidyl)amino-N-(2,2,6,6-tetramethyl-4-piperidyl)propionamide, tetrakis(2,2,6,6-tetramethyl-4-piperidyl) 1,2,3,4-butanetetracarboxylate, tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl) 1,2,3,4-butanetetracarboxylate.[b] mixed ester of 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-pentamethyl-4-piperidinol and 1-tridecanol, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetramethyl-4-piperidinol and 1-tridecanol, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-pentamethyl-4-piperidinol and 3,9-bis(2-hydroxy-1,1-dimethylethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetramethyl-4-piperidinol and 3,9-bis(2-hydroxy-1,1-dimethylethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane.[c] polycondensate of dimethyl succinate and 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidine, poly[(6-morpholino-1,3,5-triazine-2,4-diyl)((2,2,6,6-tetramethyl-4-piperidyl)imino)hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino)], poly[(6-(1,1,3,3-tetramethylbutyl)imino-1,3,5-triazine-2,4-diyl)((2,2,6,6-tetramethyl-4-piperidyl)imino)hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino)], polycondensate of N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 1,2-dibromoethane, N,N′,4,7-tetrakis[4,6-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine, N,N′,4-tris[4,6-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine, N,N′,4,7-tetrakis[4,6-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino)-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine, N,N′,4-tris[4,6-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino)-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine.[2] acrylate light stabilizer such as ethyl α-cyano-β,β-diphenylacrylate, isooctyl α-cyano-β,β-diphenylacrylate, methyl α-carbomethoxycinnamate, methyl α-cyano-β-methyl-p-methoxycinnamate, butyl α-cyano-β-methyl-p-methoxycinnamate, methyl α-carbomethoxy-p-methoxycinnamate, N-(β-carbomethoxy-β-cyanovinyl)-2-methylindoline and the like.[3] nickel light stabilizer such as nickel complex of 2,2′-thiobis-[4-(1,1,3,3-tetramethylbutyl)phenol], nickel dibutyldithiocarbamate, nickel salt of monoalkylester, nickel complex of ketoxime and the like.[4] oxamide light stabilizer such as 4,4′-dioctyloxyoxanilide, 2,2′-diethoxyoxanilide, 2,2′-dioctyloxy-5,5′-di-t-butylanilide, 2,2′-didodecyloxy-5,5′-di-t-butylanilide, 2-ethoxy-2′-ethyloxanilide, N,N′-bis(3-dimethylaminopropyl)oxamide, 2-ethoxy-5-t-butyl-2′-ethoxyanilide, 2-ethoxy-5,4′-di-t-butyl-2′-ethyloxanilide and the like.[5] 2-(2-hydroxyphenyl)-1,3,5-triazine light stabilizer such as 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2,4-bis(2-hydroxy-4-propyloxyphenyl)-6-(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(4-methylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-butyloxypropoxy)phenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-octyloxypropoxy)phenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine and the like.

Examples of the stabilizer include hydroxyamines such as N,N-dibenzylhydroxyamine, N,N-diethylhydroxyamine, N,N-dioctylhydroxyamine, N,N-dilauryl hydroxyamine, N,N-ditetradecylhydroxyamine, N,N-dihexadecylhydroxyamine, N,N-dioctadecylhydroxyamine, N-hexadecyl-N-octadecylhydroxyamine, N-heptadecyl-N-octadecylhydroxyamine and the like, and the like.

Examples of the lubricant include aliphatic hydrocarbon such as paraffin, wax and the like, C_8-22 higher fatty acid, metal (Al, Ca, Mg, Zn) salt of C_8-22 higher fatty acid, C_8-22 aliphatic alcohol, polyglycol, ester of C_4-22 fatty acid and C_4-18 aliphatic monovalent alcohol, C_8-22 higher aliphatic amide, silicone oil, rosin derivative and the like.

Of the aforementioned other additives, phenol antioxidant, phosphorus antioxidant, sulfur antioxidant, UV absorber and hindered amine light stabilizer are preferable, and phenol antioxidant is more preferable.

Examples of particularly preferable phenol antioxidant include those described below: 2,6-di-t-butyl-4-methylphenol, 2,4,6-tri-t-butylphenol, 2,4-bis(octylthiomethyl)-6-t-butylphenol, 2,2′-thiobis(6-t-butylphenol), 2,2′-methylenebis(4-methyl-6-t-butylphenol), 2,2′-methylenebis(4-ethyl-6-t-butylphenol), 2,2′-methylenebis[4-methyl-6-α-methylcyclohexyl)phenol], 2,2′-methylenebis(4-methyl-6-cyclohexylphenol), 2,2′-methylenebis(4,6-di-t-butylphenol), 2,2′-ethylidenebis(4,6-di-t-butylphenol), 4,4′-methylenebis(6-t-butyl-2-methylphenol), 4,4′-methylenebis(2,6-di-t-butylphenol), 4,4′-butylidenebis(3-methyl-6-t-butylphenol), 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(5-t-butyl-4-hydroxy-2-methylphenyl)butane, 1,1,3-tris(5-t-butyl-4-hydroxy-2-methylphenyl)butane, ethylene glycol bis[3,3-bis(3′-t-butyl-4′-hydroxyphenyl)butyrate], 2,4,6-tris(3,5-di-t-butyl-4-phenoxy)-1,3,5-triazine, tris(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate, bis(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, tris[2-(3′,5′-di-t-butyl-4′-hydroxycinnamoyloxy)ethyl]isocyanurate, diethyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, calcium salt of 3,5-di-t-butyl-4-hydroxybenzylphosphonic acid monoester, neopentanetetrayl tetrakis(3,5-di-t-butyl-4-hydroxycinnamate), thiodiethylene bis(3,5-di-t-butyl-4-hydroxycinnamate), 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, 3,6-dioxaoctamethylene bis(3,5-di-t-butyl-4-hydroxycinnamate), hexamethylene bis(3,5-di-t-butyl-4-hydroxycinnamate), triethylene glycol bis(5-t-butyl-4-hydroxy-3-methylcinnamate), 3,9-bis[2-(3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy)-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, N,N′-bis[3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionyl]hydrazine, N,N′-bis[3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionyl]hexamethylenediamine.

Examples of particularly preferable phosphorus antioxidant include those described below: 2,2′-ethylidenebis(4,6-di-t-butylphenyl)fluorophosphite, bis(2,4-di-t-butyl-6-methylphenyl)ethyl phosphite, 2-(2,4,6-tri-t-butylphenyl)-5-ethyl-5-butyl-1,3,2-oxaphosphorinan.

Examples of particularly preferable UV absorber include those described below: phenyl salicylate, 4-t-butylphenyl is salicylate, 2,4-di-t-butylphenyl 3′,5′-di-t-butyl-4′-hydroxybenzoate, 4-t-octylphenyl salicylate, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, bis(5-benzoyl-4-hydroxy-2-methoxyphenyl)methane, 2,2′,4,4′-tetrahydroxybenzophenone, 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(3′,5′-di-t-butyl-2′-hydroxyphenyl)benzotriazole, 2-(5′-t-butyl-2′-hydroxyphenyl)benzotriazole, 2-(2′-hydroxy-5′-t-octylphenyl)benzotriazole, 2-(3-t-butyl-2-hydroxy-5-methylphenyl)-5-chlorobenzotriazole, 2-(3′-sec-butyl-2′-hydroxy-5′-t-butylphenyl)benzotriazole, 2-(2′-hydroxy-4′-octyloxyphenyl)benzotriazole, 2-(3′,5′-di-t-pentyl-2′-hydroxyphenyl)benzotriazole, 2-[2′-hydroxy-3′,5′-bis(α,α-dimethylbenzyl)phenyl]-2H-benzotriazole.

Examples of particularly preferable hindered amine light stabilizer include those described below: bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, bis(N-octoxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(N-benzyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(N-cyclohexyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-butylmalonate, bis(1-acryloyl-2,2,6,6-tetramethyl-4-piperidyl) 2,2-bis(3,5-di-t-butyl-4-hydroxybenzyl)-2-butylmalonate, bis(2,2,6,6-tetramethyl-4-piperidyl)succinate, 2,2,6,6-tetramethyl-4-piperidyl methacrylate, 4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-1-[2-(3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy)ethyl]-2,2,6,6-tetramethylpiperidine, 2-methyl-2-(2,2,6,6-tetramethyl-4-piperidyl)amino-N-(2,2,6,6-tetramethyl-4-piperidyl)propionamide, tetrakis(2,2,6,6-tetramethyl-4-piperidyl) 1,2,3,4-butanetetracarboxylate, tetrakis(1,2,6,6-pentamethyl-4-piperidyl) 1,2,3,4-butanetetracarboxylate, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-pentamethyl-4-piperidinol and 1-tridecanol, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetramethyl-4-piperidinol and 1-tridecanol, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-pentamethyl-4-piperidinol and 3,9-bis(2-hydroxy-1,1-dimethylethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane, mixed ester of 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetramethyl-4-piperidinol and 3,9-bis(2-hydroxy-1,1-dimethylethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane, polycondensate of dimethyl succinate and 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidine, poly[(6-morpholino-1,3,5-triazine-2,4-diyl)((2,2,6,6-tetramethyl-4-piperidyl)imino)hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino)], poly[(6-(1,1,3,3-tetramethylbutyl)imino-1,3,5-triazine-2,4-diyl)((2,2,6,6-tetramethyl-4-piperidyl)imino)hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino)].

Examples of the production method of the processing stabilizer of the present invention include a method including mixing the essential components and optional components used as necessary (i.e., compounds (1)-(8), compound (9) and other additives) of the first-fourth processing stabilizers in a blending machine such as Henschel mixer, super mixer, high speed mixer and the like and the like. The thus-obtained mixture (processing stabilizer) may be further subjected to extrusion molding or agitation granulation.

Next, the thermoplastic polymer composition of the present invention is explained. The thermoplastic polymer composition of the present invention contains respective essential components of the first-fourth processing stabilizers (i.e., compound (1), compound (2), at least one selected from the group consisting of compounds represented by the formulas (3)-(7) or compound (8), and compound (9)) and a thermoplastic polymer. The thermoplastic polymer composition of the present invention may contain each optional component of the first-fourth processing stabilizers (i.e., compound (1)-compound (8), which are not essential components, and the aforementioned other additives). Only one kind of thermoplastic polymers may be used or two or more kinds thereof may be used in combination.

Examples of the thermoplastic polymer include polyethylene resin (high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ethylene-vinyl alcohol copolymer (EVOH), ethylene-ethyl acrylate copolymer (EEA), ethylene-vinyl acetate copolymer (EVA) and the like), polypropylene resin (crystalline propylene homopolymer, propylene-ethylene random copolymer, propylene-α-olefin random copolymer, propylene-ethylene-α-olefin copolymer, polypropylene block copolymer comprised of a block of propylene homopolymer or copolymer containing propylene as a main component and a block of copolymer of propylene and ethylene and/or other α-olefin, and the like), methylpentene polymer, polystyrene resin (polystyrenes such as polystyrene (PS), poly(p-methylstyrene), poly(α-methylstyrene) and the like, acrylonitrile-styrene copolymer (SAN), acrylonitrile-butadiene-styrene copolymer (ABS), special acrylic rubber-acrylonitrile-styrene copolymer, acrylonitrile-chlorinated polyethylene-styrene copolymer (ACS) and the like), polybutadiene resin (polybutadiene; polybutadiene rubber (BR); styrene-butadiene copolymer (SB); styrene-butadiene block copolymer (SBS); impact resistance polystyrene (HI-PS) modified by polybutadiene, styrene-butadiene copolymer or SBS and the like), chlorinated polyethylene (CPE), polychloroprene, chlorinated rubber, poly(vinyl chloride) thermoplastic elastomer, poly(vinyl chloride) (PVC), poly(vinylidene chloride) (PVDC), methacrylate resin, fluororesin, polyacetal (POM), grafted poly(phenylene ether) resin, poly(phenylene sulfide) resin (PPS), polyurethane (PU), polyamide (PA), polyester resin (e.g., poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT) and the like), poly(lactic acid) (PLA), polycarbonate (PC), polyacrylate, polysulfone (PPSU), poly(ether ether ketone) (PEEK), poly(ether sulfone) (PES), aromatic polyester, diallyl phthalate prepolymer, silicone resin (SI), 1,2-polybutadiene, polyisoprene, butadiene-acrylonitrile copolymer (NBR), ethylene-methyl methacrylate copolymer (EMMA) and the like.

Of these, due to good molding processability, polyethylene resin, polypropylene resin, polystyrene resin and polybutadiene resin are preferable, polyethylene resin and polybutadiene resin are more preferable. In the first-third thermoplastic polymer compositions, ethylene-vinyl alcohol copolymer (EVOH) and styrene-butadiene block copolymer (SES) are more preferable, and in the fourth thermoplastic polymer composition, a styrene-butadiene block copolymer (SBS) is still more preferable.

While the weight average molecular weight (Mw) of the thermoplastic polymer to be used is not particularly limited, it is generally not less than 1000 and not more than 300,000. Mw can be measured by, for example, gel permeation chromatography (GPC) using polystyrene as a standard.

The content of the first processing stabilizer in the first thermoplastic polymer composition is determined by the total amount of compound (1) and compound (9). The total amount of compound (1) and compound (9) in the first thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight, still more preferably not less than 0.1 part by weight, particularly preferably not less than 0.5 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight, still more preferably not more than 1 part by weight), relative to 100 parts by weight of the thermoplastic polymer.

When the first processing stabilizer containing at least one of compound (2)-compound (7) is used, the content of each of compound (2)-compound (7) in the first thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight), relative to 100 parts by weight of the thermoplastic polymer.

The content of the second processing stabilizer in the second thermoplastic polymer composition is determined by the total amount of compound (8) and compound (9). The total amount of compound (8) and compound (9) in the second thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight, still more preferably not less than 0.1 part by weight, particularly preferably not less than 0.5 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight, still more preferably not more than 1 part by weight), relative to 100 parts by weight of the thermoplastic polymer.

When the second processing stabilizer containing at least one of compound (2)-compound (7) is used, the content of each of compound (2)-compound (7) in the second thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight), relative to 100 parts by weight of the thermoplastic polymer.

The content of the third processing stabilizer in the third thermoplastic polymer composition is determined by the total amount of compound (2) and compound (9). The total amount of compound (2) and compound (9) in the third thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight, still more preferably not less than 0.1 part by weight, particularly preferably not less than 0.5 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight, still more preferably not more than 1 part by weight), relative to 100 parts by weight of the thermoplastic polymer.

When the third processing stabilizer containing at least one of compound (1), compound (3)-compound (8) is used, the content of each of compound (1), compound (3)-compound (8) in the third thermoplastic polymer composition is preferably not less than 0.001 part by weight (more preferably not less than 0.02 parts by weight), preferably not more than 3 parts by weight (more preferably not more than 2 parts by weight), relative to 100 parts by weight of the thermoplastic polymer.

The content of the fourth processing stabilizer in the fourth thermoplastic polymer composition is determined by the total amount of compound (9) and the compound selected from the group consisting of compound (3)-compound (7). The total amount of compound (9) and the compound selected from the group consisting of compound (3)-compound (7) in the fourth thermoplastic polymer composition is preferably 0.001-3 parts by weight, more preferably 0.02-2 parts by weight, still more preferably 0.02-1 part by weight, relative to 100 parts by weight of the thermoplastic polymer. The preferable range of weight ratio of the compound selected from the group consisting of compound (3)-compound (7) and compound (9) (i.e., compound selected from the group consisting of compound (3)-compound (7):compound (9)) in the fourth thermoplastic polymer composition is the same as the preferable range of weight ratio in the aforementioned fourth processing stabilizer.

When the fourth processing stabilizer containing at least one of compound (1), compound (2) and compound (8) is used, the content of each of compound (1), compound (2) and compound (8) in the fourth thermoplastic polymer composition is preferably 0.001-3 parts by weight, more preferably 0.02-2 parts by weight, relative to 100 parts by weight of the thermoplastic polymer.

Examples of the production method of the thermoplastic polymer composition of the present invention include a method including mixing the processing stabilizer of the present invention produced as mentioned above and a thermoplastic polymer and the like. This production method also includes, for example, a method including separately adding, when kneading a thermoplastic polymer, each component that can be contained in the processing stabilizer of the present invention, i.e., compounds (1)-(8), compound (9) and other additives, to a thermoplastic polymer, and mixing them (i.e., the processing stabilizer of the present invention and thermoplastic polymer).

Examples of the mixing method of a processing stabilizer and a thermoplastic polymer include (a) a method including dry-blending a processing stabilizer and a thermoplastic polymer, melt-kneading them and extruding the mixture in a single screw or multiscrew extruder to give pellets of a thermoplastic polymer composition; (b) a method including dissolving a processing stabilizer in a solvent such as cyclohexane and the like to give a solution of the processing stabilizer, adding the solution to a polymer solution after completion of thermoplastic polymer polymerization, and desolvating the mixture; and the like.

The obtained thermoplastic polymer composition may be supplied in a molten state without cooling to a molding machine for molding. The molding method is not particularly limited and, for example, molding method such as injection molding method, extrusion molding method, extrusion blow molding method, injection blow molding method, biaxial orientation blow molding method and the like can be used.

By cooling after molding, a thermoplastic polymer molded product comprised of the thermoplastic polymer composition of the present invention is obtained. Examples of the use of the obtained thermoplastic polymer molding product include electronic component (e.g., coil bobbin, connector, switch, resistor component, socket, relay, condenser case, fuse, motor, oven, printed circuit board, IC manufacturing equipment, lamp and the like), automobile part (e.g., air outlet garnish, hood vent, distributor cap, exhaust gas control valve and the like), clock component (e.g., machine component such as gear, cam and the like, ground plane and the like), camera component (e.g., bottom cover, barrel, lever and the like), component of leisure goods (e.g., reel and the like), household electrical appliance housing, illumination wiring equipment, film, bottle, fiber, septic tank, toilet tank, bath tub, unit bath, water tank, boats and ships, chemicals tank, pipe, corrugated plate, flat plate, paint, decorative laminate, mounting agent for electronic component, resin concrete and the like.

EXAMPLES

The present invention is explained in more detail in the following by referring to Examples and the like. In the following, “part” and “%” is, unless particularly explained, on the weight basis. In addition, the “melt flow rate” is described as “MFR”.

[1] Components The components used in the following Examples and the like are as follows.

compound (1-1): 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate (“Sumilizer (registered trade mark) GS(F)” manufactured by Sumitomo Chemical Company, Limited)

compound (1-2): 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (“Sumilizer (registered trade mark) GM” manufactured by Sumitomo Chemical Company, Limited)

compound (2-1): octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (“Irganox (registered trade mark) 1076” manufactured by BASF) compound (2-2): 3,9-bis[2-{3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane (“Sumilizer (registered trade mark) GA-80” manufactured by Sumitomo Chemical Company, Limited)

compound (2-3): pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate] (“Irganox (registered trade mark) 1010” manufactured by BASF)

compound (3-1): tris(2,4-di-t-butylphenyl)phosphite (“Irgafos (registered trade mark) 168” manufactured by BASF) compound (4-1): tetrakis(2,4-di-t-butylphenyl)-4,4-biphenylene diphoshonite (“Sandostab (registered trade mark) P-EPQ” manufactured by Clariant)

compound (5-1): bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite (“Adekastab (registered trade mark) PEP-36” manufactured by ADEKA)

compound (5-2): bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite (“Ultranox (registered trade mark) 626” manufactured by GE Plastics)

compound (5-3): bis(2,4-dicumylphenyl)pentaerythritol diphosphite (“Doverphos S9228T” manufactured by Dover Chemical Corporation)

compound (6-1): 6,6′,6″-[nitrilotris(ethyleneoxy)]tris(2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine) (“Irgafos (registered trade mark) 12” manufactured by BASF)

compound (7-1): 2,2-methylenebis(4,6-di-t-butylphenyl)octyl phosphite (“Adekastab (registered trade mark) HP-10” manufactured by ADEKA)

compound (8-1): 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphosphepine (“Sumilizer (registered trade mark) GP” manufactured by Sumitomo Chemical Company, Limited)

compound (9-1): methyl α-D-glucopyranoside (manufactured by Tokyo Chemical Industry Co., Ltd.)

In the following Example 1-1-Example 1-183, the first processing stabilizer containing compound (1) and compound (9) as essential components is used, in Example 2-1-Example 2-163, the second processing stabilizer containing compound (8) and compound (9) as essential components is used, in Example 3-1-Example 3-131, the third processing stabilizer containing compound (2) and compound (9) as essential components is used, and in Example 4-1-Example 4-196, the fourth processing stabilizer containing compound (9) and at least one selected from the group consisting of compound (3)-compound (7) as essential components is used.

[2] Evaluation of processing stability of thermoplastic polymer composition

The processing stability of the thermoplastic polymer compositions obtained in the following Examples and the like was evaluated by the method of the following (1) or (2).

(1) MFR Variation Rate

Dwell MFR tests were performed using the pellets of the thermoplastic polymer compositions. The test was based on JIS K 7210, and 0 min Dwell MFR (g/10 min) and 30 min Dwell MFR (g/10 min) were measured by a melt indexer (L217-E14011 manufactured by Technol Seven Co., Ltd.) under the conditions of temperature in a cylinder 270° C. and load 2.16 kg. The 0 min Dwell MFR was measured after 5-min preheating time after filling pellets of the thermoplastic polymer composition in the cylinder. The 30 min Dwell MFR was measured after 30-min dwell time, including the preheating time, of the pellets of the thermoplastic polymer composition in the cylinder. The MFR variation rate was calculated by the following formula and using the thus-measured 0 min Dwell MFR and 30 min Dwell MFR:

MFR variation rate (%)=absolute value of (30 min Dwell MFR-0 min Dwell MFR)×100/(0 min Dwell MFR)

A smaller MFR variation rate means better processing stability of the thermoplastic polymer composition.

(2) Inhibition Rate of MFR Increment

Dwell MFR tests were performed using the pellets of the thermoplastic polymer compositions. The test was based on JIS K 7210, and 30 min Dwell MFR (g/10 min) were measured by a melt indexer (L217-E14011 manufactured by Technol Seven Co., Ltd.) under the conditions of temperature in a cylinder 270° C. and load 2.16 kg. The 30 min Dwell MFR was measured after 30-min dwell time, including the preheating time, of the pellets of the thermoplastic polymer composition in the cylinder. The inhibition rate of MFR increment was calculated by the following formula and using the 30 min Dwell MFR obtained in the Example and the 30 min Dwell MFR of Comparative Example:

inhibition rate of MFR increment (%)=(30 min Dwell MFR of Comparative Example−30 min Dwell MFR of Example)×100/(30 min Dwell MFR of Comparative Example)

When polypropylene is used as a thermoplastic polymer, decomposition of polypropylene is accelerated by the heat of processing, and 30 min Dwell MFR increases. Therefore, in a thermoplastic polymer composition containing polypropylene, the processing stability of the thermoplastic polymer composition becomes higher as 30 min Dwell MFR is smaller and the inhibition rate of MFR increment is larger.

Example 1-1

Production of Processing Stabilizer

Compound (1-1) and compound (9-1) in the amounts described in Table 1 were mixed to produce a processing stabilizer.

Example 1-2

Production of Processing Stabilizer

Compound (1-1), compound (9-1) and compound (2-1) in the amounts described in Table 1 were mixed to produce a processing stabilizer.

Reference Example 1-1

Production of Processing Stabilizer

Compound (1-1) and compound (2-1) in the amounts described in Table 1 were mixed to produce a processing stabilizer.

Example 1-3

Production of Thermoplastic Polymer Composition

The processing stabilizer obtained in Example 1-1 (0.31 part) and a styrene-butadiene block copolymer (“Asaflex 830” manufactured by Asahi Kasei Corp.) (100 parts) were dry-blended, the obtained mixture was knead-extruded by a single screw extruder having a screw diameter of 30 mm (“VS30-28 type extruder” manufactured by TANABE PLASTICS MACHINERY CO., LTD.) under the conditions of temperature 230° C. and screw rotation 50 rpm to give strands, and the strands were cut by a pelletizer to give a thermoplastic polymer composition as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 2.

Comparative Example 1-1

Production of Thermoplastic Polymer Composition

In the same manner as in Example 1-3 except that compound (1-1) (0.3 part) alone was used instead of the processing stabilizer obtained in Example 1-1, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 2.

Example 1-4

Production of Thermoplastic Polymer Composition

In the same manner as in Example 1-3 except that the stabilizer composition (0.51 part) obtained in Example 1-2 was used instead of the stabilizer composition obtained in Example 1-1, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 2.

Reference Example 1-2

Production of Thermoplastic Polymer Composition

In the same manner as in Example 1-3 except that the processing stabilizer (0.5 part) obtained in Reference Example 1-1 was used instead of the processing stabilizer obtained in Example 1-1, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 2.

TABLE 1
processing stabilizer
	compound	compound	compound
	(1-1) (part)	(9-1) (part)	(2-1) (part)
	Ex. 1-1	0.3	0.01	—
	Ex. 1-2	0.3	0.01	0.2
	Ref. Ex. 1-1	0.3	—	0.2

TABLE 2
thermoplastic polymer composition
					MFR
	thermo-	processing	0 min	30 min	varia-
	plastic	stabilizer	Dwell	Dwell	tion
	polymer		amount	MFR	MFR	rate
	SBS (part)	kind	(part)	(g/10 min)	(g/10 min)	(%)
Ex.	100	Ex.	0.31	16.3	2.5	84.7
1-3		1-1
Comp.	100	compound	0.3	18.2	2.1	88.5
Ex.		(1-1)
1-1
Ex.	100	Ex.	0.51	18.0	5.8	67.8
1-4		1-2
Ref.	100	Ref. Ex.	0.5	19.2	5.6	70.8
Ex.		1-1
1-2
SBS: styrene-butadiene block copolymer

From the results shown in Table 2, it is clear that a combined use of compound (1) and compound (9) improves the processing stability of thermoplastic polymer compositions as compared to a single use of compound (1). In addition, it is clear that the processing stability of thermoplastic polymer compositions is improved by using compound (9) in combination, even when compound (2) is used in addition to compound (1).

Example 1-5-Example 1-97

Production of Processing Stabilizer

By mixing the components described in Table 3-1-Table 3-3, processing stabilizers are obtained.

TABLE 3-1
processing stabilizer
	compound	compound	compound	compounds
	(1)	(9-1)	(2)	(3)-(7)
		amount	amount		amount		amount
Example	kind	(part)	(part)	kind	(part)	kind	(part)
1-5	(1-1)	0.01	0.2	—	—	—	—
1-6	(1-1)	0.05	0.15	—	—	—	—
1-7	(1-1)	0.1	0.1	—	—	—	—
1-8	(1-1)	0.15	0.05	—	—	—	—
1-9	(1-1)	0.2	0.01	—	—	—	—
1-10	(1-1)	0.2	0.005	—	—	—	—
1-11	(1-1)	0.2	0.001	—	—	—	—
1-12	(1-1)	0.2	0.0005	—	—	—	—
1-13	(1-1)	0.2	0.0002	—	—	—	—
1-14	(1-1)	0.01	0.2	(2-2)	0.2	—	—
1-15	(1-1)	0.1	0.1	(2-2)	0.2	—	—
1-16	(1-1)	0.2	0.01	(2-2)	0.2	—	—
1-17	(1-1)	0.2	0.005	(2-2)	0.2	—	—
1-18	(1-1)	0.2	0.001	(2-2)	0.2	—	—
1-19	(1-1)	0.2	0.0005	(2-2)	0.2	—	—
1-20	(1-1)	0.01	0.2	(2-3)	0.2	—	—
1-21	(1-1)	0.1	0.1	(2-3)	0.2	—	—
1-22	(1-1)	0.2	0.01	(2-3)	0.2	—	—
1-23	(1-1)	0.2	0.005	(2-3)	0.2	—	—
1-24	(1-1)	0.2	0.001	(2-3)	0.2	—	—
1-25	(1-1)	0.2	0.0005	(2-3)	0.2	—	—
1-26	(1-1)	0.01	0.2	—	—	(3-1)	0.2
1-27	(1-1)	0.1	0.1	—	—	(3-1)	0.2
1-28	(1-1)	0.2	0.01	—	—	(3-1)	0.2
1-29	(1-1)	0.2	0.005	—	—	(3-1)	0.2
1-30	(1-1)	0.2	0.001	—	—	(3-1)	0.2
1-31	(1-1)	0.2	0.0005	—	—	(3-1)	0.2
1-32	(1-1)	0.01	0.2	—	—	(4-1)	0.2
1-33	(1-1)	0.1	0.1	—	—	(4-1)	0.2
1-34	(1-1)	0.2	0.01	—	—	(4-1)	0.2
1-35	(1-1)	0.2	0.005	—	—	(4-1)	0.2

TABLE 3-2
processing stabilizer
	compound	compound	compound	compounds
	(1)	(9-1)	(2)	(3)-(7)
		amount	amount		amount		amount
Example	kind	(part)	(part)	kind	(part)	kind	(part)
1-36	(1-1)	0.2	0.001	—	—	(4-1)	0.2
1-37	(1-1)	0.2	0.0005	—	—	(4-1)	0.2
1-38	(1-1)	0.01	0.2	—	—	(5-1)	0.2
1-39	(1-1)	0.1	0.1	—	—	(5-1)	0.2
1-40	(1-1)	0.2	0.01	—	—	(5-1)	0.2
1-41	(1-1)	0.2	0.005	—	—	(5-1)	0.2
1-42	(1-1)	0.2	0.001	—	—	(5-1)	0.2
1-43	(1-1)	0.2	0.0005	—	—	(5-1)	0.2
1-44	(1-1)	0.01	0.2	—	—	(5-2)	0.2
1-45	(1-1)	0.1	0.1	—	—	(5-2)	0.2
1-46	(1-1)	0.2	0.01	—	—	(5-2)	0.2
1-47	(1-1)	0.2	0.005	—	—	(5-2)	0.2
1-48	(1-1)	0.2	0.001	—	—	(5-2)	0.2
1-49	(1-1)	0.2	0.0005	—	—	(5-2)	0.2
1-50	(1-1)	0.01	0.2	—	—	(5-3)	0.2
1-51	(1-1)	0.1	0.1	—	—	(5-3)	0.2
1-52	(1-1)	0.2	0.01	—	—	(5-3)	0.2
1-53	(1-1)	0.2	0.005	—	—	(5-3)	0.2
1-54	(1-1)	0.2	0.001	—	—	(5-3)	0.2
1-55	(1-1)	0.2	0.0005	—	—	(5-3)	0.2
1-56	(1-1)	0.01	0.2	—	—	(6-1)	0.2
1-57	(1-1)	0.1	0.1	—	—	(6-1)	0.2
1-58	(1-1)	0.2	0.01	—	—	(6-1)	0.2
1-59	(1-1)	0.2	0.005	—	—	(6-1)	0.2
1-60	(1-1)	0.2	0.001	—	—	(6-1)	0.2
1-61	(1-1)	0.2	0.0005	—	—	(6-1)	0.2
1-62	(1-1)	0.01	0.2	—	—	(7-1)	0.2
1-63	(1-1)	0.1	0.1	—	—	(7-1)	0.2
1-64	(1-1)	0.2	0.01	—	—	(7-1)	0.2
1-65	(1-1)	0.2	0.005	—	—	(7-1)	0.2
1-66	(1-1)	0.2	0.001	—	—	(7-1)	0.2

TABLE 3-3
processing stabilizer
	compound	compound	compound	compounds
	(1)	(9-1)	(2)	(3)-(7)
		amount	amount		amount		amount
Example	kind	(part)	(part)	kind	(part)	kind	(part)
1-67	(1-1)	0.2	0.0005	—	—	(7-1)	0.2
1-68	(1-1)	0.01	0.2	(2-1)	0.2	(3-1)	0.2
1-69	(1-1)	0.1	0.1	(2-1)	0.2	(3-1)	0.2
1-70	(1-1)	0.2	0.01	(2-1)	0.2	(3-1)	0.2
1-71	(1-1)	0.2	0.005	(2-1)	0.2	(3-1)	0.2
1-72	(1-1)	0.2	0.001	(2-1)	0.2	(3-1)	0.2
1-73	(1-1)	0.2	0.0005	(2-1)	0.2	(3-1)	0.2
1-74	(1-1)	0.01	0.2	(2-2)	0.2	(3-1)	0.2
1-75	(1-1)	0.1	0.1	(2-2)	0.2	(3-1)	0.2
1-76	(1-1)	0.2	0.01	(2-2)	0.2	(3-1)	0.2
1-77	(1-1)	0.2	0.005	(2-2)	0.2	(3-1)	0.2
1-78	(1-1)	0.2	0.001	(2-2)	0.2	(3-1)	0.2
1-79	(1-1)	0.2	0.0005	(2-2)	0.2	(3-1)	0.2
1-80	(1-1)	0.01	0.2	(2-3)	0.2	(3-1)	0.2
1-81	(1-1)	0.1	0.1	(2-3)	0.2	(3-1)	0.2
1-82	(1-1)	0.2	0.01	(2-3)	0.2	(3-1)	0.2
1-83	(1-1)	0.2	0.005	(2-3)	0.2	(3-1)	0.2
1-84	(1-1)	0.2	0.001	(2-3)	0.2	(3-1)	0.2
1-85	(1-1)	0.2	0.0005	(2-3)	0.2	(3-1)	0.2
1-86	(1-2)	0.01	0.2	—	—	—	—
1-87	(1-2)	0.05	0.15	—	—	—	—
1-88	(1-2)	0.1	0.1	—	—	—	—
1-89	(1-2)	0.15	0.05	—	—	—	—
1-90	(1-2)	0.2	0.01	—	—	—	—
1-91	(1-2)	0.2	0.005	—	—	—	—
1-92	(1-2)	0.2	0.001	—	—	—	—
1-93	(1-2)	0.2	0.0005	—	—	—	—
1-94	(1-2)	0.2	0.0002	—	—	—	—
1-95	(1-2)	0.1	0.1	(2-1)	0.2	—	—
1-96	(1-2)	0.1	0.1	—	—	(3-1)	0.2
1-97	(1-2)	0.1	0.1	(2-1)	0.2	(3-1)	0.2

Example 1-98-Example 1-183

Production of Thermoplastic Polymer Composition

In the same manner as in Example 1-3 except that the thermoplastic polymers and processing stabilizers described in Table 4-1-Table 4-3 are used, thermoplastic polymer compositions are obtained as pellets.

The meanings of the abbreviations of the thermoplastic polymers described in Table 4-1-Table 4-3 are as follows.

P1-1: high density polyethylene (HDPE)P1-2: low density polyethylene (LDPE)P1-3: linear low density polyethylene (LLDPE)P1-4: ethylene-vinyl alcohol copolymer (EVOH)P1-5: ethylene-ethyl acrylate copolymer (EEA)P1-6: ethylene-vinyl acetate copolymer (EVA)P1-7: crystalline propylene homopolymerP1-8: propylene-ethylene random copolymerP1-9: propylene-α-olefin random copolymerP1-10: propylene-ethylene-α-olefin copolymerP1-11: polystyrene (PS)P1-12: acrylonitrile-styrene copolymer (SAN)P1-13: acrylonitrile-butadiene-styrene copolymer (ABS)P1-14: special acrylic rubber-acrylonitrile-styrene copolymerP1-15: acrylonitrile-chlorinated polyethylene-styrene copolymer (ACS)P1-16: polybutadiene rubber (BR)P1-17: styrene-butadiene copolymer (SB)P1-18: chlorinated polyethylene (CPE)P1-19: polychloropreneP1-20: chlorinated rubberP1-21: polyvinyl chloride) (PVC)P1-22: poly(vinylidene chloride) (PVDC)P1-23: methacrylate resinP1-24: fluororesinP1-25: polyacetal (POM)P1-26: grafted poly(phenylene ether) resinP1-27: poly(phenylene sulfide) resin (PPS)P1-28: polyurethane (PU)P1-29: polyamide (PA)P1-30: poly(ethylene terephthalate) (PET)P1-31: poly(butylene terephthalate) (PBT)P1-32: poly(lactic acid) (PLA)P1-33: polycarbonate (PC)P1-34: polyacrylateP1-35: polysulfone (PPSU)P1-36: poly(ether ether ketone) (PEEK)P1-37: poly(ether sulfone) (PES)P1-38: aromatic polyesterP1-39: diallyl phthalate prepolymerP1-40: silicone resin (SI)P1-41: 1,2-polybutadieneP1-42: polyisopreneP1-43: butadiene-acrylonitrile copolymer (NBR)P1-44: ethylene-methyl methacrylate copolymer (EMMA)

TABLE 4-1
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	1-98	P1-1	100	Ex. 1-1	0.31
	1-99	P1-2	100	Ex. 1-1	0.31
	1-100	P1-3	100	Ex. 1-1	0.31
	1-101	P1-3	100	Ex. 1-2	0.51
	1-102	P1-3	100	Ex. 1-5	0.21
	1-103	P1-3	100	Ex. 1-7	0.2
	1-104	P1-3	100	Ex. 1-11	0.201
	1-105	P1-3	100	Ex. 1-13	0.2002
	1-106	P1-3	100	Ex. 1-28	0.41
	1-107	P1-3	100	Ex. 1-70	0.61
	1-108	P1-4	100	Ex. 1-1	0.31
	1-109	P1-4	100	Ex. 1-2	0.51
	1-110	P1-4	100	Ex. 1-5	0.21
	1-111	P1-4	100	Ex. 1-7	0.2
	1-112	P1-4	100	Ex. 1-11	0.201
	1-113	P1-4	100	Ex. 1-13	0.2002
	1-114	P1-4	100	Ex. 1-28	0.41
	1-115	P1-4	100	Ex. 1-70	0.61
	1-116	P1-5	100	Ex. 1-1	0.31
	1-117	P1-6	100	Ex. 1-1	0.31
	1-118	P1-7	100	Ex. 1-1	0.31
	1-119	P1-7	100	Ex. 1-2	0.51
	1-120	P1-7	100	Ex. 1-5	0.21
	1-121	P1-7	100	Ex. 1-7	0.2
	1-122	P1-7	100	Ex. 1-11	0.201
	1-123	P1-7	100	Ex. 1-13	0.2002
	1-124	P1-7	100	Ex. 1-28	0.41
	1-125	P1-7	100	Ex. 1-70	0.61
	1-126	P1-8	100	Ex. 1-1	0.31

TABLE 4-2
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	1-127	P1-9	100	Ex. 1-1	0.31
	1-128	P1-10	100	Ex. 1-1	0.31
	1-129	P1-11	100	Ex. 1-1	0.31
	1-130	P1-11	100	Ex. 1-2	0.51
	1-131	P1-11	100	Ex. 1-5	0.21
	1-132	P1-11	100	Ex. 1-7	0.2
	1-133	P1-11	100	Ex. 1-11	0.201
	1-134	P1-11	100	Ex. 1-13	0.2002
	1-135	P1-11	100	Ex. 1-28	0.41
	1-136	P1-11	100	Ex. 1-70	0.61
	1-137	P1-12	100	Ex. 1-1	0.31
	1-138	P1-13	100	Ex. 1-1	0.31
	1-139	P1-13	100	Ex. 1-2	0.51
	1-140	P1-13	100	Ex. 1-5	0.21
	1-141	P1-13	100	Ex. 1-7	0.2
	1-142	P1-13	100	Ex. 1-11	0.201
	1-143	P1-13	100	Ex. 1-13	0.2002
	1-144	P1-13	100	Ex. 1-28	0.41
	1-145	P1-13	100	Ex. 1-70	0.61
	1-146	P1-14	100	Ex. 1-1	0.31
	1-147	P1-15	100	Ex. 1-1	0.31
	1-148	P1-16	100	Ex. 1-1	0.31
	1-149	P1-17	100	Ex. 1-1	0.31
	1-150	P1-17	100	Ex. 1-2	0.51
	1-151	P1-17	100	Ex. 1-5	0.21
	1-152	P1-17	100	Ex. 1-7	0.2
	1-153	P1-17	100	Ex. 1-11	0.201
	1-154	P1-17	100	Ex. 1-13	0.2002
	1-155	P1-17	100	Ex. 1-28	0.41

TABLE 4-3
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	1-156	P1-17	100	Ex. 1-70	0.61
	1-157	P1-18	100	Ex. 1-1	0.31
	1-158	P1-19	100	Ex. 1-1	0.31
	1-159	P1-20	100	Ex. 1-1	0.31
	1-160	P1-21	100	Ex. 1-1	0.31
	1-161	P1-22	100	Ex. 1-1	0.31
	1-162	P1-23	100	Ex. 1-1	0.31
	1-163	P1-24	100	Ex. 1-1	0.31
	1-164	P1-25	100	Ex. 1-1	0.31
	1-165	P1-26	100	Ex. 1-1	0.31
	1-166	P1-27	100	Ex. 1-1	0.31
	1-167	P1-28	100	Ex. 1-1	0.31
	1-168	P1-29	100	Ex. 1-1	0.31
	1-169	P1-30	100	Ex. 1-1	0.31
	1-170	P1-31	100	Ex. 1-1	0.31
	1-171	P1-32	100	Ex. 1-1	0.31
	1-172	P1-33	100	Ex. 1-1	0.31
	1-173	P1-34	100	Ex. 1-1	0.31
	1-174	P1-35	100	Ex. 1-1	0.31
	1-175	P1-36	100	Ex. 1-1	0.31
	1-176	P1-37	100	Ex. 1-1	0.31
	1-177	P1-38	100	Ex. 1-1	0.31
	1-178	P1-39	100	Ex. 1-1	0.31
	1-179	P1-40	100	Ex. 1-1	0.31
	1-180	P1-41	100	Ex. 1-1	0.31
	1-181	P1-42	100	Ex. 1-1	0.31
	1-182	P1-43	100	Ex. 1-1	0.31
	1-183	P1-44	100	Ex. 1-1	0.31

Example 2-1

Production of Processing Stabilizer

Compound (8-1) and compound (9-1) were mixed to produce a processing stabilizer.

Example 2-2

Production of Thermoplastic Polymer Composition

The processing stabilizer (0.11 part) obtained in Example 2-1 and an ethylene-vinyl alcohol copolymer (“EVAL F171B” manufactured by KURARAY CO., LTD.) (100 parts) were dry-blended, the obtained mixture was knead-extruded by a single screw extruder having a screw diameter of 30 mm (“VS30-28 type extruder” manufactured by TANABE PLASTICS MACHINERY CO., LTD.) under the conditions of temperature 230° C. and screw rotation 50 rpm to give strands, and the strands were cut by a pelletizer to give a thermoplastic polymer composition as pellets.

Comparative Example 2-1

Production of Thermoplastic Polymer Composition

In the same manner as in Example 2-2 except that compound (8-1) (0.1 part) alone was used instead of the processing stabilizer obtained in Example 2-1, a thermoplastic polymer composition was obtained as pellets.

The composition of the processing stabilizer obtained in Example 2-1 is shown in Table 5, and the compositions and the results of processing stability of the thermoplastic polymer compositions obtained in Example 2-2 and Comparative Example 2-1 are shown in Table 6.

TABLE 5
processing stabilizer
	compound	compound	mass ratio of compound
	(8-1) (part)	(9-1) (part)	(8-1):compound (9-1)
Ex. 2-1	0.1	0.01	10:1

TABLE 6
thermoplastic polymer composition
	thermo-
	plastic	processing	0 min	30 min	MFR
	polymer	stabilizer	Dwell	Dwell	variation
	EVOH		amount	MFR	MFR	rate
	(part)	kind	(part)	(g/10 min)	(g/10 min)	(%)
Ex.	100	Ex.	0.11	13.3	11.1	17
2-2		2-1
Comp.	100	com-	0.1	14.5	35.7	147
Ex.		pound
2-1		(8-1)
EVOH: ethylene-vinyl alcohol copolymer

From the comparison of Example 2-2 and Comparative Example 2-1, it is clear that a combined use of compound (8) and compound (9) improves the processing stability of thermoplastic polymer compositions as compared to a single use of compound (8).

Example 2-3-Example 2-89

Production of Processing Stabilizer

By mixing the components described in Table 7-1-Table 7-3, processing stabilizers are obtained.

TABLE 7-1
processing stabilizer
	compound	compound	compound	compounds
	(8-1)	(9-1)	(2)	(3)-(7)
	amount	amount		amount		amount
Example	(part)	(part)	kind	(part)	kind	(part)
2-3	0.01	0.2	—	—	—	—
2-4	0.05	0.15	—	—	—	—
2-5	0.1	0.1	—	—	—	—
2-6	0.15	0.05	—	—	—	—
2-7	0.2	0.01	—	—	—	—
2-8	0.2	0.005	—	—	—	—
2-9	0.2	0.001	—	—	—	—
2-10	0.2	0.0005	—	—	—	—
2-11	0.2	0.0002	—	—	—	—
2-12	0.01	0.2	(2-1)	0.2	—	—
2-13	0.1	0.1	(2-1)	0.2	—	—
2-14	0.2	0.01	(2-1)	0.2	—	—
2-15	0.2	0.005	(2-1)	0.2	—	—
2-16	0.2	0.001	(2-1)	0.2	—	—
2-17	0.2	0.0005	(2-1)	0.2	—	—
2-18	0.01	0.2	(2-2)	0.2	—	—
2-19	0.1	0.1	(2-2)	0.2	—	—
2-20	0.2	0.01	(2-2)	0.2	—	—
2-21	0.2	0.005	(2-2)	0.2	—	—
2-22	0.2	0.001	(2-2)	0.2	—	—
2-23	0.2	0.0005	(2-2)	0.2	—	—
2-24	0.01	0.2	(2-3)	0.2	—	—
2-25	0.1	0.1	(2-3)	0.2	—	—
2-26	0.2	0.01	(2-3)	0.2	—	—
2-27	0.2	0.005	(2-3)	0.2	—	—
2-28	0.2	0.001	(2-3)	0.2	—	—
2-29	0.2	0.0005	(2-3)	0.2	—	—
2-30	0.01	0.2	—	—	(3-1)	0.2
2-31	0.1	0.1	—	—	(3-1)	0.2

TABLE 7-2
processing stabilizer
	compound	compound	compound	compounds
	(8-1)	(9-1)	(2)	(3)-(7)
	amount	amount		amount		amount
Example	(part)	(part)	kind	(part)	kind	(part)
2-32	0.2	0.01	—	—	(3-1)	0.2
2-33	0.2	0.005	—	—	(3-1)	0.2
2-34	0.2	0.001	—	—	(3-1)	0.2
2-35	0.2	0.0005	—	—	(3-1)	0.2
2-36	0.01	0.2	—	—	(4-1)	0.2
2-37	0.1	0.1	—	—	(4-1)	0.2
2-38	0.2	0.01	—	—	(4-1)	0.2
2-39	0.2	0.005	—	—	(4-1)	0.2
2-40	0.2	0.001	—	—	(4-1)	0.2
2-41	0.2	0.0005	—	—	(4-1)	0.2
2-42	0.01	0.2	—	—	(5-1)	0.2
2-43	0.1	0.1	—	—	(5-1)	0.2
2-44	0.2	0.01	—	—	(5-1)	0.2
2-45	0.2	0.005	—	—	(5-1)	0.2
2-46	0.2	0.001	—	—	(5-1)	0.2
2-47	0.2	0.0005	—	—	(5-1)	0.2
2-48	0.01	0.2	—	—	(5-2)	0.2
2-49	0.1	0.1	—	—	(5-2)	0.2
2-50	0.2	0.01	—	—	(5-2)	0.2
2-51	0.2	0.005	—	—	(5-2)	0.2
2-52	0.2	0.001	—	—	(5-2)	0.2
2-53	0.2	0.0005	—	—	(5-2)	0.2
2-54	0.01	0.2	—	—	(5-3)	0.2
2-55	0.1	0.1	—	—	(5-3)	0.2
2-56	0.2	0.01	—	—	(5-3)	0.2
2-57	0.2	0.005	—	—	(5-3)	0.2
2-58	0.2	0.001	—	—	(5-3)	0.2
2-59	0.2	0.0005	—	—	(5-3)	0.2
2-60	0.01	0.2	—	—	(6-1)	0.2

TABLE 7-3
processing stabilizer
	compound	compound	compound	compounds
	(8-1)	(9-1)	(2)	(3)-(7)
	amount	amount		amount		amount
Example	(part)	(part)	kind	(part)	kind	(part)
2-61	0.1	0.1	—	—	(6-1)	0.2
2-62	0.2	0.01	—	—	(6-1)	0.2
2-63	0.2	0.005	—	—	(6-1)	0.2
2-64	0.2	0.001	—	—	(6-1)	0.2
2-65	0.2	0.0005	—	—	(6-1)	0.2
2-66	0.01	0.2	—	—	(7-1)	0.2
2-67	0.1	0.1	—	—	(7-1)	0.2
2-68	0.2	0.01	—	—	(7-1)	0.2
2-69	0.2	0.005	—	—	(7-1)	0.2
2-70	0.2	0.001	—	—	(7-1)	0.2
2-71	0.2	0.0005	—	—	(7-1)	0.2
2-72	0.01	0.2	(2-1)	0.2	(3-1)	0.2
2-73	0.1	0.1	(2-1)	0.2	(3-1)	0.2
2-74	0.2	0.01	(2-1)	0.2	(3-1)	0.2
2-75	0.2	0.005	(2-1)	0.2	(3-1)	0.2
2-76	0.2	0.001	(2-1)	0.2	(3-1)	0.2
2-77	0.2	0.0005	(2-1)	0.2	(3-1)	0.2
2-78	0.01	0.2	(2-2)	0.2	(3-1)	0.2
2-79	0.1	0.1	(2-2)	0.2	(3-1)	0.2
2-80	0.2	0.01	(2-2)	0.2	(3-1)	0.2
2-81	0.2	0.005	(2-2)	0.2	(3-1)	0.2
2-82	0.2	0.001	(2-2)	0.2	(3-1)	0.2
2-83	0.2	0.0005	(2-2)	0.2	(3-1)	0.2
2-84	0.01	0.2	(2-3)	0.2	(3-1)	0.2
2-85	0.1	0.1	(2-3)	0.2	(3-1)	0.2
2-86	0.2	0.01	(2-3)	0.2	(3-1)	0.2
2-87	0.2	0.005	(2-3)	0.2	(3-1)	0.2
2-88	0.2	0.001	(2-3)	0.2	(3-1)	0.2
2-89	0.2	0.0005	(2-3)	0.2	(3-1)	0.2

Example 2-90-Example 2-163

Production of Thermoplastic Polymer Composition

In the same manner as in Example 2-2 except that the thermoplastic polymers and processing stabilizers described in Table 8-1-Table 8-3 are used, thermoplastic polymer compositions are obtained as pellets.

The meanings of the abbreviations of the thermoplastic polymers described in Table 8-1-Table 8-3 are as follows.

P2-1: high density polyethylene (HDPE)P2-2: low density polyethylene (LDPE)P2-3: linear low density polyethylene (LLDPE)P2-4: ethylene-ethyl acrylate copolymer (EEA)P2-5: ethylene-vinyl acetate copolymer (EVA)P2-6: crystalline propylene homopolymerP2-7: propylene-ethylene random copolymerP2-8: propylene-α-olefin random copolymerP2-9: propylene-ethylene-α-olefin copolymerP2-10: polystyrene (PS)P2-11: acrylonitrile-styrene copolymer (SAN)P2-12: acrylonitrile-butadiene-styrene copolymer (ABS)P2-13: special acrylic rubber-acrylonitrile-styrene copolymerP2-14: acrylonitrile-chlorinated polyethylene-styrene copolymer (ACS)P2-15: polybutadiene rubber (BR)P2-16: styrene-butadiene copolymer (SB)P2-17: styrene-butadiene block copolymer (SBS)P2-18: chlorinated polyethylene (CPE)P2-19: polychloropreneP2-20: chlorinated rubberP2-21: poly(vinyl chloride) (PVC)P2-22: poly(vinylidene chloride) (PVDC)P2-23: methacrylate resinP2-24: fluororesinP2-25: polyacetal (POM)P2-26: grafted poly(phenylene ether) resinP2-27: poly(phenylene sulfide) resin (PPS)P2-28: polyurethane (PU)P2-29: polyamide (PA)P2-30: poly(ethylene terephthalate) (PET)P2-31: poly(butylene terephthalate) (PBT)P2-32: poly(lactic acid) (PLA)P2-33: polycarbonate (PC)P2-34: polyacrylateP2-35: polysulfone (PPSU)P2-36: poly(ether ether ketone) (PEEK)P2-37: poly(ether sulfone) (PES)P2-38: aromatic polyesterP2-39: diallyl phthalate prepolymerP2-40: silicone resin (SI)P2-41: 1,2-polybutadieneP2-42: polyisopreneP2-43: butadiene-acrylonitrile copolymer (NBR)P2-44: ethylene-methyl methacrylate copolymer (EMMA)

TABLE 8-1
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	2-90	P2-1	100	Ex. 2-1	0.11
	2-91	P2-2	100	Ex. 2-1	0.11
	2-92	P2-3	100	Ex. 2-1	0.11
	2-93	P2-3	100	Ex. 2-4	0.2
	2-94	P2-3	100	Ex. 2-5	0.2
	2-95	P2-3	100	Ex. 2-6	0.2
	2-96	P2-3	100	Ex. 2-9	0.201
	2-97	P2-3	100	Ex. 2-11	0.2002
	2-98	P2-4	100	Ex. 2-1	0.11
	2-99	P2-5	100	Ex. 2-1	0.11
	2-100	P2-6	100	Ex. 2-1	0.11
	2-101	P2-6	100	Ex. 2-4	0.2
	2-102	P2-6	100	Ex. 2-5	0.2
	2-103	P2-6	100	Ex. 2-6	0.2
	2-104	P2-6	100	Ex. 2-9	0.201
	2-105	P2-6	100	Ex. 2-11	0.2002
	2-106	P2-7	100	Ex. 2-1	0.11
	2-107	P2-8	100	Ex. 2-1	0.11
	2-108	P2-9	100	Ex. 2-1	0.11
	2-109	P2-10	100	Ex. 2-1	0.11
	2-110	P2-10	100	Ex. 2-4	0.2
	2-111	P2-10	100	Ex. 2-5	0.2
	2-112	P2-10	100	Ex. 2-6	0.2
	2-113	P2-10	100	Ex. 2-9	0.201
	2-114	P2-10	100	Ex. 2-11	0.2002

TABLE 8-2
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	2-115	P2-11	100	Ex. 2-1	0.11
	2-116	P2-12	100	Ex. 2-1	0.11
	2-117	P2-12	100	Ex. 2-4	0.2
	2-118	P2-12	100	Ex. 2-5	0.2
	2-119	P2-12	100	Ex. 2-6	0.2
	2-120	P2-12	100	Ex. 2-9	0.201
	2-121	P2-12	100	Ex. 2-11	0.2002
	2-122	P2-13	100	Ex. 2-1	0.11
	2-123	P2-14	100	Ex. 2-1	0.11
	2-124	P2-15	100	Ex. 2-1	0.11
	2-125	P2-16	100	Ex. 2-1	0.11
	2-126	P2-16	100	Ex. 2-4	0.2
	2-127	P2-16	100	Ex. 2-5	0.2
	2-128	P2-16	100	Ex. 2-6	0.2
	2-129	P2-16	100	Ex. 2-9	0.201
	2-130	P2-16	100	Ex. 2-11	0.2002
	2-131	P2-17	100	Ex. 2-1	0.11
	2-132	P2-17	100	Ex. 2-4	0.2
	2-133	P2-17	100	Ex. 2-5	0.2
	2-134	P2-17	100	Ex. 2-6	0.2
	2-135	P2-17	100	Ex. 2-9	0.201
	2-136	P2-17	100	Ex. 2-11	0.2002
	2-137	P2-18	100	Ex. 2-1	0.11
	2-138	P2-19	100	Ex. 2-1	0.11
	2-139	P2-20	100	Ex. 2-1	0.11

TABLE 8-3
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	2-140	P2-21	100	Ex. 2-1	0.11
	2-141	P2-22	100	Ex. 2-1	0.11
	2-142	P2-23	100	Ex. 2-1	0.11
	2-143	P2-24	100	Ex. 2-1	0.11
	2-144	P2-25	100	Ex. 2-1	0.11
	2-145	P2-26	100	Ex. 2-1	0.11
	2-146	P2-27	100	Ex. 2-1	0.11
	2-147	P2-28	100	Ex. 2-1	0.11
	2-148	P2-29	100	Ex. 2-1	0.11
	2-149	P2-30	100	Ex. 2-1	0.11
	2-150	P2-31	100	Ex. 2-1	0.11
	2-151	P2-32	100	Ex. 2-1	0.11
	2-152	P2-33	100	Ex. 2-1	0.11
	2-153	P2-34	100	Ex. 2-1	0.11
	2-154	P2-35	100	Ex. 2-1	0.11
	2-155	P2-36	100	Ex. 2-1	0.11
	2-156	P2-37	100	Ex. 2-1	0.11
	2-157	P2-38	100	Ex. 2-1	0.11
	2-158	P2-39	100	Ex. 2-1	0.11
	2-159	P2-40	100	Ex. 2-1	0.11
	2-160	P2-41	100	Ex. 2-1	0.11
	2-161	P2-42	100	Ex. 2-1	0.11
	2-162	P2-43	100	Ex. 2-1	0.11
	2-163	P2-44	100	Ex. 2-1	0.11

Example 3-1

Production of Processing Stabilizer

Compound (2-1) and compound (9-1) in the amounts described in Table 9 were mixed to produce a processing stabilizer.

Example 3-2

Production of Processing Stabilizer

Compound (2-1), compound (9-1) and compound (1-1) in the amounts described in Table 9 were mixed to produce a processing stabilizer.

Example 3-3

Production of Thermoplastic Polymer Composition

The processing stabilizer (0.21 part) obtained in Example 2-1 and a styrene-butadiene block copolymer (“Asaflex 830” manufactured by Asahi Kasei Corp.) (100 parts) were dry-blended, the obtained mixture was knead-extruded by a single screw extruder having a screw diameter of 30 mm (“VS30-28 type extruder” manufactured by TANABE PLASTICS MACHINERY CO., LTD.) under the conditions of temperature 230° C. and screw rotation 50 rpm to give strands, and the strands were cut by a pelletizer to give a thermoplastic polymer composition as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 10.

Example 3-4

Production of Thermoplastic Polymer Composition

In the same manner as in Example 3-3 except that the stabilizer composition (0.51 part) obtained in Example 3-2 was used instead of the stabilizer composition obtained in Example 3-1, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 10.

Comparative Example 3-1

Production of Thermoplastic Polymer Composition

In the same manner as in Example 3-3 except that compound (2-1) (0.2 part) alone was used instead of the processing stabilizer obtained in Example 3-1, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 10.

Example 3-5

Production of Processing Stabilizer

Compound (2-2) and compound (9-1) in the amounts described in Table 9 were mixed to produce a processing stabilizer.

Example 3-6

Production of Thermoplastic Polymer Composition

In the same manner as in Example 3-3 except that the processing stabilizer (0.2 part) obtained in Example 3-5 was used instead of the processing stabilizer obtained in Example 3-1, and polypropylene (“NOBRENE” manufactured by Sumitomo Chemical Company, Limited) (100 parts) was used instead of a styrene-butadiene block copolymer, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 10.

Comparative Example 3-2

Production of Thermoplastic Polymer Composition

In the same manner as in Example 3-6 except that compound (2-2) (0.1 part) alone was used instead of the processing stabilizer obtained in Example 3-5, a thermoplastic polymer composition was obtained as pellets. The results of the processing stability of the obtained thermoplastic polymer composition are shown in Table 10.

TABLE 9
processing stabilizer
	compound (2)	compound	compound
	kind	amount (part)	(9-1) (part)	(1-1) (part)
Ex. 3-1	(2-1)	0.2	0.01	—
Ex. 3-2	(2-1)	0.2	0.01	0.3
Ex. 3-5	(2-2)	0.1	0.1	—

TABLE 10
thermoplastic polymer composition
	thermo-				MFR
	plastic	processing	0 min	30 min	varia-
	polymer	stabilizer	Dwell	Dwell	tion
	SBS	PP		amount	MFR	MFR	rate
	(part)	(part)	kind	(part)	(g/10 min)	(g/10 min)	(%)
Ex.	100	—	Ex.	0.21	14.9	1.2	91.9
3-3			3-1
Ex.	100	—	Ex.	0.51	18.9	5.8	67.8
3-4			3-2
Comp.	100	—	com-	0.2	16.2	0.6	96.3
Ex.			pound
3-1			(2-1)
Ex.	—	100	Ex.	0.2	17.2	19.4	12.8
3-6			3-5
Comp.	—	100	com-	0.1	19.3	22.8	18.1
Ex.			pound
3-2			(2-2)
SBS: styrene-butadiene block copolymer
PP: polypropylene

From the results shown in Table 10, it is clear that a combined use of compound (2) and compound (9) improves the processing stability as compared to a single use of compound (2). In addition, it is clear that the processing stability is improved by using compound (9) in combination, even when compound (1) is used in addition to compound (2).

Example 3-7-Example 3-75

Production of Processing Stabilizer

By mixing the components described in Table 11-1-Table 11-3, processing stabilizers are obtained.

TABLE 11-1
processing stabilizer
	compound	compound	compound	compounds	compound
	(2)	(9)	(1)	(3)-(7)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
3-7	(2-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
3-8	(2-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
3-9	(2-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
3-10	(2-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
3-11	(2-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
3-12	(2-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
3-13	(2-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
3-14	(2-2)	0.01	(9-1)	0.2	—	—	—	—	—	—
3-15	(2-2)	0.05	(9-1)	0.15	—	—	—	—	—	—
3-16	(2-2)	0.1	(9-1)	0.1	—	—	—	—	—	—
3-17	(2-2)	0.15	(9-1)	0.05	—	—	—	—	—	—
3-18	(2-2)	0.2	(9-1)	0.01	—	—	—	—	—	—
3-19	(2-2)	0.2	(9-1)	0.001	—	—	—	—	—	—
3-20	(2-2)	0.2	(9-1)	0.0002	—	—	—	—	—	—
3-21	(2-3)	0.01	(9-1)	0.2	—	—	—	—	—	—
3-22	(2-3)	0.05	(9-1)	0.15	—	—	—	—	—	—
3-23	(2-3)	0.1	(9-1)	0.1	—	—	—	—	—	—
3-24	(2-3)	0.15	(9-1)	0.05	—	—	—	—	—	—
3-25	(2-3)	0.2	(9-1)	0.01	—	—	—	—	—	—
3-26	(2-3)	0.2	(9-1)	0.001	—	—	—	—	—	—
3-27	(2-3)	0.2	(9-1)	0.0002	—	—	—	—	—	—
3-28	(2-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
3-29	(2-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—

	TABLE 11-2
	compound	compound	compound	compounds	compound
	(2)	(9)	(1)	(3)-(7)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
3-30	(2-1)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
3-31	(2-2)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
3-32	(2-2)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
3-33	(2-2)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
3-34	(2-3)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
3-35	(2-3)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
3-36	(2-3)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
3-37	(2-1)	0.01	(9-1)	0.2	(1-2)	0.2	—	—	—	—
3-38	(2-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
3-39	(2-1)	0.2	(9-1)	0.0002	(1-2)	0.2	—	—	—	—
3-40	(2-1)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	—	—
3-41	(2-2)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	—	—
3-42	(2-3)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	—	—
3-43	(2-1)	0.2	(9-1)	0.01	—	—	(4-1)	0.2	—	—
3-44	(2-2)	0.2	(9-1)	0.01	—	—	(4-1)	0.2	—	—
3-45	(2-3)	0.2	(9-1)	0.01	—	—	(4-1)	0.2	—	—
3-46	(2-1)	0.2	(9-1)	0.01	—	—	(5-1)	0.2	—	—
3-47	(2-2)	0.2	(9-1)	0.01	—	—	(5-1)	0.2	—	—
3-48	(2-3)	0.2	(9-1)	0.01	—	—	(5-1)	0.2	—	—
3-49	(2-1)	0.2	(9-1)	0.01	—	—	(5-2)	0.2	—	—
3-50	(2-2)	0.2	(9-1)	0.01	—	—	(5-2)	0.2	—	—
3-51	(2-3)	0.2	(9-1)	0.01	—	—	(5-2)	0.2	—	—
3-52	(2-1)	0.2	(9-1)	0.01	—	—	(5-3)	0.2	—	—

TABLE 11-3
processing stabilizer
	compound	compound	compound	compound	compound
	(2)	(9)	(1)	(3)-(7)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
3-53	(2-2)	0.2	(9-1)	0.01	—	—	(5-3)	0.2	—	—
3-54	(2-3)	0.2	(9-1)	0.01	—	—	(5-3)	0.2	—	—
3-55	(2-1)	0.2	(9-1)	0.01	—	—	(6-1)	0.2	—	—
3-56	(2-2)	0.2	(9-1)	0.01	—	—	(6-1)	0.2	—	—
3-57	(2-3)	0.2	(9-1)	0.01	—	—	(6-1)	0.2	—	—
3-58	(2-1)	0.2	(9-1)	0.01	—	—	(7-1)	0.2	—	—
3-59	(2-2)	0.2	(9-1)	0.01	—	—	(7-1)	0.2	—	—
3-60	(2-3)	0.2	(9-1)	0.01	—	—	(7-1)	0.2	—	—
3-61	(2-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
3-62	(2-2)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
3-63	(2-3)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
3-64	(2-1)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	—	—
3-65	(2-2)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	—	—
3-66	(2-3)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	—	—
3-67	(2-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
3-68	(2-2)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
3-69	(2-3)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
3-70	(2-1)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	(8-1)	0.2
3-71	(2-2)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	(8-1)	0.2
3-72	(2-3)	0.2	(9-1)	0.01	—	—	(3-1)	0.2	(8-1)	0.2
3-73	(2-1)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	(8-1)	0.2
3-74	(2-2)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	(8-1)	0.2
3-75	(2-3)	0.2	(9-1)	0.01	(1-1)	0.2	(3-1)	0.2	(8-1)	0.2

Example 3-76-Example 3-131

Production of Thermoplastic Polymer Composition

In the same manner as in Example 3-3 except that the thermoplastic polymers and processing stabilizers described in Table 12-1 and Table 12-2 are used, thermoplastic polymer compositions are obtained as pellets.

The meanings of the abbreviations of the thermoplastic polymers described in Table 12-1 and Table 12-2 are as follows.

P3-1: high density polyethylene (HDPE)P3-2: low density polyethylene (LDPE)P3-3: linear low density polyethylene (LLDPE)P3-4: ethylene-vinyl alcohol copolymer (EVOH)P3-5: ethylene-ethyl acrylate copolymer (EEA)P3-6: ethylene-vinyl acetate copolymer (EVA)P3-7: propylene-ethylene random copolymerP3-8: propylene-α-olefin random copolymerP3-9: propylene-ethylene-α-olefin copolymerP3-10: polystyrene (PS)P3-11: acrylonitrile-styrene copolymer (SAN)P3-12: acrylonitrile-butadiene-styrene copolymer (ABS)P3-13: special acrylic rubber-acrylonitrile-styrene copolymerP3-14: acrylonitrile-chlorinated polyethylene-styrene copolymer (ACS)P3-15: polybutadiene rubber (BR)P3-16: styrene-butadiene copolymer (SB)P3-17: styrene-butadiene block copolymer (SBS)P3-18: chlorinated polyethylene (CPE)P3-19: polychloropreneP3-20: chlorinated rubberP3-21: polyvinyl chloride) (PVC)P3-22: poly(vinylidene chloride) (PVDC)P3-23: methacrylate resinP3-24: fluororesinP3-25: polyacetal (POM)P3-26: grafted poly(phenylene ether) resinP3-27: poly(phenylene sulfide) resin (PPS)P3-28: polyurethane (PU)P3-29: polyamide (PA)P3-30: poly(ethylene terephthalate) (PET)P3-31: poly(butylene terephthalate) (PBT)P3-32: poly(lactic acid) (PLA)P3-33: polycarbonate (PC)P3-34: polyacrylateP3-35: polysulfone (PPSU)P3-36: poly(ether ether ketone) (PEEK)P3-37: poly(ether sulfone) (PES)P3-38: aromatic polyesterP3-39: diallyl phthalate prepolymerP3-40: silicone resin (SI)P3-41: 1,2-polybutadieneP3-42: polyisopreneP3-43: butadiene-acrylonitrile copolymer (NBR)P3-44: ethylene-methyl methacrylate copolymer (EMMA)

TABLE 12-1
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	3-76	P3-1	100	Ex. 3-1	0.21
	3-77	P3-2	100	Ex. 3-1	0.21
	3-78	P3-3	100	Ex. 3-1	0.21
	3-79	P3-3	100	Ex. 3-2	0.51
	3-80	P3-3	100	Ex. 3-40	0.41
	3-81	P3-3	100	Ex. 3-64	0.61
	3-82	P3-4	100	Ex. 3-1	0.21
	3-83	P3-4	100	Ex. 3-2	0.51
	3-84	P3-4	100	Ex. 3-40	0.41
	3-85	P3-4	100	Ex. 3-64	0.61
	3-86	P3-5	100	Ex. 3-1	0.21
	3-87	P3-6	100	Ex. 3-1	0.21
	3-88	P3-7	100	Ex. 3-1	0.21
	3-89	P3-8	100	Ex. 3-1	0.21
	3-90	P3-9	100	Ex. 3-1	0.21
	3-91	P3-10	100	Ex. 3-1	0.21
	3-92	P3-10	100	Ex. 3-2	0.51
	3-93	P3-10	100	Ex. 3-40	0.41
	3-94	P3-10	100	Ex. 3-64	0.61
	3-95	P3-11	100	Ex. 3-1	0.21
	3-96	P3-12	100	Ex. 3-1	0.21
	3-97	P3-12	100	Ex. 3-2	0.51
	3-98	P3-12	100	Ex. 3-40	0.41
	3-99	P3-12	100	Ex. 3-64	0.61
	3-100	P3-13	100	Ex. 3-1	0.21
	3-101	P3-14	100	Ex. 3-1	0.21
	3-102	P3-15	100	Ex. 3-1	0.21
	3-103	P3-16	100	Ex. 3-1	0.21

TABLE 12-2
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	3-104	P3-17	100	Ex. 3-1	0.21
	3-105	P3-18	100	Ex. 3-1	0.21
	3-106	P3-19	100	Ex. 3-1	0.21
	3-107	P3-20	100	Ex. 3-1	0.21
	3-108	P3-21	100	Ex. 3-1	0.21
	3-109	P3-22	100	Ex. 3-1	0.21
	3-110	P3-23	100	Ex. 3-1	0.21
	3-111	P3-24	100	Ex. 3-1	0.21
	3-112	P3-25	100	Ex. 3-1	0.21
	3-113	P3-26	100	Ex. 3-1	0.21
	3-114	P3-27	100	Ex. 3-1	0.21
	3-115	P3-28	100	Ex. 3-1	0.21
	3-116	P3-29	100	Ex. 3-1	0.21
	3-117	P3-30	100	Ex. 3-1	0.21
	3-118	P3-31	100	Ex. 3-1	0.21
	3-119	P3-32	100	Ex. 3-1	0.21
	3-120	P3-33	100	Ex. 3-1	0.21
	3-121	P3-34	100	Ex. 3-1	0.21
	3-122	P3-35	100	Ex. 3-1	0.21
	3-123	P3-36	100	Ex. 3-1	0.21
	3-124	P3-37	100	Ex. 3-1	0.21
	3-125	P3-38	100	Ex. 3-1	0.21
	3-126	P3-39	100	Ex. 3-1	0.21
	3-127	P3-40	100	Ex. 3-1	0.21
	3-128	P3-41	100	Ex. 3-1	0.21
	3-129	P3-42	100	Ex. 3-1	0.21
	3-130	P3-43	100	Ex. 3-1	0.21
	3-131	P3-44	100	Ex. 3-1	0.21

Example 4-1

Production of Processing Stabilizer

Compound (3-1) (0.1 part) and compound (9-1) (0.01 part) were mixed to produce a processing stabilizer.

Example 4-2

Production of Thermoplastic Polymer Composition

The processing stabilizer (0.11 part) obtained in Example 4-1 and polypropylene (“NOBRENE” manufactured by Sumitomo Chemical Company, Limited) (100 parts) were dry-blended, the obtained mixture was knead-extruded by a single screw extruder having a screw diameter of 30 mm (“VS30-28 type extruder” manufactured by TANABE PLASTICS MACHINERY CO., LTD.) at temperature 230° C. and screw rotation 50 rpm to give strands, and the strands were cut by a pelletizer to give a thermoplastic polymer composition as pellets.

Comparative Example 4-1

In the same manner as in Example 4-2 except that compound (3-1) (0.1 part) alone was used instead of the processing stabilizer obtained in Example 4-1, a thermoplastic polymer composition was obtained as pellets.

The composition of the processing stabilizer obtained in Example 4-1 is shown in Table 13, and the compositions and the results of processing stability of the thermoplastic polymer compositions obtained in Example 4-2 and Comparative Example 4-1 are shown in Table 14.

TABLE 13
processing stabilizer
	compound	compound	mass ratio of compound
	(3-1) (part)	(9-1) (part)	(3-1):compound (9-1)
Ex. 4-1	0.1	0.01	10:1

TABLE 14
thermoplastic polymer composition
	thermoplastic	processing	30 min	inhibition
	polymer	stabilizer	Dwell	rate of MFR
	polypropylene		amount	MFR	increment
	(part)	kind	(part)	(g/10 min)	(%)
Ex. 4-2	100	Ex. 4-1	0.11	11.3	29.4
Comp.	100	compound	0.1	16.0	—
Ex. 4-1		(3-1)

Example 4-3-Example 4-132

Production of Processing Stabilizer

By mixing the components described in Table 15-1-Table 15-4, processing stabilizers are obtained. These processing stabilizers are predicted to improve the processing stability of a thermoplastic polymer composition (that is, inhibiting MFR variation rate or increasing inhibition rate of MFR increment).

TABLE 15-1
processing stabilizer
	compounds	compound	compound	compound	compound
	(3)-(7)	(9)	(1)	(2)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
4-3	(3-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-4	(3-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-5	(3-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-6	(3-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-7	(3-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-8	(3-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-9	(3-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-10	(4-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-11	(4-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-12	(4-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-13	(4-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-14	(4-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-15	(4-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-16	(4-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-17	(5-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-18	(5-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-19	(5-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-20	(5-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-21	(5-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-22	(5-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-23	(5-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-24	(5-2)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-25	(5-2)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-26	(5-2)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-27	(5-2)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-28	(5-2)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-29	(5-2)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-30	(5-2)	0.2	(9-1)	0.0002	—	—	—	—	—	—

TABLE 15-2
processing stabilizer
	compounds	compound	compound	compound	compound
	(3)-(7)	(9)	(1)	(2)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
4-31	(5-3)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-32	(5-3)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-33	(5-3)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-34	(5-3)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-35	(5-3)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-36	(5-3)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-37	(5-3)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-38	(6-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-39	(6-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-40	(6-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-41	(6-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-42	(6-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-43	(6-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-44	(6-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-45	(7-1)	0.01	(9-1)	0.2	—	—	—	—	—	—
4-46	(7-1)	0.05	(9-1)	0.15	—	—	—	—	—	—
4-47	(7-1)	0.1	(9-1)	0.1	—	—	—	—	—	—
4-48	(7-1)	0.15	(9-1)	0.05	—	—	—	—	—	—
4-49	(7-1)	0.2	(9-1)	0.01	—	—	—	—	—	—
4-50	(7-1)	0.2	(9-1)	0.001	—	—	—	—	—	—
4-51	(7-1)	0.2	(9-1)	0.0002	—	—	—	—	—	—
4-52	(3-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-53	(3-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-54	(3-1)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
4-55	(4-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-56	(4-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-57	(4-1)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
4-58	(5-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-59	(5-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-60	(5-2)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
4-61	(5-2)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-62	(5-2)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-63	(5-3)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
4-64	(6-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-65	(6-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-66	(6-1)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—
4-67	(7-1)	0.01	(9-1)	0.2	(1-1)	0.2	—	—	—	—
4-68	(7-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	—	—
4-69	(7-1)	0.2	(9-1)	0.0002	(1-1)	0.2	—	—	—	—

TABLE 15-3
processing stabilizer
	compounds	compound	compound	compound	compound
	(3)-(7)	(9)	(1)	(2)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
4-70	(3-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-71	(4-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-72	(5-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-73	(5-2)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-74	(5-3)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-75	(6-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-76	(7-1)	0.2	(9-1)	0.01	(1-2)	0.2	—	—	—	—
4-77	(3-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-78	(4-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-79	(5-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-80	(5-2)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-81	(5-3)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-82	(6-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-83	(7-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	—	—
4-84	(3-1)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-85	(4-1)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-86	(5-1)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-87	(5-2)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-88	(5-3)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-89	(6-1)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-90	(7-1)	0.2	(9-1)	0.01	—	—	(2-2)	0.2	—	—
4-91	(3-1)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-92	(4-1)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-93	(5-1)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-94	(5-2)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-95	(5-3)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-96	(6-1)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-97	(7-1)	0.2	(9-1)	0.01	—	—	(2-3)	0.2	—	—
4-98	(3-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-99	(4-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-100	(5-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-101	(5-2)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-102	(5-3)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-103	(6-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2
4-104	(7-1)	0.2	(9-1)	0.01	—	—	—	—	(8-1)	0.2

TABLE 15-4
processing stabilizer
	compounds	compound	compound	compound	compound
	(3)-(7)	(9)	(1)	(2)	(8)
		amount		amount		amount		amount		amount
Example	kind	(part)	kind	(part)	kind	(part)	kind	(part)	kind	(part)
4-105	(3-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-106	(4-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-107	(5-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-108	(5-2)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-109	(5-3)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-110	(6-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-111	(7-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	—	—
4-112	(3-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-113	(4-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-114	(5-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-115	(5-2)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-116	(5-3)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-117	(6-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-118	(7-1)	0.2	(9-1)	0.01	(1-1)	0.2	—	—	(8-1)	0.2
4-119	(3-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-120	(4-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-121	(5-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-122	(5-2)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-123	(5-3)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-124	(6-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-125	(7-1)	0.2	(9-1)	0.01	—	—	(2-1)	0.2	(8-1)	0.2
4-126	(3-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-127	(4-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-128	(5-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-129	(5-2)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-130	(5-3)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-131	(6-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2
4-132	(7-1)	0.2	(9-1)	0.01	(1-1)	0.2	(2-1)	0.2	(8-1)	0.2

Example 4-133-Example 4-196

Production of Thermoplastic Polymer Composition

In the same manner as in Example 4-2 except that the thermoplastic polymers and processing stabilizers described in Table 16-1 and Table 16-2 are used, thermoplastic polymer compositions are obtained as pellets. The obtained thermoplastic polymer compositions are predicted to be superior in processing stability.

The meanings of the abbreviations of the thermoplastic polymers described in Table 16-1 and Table 16-2 are as follows.

P4-1: high density polyethylene (HDPE)P4-2: low density polyethylene (LDPE)P4-3: linear low density polyethylene (LLDPE)P4-4: ethylene-vinyl alcohol copolymer (EVOH)P4-5: ethylene-ethyl acrylate copolymer (EEA)P4-6: ethylene-vinyl acetate copolymer (EVA)P4-7: propylene-ethylene random copolymerP4-8: propylene-α-olefin random copolymerP4-9: propylene-ethylene-α-olefin copolymerP4-10: polystyrene (PS)P4-11: acrylonitrile-styrene copolymer (SAN)P4-12: acrylonitrile-butadiene-styrene copolymer (ABS)P4-13: special acrylic rubber-acrylonitrile-styrene copolymerP4-14: acrylonitrile-chlorinated polyethylene-styrene copolymer (ACS)P4-15: polybutadiene rubber (BR)P4-16: styrene-butadiene copolymer (SB)P4-17: styrene-butadiene block copolymer (SBS)P4-18: chlorinated polyethylene (CPE)P4-19: polychloropreneP4-20: chlorinated rubberP4-21: poly(vinyl chloride) (PVC)P4-22: poly(vinylidene chloride) (PVDC)P4-23: methacrylate resinP4-24: fluororesinP4-25: polyacetal (POM)P4-26: grafted poly(phenylene ether) resinP4-27: poly(phenylene sulfide) resin (PPS)P4-28: polyurethane (PU)P4-29: polyamide (PA)P4-30: poly(ethylene terephthalate)(PET)P4-31: poly(butylene terephthalate)(PBT)P4-32: poly(lactic acid) (PLA)P4-33: polycarbonate (PC)P4-34: polyacrylateP4-35: polysulfone (PPSU)P4-36: poly(ether ether ketone) (PEEK)P4-37: poly(ether sulfone) (PES)P4-38: aromatic polyesterP4-39: diallyl phthalate prepolymerP4-40: silicone resin (SI)P4-41: 1,2-polybutadieneP4-42: polyisopreneP4-43: butadiene-acrylonitrile copolymer (NBR)P4-44: ethylene-methyl methacrylate copolymer (EMMA)

TABLE 16-1
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	4-133	P4-1	100	Ex. 4-1	0.11
	4-134	P4-2	100	Ex. 4-1	0.11
	4-135	P4-3	100	Ex. 4-1	0.11
	4-136	P4-3	100	Ex. 4-42	0.21
	4-137	P4-3	100	Ex. 4-53	0.41
	4-138	P4-3	100	Ex. 4-79	0.41
	4-139	P4-3	100	Ex. 4-105	0.61
	4-140	P4-4	100	Ex. 4-1	0.11
	4-141	P4-4	100	Ex. 4-42	0.21
	4-142	P4-4	100	Ex. 4-53	0.41
	4-143	P4-4	100	Ex. 4-79	0.41
	4-144	P4-4	100	Ex. 4-105	0.61
	4-145	P4-5	100	Ex. 4-1	0.11
	4-146	P4-6	100	Ex. 4-1	0.11
	4-147	P4-7	100	Ex. 4-1	0.11
	4-148	P4-8	100	Ex. 4-1	0.11
	4-149	P4-9	100	Ex. 4-1	0.11
	4-150	P4-10	100	Ex. 4-1	0.11
	4-151	P4-10	100	Ex. 4-42	0.21
	4-152	P4-10	100	Ex. 4-53	0.41
	4-153	P4-10	100	Ex. 4-79	0.41
	4-154	P4-10	100	Ex. 4-105	0.61
	4-155	P4-11	100	Ex. 4-1	0.11
	4-156	P4-12	100	Ex. 4-1	0.11
	4-157	P4-12	100	Ex. 4-42	0.21
	4-158	P4-12	100	Ex. 4-53	0.41
	4-159	P4-12	100	Ex. 4-79	0.41
	4-160	P4-12	100	Ex. 4-105	0.61
	4-161	P4-13	100	Ex. 4-1	0.11
	4-162	P4-14	100	Ex. 4-1	0.11
	4-163	P4-15	100	Ex. 4-1	0.11
	4-164	P4-16	100	Ex. 4-1	0.11
	4-165	P4-17	100	Ex. 4-1	0.11
	4-166	P4-17	100	Ex. 4-42	0.21
	4-167	P4-17	100	Ex. 4-53	0.41
	4-168	P4-17	100	Ex. 4-79	0.41
	4-169	P4-17	100	Ex. 4-105	0.61

TABLE 16-2
thermoplastic polymer composition
	thermoplastic polymer		processing stabilizer
			amount		amount
	Example	kind	(part)	kind	(part)
	4-170	P4-18	100	Ex. 4-1	0.11
	4-171	P4-19	100	Ex. 4-1	0.11
	4-172	P4-20	100	Ex. 4-1	0.11
	4-173	P4-21	100	Ex. 4-1	0.11
	4-174	P4-22	100	Ex. 4-1	0.11
	4-175	P4-23	100	Ex. 4-1	0.11
	4-176	P4-24	100	Ex. 4-1	0.11
	4-177	P4-25	100	Ex. 4-1	0.11
	4-178	P4-26	100	Ex. 4-1	0.11
	4-179	P4-27	100	Ex. 4-1	0.11
	4-180	P4-28	100	Ex. 4-1	0.11
	4-181	P4-29	100	Ex. 4-1	0.11
	4-182	P4-30	100	Ex. 4-1	0.11
	4-183	P4-31	100	Ex. 4-1	0.11
	4-184	P4-32	100	Ex. 4-1	0.11
	4-185	P4-33	100	Ex. 4-1	0.11
	4-186	P4-34	100	Ex. 4-1	0.11
	4-187	P4-35	100	Ex. 4-1	0.11
	4-188	P4-36	100	Ex. 4-1	0.11
	4-189	P4-37	100	Ex. 4-1	0.11
	4-190	P4-38	100	Ex. 4-1	0.11
	4-191	P4-39	100	Ex. 4-1	0.11
	4-192	P4-40	100	Ex. 4-1	0.11
	4-193	P4-41	100	Ex. 4-1	0.11
	4-194	P4-42	100	Ex. 4-1	0.11
	4-195	P4-43	100	Ex. 4-1	0.11
	4-196	P4-44	100	Ex. 4-1	0.11

INDUSTRIAL APPLICABILITY

The thermoplastic polymer composition of the present invention containing compound (1), compound (2), at least one selected from the group consisting of compound (3)-compound (7), or compound (8) and compound (9) shows superior processing stability. The thermoplastic polymer composition of the present invention can be used for production of, for example, electronic component, automobile part, clock component, camera component, component of leisure goods and the like.

Claims

1. A thermoplastic polymer composition comprising a compound represented by the formula (1):

2. The thermoplastic polymer composition according to claim 1, wherein the total amount of the compound represented by the formula (1) and compound (9) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.

3. A processing stabilizer comprising a compound represented by the formula (1):

4. The processing stabilizer according to claim 3, wherein the compound represented by the formula (1) is at least one selected from the group consisting of 2,4-di-t-pentyl-6-[1-(3,5-di-t-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate and 2-t-butyl-6-(3-t-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate.

5. The processing stabilizer according to claim 3 or 4, wherein m is 6.

6. The processing stabilizer according to claim 5, wherein compound (9) is methyl α-D-glucopyranoside.

7. The processing stabilizer according to claim 3 or 4, wherein the content of compound (9) is 0.1-95 wt % of the total of a compound represented by the formula (1) and compound (9).

8. The processing stabilizer according to claim 3 or 4, further comprising a compound represented by the formula (2):

9. The processing stabilizer according to claim 3 or 4, further comprising at least one selected from the group consisting of the compounds represented by the formulas (3)-(7):

10. The processing stabilizer according to claim 3 or 4, further comprising a compound represented by the formula (3):

11. A thermoplastic polymer composition comprising a compound represented by the formula (8):

12. The thermoplastic polymer composition according to claim 11, wherein the total amount of the compound represented by the formula (8) and compound (9) is 0.001-3 parts by weight relative to 100 parts by weight of the thermoplastic polymer.

13.-34. (canceled)